CN102085162B - Face cleansing emulsion without surfactant and preparation method thereof - Google Patents
Face cleansing emulsion without surfactant and preparation method thereof Download PDFInfo
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- CN102085162B CN102085162B CN 201110007273 CN201110007273A CN102085162B CN 102085162 B CN102085162 B CN 102085162B CN 201110007273 CN201110007273 CN 201110007273 CN 201110007273 A CN201110007273 A CN 201110007273A CN 102085162 B CN102085162 B CN 102085162B
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Abstract
The invention discloses an oil-in-water type face cleansing emulsion which comprises 5-20% by weight of oil phase and 80-95% by weight of water phase, the oil-in-water type face cleansing emulsion does not contain a surfactant, and 0.1-5% by weight of stabilizer is contained in water-based ingredients for constituting the water phase relative to the total weight of a composition. The face cleansing emulsion does not use the surfactant, and phase inversion can be promoted by a small amount of oil, thereby providing initial dissolving power for cosmetic ingredients and full face cleansing power. The hand feeling which is not greasy, light and slippery can not cause burden on skin, and the face cleansing emulsion has the effect of reducing cost; as the surfactant is not used, a face cleansing product which is very safe to the skin can be provided.
Description
Technical field
The present invention relates to a kind of face cleansing emulsion, more specifically, the present invention relates to a kind ofly also can remove cosmetic ingredient fully with a small amount of oil, do not contain surfactant, the oil-in-water type that the skin safe performance is very high (O/W) face cleansing emulsion.
Background technology
Usually, existing clean product removing cosmetic ingredient can be divided into two classes: a class is to use the system of exhibiting high surface activating agent in order to wash; Another kind of is common clean product.Light water oil-in (O/W) Emulsion can be divided into two classes: namely, one class is that the oil content as interior phase is 50-70%, will phase inversion (phenomenon that the oil of interior phase flows out toward the foreign minister) when hands slides, will be dissolved with the cosmetics residue that oily composition affinity is high, reach the Emulsion of clean effect with this; Another kind of is that interior phase (oil phase) is 15-30%, with the less face cleansing emulsion of oil.With regard to the former, entering phase inversion also needs a little times, also very greasy because of a large amount of oil and not salubrious sense behind the phase inversion.Moreover, may bring stimulation and cause burden oily skin, so the cutaneous safety problem occurs easily.In addition, because many with oil mass, consider that from manufacturer's position the cost aspect can cause burden.In addition, with regard to latter's face cleansing emulsion, because interior phase (oil phase) is few, be difficult for forming phase inversion, cosmetics residue solvability also can reduce, and in a word, much can't remove cosmetic ingredient fully because clean power reduces.Moreover, do not entering under the state of phase inversion, can firmly smear because of the dry and astringent nature of the feel of smearing, the friction of this moment is with Diazolidinyl Urea, and in the time of clean, clean product can be inhaled into skin.
Summary of the invention
In order to overcome defects, the invention provides a kind of oil-in-water type face cleansing emulsion, comprise the oil phase of 5-20wt% and the water of 80-95wt%, wherein do not contain surfactant, in the aqueous composition that forms water, with respect to the gross weight of compositions, comprise the stabilizing agent of 0.1-5.0wt%.
Wherein form the oil phase composition and be selected from one or more combination in hydrocarbon, senior ethanol high-grade aliphatic ester class, senior alcohol type, higher fatty acids esters, triglyceride and the silicone oil; Wherein hydrocarbon can be Dormant oils, paraffin oil, Squalene etc.; Senior ethanol high-grade aliphatic ester class can be cetyl monooctyl ester, isopropyl myristate, isopropyl palmitate, octyldodecanol myristinate, sad hexadecyl ester, glyceryl stearate etc.; Senior alcohol type can be spermol, isopropyl alcohol, isooctadecanol etc.; The higher fatty acids class can be stearic acid, Palmic acid, lauric acid etc.; Iriglycerides can be caprylic/capric triglyceride, hydrogenation C12-18 acid glycerol three esters, oleic acid/linoleic acid triglyceride etc.From considering the combination of one or more in the preferred isopropyl myristate of oiliness composition, isopropyl palmitate, octyldodecanol myristinate, the sad hexadecyl ester with affinity and the removal efficient aspect of cosmetic ingredient.If the oiliness composition is less than 5wt%, then can not fully remove cosmetics, and when surpassing 20wt%, just as said in the prior art, have heavy burden sense and greasy feeling, therefore the oil phase that forms of this type of oiliness composition 5-20wt% of present composition gross weight preferably, preferred 5-15wt%, more preferably 5-10wt%.
Wherein, described stabilizing agent is selected from more than one in the alkyl acrylate polymer, carboxymethyl cellulose, hydroxyethyl-cellulose, polyacrylamide, metering system polyglycerol, xanthan gum, sodium magnesium silicate of CVP Carbopol ETD2050, acrylate/C10-30 and the group that zeopan forms.
Face cleansing emulsion of the present invention does not use surfactant, and can promote phase inversion with a small amount of oil yet, provides cosmetic ingredient initial stage dissolving power and sufficient clean power with this.Non-greasy and slim and graceful feel of sliding can not cause burden to skin, have the cost effectiveness of reduction.Because not using surfactant can provide clean very safe product of skin.
Description of drawings
Fig. 1 is the forearm inside line, and the front picture of the strong lipstick of vitality is smeared at 2 positions of 3x3cm size;
Fig. 2 is the picture of smearing behind the strong lipstick of vitality;
Fig. 3 smears clean the picture behind the product in the position, both sides; (1) and (2) in left side is that clean product of embodiment 1 and comparative example 1 smeared picture among the present invention, and (3) on right side and (4) are that clean product of comparative example 3 and comparative example 4 smeared picture;
Fig. 4 is with clean of separately clean product, and stays view on the skin with lipstick after the cotton paper wiping, and wherein (1) is embodiment 1, and (2) are comparative example 1, and (3) are comparative example 2, and (4) are comparative example 3.
The specific embodiment
Describe the present invention in detail below with reference to the specific embodiment, but the specific embodiment is only to having invented the explanation effect, the protection domain that is not intended to limit the present invention.
Clean the product of embodiment 1 and comparative example 1-3 is Emulsion, and it forms as shown in table 1 separately, and its preparation method is as follows:
(1) the oiliness composition of embodiment 1 and comparative example 1 is evenly to mix at room temperature.
(2) comparative example 2 and 3 oiliness composition are at mixed uniformly 70 degree that are heated to simultaneously.
(3) the aqueous composition of embodiment 1 and comparative example 1 is uniformly mixed at room temperature after, drop into respectively the oiliness composition of above-mentioned (1), obtain clean product of embodiment 1 and comparative example 1 with this.
(4) the aqueous composition with comparative example 2 and 3 is heated to the rear stirring of 70 degree, then drops into respectively the oiliness composition of above-mentioned (2), obtains clean product of comparative example 2 and 3 with this.
The composition of table 1 embodiment 1 and comparative example 1-3
Experimental example 1
Clean product for comparing embodiment 1 and comparative example 1-3 manufacturing, specify 2 positions of 3x3cm size at measured's both sides forearm inside line, evenly smear the high lipstick of persistence, place 10 minutes (drying), then use clean the product of above-described embodiment 1 and comparative example 1-3, draw herein circle 5 times with identical pressure, and wipe lipstick and clean the product that dissolves with cotton paper, the last degree of lipstick after clean is compared.Experimentation is shown in accompanying drawing 1-4.Fig. 1 is the forearm inside line, and the front picture of the strong lipstick of vitality is smeared at 2 positions of 3x3cm size; Fig. 2 is the picture of smearing behind the strong lipstick of vitality; Fig. 3 smears clean the picture behind the product in the position, both sides; (1) and (2) in left side is that clean product of embodiment 1 and comparative example 1 smeared picture among the present invention, and (3) on right side and (4) are that clean product of comparative example 3 and comparative example 4 smeared picture; Fig. 4 is with clean of separately clean product, and stays view on the skin with lipstick after the cotton paper wiping, and wherein (1) is embodiment 1, and (2) are comparative example 1, and (3) are comparative example 2, and (4) are comparative example 3.
From the above results as can be known, removing clean minimum product of cosmetics ability is clean product of comparative example 1.Comparative example 1 is in the prior art, the constituent of clean gel of called after because topping-up is not transparent, does not have greasy feeling in the time of clean and has salubrious sense, yet because not containing the oil that has affinity with cosmetic composition, the cosmetic composition dissolved efficiency is not high actually.Comparative example 1 used surfactant is polysorbate60 and alkyl polyglucoside, and its consumption is 16 % by weight, and surface-active contents is very high, but cosmetics dissolution and little.Just when washing by exhibiting high surface activating agent water, it can be washed out.This is to stimulate less non-ionic surface active agent, but can get rid of the probability of using releasing stimulus skin because of a large amount of.Comparative example 2 and comparative example 3 use respectively 33 % by weight and the 50 % by weight oil high with the cosmetic ingredient affinity, but together use 2-4 % by weight surfactant for the stability of emulsifying, so evening occurs the phase inversion of oil in the time of clean, it is lower to confirm to remove cosmetics speed with this.In surfactant-like weight, comparative example 3 used oil weight are higher than comparative example 2 used weight, and the phase inversion of oil is a bit fast in the time of clean, therefore clean efficient of comparative example 3 is also higher, but when comparing with clean product embodiments 1 of the present invention, clean efficient or low can be confirmed by Fig. 4.Embodiments of the invention 1 are different from comparative example 2-3, do not contain surfactant, the a small amount of oil that contains 10 % by weight, keep the stability of emulsifying by acrylate/C10-30 alkyl acrylate polymer, in the time of clean, affected by external force and phase inversion occurs easily, therefore also can be fast clean with a small amount of oil, and can fully remove cosmetic ingredient.
Experimental example 2
For clean the efficient that compares embodiments of the invention 1 and comparative example 1-3 feels that with using consumer 60 outside full 28.5 years old company is called objects take the mean age, assesses.Appraisal procedure is to divide the preference degree (whether to like) of middle selection to projects at 1-9, and is as follows:
1-----2-----3-----4-----5-----6-----7-----8-----9
Very poor generally fine
By to the each side scoring, demonstrate its result at table 2.
Clean efficient of clean product of table 2 and use perceptual result
As shown in table 2, embodiment 1 is different from comparative example 1-3, moisturizing sense height in the time of clean, and greasy feeling is low, and makeup removing speed and removal efficient are remarkable.In addition, comparative example 1 is in the time of clean, and moisturizing sense or greasy feeling are low, although the preference degree is high, is not suitable for as clean product removing cosmetics.Comparative example 2 and 3 has suitable makeup removing speed and makeup removing efficient, but because greasy feeling or heavy burden sense, and it is clouding and increase the weight of the skin burden to demonstrate skin.
Experimental example 3
In order to assess the relevant emulsion stability of clean product of the present invention who does not contain surfactant, in 4-45 ℃ variations in temperature, measure the separation degree of embodiment 1 and comparative example 1-3, and demonstrate its result at table 3.
The emulsion stability result of clean product of table 3
As shown in table 3, when the comparative example 1-3 that does not contain this clean relevant clean product with prior art of product of surfactant compared, emulsion stability was similar or higher, and has confirmed not have surfactant also can keep its stability.Wherein, the oil-in-water type oil of having confirmed comparative example 3 is 50 % by weight, and under higher 45 ℃ of temperature, as time goes by, it is with separated.
Experimental example 4
In order to assess various clean products to the safety of skin, for embodiments of the invention and comparative example, with 30 objects by name in the company, implemented the human body skin irritant test, its method is to carry out skin anaphylactic test in the quantity that forearm was smeared 15 μ l/chamber (Hay ' s chamber) in inboard 48 hours, detects to 96 hours, reaction test is after hypersensitive test finishes, through 1 hour and 48 hours, implement according to the ICDRG regulation, and demonstrate its result at table 4.
Clean product of table 4 is to the safety results of skin
As shown in table 4, embodiment 1 and comparative example 1-3 all non-stimulated or its stimulation degree a little less than, can be used as product.Especially the makeup removing that does not contain surfactant among the present invention is non-stimulated to skin with clean product, demonstrates the safety of highly significant.
Claims (2)
1. oil-in-water type face cleansing emulsion, it is comprised of oiliness composition and aqueous composition, and wherein said oiliness composition is comprised of sad hexadecyl ester 7 weight portions and isopropyl palmitate 3 weight portions; Ethylenediamine tetraacetic ethyl disodium is 0.01 weight portion in the aqueous composition; Propylene glycol is 3 weight portions; Antiseptic is 0.40 weight portion; Triethanolamine is 0.30 weight portion; Acrylate/C10-30 alkyl acrylate polymer 0.30 weight portion; Water adds to 100 weight portions.
2. the preparation method of oil-in-water type face cleansing emulsion according to claim 1, its step is as follows:
(1) at room temperature evenly miscella sexual element;
(2) the aqueous composition is uniformly mixed at room temperature after, drop into the oiliness composition that step (1) is mixed.
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| Application Number | Priority Date | Filing Date | Title |
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| CN 201110007273 CN102085162B (en) | 2011-01-13 | 2011-01-13 | Face cleansing emulsion without surfactant and preparation method thereof |
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| CN 201110007273 CN102085162B (en) | 2011-01-13 | 2011-01-13 | Face cleansing emulsion without surfactant and preparation method thereof |
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| CN102085162A CN102085162A (en) | 2011-06-08 |
| CN102085162B true CN102085162B (en) | 2013-04-03 |
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| CN102860922B (en) * | 2012-10-09 | 2014-08-13 | 江南大学 | Preparation method of cream emulsion cosmetics without surfactant |
| CN109223608B (en) * | 2018-11-29 | 2022-02-01 | 四川省中医药科学院 | High-speed homogeneous forced solubilization method and application thereof |
| DE102019209909A1 (en) | 2019-07-05 | 2021-01-07 | Beiersdorf Ag | Cleaning emulsion containing fatty acid polyglyceryl esters |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1145217A (en) * | 1994-07-11 | 1997-03-19 | 莱雅公司 | Surfactant-free oil-in-water emulsion stabilized by hollow thermoplastic particles |
| CN1589770A (en) * | 2003-05-02 | 2005-03-09 | 吴宗满 | Carbon added face washing milk |
| CN101677913A (en) * | 2007-05-10 | 2010-03-24 | 诺伊堡皮肤护理两合公司 | Surfactant-free foam formulations |
-
2011
- 2011-01-13 CN CN 201110007273 patent/CN102085162B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1145217A (en) * | 1994-07-11 | 1997-03-19 | 莱雅公司 | Surfactant-free oil-in-water emulsion stabilized by hollow thermoplastic particles |
| CN1589770A (en) * | 2003-05-02 | 2005-03-09 | 吴宗满 | Carbon added face washing milk |
| CN101677913A (en) * | 2007-05-10 | 2010-03-24 | 诺伊堡皮肤护理两合公司 | Surfactant-free foam formulations |
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| CN102085162A (en) | 2011-06-08 |
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Address after: 510663 No.15, Kelin Road, Guangzhou Science City, Guangzhou high tech Industrial Development Zone, Guangdong Province Patentee after: Guangzhou Huanya cosmetics technology Co.,Ltd. Address before: 510800 No. 15, Kelin Road, Science City, Guangzhou, Guangdong Patentee before: GUANGZHOU HUANYA COSMETICS TECHNOLOGY Co.,Ltd. |
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Application publication date: 20110608 Assignee: Guangzhou nabion Biotechnology Co.,Ltd. Assignor: Guangzhou Huanya cosmetics technology Co.,Ltd. Contract record no.: X2022980010117 Denomination of invention: A cleansing emulsion without surfactant and its preparation method Granted publication date: 20130403 License type: Common License Record date: 20220712 |
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