CN102046144A - Cosmetic preparation - Google Patents
Cosmetic preparation Download PDFInfo
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- CN102046144A CN102046144A CN2009801211670A CN200980121167A CN102046144A CN 102046144 A CN102046144 A CN 102046144A CN 2009801211670 A CN2009801211670 A CN 2009801211670A CN 200980121167 A CN200980121167 A CN 200980121167A CN 102046144 A CN102046144 A CN 102046144A
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- hydrogen atom
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- general formula
- surfactant
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
Abstract
Disclosed is a cosmetic preparation characterized by containing (A) an amphoteric surfactant or an anionic surfactant, and (B) an acrylic polymer which contains, as constitutional units, 70-95% by mole of a monomer unit represented by general formula (1) and 5-30% by mole of a monomer unit represented by general formula (2). The cosmetic preparation is also characterized in that the mass ratio (A)/(B) is within the range of 0.1-50.0. In the formulae, R1 represents a hydrogen atom or a methyl group; R2 represents a hydrogen atom or a -CH2OH group; A represents an oxygen atom or an -NH- group; R3 represents a hydrogen atom or a methyl group; and M represents a hydrogen atom, an alkali metal atom, an ammonium or an amine.
Description
Technical field
The present invention relates to the cosmetic material of alveolar substance excellence.
Background technology
In the cosmetic material, cosmetic material for wash types such as shampoo, cleansing milk, bath gel, wish to spread upon when bubbling on hair, the skin, the alveolar substance exquisiteness, have conformality, be difficult for the abundant alveolar substance of froth breaking, on the other hand, for the so non-wash type of the hair foam material of making up, rapid froth breaking etc. can be applicable to the good alveolar substance of each product type when requiring when container is extruded alveolar substance exquisiteness, have conformality and soaking into hair etc.
And then during the hair class was made up and expected, the hair meeting of handling of having hair dyed be faded owing to having one's hair wash, and therefore, expected can suppress to fade to make the color development after having hair dyed continue thereby require the hair class to make up.At this situation, the someone has proposed to use the hair class of the special surfactant material (with reference to patent documentation 1: Japanese patent laid-open 7-233033 communique, patent documentation 2: the spy opens the 2002-275038 communique) of making up.But also existing fades prevents degradation problem under the insufficient or alveolar substance of effect.In view of the above problems, people wait in expectation to fade and prevent effect excellence, the good hair class cosmetic material of alveolar substance.
In addition, in the skin cosmetic, thereby the skin after the cleaning is because cuticular composition stripping waits under the exsiccant environment in the winter time, and elbow, wrist, shin etc. become not only white but also withered state (albefaction) sometimes.Given this, people expect a kind of like this skin cosmetic always, and it can prevent the skin albefaction at these positions but also have good alveolar substance.
Patent documentation 1: Japanese patent laid-open 7-233033 communique
Patent documentation 2: the Japan Patent spy opens the 2002-275038 communique
Patent documentation 3: the Japan Patent spy opens the 2007-161986 communique
Patent documentation 4: Japanese patent laid-open 7-315463 communique
Summary of the invention
The present invention In view of the foregoing finishes, and purpose is to provide a kind of cosmetic material of alveolar substance excellence.And then specific to hair class cosmetic material, its purpose is to provide a kind of hair class cosmetic material that prevents Achromotrichia effect excellence, specific to skin cosmetic, then provides the skin cosmetic that a kind of skin albefaction prevents the effect excellence.
The present inventor to achieve these goals, research with keen determination, found that: by and with (A) amphoteric surfactant or anionic surfactant and specific (B) acrylic acid series polymeric compounds, and to make the mass ratio shown in (A)/(B) be 0.1～50.0, can improve alveolar substance, and then, specific to hair class cosmetic material, fading of hair prevents the effect excellence, specific to skin cosmetic, the albefaction that then is skin prevents the effect excellence, has finished the present invention in view of the above.
Therefore, the present invention is as follows:
[1]. a kind of cosmetic material, it is characterized in that, contain (A) amphoteric surfactant or anionic surfactant, and (B) contain the acrylic acid series polymeric compounds of 5～30 moles of % of monomeric unit shown in 70～95 moles of % of the monomeric unit shown in the following general formula (1) and the following general formula (2) as construction unit, (A)/(B) mass ratio shown in is 0.1～50.0
[changing 1]
(in the formula, R
1Expression hydrogen atom or methyl, R
2The expression hydrogen atom or-CH
2OH base, A represent oxygen atom or-NH-.)
[changing 2]
(in the formula, R
3Expression hydrogen atom or methyl, M represents hydrogen atom, alkali metal atom, ammonium or amine.)
[2]. as the change make-up material of above-mentioned [1] record, (A) composition is the surfactant that is selected from carboxybetaine type amphoteric surfactant, sulfuric acid ester type anionic surfactant and N-acyl amino acid type anionic surfactant.
The invention effect
According to the present invention, the make up albefaction of material and skin of the hair class that can provide fading of alveolar substance that can improve the material of making up and then hair to prevent the effect excellence prevents the skin cosmetic of effect excellence.
The specific embodiment
Cosmetic material of the present invention contains (A) amphoteric surfactant or anionic surfactant, and (B) contain the acrylic acid series polymeric compounds of 5～30 moles of % of monomeric unit shown in 70～95 moles of % of the monomeric unit shown in the following general formula (1) and the following general formula (2) as construction unit, (A)/(B) mass ratio shown in is 0.1～50.0.
(A) amphoteric surfactant or anionic surfactant
Amphoteric surfactant can exemplify; the carboxybetaine type amphoteric surfactant of coco-nut oil fatty acid amido propyl betaine, lauric amide CAB, lauryl dimethyl aminoacetic acid betanin etc.; the sulfobetaines type of lauryl hydroxyl sulfo betaine etc.; the aminocarboxylic acid type of lauryl alanine etc.; the imidazolinium betaine type of 2-alkyl-N-carboxyl methyl-N-hydroxyethyl imidazole quinoline betanin, N-coco-nut oil fatty acid acyl group-N-carboxy ethyl-N-hydroxyethyl-ethylenediamine salt etc., lecithin etc.They can a kind of use or suitable combination use more than 2 kinds separately.
The anionic surfactant can exemplify; alkyl (preferred carbon number 10～16) sulfate; the sulfuric acid ester type anionic surfactant of polyxyethylated (preferred carbon number 10～16) ether sulfate etc.; alpha-alkene sulfonate; N-acyl group-N methyl taurine salt; the sulfonic acid type of sulfosuccinic dialkylaminobenzoic acid salt etc.; N-acyl group-sarcosine salt; N-acyl group-N-methyl-Beta-alanine salt (N-lauroyl-N-methyl-beta Alanine salt etc.); the N-acyl group of N-acyl glutamate (N-coco-nut oil fatty acid acyl group-L-glutamate, Glu etc.) etc. (preferred carbon number 10～18) amino acid pattern anionic surfactant, alkylphosphonic; the phosphate type of polyoxyethylene alkyl ether phosphate etc. etc.
Be used for these surfactants salt can exemplify the alkali metal salt of sodium salt, potassium salt etc., the amine salt of ammonium salt, triethanolamine salt, aminomethyl propanol salt etc. to ion.
(A) composition preferably is selected from carboxybetaine type amphoteric surfactant, sulfuric acid ester type anionic surfactant and N-acyl amino acid type anionic surfactant's surfactant.
(A) use level of composition is not particularly limited, in the material of making up, be generally more than the 0.01 quality %, 0.1～50 quality % better, 0.2～25 quality % is better.During use level less than 0.01 quality %, may can not get the purpose effect.Wash type hair class is made up and is expected that 5～20 quality % are better, and non-wash type hair class is made up and expected that 0.2～1 quality % is better, skin cosmetic, and 0.2～10 quality % is better.
(B) acrylic acid series polymeric compounds
Be to contain the acrylic acid series polymeric compounds of 5～30 moles of % of monomeric unit shown in 70～95 moles of % of the monomeric unit shown in the general formula (1) and the general formula (2), can use a kind or suitable combination use more than 2 kinds separately as the copolymer formation of construction unit.
[changing 3]
(in the formula, R
1Expression hydrogen atom or methyl, R
2The expression hydrogen atom or-CH
2OH base, A represent oxygen atom or-NH-.)
[changing 4]
(in the formula, R
3Expression hydrogen atom or methyl, M represents hydrogen atom, alkali metal atom, ammonium or amine.)
Alkali metal atom can exemplify sodium atom, potassium atom, and amine can exemplify monoethanolamine, diethanolamine, triethanolamine etc., and when M was alkali metal atom, ammonium or amine ,-COOM formed salt.
The monomer suitable with the monomeric unit shown in the general formula (1) can exemplified by acrylic-2-hydroxyethyl ester, methacrylic acid-2-hydroxyethyl ester, 2-ethoxy acrylamide, 2-hydroxyethyl methacrylamide, acrylic acid-2,3-dihydroxypropyl ester, methacrylic acid-2,3-dihydroxypropyl ester etc.The monomer suitable with the monomeric unit shown in the general formula (2) can exemplified by acrylic, methacrylic acid and their salt.
The ratio of the monomeric unit shown in the general formula (1) in acrylic acid series polymeric compounds (among complete 100 moles of % of monomeric unit) is that 70～95 moles of %, 75～85 moles of % are better, and the ratio of the monomeric unit shown in the general formula (2) in acrylic acid series polymeric compounds (among complete 100 moles of % of monomeric unit) is that 5～30 moles of %, 10～20 moles of % are better.The ratio of the monomeric unit shown in 70 moles of % of the ratio deficiency of the monomeric unit shown in the general formula (1), the general formula (2) surpasses 30 moles of %, can not obtain the purpose effect; The ratio of the monomeric unit shown in the general formula (1) surpasses 5 moles of % of ratio less than of the monomeric unit shown in 95 moles of %, the general formula (2), can not obtain alveolar substance and improve effect.
In addition, only otherwise damage effect of the present invention, can also contain other monomeric units beyond the monomeric unit shown in above-mentioned general formula (1) or (2) in the acrylic acid series polymeric compounds of the present invention.Other monomeric unit can exemplify non-ionic monomer, ampholytic monomer, semi-polarity monomer, cationic monomer, with the suitable monomeric unit of monomer that contains polysiloxane group.But these monomers do not comprise and the suitable monomer of monomeric unit shown in above-mentioned (1) or (2).The ratio of the monomeric unit beyond the monomeric unit shown in general formula (1) or (2), it is better to account for 0～15 mole of % in acrylic acid series polymeric compounds.Acrylic acid series polymeric compounds of the present invention both can be that random copolymer also can be a block copolymer, the acrylic acid series polymeric compounds that acrylic acid series polymeric compounds of the present invention preferably is made of the copolymer that with the monomeric unit shown in general formula (1) and (2) is construction unit.
Non-ionic monomer can exemplify the alcohol and (methyl) acrylic acid ester of carbon number 1～22, the alkylamine of carbon number 1～22 and (methyl) acrylic acid amide, ethylene glycol, 1, ammediol etc. and (methyl) acrylic acid monoesters, and then, the hydroxyl of this monoesters is by the ester of etherificates such as methanol or ethanol, (methyl) acryloyl morpholine etc.; Ampholytic monomer can exemplify (methyl) acrylic ester that contains the Radix Betae base, (methyl) acrylamide that contains the Radix Betae base etc.; The semi-polarity monomer can exemplify (methyl) acrylic ester that contains the oxidation amido, (methyl) acrylamide that contains the oxidation amido etc.; Cationic monomer can exemplify, contain quaternary ammonium salt base (methyl) acrylic ester, contain (methyl) acrylamide of quaternary ammonium salt base etc.
The monomer that contains polysiloxane group has polysiloxane structure, is the chemical compound with the structure that can be connected with acrylic acid series polymeric compounds by covalent bond.Such construction unit in cosmetic combination with usually and the affinity height of the silicone oil of usefulness, performance be connected in the acrylic acid series polymeric compounds other the construction unit and the effect of silicone oil, for skin, hair, especially damaged hair etc., can bring into play the effect of the absorption affinity that improves silicone oil.
The ratio of each monomeric unit in the acrylic acid series polymeric compounds, the IR that can pass through carbonyl, amido link, polysiloxane structure and various functional groups etc. absorbs, the methyl of polydimethylsiloxane, amide linkage position and the methyl adjacent with them, methylene etc.
1H-NMR or
13Mensuration such as C-NMR.
The weight average molecular weight of acrylic acid series polymeric compounds is generally 3,000～100, and 000.Less than 3,000 has alveolar substance to improve the worry that effect dies down, and surpasses 100,000, has the worry that produces stiff harsh feeling on hair and the skin.From the viewpoint of the sense of touch that improves dried hair and skin better, weight average molecular weight be 10,000～30,000 better, 10,000～20,000 better, 12,000～17,000 is better.
The weight average molecular weight of acrylic acid series polymeric compounds can be measured by gel filtration chromatography, particularly, adopt device: East ソ one Co., Ltd.'s system, SC8010, SD8022, RI8020, CO8011, PS8010, chromatographic column: the Wakopak of Wako Pure Chemical Industries, Ltd. (Wakobeads G-50), launch solvent: water/methanol/acetic acid/sodium acetate=6/4/0.3/0.41 is that standard substance is obtained weight average molecular weight with the Polyethylene Glycol.
The adjustment of the molecular weight of acrylic acid series polymeric compounds can be undertaken by the degree of polymerization of for example controlling polymers.In addition, also can control molecular weight and viscosity by the addition of cross-linking agent such as increase and decrease polyfunctional acrylic ester.But even the excessive interpolation of cross-linking agent little by little, molecular weight and viscosity also can sharply increase etc., are difficult to control on commercial production.Therefore, preferably do not contain cross-linking agent.
Acrylic acid series polymeric compounds of the present invention can be opened the method for putting down in writing in the 2007-161986 communique according to the Japan Patent spy and obtain.For example, can make like this: mix monomer or its presoma that various construction units are provided, after method copolymerization such as polymerisation in solution, outstanding turbid polymerization, emulsion polymerization, carry out the addition, condensation reaction of polysiloxane structure etc. as required.In addition, anionic property shown in the general formula (2) monomeric to ion can be before polymerization by neutralization reaction with it part or all instead of the ion beyond the hydrion, offer polymerization again, also can part or all replaces with hydrion ion in addition with it by neutralization reaction after polymerization or other reaction.These all can be undertaken by suitable selection of synthetic difficulty.Mix each monomer, make it be specific molar ratio with respect to whole monomeric total amounts (100 moles of %).In the copolymer of the present invention, the ratio of the construction unit that constitutes by each monomer during with copolymerization each monomeric use level identical.
Polyreaction is preferably carried out in hydrophilic solvent.Hydrophilic solvent can exemplify ketone series solvents such as acetone, methyl ethyl ketone, methyl iso-butyl ketone (MIBK), pure series solvents such as methanol, ethanol, normal propyl alcohol, isopropyl alcohol, n-butyl alcohol, isobutanol, sec-butyl alcohol, water etc.These can use separately, and also two or more kinds may be used.The pure series solvent of wherein preferred use.
Polymerization initiator can use 2,2 '-azodiisobutyronitrile, 2,2 '-azo two (2, the 4-methyl pentane nitrile), 2,2 '-azo two (4-methoxyl group-2, the 4-methyl pentane nitrile), dimethyl-2,2 '-azo-bis-isobutyrate, 2,2 '-azo two (2-methylbutyronitrile), 1,1 '-azo two (1-hexamethylene formonitrile HCN), 2,2 '-azo two (2-methyl-N-(2-ethoxy)-propionic acid amide .), 2,2 '-azo diisobutyl amidine dihydrochloride, 2,2 '-azo two azo-compounds such as (2 Methylpropionic acid methyl ester), benzoyl peroxide, dicumyl peroxide, di-tert-butyl peroxide, peroxide such as lauroyl peroxide, persulfate or its redox system etc. can use without restriction.Polymerization initiator preferably uses in the scope of 0.01～5 quality % with respect to whole monomers.
Polyreaction can be for example, under atmosphere of inert gases such as nitrogen or argon, and preferred 30～120 ℃, more preferably under 40～100 ℃, carried out usually 1～30 hour.After polymerization finishes, can distill, add suitable means such as poor solvent by solvent the copolymer of generation is separated from reactant liquor.This copolymer can be directly or further refining after be used for for example the making up manufacturing of material.Refining can make up redeposition, solvent clean, membrance separation etc. as required suitable means are carried out.
(B) use level of composition is not particularly limited, be generally in the material of making up that 0.01 quality % is above, 0.1～10 quality % better, 0.2～5 quality % is better.During use level less than 0.01 quality %, may can not get the purpose effect.
Among the present invention, in order to obtain the purpose effect, (A)/(B) (A) composition shown in is necessary in 0.1～50.0 scope preferred 0.1～35.0 with (B) mass ratio of composition.(A)/(B) during less than 0.1, can not obtain ideal alveolar substance, surpass at 50.0 o'clock, it is insufficient that alveolar substance is improved effect, simultaneously, can not obtain the albefaction that fading of hair prevent effect or skin and suppress effect.The wash type hair class material of making up is preferred 1.0～35.0, and the non-wash type hair class material of making up is preferred 0.1～1.0, skin cosmetic preferred 5.0～35.0.
Except that mentioned component, according to purpose, in the scope of not damaging effect of the present invention, cosmetic material of the present invention can also the mixed-cation surfacant, the macromolecular compound beyond the nonionic surfactant, semi-polarity surfactant, (B) composition, polyhydric alcohol, higher alcohol, polysiloxane-based, lower alcohol, long-chain fatty acid, ester oil, viscosifier, spice, UV absorbent, fine-particle powder, plant extract, protein and derivant thereof, aminoacid, antiseptic, coloring agent, pH adjust agent, antioxidant, chelating agen, Purified Water etc.
When cosmetic material of the present invention has mixed spice, opening spice, the flavor compositions put down in writing in the 2003-95895 communique with the Japan Patent spy is benchmark, during the potpourri compositions, the spice that uses is mixed into that flavor compositions accounts for 0.00001～50 quality % in the material of making up, more preferably 0.0001～30 quality %.
The material of making up can exemplify hair or skin cosmetic, the hair class of wash type is made up and is used shampoo agent hair cleansing compositions such as (プ レ シ ヤ Application プ one drug) before material can exemplify shampoo, submissive (リ Application ス イ Application) shampoo, hair washing, wash type inorganic agent (ト リ one ト メ Application ト), eluent, softener etc.; The hair class of non-wash type is made up and is expected to exemplify non-flushing inorganic agent (ト リ one ト メ Application ト), modeling agent etc.Such cosmetic material can be made and be filled in the foam that spues and use with blister in the Foam Container.Foam Container can exemplify non-pneumatic type foam spue container, use the aerosol container of propellant and pressure vessel, the preferred non-pneumatic type foam container that spues.Non-pneumatic type foam spues container so long as the material of making up can be mixed with air, spue with foamed state and to get final product, be not particularly limited, for example, crushed foam container by the bubble that can spue with the hands extrusion bottle, by depressing the spue pump Foam Container etc. of bubble of spray nozzle part, can select according to purpose is suitable.Skin cosmetic can exemplify bath gel, cleansing milk etc.
Cosmetic material of the present invention can be prepared according to well-established law, for example, mixes above-mentioned (A) composition, (B) composition, composition and water (nubbin) and obtain arbitrarily.The cosmetic material that obtains can be filled in the suitable container.
Hair class of the present invention make up the pH of material be 3～7 better, the pH of skin cosmetic are 4～11 better.Preferred pH adjusts agent can exemplify inorganic acid salts such as sodium hydroxide, tetrasodium pyrophosphate, organic acid such as glycolic acid, citric acid.Among the present invention, the mensuration of pH is used East Asia electric wave industry system HM-25R type pH meter, carries out under 25 ℃.
Cosmetic material of the present invention especially has the effect of the Achromotrichia handled of preventing to have hair dyed in the hair class is made up material, therefore, be applicable to the hair of having hair dyed and handling.
Embodiment
Below, specifying the present invention with embodiment and comparative example, the present invention is not limited to following examples.In the following example, if no specified otherwise, " % " expression quality % of composition, ratio are represented mass ratio, and the amount of each composition in the table is if no specified otherwise is pure branch conversion amount.
[formulation example of polymer (1)]
The ethanol of in reactor, packing into 100 mass parts with reflux cooler, Dropping funnel, thermometer, nitrogen ingress pipe and agitating device, to pack in the reactor by the monomer mixed solution that 2-ethoxy acrylamide 96.8 mass parts, acrylic acid 3.2 mass parts and ethanol 80 mass parts constitute with Dropping funnel, will be replaced into nitrogen post-heating to 80 ℃ in the reactor.With dimethyl-2,2 '-azo two (2 Methylpropionic acid ester) (V-601; With the pure pharmaceutical worker of light industry (strain) system) after 1 mass parts drops into reactor, with 2 hours monomer mixed solutions that drip.Dripping makes its reaction 6 hours after finishing, and cooling obtains polymer (1) then.
[formulation example of polymer (2)～(7)]
Except monomer and use level thereof being adjusted into the construction unit that table 1 puts down in writing, according to the preparation method of polymer (1) prepared polymer (2)～(7) similarly.Adopt device: eastern ソ one Co., Ltd.'s system, SC8010, SD8022, RI8020, CO8011, PS8010, chromatographic column: the Wakopak of Wako Pure Chemical Industries, Ltd. (Wakobeads G-50), launch solvent: water/methanol/acetic acid/sodium acetate=6/4/0.3/0.41 is that standard substance is obtained weight average molecular weight with the Polyethylene Glycol.
[table 1]
HEAA:2-hydroxyethyl acrylamide
GLM:2-methyl-2-acrylic acid-2,3-dihydroxy propyl ester
AA: acrylic acid
MA: methacrylic acid
[embodiment 1～15, comparative example 1～9]
According to the composition shown in table 2～4, according to well-established law preparation hair cleansing composition.Each hair abluent is carried out following evaluation.The result remembers in the lump in table 2～4.PH adjusts and uses East Asia electric wave industry system HM-25R type pH meter to carry out under 25 ℃.
＜fading prevents effect 〉
The black topknot of long 10cm, quality 1g is immersed in the typical liquid lime chloride shown in the composition 1 of 10 times of quality, dipping is 30 minutes under the room temperature.Then, with warm water fully clean, drying.And then, smear the commercially available hair dye commensurability (Beautylabo hair color (fashion is brown) with the topknot quality; ホ one ユ one (strain) system), wrap and at room temperature handle 30 minutes.Then, smear 10%POE (2) the Laurel ether sodium sulfate of topknot quality 1/10 quality, comb is logical after 1 minute, uses warm water washing 1 minute, and dried topknot is used topknot with judging.Make the tone that colour difference meter SE2000 measures this topknot with Japan electric color industry society, as initial value.
With water-wet evaluation topknot, smear 0.1g sample hair cleansing composition, logical 1 minute of comb uses hands moistening topknot all rapidly.Then, use warm water washing 1 minute, drying.Repeat this operation 30 times, then, measure the tone of topknot once more with colour difference meter, obtain aberration (Δ E with initial value
*).This value has following relation with the impression of range estimation.
Δ E
*Be 0 above less than 1.6: almost do not have change in color
Δ E
*It is 1.6 above less thaies 2.5: change in color a little
Δ E
*It is more than 2.5: coloured variation
(forming 1) typical liquid lime chloride
Hydrogen peroxide 6%
Ammonia 2%
Sodium hydroxide is adjusted to pH10.5
The Purified Water nubbin
Add up to 100%
＜alveolar substance evaluation 〉
With Purified Water the sample hair cleansing composition is diluted to 10 times of quality (dilution ratio when being equivalent to have one's hair wash), use non-aerosol foam pump (foam of Fig. 1 of Japanese patent laid-open 7-315463 communique record discharges and uses pump receptacle) to allow this liquid bubble, catch and get this foam, according to following metewand, this foamy " sophistication " and " hardness of bubble " are carried out the sense evaluation.The result represents with the meansigma methods that 5 estimators estimate.
[metewand]
5 minutes: good alveolar substance
4 minutes: good slightly alveolar substance
3 minutes: bad slightly alveolar substance
2 minutes: bad alveolar substance
1 minute: do not bubble
[table 2]
[table 3]
[table 4]
[embodiment 16～26]
According to the composition shown in the table 5,6, according to following compound method preparation shampoo composite.For each shampoo composite, the enforcement that prevents effect of fading is identical with embodiment 1, and the alveolar substance evaluation is implemented according to following evaluation.The result is recorded in table 5,6 in the lump.
Table 5: mix each composition, adjust pH with glycolic acid or citric acid at last, the preparation shampoo composite.
Table 6: (a) composition is heated under 80 ℃, under well-beaten state, slowly be added in the Purified Water that is warmed to 80 ℃ equally while stir.Make the addition of Purified Water be equivalent to 25% of compositions full dose this moment.Be cooled to 50 ℃ while stirring this mixed solution.Be pre-mixed remaining composition in addition, mix, the preparation shampoo composite while stir these two kinds of solution.
＜alveolar substance evaluation 〉
Use shampoo composite (consumption is suitable selected according to the hair amount), carry out common hair washing, " sophistication " and " hardness of bubble " that steeps carried out the sense evaluation according to following metewand.The result represents with the meansigma methods that 5 estimators estimate.
[metewand]
5 minutes: good alveolar substance
4 minutes: good slightly alveolar substance
3 minutes: bad slightly alveolar substance
2 minutes: bad alveolar substance
1 minute: do not bubble
[table 5]
[table 6]
[embodiment 27～29, comparative example 10～12]
According to the composition shown in the table 7, handle (ト リ one ト メ Application ト) foam according to the well-established law preparation, be filled in the non-aerosol foam pump (bubble of Fig. 1 of Japanese patent laid-open 7-315463 communique record discharges and uses pump receptacle).Each is handled foam carry out following evaluation.The result is recorded in table 7 in the lump.
＜fading prevents effect 〉
Estimate and carry out similarly to Example 1 with the preparation of topknot and the mensuration of initial value.Swab is handled foam 0.5g on estimating with topknot, and combing 1 minute allows all moistenings rapidly of topknot, uses the hair-dryer drying then.Dry intact after 2 hours with warm water with the topknot moistening, smear 10%POE (2) Laurel ether sodium sulfate 0.1g, combing is after 1 minute, with warm water washing 1 minute, drying.This sample is handled foam carries out repeatedly smearing → drying → cleaning treatment for 30 times, then, measure the tone of topknot once more with colour difference meter, obtain and initial value between aberration (Δ E
*).This value has following relation with the impression of range estimation.
Δ E
*Be 0 above less than 1.6: almost do not have change in color
Δ E
*Be 1.6 above less thaies 2.5: change color is slightly arranged
Δ E
*It is more than 2.5: coloured variation
＜alveolar substance evaluation 〉
Make the non-aerosol foam pump 3g blister that spues handle foam, " sophistication " and " hardness of bubble " of bubble carried out the sense evaluation according to following metewand.The result represents with 5 estimators' meansigma methods.
[metewand]
5 minutes: good alveolar substance
4 minutes: good slightly alveolar substance
3 minutes: bad slightly alveolar substance
2 minutes: bad alveolar substance
1 minute: do not bubble
[table 7]
[embodiment 30, comparative example 13]
According to the composition shown in the table 8, according to well-established law preparation skin abluent.The skin abluent that obtains is filled in the non-aerosol foam pump receptacle of Japanese patent laid-open 7-315463 communique record.Each skin abluent is implemented following evaluation.The result is recorded in table 8 in the lump.
The albefaction of＜skin suppresses effect 〉
Allow skin abluent 6g spue with blister, clean to the top of elbow near the beginning wrist always from non-aerosol foam pump.With towel push wipe moisture away after, under the environment of 23 ℃ of room temperatures, relative humidity 40%, leave standstill, with the albefaction state of following benchmark evaluation elbow and preceding wrist skin after 1 hour.Evaluation is undertaken by 5 estimators that winter, wrist bleached easily, and the result represents with 5 estimators' meansigma methods.
[metewand]
5 minutes: can't see albefaction fully
4 minutes: can't see albefaction basically
3 minutes: see slight albefaction
2 minutes: see more albefaction
1 minute: see intensive albefaction
＜alveolar substance evaluation 〉
The alveolar substance evaluation is carried out similarly to Example 27.
[table 8]
The raw material that uses in the above-mentioned example is as follows.
[table 9]
[table 10]
(annotating 1) use level is shown with the scale of distearyl acid ethylene glycol.
(annotating 2) is to contain high polymerization dimethyl polysiloxane (1,000 ten thousand mm with 4.5% pair of Polyoxyethylene cetyl ether (15E.O.)
2/ s) 9%, high polymerization dimethyl polysiloxane (4,000,000 mm
2/ s) 9% and dimethyl polysiloxane (1000mm
2/ s) 42% mixture carries out the latex that emulsifying obtains, and combined amount is represented with the total amount of high polymerization dimethyl polysiloxane and dimethyl polysiloxane.(annotating 3) is the latex that contains poly-silicon alkane (mechicone) the dimethyl polysiloxane copolymer of 40% aminoethyl aminopropyl methyl hydrogen, and combined amount is shown with the scale of poly-silicon alkane (mechicone) the dimethyl polysiloxane copolymer of aminoethyl aminopropyl methyl hydrogen.
Claims (2)
1. change the make-up material for one kind, it is characterized in that, contain: (A) amphoteric surfactant or anionic surfactant and (B) contain the acrylic acid series polymeric compounds of 5～30 moles of % of monomeric unit shown in 70～95 moles of % of the monomeric unit shown in the following general formula (1) and the following general formula (2) as construction unit, (A)/(B) mass ratio shown in is 0.1～50.0
[changing 1]
In the formula, R
1Expression hydrogen atom or methyl, R
2The expression hydrogen atom or-CH
2OH base, A represent oxygen atom or-NH-,
[changing 2]
In the formula, R
3Expression hydrogen atom or methyl, M represents hydrogen atom, alkali metal atom, ammonium or amine.
2. as the change make-up material of claim 1 record, (A) composition is the surfactant that is selected from carboxybetaine type amphoteric surfactant, sulfuric acid ester type anionic surfactant and N-acyl amino acid type anionic surfactant.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2008-098266 | 2008-04-04 | ||
| JP2008098266A JP5509533B2 (en) | 2008-04-04 | 2008-04-04 | Hair cleanser and cleanser product |
| PCT/JP2009/054013 WO2009122844A1 (en) | 2008-04-04 | 2009-03-04 | Cosmetic preparation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102046144A true CN102046144A (en) | 2011-05-04 |
Family
ID=41135236
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009801211670A Pending CN102046144A (en) | 2008-04-04 | 2009-03-04 | Cosmetic preparation |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP5509533B2 (en) |
| KR (1) | KR101659635B1 (en) |
| CN (1) | CN102046144A (en) |
| MY (1) | MY159473A (en) |
| WO (1) | WO2009122844A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5912312B2 (en) * | 2011-06-30 | 2016-04-27 | 互応化学工業株式会社 | Cleaning composition |
| JP7333686B2 (en) * | 2018-10-05 | 2023-08-25 | ライオン株式会社 | Foam container containing skin cleanser composition |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0878185A2 (en) * | 1997-05-16 | 1998-11-18 | Showa Denko Kabushiki Kaisha | Hair-care preparations |
| US5965500A (en) * | 1997-07-24 | 1999-10-12 | Levers Brothers Company, Division Of Conopco, Inc. | Stable liquid composition comprising high levels of emollients |
| FR2774694B1 (en) * | 1998-01-19 | 2003-08-08 | Rhodia Chimie Sa | USE OF COPOLYMERS BASED ON UNSATURATED ACIDS OR DERIVATIVES THEREOF AS FOAMENING AGENTS |
| JP2002193789A (en) * | 2000-12-26 | 2002-07-10 | Lion Corp | Cleansing agent composition |
| JP2002309291A (en) * | 2001-04-13 | 2002-10-23 | Lion Corp | Detergent composition |
| JP2005306843A (en) * | 2004-03-25 | 2005-11-04 | Kose Corp | Skin detergent composition |
| JP4424037B2 (en) * | 2004-03-31 | 2010-03-03 | 日油株式会社 | Cleaning composition |
| JP4736741B2 (en) * | 2005-11-18 | 2011-07-27 | 三菱化学株式会社 | Cosmetic composition |
| JP5167601B2 (en) * | 2005-11-18 | 2013-03-21 | 三菱化学株式会社 | Hair cosmetics |
| JP5804665B2 (en) * | 2008-04-04 | 2015-11-04 | ライオン株式会社 | Hair cosmetics |
-
2008
- 2008-04-04 JP JP2008098266A patent/JP5509533B2/en not_active Expired - Fee Related
-
2009
- 2009-03-04 WO PCT/JP2009/054013 patent/WO2009122844A1/en active Application Filing
- 2009-03-04 KR KR1020107024517A patent/KR101659635B1/en active IP Right Grant
- 2009-03-04 MY MYPI2010004418A patent/MY159473A/en unknown
- 2009-03-04 CN CN2009801211670A patent/CN102046144A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JP2009249330A (en) | 2009-10-29 |
| WO2009122844A1 (en) | 2009-10-08 |
| MY159473A (en) | 2017-01-13 |
| JP5509533B2 (en) | 2014-06-04 |
| KR101659635B1 (en) | 2016-09-26 |
| KR20100133461A (en) | 2010-12-21 |
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