CN102037994A - Pesticide composition containing emamectin benzoate and cidial - Google Patents
Pesticide composition containing emamectin benzoate and cidial Download PDFInfo
- Publication number
- CN102037994A CN102037994A CN2010106136844A CN201010613684A CN102037994A CN 102037994 A CN102037994 A CN 102037994A CN 2010106136844 A CN2010106136844 A CN 2010106136844A CN 201010613684 A CN201010613684 A CN 201010613684A CN 102037994 A CN102037994 A CN 102037994A
- Authority
- CN
- China
- Prior art keywords
- benzoate
- emamectin
- composition pesticide
- percentage
- dimephenthoate cidial
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a pesticide composition containing emamectin benzoate and cidial. The invention is characterized in that the composition is missible oil, wettable powder, emulsion in water or granules prepared by taking emamectin benzoate and cidial as active ingredients and solvent, a carrier, surfactant and accessories as assisting agents, wherein the weight percent of the active ingredients is 10.1-60%. The composition has reasonable matching, enhances quick acting effect, reduces drug cost, produces less damage and pollution to the ecological environment and is beneficial to safety protection of man and beast, thus being a blended preparation which has high efficiency and low toxicity and preventing injurious insets from producing drug resistance.
Description
Technical field
The present invention relates to field of agrochemicals, specifically, the present invention relates to a kind of compound pesticide composition that contains insecticide emamectin-benzoate and phenthoate dimephenthoate cidial, be applicable to resistant insects such as control striped rice borer, paddy stem borer, rice leaf roller, cotton bollworm, smaller green leaf hopper.
Background technology
Emamectin-benzoate is a kind of new and effective semisynthetic antibiotics insecticide that begins to synthesize from fermented product Avermectin B1, it has super-high-efficient, low toxicity (preparation is closely nontoxic), noresidue, the nuisanceless characteristics that wait biopesticide, with Avermectin at first insecticidal activity improved 1-3 the order of magnitude, active high to the larva of lepidopterous insects and other many insects and mite class, the double again action of contace poison of existing stomach poison function, (has good effect under 0.084～2g/ha) at low-down dosage, and in the process of pest control, beneficial insect is not injured, help integrated control to insect, enlarged insecticidal spectrum in addition, reduced toxicity people and animals.In a word, the methylamino emamectin-benzoate is a kind of efficient, high selection, green, environment-friendly type, biological source insecticide.Emamectin-benzoate is used to prevent and treat insects such as striped rice borer, paddy stem borer, rice leaf roller, cotton bollworm, smaller green leaf hopper in recent years good effect, but quick-acting is poor slightly, and long-term the use, and insect has been produced resistance.
Phenthoate dimephenthoate cidial phenthoate also has very strong interior suction, stomach poison function except that stronger action of contace poison is arranged, the broad spectrum organic phosphorus insecticides has quick-acting.Permeability is preferably arranged on plant leaf blade.Its mechanism of action is to suppress cholinesterase in the insect bodies.
The single formulation chemical pesticide of long-term use, insect is easy to generate pesticide resistance, in order to reach the effect of control of insect, have to strengthen the agricultural chemicals usage amount or use more highly toxic agricultural chemicals, so not only increase the weight of peasant's financial burden, pollution of ecological environment destroys the ecological balance, influence the safety of agricultural product, and a large amount of natural enemies quilt extremely, causes the rampant more of insect, and is big to people and animals' toxicity, and long-term the use, insect also can develop immunity to drugs.
Delay the resistance that insect produces emamectin-benzoate, and effectively solve its quick-acting problem, I research staff of company carries out emamectin-benzoate and phenthoate dimephenthoate cidial composite, make its mode of action and speed of action complementation, not only improved the activity of emamectin-benzoate, delayed the resistance of insect, prolonged the service life of product emamectin-benzoate and phenthoate dimephenthoate cidial, and the cost of reduction pesticide control, improve control efficiency.Environmentally friendly.
Summary of the invention
The technical problem to be solved in the present invention is to delay the resistance that insect produces emamectin-benzoate, and effectively solve its quick-acting problem, provide a kind of with emamectin-benzoate and the composite agricultural chemicals of phenthoate dimephenthoate cidial, make its mode of action and speed of action complementation, not only improve the activity of emamectin-benzoate, prolonged the service life of product.
For solving the problems of the technologies described above, the invention provides following technical scheme: a kind of emamectin-benzoate and phenthoate dimephenthoate cidial composition pesticide of containing, it is an active ingredient with emamectin-benzoate, phenthoate dimephenthoate cidial, and be aided with solvent, carrier, surfactant and auxiliary agent and be prepared into missible oil, wetting powder, aqueous emulsion or granule formulation, wherein the percentage by weight of effective ingredient is 10.1%-60%.
As a kind of preferred version that contains emamectin-benzoate and phenthoate dimephenthoate cidial composition pesticide of the present invention, wherein: the percentage by weight of described active ingredient is 30%-50%.
As a kind of preferred version that contains emamectin-benzoate and phenthoate dimephenthoate cidial composition pesticide of the present invention, wherein: to account for the percentage by weight of composition pesticide be 0.1%-10% to emamectin-benzoate in the active ingredient, and the percentage by weight that phenthoate dimephenthoate cidial accounts for composition pesticide is 10%-50%.
As a kind of preferred version that contains emamectin-benzoate and phenthoate dimephenthoate cidial composition pesticide of the present invention, wherein: to account for the percentage by weight of composition pesticide be 0.2%-0.6% to emamectin-benzoate in the active ingredient, and the percentage by weight that phenthoate dimephenthoate cidial accounts for composition pesticide is 19.9%-39.6%.
As a kind of preferred version that contains emamectin-benzoate and phenthoate dimephenthoate cidial composition pesticide of the present invention, wherein: to account for the percentage by weight of composition pesticide be 0.4%-0.6% to emamectin-benzoate in the active ingredient, and the percentage by weight that phenthoate dimephenthoate cidial accounts for composition pesticide is 29.8%-39.6%.
As a kind of preferred version that contains emamectin-benzoate and phenthoate dimephenthoate cidial composition pesticide of the present invention, wherein: the percentage by weight that contains surfactant is 1%-25%, and containing solvent, carrier and auxiliary agent percentage by weight is 15%-88.9%.
In the Recompounded pesticide of emamectin-benzoate and phenthoate dimephenthoate cidial, selected solvent is that solvent comprises: the mixture of one or more of water, benzene,toluene,xylene, methyl alcohol, ethanol, isopropyl alcohol, butanols, cyclohexanone, a line oil, acetonitrile, carrene, chloroform, diformamide, dioxane, naphthalene, methyl naphthalene, dimethyl sulfoxide (DMSO), N-Methyl pyrrolidone, ethyl acetate, acetone, butanone, ether, gylcol ether; Selected emulsifier is to be selected from farming breast 2201, ` farming breast 650, farming breast 0201, the farming breast 0204 one or more; Described carrier comprises one or more mixtures in kaolin, bentonite, atlapulgite, sepiolite, white carbon, diatomite, precipitated calcium carbonate, talcum powder, the plaster of paris, chalky soil, potter's clay, imvite, the clay; Other selected auxiliary agent comprises one or more mixtures in ethylene glycol, propane diols, glycerine, urea, xanthans, methylol (ethyl) cellulose, gum Arabic, gelatin, modified starch, polyvinylpyrrolidone, octanol, the silicone; Synergist is one or more in selection autosynergism ether, Piprotal, the sulfoxide; The pH value conditioning agent is to be selected from acetic acid, hydrochloric acid, sodium hydroxide, the potassium hydroxide one or more.
When the present invention was missible oil, solvent for use was one or more mixtures in benzene,toluene,xylene, methyl alcohol, ethanol, isopropyl alcohol, butanols, a line oil, cyclohexanone, dimethyl formamide, dimethyl sulfoxide (DMSO), N-Methyl pyrrolidone, ethyl acetate, acetone, butanone, the gylcol ether.Selected emulsifier is to be selected from farming breast 2201, ` farming breast 650, farming breast 0201, the farming breast 0204 one or more.
When the present invention was wetting powder and granule, used carrier was one or more mixtures in kaolin, bentonite, atlapulgite, sepiolite, white carbon, diatomite, precipitated calcium carbonate, talcum powder, the plaster of paris, chalky soil, potter's clay, imvite, the clay.Selected emulsifier is to be selected from farming breast 2201, ` farming breast 650, farming breast 0201, the farming breast 0204 one or more.
When the present invention was aqueous emulsion, its continuous phase was water, and selected emulsifier is to be selected from farming breast 2201, ` farming breast 650, farming breast 0201, the farming breast 0204 one or more.Employed other auxiliary agent is one or more mixtures in polyvinyl alcohol, polyvinylpyrrolidone, carboxymethyl (ethyl) cellulose, xanthans, gum Arabic, gelatin, starch, alginic acid, urea, ethylene glycol, propane diols, the glycerine.
When formulation of the present invention was missible oil, the preparation method that adopts was a stirring and dissolving; When formulation is wetting powder, the preparation method that adopts for earlier various raw material being mixed then through comminution by gas stream to required particle diameter; When formulation is aqueous emulsion, the preparation method that adopts in the aqueous solution that contains surfactant, antifreezing agent, defoamer etc., two kinds of active ingredient homogeneous shears being emulsified into the liquid of the required particle diameter of milky; When formulation was granule, the preparation method who is adopted was for mixing earlier,, mediated then, through the dry gained of extruder grain to required particle diameter through comminution by gas stream.
The invention has the advantages that:
1, in the Recompounded pesticide process of preparation emamectin-benzoate and phenthoate dimephenthoate cidial,, guaranteed the stability and the stability of formulation of active insecticidal components, has been convenient to store and transportation that the shelf time is long by adding various auxiliary agents.
2, emamectin-benzoate and phenthoate dimephenthoate cidial are mixed according to the above ratio, have both kept the advantage of single agent itself, and the reduction of mixture dosage, and drug effect increases substantially, and has remedied the deficiency of single agent.
3, above-mentioned mixture has distinguished effect to multiple resistant insects such as striped rice borer, paddy stem borer, rice leaf roller, cotton bollworm, smaller green leaf hoppers, has enlarged the control of insect spectrum, has delayed pesticide resistance.
4, utilizing two kinds of agricultural chemicals that the different mode of action of insect, mechanism of action reasonably are mixed, is to prolong agricultural chemicals service life, delay pest resistance to insecticide, reduce the effective way of agricultural chemicals side effect.
5, above-mentioned mixture reasonable mixture ratio has strengthened quick-acting, has reduced the agricultural chemicals use cost, to the infringement of ecotope with pollute for a short time, helps protecting the person poultry safety, the mixture preparation that be that a class is efficient, low toxicity, insect is difficult to develop immunity to drugs.
Embodiment
The present invention is further illustrated with application below in conjunction with embodiment.
Embodiment 1
0.1 kilogram of emamectin-benzoate (rolling over hundred content)
19.9 kilograms of phenthoate dimephenthoate cidial
0,201 10 kilogram of farming breast
2 kilograms of methyl alcohol
2 kilograms of propane diols
6 kilograms of CMCs
0.5 kilogram of Piprotal
59.3 kilograms of dimethylbenzene
0.2 kilogram of hydrochloric acid
Former medicine (former powder) is dissolved with cosolvent, and the partial solvent that has high input in modulation kettle then under agitation, drops into former medicine, emulsifier, stabilizing agent, synergist, pH value conditioning agent and residual solvent successively, stirs, and analyzes, filter, and packing, promptly.
Embodiment 2
0.6 kilogram of emamectin-benzoate (rolling over hundred content)
29.4 kilograms of phenthoate dimephenthoate cidial
0,201 10 kilogram of farming breast
2 kilograms of methyl alcohol
3 kilograms of propane diols
5 kilograms of CMCs
0.6 kilogram of Piprotal
49.2 kilograms of dimethylbenzene
0.2 kilogram of hydrochloric acid
The preparation method is with embodiment 1
Embodiment 3
0.9 kilogram of emamectin-benzoate (rolling over hundred content)
49.1 kilograms of phenthoate dimephenthoate cidial
0,204 15 kilogram of farming breast
5 kilograms of isoamyl alcohol
3 kilograms of glycerine
2 kilograms of Sodium Polyacrylates
0.2 kilogram of sulfoxide
24.5 kilograms in acetone
0.3 kilogram in potassium hydroxide
The preparation method is with embodiment 1
Embodiment 4
0.4 kilogram of emamectin-benzoate (rolling over hundred content)
39.6 kilograms of phenthoate dimephenthoate cidial
2,201 12 kilograms of farming breasts
3 kilograms of ethanol
6 kilograms of ethylene glycol
7 kilograms of xanthan gums
0.5 kilogram of Butacide
31.1 kilograms of dimethylbenzene
0.4 kilogram of acetic acid
The preparation method is with embodiment 1
Embodiment 5
0.2 kilogram of emamectin-benzoate (rolling over hundred content)
29.8 kilograms of phenthoate dimephenthoate cidial
0,201 10 kilogram of farming breast
2 kilograms of methyl alcohol
4 kilograms of propane diols
4 kilograms of CMCs
0.5 kilogram of Piprotal
49.1 kilograms of dimethylbenzene
0.4 kilogram of hydrochloric acid
The preparation method is with embodiment 1
The Recompounded pesticide of above-mentioned prescription and emamectin-benzoate missible oil, phenthoate dimephenthoate cidial missible oil compare test, to co-toxicity coefficient and test of pesticide effectiveness data such as the table 1 of striped rice borer.
Table 1 emamectin-benzoate and the composite different proportionings of phenthoate dimephenthoate cidial are to the indoor determination of activity of striped rice borer table as a result
Claims (6)
1. one kind contains emamectin-benzoate and phenthoate dimephenthoate cidial composition pesticide, it is characterized in that: with emamectin-benzoate, phenthoate dimephenthoate cidial is active ingredient, and be aided with solvent, carrier, surfactant and auxiliary agent and be prepared into missible oil, wetting powder, aqueous emulsion or granule formulation, wherein the percentage by weight of effective ingredient is 10.1%-60%.
2. emamectin-benzoate and the phenthoate dimephenthoate cidial composition pesticide of containing according to claim 1, it is characterized in that: the percentage by weight of described active ingredient is 30%-50%.
3. emamectin-benzoate and the phenthoate dimephenthoate cidial composition pesticide of containing according to claim 1, it is characterized in that: to account for the percentage by weight of composition pesticide be 0.1%-10% to emamectin-benzoate in the active ingredient, and the percentage by weight that phenthoate dimephenthoate cidial accounts for composition pesticide is 10%-50%.
4. emamectin-benzoate and the phenthoate dimephenthoate cidial composition pesticide of containing according to claim 1, it is characterized in that: to account for the percentage by weight of composition pesticide be 0.2%-0.6% to emamectin-benzoate in the active ingredient, and the percentage by weight that phenthoate dimephenthoate cidial accounts for composition pesticide is 19.9%-39.6%.
5. emamectin-benzoate and the phenthoate dimephenthoate cidial composition pesticide of containing according to claim 1, it is characterized in that: to account for the percentage by weight of composition pesticide be 0.4%-0.6% to emamectin-benzoate in the active ingredient, and the percentage by weight that phenthoate dimephenthoate cidial accounts for composition pesticide is 29.8%-39.6%.
6. according to described emamectin-benzoate and the phenthoate dimephenthoate cidial composition pesticide of containing of arbitrary claim in the claim 1 to 5, it is characterized in that: the percentage by weight that wherein contains surfactant is 1%-25%, and containing solvent, carrier and auxiliary agent percentage by weight is 15%-88.9%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010106136844A CN102037994A (en) | 2010-12-30 | 2010-12-30 | Pesticide composition containing emamectin benzoate and cidial |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010106136844A CN102037994A (en) | 2010-12-30 | 2010-12-30 | Pesticide composition containing emamectin benzoate and cidial |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102037994A true CN102037994A (en) | 2011-05-04 |
Family
ID=43904812
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010106136844A Pending CN102037994A (en) | 2010-12-30 | 2010-12-30 | Pesticide composition containing emamectin benzoate and cidial |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102037994A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015120786A1 (en) * | 2014-02-14 | 2015-08-20 | 南京善为生物科技有限公司 | Environmentally-friendly emamectin benzoate preparation and preparation method therefor |
| CN108029683A (en) * | 2017-10-26 | 2018-05-15 | 江苏腾龙生物药业有限公司 | A kind of aqueous emulsion and its preparation process containing phenthoate dimephenthoate cidial and avermectin |
| CN111066780A (en) * | 2019-12-30 | 2020-04-28 | 江苏腾龙生物药业有限公司 | Emulsifiable concentrate containing 40% phenthoate and lambda-cyhalothrin |
| CN111096330A (en) * | 2019-12-30 | 2020-05-05 | 江苏腾龙生物药业有限公司 | Emulsion in water containing phenthoate and emamectin benzoate |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1399884A (en) * | 2001-07-31 | 2003-03-05 | 马韵升 | Methlaminoabamectin benzoate pesticide and miticide composite |
| CN1860888A (en) * | 2006-06-16 | 2006-11-15 | 张俊 | Composite pesticide used for prevention and control of harmful insect of rice |
| CN101180968A (en) * | 2007-12-18 | 2008-05-21 | 海南利蒙特生物农药有限公司 | Compounded pesticide of emamectin-benzoate and fenitrothion |
| CN101185440A (en) * | 2007-12-18 | 2008-05-28 | 张少武 | Compound pesticides containing avermectin |
-
2010
- 2010-12-30 CN CN2010106136844A patent/CN102037994A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1399884A (en) * | 2001-07-31 | 2003-03-05 | 马韵升 | Methlaminoabamectin benzoate pesticide and miticide composite |
| CN1860888A (en) * | 2006-06-16 | 2006-11-15 | 张俊 | Composite pesticide used for prevention and control of harmful insect of rice |
| CN101180968A (en) * | 2007-12-18 | 2008-05-21 | 海南利蒙特生物农药有限公司 | Compounded pesticide of emamectin-benzoate and fenitrothion |
| CN101185440A (en) * | 2007-12-18 | 2008-05-28 | 张少武 | Compound pesticides containing avermectin |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015120786A1 (en) * | 2014-02-14 | 2015-08-20 | 南京善为生物科技有限公司 | Environmentally-friendly emamectin benzoate preparation and preparation method therefor |
| CN108029683A (en) * | 2017-10-26 | 2018-05-15 | 江苏腾龙生物药业有限公司 | A kind of aqueous emulsion and its preparation process containing phenthoate dimephenthoate cidial and avermectin |
| CN111066780A (en) * | 2019-12-30 | 2020-04-28 | 江苏腾龙生物药业有限公司 | Emulsifiable concentrate containing 40% phenthoate and lambda-cyhalothrin |
| CN111096330A (en) * | 2019-12-30 | 2020-05-05 | 江苏腾龙生物药业有限公司 | Emulsion in water containing phenthoate and emamectin benzoate |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100586282C (en) | Insecticidal composition containing chlorantraniliprole and monosultap | |
| CN104663679B (en) | A kind of insecticide acaricide composition containing macrolide insecticide | |
| CN103385251B (en) | A kind of Pesticidal combination of pyriproxyfen-containing | |
| CN106689145A (en) | Weeding composition containing pyroxasulfone and amide herbicides | |
| CN104115845A (en) | Efficient pesticide composition containing flubendiamide | |
| CN102037994A (en) | Pesticide composition containing emamectin benzoate and cidial | |
| CN103004867B (en) | Insecticidal composition with synergism | |
| CN101589720B (en) | Pesticide composition containing indoxacarb | |
| CN102084862A (en) | Insecticidal composition containing ethiprole | |
| CN102228056B (en) | Pesticide composition containing sulfur-fluorine oxime ether and part of organophosphorus pesticides | |
| CN101427682B (en) | Disinfection composition of mycophenolic ketone and dimethomorph | |
| CN106857560A (en) | A kind of new nematicide and its application | |
| CN101444221B (en) | Composite containing oxadiazines and pyrromonazole pesticide | |
| CN102210320A (en) | Sulfoxaflor-containing insecticidal composition | |
| CN103283740A (en) | Cyantraniliprole-containing pesticidal composition | |
| CN105494407A (en) | Herbicide composition containing metamifop and cafenstrole | |
| CN102037991B (en) | Composite pesticide containing abamectin and cidial | |
| CN102334488B (en) | Insect-killing and disease-preventing suspension seed coating formulation | |
| CN102037992A (en) | Pesticide composition containing abamectin and fenitrothion | |
| CN103518773B (en) | Insecticidal composition with synergism | |
| CN102326559A (en) | Weeding composition containing diflufenican and triazines | |
| CN102067875B (en) | Pesticide combination containing phenthoate and profenofos | |
| CN102037961B (en) | Sterilization composition containing mycophenolic ketone and fenoxanil | |
| CN109430264A (en) | It is a kind of containing terpenol, the microbicide compositions of chitosan and its preparation method and application | |
| CN108077286A (en) | A kind of Pesticidal combination containing ethyl pleocidin and butene-fipronil |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20110504 |