CN102064282A - Organic electroluminescent device - Google Patents
Organic electroluminescent device Download PDFInfo
- Publication number
- CN102064282A CN102064282A CN2009102347595A CN200910234759A CN102064282A CN 102064282 A CN102064282 A CN 102064282A CN 2009102347595 A CN2009102347595 A CN 2009102347595A CN 200910234759 A CN200910234759 A CN 200910234759A CN 102064282 A CN102064282 A CN 102064282A
- Authority
- CN
- China
- Prior art keywords
- layer
- organic electroluminescence
- phosphorescent
- bepp
- acac
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Landscapes
- Electroluminescent Light Sources (AREA)
Abstract
The invention relates to an organic electroluminescent device. In order to obtain the organic electroluminescent device with high efficiency and good color purity, an organic functional layer of the device comprises a blue luminescent layer and a phosphorescence luminescent layer, wherein the phosphorescence luminescent layer can be monolayer or multilayer; and in the blue luminescent layer, a blue light material with the high triplet-state energy level is adopted, and the blue light material can be used as a main material of a phosphorescence layer simultaneously, so that singlet-state excitons and triplet-state excitons of the blue light material can be utilized effectively. Therefore the efficiency of the device is improved, the material is saved and a process is simplified simultaneously.
Description
Technical field
The present invention relates to a kind of organic electroluminescence device, relate in particular to a kind of structure of organic electroluminescent white light device.
Background technology
Incandescent lamp and fluorescent lamp are two kinds of light sources commonly used at present, but its energy utilization efficiency is all not high.The efficient of incandescent lamp has only 13～20lm/W, and it converts most of electric energy to heat energy, has caused the lot of energy waste.Fluorescent lamp plays an important role the human lives with in producing, and its efficient is about 90lm/W.But fluorescent lamp also exists a series of defectives, and, useful life low as luminous efficiency is contained a large amount of ultraviolet radiations in short, the light, causes environmental pollution thereby contain heavy metals such as a large amount of mercury and lead.So people's needs are a kind of efficiently, the new type light source of energy-saving and environmental protection.
Organic electroluminescence device (Organic Light Emitting Diode is hereinafter to be referred as OLED) is by on-load voltage between two electrodes, makes the electric field excitation light-emitting material, thereby converts electrical energy into the device of luminous energy.White OLED is because of the advantage of himself uniqueness becomes planar light source of new generation.White OLED is an area source, and is luminous even, do not glimmer; In light weight, ultra-thin, can deposit on the multiple substrate, as glass, plastics etc.; Have good chromaticity coordinates, can realize high color rendering index (CRI) (CRI) etc., so White OLED has attracted people more and more to pay close attention to holding out broad prospects aspect illumination and the plane display backlight near 100.
White OLED is divided according to luminescence center, can be divided into two luminescence centers and three luminescence centers, and the former realizes that by mixing two complementary colours as blue and yellow, orange red and sky blue, the latter often realizes by mixing the red, green, blue three primary colors.White OLED is divided according to structure, can be divided into that the unification compound emits white light, single-shot photosphere white light, multi-luminescent layer white light, the white light of laminated construction etc.In this multiple structure, the most ripe with multi-luminescent layer white light structure especially.In multi-luminescent layer white light structure, often use red, green, blue three luminescent layers, this structure can reach higher efficient, colourity and higher color rendering index preferably.The luminescent layer of OLED device adopts the structure of material of main part dopant dye usually, and the inventor has proposed a kind of new thinking through concentrating on studies, and device efficiency is higher, the material category of use still less, cost is lower.
Certainly, be not limited to send white light after the two or more blend of colors, blending under the situation of other colors, the present invention can reduce the kind of the material of use equally, raises the efficiency.
Summary of the invention
The purpose of this invention is to provide that a kind of material category is few, cost is low, the OLED device of efficient stable.
Purpose of the present invention can be achieved through the following technical solutions:
A kind of organic electroluminescence device, comprise anode layer, cathode layer and the organic function layer between anode layer and cathode layer, organic function layer comprises blue light-emitting layer, comprise first phosphorescent layer of the material of main part and first phosphor material, comprise second phosphorescent layer of the material of main part and second phosphor material, and the triplet of the luminescent material of blue light-emitting layer is higher than the triplet of first phosphorescent coloring and second phosphorescent coloring.
The material of main part of second phosphorescent layer is identical with the luminescent material of blue light-emitting layer.The luminescent material of blue light-emitting layer can be preferably Bepp for the complex of Be, Al, Ga, In, Zn
2, AlmND
3, AlmmND
3, GamND
3, InmND
3, 4CzPBP.
Blue light-emitting layer also comprises the material of transport property, and its triplet is higher than the triplet of first phosphorescent coloring and second phosphorescent coloring, can be hole transport ability matter, electric transmission character or double carriers transport property.
Blue light-emitting layer is between first phosphorescent layer and second phosphorescent layer, and thickness is preferably 2～20nm.
Organic function layer can also comprise electron transfer layer, and the material of electron transfer layer can be identical with the material of blue light-emitting layer.
First phosphorescent coloring can be Ir (piq)
3, Ir (piq)
2(acac), Btp
2Ir (acac), Ir (MDQ)
2(acac), Ir (DBQ)
2(acac), Ir (fbi)
2(acac), Ir (2-phq)
3, Ir (2-phq)
2(acac), Ir (bt)
2(acac) or PtOEP.Second phosphorescent coloring can be Ir (ppy)
3, Ir (ppy)
2(acac) or Ir (mppy)
3The material of main part of first phosphorescent layer can be NPB, TCTA, TPD, TAPC, Bepp
2, Bebq
2, BAlq, MCP or CBP.The material of main part of second phosphorescent layer can be Bepp
2, TCTA, TAZ, TPBI or CBP.
Organic electroluminescence device produces white light.
Purpose of the present invention can also be achieved through the following technical solutions:
A kind of organic electroluminescence device, comprise anode layer, cathode layer and the organic function layer between anode layer and cathode layer, organic function layer comprises blue light-emitting layer, comprises the phosphorescent layer of material of main part and phosphorescent coloring that the triplet of the luminescent material of blue light-emitting layer is higher than the triplet of phosphorescent coloring.
The material of main part of phosphorescent layer is identical with the luminescent material of blue light-emitting layer.The luminescent material of blue light-emitting layer is the complex of Be, Al, Ga, In, Zn, is preferably Bepp
2, AlmND
3, AlmmND
3, GamND
3, InmND
3, 4CzPBP.
Blue light-emitting layer also comprises the material of transport property, and its triplet is higher than the triplet of phosphorescent coloring, can be hole transport ability matter, electric transmission character or double carriers transport property.
Blue light-emitting layer is between first phosphorescent layer and second phosphorescent layer, and thickness is preferably 2～20nm.
Organic function layer can also comprise electron transfer layer, and the material of electron transfer layer can be identical with the material of blue light-emitting layer.
Phosphorescent coloring is selected from Ir (MDQ)
2(acac), Ir (DBQ)
2(acac), Ir (fbi)
2(acac), Ir (2-phq)
3, Ir (2-phq)
2(acac) or Ir (bt)
2(acac).The material of main part of phosphorescent layer can be NPB, TCTA, Bepp
2, Bebq
2, BAlq, MCP or CBP.
Organic electroluminescence device produces white light.
The compound tense on the blu-ray layer material when electronics and hole, existing singlet exciton has triplet excitons again, and singlet exciton is used for radiation and sends blue-fluorescence, and triplet excitons is invalid compound in the ordinary course of things, can not be utilized.But can effectively utilize the triplet excitons of blu-ray layer among the present invention, because the triplet of the blu-ray layer material that the present invention adopts is higher than the triplet of phosphorescent coloring, so the energy of the triplet excitons of blu-ray layer can pass to phosphorescent coloring, in phosphorescent coloring, produce radiation transistion or compound, make the singlet exciton of blu-ray layer and the energy of triplet excitons be fully used.Therefore, the efficient of device is higher.
The material of blue light-emitting layer can reduce the kind of material requested in this case simultaneously as the material of main part or the electron transport material of other luminescent layers.
Description of drawings
Fig. 1 is the structural representation of organic electroluminescence device.
Wherein, description of reference numerals is as follows:
The 01-substrate, 02-anode layer, 03-cathode layer, 04-hole transmission layer, 05,06, the 07-luminescent layer, 08-electron transfer layer.
Embodiment
The structural formula of the main chemical substance of the present invention is described as follows:
Table 8
Basic structure in the organic electroluminescence device that the present invention proposes as shown in Figure 1, wherein 01 be substrate, can be glass or flexible substrate, a kind of material in flexible substrate employing polyesters, the polyimides compounds; 02 is anode layer, can adopt inorganic material or organic conductive polymer.Inorganic material is generally tin indium oxide (be called for short ITO), the higher metals of work function such as metal oxide such as zinc oxide, zinc tin oxide or gold, copper, silver, preferred ITO; The organic conductive polymer is preferably a kind of material in polythiophene/polyvinylbenzenesulfonic acid sodium (hereinafter to be referred as PEDOTPSS), the polyaniline (hereinafter to be referred as PANI); 03 is cathode layer, generally adopts the alloy of the lower metal of work functions such as lithium, magnesium, calcium, strontium, aluminium, indium or they and copper, gold, silver, or the electrode layer that alternately forms of metal and metal fluoride, and the present invention is preferably LiF layer, Al layer successively.
Among Fig. 1 04 is hole transmission layer, material for example, have amino substituting group De oxadiazole compound, have amino substituent triphenyl methane compound, three grades of compounds, hydrazone compound, pyrazoline compounds, enamine compound, compound of styryl, 1,2-diphenyl ethene compounds or carbazole compound.Can also adopt the halide of bismuth metal or the oxide of bismuth metal to mix.
05,06,07 is three luminescent layers, can certainly be the structure of two luminescent layers.Material of main part and dyestuff to phosphorescent layer are not particularly limited.For example, Ir (ppy)
3, Ir (ppy)
2(acac) or Ir (mppy)
3Can be used as the green glow dyestuff; Ir (piq)
3, Ir (piq)
2(acac), Btp
2Ir (acac), Ir (MDQ)
2(acac), Ir (DBQ)
2(acac), Ir (fbi)
2(acac), Ir (2-phq)
3, Ir (2-phq)
2(acac), Ir (bt)
2(acac) or PtOEP can be used as red dye; Ir (MDQ)
2(acac), Ir (DBQ)
2(acac), Ir (fbi)
2(acac), Ir (2-phq)
3, Ir (2-phq)
2(acac) or Ir (bt)
2(acac) can be used as the gold-tinted dyestuff.
08 is electron transfer layer (nonessential), and material can be anthracene compound, phenanthrene compound, fluoranthene compound, benzo (9,10) phenanthrene compound, diazole compounds or vinylidene compound.
To provide some embodiment below, and specific explanations technical scheme of the present invention in conjunction with the accompanying drawings.Should be noted that the following examples only are used for helping to understand invention, rather than limitation of the present invention.
(1) embodiment 1-7
Embodiment 1 provides a kind of White OLED device of three luminescence centers.Three luminescent layers are respectively red, blue, green light emitting layer, and the red phosphorescent luminescent layer adopts hole transport ability material of main part NPB, doping red dye Ir (piq)
3The blue luminescence layer adopts Bepp
2The main body of green phosphorescent luminescent layer adopts and blue luminescence layer identical materials Bepp
2, doping green dyestuff Ir (ppy)
3The device architecture of present embodiment is as follows:
ITO/NPB/NPB：Ir(piq)
3/Bepp
2/Bepp
2：Ir(ppy)
3/Bepp
2/LiF/Al (1)
The concrete preparation method who prepares the OLED device with above structure (1) is as follows:
1. utilize the ultrasonic and ultrasonic method of deionized water of the washing agent boil that glass substrate 01 is cleaned, and be placed on infrared lamp under and dry.As anode 02, thickness is 180nm at evaporation one deck ITO on glass;
2. the above-mentioned glass substrate that has anode is placed in the vacuum chamber, be evacuated to 1 * 10
-5Pa continues evaporation one deck NPB film as hole transmission layer 04 on above-mentioned anode tunic, speed is 0.1nm/s, and the evaporation thickness is 20nm;
3. the evaporation that the method that adopts double source to steam is altogether again carried out red phosphorescent luminescent layer 05 mixes Ir (piq)
3Doping content in NPB is 0.7wt%, and the evaporation thickness is 15nm;
4. evaporation Bepp on the red phosphorescent luminescent layer
2Material is as blue light-emitting layer 06, and single source evaporation, thickness are 2nm; 5. evaporation green phosphorescent luminescent layer 07 on blue light-emitting layer 06, the method that adopts double source to steam is altogether carried out Ir (ppy)
3At Bepp
2In doping content be 15wt%, the evaporation thickness is 35nm;
6. on the green phosphorescent luminescent layer, continue evaporation one deck Bepp
2Material is as electron transfer layer 08, and its evaporation speed is 0.2nm/s, and the evaporation total film thickness is 25nm;
7. last, evaporation LiF layer and Al layer are as the cathode layer 03 of device successively on above-mentioned luminescent layer, and wherein the evaporation speed of LiF layer is 0.01～0.02nm/s, and thickness is 0.7nm, and the evaporation speed of Al layer is 2.0nm/s, and thickness is 150nm.
Device architecture and the preparation method of embodiment 2-embodiment 7 are substantially the same manner as Example 1, and the difference part is that the thickness of the blue light-emitting layer of embodiment 2-embodiment 7 is respectively 4nm, 6nm, 8nm, 10nm, 15nm, 20nm.
The OLED device architecture performance of the foregoing description 1-embodiment 7 is as shown in table 1, and wherein, x% represents the doping percentage by weight of red light emitting layer dyestuff in material of main part, and y% represents the doping percentage by weight of green light emitting layer dyestuff in material of main part.
Table 1
| Ruddiness | Green glow | Luminous | Chromaticity coordinates |
| Device | The luminescent layer device architecture | Layer x% | Layer y% | Efficient (cd/A) | (x，y) |
| Embodiment 1 | NPB：Ir(piq) 3(15nm)/Bepp 2(2nm)/Bepp 2： Ir(ppy) 3(35nm) | 0.7 | ?15 | 21.2 | (0.44，0.45) |
| Embodiment 2 | NPB：Ir(piq) 3(15nm)/Bepp 2(4nm)/Bepp 2： Ir(ppy) 3(35nm) | 0.7 | ?15 | 20.4 | (0.43，0.44) |
| Embodiment 3 | NPB：Ir(piq) 3(15nm)/Bepp 2(6nm)/Bepp 2： Ir(ppy) 3(35nm) | 0.7 | ?15 | 19.5 | (0.40，0.42) |
| Embodiment 4 | NPB：Ir(piq) 3(15nm)/Bepp 2(8nm)/Bepp 2： Ir(ppy) 3(35nm) | 0.7 | ?15 | 19.1 | (0.39，0.39) |
| Embodiment 5 | NPB：Ir(piq) 3(15nm)/Bepp 2(10nm)/Bepp 2： Ir(ppy) 3(35nm) | 0.7 | ?15 | 18.7 | (0.37，0.37) |
| Embodiment 6 | NPB：Ir(piq) 3(15nm)/Bepp 2(15nm)/Bepp 2： Ir(ppy) 3(35nm) | 0.7 | ?15 | 18.1 | (0.36，0.36) |
| Embodiment 7 | NPB：Ir(piq) 3(15nm)/Bepp 2(20nm)/Bepp 2： Ir(ppy) 3(35nm) | 0.7 | ?15 | 17.8 | (0.34，0.35) |
Comparative Examples 1
Device architecture is as follows:
ITO/NPB/NPB：Ir(piq)
3/NPB/Bepp
2：BD/Bepp
2/Bepp
2：Ir(ppy)
3/Bepp
2/LiF/Al (2)
The concrete preparation method of OLED device with above structure (2) is as follows:
1. utilize the ultrasonic and ultrasonic method of deionized water of the washing agent boil that glass substrate is cleaned, and be placed on infrared lamp under and dry, as anode, thickness is 180nm at evaporation one deck ITO on glass;
2. the above-mentioned glass substrate that has anode is placed in the vacuum chamber, be evacuated to 1 * 10
-5Pa, evaporation one deck NPB film is as hole transmission layer on above-mentioned anode tunic, and speed is 0.1nm/s, and the evaporation thickness is 20nm;
3. the evaporation that the method that adopts double source to steam is altogether again carried out the red phosphorescent luminescent layer mixes Ir (piq)
3Doping content in NPB is 0.7wt%, and the evaporation thickness is 15nm;
4. evaporation one deck NPB film is as first barrier layer on the red phosphorescent luminescent layer, and speed is 0.1nm/s, and the evaporation thickness is 2nm;
5. the method evaporation blue light-emitting layer that adopts double source to steam altogether, BD is at Bepp
2In doping content be 5wt%, thickness is 10nm;
6. evaporation Bepp on blue light-emitting layer
2Material is as second barrier layer, and thickness is 2nm;
7. evaporation green phosphorescent luminescent layer on blue light-emitting layer 07, the method that adopts double source to steam is altogether carried out Ir (ppy)
3At Bepp
2In doping content be 15wt%, the evaporation thickness is 35nm;
8. on the green phosphorescent luminescent layer, continue evaporation one deck Bepp
2Material is as electron transfer layer, and its evaporation speed is 0.2nm/s, and the evaporation total film thickness is 25nm;
9. last, evaporation LiF layer and Al layer are as the cathode layer of device successively on above-mentioned luminescent layer, and wherein the evaporation speed of LiF layer is 0.01～0.02nm/s, and thickness is 0.7nm, and the evaporation speed of Al layer is 2.0nm/s, and thickness is 150nm.
Compare with embodiment 1-embodiment 7, the blue light-emitting layer of Comparative Examples 1 adopts the structure of main body dopant dye, and material of main part is Bepp
2, dyestuff abbreviates BD (structural formula is as shown in table 8) as.Comparative Examples 2 is identical with the device architecture of Comparative Examples 1, and 3. difference is step, the Ir of Comparative Examples 2 (piq)
3Doping content in NPB is 5wt%.The device performance of Comparative Examples 1 and Comparative Examples 2 is as shown in table 2:
Table 2
| The luminescent layer device architecture | Ruddiness layer x% | Green glow layer y% | Luminous efficiency (cd/A) | Chromaticity coordinates (x, y) | |
| Comparative Examples 1 | NPB：Ir(piq) 3(15nm)/NPB(2 nm)/Bepp 2：BD(10nm，5％)/Bepp 2(2 nm)/Bepp 2：Ir(ppy) 3(35nm) | ?0.7 | ?15 | 5.5 | (0.18，0.27) |
| Comparative Examples 2 | NPB：Ir(piq) 3(15nm)/NPB(2 nm)/Bepp 2：BD(10nm，5％)/Bepp 2(2 nm)/Bepp 2：Ir(ppy) 3(35nm) | ?5 | ?15 | 8.5 | (0.34，0.38) |
As can be seen from Table 2, the device of Comparative Examples 1 is blue.The analysis reason is as follows: if with the form of blue light-emitting layer with the material of main part dopant dye, then need to add the barrier layer between fluorescence coating and the phosphorescent layer, this is to transmit energy for the singlet exciton of the material of main part of block blue luminescent layer to the dyestuff of phosphorescent layer, but pass to the blue light dyestuff, be used for launching blue-fluorescence; Allow triplet excitons transmit energy simultaneously to phosphorescent layer as far as possible.But in the Comparative Examples 1, because the transport property of the material of main part of first phosphorescent layer and second phosphorescent layer, it is compound to make that electronics and hole are easy in blue fluorescent body, the relative intensity of ruddiness composition and green glow composition is very weak, the device glow color is blue partially, and chromaticity coordinates is bad, and efficient is not high yet.Comparative Examples 2 has increased the concentration that red dye mixes, and makes the relative intensity of ruddiness composition increase, and improved chromaticity coordinates, but the relative intensity of green composition is still very weak, so whole efficiency is still very low.And the thickness on barrier layer also is not easy control.
This structure of the present invention: the red phosphorescent luminescent layer is near anode, its main body is the hole transport ability material, and the green phosphorescent luminescent layer is near negative electrode, and its main body is the electron-transporting material, middle is the blue fluorescent body of unification compound, and blue fluorescent body need not doping.The result of above embodiment and Comparative Examples shows, this structure can access higher efficient and colorimetric purity preferably, because:
The material of main part of red phosphorescent luminescent layer is a hole transport character, the material of main part of green phosphorescent luminescent material is an electric transmission character, so the hole is easy to be transferred to red phosphorescent layer/blue-fluorescence bed boundary, electronics is easy to be transferred to green phosphorescent layer/blue-fluorescence bed boundary, again because the material of blue fluorescent body and the material of main part of green phosphorescent luminescent layer are commaterials, also be electric transmission character, be transferred to red phosphorescent layer/blue-fluorescence bed boundary so have portions of electronics, hole-recombination at the interface therewith, again because the blue fluorescent body thinner thickness, the singlet exciton that electronics and hole-recombination form, cause the emission of blue-fluorescence, the triplet excitons that electronics and hole-recombination form can partly be transferred to the red phosphorescent layer that closes on, strengthen the emission of ruddiness, part is transferred to the green phosphorescent layer that closes on, strengthen the emission of green glow, make the singlet exciton and the triplet excitons of blue fluorescent body all be fully used like this, make that finally the efficient of white light of RGB three luminescence centers is higher, color is purer.
(2) embodiment 8-14
Compare with embodiment 1-7, embodiment 8-14 has increased hole injection layer, and the material of main part and the phosphorescent coloring of hole mobile material, red phosphorescent layer are also different.
The device architecture of embodiment 8-11:
ITO/HIL：HD/TAPC/TCTA：Ir(mdq)
2(acac)/Bepp
2/Bepp
2：Ir(ppy)
3/Bepp
2/LiF/Al (3)
The device architecture of embodiment 12-14 is respectively:
ITO/HIL：HD/TAPC/TAPC：Ir(mdq)
2(acac)/Bepp
2/Bepp
2：Ir(ppy)
3/Bepp
2/LiF/Al (4)
ITO/HIL：HD/TAPC/TPD：Ir(mdq)
2(acac)/Bepp
2/Bepp
2：Ir(ppy)
3/Bepp
2/LiF/Al (5)
ITO/HIL：HD/TAPC/NPB：Ir(mdq)
2(acac)/Bepp
2/Bepp
2：Ir(ppy)
3/Bepp
2/LiF/Al (6)
The device architecture of Comparative Examples 3-4:
ITO/HIL：HD/TAPC/TCTA：Ir(mdq)
2(acac)/TCTA/Bepp
2：BD/Bepp
2/Bepp
2：Ir(ppy)
3/Bepp
2/LiF/Al (7)
Table 3
| The luminescent layer device architecture | Orange red photosphere x% | Green glow layer y% | Luminous efficiency (cd/ A) | Chromaticity coordinates (x, y) | |
| Embodiment 8 | TCTA： Ir(mdq) 2(acac)(15nm)/Bepp 2(2nm)/Be pp 2：Ir(ppy) 3(35nm) | 0.7 | ?15 | 54.4 | (0.44，0.49) |
| Embodiment 9 | TCTA： Ir(mdq) 2(acac)(15nm)/Bepp 2(6nm)/Be pp 2：Ir(ppy) 3(35nm) | 0.7 | ?15 | 51.0 | (0.43，0.46) |
| Embodiment 10 | TCTA： Ir(mdq) 2(acac)(15nm)/Bepp 2(10nm)/B epp 2：Ir(ppy) 3(35nm) | 0.7 | ?15 | 45.2 | (0.40，0.41) |
| Embodiment 11 | TCTA：Ir(mdq) 2(acac)(15nm)/Bepp 2(1 5nm)/Bepp 2：Ir(ppy) 3(35nm) | 0.7 | ?15 | 42.3 | (0.36，0.39) |
| Embodiment 12 | TAPC：Ir(mdq) 2(acac)(15nm)/Bepp 2(2n m)/Bepp 2：Ir(ppy) 3(35nm) | 0.7 | ?15 | 53.2 | (0.43，0.47) |
| Embodiment 13 | TPD：Ir(mdq) 2(acac)(15nm)/Bepp 2(6n m)/Bepp 2：Ir(ppy) 3(35nm) | 0.7 | ?15 | 48.2 | (0.42，0.44) |
| Embodiment 14 | NPB：Ir(mdq) 2(acac)(15nm)/Bepp 2(10n m)/Bepp 2：Ir(ppy) 3(35nm) | 0.7 | ?15 | 32.5 | (0.37，0.39) |
| Comparative Examples 3 | TCTA：Ir(mdq) 2(acac)(15nm)/TCTA(2 nm)/Bepp 2：BD(10nm，5％)/Bepp 2(2 nm)/Bepp 2：Ir(ppy) 3(35nm) | 0.7 | ?15 | 9.5 | (0.18，0.27) |
| Comparative Examples 4 | TCTA：Ir(mdq) 2(acac)(15nm)/TCTA(2 nm)/Bepp 2：BD(10nm，5％)/Bepp 2(2 nm)/Bepp 2：Ir(ppy) 3(35nm) | 5 | ?15 | 14.0 | (0.34，0.36) |
(3) embodiment 15-20
Embodiment 15-20 has adopted different blue light-emitting layers and electric transmission layer material, and device architecture is as follows:
ITO/HIL:HD/TAPC/TCTA:Ir (mdq)
2(acac)/blu-ray layer/Bepp
2: Ir (ppy)
3/ electron transfer layer/LiF/Al (8)
Table 4
| Device | Blu-ray layer | Electron transfer layer | Luminous efficiency (cd/A) | Chromaticity coordinates (x, y) |
| Embodiment 15 | Bepp 2(6nm) | Bebq 2(25nm) | 49 | (0.42，0.46) |
| Embodiment 16 | AlmND 3(6nm) | AlmND3(25nm) | 47 | (0.41，0.42) |
| Embodiment 17 | AlmmND 3(6nm) | AlmND3(25nm) | 45.5 | (0.40，0.42) |
| Embodiment 18 | GamND 3(6nm) | GamND3(25nm) | 43 | (0.42，0.43) |
| Embodiment 19 | InmND 3(6nm) | InmND3(25nm) | 42 | (0.43，0.43) |
| Embodiment 20 | 4CzPBP(6nm) | Bepp 2(25nm) | 41.2 | (0.41，0.42) |
(4) embodiment 21-25
Embodiment 21-23 has increased the material of transport property at blue light-emitting layer, and device architecture is:
ITO/HIL：HD/TAPC/TCTA：Ir(mdq)
2(acac)/Bepp
2：TCTA/Bepp
2：Ir(ppy)
3/Bepp
2/LiF/Al (9)
The device architecture of embodiment 24:
ITO/HIL：HD/TAPC/TCTA：Ir(mdq)
2(acac)/Bepp
2：TAPC/Bepp
2：Ir(ppy)
3/Bepp
2/LiF/Al (10)
The device architecture of embodiment 25:
ITO/HIL：HD/TAPC/TCTA：Ir(mdq)
2(acac)/Bepp
2：CBP/Bepp
2：Ir(ppy)
3/Bepp
2/LiF/Al (11)
Table 5
| The blu-ray layer device architecture | Ruddiness layer x % | Green glow layer y% | Luminous efficiency (cd/ A) | Chromaticity coordinates (x, y) | |
| Embodiment 21 | TCTA：Ir(mdq) 2(acac)/Bepp 2：5％TCT A(6nm)/Bepp 2：Ir(ppy) 3 | 0.7 | ?15 | 52.4 | (0.41，0.41) |
| Embodiment 22 | TCTA：Ir(mdq) 2(acac)/Bepp 2：10％TC TA(6nm)/Bepp 2：Ir(ppy) 3 | 0.7 | ?15 | 52.0 | (0.40，0.41) |
| Embodiment 23 | TCTA：Ir(mdq) 2(acac)/Bepp 2：20％TC TA(6nm)/Bepp 2：Ir(ppy) 3 | 0.7 | ?15 | 50.2 | (0.40，0.41) |
| Embodiment 24 | TCTA：Ir(mdq) 2(acac)/Bepp 2：10％TA | 0.7 | ?15 | 52.3 | (0.39，0.42) |
| PC(6nm)/Bepp 2：Ir(ppy) 3 | |||||
| Embodiment 25 | TCTA：Ir(mdq) 2(acac)/Bepp 2：10％CB P(6nm)/Bepp 2：Ir(ppy) 3 | 0.7 | 15 | 53.1 | (0.39，0.39) |
If blu-ray layer is an electric transmission character, as embodiment 8-14, Bepp
2Itself be electric transmission character, then electronics and hole major part are compound at red/blue edge face.Embodiment 21-25 has increased the material TCTA of hole transport character or the CBP of TAPC or double carriers transport property in blu-ray layer, the zone of electronics and hole-recombination can be widened, blue/as greenly to have more electron-hole recombinations luminous at the interface, compound probability can be improved, the efficient of resulting devices is improved, and the stability of color can be better.
Simultaneously, after blu-ray layer added the material of transport property, exciton was not only at Bepp
2Last formation, also can on transferring material, form, because transferring material does not participate in luminous, and the triplet of transferring material is higher than ruddiness phosphorescent coloring and green glow phosphorescent coloring, so ruddiness phosphorescent coloring and green glow phosphorescent coloring around the exciton that forms on transferring material can be given energy delivery make energy delivery more effective.
In order to reach the balance of both hole and electron transmission, can add the material of different transport properties according to the position of the transport property of blue light material and blu-ray layer.
(5) embodiment 26-28
Embodiment 26-embodiment 28 is with Bepp
2As the material of main part of ruddiness layer, the green glow layer is near anode simultaneously; The ruddiness layer is near negative electrode; Blu-ray layer is positioned at the centre of three luminescent layers.The device architecture of embodiment 26-embodiment 28 all is a formula (12), and the thickness of blue light-emitting layer is followed successively by 2nm, 6nm, 10nm.
ITO/NPB/TCTA：Ir(ppy)
3/Bepp
2/Bepp
2：Ir(piq)
3/Bepp
2/LiF/Al (12)
Table 6
| The luminescent layer device architecture | Ruddiness layer x % | Green glow layer y% | Luminous efficiency (cd/A) | Chromaticity coordinates (x, y) | |
| Embodiment 26 | TCTA：Ir(ppy) 3(12nm)/Bepp 2(2nm)/Bepp 2： Ir(piq) 3(18nm) | 1 | 10 | 19.0 | (0.42，0.43) |
| Embodiment 27 | TCTA：Ir(ppy) 3(12nm)/Bepp 2(6nm)/Bepp 2： Ir(piq) 3(18nm) | 1 | 10 | 18.0 | (0.39，0.40) |
| Embodiment 28 | TCTA：Ir(ppy) 3(12nm)/Bepp 2(10nm)/Bepp 2： Ir(piq) 3(18nm) | 1 | 10 | 17.5 | (0.37，0.38) |
As can be seen from Table 6, Bepp
2Can do the material of main part of ruddiness layer equally, and the green glow layer can be positioned at also near anode one side.
(6) embodiment 29-32
Embodiment 29-32 is the white light parts of two luminescence centers.The device architecture of embodiment 29-31 all is a formula (13), and the device architecture of embodiment 32 is formula (14), the performance such as the table 7 of device.
ITO/NPB/Bepp
2/Bepp
2：Ir(bt)
2(acac)(35nm)/Bepp
2/LiF/Al (13)
ITO/NPB/Bepp
2/Bebq
2：Ir(bt)
2(acac)(35nm)/Bepp
2/LiF/Al (14)
Table 7
| The luminescent layer device architecture | Blu-ray layer thickness | Gold-tinted layer doping content y% | Luminous efficiency (cd/ A) | Chromaticity coordinates (x, y) | |
| Embodiment 29 | Bepp 2(4nm)/Bepp 2：Ir(bt) 2(acac)(35nm) | 4nm | ?0.7 | 23.0 | (0.36，0.37) |
| Embodiment 30 | Bepp 2(6nm)/Bepp 2：Ir(bt) 2(acac)(35nm) | 6nm | ?0.7 | 22.5 | (0.34，0.36) |
| Embodiment 31 | Bepp 2(10nm)/Bepp 2：Ir(bt) 2(acac)(35nm) | 10nm | ?0.7 | 22.0 | (0.34，0.35) |
| Embodiment 32 | Bepp 2(6nm)/Bebq 2：Ir(bt) 2(acac)(35nm) | 6nm | ?0.7 | 21.1 | (0.35，0.36) |
Though the present invention discloses as above with preferred embodiment; yet it is not in order to limit the present invention; anyly be familiar with this technology personage; without departing from the spirit and scope of the present invention; when being used for a variety of modifications and variations; therefore, protection scope of the present invention is as the criterion when the claim with application defines.
Claims (25)
1. an organic electroluminescence device comprises anode layer, cathode layer and the organic function layer between anode layer and cathode layer, and organic function layer comprises:
(1) blue light-emitting layer;
(2) first phosphorescent layer comprise the material of main part and first phosphorescent coloring;
(3) second phosphorescent layer comprise the material of main part and second phosphorescent coloring;
It is characterized in that the triplet of the luminescent material of blue light-emitting layer is higher than the triplet of first phosphorescent coloring and second phosphorescent coloring.
2. organic electroluminescence device according to claim 1 is characterized in that, the material of main part of described second phosphorescent layer is identical with the luminescent material of blue light-emitting layer.
3. organic electroluminescence device according to claim 1 and 2 is characterized in that, the luminescent material of described blue light-emitting layer is the complex of Be, Al, Ga, In, Zn.
4. organic electroluminescence device according to claim 1 and 2 is characterized in that, the luminescent material of described blue light-emitting layer is Bepp
2, AlmND
3, AlmmND
3, GamND
3, InmND
3, 4CzPBP.
5. organic electroluminescence device according to claim 1 and 2, it is characterized in that, described blue light-emitting layer also comprises the material of transport property, and the triplet of the material of described transport property is higher than the triplet of first phosphorescent coloring and second phosphorescent coloring.
6. organic electroluminescence device according to claim 5 is characterized in that, the material of described transport property is hole transport character, electric transmission character or double carriers transport property.
7. organic electroluminescence device according to claim 1 and 2 is characterized in that, described blue light-emitting layer is between first phosphorescent layer and second phosphorescent layer.
8. organic electroluminescence device according to claim 7 is characterized in that, the thickness of described blue light-emitting layer is 2～20nm.
9. organic electroluminescence device according to claim 1 and 2 is characterized in that described organic function layer also comprises electron transfer layer, and the material of electron transfer layer is identical with the material of blue light-emitting layer.
10. organic electroluminescence device according to claim 1 and 2 is characterized in that, described first phosphorescent coloring is selected from Ir (piq)
3, Ir (piq)
2(acac), Btp
2Ir (acac), Ir (MDQ)
2(acac), Ir (DBQ)
2(acac), Ir (fbi)
2(acac), Ir (2-phq)
3, Ir (2-phq)
2(acac), Ir (bt)
2(acac) or PtOEP.
11. organic electroluminescence device according to claim 1 and 2 is characterized in that, described second phosphorescent coloring is selected from Ir (ppy)
3, Ir (ppy)
2(acac) or Ir (mppy)
3
12. organic electroluminescence device according to claim 1 and 2 is characterized in that, the material of main part of described first phosphorescent layer is selected from NPB, TCTA, TPD, TAPC, Bepp
2, Bebq
2, BAlq, MCP or CBP.
13. organic electroluminescence device according to claim 1 and 2 is characterized in that, the material of main part of described second phosphorescent layer is selected from Bepp
2, TCTA, TAZ, TPBI or CBP.
14. organic electroluminescence device according to claim 1 and 2 is characterized in that, described organic electroluminescence device produces white light.
15. an organic electroluminescence device comprises anode layer, cathode layer and the organic function layer between anode layer and cathode layer, and organic function layer comprises:
(1) blue light-emitting layer;
(2) phosphorescent layer comprises material of main part and phosphorescent coloring;
It is characterized in that the triplet of the luminescent material of blue light-emitting layer is higher than the triplet of phosphorescent coloring.
16. organic electroluminescence device according to claim 15 is characterized in that, the material of main part of described phosphorescent layer is identical with the luminescent material of blue light-emitting layer.
17., it is characterized in that the luminescent material of described blue light-emitting layer is the complex of Be, Al, Ga, In, Zn according to claim 15 or 16 described organic electroluminescence devices.
18., it is characterized in that the luminescent material of described blue light-emitting layer is Bepp according to claim 15 or 16 described organic electroluminescence devices
2, AlmND
3, AlmmND
3, GamND
3, InmND
3, 4CzPBP.
19. according to claim 15 or 16 described organic electroluminescence devices, it is characterized in that described blue light-emitting layer also comprises the material of transport property, the triplet of the material of described transport property is higher than the triplet of phosphorescent coloring.
20. organic electroluminescence device according to claim 19 is characterized in that, the material of described transport property is hole transport character, electric transmission character or double carriers transport property.
21., it is characterized in that the thickness of described blue light-emitting layer is 2nm～20nm according to claim 15 or 16 described organic electroluminescence devices.
22. according to claim 15 or 16 described organic electroluminescence devices, it is characterized in that described organic function layer also comprises electron transfer layer, the material of electron transfer layer is identical with the material of blue light-emitting layer.
23., it is characterized in that the phosphorescent coloring of described phosphorescent layer is selected from Ir (MDQ) according to claim 15 or 16 described organic electroluminescence devices
2(acac), Ir (DBQ)
2(acac), Ir (fbi)
2(acac), Ir (2-phq)
3, Ir (2-phq)
2(acac) or Ir (bt)
2(acac).
24., it is characterized in that the material of main part of described phosphorescence luminescent layer is selected from NPB, TCTA, Bepp according to claim 15 or 16 described organic electroluminescence devices
2, Bebq
2, BAlq, MCP or CBP.
25., it is characterized in that described organic electroluminescence device produces white light according to claim 15 or 16 described organic electroluminescence devices.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910234759 CN102064282B (en) | 2009-11-13 | 2009-11-13 | Organic electroluminescent device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910234759 CN102064282B (en) | 2009-11-13 | 2009-11-13 | Organic electroluminescent device |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102064282A true CN102064282A (en) | 2011-05-18 |
| CN102064282B CN102064282B (en) | 2013-06-12 |
Family
ID=43999479
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200910234759 Active CN102064282B (en) | 2009-11-13 | 2009-11-13 | Organic electroluminescent device |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102064282B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102738400A (en) * | 2011-03-31 | 2012-10-17 | 海洋王照明科技股份有限公司 | White-light electroluminescent device |
| CN103887435A (en) * | 2012-12-21 | 2014-06-25 | 厦门天马微电子有限公司 | Organic light emitting diode |
| CN104241539A (en) * | 2013-06-05 | 2014-12-24 | 剑桥显示技术有限公司 | Organic light-emitting device |
| CN107611275A (en) * | 2017-09-19 | 2018-01-19 | 上海天马有机发光显示技术有限公司 | A kind of white luminous device, its display device and preparation method thereof |
| CN108288678A (en) * | 2018-03-29 | 2018-07-17 | 佛山科学技术学院 | A kind of double blu-ray layer hydridization white light organic electroluminescent devices |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100459216C (en) * | 2007-03-21 | 2009-02-04 | 吉林大学 | Organic electroluminescent white light device with multi-luminescent layer |
-
2009
- 2009-11-13 CN CN 200910234759 patent/CN102064282B/en active Active
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102738400A (en) * | 2011-03-31 | 2012-10-17 | 海洋王照明科技股份有限公司 | White-light electroluminescent device |
| CN102738400B (en) * | 2011-03-31 | 2015-11-25 | 海洋王照明科技股份有限公司 | A kind of white-light electroluminescence device |
| CN103887435A (en) * | 2012-12-21 | 2014-06-25 | 厦门天马微电子有限公司 | Organic light emitting diode |
| CN104241539A (en) * | 2013-06-05 | 2014-12-24 | 剑桥显示技术有限公司 | Organic light-emitting device |
| CN107611275A (en) * | 2017-09-19 | 2018-01-19 | 上海天马有机发光显示技术有限公司 | A kind of white luminous device, its display device and preparation method thereof |
| CN107611275B (en) * | 2017-09-19 | 2019-06-25 | 上海天马有机发光显示技术有限公司 | A kind of white luminous device, display device and preparation method thereof |
| CN108288678A (en) * | 2018-03-29 | 2018-07-17 | 佛山科学技术学院 | A kind of double blu-ray layer hydridization white light organic electroluminescent devices |
| CN108288678B (en) * | 2018-03-29 | 2023-12-01 | 佛山科学技术学院 | Double blue light layer hybridization white light organic electroluminescent device |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102064282B (en) | 2013-06-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101630721B (en) | Organic electroluminescent component | |
| CN100484353C (en) | Organic electroluminescent part | |
| CN102136550B (en) | White light organic electroluminescent device and preparation method thereof | |
| CN101217187B (en) | Preparation method if organic electroluminescence device with super-thin layer structure | |
| CN106898700A (en) | A kind of phosphorescent organic electroluminescent device | |
| CN106784358A (en) | A kind of white light organic electroluminescent device | |
| CN101694849B (en) | Organic electroluminescence lamination device | |
| CN102779948B (en) | White color organic electroluminescence device and manufacture method thereof | |
| CN110190200B (en) | Efficient pure white light organic electroluminescent device with high color rendering index and preparation method thereof | |
| CN102097598B (en) | Organic light-emitting device and production method thereof | |
| CN101635334A (en) | Red organic electroluminescence device and preparation method thereof | |
| CN102185112A (en) | Laminated organic light-emitting diode and preparation method thereof | |
| CN105591035A (en) | Hybrid white light organic electroluminescence device | |
| CN102064282B (en) | Organic electroluminescent device | |
| CN104347808B (en) | A kind of color stability white light organic electroluminescent device high | |
| CN101079471B (en) | An organic EL part | |
| CN102569660A (en) | Organic electroluminescent device with laminated structure | |
| CN103490017A (en) | Hybrid white light organic lighting emitting device | |
| CN102208552A (en) | White-light organic electroluminescent device and preparation method thereof | |
| CN102931357B (en) | Two emission layer hemispherical shell organic electroluminescence device and preparation method thereof | |
| CN106328818A (en) | Fluorescent/phosphorescent hybrid white organic light-emitting diode | |
| CN108807710A (en) | Undoped organic electroluminescence device and the preparation method of connecting with the complementary white light of doping | |
| CN105374949A (en) | Organic light-emitting device and preparation method thereof | |
| CN102842682A (en) | Stacked organic electroluminescence device and manufacturing method thereof | |
| CN101394696A (en) | Organic EL device |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20160202 Address after: 065500 Guan County, Hebei Province emerging industry demonstration park Patentee after: GU'AN YEOLIGHT TECHNOLOGY CO., LTD. Patentee after: Tsinghua University Address before: 215300 Kunshan high tech Zone, Jiangsu Province, Feng Feng Road, No. 188, No. Patentee before: Weixinnuo Display Tech Co., Ltd. Patentee before: Tsinghua University Patentee before: Weixinnuo Science and Technology Co., Ltd., Beijing |