CN102054882A - Conductive silver paste with grid electrode front of crystalline silicon solar cell and preparation method - Google Patents
Conductive silver paste with grid electrode front of crystalline silicon solar cell and preparation method Download PDFInfo
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- CN102054882A CN102054882A CN2009101979189A CN200910197918A CN102054882A CN 102054882 A CN102054882 A CN 102054882A CN 2009101979189 A CN2009101979189 A CN 2009101979189A CN 200910197918 A CN200910197918 A CN 200910197918A CN 102054882 A CN102054882 A CN 102054882A
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- China
- Prior art keywords
- silver paste
- conductive silver
- silicon solar
- crystal silicon
- solar energy
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title claims abstract description 89
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 229910021419 crystalline silicon Inorganic materials 0.000 title abstract 5
- 229910052709 silver Inorganic materials 0.000 claims abstract description 27
- 239000004332 silver Substances 0.000 claims abstract description 27
- 239000011521 glass Substances 0.000 claims abstract description 26
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 26
- 239000010703 silicon Substances 0.000 claims abstract description 26
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000002904 solvent Substances 0.000 claims abstract description 22
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 16
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 16
- 239000000843 powder Substances 0.000 claims abstract description 12
- 238000005245 sintering Methods 0.000 claims abstract description 10
- 239000011347 resin Substances 0.000 claims description 29
- 229920005989 resin Polymers 0.000 claims description 29
- 239000002002 slurry Substances 0.000 claims description 27
- 239000013078 crystal Substances 0.000 claims description 23
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 claims description 16
- 239000000428 dust Substances 0.000 claims description 15
- 150000002902 organometallic compounds Chemical class 0.000 claims description 15
- 229920002521 macromolecule Polymers 0.000 claims description 14
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 12
- 239000002994 raw material Substances 0.000 claims description 12
- 238000005303 weighing Methods 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000001856 Ethyl cellulose Substances 0.000 claims description 10
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims description 10
- 150000002148 esters Chemical class 0.000 claims description 10
- 229920001249 ethyl cellulose Polymers 0.000 claims description 10
- 235000019325 ethyl cellulose Nutrition 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 229940120693 copper naphthenate Drugs 0.000 claims description 6
- SEVNKWFHTNVOLD-UHFFFAOYSA-L copper;3-(4-ethylcyclohexyl)propanoate;3-(3-ethylcyclopentyl)propanoate Chemical compound [Cu+2].CCC1CCC(CCC([O-])=O)C1.CCC1CCC(CCC([O-])=O)CC1 SEVNKWFHTNVOLD-UHFFFAOYSA-L 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- 239000012535 impurity Substances 0.000 claims description 6
- 239000011787 zinc oxide Substances 0.000 claims description 6
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 claims description 4
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000007983 Tris buffer Substances 0.000 claims description 4
- 239000004744 fabric Substances 0.000 claims description 4
- 229910052738 indium Inorganic materials 0.000 claims description 4
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 4
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 4
- 229910001887 tin oxide Inorganic materials 0.000 claims description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 4
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 claims description 4
- 229910052733 gallium Inorganic materials 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract 3
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000002952 polymeric resin Substances 0.000 abstract 1
- 238000010301 surface-oxidation reaction Methods 0.000 abstract 1
- 229920003002 synthetic resin Polymers 0.000 abstract 1
- 239000004065 semiconductor Substances 0.000 description 9
- 238000005516 engineering process Methods 0.000 description 3
- 230000010307 cell transformation Effects 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 230000001172 regenerating effect Effects 0.000 description 2
- 241000287828 Gallus gallus Species 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000011267 electrode slurry Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 229910001195 gallium oxide Inorganic materials 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 229920005591 polysilicon Polymers 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Images
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Conductive Materials (AREA)
- Photovoltaic Devices (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2009101979189A CN102054882B (en) | 2009-10-29 | 2009-10-29 | Conductive silver paste with grid electrode front of crystalline silicon solar cell and preparation method |
Applications Claiming Priority (1)
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---|---|---|---|
CN2009101979189A CN102054882B (en) | 2009-10-29 | 2009-10-29 | Conductive silver paste with grid electrode front of crystalline silicon solar cell and preparation method |
Publications (2)
Publication Number | Publication Date |
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CN102054882A true CN102054882A (en) | 2011-05-11 |
CN102054882B CN102054882B (en) | 2012-07-18 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN2009101979189A Expired - Fee Related CN102054882B (en) | 2009-10-29 | 2009-10-29 | Conductive silver paste with grid electrode front of crystalline silicon solar cell and preparation method |
Country Status (1)
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CN (1) | CN102054882B (en) |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102262916A (en) * | 2011-07-19 | 2011-11-30 | 彩虹集团公司 | Front silver paste for crystalline silicon solar cell and preparation method |
CN102568648A (en) * | 2011-12-29 | 2012-07-11 | 广东爱康太阳能科技有限公司 | Conductive silver paste and preparation method thereof |
CN102629496A (en) * | 2012-04-27 | 2012-08-08 | 西安银泰新能源材料科技有限公司 | Crystalline silicon solar battery front side electrode lead-free conductive lead slurry and preparation method of crystalline silicon solar battery front side electrode lead-free conductive lead slurry |
CN103093861A (en) * | 2013-02-17 | 2013-05-08 | 上海大洲电子材料有限公司 | Low-cost unleaded environmental protection silver paste for back electrode of silicon solar cell and application thereof |
CN103440898A (en) * | 2013-08-06 | 2013-12-11 | 浙江光达电子科技有限公司 | Solar cell front face electrode silver paste with low silver content and method for preparing same |
CN103578604A (en) * | 2013-09-22 | 2014-02-12 | 杭州正银电子材料有限公司 | Front-face electrode slurry with low silver content for silica-based solar cell main grid and preparation method of front-face electrode slurry |
CN103915248A (en) * | 2014-03-27 | 2014-07-09 | 深圳振华富电子有限公司 | Manufacturing method of base metal terminal electrode inductor |
CN104185875A (en) * | 2012-03-28 | 2014-12-03 | 东丽株式会社 | Photosensitive conductive paste and method for manufacturing conductive substrate with wiring |
CN105590663A (en) * | 2016-01-07 | 2016-05-18 | 清华大学 | Lead-free and bismuth-free conductive silver paste, preparation method of silver grid line, and silicon solar cell |
CN105761775A (en) * | 2014-12-18 | 2016-07-13 | 上海宝银电子材料有限公司 | Conductive silver paste for on-chip inductor external electrode and preparation method of conductive silver paste |
CN106573301A (en) * | 2014-07-31 | 2017-04-19 | 同和电子科技有限公司 | Silver powder, method for producing same, and conductive paste |
CN107274962A (en) * | 2017-05-18 | 2017-10-20 | 江苏东昇光伏科技有限公司 | A kind of slurry used for solar batteries and preparation method thereof |
US9993871B2 (en) | 2014-07-31 | 2018-06-12 | Dowa Electronics Materials Co., Ltd. | Silver powder, method for producing same, and conductive paste |
CN109192396A (en) * | 2018-09-28 | 2019-01-11 | 王敏 | A kind of preparation method of anti-oxidative conductive silver paste thick-film material |
CN113471314A (en) * | 2021-05-07 | 2021-10-01 | 盐城工学院 | Method for preparing selective emitter by using gallium-doped silicon nano slurry |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100385573C (en) * | 2003-04-21 | 2008-04-30 | 上海宝银电子材料有限公司 | Dedicated silve paste of stannum indium oxide and manufacturing method |
CN101436442A (en) * | 2008-12-09 | 2009-05-20 | 彩虹集团公司 | Low-temperature conductive slurry |
-
2009
- 2009-10-29 CN CN2009101979189A patent/CN102054882B/en not_active Expired - Fee Related
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102262916A (en) * | 2011-07-19 | 2011-11-30 | 彩虹集团公司 | Front silver paste for crystalline silicon solar cell and preparation method |
CN102568648A (en) * | 2011-12-29 | 2012-07-11 | 广东爱康太阳能科技有限公司 | Conductive silver paste and preparation method thereof |
CN104185875A (en) * | 2012-03-28 | 2014-12-03 | 东丽株式会社 | Photosensitive conductive paste and method for manufacturing conductive substrate with wiring |
CN102629496A (en) * | 2012-04-27 | 2012-08-08 | 西安银泰新能源材料科技有限公司 | Crystalline silicon solar battery front side electrode lead-free conductive lead slurry and preparation method of crystalline silicon solar battery front side electrode lead-free conductive lead slurry |
CN102629496B (en) * | 2012-04-27 | 2015-02-18 | 西安银泰新能源材料科技有限公司 | Crystalline silicon solar battery front side electrode lead-free conductive lead slurry and preparation method of crystalline silicon solar battery front side electrode lead-free conductive lead slurry |
CN103093861A (en) * | 2013-02-17 | 2013-05-08 | 上海大洲电子材料有限公司 | Low-cost unleaded environmental protection silver paste for back electrode of silicon solar cell and application thereof |
CN103440898A (en) * | 2013-08-06 | 2013-12-11 | 浙江光达电子科技有限公司 | Solar cell front face electrode silver paste with low silver content and method for preparing same |
CN103440898B (en) * | 2013-08-06 | 2017-06-06 | 浙江光达电子科技有限公司 | A kind of front electrode of solar battery silver paste of low silver content and preparation method thereof |
CN103578604A (en) * | 2013-09-22 | 2014-02-12 | 杭州正银电子材料有限公司 | Front-face electrode slurry with low silver content for silica-based solar cell main grid and preparation method of front-face electrode slurry |
CN103915248A (en) * | 2014-03-27 | 2014-07-09 | 深圳振华富电子有限公司 | Manufacturing method of base metal terminal electrode inductor |
CN103915248B (en) * | 2014-03-27 | 2016-09-28 | 深圳振华富电子有限公司 | The preparation method of base metal termination electrode inducer |
CN106573301B (en) * | 2014-07-31 | 2019-08-09 | 同和电子科技有限公司 | Silver powder and its conductive paste |
CN106573301A (en) * | 2014-07-31 | 2017-04-19 | 同和电子科技有限公司 | Silver powder, method for producing same, and conductive paste |
US9993871B2 (en) | 2014-07-31 | 2018-06-12 | Dowa Electronics Materials Co., Ltd. | Silver powder, method for producing same, and conductive paste |
US10252331B2 (en) | 2014-07-31 | 2019-04-09 | Dowa Electronics Materials Co., Ltd. | Silver powder, method for producing same, and conductive paste |
CN105761775A (en) * | 2014-12-18 | 2016-07-13 | 上海宝银电子材料有限公司 | Conductive silver paste for on-chip inductor external electrode and preparation method of conductive silver paste |
CN105761775B (en) * | 2014-12-18 | 2017-07-21 | 上海宝银电子材料有限公司 | A kind of chip inductor external electrode conductive silver paste and preparation method thereof |
CN105590663A (en) * | 2016-01-07 | 2016-05-18 | 清华大学 | Lead-free and bismuth-free conductive silver paste, preparation method of silver grid line, and silicon solar cell |
CN107274962A (en) * | 2017-05-18 | 2017-10-20 | 江苏东昇光伏科技有限公司 | A kind of slurry used for solar batteries and preparation method thereof |
CN109192396A (en) * | 2018-09-28 | 2019-01-11 | 王敏 | A kind of preparation method of anti-oxidative conductive silver paste thick-film material |
CN113471314A (en) * | 2021-05-07 | 2021-10-01 | 盐城工学院 | Method for preparing selective emitter by using gallium-doped silicon nano slurry |
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Publication number | Publication date |
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CN102054882B (en) | 2012-07-18 |
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Owner name: BAOYIN ELECTRONIC MATERIAL CO., LTD., SHANGHAI Effective date: 20140718 Owner name: SHANGHAI NUCLEAR INDUSTRY NO.8 INST. Free format text: FORMER OWNER: BAOYIN ELECTRONIC MATERIAL CO., LTD., SHANGHAI Effective date: 20140718 |
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Effective date of registration: 20140718 Address after: 201800, 1719 Jia Luo Road, Shanghai, Jiading District Patentee after: Shanghai Nuclear Industry N.4 Inst. Patentee after: Shanghai Baoyin Electronic Materials Ltd. Address before: 201800 Shanghai city Jiading District Road No. 1719 Patentee before: Shanghai Baoyin Electronic Materials Ltd. |
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CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120718 |
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CF01 | Termination of patent right due to non-payment of annual fee |