CN102065831A - Composition - Google Patents
Composition Download PDFInfo
- Publication number
- CN102065831A CN102065831A CN200980122955.1A CN200980122955A CN102065831A CN 102065831 A CN102065831 A CN 102065831A CN 200980122955 A CN200980122955 A CN 200980122955A CN 102065831 A CN102065831 A CN 102065831A
- Authority
- CN
- China
- Prior art keywords
- compositions
- wax
- polysiloxanes
- polymer
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a hair conditioning composition comprising hydrophobically modified anionic polymer and a fatty acid.
Description
The present invention relates to improved care composition.
Although existing prior art, but still need improved care composition.
Therefore, the invention provides the Wo 2008069000 of the anionic polymer that comprises hydrophobically modified.
The anionic polymer of hydrophobically modified provides better flush away (rinse-off) performance.Particularly it is like this when compositions is sent out film composition (conditioning mask composition) for conditioning.
Preferably, polymer is acrylate polymer or methacrylate polymers.
Preferably, hydrophobically modified comprises alkylation.
Preferably, alkyl comprises 6-30 carbon, more preferably 16-28 carbon and 18-24 carbon most preferably.
Preferred polymer is by Rohm ﹠amp; Haas sells, and commodity are called Aculyn.Most preferred polymer is Aculyn 28
TM
Polymer is with 0.01 weight %-5 weight %, and more preferably the amount of 0.05 weight %-1 weight % exists.
Compositions of the present invention also comprises fatty acid.Example is other homologues of branched chain fatty acid such as 18-methyl arachic acid and this series, straight chain fatty acid such as stearic acid, myristic acid and Palmic acid, and unsaturated fatty acid such as oleic acid, linoleic acid, linolenic acid and arachidonic acid.Preferred fatty acid is a stearic acid.Fatty acid can be individually, add as mixture or with the form of mixtures from the extract of for example lanoline.
Fatty acid is with 0.01 weight %-5 weight %, and the amount that is preferably 0.05 weight %-1 weight % exists.
Preferably, comprise structural agent (structurant) according to the described compositions of aforementioned each claim.Structural agent improves the product sensation in the user hands.
The structural agent that is used for " structuring (structuring) " compositions of the present invention can be natural or synthetic crystalline wax.Mineral, animal or plant wax are native paraffin.Synthetic wax is those waxes that formed from the raw material synthesized polymer or the native paraffin of chemical modification.
The example of spendable natural crystalline wax comprises petroleum base wax, as paraffin and microwax.Chemically, crystallite (MC) wax is very similar with paraffin, is made of long saturated hydrocarbon chain.Two types wax separates from crude oil, and MC wax has higher molecular weight usually.In refining process, from the high boiling fraction of crude oil, extract paraffin by cooling and filtration.After using sweating process (sweating process) except that the Residual oil in the dewax, the paraffin that obtains has the oil less than 0.5% usually.
The wax that has available many different brackets, it mainly is the fusing point difference.Generally speaking, paraffin is colourless or white and transparent.Paraffin is mainly by straight chain molecule with a spot ofly mainly form at the branched chain molecule that has side chain near the chain end place.Because the existence of long linear, paraffin has the good crystal of big formation.Although there is the more paraffin of long-chain (molecular weight is up to 600), the molecular weight of paraffin is generally 360-420 (26-30 carbon atom).Typical fusing point is 126-134 ℉ (52-57 a ℃), and high-molecular weight melting point of paraffin wax is near 170 ℉ (77 ℃).Paraffin is brittle, and adds oil meeting weakening its structure (reduction tensile strength).
Microwax (MC) there are differences on physical property, chain structure and length and processing technique with paraffin.They are more tough and tensile, more pliable and tougher and have higher tensile strength and a fusing point than paraffin.MC wax has high-affinity to the plastic oil that increases wax when being added.MC wax can not distill under Undec situation, so MC wax is isolating from the residual distillation fraction of crude oil by dewaxing technique, and this dewaxing technique is included in and carries out recrystallization and centrifugal in the organic solvent.The content of oil is different according to grade, but is generally about 2%-12%.MC wax mainly comprises along the molecule of the side chain of the chain random distribution with some straight chains.Typical fusing point is 145-195 ℉ (63-91 a ℃).High needle penetration (penetration number) shows the flexibility of wax, but flexibility is not the function of fusing point.
Also there are other mineral waxs, for example montan wax (montan wax), montan wax (lignite wax), osocerite, ceresine, Utah wax (utah wax) and peat wax.
Can for example Apis, insecticide or whale obtain animal wax from such animal.These waxes include but not limited to Cera Flava, Chinese wax, shellac wax, spermaceti and lanocerin.The Cera Flava that for example is classified as animal wax is excretory by Apis, to make up Nidus Vespae.Gather in the crops wax by melting Nidus Vespae and filtering out wax.Mellisic fusing point is about 61-65 ℃, and compatible with the oil energy with nearly all wax.
Can obtain vegetable wax from beans, leaf and berry.Vegetable wax can comprise bayberry, the wax Radix Euphorbiae Pekinensis, babassu, Cotton Gossypii, esparto, fir, Japan wax (Japan), ouricury, Petiolus Trachycarpi, Testa oryzae oil, Caulis Sacchari sinensis, Semen Myristicae (ucuhuba) and cupu oil wax.
The example of available synthetic crystalline wax comprises wax, polyalphaolefin and the synthetic animal wax of crystalline polymer such as polyethylene, polymethylene (polymethylene), chemical modification.For example, can use to passing through mellisic silica-based (siliconyl) Cera Flava of chemical modification.
The example of spendable various waxes and character thereof are listed in in the following table 1 according to the present invention.
Table 1: wax and character thereof
*MC: crystallite; P: paraffin; N: natural/animal; DN: the derivant of natural/animal wax
*Needle penetration: by the penetration number of manufacturer's report, the pin of the pertroleum wax of use American Society Testing and Materials is gone into the standard method of test (ASTM D 1321) of (needle penetration).Use penetrometer to measure the degree of depth that 1/10th (dmm) with millimeter go into as the pin of unit, this penetrometer under 100 loads that restrain to sample administration standard pin 5 seconds.
Another structured material of the present invention (for example being used for other beneficial agents of structuring) is a microwax vaseline (being also referred to as vaseline or mineral jelly), and it comprises natural mixture and a spot of other impurity of the microwax of about 90 weight % usually.
Compositions of the present invention can comprise any composition of the conventional multiple composition that uses in the care composition.
Compositions of the present invention can also be formulated as the conditioner that is used for hair treatment (usually in hair washing (shampooing) back) and follow-up flushing.
Such conditioner comprises one or more and makes up acceptable and be suitable for being applied topically to the conditioning surfactant of hair.
Suitable conditioning surfactant is selected from cationic surfactant, uses separately or the mixing use.Example comprises quaternary ammonium hydroxide or its salt, for example chloride.
The suitable cationic surfactants that is used for hair conditioner of the present invention comprises cetyl trimethyl ammonium chloride, INCROQUAT TMC-80 ECONOL TM22, cetyl pyridinium chloride
Tetramethyl ammonium chloride, tetraethylammonium chloride, octyl group trimethyl ammonium chloride, Dodecyl trimethyl ammonium chloride, hexadecyltrimethylammonium chloride, octyldimethyl benzyl ammonium chloride, decyl dimethyl benzyl ammonium chloride, stearyl dimethyl benzyl ammonium chloride, two (dodecyl) alkyl dimethyl ammonium chloride, two (octadecyl) alkyl dimethyl ammonium chloride, Adeps Bovis seu Bubali base trimethyl ammonium chloride, cocoyl trimethyl ammonium chloride and corresponding hydroxide thereof.Other suitable cationic surfactants comprise the material of those CTFA called after quaternary ammonium salts-5, quaternary ammonium salt-31 and quaternary ammonium salt-18.The mixture of above-mentioned any materials also is suitable.The cationic surfactant that is particularly useful that is used for hair conditioner of the present invention is the cetyl trimethyl ammonium chloride, for example, can be commercially available with the title of DEHYQUART from Henkel.
In conditioner of the present invention, the content of cationic surfactant accounts for the preferred 0.01-10% of composition weight, more preferably 0.05-5%, 0.1-2% most preferably.
Conditioner of the present invention advantageously contains fatty alcohol material.In care composition, be used in combination fatty alcohol material and cationic surfactant and be considered to particularly advantageous, be scattered in wherein lamellar phase because this causes forming cationic surfactant.
Representative fatty alcohols comprises 8-22 carbon atom, more preferably 16-20 carbon atom.The example of suitable aliphatic alcohol comprises spermol, stearyl alcohol and composition thereof.The favourable part of the use of these materials is that also they help the whole conditioning performance of compositions of the present invention.
The content of the fatty alcohol material in the conditioner of the present invention generally is to account for 0.01% to 10% of composition weight, preferred 0.1% to 5%.The weight ratio of cationic surfactant and aliphatic alcohol suitably is 10: 1 to 1: 10, and preferred 4: 1 to 1: 8, the best was 1: 1 to 1: 4.
Polysiloxanes is a particularly preferred composition in the hair-treatment composition of the present invention.Especially, conditioner of the present invention preferably also comprises the polysiloxanes emulsifying microgranule that is used to improve conditioning performance.Polysiloxanes is insoluble in the aqueous matrix of compositions, thereby exists with the emulsifying form, and wherein polysiloxanes exists as disperse particles.
Suitable polysiloxanes comprises polydiorganosiloxanepolyurea, and particularly the CTFA name is called the polydimethylsiloxane of dimethicone (dimethicone).The polysiloxanes that is suitable for the present composition comprises that also the CTFA name is called the polydimethylsiloxane that contains hydroxyl end groups of dimethiconol (dimethiconol).The polysiloxanes that is suitable for the present composition also comprises the 96/31188 described silicone gums (silicone gum) with low crosslinking degree as WO.These materials can give the hair scale of construction (body), plentiful (volume) but and constancy, and good wet and do conditioning property.
The viscosity of emulsifying polysiloxanes self (not being emulsion or final Wo 2008069000) is generally at least 10,000cst.Generally speaking, we find that conditioning performance increases and increases along with viscosity.Therefore, the viscosity of polysiloxanes self is preferably at least 60, and 000cst most preferably is at least 500, and 000cst is desirably at least 1,000,000cst.Preferably, for easy preparation, viscosity is no more than 10
9Cst.
Be used for the present composition conditioner the emulsifying polysiloxanes average granular of polyorganosiloxane size usually less than 30 microns, preferably less than 20 microns, be more preferably less than 10 microns.We have found that, reduce particle size and improve conditioning performance usually.Most preferably, the average granular of polyorganosiloxane size of emulsifying polysiloxanes is desirably the 0.01-1 micron less than 2 microns in the compositions.Polysiloxane emulsion with average granular of polyorganosiloxane size≤0.15 micron is commonly called microemulsion.
Particle size can use the 2600D Particle Sizer from Malvern Instruments to measure by laser scattering technology.
Be used for suitable polysiloxane emulsion of the present invention in advance the emulsifying form be purchased.
The example of suitable preformed emulsion comprises emulsion DC2-1766, DC2-1784 and microemulsion DC2-1865 and DC2-1870, and they all can be bought from Dow Corning.These are the emulsion/microemulsion of dimethiconol entirely.Can also obtain the crosslinked polysiloxane glue of pre-emulsifying form, its easiness to preparation is favourable.Preferred example be the material DC X2-1787 from Dow Corning acquisition, and it is the emulsion of crosslinked dimethiconol glue.Further preferred example is the material DCX2-1391 that obtains from Dow Corning, and it is the microemulsion of crosslinked dimethiconol glue.
The further preferred polysiloxanes type that comprises in conditioner of the present invention is an amino functionalised." amino functionalised " is meant the polysiloxanes that contains at least one primary amine, secondary amine or tertiary amine group or quaternary ammonium group.
The example of suitable amino functionalised comprises:
(i) the CTFA name is called the polysiloxanes of " amino-terminated polydimethylsiloxane (amodimethicone) ", has following general formula:
HO-[Si(CH
3)
2-O-]
x-[Si(OH)(CH
2CH
2CH
2-NH-CH
2CH
2NH
2)-O-]
y-H
Wherein, x and y are the numerical value that depends on the molecular weight of polymer, make that usually molecular weight is about 5,000-500,000.
The polysiloxanes that (ii) has following general formula:
R′
aG
3-a-Si(OSiG
2)
n-(OSiG
bR′
2-b)
m-O-SiG
3-a-R′
a
Wherein: G is selected from H, phenyl, OH or C
1-8Alkyl such as methyl;
A is 0 or the integer of 1-3, preferred 0;
B is 0 or 1, preferred 1;
M and n are for making (m+n) be 1-2000, be preferably the numerical value of 50-150;
M is the numerical value of 1-2000, preferred 1-10;
N be 0-1999, preferred 49-149 numerical value and
R ' is formula-C
qH
2qThe L monoradical, wherein, q is the numerical value of 2-8, L is the aminofunctional group that is selected from following group:
-NR″-CH
2-CH
2-N(R″)
2
-N(R″)
2
-N
+(R″)
3A
-
-N
+H(R″)
2A
-
-N
+H
2(R″)A
-
-N(R″)-CH
2-CH
2-N
+H
2(R″)A
-
Wherein, R " be selected from H, phenyl, benzyl or saturated univalence hydrocarbyl such as C
1-20Alkyl and;
A is a halide ion, for example chloride ion or bromide ion.
The suitable amino functionalised of corresponding following formula comprises those polysiloxanes of as described below being called as " the amino polydimethylsiloxane of trimethyl silyl ", and it is fully water-insoluble so that be applicable in the compositions of the present invention:
Si(CH
3)
3-O-[Si(CH
3)
2-O-]
x-[Si(CH
3)(R-NH-
CH
2CH
2NH
2)-O-]
y-Si(CH
3)
3
Wherein, x+y is the numerical value of about 50-about 500, and wherein R is the alkylidene with 2-5 carbon atom.Preferably, numerical value x+y is about 100-about 300.
The quaternary ammonium polysiloxane alkane polymer that (iii) has following general formula:
{(R
1)(R
2)(R
3)N
+CH
2CH(OH)CH
2O(CH
2)
3[Si(R
4)(R
5)-O-]
n-Si(R
6)(R
7)-
(CH
2)
3-O-CH
2CH(OH)CH
2N
+(R
8)(R
9)(R
10)}(X
-)
2
Wherein, R
1And R
10Can be identical or different, and can be independently selected from H, saturated or unsaturated length or short chain alkane (alkene) base, branched alkane (alkene) base and C
5-C
8Loop systems;
R
2To R
9Can be identical or different, and can be independently selected from H, straight or branched lower alkyl (alkene) base and C
5-C
8Loop systems; N is the numerical value of about 60-about 120, be preferably about 80 and
X
-Be preferably acetate, but also can be for example halide ion, organic carboxyl acid root, organic sulfonic acid root etc.The suitable quaternary ammonium polysiloxane alkane polymer of the type has description in EP-A-0 530 974.
The amine degree of functionality mole % that is applicable to the amino functionalised in the conditioner of the present invention is generally the about 8.0 moles of % of about 0.1-, is preferably the about 5.0 moles of % of about 0.1-, most preferably is the about 2.0 moles of % of about 0.1-.Generally speaking, the concentration of amine should be no more than about 8.0 moles of % because the excessive concentration that we find amine for the deposition of total polysiloxanes, be deleterious to conditioning performance then.
The viscosity of amino functionalised is not particular importance, can be suitably for about 100-is about 500,000cst.
The object lesson that is applicable to amino functionalised of the present invention is amino silicones oil DC2-8220, DC2-8166, DC2-8466 and DC2-8950-114 (all from Dow Corning) and GE 1149-75 (from General Electric Silicones).
The emulsion that comprises the amino functionalised oil of nonionic and/or cationic surfactant also is suitable.
In the compositions particle size of the average amino functionalised of so preformed emulsion suitably less than 30 microns, preferably less than 20 microns, be more preferably less than 10 microns.In addition, we have found that reducing particle size generally can improve conditioning performance.In the compositions particle size of average amino functionalised most preferably less than 2 microns, be desirably the 0.01-1 micron.Polysiloxane emulsion with particle size≤0.15 micron of average polysiloxanes is commonly called microemulsion.
The pre-formation emulsion of amino functionalised also can be from supplier such as the Dow Corning and the General Electric purchase of polysiloxane oil.Object lesson comprises DC929Cationic Emulsion, DC939 Cationic Emulsion and non-ionic emulsion DC2-7224, DC2-8467, DC2-8177 and DC2-8154 (all from Dow Corning).
The example that is used for quaternary ammonium polysiloxane alkane polymer of the present invention is the material K3474 from Goldschmidt.
The total amount that adds the polysiloxanes in the present composition depends on the material of the gentle use of opsonic water of needs.Preferred amount is about 0.01%-about 10% of total composition weight.
We have found that the preferred content of polysiloxanes total amount is the 0.3-5% of total composition weight, is preferably 0.5-3%.
Other compositions can comprise viscosity modifier, antiseptic, coloring agent, polyhydric alcohol such as glycerol and polypropylene glycol, chelating agen such as EDTA, antioxidant such as Vitamin E acetate, aromatic, antimicrobial and opacifier.Every kind amount of these compositions is enough to realize its purposes.The content of these selectable compositions that comprised usually is up to about 5% for total composition weight independently.
Preferably, compositions of the present invention also comprises the adjuvant that is suitable for hair nursing.The content of this composition that is comprised is respectively done for oneself being up to 2%, preferably being up to 1% of total composition weight usually.
Suitable hair nursing adjuvant is:
(i) natural hair root nutrition thing, for example aminoacid and sugar.Suitable amino acid whose example comprises arginine, cysteine, glutamine, glutamic acid, isoleucine, leucine, methionine, serine and valine, and/or its precursor and derivant.Aminoacid can be separately, mix or add with the form (for example dipeptides and tripeptides) of peptide.Aminoacid can also add with the form (for example keratin or collagen hydrolysate) of protein hydrolysate.Suitable sugar is glucose, dextrose and fructose.These can add separately or with the form of for example fruit extract.
(ii) hair fiber beneficial agent.Example is:
-fiber and keep the complete ceramide of horny layer (cuticle) is used to preserve moisture.Ceramide can extract obtain from natural origin, or is that synthetic ceramide and false vitalility are through amide.Preferred ceramide is the Ceramide II from Quest.The mixture of ceramide also is suitable, for example from the Ceramides LS of Laboratoires Serobiologiques.
Can also use the mixture of above-mentioned any active component.
In second aspect, provide the method that is used to prepare according to the care composition of first aspect.This method comprises: form the conditioning gel phase that comprises cationic surfactant and fatty material, and the independent in addition solution that forms the polymer of hydrophobically modified, it randomly comprises cationic surfactant, and if have cationic surfactant, add in the entry earlier.
In that residual components is added with before forming care composition, two kinds of mixture are added in the another kind mutually then.
Preferably, extra composition comprises flavouring agent, thickening agent, antiseptic, coloring agent and conditioning polysiloxanes.
Embodiment 1
According to preparation of the present invention.It is to add the preparation of stearamide propyl dimethylamine again after earlier the water of about 35 weight % being heated to 65-70 ℃.Continue to mix and dissolve fully up to product.
Under high shear add Aculyn28 with aid dispersion.
In addition individually, INCROQUAT TMC-80 ECONOL TM22, cetearyl alcohol, stearic acid and paraffin are melted simultaneously, and this molten mixture added with Aculyn and stearamide propyl dimethylamine become owner of blender.
Be cooled to 40-45 ℃, add conditioning polysiloxanes, aromatic and antiseptic then.
Embodiment 2
Compositions A is the compositions according to embodiment 1, and reference composition B is identical except lacking stearic acid.
The ability of the deposition polysiloxanes of Comparative composition A and B.
Compositions A scoring is 2403ppm, and compositions B scoring only is 1327ppm.
Claims (11)
1. the Wo 2008069000 that comprises anionic polymer, polysiloxanes and the fatty acid of hydrophobically modified.
2. compositions as claimed in claim 1, it comprises structural agent.
3. compositions as claimed in claim 1 or 2, wherein said polymer are acrylate polymer.
4. the described compositions of each claim as described above, wherein said polymer is a methacrylate polymers.
5. the described compositions of each claim as described above, wherein said hydrophobically modified comprises alkylation.
6. compositions as claimed in claim 5, wherein said alkyl comprise 6-30 carbon.
7. as each described compositions among the claim 2-6, wherein said structural agent is a paraffin.
8. the described compositions of each claim as described above, it comprises the polymer of 0.01 weight %-5 weight %.
9. the described compositions of each claim as described above, wherein said fatty acid comprises 8-28 carbon.
10. the described compositions of each claim as described above, wherein said fatty acid is a straight chain.
11. the described compositions of each claim as described above, wherein said fatty acid is a stearic acid.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP08158656.2 | 2008-06-20 | ||
EP08158656 | 2008-06-20 | ||
PCT/EP2009/057515 WO2009153280A1 (en) | 2008-06-20 | 2009-06-17 | Composition |
Publications (1)
Publication Number | Publication Date |
---|---|
CN102065831A true CN102065831A (en) | 2011-05-18 |
Family
ID=39956126
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN200980122955.1A Pending CN102065831A (en) | 2008-06-20 | 2009-06-17 | Composition |
Country Status (11)
Country | Link |
---|---|
EP (1) | EP2293768A1 (en) |
JP (1) | JP2011524875A (en) |
KR (1) | KR20110020927A (en) |
CN (1) | CN102065831A (en) |
AR (1) | AR072274A1 (en) |
AU (1) | AU2009259417A1 (en) |
BR (1) | BRPI0909933A2 (en) |
EA (1) | EA201170062A1 (en) |
MX (1) | MX2010014096A (en) |
TW (1) | TW201004654A (en) |
WO (1) | WO2009153280A1 (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2898874A1 (en) * | 2011-09-12 | 2015-07-29 | The Procter and Gamble Company | Method for colouring hair |
JP5907608B2 (en) * | 2012-01-13 | 2016-04-26 | 株式会社ミルボン | Multi-agent hair treatment |
DE102012201861A1 (en) * | 2012-02-08 | 2013-08-08 | Henkel Ag & Co. Kgaa | Conditioning hair cleanser |
CN104168961A (en) * | 2012-03-30 | 2014-11-26 | 宝洁公司 | Hair conditioning composition comprising mono-alkyl amine cationic surfactant system, deposition polymer, and silicone |
JP2015512415A (en) * | 2012-03-30 | 2015-04-27 | ザ プロクター アンド ギャンブルカンパニー | Hair conditioning composition comprising a cationic surfactant and an adhesion polymer |
EP3052073A1 (en) * | 2013-09-30 | 2016-08-10 | The Procter & Gamble Company | Hair conditioning composition comprising higher percent of cationic surfactant and deposition polymer |
BR112019025116B1 (en) | 2017-06-15 | 2023-05-09 | Unilever Ip Holdings B.V | HAIR TREATMENT COMPOSITION AND WATER SAVING METHOD |
US20200197273A1 (en) | 2017-06-15 | 2020-06-25 | Conopco, Inc., D/B/A Unilever | Hair conditioning composition having improved rinse properties |
CN110769806A (en) | 2017-06-15 | 2020-02-07 | 荷兰联合利华有限公司 | Hair conditioning composition for improved rinsing |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5656257A (en) * | 1995-04-28 | 1997-08-12 | Electronics Hair Styling, Inc. | Shampoo and conditioning composition |
MA25005A1 (en) * | 1998-10-09 | 2000-07-01 | Colgate Palmolive Co | VOLUME HAIR CARE COMPOSITIONS |
US20030005526A1 (en) * | 2001-05-15 | 2003-01-09 | Stephen Casperson | Two-part aqueous composition for oxidative coloration of hair |
US20060193789A1 (en) * | 2002-10-25 | 2006-08-31 | Foamix Ltd. | Film forming foamable composition |
DE102005022021A1 (en) * | 2005-05-12 | 2006-11-16 | Basf Ag | Isoalkane mixture, useful in hydrophobic component of homogenous/heterogeneous phase of cosmetic or pharmaceutical composition e.g. skin protectant, decorative cosmetic and hair treatment agent for damp bearing of skin |
WO2007111962A2 (en) * | 2006-03-22 | 2007-10-04 | The Procter & Gamble Company | Aerosol product comprising a foaming concentrate composition comprising particulate materials |
-
2009
- 2009-06-11 TW TW098119554A patent/TW201004654A/en unknown
- 2009-06-17 JP JP2011514029A patent/JP2011524875A/en not_active Withdrawn
- 2009-06-17 CN CN200980122955.1A patent/CN102065831A/en active Pending
- 2009-06-17 EP EP09765860A patent/EP2293768A1/en not_active Withdrawn
- 2009-06-17 MX MX2010014096A patent/MX2010014096A/en not_active Application Discontinuation
- 2009-06-17 EA EA201170062A patent/EA201170062A1/en unknown
- 2009-06-17 BR BRPI0909933A patent/BRPI0909933A2/en not_active IP Right Cessation
- 2009-06-17 KR KR1020117001352A patent/KR20110020927A/en not_active Application Discontinuation
- 2009-06-17 AU AU2009259417A patent/AU2009259417A1/en not_active Abandoned
- 2009-06-17 WO PCT/EP2009/057515 patent/WO2009153280A1/en active Application Filing
- 2009-06-22 AR ARP090102278A patent/AR072274A1/en not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
AU2009259417A1 (en) | 2009-12-23 |
EA201170062A1 (en) | 2011-06-30 |
AR072274A1 (en) | 2010-08-18 |
BRPI0909933A2 (en) | 2015-10-20 |
EP2293768A1 (en) | 2011-03-16 |
MX2010014096A (en) | 2011-03-04 |
WO2009153280A1 (en) | 2009-12-23 |
JP2011524875A (en) | 2011-09-08 |
KR20110020927A (en) | 2011-03-03 |
TW201004654A (en) | 2010-02-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102065831A (en) | Composition | |
CN102065830A (en) | Composition | |
CN102448427B (en) | Composition | |
CN108430432A (en) | The method for handling hair | |
CN108367168A (en) | The method for handling hair | |
CN101005826B (en) | Hair care composition comprising a dendritic compositions | |
JP2002509868A (en) | Hair conditioning composition | |
JP2001525352A (en) | Hair treatment composition | |
TWI733764B (en) | Biphase cosmetic composition and its use by topical application | |
TWI526226B (en) | Composition | |
JP4754326B2 (en) | Hair cosmetics | |
TWI515018B (en) | Hair conditioning composition | |
JP2008509979A (en) | Hair care compositions based on dendritic polymers composed of anhydride units | |
MX2011006443A (en) | Hair care composition comprising a dendritic macromolecule. | |
TW201036642A (en) | Composition | |
TW201102104A (en) | Hair cosmetic | |
CN116850078A (en) | Hair composition with internal and external synergistic nutrition and hair restoration effects | |
JP2023074095A (en) | Oil-dispersible micelle composition and hair cosmetic comprising the same | |
CN111093605A (en) | Hair styling composition | |
JP2016193837A (en) | Emulsion composition for cosmetic containing acylated hydrolyzed collagen and manufacturing method of the same, and hair cosmetic blending emulsion composition for cosmetic containing acylated hydrolyzed collagen |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20110518 |