CN102027942A - Compounded herbicide composition for rice field - Google Patents
Compounded herbicide composition for rice field Download PDFInfo
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Abstract
The invention relates to a compounded herbicide composition for rice fields, which contains the following two effective components: component (A): pyribenzoxim; component (B): a herbicide which is one of the following compounds: triazines compounds, heterocyclic compounds, phenoxy compounds, amide compounds, diphoenyl ether compounds, sulfonylurea compounds, phenoxyalkanoic acid compounds, botanical compounds, organic phosphorus compounds, urea compounds, dinitroaniline compounds, benzamide compounds and carbamate compounds; and wherein, the weight ratio of the component (A) to the component (B) is 1-50: 1-50.
Description
Technical field
The present invention relates to pesticide field, more particularly, relate to a kind of paddy field compound herbicide composition.
Background technology
Preventing and kill off of paddy field weed is the key of agricultural foison, China's paddy rice cultivated area is bigger, the problem of preventing and kill off of weeds in field is very outstanding, because the variation of rice ecosystem and weeds pesticide resistance strengthen, the generation of weeds, harm have become the major obstacle that the restriction rice yield improves in recent years.
Therefore, this area presses for a kind of mixture of herbicides composition that can effectively enlarge the paddy field special use of killing grass spectrum, raising preventive effect of herbicide for paddy field of exploitation.
Summary of the invention
The invention provides a kind of efficient, low toxicity, broad weed-killing spectrum and paddy field herbicide composition specially safe in utilization, thereby solved problems of the prior art.
On the one hand, the invention provides a kind of paddy field compound herbicide composition, it comprises following two kinds of active ingredients:
Composition (A): pyribenzoxim;
Composition (B): weed killer herbicide, it is selected from a kind of in the following compound: compound in triazine class, heterocycle compound, benzene oxygen compounds, amides compound, diphenyl ether compound, sulfonyl urea compound, the phenoxy carboxylic acid compound, plant resource compound, organophosphorus compound, carbamide compounds, dinitroanilines, benzamides compound, and carbamate compound;
Wherein, described composition (A) is 1-50: 1-50 with the weight ratio of composition (B).
One preferred embodiment in, described compound in triazine class is selected from prometryn and symetryne,
Described heterocycle compound is selected from bentazone, clomazone and dichloro quinolinic acid,
Described benzene oxygen compounds Xuan Zi oxazole acyl grass amine,
Described amides compound is selected from mefenacet, alachlor, Acetochlor, propisochlor, third careless amine and the butachlor,
Described diphenyl ether compound is selected from Oxyfluorfen and cyhalofop-butyl,
Described sulfonyl urea compound is selected from that fluorine pyrrole sulphur is grand, AC322140, bensulfuron-methyl and ethoxy sulphur are grand,
Described phenoxy carboxylic acid compound is selected from 2 first, 4 chlorine sodium and 2, the 4-d butyl ester,
Described plant resource compound Xuan Zi oxazine humulone and pyriftalid,
Described organophosphorus compound is selected from anilofos,
Described carbamide compounds is selected from daimuron,
Described dinitroanilines is selected from pendimethalin,
Described benzamides compound is selected from KIH 6127,
Described carbamate compound is selected from molinate and benthiocarb.
Another preferred embodiment in, the weight ratio of described composition (A) and composition (B) is 1: 25 to 25: 1.
Another preferred embodiment in, the weight ratio of described composition (A) and composition (B) is 1: 5 to 5: 1.
Another preferred embodiment in, the weight ratio of described composition (A) and composition (B) is 1: 5.
Another preferred embodiment in, described composition also comprises auxiliary agent, solvent, mineral salt, antifreeze and solid carrier.
Another preferred embodiment in, described auxiliary agent is selected from emulsifier and surfactant;
Described solvent is selected from toluene, cyclohexanone, dimethylbenzene, phenol, trimethylbenzene, Solvesso 150#, Solvesso200#, Solvesso 100#, nonyl phenol, D-hesperidene, N-Methyl pyrrolidone, N-octylpyrrolidone, benzoic acid, acetophenone, DOW, BAC, turpentine oil, nicotinic acid, soya-bean oil, corn oil, White Mineral Oil, glycerine and oleic acid;
Described mineral salt are selected from sodium chloride, ammonium chloride, magnesium chloride, calcium chloride, copper chloride, zinc chloride, sodium sulphate, magnesium sulfate, aluminum sulfate, copper sulphate, calcium sulphate, sodium nitrate, aluminum nitrate, magnesium nitrate and nitrate of lime;
Described antifreeze is selected from diethylene glycol, ethylene glycol, propane diols, glycerine, polyethylene glycol and urea;
Described solid carrier is selected from bentonite, white carbon, kaolin, potter's clay, diatomite, starch and precipitated calcium carbonate.
Another preferred embodiment in, described emulsifier is selected from aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, the phenethyl phenol polyethenoxy ether, the alkylphenol polyoxyethylene formaldehyde condensation products, the aryl phenol APEO, the aryl phenol polyoxyethylene ether sulfate, alkylphenol polyoxyethylene sulphate, fatty alcohol polyoxyethylene ether sulfate, castor oil polyoxyethylene ether, calcium dodecyl benzene sulfonate, dodecyl benzyl dimethyl ammonium chloride, special OPEO, special OPEO sulphate, aryl polyoxyethylene polyoxypropylene ether sulfate, the random ether altogether of alkylaryl polyoxyethylene polyoxypropylene, alkylphenol polyoxyethylene, the coconut oil alkanolamide, polyoxyethylene stearic acid ester, polyoxyethylene stearic acid ester, the lauric acid polyoxyethylene ester, the lauric acid polyoxyethylene ester, fatty alcohol-polyoxyethylene ether, fatty alcohol phosphate, polyoxyethylene carboxylate, the newborn 500# of farming, the newborn 600# of farming, Nongru-700 #, farming breast 2201, farming breast 8209, farming breast 8316, farming breast 8312, farming breast 8210, the newborn NP-10 of farming, farming breast 0425, farming breast 0408, farming breast 3517, ALKAMULSOR/40, GERONOL CH/200, GERONOL CH/100, among GERONOL FF/4 and the CANTAROX B500 one or more; Described surfactant is selected from Negel, lignosulfonates and carboxymethyl cellulose.
Another preferred embodiment in, described composition is to be selected from down the formulation preparation of group: missible oil, emulsifiable concentrate, wetting powder, granule, oil-suspending agent, suspending agent and microcapsule formulations.
On the other hand, the present invention relates to above-mentioned compound herbicide composition is used for the weed killer herbicide of grassy weed, sedge family and broad leaved weed in preparation application.
Embodiment
The present inventor finds after having carried out extensive and deep research, by with specific ratio with pyribenzoxim and another kind of specific mixture of herbicides, its herbicide action and activity level have exceeded the stack of each component, have synergistic effect, to paddy field have efficient herbicidal effect, kill careless spectrum width, moderate to crop safety, cost.Based on above-mentioned discovery, the present invention is accomplished.
In a first aspect of the present invention, a kind of paddy field herbicide composition specially is provided, it is the preparation that is processed by pyribenzoxim, another kind of agricultural chemicals (weed killer herbicide), auxiliary agent, solvent or solid diluent etc.
In herbicidal composition of the present invention, active ingredient " pyribenzoxim ": the weight ratio of " another kind of agricultural chemicals (weed killer herbicide) " is 1-50: 1-50, preferred 1: 1 to 1: 50, and more preferably 1: 1 to 1: 25, most preferably 1: 5.
In the present invention, active ingredient " pyribenzoxim " belongs to acetolactate synthestase (ALS) inhibitor, selectivity efficient pyrimidine ether weed killer herbicide, be mainly used in and prevent and kill off the numerous grass family of paddy field, sedge family and broad leaved weed, can be used for preventing and kill off barnyard grass grass, Paspalum distichum, needle spikesedge herb, difformed galingale herb, Monochoria vaginalis, mexicana, pondweed, Li Intestinal etc.; Pure product are tasteless white solid, fusing point 128-130 ℃; Solvability in the water: 3.5ppm, pyribenzoxim acute LD 50 (mg/kg): rat oral＞5000 (female); Through skin mouse＞2000; To rabbit skin and eyes nonirritant; Animal there are not teratogenesis, mutagenesis, carcinogenesis.
In the present invention, active ingredient " another kind of agricultural chemicals (weed killer herbicide) " can be a kind of of following compound: prometryn, symetryne (triazines), bentazone clomazone, dichloro quinolinic acid (heterocyclic) oxazole acyl grass amine (benzene oxygen class), mefenacet, alachlor, Acetochlor, propisochlor, the third careless amine, butachlor (amide-type), Oxyfluorfen, cyhalofop-butyl (diphenyl ether), fluorine pyrrole sulphur is grand, AC322140, bensulfuron-methyl, ethoxy sulphur swells (sulfonylurea), 2 first, 4 chlorine sodium, 2,4-d butyl ester (phenoxy carboxylic acid) oxazine humulone, pyriftalid (plant resource), anilofos (organic phosphates), daimuron (ureas), pendimethalin (dinitroaniline), KIH 6127 (benzamides), molinate, benthiocarb (carbamates) etc.
In the present invention, described herbicidal composition also comprises auxiliary agent, and this auxiliary agent comprises surfactant (anion surfactant, non-ionic surface active agent), emulsifier etc.
In the present invention, described emulsifier can be an aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, the phenethyl phenol polyethenoxy ether, the alkylphenol polyoxyethylene formaldehyde condensation products, the aryl phenol APEO, the aryl phenol polyoxyethylene ether sulfate, alkylphenol polyoxyethylene sulphate, fatty alcohol polyoxyethylene ether sulfate, castor oil polyoxyethylene ether, calcium dodecyl benzene sulfonate, dodecyl benzyl dimethyl ammonium chloride, special OPEO, special OPEO sulphate, aryl polyoxyethylene polyoxypropylene ether sulfate, the random ether altogether of alkylaryl polyoxyethylene polyoxypropylene, alkylphenol polyoxyethylene, the coconut oil alkanolamide, polyoxyethylene stearic acid ester, polyoxyethylene stearic acid ester, the lauric acid polyoxyethylene ester, the lauric acid polyoxyethylene ester, fatty alcohol-polyoxyethylene ether, fatty alcohol phosphate, polyoxyethylene carboxylate, farming newborn 500# (company is changed very much in Nanjing), farming newborn 600# (company is changed very much in Nanjing), Nongru-700 # (Xingtai blue star company), farming breast 2201 (Xingtai blue star companies), farming breast 8209 (blue sky, Xingtai companies), farming breast 8316 (blue sky, Xingtai companies), farming breast 8312 (blue sky, Xingtai companies), farming breast 8210 (Handan Xin Diya companies), farming newborn NP-10 (company is changed very much in Nanjing), farming breast 0425 (Handan Xin Diya company), farming breast 0408 (Handan Xin Diya company), farming breast 3517 (Handan Xin Diya companies), ALKAMULS OR/40 (Rhodia), GERONOL CH/200 (Rhodia), GERONOL CH/100 (Rhodia), GERONOL FF/4 (Rhodia), the blended emulsifier of one or more among the CANTAROX B500 (Rhodia).
In the present invention, the surfactant of described dispersion usefulness can be Negel, lignosulfonates, carboxymethyl cellulose etc.
In the present invention, described herbicidal composition also comprises solvent, and described can be toluene, cyclohexanone, dimethylbenzene, phenol, trimethylbenzene, Solvesso 150# (Yangzhou Hua Lun company), Solvesso 200# (Yangzhou Hua Lun company), Solvesso 100# (Yangzhou Hua Lun company), nonyl phenol, D-hesperidene, N-Methyl pyrrolidone, N-octylpyrrolidone, benzoic acid, acetophenone, DOW (company is changed very much in Nanjing), BAC (company is changed very much in Nanjing), turpentine oil, nicotinic acid, soya-bean oil, corn oil, White Mineral Oil, glycerine, oleic acid etc.
In the present invention, described herbicidal composition also comprises mineral salt, and described mineral salt can be sodium chloride, ammonium chloride, magnesium chloride, calcium chloride, copper chloride, zinc chloride, sodium sulphate, magnesium sulfate, aluminum sulfate, copper sulphate, calcium sulphate, sodium nitrate, aluminum nitrate, magnesium nitrate, nitrate of lime etc.
In the present invention, described herbicidal composition also comprises antifreeze, and described antifreeze can be a kind of in diethylene glycol, ethylene glycol, propane diols, glycerine, polyethylene glycol and the urea.
In the present invention, described herbicidal composition also comprises solid carrier, and this solid carrier is bentonite, white carbon, kaolin, potter's clay, diatomite, starch, precipitated calcium carbonate etc.
In the present invention, described herbicidal composition can be selected from down the formulation preparation of group: missible oil, emulsifiable concentrate, wetting powder, granule, oil-suspending agent, suspending agent, microcapsule formulations etc.
Preferably, paddy field of the present invention comprises following two kinds of active ingredients with compound herbicide composition: pyribenzoxim is with clomazone, and its weight ratio is 1: 50 to 50: 1, and preferred 1: 25 to 25: 1, more preferably 1: 5.
Preferably, paddy field of the present invention comprises following two kinds of active ingredients with compound herbicide composition: pyribenzoxim and cyhalofop-butyl, its weight ratio are 1: 50 to 50: 1, preferred 1: 25 to 25: 1, and more preferably 1: 5.
Preferably, paddy field of the present invention comprises following two kinds of active ingredients with compound herbicide composition: pyribenzoxim is with oxazole acyl grass amine, and its weight ratio is 1: 50 to 50: 1, and preferred 1: 25 to 25: 1, more preferably 1: 5.
In a second aspect of the present invention, relate to said herbicidal composition is used for the weed killer herbicide of grassy weed, sedge family and broad leaved weed in preparation application.
Major advantage of the present invention is:
The herbicide action of herbicidal composition of the present invention and activity level have exceeded the stack of each independent component, have synergistic effect; Have efficient herbicidal effect simultaneously, kill careless spectrum width, moderate to crop safety, cost, and grassy weed, sedge family, broad leaved weed all had better control efficiency.
Below in conjunction with specific embodiment, further set forth the present invention.Should be understood that these embodiment only to be used to the present invention is described and be not used in and limit the scope of the invention.The experimental technique of unreceipted actual conditions in the following example, usually according to normal condition, or the condition of advising according to manufacturer.Unless indicate, otherwise all umbers are parts by weight that all percentages are weight percentage.
Embodiment 1:50% pyribenzoxim clomazone microcapsule formulations
Recipe ingredient is as follows: pyribenzoxim active ingredient, 1%; Clomazone active ingredient, 49%; Polyurethane, 20%; Polyethylene glycol, 2%; Carboxymethyl cellulose, 8%; Propane diols, 5%; Organosilicon, 0.2%; Water supplies 100%.
Drug effect report: grassy weed such as barnyard grass grass and part broadleaved herb, nutgrass flatsedge, 2 to 6 leaf phase dispensers, 20 days anti-effects of investigation strain behind the medicine, concrete outcome sees the following form:
* EC: missible oil
* CS: microcapsule formulations
Result of the test shows that pyribenzoxim helps increasing mutually drug effect Yu the composite back of clomazone herbicidal effect will be higher than any one single agent in the component, there is no antagonism, and enlarges grass spectrum extremely.
Embodiment 2:25% pyribenzoxim clomazone microcapsule formulations
Recipe ingredient is as follows: pyribenzoxim active ingredient, 1%; Clomazone active ingredient, 24%; Polyurethane, 6%; Polyethylene glycol, 8%; Carboxymethyl cellulose, 7%; Propane diols, 6%; Organosilicon, 0.2%; Water supplies 100%.
Drug effect report: grassy weed such as barnyard grass grass and part broadleaved herb, nutgrass flatsedge, 2 to 6 leaf phase dispensers, 20 days anti-effects of investigation strain behind the medicine, concrete outcome sees the following form:
Result of the test shows that pyribenzoxim helps increasing mutually drug effect Yu the composite back of clomazone herbicidal effect will be higher than any one single agent in the component, there is no antagonism, and enlarges grass spectrum extremely.
Embodiment 3:26% pyribenzoxim clomazone microcapsule formulations
Recipe ingredient is as follows: pyribenzoxim active ingredient, 4%; Clomazone active ingredient, 22%; Polyurethane, 8%; Polyethylene glycol, 8%; Carboxymethyl cellulose, 5%; Propane diols, 9%; Organosilicon, 0.2%; Water supplies 100%.
Drug effect report: grassy weed such as barnyard grass grass and part broadleaved herb, nutgrass flatsedge, 2 to 6 leaf phase dispensers, 20 days anti-effects of investigation strain behind the medicine, concrete outcome sees the following form:
Result of the test shows that pyribenzoxim helps increasing mutually drug effect Yu the composite back of clomazone herbicidal effect will be higher than any one single agent in the component, there is no antagonism, and enlarges grass spectrum extremely.
Embodiment 4:25% pyribenzoxim clomazone microcapsule formulations
Recipe ingredient is as follows: pyribenzoxim active ingredient, 24%; Clomazone active ingredient, 1%; Polyurethane, 6%; Polyethylene glycol, 6%; Carboxymethyl cellulose, 5%; Propane diols, 8%; Organosilicon, 0.2%; Water supplies 100%.
Drug effect report: grassy weed such as barnyard grass grass and part broadleaved herb, nutgrass flatsedge, 2 to 6 leaf phase dispensers, 20 days anti-effects of investigation strain behind the medicine, concrete outcome sees the following form:
Result of the test shows that pyribenzoxim helps increasing mutually drug effect Yu the composite back of clomazone herbicidal effect will be higher than any one single agent in the component, there is no antagonism, and enlarges grass spectrum extremely.
Embodiment 5:50% pyribenzoxim clomazone microcapsule formulations
Recipe ingredient is as follows: pyribenzoxim active ingredient, 49%; Clomazone active ingredient, 1%; Polyurethane, 5%; Polyethylene glycol, 3%; Carboxymethyl cellulose, 7%; Propane diols, 6%; Organosilicon, 0.2%; Water supplies 100%.
Drug effect report: grassy weed such as barnyard grass grass and part broadleaved herb, nutgrass flatsedge, 2 to 6 leaf phase dispensers, 20 days anti-effects of investigation strain behind the medicine, concrete outcome sees the following form:
Result of the test shows that pyribenzoxim helps increasing mutually drug effect Yu the composite back of clomazone herbicidal effect will be higher than any one single agent in the component, there is no antagonism, and enlarges grass spectrum extremely.
Embodiment 6:50% pyribenzoxim cyhalofop-butyl microemulsion
Recipe ingredient is as follows: pyribenzoxim active ingredient, 1%; Cyhalofop-butyl active ingredient, 49%; Calcium dodecyl benzene sulfonate, 5%; Castor oil polyoxyethylene ether, 12%; Ethylene glycol, 9%; Organosilicon, 0.2%; Water supplies 100%.
Drug effect report: grassy weed such as barnyard grass grass and part broadleaved herb, nutgrass flatsedge, 2 to 6 leaf phase dispensers, 20 days anti-effects of investigation strain behind the medicine, concrete outcome sees the following form:
* ME: microemulsion
Result of the test shows that the composite back of pyribenzoxim and cyhalofop-butyl herbicidal effect will be higher than any one single agent in the component, helps increasing mutually drug effect, there is no antagonism, and enlarges grass spectrum extremely.
Embodiment 7:25% pyribenzoxim cyhalofop-butyl microemulsion
Recipe ingredient is as follows: pyribenzoxim active ingredient, 1%; Cyhalofop-butyl active ingredient, 24%; Calcium dodecyl benzene sulfonate, 7%; Castor oil polyoxyethylene ether, 12%; Ethylene glycol, 8%; Organosilicon, 0.2%; Water supplies 100%.
Drug effect report: grassy weed such as barnyard grass grass and part broadleaved herb, nutgrass flatsedge, 2 to 6 leaf phase dispensers, 20 days anti-effects of investigation strain behind the medicine, concrete outcome sees the following form:
Result of the test shows that the composite back of pyribenzoxim and cyhalofop-butyl herbicidal effect will be higher than any one single agent in the component, helps increasing mutually drug effect, there is no antagonism, and enlarges grass spectrum extremely.
Embodiment 8:9% pyribenzoxim cyhalofop-butyl microemulsion
Recipe ingredient is as follows: pyribenzoxim active ingredient, 2%; Cyhalofop-butyl active ingredient, 7%; Calcium dodecyl benzene sulfonate, 6%; Castor oil polyoxyethylene ether, 10%; Ethylene glycol, 9%; Organosilicon, 0.2%; Water supplies 100%.
Drug effect report: grassy weed such as barnyard grass grass and part broadleaved herb, nutgrass flatsedge, 2 to 6 leaf phase dispensers, 20 days anti-effects of investigation strain behind the medicine, concrete outcome sees the following form:
Result of the test shows that the composite back of pyribenzoxim and cyhalofop-butyl herbicidal effect will be higher than any one single agent in the component, helps increasing mutually drug effect, there is no antagonism, and enlarges grass spectrum extremely.
Embodiment 9:25% pyribenzoxim cyhalofop-butyl microemulsion
Recipe ingredient is as follows: pyribenzoxim active ingredient, 24%; Cyhalofop-butyl active ingredient, 1%; Calcium dodecyl benzene sulfonate, 7%; Castor oil polyoxyethylene ether, 8%; Ethylene glycol, 9%; Organosilicon, 0.2%; Water supplies 100%.
Drug effect report: grassy weed such as barnyard grass grass and part broadleaved herb, nutgrass flatsedge, 2 to 6 leaf phase dispensers, 20 days anti-effects of investigation strain behind the medicine, concrete outcome sees the following form:
Result of the test shows that the composite back of pyribenzoxim and cyhalofop-butyl herbicidal effect will be higher than any one single agent in the component, helps increasing mutually drug effect, there is no antagonism, and enlarges grass spectrum extremely.
Embodiment 10:50% pyribenzoxim cyhalofop-butyl microemulsion
Recipe ingredient is as follows: pyribenzoxim active ingredient, 50%; Cyhalofop-butyl active ingredient, 1%; Calcium dodecyl benzene sulfonate, 6.4%; Castor oil polyoxyethylene ether, 9%; Ethylene glycol, 9%; Organosilicon, 0.2%; Water supplies 100%.
Drug effect report: grassy weed such as barnyard grass grass and part broadleaved herb, nutgrass flatsedge, 2 to 6 leaf phase dispensers, 20 days anti-effects of investigation strain behind the medicine, concrete outcome sees the following form:
Result of the test shows that the composite back of pyribenzoxim and cyhalofop-butyl herbicidal effect will be higher than any one single agent in the component, helps increasing mutually drug effect, there is no antagonism, and enlarges grass spectrum extremely.
Embodiment 11:50% Mi pyridine oxime Cao Mi oxazole acyl grass amine missible oil
Recipe ingredient is as follows: pyribenzoxim active ingredient, 1%; Oxazole acyl grass amine active ingredient, 49%; Calcium dodecyl benzene sulfonate, 10%; Castor oil polyoxyethylene ether, 5%; Trimethylbenzene supplies 100%.
Drug effect report: grassy weed such as barnyard grass grass and part broadleaved herb, nutgrass flatsedge, 2 to 6 leaf phase dispensers, 20 days anti-effects of investigation strain behind the medicine, concrete outcome sees the following form:
Result of the test shows that pyribenzoxim helps increasing mutually drug effect Yu the composite back of oxazole acyl grass amine herbicidal effect will be higher than any one single agent in the component, there is no antagonism, and enlarges grass spectrum extremely.
Embodiment 12:25% Mi pyridine oxime Cao Mi oxazole acyl grass amine missible oil
Recipe ingredient is as follows: pyribenzoxim active ingredient, 1%; Oxazole acyl grass amine active ingredient, 24%; Calcium dodecyl benzene sulfonate, 7%; Castor oil polyoxyethylene ether, 6%; Trimethylbenzene supplies 100%.
Drug effect report: grassy weed such as barnyard grass grass and part broadleaved herb, nutgrass flatsedge, 2 to 6 leaf phase dispensers, 20 days anti-effects of investigation strain behind the medicine, concrete outcome sees the following form:
Result of the test shows that pyribenzoxim helps increasing mutually drug effect Yu the composite back of oxazole acyl grass amine herbicidal effect will be higher than any one single agent in the component, there is no antagonism, and enlarges grass spectrum extremely.
Embodiment 13:10% Mi pyridine oxime Cao Mi oxazole acyl grass amine missible oil
Recipe ingredient is as follows: pyribenzoxim active ingredient, 2%; Oxazole acyl grass amine active ingredient, 8%; Calcium dodecyl benzene sulfonate, 5%; Castor oil polyoxyethylene ether, 5%; Trimethylbenzene supplies 100%.
Drug effect report: grassy weed such as barnyard grass grass and part broadleaved herb, nutgrass flatsedge, 2 to 6 leaf phase dispensers, 20 days anti-effects of investigation strain behind the medicine, concrete outcome sees the following form:
Result of the test shows that pyribenzoxim helps increasing mutually drug effect Yu the composite back of oxazole acyl grass amine herbicidal effect will be higher than any one single agent in the component, there is no antagonism, and enlarges grass spectrum extremely.
Embodiment 14:25% Mi pyridine oxime Cao Mi oxazole acyl grass amine missible oil
Recipe ingredient is as follows: pyribenzoxim active ingredient, 24%; Oxazole acyl grass amine active ingredient, 1%; Calcium dodecyl benzene sulfonate, 6.5%; Castor oil polyoxyethylene ether, 5.5%; Trimethylbenzene supplies 100%.
Drug effect report: grassy weed such as barnyard grass grass and part broadleaved herb, nutgrass flatsedge, 2 to 6 leaf phase dispensers, 20 days anti-effects of investigation strain behind the medicine, concrete outcome sees the following form:
Result of the test shows that pyribenzoxim helps increasing mutually drug effect Yu the composite back of oxazole acyl grass amine herbicidal effect will be higher than any one single agent in the component, there is no antagonism, and enlarges grass spectrum extremely
Embodiment 15:50% Mi pyridine oxime Cao Mi oxazole acyl grass amine missible oil
Recipe ingredient is as follows: pyribenzoxim active ingredient, 49%; Oxazole acyl grass amine active ingredient, 1%; Calcium dodecyl benzene sulfonate, 12%; Castor oil polyoxyethylene ether, 8%; Trimethylbenzene supplies 100%.
Drug effect report: grassy weed such as barnyard grass grass and part broadleaved herb, nutgrass flatsedge, 2 to 6 leaf phase dispensers, 20 days anti-effects of investigation strain behind the medicine, concrete outcome sees the following form:
Result of the test shows that pyribenzoxim helps increasing mutually drug effect Yu the composite back of oxazole acyl grass amine herbicidal effect will be higher than any one single agent in the component, there is no antagonism, and enlarges grass spectrum extremely.
Though for the purpose that is aware and understand, the present invention is described in detail, but after having read present specification, those skilled in the art will be appreciated that, under the prerequisite that does not depart from spirit of the present invention and essence, can carry out various modifications and change to the present invention, these modifications and change all fall within the included scope of appended claims and content of equal value thereof.
Claims (10)
1. paddy field compound herbicide composition, it comprises following two kinds of active ingredients:
Composition (A): pyribenzoxim;
Composition (B): weed killer herbicide, it is selected from a kind of in the following compound: compound in triazine class, heterocycle compound, benzene oxygen compounds, amides compound, diphenyl ether compound, sulfonyl urea compound, the phenoxy carboxylic acid compound, plant resource compound, organophosphorus compound, carbamide compounds, dinitroanilines, benzamides compound, and carbamate compound;
Wherein, described composition (A) is 1-50: 1-50 with the weight ratio of composition (B).
2. composition as claimed in claim 1 is characterized in that,
Described compound in triazine class is selected from prometryn and symetryne,
Described heterocycle compound is selected from bentazone, clomazone and dichloro quinolinic acid,
Described benzene oxygen compounds Xuan Zi oxazole acyl grass amine,
Described amides compound is selected from mefenacet, alachlor, Acetochlor, propisochlor, third careless amine and the butachlor,
Described diphenyl ether compound is selected from Oxyfluorfen and cyhalofop-butyl,
Described sulfonyl urea compound is selected from that fluorine pyrrole sulphur is grand, AC322140, bensulfuron-methyl and ethoxy sulphur are grand,
Described phenoxy carboxylic acid compound is selected from 2 first, 4 chlorine sodium and 2, the 4-d butyl ester,
Described plant resource compound Xuan Zi oxazine humulone and pyriftalid,
Described organophosphorus compound is selected from anilofos,
Described carbamide compounds is selected from daimuron,
Described dinitroanilines is selected from pendimethalin,
Described benzamides compound is selected from KIH 6127,
Described carbamate compound is selected from molinate and benthiocarb.
3. composition as claimed in claim 1 or 2 is characterized in that, described composition (A) is 1: 25 to 25: 1 with the weight ratio of composition (B).
4. composition as claimed in claim 1 or 2 is characterized in that, described composition (A) is 1: 5 to 5: 1 with the weight ratio of composition (B).
5. composition as claimed in claim 1 or 2 is characterized in that, described composition (A) is 1: 5 with the weight ratio of composition (B).
6. composition as claimed in claim 1 or 2 is characterized in that described composition also comprises auxiliary agent, solvent, mineral salt, antifreeze and solid carrier.
7. composition as claimed in claim 6 is characterized in that,
Described auxiliary agent is selected from emulsifier and surfactant;
Described solvent is selected from toluene, cyclohexanone, dimethylbenzene, phenol, trimethylbenzene, Solvesso 150#, Solvesso200#, Solvesso 100#, nonyl phenol, D-hesperidene, N-Methyl pyrrolidone, N-octylpyrrolidone, benzoic acid, acetophenone, DOW, BAC, turpentine oil, nicotinic acid, soya-bean oil, corn oil, White Mineral Oil, glycerine and oleic acid;
Described mineral salt are selected from sodium chloride, ammonium chloride, magnesium chloride, calcium chloride, copper chloride, zinc chloride, sodium sulphate, magnesium sulfate, aluminum sulfate, copper sulphate, calcium sulphate, sodium nitrate, aluminum nitrate, magnesium nitrate and nitrate of lime;
Described antifreeze is selected from diethylene glycol, ethylene glycol, propane diols, glycerine, polyethylene glycol and urea;
Described solid carrier is selected from bentonite, white carbon, kaolin, potter's clay, diatomite, starch and precipitated calcium carbonate.
8. composition as claimed in claim 7, it is characterized in that described emulsifier is selected from aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, the phenethyl phenol polyethenoxy ether, the alkylphenol polyoxyethylene formaldehyde condensation products, the aryl phenol APEO, the aryl phenol polyoxyethylene ether sulfate, alkylphenol polyoxyethylene sulphate, fatty alcohol polyoxyethylene ether sulfate, castor oil polyoxyethylene ether, calcium dodecyl benzene sulfonate, dodecyl benzyl dimethyl ammonium chloride, special OPEO, special OPEO sulphate, aryl polyoxyethylene polyoxypropylene ether sulfate, the random ether altogether of alkylaryl polyoxyethylene polyoxypropylene, alkylphenol polyoxyethylene, the coconut oil alkanolamide, polyoxyethylene stearic acid ester, polyoxyethylene stearic acid ester, the lauric acid polyoxyethylene ester, the lauric acid polyoxyethylene ester, fatty alcohol-polyoxyethylene ether, fatty alcohol phosphate, polyoxyethylene carboxylate, the newborn 500# of farming, the newborn 600# of farming, Nongru-700 #, farming breast 2201, farming breast 8209, farming breast 8316, farming breast 8312, farming breast 8210, the newborn NP-10 of farming, farming breast 0425, farming breast 0408, farming breast 3517, ALKAMULS OR/40, GERONOL CH/200, GERONOL CH/100, among GERONOL FF/4 and the CANTAROX B500 one or more;
Described surfactant is selected from Negel, lignosulfonates and carboxymethyl cellulose.
9. composition as claimed in claim 1 or 2 is characterized in that, described composition is to be selected from down the formulation preparation of group: missible oil, emulsifiable concentrate, wetting powder, granule, oil-suspending agent, suspending agent and microcapsule formulations.
10. each described compound herbicide composition is used for the application of the weed killer herbicide of grassy weed, sedge family and broad leaved weed among the claim 1-9 in preparation.
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1725952A (en) * | 2002-11-21 | 2006-01-25 | 辛根塔参与股份公司 | Herbicidal composition |
| CN101473823A (en) * | 2008-12-18 | 2009-07-08 | 孙家隆 | Herbicidal composition containing pyribenzoxim and picolinafen |
-
2010
- 2010-12-30 CN CN2010106142493A patent/CN102027942A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1725952A (en) * | 2002-11-21 | 2006-01-25 | 辛根塔参与股份公司 | Herbicidal composition |
| CN101473823A (en) * | 2008-12-18 | 2009-07-08 | 孙家隆 | Herbicidal composition containing pyribenzoxim and picolinafen |
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