CN102504459A - PVB (polyvinyl butyral) sheet with single-layer and double-layer materials compatible on basis of compatibilizer and preparation method thereof - Google Patents
PVB (polyvinyl butyral) sheet with single-layer and double-layer materials compatible on basis of compatibilizer and preparation method thereof Download PDFInfo
- Publication number
- CN102504459A CN102504459A CN2011103920242A CN201110392024A CN102504459A CN 102504459 A CN102504459 A CN 102504459A CN 2011103920242 A CN2011103920242 A CN 2011103920242A CN 201110392024 A CN201110392024 A CN 201110392024A CN 102504459 A CN102504459 A CN 102504459A
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- Prior art keywords
- pvb
- double
- sheet
- compatible
- deck
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
Abstract
The invention provides a PVB (polyvinyl butyral) sheet with single-layer and double-layer materials compatible on the basis of compatibilizer, which belongs to the technical field of thermoplastic high polymer materials. The PVB sheet is prepared by the following raw materials: by weight parts, 90 to 110 parts of PVB resin powder, 0.2 to 0.5 part of oxidation inhibitor, 0.2 to 0.5 part of ultraviolet absorber, 35 to 45 parts of plasticizer, 20 to 35 parts of PVB double-layer materials, 0.001 to 0.004 part of fluorescent whitening agent and 1 to 7 parts of the compatibilizer. The invention further provides a preparation method of the PVB sheet, which includes steps of adding the above raw materials excluding the compatibilizer and the plasticizer into a mixer to mix uniformly, adding the compatibilizer and the plasticizer which are mixed uniformly into the mixer to mix uniformly, filtering melts after the melts are extruded from a double-screw extruder, sending the melts into a mould head by a gear pump to form a sheet, and accordingly the PVB sheet is prepared. The PVG sheet overcomes the defects of obscurity and mist, and optical performance thereof cannot be affected.
Description
Technical field
The invention belongs to the thermoplastic macromolecule material technical field, relate in particular to based on expanding material and make the compatible PVB sheet material of single double-deck material.Simultaneously, the invention still further relates to the preparation method of this kind PVB sheet material.
Background technology
PVB is the abbreviation of polyvinyl butyral acetal; It is a kind of polymkeric substance that forms through the Z 150PH of higher molecular weight and butyraldehyde condensation reaction under the catalysis of hydrochloric acid; Push and a kind of macromolecular material of moulding through the softening agent plasticizing, this product is the special plastic material of laminated safety glass.The PVB glued membrane becomes the necessary starting material of producing all kinds of shatter proof glasses with its good optical property, high temperature resistant, low temperature, mechanical property with to the good adhesive property of unorganic glass.When receiving extraneous intense impact, the PVB glued membrane can absorb impact energy, does not produce flinders, when having security feature, also has excellent sound insulation, light-operated, insulation, performance such as heat insulation, antifog, is ideal shatter proof glass work material.
PVB mainly is divided into by purposes: building safety glass with PVB film, automotive safety glass with PVB film and sun power PVB film.Its formula technique of PVB film, the product performance in three big fields have nothing in common with each other.Automotive safety glass mainly contains following kind with the PVB film: the transparent automotive safety glass of common grade has the PVB film, thermal isolation film (double-deck material) etc. of gradual change type color with PVB film, limit portion.Wherein double-deck material is a technology content very high " trilamellar membrane " product that Japanese ponding company releases, and its structure is a two-layer PVB material up and down, and the centre is one deck functional materials.The intermediary functional materials mainly is made up of two portions: jointing material and functional mass, functional mass is well-proportioned to be dispersed in the jointing material.Through experiment repeatedly, this double-deck material is after the effect that the forcing machine fusion is sheared, and the film that flows out die head presents fuzzy, as to send out mist phenomenon.The mist degree of film can reach more than 10%, almost becomes translucent material.Just because of this critical defect, the double-deck material of import PVB scrap stock become the not high substandard goods material of use value already on market.It can only be used for production oyster white PVB film or porcelain white PVB film, can not be used for the production of transparent PVB film.The price of market upper inlet individual layer scrap stock is 26000 yuan/ton, and the price of resin-oatmeal is 32000 yuan/ton, and the double-deck material of import PVB is limited owing to use range, and its price is merely 6000 yuan/ton, and difference in selling prices shows huge difference.
Summary of the invention
The object of the invention is intended to overcome the shortcoming that above-mentioned prior art exists; A kind of PVB sheet material that contains expanding material is provided; This kind expanding material can make PVB individual layer material well compatible with the double-deck material of PVB intermediate layer material; The drawback of mist does not appear bluring, sending out in the PVB sheet material of producing, and its optical property is unaffected.
Therefore, the object of the invention provides based on expanding material and makes the compatible PVB sheet material of single double-deck material, and it is to be prepared from following materials based on weight:
PVB resin-oatmeal: 90~110
Oxidation inhibitor: 0.2~0.5
UV light absorber: 0.2~0.5
Softening agent: 35~45
The double-deck material of PVB: 20~35
White dyes: 0.001~0.004
Expanding material: 1~7.
Further, described oxidation inhibitor is antioxidant 1010, and it can prevent more effectively that diaphragm is oxidized in the extrusion moulding process; Described UV light absorber is a ultraviolet absorbent uv-326, and its effect is that the pvb film that contains it has the ultraviolet function of absorption; Described softening agent is 3GO, and this softening agent is a PVB characteristic softening agent, contains hydroxyl and ehter bond in the molecular structure, can be well compatible with PVB, and it can make pvb film possess resistance to low temperature; Described white dyes is white dyes OB; Described expanding material is a poly glycol monomethyl ether, and its molecular structure is H-(O-CH
2-CH
2) n-O-CH
3, n≤22 wherein.
Further, described expanding material and PVB are mutually, polyoxyethylene glycol two (2 ethyl hexanoic acid) esters in the double-deck material of PVB middle layer are mutually compatible so that two (2 ethyl hexanoic acid) esters of polyoxyethylene glycol mutually with PVB consistency increase mutually.The molecular structure of the expanding material poly glycol monomethyl ether of choosing is: H-(O-CH
2-CH
2) n-O-CH
3,Wherein terminal hydroxy group-OH is contained in its molecule, ehter bond-O-in n≤22; Hydroxyl-the OH and the ehter bond-O-that contain in more little its molecule of poly glycol monomethyl ether of molecular-weight average are more, and the consistency of it and PVB is just good more.After poly glycol monomethyl ether adds co-mixing system; To form three-phase structure with two (2 ethyl hexanoic acid) esters of polyoxyethylene glycol and PVB; Poly glycol monomethyl ether plays the effect of similar connection phase; Two (2 ethyl hexanoic acid) ester phases of polyoxyethylene glycol, PVB are all mutually compatible with poly glycol monomethyl ether mutually; So just make two (2 ethyl hexanoic acid) esters of polyoxyethylene glycol increase with PVB reactive force mutually mutually, two (2 ethyl hexanoic acid) ester molecule chains of polyoxyethylene glycol and the interpenetrative probability of PVB molecular chain increase, thereby increase consistency.
Another object of the present invention is to provides the preparation method who makes the compatible PVB sheet material of single double-deck material based on expanding material, and it comprises the steps:
(1) the double-deck material of PVB is ground into particulate material with crusher, sends into polygonally in cone-type mixer through blast system, add the PVB resin-oatmeal simultaneously;
(2) oxidation inhibitor, UV light absorber, white dyes are added in the said mixing machine mix, simultaneously expanding material poly glycol monomethyl ether and softening agent are mixed the back and squeeze into mixing machine through volume pump;
(3) with the mixing machine chuck with the water quench below 18 ℃; Again this mixture is mixed stirring and add twin screw extruder after 25~35 minutes melt extrusion; Refilter, send into die head with toothed gear pump and carry out extrusion moulding, promptly get the PVB sheet material of double-deck material and individual layer material consistency.
Further, the oxidation inhibitor described in the step (2) is antioxidant 1010; Described UV light absorber is a ultraviolet absorbent uv-326; Described white dyes is white dyes OB; Described expanding material is a poly glycol monomethyl ether, and its molecular structure is H-(O-CH
2-CH
2) n-O-CH
3, n≤22 wherein; Described softening agent is 3GO;
Further, the melt temperature extruded of the twin screw extruder described in the step (3) is 145~155 ℃.
In the prescription of PVB sheet material of the present invention, add double-deck material; Through adding expanding material; Make these double-deck material in the process that melt extrudes, being on good terms of intermediate layer material is well mutually compatible with the PVB macromole, the phenomenon that weakens or can not occur being separated; That the pvb film of extruding does not produce is fuzzy, send out the drawback of mist, and optical property is unaffected.Simultaneously, the bilayer material owing to add appropriate umber at prescription of the present invention makes its production cost of product per ton reduce by 3500 yuan at least, is equivalent to the income that the company that can be every year creates 35000000 yuan.
The beneficial effect that is brought in order more to know the present invention, following form are that to detect the data list contrast by each item index with regard to the PVB sheet material that the product of the present invention draw and the usual prodn that does not carry out formula adjustment, international most advanced level product are detected in national chemical building material quality supervision and test center as shown in table 1:
Project | Product of the present invention | Usual prodn | The international most advanced level product |
Shrinking percentage (%) | 2 | 2 | 2 |
Mist degree (%) | 0.6 | 0.3 | 0.5 |
Transmittance (%) | 89 | 89 | 90 |
Tensile strength (Mpa) | 24.0 | 21 | 24.0 |
Elongation at break (%) | 260 | 214 | 250 |
Yellowness index (%) | 8.5 | 9 | 8 |
Knock rank | 8 | 7 | 8 |
Table 1
Embodiment
Can further be well understood to the present invention through specific embodiment of the present invention given below.But they are not to qualification of the present invention.
Produce qualified PVB sheet material with PVB resin-oatmeal, the double-deck material of PVB, expanding material according to production technique:
Embodiment 1
35kg is ground into particulate material with crusher with the double-deck material of the PVB that weighs up weight; (high-power blower is installed at crusher discharge port place through blast system; Broken good particulate material is sent into the hollow iron sheet tube of the about 30cm of diameter through the wind-force of blower fan; Be admitted in the mixing machine then) send into polygonal in cone-type mixer; And add ground PVB resin 90kg simultaneously, and antioxidant 1010 0.4kg, ultraviolet absorbent uv-326 0.4kg, white dyes OB 0.1kg are added in the mixing machine mix, expanding material poly glycol monomethyl ether 2.5kg and softening agent 3GO 34kg are mixed then squeeze into mixing machine simultaneously with volume pump.The mixing machine chuck is with the water quench below 18 ℃.After this mixture mixed 25~35 minutes; Add twin screw extruder with melt extrusion, 145~155 ℃ of control melt temperatures, melt is through filtering; Send into die head with toothed gear pump; Adjust the die lip gap of die head and the pulling speed of cooling roller according to the condition of production of reality,, promptly make the double-deck material of the present invention PVB sheet material compatible with the individual layer material so that the thickness of the PVB film of producing is 0.76mm.
Embodiment 2
15kg is ground into particulate material with crusher with the double-deck material of the PVB that weighs up weight; Send into polygonal in cone-type mixer through blast system; And add ground PVB resin 110kg simultaneously; Antioxidant 1010 0.35kg, ultraviolet absorbent uv-326 0.35kg, white dyes OB 0.1kg added in the mixing machine mix, expanding material poly glycol monomethyl ether 1kg and softening agent 3GO 41kg are mixed then squeeze into mixing machine simultaneously with volume pump.The mixing machine chuck is with the water quench below 18 ℃.After this mixture mixed 25~35 minutes; Add twin screw extruder with melt extrusion, 145~155 ℃ of control melt temperatures, melt is through filtering; Send into die head with toothed gear pump; Adjust the die lip gap of die head and the pulling speed of cooling roller according to the condition of production of reality,, promptly make the double-deck material of the present invention PVB sheet material compatible with the individual layer material so that the thickness of the PVB film of producing is 0.76mm.
Embodiment 3
60kg is ground into particulate material with crusher with the double-deck material of the PVB that weighs up weight; Send into polygonal in cone-type mixer through blast system; And add ground PVB resin 400kg simultaneously; Antioxidant 1010 1.2kg, ultraviolet absorbent uv-326 1.2kg, white dyes OB 0.35kg added in the mixing machine mix, expanding material poly glycol monomethyl ether 5.5kg and softening agent 3GO 120kg are mixed then squeeze into mixing machine simultaneously with volume pump.The mixing machine chuck is with the water quench below 18 ℃.After this mixture mixed 25~35 minutes; Add twin screw extruder with melt extrusion, 145~155 ℃ of control melt temperatures, melt is through filtering; Send into die head with toothed gear pump; Adjust the die lip gap of die head and the pulling speed of cooling roller according to the condition of production of reality,, promptly make the double-deck material of the present invention PVB sheet material compatible with the individual layer material so that the thickness of the PVB film of producing is 0.76mm.
The foregoing description is merely preferred embodiment of the present invention, is not to limit protection scope of the present invention according to this, so: all equivalences of doing according to principle of the present invention change, and all should be covered by within protection scope of the present invention.
Claims (6)
1. make the compatible PVB sheet material of single double-deck material based on expanding material, it is characterized in that it is to be prepared from following materials based on weight:
PVB resin-oatmeal: 90~110
Oxidation inhibitor: 0.2~0.5
UV light absorber: 0.2~0.5
Softening agent: 35~45
The double-deck material of PVB: 20~35
White dyes: 0.001~0.004
Expanding material: 1~7.
2. according to claim 1ly make the compatible PVB sheet material of single double-deck material, it is characterized in that based on expanding material:
Described oxidation inhibitor is antioxidant 1010;
Described UV light absorber is a ultraviolet absorbent uv-326;
Described softening agent is 3GO;
Described white dyes is white dyes OB;
Described expanding material is a poly glycol monomethyl ether, and its molecular structure is H-(O-CH
2-CH
2) n-O-CH
3, n≤22 wherein.
3. according to claim 1ly make the compatible PVB sheet material of single double-deck material based on expanding material; It is characterized in that: described expanding material and PVB are mutually, two (2 ethyl hexanoic acid) esters of the double-deck material of PVB intermediate layer material polyoxyethylene glycol are mutually compatible so that two (2 ethyl hexanoic acid) esters of polyoxyethylene glycol mutually with PVB consistency increase mutually.
4. make the preparation method of the compatible PVB sheet material of single double-deck material based on expanding material, it is characterized in that: it comprises the steps:
(1) the double-deck material of PVB is ground into particulate material with crusher, sends into polygonally in cone-type mixer through blast system, add the PVB resin-oatmeal simultaneously;
(2) oxidation inhibitor, UV light absorber, white dyes are added in the said mixing machine mix, simultaneously expanding material poly glycol monomethyl ether and softening agent are mixed the back and squeeze into mixing machine through volume pump;
(3) with said mixing machine chuck with the water quench below 18 ℃, said mixture is stirred add twin screw extruder with melt extrusion after 25~35 minutes again, refilter, send into die head with toothed gear pump and carry out extrusion moulding, promptly make said PVB sheet material.
5. the preparation method of PVB sheet material according to claim 4 is characterized in that:
Described oxidation inhibitor is antioxidant 1010;
Described UV light absorber is a ultraviolet absorbent uv-326;
Described white dyes is white dyes OB;
Described softening agent is 3GO;
Described expanding material is a poly glycol monomethyl ether, and its molecular structure is H-(O-CH
2-CH
2) n-O-CH
3, n≤22 wherein.
6. the preparation method of PVB sheet material according to claim 4 is characterized in that: the melt temperature that described twin screw extruder is extruded is 145~155 ℃.
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CN2011103920242A CN102504459A (en) | 2011-12-01 | 2011-12-01 | PVB (polyvinyl butyral) sheet with single-layer and double-layer materials compatible on basis of compatibilizer and preparation method thereof |
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CN2011103920242A CN102504459A (en) | 2011-12-01 | 2011-12-01 | PVB (polyvinyl butyral) sheet with single-layer and double-layer materials compatible on basis of compatibilizer and preparation method thereof |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104497395A (en) * | 2014-12-16 | 2015-04-08 | 重庆理工大学 | In-situ self-enhanced polyformaldehyde/polyethylene composite material and preparation method |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102076792A (en) * | 2009-05-11 | 2011-05-25 | 录象射流技术公司 | Thermal ink jet ink composition |
CN102174238A (en) * | 2011-03-04 | 2011-09-07 | 浙江德斯泰塑胶有限公司 | Formula for preparing high-strength PVB (Polyvinyl Butyral) sheet |
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102076792A (en) * | 2009-05-11 | 2011-05-25 | 录象射流技术公司 | Thermal ink jet ink composition |
CN102174238A (en) * | 2011-03-04 | 2011-09-07 | 浙江德斯泰塑胶有限公司 | Formula for preparing high-strength PVB (Polyvinyl Butyral) sheet |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104497395A (en) * | 2014-12-16 | 2015-04-08 | 重庆理工大学 | In-situ self-enhanced polyformaldehyde/polyethylene composite material and preparation method |
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Application publication date: 20120620 |