CN102040914A - Environmentally-friendly GYS inorganic adhesive for fireproof door - Google Patents
Environmentally-friendly GYS inorganic adhesive for fireproof door Download PDFInfo
- Publication number
- CN102040914A CN102040914A CN2009100708620A CN200910070862A CN102040914A CN 102040914 A CN102040914 A CN 102040914A CN 2009100708620 A CN2009100708620 A CN 2009100708620A CN 200910070862 A CN200910070862 A CN 200910070862A CN 102040914 A CN102040914 A CN 102040914A
- Authority
- CN
- China
- Prior art keywords
- gys
- percent
- inorganic adhesive
- adhesive
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention relates to a nontoxic, pollution-free, noncombustible and non-explosive single-component environmentally-friendly GYS inorganic adhesive applied to a fireproof door and related fields, and a preparation method thereof. The adhesive has high bonding effect and high-temperature resistant and noncombustible fireproof performance. The adhesive consists of 40 to 55 percent of water-soluble silicate (SiO2/Na2O), 30 to 50 percent of phosphate and silicate ore powder, such as Suzhou clay, kaolin and the like, 1 to 5 percent of metal powder (ferrosilicon or other metal powder, and the like), 1 to 2 percent of reinforcing fiber (alumina or high-silicon aluminum and other fibers) and 1 to 5 percent of functional aid. The adhesive has the colloid density of 1.5 to 1.8 g/cm<3> and the bond strength of more than 5MP, the toxicity of the produced smoke meets AQ1 (GB12955-2008), the combustion performance reaches an A1 level, and the refractoriness is more than 1,300 DEG C (GB12955-2008).
Description
Technical field:
The present invention relates to a kind of the nontoxic, pollution-free of fire door and association area that be applied to, do not fire, not quick-fried single component environment-friendly type GYS inorganic adhesive and preparation method thereof, the existing high bonding effect of this tackiness agent has high temperature resistant non-combustible fire-proof function again.
Background technology:
China starts late in fire door market, but development rapidly.For many years, positive effect has been played in the development of fire door and related products, exploitation and production to assuring the safety for life and property of the people.But developed in recent years and advance by leaps and bounds along with fire door market, quality problems appear in fire door and related products repeatly, hazardous and noxious substances severe overweight particularly, and fire door not fp incident happens occasionally, and causes the government and the public's common concern.At adhesive area, the organic synthesis tackiness agent is because its superior adhesive property is occupied dominant position always, but nearly all many non-refractories of organic adhesive material, and great majority are non-environmentfriendly products are restricted its application in a lot of fields.Organic gel such as the white glue with vinyl that wherein a lot of now enterprises still use, PU glue stick with glue agent as fire door, venomous injurant severe overweights such as product organic volatile, free formaldehyde, and there is not fire-resistant function, grievous injury consumers in general's interests, also damaged the image of fire door and relevant industries.
In today that Environmental awareness and health perception improve day by day, the green tackiness agent of environment-friendly type is pressing for of contemporary Sustainable development, and country has put into effect relevant compulsory standard (promulgation of 2009.1.1 country is also executed fire door new standard GB12955-2008).The infringement that formaldehyde, benzene, ammonia etc. pollute body is stopped in " little gluing big environmental protection ", strictness, and the poisonous and harmful tackiness agent that uses before replacing with environmental-protection type adhesive, inorganic environment-friendly glue will be the emphasis and the directions of adhesive industry development from now on.Inorganic adhesive have do not burn, high temperature resistant, and abundant raw material, price low, advantage such as do not pollute, be subject to people's attention day by day.
Fire door is that a kind of high temperature resistant, cohesiveness composite by multiple inorganic silicate, phosphoric acid salt etc., that be processed into through special process is strong, the single-component inorganic environment-friendly adhesive of nontoxic pollution-free with environment-friendly type GYS inorganic adhesive.
Summary of the invention:
The GYS inorganic environment-friendly tackiness agent that the purpose of this invention is to provide a kind of high temperature resistant, nontoxic pollution-free that in fire door and association area, uses
GYS inorganic environment-friendly tackiness agent provided by the invention, its composition: water-soluble silicate (SiO
2/ Na
2O) 40-55%, phosphoric acid salt, silicate mine stone powder (as Suzhou soil, kaolin etc.) 30-50%, metal-powder (ferrosilicon or other metal-powder etc.) 1-5%, fortifying fibre (fibers such as aluminum oxide or high sial) 1-2%, functional agent 1-5%.
GYS inorganic environment-friendly tackiness agent provided by the invention, its preparation: phosphoric acid salt, silicate mine stone powder and metal-powder grind, sieve and stir, and sneak into water-soluble silicate, fortifying fibre, catalyzer and stir and got final product in 30-40 minute.
Technical parameter:
Colloid density: 1.5-1.8g/cm
3
Cohesive strength＞5MP
Material producing smoke toxicity reaches AQ1 (GB12955-2008)
Combustionproperty reaches the A1 level, refractoriness＞1300 ℃ (GB12955-2008)
The product operation characteristics:
1, single component glue, glue consumption is few, bonding force strong (recommend glue consumption: steel door-250～300 gram/square metre, wooden door-300-350 gram/square metre)
2, easy and simple to handle, set time is short, and (steel plate can not made bonderizing; Hot pressing temperature reaches removable curing, 10-15 minute completely solidified at 75 ℃-100 ℃ in 6-8 minute; The envrionment temperature of colding pressing was reaching removable curing, 6-7 hour completely solidified in 3-4 hour more than 10 ℃.)
This fire prevention glue is single component glue, and glue consumption is few, and bonding force is strong; Easy and simple to handle, set time is short; Can bonding aluminium silicate wool, rock wool, perlite PLASTIC LAMINATED, vermiculite PLASTIC LAMINATED, glass magnesium plate, plank, three ply board, high-density plate, and metals such as materials such as metal, pottery and steel plate is bonding, and plastic-blasting heats and does not influence glue-line intensity.
Embodiment:
1, prescription:
Water-soluble silicate (SiO
2/ Na
2O): 45
Phosphoric acid salt, silicate mine stone powder (as Suzhou soil, kaolin etc.): 45
Metal-powder (ferrosilicon or other metal-powder etc.): 3
Fortifying fibre (fibers such as aluminum oxide or high sial): 2
Ester class or other class catalyzer: 5
2, preparation:
1. phosphoric acid salt, silicate mine stone powder, metal-powder grind
2. 480 orders sieve the powder after the above-mentioned grinding respectively
3. the powder after will sieving stirs
4. the powder that stirs is poured in the water-soluble silicate, added fortifying fibre, catalyzer stirring 30 minutes again.
Claims (3)
1. the present invention relates to a kind of the nontoxic, pollution-free of fire door and association area that be applied to, do not fire, not quick-fried environment-friendly type GYS inorganic adhesive and preparation method thereof.The existing high bonding effect of this tackiness agent has high temperature resistant non-combustible fire-proof function again.Its composition: water-soluble silicate (SiO
2/ Na
2O) 40-55%, phosphoric acid salt, silicate mine stone powder (as Suzhou soil, kaolin etc.) 30-50%, metal-powder (ferrosilicon or other metal-powder etc.) 1-5%, fortifying fibre (fibers such as aluminum oxide or high sial) 1-2%, functional agent 1-5%.
2. by the operating features of right 1 described environment-friendly type GYS inorganic adhesive: single component glue, glue consumption is few, bonding force strong (recommend glue consumption: steel door-250～300 gram/square metre, wooden door-300-350 gram/square metre); Easy and simple to handle, set time is short, and (steel plate can not made bonderizing; Hot pressing temperature reaches removable curing, 10-15 minute completely solidified at 75 ℃-100 ℃ in 6-8 minute; The envrionment temperature of colding pressing was reaching removable curing, 6-7 hour completely solidified in 3-4 hour more than 10 ℃.)
3. by right 1 described environment-friendly type GYS inorganic adhesive characteristics: colloid density: 1.5-1.8g/cm
3, cohesive strength＞5MP, material producing smoke toxicity reach AQ1 (GB12955-2008), combustionproperty reaches A1 level, refractoriness＞1300 ℃ (GB12955-2008).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100708620A CN102040914A (en) | 2009-10-19 | 2009-10-19 | Environmentally-friendly GYS inorganic adhesive for fireproof door |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100708620A CN102040914A (en) | 2009-10-19 | 2009-10-19 | Environmentally-friendly GYS inorganic adhesive for fireproof door |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102040914A true CN102040914A (en) | 2011-05-04 |
Family
ID=43907469
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009100708620A Pending CN102040914A (en) | 2009-10-19 | 2009-10-19 | Environmentally-friendly GYS inorganic adhesive for fireproof door |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102040914A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102116124A (en) * | 2009-12-30 | 2011-07-06 | 杨新华 | Application of kaolin in special material for fire door |
| CN103936386A (en) * | 2014-03-27 | 2014-07-23 | 公安部四川消防研究所 | Non-toxic high-temperature-resistant compound glue for fireproof door |
| CN104387992A (en) * | 2014-11-28 | 2015-03-04 | 苏州伊埃夫化学材料科技有限公司 | Environment-friendly adhesive for artificial board and preparation method of environment-friendly adhesive |
| CN104449502A (en) * | 2014-12-12 | 2015-03-25 | 青岛福启源新型建材有限公司 | Thermosetting fire retardant adhesive |
| CN105567098A (en) * | 2016-03-05 | 2016-05-11 | 胡伙送 | Inorganic adhesive |
| CN109749633A (en) * | 2017-11-08 | 2019-05-14 | 山东工业陶瓷研究设计院有限公司 | A kind of normal temperature cure silicate high temperature resistant binder and preparation method thereof |
| CN115595059A (en) * | 2022-09-20 | 2023-01-13 | 哈尔滨工业大学（Cn） | Preparation method of green fireproof coating |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4018616A (en) * | 1974-09-13 | 1977-04-19 | Mizusawa Kagaku Kogyo Kabushiki Kaisha | Water glass composition |
| GB1584442A (en) * | 1977-03-23 | 1981-02-11 | Woellner Werke | Bonding foamed plastics boards with an adhesive containing finely divided inorganic powders and based on alkali metal silicate solutions |
| CN1172709A (en) * | 1996-02-29 | 1998-02-11 | 博登化学公司 | Binders for cores and molds |
-
2009
- 2009-10-19 CN CN2009100708620A patent/CN102040914A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4018616A (en) * | 1974-09-13 | 1977-04-19 | Mizusawa Kagaku Kogyo Kabushiki Kaisha | Water glass composition |
| GB1584442A (en) * | 1977-03-23 | 1981-02-11 | Woellner Werke | Bonding foamed plastics boards with an adhesive containing finely divided inorganic powders and based on alkali metal silicate solutions |
| CN1172709A (en) * | 1996-02-29 | 1998-02-11 | 博登化学公司 | Binders for cores and molds |
Non-Patent Citations (1)
| Title |
|---|
| 徐全祥: "《合成胶粘剂及其应用》", 31 March 1986, 辽宁科学技术出版社 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102116124A (en) * | 2009-12-30 | 2011-07-06 | 杨新华 | Application of kaolin in special material for fire door |
| CN103936386A (en) * | 2014-03-27 | 2014-07-23 | 公安部四川消防研究所 | Non-toxic high-temperature-resistant compound glue for fireproof door |
| CN103936386B (en) * | 2014-03-27 | 2016-02-17 | 公安部四川消防研究所 | The compound nontoxic high-temperature plastic of fire door |
| CN104387992A (en) * | 2014-11-28 | 2015-03-04 | 苏州伊埃夫化学材料科技有限公司 | Environment-friendly adhesive for artificial board and preparation method of environment-friendly adhesive |
| CN104449502A (en) * | 2014-12-12 | 2015-03-25 | 青岛福启源新型建材有限公司 | Thermosetting fire retardant adhesive |
| CN105567098A (en) * | 2016-03-05 | 2016-05-11 | 胡伙送 | Inorganic adhesive |
| CN109749633A (en) * | 2017-11-08 | 2019-05-14 | 山东工业陶瓷研究设计院有限公司 | A kind of normal temperature cure silicate high temperature resistant binder and preparation method thereof |
| CN115595059A (en) * | 2022-09-20 | 2023-01-13 | 哈尔滨工业大学（Cn） | Preparation method of green fireproof coating |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102040914A (en) | Environmentally-friendly GYS inorganic adhesive for fireproof door | |
| CA2447928C (en) | Proppants and their manufacture | |
| JP2017502913A (en) | Geopolymer cement made from recycled glass and its manufacturing process | |
| CN106032313A (en) | Alkali-activated slag powder geopolymer mortar for structure reinforcement and preparation method thereof | |
| CN107117930A (en) | A kind of high temperature resistance and high strength fire-resistant door core sheet material and preparation method thereof | |
| CN102701770A (en) | Continuous basalt fiber reinforced ceramic composite and preparation method for same | |
| CN102320782A (en) | Rice hull ash and metakaolin based polymer composite fireproof paint and preparation method thereof | |
| KR20140080791A (en) | Eco building interior boards and method for manufacturing thereof | |
| CN106519993A (en) | Silicate inorganic adhesive and preparation method thereof | |
| CN102459114B (en) | Substitute silica-based nonflammable material of asbestos and preparation method thereof | |
| CN106187050B (en) | A kind of porous silica sand noise reducing plate and preparation method thereof | |
| CN106554743A (en) | Acoustic mastic and preparation method thereof is built in a kind of high one-component epoxy resin capital construction of corrosion resistance adhesion strength | |
| CN107417167A (en) | A kind of Novel fireproof material and preparation method thereof | |
| CN106554745A (en) | Acoustic mastic and preparation method thereof is built in a kind of environment-friendly type anophelifuge one-component epoxy resin capital construction | |
| CN101143501B (en) | Method for manufacturing multi-layer composite board | |
| CN103319135B (en) | A kind of light lath for building partition wall Diatomite binder | |
| CN101195735A (en) | Fireproof glue and method for producing the same | |
| CN105569507A (en) | Coal ash based wood fiber artificial fireproof plate and manufacturing method thereof | |
| CN109133946A (en) | A kind of light thermal insulation fire-resistant material and preparation method thereof | |
| CN103693921B (en) | A kind of lightweight fiberglass foam cement batten and production method thereof | |
| CN101863651B (en) | Stuffing of fire door | |
| CN101823866A (en) | Inorganic high-temperature agglomerant | |
| CN110862774A (en) | Modified inorganic adhesive, preparation method and application in production of wood-based panel | |
| CN115352137B (en) | Fireproof assembly for steel structure, and preparation process and application thereof | |
| CN107473692A (en) | A kind of building decoration ecology stone-wood floor brick and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20110504 |