CN102076792A - Thermal ink jet ink composition - Google Patents
Thermal ink jet ink composition Download PDFInfo
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- CN102076792A CN102076792A CN200980111809.9A CN200980111809A CN102076792A CN 102076792 A CN102076792 A CN 102076792A CN 200980111809 A CN200980111809 A CN 200980111809A CN 102076792 A CN102076792 A CN 102076792A
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Abstract
Disclosed are ink jet ink compositions suitable for use in thermal ink jet printers. The ink jet ink compositions contain one or more volatile organic solvents, one or more humectants, one or more binder resins, and one or more colorants. The ink jet ink compositions may also contain additives such as a plasticizer and/or a surfactant. Embodiments of the ink jet ink compositions have short dry times, good adhesion to a variety of substrates, and/or long decap times.
Description
Background technology
Hot ink-jet (TIJ) shower nozzle produces ink droplet by hot vaporized ink solvent.In course of injection, resistance is produced steam bubble by rapid heating, sprays drop subsequently from nozzle.This process extremely effectively and can repeat.The modern TIJ shower nozzle of industry drawing usefulness can produce volume under 36KHz or bigger frequency be 4pL or littler symmetrical liquid drop.Typical commercial TIJ equipment by special design with vaporize water or physical properties solvent (for example high boiling point, big thermal capacitance, lower molecular weight) near water.
Although the TIJ print system can be with having surpassed 30 years, nearly all commercial ink that is used for hot ink-jet system all is water base, and promptly they comprise and surpass 50% water.Such water-base ink has one or more defective, for example the sticking power of Chang ink drying time or double porous or nonporous substrate difference.
When people's expectation is printed on half porous and nonporous substrate when use TIJ system, the attractive performance characteristic of ink, for example anti-the exposing to the sun the time (decap time) and the good sticking power of Duan time of drying, length.
Summary of the invention
The invention provides a kind of hot ink jet ink composition, said composition comprises one or more and plants volatile organic solvent, one or more kind wetting Agent for Printing Inkss, one or more kind adhesive resins and one or more kind dyestuffs.In one embodiment, the amount that exists in ink jet ink composition of wetting Agent for Printing Inks is no more than 30 weight %.
In another embodiment, the invention provides a kind of hot ink jet ink composition, said composition comprises one or more kind alcohol, one or more plant wetting Agent for Printing Inkss, one or more kind adhesive resins, one or more kind colorants and one or more kind softening agent.In a concrete embodiment, the amount that softening agent exists in ink jet ink composition is no more than 5 weight %.
In another embodiment, the invention provides a kind of hot ink jet ink composition, said composition comprises one or more and plants volatile organic solvent, one or more kind wetting Agent for Printing Inkss, one or more kind adhesive resins and one or more kind pigment.In a concrete embodiment, the amount that wetting Agent for Printing Inks exists in ink jet ink composition is no more than 30 weight %.In another concrete embodiment, ink jet ink composition does not contain or does not contain substantially the aggretion type tensio-active agent.
The present invention also provides a kind of method with thermal ink jet printers print image on base material, and described method comprises: make the stream of liquid droplets of hot ink jet ink composition of the present invention point to base material, and make described ink droplet drying, thereby on base material print image.
Hot ink jet ink composition of the present invention has one or more following feature: short time of drying, long anti-time of exposing to the sun, to the good sticking power of base material, safety, material compatibility.Anti-exposing to the sun the time (decap time) is defined as, and nozzle keeps dormant state and then injection and liquid drop speed, weight or direction do not had the time quantum of disadvantageous effect.There is the fluid definition of good material compatibility in one rationally long period, can not reduce the fluid of the jet power of TIJ print cartridge for those.When printing on half porous and nonporous substrate, hot ink jet ink composition does not need heat auxiliary (as heat drier)
Embodiment
The invention provides a kind of hot ink jet ink composition, said composition comprises one or more and plants volatile organic solvent, one or more kind wetting Agent for Printing Inkss, one or more kind adhesive resins and one or more kind colorants.
In one embodiment, the invention provides a kind of hot ink jet ink composition, said composition comprises one or more and plants volatile organic solvent, one or more kind wetting Agent for Printing Inkss, one or more kind adhesive resins and one or more kind dyestuffs, wherein the amount that exists in ink jet ink composition of wetting Agent for Printing Inks is no more than 30 weight %, and wherein one or more are planted volatile organic solvents and are selected from by C
1-C
4Alcohol, C
4-C
8Ether, C
3-C
6Ketone, C
3-C
6The group that ester and their mixture are formed.
In another embodiment, the invention provides a kind of hot ink jet ink composition, said composition comprises one or more and plants C
1-C
4Alcohol, one or more kind wetting Agent for Printing Inkss, one or more kind adhesive resins, one or more kind colorants and one or more kind softening agent, wherein the amount that exists in ink jet ink composition of softening agent is no more than 5 weight %, and softening agent is selected from by butyl benzyl phthalate, n-ethyl neighbour, the group that right-toluol sulfonamide (n-ethyl o, p-toluene sulfonamide) and their mixture are formed
In another embodiment, the invention provides a kind of hot ink jet ink composition, said composition comprises that one or more plant volatile organic solvents, one or more plant wetting Agent for Printing Inkss, one or more plant adhesive resins, one or more plant pigment, wherein the amount that exists in ink jet ink composition of wetting Agent for Printing Inks is no more than 30 weight %, and this ink jet ink composition does not contain or do not contain the aggretion type tensio-active agent substantially, and wherein one or more kind volatile organic solvents are selected from by C
1-C
4Alcohol, C
4-C
8Ether, C
3-C
6Ketone, C
3-C
6The group that ester and their mixture are formed.
According to embodiment, volatile organic solvent is selected from by C
1-C
4Alcohol, C
4-C
8Ether, C
3-C
6Ketone, C
3-C
6The group that ester and their mixture are formed.C
1-C
4The example of alcohol comprises methyl alcohol, ethanol, 1-propyl alcohol, 2-propyl alcohol.C
4-C
8The example of ether comprises diethyl ether, dipropyl ether, dibutyl ether and tetrahydrofuran (THF).C
3-C
6The example of ketone comprises acetone, ethyl methyl ketone and pimelinketone.C
3-C
6The example of ester comprises methyl acetate, ethyl acetate and n-butyl acetate.Organic solvents in particular is alcohols, ketone and the attractive feature of ester class: they are than the surface of easier infiltration half porous of water-based ink or nonporous substrate, thereby have shortened time of drying and improved sticking power.
One or more are planted volatile organic solvent and can be present in the ink jet ink composition with any appropriate amount, this content for example is 50 weight % or more, about 60 weight % or more, about 70 weight % or more, about 80 weight % or more, about 90 weight % or more.In one embodiment, one or more amounts of planting that volatile organic solvents exist in ink jet ink composition are about 50% to about 99%, are preferably about 60% to about 97%, more preferably about 80% to about 95%.Hot ink jet ink composition of the present invention comprises an amount of water alternatively, for example accounts for the 49 weight % at the most of ink jet ink composition, about at the most 25 weight %, or about at the most 10 weight %, about at the most 5 weight %, or about at the most 2 weight %.
Hot ink jet ink composition of the present invention can comprise suitable colorant or multiple colorant, and these colorants can be dyestuff or pigment.In an embodiment of the invention, one or more are planted dyestuff and are used as colorant, and wherein one or more are planted dyestuff and are selected from the group of being made up of following: matching stain, basic dyestuff, solvent dye, dispersed dye, mordanting dye and their composition.The example of solvent dye comprises naphthol dye, azoic dyestuff, metal complex dyes, anthraquinone dye, quinonimine dye, indigoide colors, dyes, carbonium dye, naphthoquinone dyestuff, naphthalimide dyestuff, phthalocyanine pigment He perylene dyestuff.
For example, hot ink jet ink composition can comprise one or more and plant dyestuff, and these dyestuffs are selected from the group of following composition: the C.I. solvent yellow 19, C.I. solvent yellow 21, C.I. solvent yellow 61, C.I. solvent yellow 80, C.I. the solvent orange 1, C.I. the solvent orange 37, C.I. the solvent orange 40, C.I. the solvent orange 54, C.I. solvent orange 63, C.I. solvent red 8, C.I. solvent red 49, C.I. solvent red 81, C.I. solvent red 82, C.I solvent red 84, C.I. solvent red 100, C.I. acid red 92, C.I. react red 31, pearl pink 312, C.I. alkaline purple 3, C.I. alkalescence purple 4, C.I. solvent purple 8, C.I. solvent violet 21, C.I. solvent blue 2, C.I. solvent blue 5, C.I. solvent blue 19 1, C.I. solvent blue 25, C.I. solvent blue 36, C.I. solvent blue 38, C.I. solvent blue 55, C.I. solvent blue 70, C.I. solvent green 3, C.I. solvent black 3, C.I. solvent black 5, C.I. solvent black 7, C.I. solvent black 22, C.I. solvent black 26, C.I. solvent black 27 (MORFAST BLACK 101), C.I. solvent black 29 (VALIFAST BLACK3808), C.I. Acid Black 1 23, C.I. solvent black 48, C.I. oil blue 613 and their arbitrary composition; Described dyestuff is preferably one or more and is selected from dyestuff by the following group of forming: C.I. solvent black 29 (ORASOL BLACK RLI
TM), C.I. solvent black 26, C.I. solvent black 48, C.I. solvent black 3 (glossy black 860), C.I. alkaline purple 3, C.I. solvent blue 38, C.I. solvent blue 70, C.I. oil blue 613, C.I. solvent red 49 (ORIENT PINK
TM312), C.I. solvent orange 54 (VALIFASTORANGE
TM3210) and their arbitrary composition.
Can use any suitable pigment, for example use one or more kinds to be selected from pigment: phthalocyanine blue by the following group of forming, carbon black, Mars black, Kui acridone fuchsin, abasier, Prussian blue, cobalt blue, ultramarine blue, manganese indigo plant, cerulean blue, indanthrone blue, chromic oxide, Guinea green (viridian), cobalt green, soil is green, the nickel azophosphine, light green oxide compound, phthalocyanine green-chlorating CuPc, burnt sienna, purple cyclic ketones orange, pigment orange (irgazine organe), Kui acridone fuchsin, cobalt violet, ultramarine violet, manganese violet dioxazine violet, zinc white, titanium white, white lead, hydrated aluminum, barium white (blanc fixe), potter's clay, lithopone, the yellow G of aryl, the yellow 10G of aryl, baryta yellow, chrome yellow, chrome lemon, zinc yellow, cadmium yellow, primulin, Naples yellow, nickel titanate, the yellow GX of aryl, the isoindolinone Huang, the flavanthrone Huang, chalcopyrite, the yellow 8GN of chromophthal, toluidine red, the Kui acridone is red, forever dark red, rose-red, alizarin is dark red, bright red, cadmium red, permanent red FRG, bromination anthraquinone (brominated anthranthrone), naphthols urea perylene is red, the Kui acridone is red, the red BRN of chromophthal, the chromophthal scarlet R, aluminum oxide, barium oxide, bismuth oxide, boron oxide, Cadmium oxide, calcium oxide, cerium oxide, chromic oxide, cobalt oxide, cupric oxide, iridium oxide, plumbous oxide, magnesium oxide, manganese oxide, nickel oxide, phosphorous oxides, potassium oxide, rutile, silicon oxide, silver suboxide, sodium oxide, strontium oxide, stannic oxide, titanium oxide, vanadium oxide, zinc oxide, zirconium white and their arbitrary composition.
In embodiment, pigment is selected from the group of being made up of azo pigment, phthalocyanine pigment, Kui acridone pigment, triazine dioxin pigment, isoindolinone pigment, metal oxide pigment, carbon black and their arbitrary composition.
Pigment can have any suitable particle size, for example from about 0.005 micron to about 15 microns, preferably from about 0.005 micron to about 1 micron, more preferably from about 0.01 micron to about 0.3 micron.
In the above in any one embodiment, the amount that colorant (dyestuff or pigment) exists in ink jet ink composition from about 0.01 weight % to about 10 weight %, preferably from about 0.5 weight % to about 7 weight %, more preferably from about 1 weight % to about 5 weight %.
In any one embodiment, can use any suitable wetting Agent for Printing Inks in the above.Preferably, the boiling point of wetting Agent for Printing Inks is higher than 150 ℃, is higher than 200 ℃ or be higher than 250 ℃, and/or the relative rate of evaporation of wetting Agent for Printing Inks is less than 1.0, less than 0.9, and less than 0.7, less than 0.4, less than 0.1, or less than 0.01.Wetting Agent for Printing Inks normally has one or more for example solvent of the polar functional group of hydroxyl, ether, amide group, ester group, ketone group and carbonate group, for example, be solvent with two functional groups, these two functional groups can be identical or different, as two hydroxyls or a hydroxyl, an ether.In one embodiment, a kind of or more kinds of wetting Agent for Printing Inks is selected from the group of being made up of following: polyvalent alcohol, glycol ether, Pyranton, 2-Pyrrolidone, N-Methyl pyrrolidone, ethyl lactate, carbonic acid ethylidene ester, 1,3-dimethyl-2-imidazolinedione, alkyl ester and their arbitrary composition.
For example, polyvalent alcohol is selected from the group of being made up of following: polyoxyethylene glycol, polypropylene glycol, poly-(ethylene glycol-altogether-propylene glycol), polyvinyl alcohol, TriMethylolPropane(TMP), ethylene glycol, glycerol, Diethylene Glycol, triethylene glycol, tripropylene glycol, TEG, five ethylene glycol, 1, the 2-propylene glycol, 1, ammediol, butyleneglycol, triethylene glycol, 1,2, the 6-hexanetriol, thio-diethylene glycol, hexylene glycol, two (2-hydroxyethyl) ether, 1, the 4-butyleneglycol, 1, the 2-butyleneglycol, 1, the 4-butyleneglycol, 1, the 3-butyleneglycol, 1, the 5-pentanediol, 2, the 4-pentanediol, 2, the 4-heptanediol, 1, the 8-ethohexadiol, decamethylene-glycol, 1, the 12-dodecanediol, 1, the 4-cyclohexanediol, 1, the 4-cyclohexanedimethanol, 1, two (methylol) hexanaphthenes of 2-, 1, two (hydroxyethyl) hexanaphthenes of 2-, the 3-methyl isophthalic acid, the 5-pentanediol, 2,2,4-trimethylammonium-1,3-pentanediol, neopentyl glycol, new penta tetrol, Sorbitol Powder, mannitol and their arbitrary composition; Preferably, polyvalent alcohol is selected from the group of being made up of polyoxyethylene glycol, TriMethylolPropane(TMP), ethylene glycol, glycerol, Diethylene Glycol, tripropylene glycol and their arbitrary composition.
Preferred wetting Agent for Printing Inks is a glycol ether, for example, be selected from by the glycol ether in the following group of forming: ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, propylene glycol monomethyl ether, the tripropylene glycol monomethyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, the propylene glycol positive propyl ether, the glycol tertiary butyl ether, propylene glycol n-butyl ether, dipropylene glycol methyl ether, the dipropylene glycol positive propyl ether, dipropylene glycol uncle butyl ether, the dipropylene glycol n-butyl ether, the tripropylene glycol positive propyl ether, tripropylene glycol uncle butyl ether, the tripropylene glycol n-butyl ether, ethyl cellosolve, methylcyclohexane, poly glycol monomethyl ether, the polypropylene glycol monomethyl ether, the methoxyl group triethylene glycol, the oxyethyl group triethylene glycol, the butoxy triethylene glycol, 1-butoxyethoxy-2-propanol and their arbitrary composition; Preferably, glycol ether is selected from the group of being made up of ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, propylene glycol monomethyl ether, tripropylene glycol monomethyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether and their arbitrary composition.In embodiments of the present invention, propylene glycol monomethyl ether is preferred wetting Agent for Printing Inks.
Wetting Agent for Printing Inks to small part helps the feature of hot ink jet ink composition.So, wetting Agent for Printing Inks can prolong anti-exposing to the sun the time; Yet excessive wetting Agent for Printing Inks can increase the time of drying of ink jet ink composition.In any one embodiment, one or more are planted wetting Agent for Printing Inks and can any appropriate vol exist, for example, content is about 50 weight % or still less, is about 40 weight % or still less, preferably is about 30 weight % or still less, be about 25 weight % or still less, be about 20 weight % or still less, be about 15 weight % or still less, be about 10 weight % or still less.In one embodiment, one or more amounts of planting that wetting Agent for Printing Inkss exist in ink jet ink composition are about 1% to about 30%, are preferably about 2% to about 15%, more preferably about 3% to about 10%.
As discussed, hot ink jet ink composition of the present invention comprises one or more kind adhesive resins.Any suitable binder resin (solubility or dispersibility) can use the adhesive resin of preferred solvent solubility.In one embodiment, hot ink jet ink composition of the present invention comprises one or more kinds and is selected from adhesive resin by the following group of forming: polyamide resin, urethane resin, rosin ester resin, acrylic resin, polyvinyl butyral resin, polyester, urethane, resol, polyimide, Vinylite, ethylene vinyl acetate resin, polystyrene/acrylate, ether of cellulose, nitrocellulose resin, polymaleic anhydride, acetal polymer (acetal polymer), polystyrene/divinyl, polystyrene/methacrylic ester, sulfonated polyester, urea formaldehyde, polyketone resin and their arbitrary composition; Preferably, one or more are planted adhesive resin and are selected from the group of being made up of polyamide resin, rosin ester resin, acrylic resin, polyketone resin and their arbitrary composition.The example of suitable polyamide resin is from ArizonaChemical Company, Jacksonville, the ARIZONA 201-150 that FL obtains
TM, or from Cognis GmbH, Monheim am Rhein, the COGNIS VERSAMID756 that Germany obtains
TM, the two all is pure soluble polyamide resin.The example of wood rosin ester resin comprises the Color from Penn, Doylestown, the UNIREZ that PA obtains
TM8115 (40% solution in the ethanol, it is the hydrogenant rosin ester); STAYBELITE from Chem Central Corporation
TMESTER 10.The example of nitrocellulose resin is the NOBEL that obtains from Nobel Enterprises
TMDLX 3-5 or NOBEL
TMDHX 5-8.The example of polyvinyl butyral resin is the PIOLOFORM that obtains from Wacker Chemic AG
TMBN 18 and from Kuraray America, the MOWITAL that Inc. obtains
TMB20H.
Adhesive resin can be any appropriate vol exist, for example, content be ink jet ink composition about 0.1% to about 30%, preferred about 0.2% to about 15%, more preferably from about 0.3% to about 8%.
In an embodiment of hot ink jet ink composition of the present invention, the amount that volatile organic solvent exists in ink jet ink composition from about 50 weight % to about 95 weight %; The amount that colorant (dyestuff, pigment or their composition) exists in ink jet ink composition from about 1 weight % to about 8 weight %; The amount that glycol ether exists in ink jet ink composition from about 3 weight % to about 30 weight %; The amount that adhesive resin exists in ink jet ink composition from about 1 weight % to about 15 weight %.
Hot ink jet ink composition of the present invention can further comprise one or more and plant additive, for example tensio-active agent, softening agent or conducting salt.Preferably, use the aggretion type tensio-active agent.The example of tensio-active agent comprises: siloxanes, silicone, silanol, polyoxy alkylidene amine, propenoxylated (poly-(oxygen propylidene)) diamines, alkyl ether amine, nonyl phenol ethoxylate, the aliphatic amide of ethoxylation, the quaternized multipolymer of vinyl pyrrolidone and dimethylaminoethyl methacrylate, fluorizated organic acid diethanolamine salt, oxyalkylated quadrol, polyethylene oxide, polyoxy alkylidene polyalkylene polyamine (polyoxyalkylene polyalkylene polyamines amines), the many imines of polyoxy alkylidene polyalkylene, the mixture of alkyl phosphate b-oxide, the poly (oxyalkylene) radical derivative of propylene glycol and polyoxy ethylization Fatty Alcohol(C12-C14 and C12-C18).The object lesson of suitable aggretion type tensio-active agent is for example from Dow Corning Co, Midland, and the Silicone Fluid SF-69 that MI obtains, it is the blend of silanol and ring-type silicone.Other examples of aggretion type tensio-active agent comprise DISPERSYBYK
TM(BYKChemie, USA), SOLSPERSE
TM(for example SOLSPERSE 13940, and it is polymkeric substance/lipid acid condensation polymer) and EFKA
TM(EFKA Chemicals) aggretion type dispersion agent.
In any one embodiment of the present invention, the amount that tensio-active agent exists in ink jet ink composition can be from about 0.01% to about 1.0%, preferably from about 0.01% to about 0.5%, and more preferably from about 0.01% to about 0.1%.
The example of suitable manufacturing methods comprises phthalic ester plasticizer, for example phthalic acid alkyl benzyl ester, butyl benzyl phthalate, dioctyl phthalate (DOP), diisobutyl phthalate, dicyclohexyl phthalate, diethyl phthalate, dimethyl isophthalate, dibutyl phthalate, dimethyl phthalate; Ester class, for example hexanodioic acid two-(2-ethylhexyl) ester, diisobutyl adipate, glycerol three benzoic ethers, sucrose benzoate, polypropylene glycol dibenzoate, neopentyl glycol dibenzoate, Uniflex DBS, three n-hexyl trimellitates; And sulfonamide plasticizer, for example from Monsanto Co., St.Louis, the Plasticizer8 that MO obtains, it is n-ethyl neighbour, and is right-toluol sulfonamide.
In embodiments of the present invention, the amount that softening agent exists in ink jet ink composition can be from about 0.1% to about 5.0%, preferably from about 0.3% to about 3.0%, and more preferably from about 0.5% to about 2.0%.
Hot ink jet ink composition of the present invention can comprise annexing ingredient, for example known other reagent of tensio-active agent, sterilant, mycocide, algicide, sequestrant, buffer reagent, inhibiter, antioxidant, photostabilizer, anticurl agent, thickening material or association area.In one embodiment, composition for ink of the present invention does not contain or does not contain substantially antioxidant.
Hot ink jet ink composition of the present invention has one or more attracting feature, and for example short, the anti-time of exposing to the sun of non helping hand time of drying of letter punch numeral or graph image is long and the sticking power of double porous or nonporous substrate is good, safety, have material compatibility with one or more member in the thermal ink jet printers.For example, the embodiment of the hot ink jet ink composition of the present invention is about 10 seconds or shorter time of drying under envrionment conditions, for example 7 seconds or shorter.4 seconds or shorter, or 2 seconds or shorter.On porous substrate, time of drying is than shorter on half porous or nonporous substrate.For example, the embodiment of the hot ink jet ink composition of the present invention is about 1 second the time of drying on porous substrate, less than about 5 seconds, preferably less than about 2 seconds, is more preferably less than about 1 second on half porous base material.
Hot ink jet ink composition of the present invention can have any suitable viscosity or surface tension.In embodiments of the present invention, the viscosity of hot ink jet ink composition preferably less than about 5cPs, is more preferably less than about 3cPs less than about 10cPs, for example under 25 ℃, viscosity from about 1cPs to 4cPs, or from about 1cPs to about 3cPs.
In embodiments of the present invention, the surface tension under 25 ℃ of the hot ink jet ink compositions from about 20mN/m to about 50mN/m, from about 21mN/m to about 40mN/m, or from about 22mN/m to about 30mN/m.
Hot ink jet ink composition of the present invention can pass through prepared by any suitable process.For example, with selected each combination of components and suitable the mixing of employing, remove any insoluble impurity thereby filter the gained fluid.
The present invention also provides a kind of method with thermal ink jet printers print image on base material, described method comprises: make the stream of liquid droplets of any embodiment of the hot ink jet ink composition of the present invention point to base material, and make described ink droplet drying, thus on base material print image.Can on any suitable substrates, print according to the present invention.The example of suitable substrates comprises for example uncoated paper of porous substrate; Half porous substrate is paper, the paper of clay coated, the paper of silica coating, the paper of the outer coating of UV, the paper of the outer coating of polymkeric substance and the paper of the outer coating of varnish of water coating for example; And nonporous substrate for example duroplasts, polymeric film, metal, glass and pottery.Paper substrates can be thin paper sheet, coil paper or cardboard.Plastics, metal, glass and ceramic base material can be with any suitable forms, for example ampuliform or jar shape, tabular, bar-shaped, cylindric etc.
The example of polymeric coating comprises polystyrene-coated, polyethylene coating, polyacrylate coatings, polymethacrylate coating, polystyrene-coated or pvc coating.The example of polymeric film base material comprises polyvinyl butyral acetal, polyolefine, polyvinyl chloride, polyethylene terephthalate, PETG, polybutylene terephthalate (PBT), polyester, polycarbonate, acrylonitrile-butadiene-styrene (ABS) (ABS) multipolymer, polyvinyl fluoride polymer, polymeric amide, polyimide and Mierocrystalline cellulose.Plastics can be the plastics or the undressed plastics of treated (for example chemical etching, corona discharge, flame plasma etc.).The example of metal comprises aluminium, copper, stainless steel and metal alloy.The example of pottery comprises the oxide compound of metal, the nitride of metal and the carbide of metal.
The following further illustration of embodiment the present invention, but should not be considered to certainly limit the scope of the invention by any way.
Embodiment 1
This embodiment illustration according to the embodiment of hot ink jet ink composition of the present invention.The raw material, consumption and the prescription that are used for preparing ink jet ink composition number all are listed in following table 1.
Embodiment 2
This embodiment illustration time of drying of embodiment of ink jet ink composition of the present invention.
The ink drying time of the embodiment of table 2. ink jet ink composition on different substrate materials
Embodiment 3
This embodiment illustration some performances of embodiment of ink jet ink composition of the present invention.
The performance of the embodiment of table 3. hot ink jet ink composition of the present invention
| Formula number | Viscosity (cPs) | Surface tension (mN/m) |
| 5521 | 3.42 | 24.1 |
| 5678 | 1.71 | 22.6 |
| 5745 | 3.10 | 24.4 |
| 5750 | 3.28 | 25.0 |
| 2520 | 3.03 | 22.0 |
| 5798 | 1.50 | 22.6 |
| 5815 | 2.31 | 20.2 |
Embodiment 4
This embodiment illustration the sticking power of the print image that obtains by the ink jet ink composition in the embodiments of the present invention.Label is ink jet ink composition print image on the clay coated base material with water external coating (EC), UV external coating (EC) or varnish external coating (EC) or on the base material of polyethylene, polypropylene, polystyrene, polyvinyl chloride, polyethylene terephthalate, glass or aluminium of 2520,5745,5750 and 5815, and this image has passed through scratch-adhesivity of the test of 1 minute wear resistance and 24 hours and tested (scratch-adhesion test).
All documents of by reference this paper being quoted (comprising publication, patent application and patent) are incorporated into this, and wherein every piece of document is considered to individually, inserts and illustrate in this article by reference particularly full content.
Unless this paper indicates in addition, or with the obvious contradiction of context, describe in the context of the present invention term " ", " a kind of " and " this " and similar formulation that (in the context of concrete appended claims) use and be appreciated that and not only comprise odd number but also comprise plural number.Except as otherwise noted, term " comprises ", " having ", " comprising " and " containing " should be interpreted into open-ended term (i.e. expression " including but not limited to ").Ji Zai numerical range is only as specifically mentioning the stenography method that falls into each the independent numerical value in this scope respectively herein, and unless otherwise stated, each independent numerical value is considered to be attached in this specification sheets in the mode of independent record.All methods as herein described can be carried out with any suitable order, unless this paper indicate in addition, or with the obvious contradiction of context.Unless otherwise, any and all examples provided herein, perhaps exemplary language (for example, " for example ") only is used for setting forth the present invention better, but not scope of invention is limited.Any statement should not be interpreted as in the specification sheets: the key element of any failed call protection is necessary for enforcement of the present invention.
This paper has described preferred implementation of the present invention, comprises the enforcement optimal mode of the present invention that the inventor knows.After having read above explanation, the mutation of these preferred implementations it will be apparent to those skilled in the art that.The inventor expects that those skilled in the art can suitably utilize these mutation, and the inventor wishes that the present invention implements to be different from the specifically described mode of this paper.Therefore, the present invention comprises all improvement and the equivalent of the theme of putting down in writing in the claim under allowed by law condition.In addition, except as otherwise noted or obviously and contradicted by context, the arbitrary combination of above-mentioned key element in the possible mode of institute also contained in the present invention.
Claims (76)
1. hot ink jet ink composition, described composition comprises: one or more plant volatile organic solvent, one or more plant wetting Agent for Printing Inks, one or more kind adhesive resins and one or more kind dyestuffs, the content of wherein said wetting Agent for Printing Inks in described ink jet ink composition is no more than 30 weight %, and wherein said one or more kind volatile organic solvents are selected from by C
1-C
4Alcohol, C
4-C
8Ether, C
3-C
6Ketone, C
3-C
6The group that ester and their mixture are formed.
2. the described hot ink jet ink composition of claim 1, wherein, described volatile organic solvent is methyl alcohol, ethanol, 1-propyl alcohol, or Virahol, or their mixture.
3. the described hot ink jet ink composition of claim 1, wherein, described one or more kind wetting Agent for Printing Inkss are selected from by polyvalent alcohol, glycol ether, Pyranton, 2-Pyrrolidone, N-Methyl pyrrolidone, ethyl lactate, 1 group that 3-dimethyl-2-imidazolinedione, alkyl ester and their mixture are formed.
4. the described hot ink jet ink composition of claim 3, wherein, described polyvalent alcohol is selected from the group of being made up of following: polyoxyethylene glycol, polypropylene glycol, poly-(ethylene glycol-altogether-propylene glycol), polyvinyl alcohol, TriMethylolPropane(TMP), ethylene glycol, glycerol, Diethylene Glycol, triethylene glycol, tripropylene glycol, TEG, five ethylene glycol, 1, the 2-propylene glycol, 1, ammediol, butyleneglycol, triethylene glycol, 1,2, the 6-hexanetriol, thio-diethylene glycol, hexylene glycol, two (2-hydroxyethyl) ether, 1, the 4-butyleneglycol, 1, the 2-butyleneglycol, 1, the 4-butyleneglycol, 1, the 3-butyleneglycol, 1, the 5-pentanediol, 2, the 4-pentanediol, 2, the 4-heptanediol, 1, the 8-ethohexadiol, 1, the 10-decanediol, 1, the 12-dodecanediol, 1, the 4-cyclohexanediol, 1,4 cyclohexane dimethanol, 1, two (methylol) hexanaphthenes of 2-, 1, two (hydroxyethyl) hexanaphthenes of 2-, the 3-methyl isophthalic acid, the 5-pentanediol, 2,2,4-trimethylammonium-1, the 3-pentanediol, neopentyl glycol, new penta tetrol, Sorbitol Powder, mannitol and their mixture.
5. the described hot ink jet ink composition of claim 4, wherein, described polyvalent alcohol is selected from the group of being made up of polyvinyl alcohol, TriMethylolPropane(TMP), ethylene glycol, glycerol, Diethylene Glycol, tripropylene glycol and their mixture.
6. the described hot ink jet ink composition of claim 1, wherein, described wetting Agent for Printing Inks is a glycol ether.
7. the described hot ink jet ink composition of claim 3, wherein, described glycol ether is selected from the group of being made up of following: ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, propylene glycol monomethyl ether, the tripropylene glycol monomethyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, the propylene glycol positive propyl ether, the glycol tertiary butyl ether, propylene glycol n-butyl ether, dipropylene glycol methyl ether, the dipropylene glycol positive propyl ether, dipropylene glycol uncle butyl ether, the dipropylene glycol n-butyl ether, the tripropylene glycol positive propyl ether, tripropylene glycol uncle butyl ether, the tripropylene glycol n-butyl ether, ethyl cellosolve, methylcyclohexane, poly glycol monomethyl ether, the polypropylene glycol monomethyl ether, the methoxyl group triethylene glycol, the oxyethyl group triethylene glycol, the butoxy triethylene glycol, 1-butoxyethoxy-2-propanol and their mixture.
8. the described hot ink jet ink composition of claim 7, wherein, described glycol ether is selected from the group of being made up of ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, propylene glycol monomethyl ether, tripropylene glycol monomethyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether and their mixture.
9. the described hot ink jet ink composition of claim 1, wherein, described one or more kind adhesive resins are selected from the group of being made up of following: polyamide resin, urethane resin, rosin ester resin, acrylic resin, polyvinyl butyral resin, polyester, urethane, resol, polyimide, Vinylite, ethylene vinyl acetate resin, polystyrene/acrylate, ether of cellulose, nitrocellulose resin, polymaleic anhydride, acetal polymer, polystyrene/divinyl, polystyrene/methacrylic ester, sulfonated polyester, urea formaldehyde, polyketone resin and their mixture.
10. the described hot ink jet ink composition of claim 9, wherein, described one or more kind adhesive resins are selected from the group of being made up of polyamide resin, rosin ester resin, acrylic resin, polyketone resin, nitrocellulose resin, polyvinyl butyral resin and their mixture.
11. the described hot ink jet ink composition of claim 1, wherein, described one or more dyestuffs are selected from the group of being made up of matching stain, basic dyestuff, solvent dye, dispersed dye, mordanting dye and their mixture.
12. the described hot ink jet ink composition of claim 1, wherein, described one or more kind dyestuffs are selected from the group of following composition: the C.I. solvent yellow 19, C.I. solvent yellow 21, C.I. solvent yellow 61, C.I. solvent yellow 80, C.I. the solvent orange 1, C.I. the solvent orange 37, C.I. the solvent orange 40, C.I. the solvent orange 54, C.I. solvent orange 63, C.I. solvent red 8, C.I. solvent red 49, C.I. solvent red 81, C.I. solvent red 82, C.I solvent red 84, C.I. solvent red 100, C.I. acid red 92, C.I. react red 31, pearl pink 312, C.I. alkaline purple 3, C.I. alkalescence purple 4, C.I. solvent purple 8, C.I. solvent violet 21, C.I. solvent blue 2, C.I. solvent blue 5, C.I. solvent blue 19 1, C.I. solvent blue 25, C.I. solvent blue 36, C.I. solvent blue 38, C.I. solvent blue 55, C.I. solvent blue 70, C.I. solvent green 3, C.I. solvent black 3, C.I. solvent black 5, C.I. solvent black 7, C.I. solvent black 22, C.I. solvent black 26, C.I. solvent black 27, C.I. solvent black 29, C.I. Acid Black 1 23, C.I. solvent black 48, C.I. oil blue 613 and their mixture.
13. the described hot ink jet ink composition of claim 12, wherein, described one or more kind dyestuffs are selected from the group of being made up of following: C.I. solvent black 29, C.I. solvent black 26, C.I. solvent black 48, C.I. solvent black 3, C.I. alkaline purple 3, C.I. solvent blue 38, C.I. solvent blue 70, C.I. oil blue 613, C.I. solvent red 49, C.I. solvent orange 54 and their mixture.
14. the described hot ink jet ink composition of claim 1, account for the described ink jet ink composition water of 49 weight % at the most its optional comprising.
15. the described hot ink jet ink composition of claim 14, its optional water that accounts for the about at the most 25 weight % of described ink jet ink composition that comprises.
16. the described hot ink jet ink composition of claim 15, its optional water that accounts for the about at the most 10 weight % of described ink jet ink composition that comprises.
17. the described hot ink jet ink composition of claim 6, wherein, the amount that described one or more kind volatile organic solvents exist in described ink jet ink composition is that 50 weight % are to about 95 weight %; The about 1 weight % of amount that described one or more kind dyestuffs exist in described ink jet ink composition is to about 8 weight %; The amount that described glycol ether exists in described ink jet ink composition is about 3 weight % to 30 weight %; The content of described one or more kind adhesive resins in described ink jet ink composition is from about 1 weight % to about 15 weight %.
18. the described hot ink jet ink composition of claim 17, wherein, described volatile organic solvent is methyl alcohol, ethanol or Virahol.
19. the described hot ink jet ink composition of claim 17, wherein, described glycol ether is a propylene glycol monomethyl ether.
20. the described hot ink jet ink composition of claim 17, wherein, described adhesive resin is polyamide resin, urethane resin, nitrocellulose resin, polyvinyl butyral resin or rosin ester resin.
21. the described hot ink jet ink composition of claim 17, the group that wherein, that described dyestuff is selected from is pink 312 by C.I. solvent orange 62, pearl, C.I. alkaline purple 3 and their mixture are formed.
22. the described hot ink jet ink composition of claim 1 further comprises tensio-active agent.
23. the described hot ink jet ink composition of claim 1, wherein, described tensio-active agent is the aggretion type tensio-active agent.
24. the described hot ink jet ink composition of claim 23, wherein, described aggretion type tensio-active agent is Silicone Fluid SF-69.
25. the described hot ink jet ink composition of claim 1 further comprises softening agent.
26. comprising one or more, a hot ink jet ink composition, described composition plant C
1-C
4Alcohol, one or more kind wetting Agent for Printing Inkss, one or more kind adhesive resins, one or more kind colorants and one or more kind softening agent, the amount that wherein said one or more kind softening agent exist in described ink jet ink composition is no more than 5 weight %, and be selected from by butyl benzyl phthalate, n-ethyl neighbour the group that right-toluol sulfonamide and their mixture are formed.
27. the described hot ink jet ink composition of claim 26, wherein, described one or more kind C
1-C
4Alcohol is selected from the group of being made up of methyl alcohol, ethanol, 1-propyl alcohol and Virahol.
28. the described hot ink jet ink composition of claim 26, wherein, described one or more kind wetting Agent for Printing Inkss are selected from by polyvalent alcohol, glycol ether, Pyranton, 2-Pyrrolidone, N-Methyl pyrrolidone, ethyl lactate, 1 group that 3-dimethyl-2-imidazolinedione, propylene carbonate, alkyl ester and their mixture are formed.
29. the described hot ink jet ink composition of claim 28, wherein, described polyvalent alcohol is selected from the group of being made up of following: polyoxyethylene glycol, polypropylene glycol, poly-(ethylene glycol-altogether-propylene glycol), polyvinyl alcohol, TriMethylolPropane(TMP), ethylene glycol, glycerol, Diethylene Glycol, triethylene glycol, tripropylene glycol, TEG, five ethylene glycol, 1, the 2-propylene glycol, 1, ammediol, butyleneglycol, triethylene glycol, 1,2, the 6-hexanetriol, thio-diethylene glycol, hexylene glycol, two (2-hydroxyethyl) ether, 1, the 4-butyleneglycol, 1, the 2-butyleneglycol, 1, the 4-butyleneglycol, 1, the 3-butyleneglycol, 1, the 5-pentanediol, 2, the 4-pentanediol, 2, the 4-heptanediol, 1, the 8-ethohexadiol, 1, the 10-decanediol, 1, the 12-dodecanediol, 1, the 4-cyclohexanediol, 1,4 cyclohexane dimethanol, 1, two (methylol) hexanaphthenes of 2-, 1, two (hydroxyethyl) hexanaphthenes of 2-, the 3-methyl isophthalic acid, the 5-pentanediol, 2,2,4-trimethylammonium-1, the 3-pentanediol, neopentyl glycol, new penta tetrol, Sorbitol Powder, mannitol and their mixture.
30. the described hot ink jet ink composition of claim 28, wherein, described polyvalent alcohol is selected from the group of being made up of polyoxyethylene glycol, TriMethylolPropane(TMP), ethylene glycol, glycerol, Diethylene Glycol, tripropylene glycol and their mixture.
31. the described hot ink jet ink composition of claim 28, wherein, described wetting Agent for Printing Inks is a glycol ether.
32. the described hot ink jet ink composition of claim 31, wherein, described glycol ether is selected from the group of being made up of following: ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, propylene glycol monomethyl ether, the tripropylene glycol monomethyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, the propylene glycol positive propyl ether, the glycol tertiary butyl ether, propylene glycol n-butyl ether, dipropylene glycol methyl ether, the dipropylene glycol positive propyl ether, dipropylene glycol uncle butyl ether, the dipropylene glycol n-butyl ether, the tripropylene glycol positive propyl ether, tripropylene glycol uncle butyl ether, the tripropylene glycol n-butyl ether, ethyl cellosolve, methylcyclohexane, poly glycol monomethyl ether, the polypropylene glycol monomethyl ether, the methoxyl group triethylene glycol, the oxyethyl group triethylene glycol, the butoxy triethylene glycol, 1-butoxyethoxy-2-propanol and their mixture.
33. the described hot ink jet ink composition of claim 32, wherein, described glycol ether is selected from the group of being made up of ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, propylene glycol monomethyl ether, tripropylene glycol monomethyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether and their mixture.
34. the described hot ink jet ink composition of claim 26, wherein, described one or more kind adhesive resins are selected from the group of being made up of following: polyamide resin, urethane resin, rosin ester resin, acrylic resin, polyvinyl butyral resin, polyester, urethane, resol, polyimide, Vinylite, ethylene vinyl acetate resin, polystyrene/acrylate, ether of cellulose, nitrocellulose resin, polymaleic anhydride, acetal polymer, polystyrene/divinyl, polystyrene/methacrylic ester, sulfonated polyester, urea formaldehyde, polyketone resin and their mixture.
35. the described hot ink jet ink composition of claim 34, wherein, described one or more kind adhesive resins are selected from the group of being made up of polyamide resin, rosin ester resin, acrylic resin, polyketone resin, nitrocellulose resin, polyvinyl butyral resin and their mixture.
36. the described hot ink jet ink composition of claim 26, wherein, described one or more kind colorants are pigment or dyestuff.
37. the described hot ink jet ink composition of claim 36, wherein, described one or more kind colorants are that one or more plant pigment.
38. the described hot ink jet ink composition of claim 37, wherein, described one or more kind pigment material are selected from the group of being made up of azo pigment, phthalocyanine pigment, Kui acridone pigment, triazine dioxin pigment, isoindolinone pigment, metal oxide pigment, carbon black and their mixture.
39. the described hot ink jet ink composition of claim 37, wherein, described one or more kind pigment are selected from the group of being made up of following: phthalocyanine blue, carbon black, Mars black, Kui acridone fuchsin, abasier, Prussian blue, cobalt blue, ultramarine blue, manganese indigo plant, cerulean blue, indanthrone blue, chromic oxide, Guinea green, cobalt green, soil is green, the nickel azophosphine, light green oxide compound, phthalocyanine green-chlorating CuPc, burnt sienna, purple cyclic ketones orange, pigment orange, Kui acridone fuchsin, cobalt violet, ultramarine violet, manganese violet dioxazine violet, zinc white, titanium white, white lead, hydrated aluminum, barium white, potter's clay, lithopone, the yellow G of aryl, the yellow 10G of aryl, baryta yellow, chrome yellow, chrome lemon, zinc-chrome yellow, cadmium yellow, primulin, Naples yellow, nickel titanate, the yellow GX of aryl, the isoindolinone Huang, the flavanthrone Huang, chalcopyrite, the yellow GX of chromophthal, toluidine red, the Kui acridone is red, forever dark red, rose-red, alizarin is dark red, bright red, cadmium red, permanent red FRG, the bromination anthraquinone, naphthols urea perylene is red, the Kui acridone is red, the red BRN of chromophthal, the chromophthal scarlet R, aluminum oxide, barium oxide, bismuth oxide, boron oxide, Cadmium oxide, calcium oxide, cerium oxide, chromic oxide, cobalt oxide, cupric oxide, iridium oxide, plumbous oxide, magnesium oxide, manganese oxide, nickel oxide, phosphorous oxides, potassium oxide, rutile, silicon oxide, silver suboxide, sodium oxide, strontium oxide, stannic oxide, titanium oxide, vanadium oxide, zinc oxide, zirconium white and their mixture.
40. the described hot ink jet ink composition of claim 26, account for the described ink jet ink composition water of 49 weight % at the most its optional comprising.
41. the described hot ink jet ink composition of claim 40, its optional water that accounts for the about at the most 25 weight % of described ink jet ink composition that comprises.
42. the described hot ink jet ink composition of claim 41, its optional water that accounts for the about at the most 10 weight % of described ink jet ink composition that comprises.
43. the described hot ink jet ink composition of claim 31, wherein, the amount that described one or more kind volatile organic solvents exist in described ink jet ink composition is that about 50 weight % are to about 95 weight %; The amount that described one or more kind colorants exist in described ink jet ink composition is that about 1 weight % is to about 8 weight %; The amount that described glycol ether exists in described ink jet ink composition is about 3 weight % to 30 weight %; The amount of described one or more kind adhesive resins in described ink jet ink composition is that about 1 weight % is to about 15 weight %.
44. the described hot ink jet ink composition of claim 43, wherein, described volatile organic solvent is methyl alcohol, ethanol or Virahol.
45. the described hot ink jet ink composition of claim 43, wherein, described glycol ether is a propylene glycol monomethyl ether.
46. the described hot ink jet ink composition of claim 43, wherein, described adhesive resin is polyamide resin, urethane resin, nitrocellulose resin, polyvinyl butyral resin or rosin ester resin.
47. hot ink jet ink composition, described composition comprises that one or more plant volatile organic solvents, one or more plant wetting Agent for Printing Inkss, one or more plant adhesive resins, one or more plant pigment, the amount that wherein said wetting Agent for Printing Inks exists in described ink jet ink composition is no more than 30 weight %, described ink jet ink composition does not contain or does not contain the aggretion type tensio-active agent substantially, and wherein said one or more kind volatile organic solvents are selected from by C
1-C
4Alcohol, C
4-C
8Ether, C
3-C
6Ketone, C
3-C
6The group that ester and their mixture are formed.
48. the described hot ink jet ink composition of claim 47, wherein, described volatile organic solvent is methyl alcohol, ethanol, 1-propyl alcohol or Virahol or their mixture.
49. the described hot ink jet ink composition of claim 47, wherein, described one or more kind wetting Agent for Printing Inkss are selected from by polyvalent alcohol, glycol ether, Pyranton, 2-Pyrrolidone, N-Methyl pyrrolidone, ethyl lactate, 1 group that 3-dimethyl-2-imidazolinedione, propylene carbonate, alkyl ester and their mixture are formed.
50. the described hot ink jet ink composition of claim 49, wherein, described polyvalent alcohol is selected from the group of being made up of following: polyoxyethylene glycol, polypropylene glycol, poly-(ethylene glycol-altogether-propylene glycol), polyvinyl alcohol, TriMethylolPropane(TMP), ethylene glycol, glycerol, Diethylene Glycol, triethylene glycol, tripropylene glycol, TEG, five ethylene glycol, 1, the 2-propylene glycol, 1, ammediol, butyleneglycol, triethylene glycol, 1,2, the 6-hexanetriol, thio-diethylene glycol, hexylene glycol, two (2-hydroxyethyl) ether, 1, the 4-butyleneglycol, 1, the 2-butyleneglycol, 1, the 4-butyleneglycol, 1, the 3-butyleneglycol, 1, the 5-pentanediol, 2, the 4-pentanediol, 2, the 4-heptanediol, 1, the 8-ethohexadiol, 1, the 10-decanediol, 1, the 12-dodecanediol, 1, the 4-cyclohexanediol, 1,4 cyclohexane dimethanol, 1, two (methylol) hexanaphthenes of 2-, 1, two (hydroxyethyl) hexanaphthenes of 2-, the 3-methyl isophthalic acid, the 5-pentanediol, 2,2,4-trimethylammonium-1, the 3-pentanediol, neopentyl glycol, new penta tetrol, Sorbitol Powder, mannitol and their mixture.
51. the described hot ink jet ink composition of claim 49, wherein, described polyvalent alcohol is selected from the group of being made up of polyoxyethylene glycol, TriMethylolPropane(TMP), ethylene glycol, glycerol, Diethylene Glycol, tripropylene glycol and their mixture.
52. the described hot ink jet ink composition of claim 47, wherein, described wetting Agent for Printing Inks is a glycol ether.
53. the described hot ink jet ink composition of claim 52, wherein, described glycol ether is selected from the group of being made up of following: ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, propylene glycol monomethyl ether, the tripropylene glycol monomethyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, the propylene glycol positive propyl ether, the glycol tertiary butyl ether, propylene glycol n-butyl ether, dipropylene glycol methyl ether, the dipropylene glycol positive propyl ether, dipropylene glycol uncle butyl ether, the dipropylene glycol n-butyl ether, the tripropylene glycol positive propyl ether, tripropylene glycol uncle butyl ether, the tripropylene glycol n-butyl ether, ethyl cellosolve, methylcyclohexane, poly glycol monomethyl ether, the polypropylene glycol monomethyl ether, the methoxyl group triethylene glycol, the oxyethyl group triethylene glycol, the butoxy triethylene glycol, 1-butoxyethoxy-2-propanol and their mixture.
54. the described hot ink jet ink composition of claim 52, wherein, described glycol ether is selected from the group of being made up of ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, propylene glycol monomethyl ether, tripropylene glycol monomethyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether and their mixture.
55. the described hot ink jet ink composition of claim 47, wherein, described one or more kind adhesive resins are selected from the group of being made up of following: polyamide resin, urethane resin, rosin ester resin, acrylic resin, polyvinyl butyral resin, polyester, urethane, resol, polyimide, Vinylite, ethylene vinyl acetate resin, polystyrene/acrylate, ether of cellulose, nitrocellulose resin, polymaleic anhydride, acetal polymer, polystyrene/divinyl, polystyrene/methacrylic ester, sulfonated polyester, urea formaldehyde, polyketone resin and their mixture.
56. the described hot ink jet ink composition of claim 47, wherein, described one or more kind adhesive resins are selected from the group of being made up of polyamide resin, rosin ester resin, acrylic resin, polyketone resin, nitrocellulose resin, polyvinyl butyral resin and their mixture.
57. the described hot ink jet ink composition of claim 47, wherein, described one or more kind pigment are selected from the group of being made up of azo pigment, phthalocyanine pigment, Kui acridone pigment, triazine dioxin pigment, isoindolinone pigment, metal oxide pigment, carbon black and their mixture.
58. the described hot ink jet ink composition of claim 47, wherein, described one or more kind pigment are selected from the group of being made up of following: phthalocyanine blue, carbon black, Mars black, Kui acridone fuchsin, abasier, Prussian blue, cobalt blue, ultramarine blue, manganese indigo plant, cerulean blue, indanthrone blue, chromic oxide, Guinea green, cobalt green, soil is green, the nickel azophosphine, light green oxide compound, phthalocyanine green-chlorating CuPc, burnt sienna, purple cyclic ketones orange, pigment orange, Kui acridone fuchsin, cobalt violet, ultramarine violet, manganese violet dioxazine violet, zinc white, titanium white, white lead, hydrated aluminum, barium white, potter's clay, lithopone, the yellow G of aryl, the yellow 10G of aryl, baryta yellow, chrome yellow, chrome lemon, zinc yellow, cadmium yellow, primulin, Naples yellow, nickel titanate, the yellow GX of aryl, the isoindolinone Huang, the flavanthrone Huang, chalcopyrite, the yellow GN of chromophthal, toluidine red, the Kui acridone is red, forever dark red, rose-red, alizarin is dark red, bright red, cadmium red, permanent red FRG, the bromination anthraquinone, naphthols urea perylene is red, the Kui acridone is red, the red BRN of chromophthal, the chromophthal scarlet R, aluminum oxide, barium oxide, bismuth oxide, boron oxide, Cadmium oxide, calcium oxide, cerium oxide, chromic oxide, cobalt oxide, cupric oxide, iridium oxide, plumbous oxide, magnesium oxide, manganese oxide, nickel oxide, phosphorous oxides, potassium oxide, rutile, silicon oxide, silver suboxide, sodium oxide, strontium oxide, stannic oxide, titanium oxide, vanadium oxide, zinc oxide, zirconium white and their mixture.
59. the described hot ink jet ink composition of claim 47, account for the described ink jet ink composition water of 49 weight % at the most its optional comprising.
60. the described hot ink jet ink composition of claim 59, its optional water that accounts for the about at the most 25 weight % of described ink jet ink composition that comprises.
61. the described hot ink jet ink composition of claim 60, its optional water that accounts for the about at the most 10 weight % of described ink jet ink composition that comprises.
62. the described hot ink jet ink composition of claim 52, wherein, the amount that described one or more kind volatile organic solvents exist in described ink jet ink composition is that about 50 weight % are to about 95 weight %; The amount that described one or more kind pigment exist in described ink jet ink composition is that about 1 weight % is to about 8 weight %; The amount that described glycol ether exists in described ink jet ink composition is about 3 weight % to 30 weight %; The content of described one or more kind adhesive resins in described ink jet ink composition is that about 1 weight % is to about 15 weight %.
63. the described hot ink jet ink composition of claim 62, wherein, described volatile organic solvent is methyl alcohol, ethanol or Virahol.
64. the described hot ink jet ink composition of claim 62, wherein, described glycol ether is a propylene glycol monomethyl ether.
65. the described hot ink jet ink composition of claim 62, wherein, described adhesive resin is polyamide resin, urethane resin or rosin ester resin.
66. the described hot ink jet ink composition of claim 47 further comprises softening agent.
67. method with thermal ink jet printers print image on base material, described method comprises: make claim 1, the stream of liquid droplets of any described hot ink jet ink composition is pointed to base material in 26 or 47, and makes described ink droplet drying, thus on base material print image.
68. the described method of claim 67, wherein, described base material is selected from the group of being made up of porous substrate, half porous substrate and nonporous substrate.
69. the described method of claim 68, wherein, described base material is a porous substrate.
70. the described method of claim 69, wherein, described porous substrate is uncoated paper.
71. the described method of claim 68, wherein, described base material is half porous substrate.
72. the described method of claim 71, wherein, paper, the paper of silica coating, the paper of clay coated, the paper of the outer coating of UV, the paper of polymeric coating and the group that the outer paper that is coated with of varnish is formed that described half porous substrate selects free water to be coated with.
73. the described method of claim 72, wherein said polymer-coated paper is the paper with polymeric coating, and described polymkeric substance is selected from the group of being made up of polystyrene, polyvinyl alcohol, polyacrylic ester, polymethacrylate, polystyrene and polyvinyl chloride.
74. the described method of claim 68, wherein, described base material is a nonporous substrate.
75. the described method of claim 74, wherein, described nonporous substrate is selected from the group of being made up of duroplasts, polymeric film, metal, glass and pottery.
76. the described method of claim 75, wherein, described polymeric film comprises the polymkeric substance that is selected from by the following group of forming: polyvinyl butyral acetal, polyolefine, polyvinyl chloride, polyethylene terephthalate, PETG, polybutylene terephthalate, polyester, polycarbonate, acrylonitrile-butadiene-styrene (ABS) (ABS) multipolymer, polyvinyl fluoride polymer, polymeric amide, polyimide and Mierocrystalline cellulose.
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|---|---|---|---|
| PCT/US2009/043462 WO2009124325A1 (en) | 2008-03-31 | 2009-05-11 | Thermal ink jet ink composition |
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| CN102076792A true CN102076792A (en) | 2011-05-25 |
| CN102076792B CN102076792B (en) | 2013-12-04 |
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