CN106489957A - A kind of rice direct seeding field ternary weeding composition containing bentazone - Google Patents

A kind of rice direct seeding field ternary weeding composition containing bentazone Download PDF

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Publication number
CN106489957A
CN106489957A CN201610862101.9A CN201610862101A CN106489957A CN 106489957 A CN106489957 A CN 106489957A CN 201610862101 A CN201610862101 A CN 201610862101A CN 106489957 A CN106489957 A CN 106489957A
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China
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bentazone
cyhalofop
butyl
direct seeding
rice
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黄自云
吴电亮
张建邦
马伦冬
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ANHUI ZHONGBANG BIOLOGICAL ENGINEERING Co Ltd
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ANHUI ZHONGBANG BIOLOGICAL ENGINEERING Co Ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/88Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N39/00Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
    • A01N39/02Aryloxy-carboxylic acids; Derivatives thereof
    • A01N39/04Aryloxy-acetic acids; Derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/541,3-Diazines; Hydrogenated 1,3-diazines

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention discloses a kind of rice direct seeding field ternary weeding composition containing bentazone, including effective ingredient, the effective ingredient is cyhalofop-butyl, bentazone and pyribenzoxim, and the mass ratio of the cyhalofop-butyl, bentazone and pyribenzoxim is 1~20: 10~50: 1~10.The Herbicidal combinations of the rice direct seeding field of the present invention have potentiation, sprayed within 10 days or so after being mainly used in rice direct seeding field transfer, the grassy weeds such as rice direct seeding field barnyard grass prevailing, Semen Euphorbiae are prevented and kill off, also and the sedge weeds such as broad leaved weed and Herba Eleocharitis aciculariies, Herba Cyperi Difformiss such as other mexicanas, Herba sagittariae pygmaeae, Herba Euphorbiae Helioscopiae grass can be prevented.The characteristics of there is activity of weeding height, broad weed-killing spectrum, convenient use, and to rice safety.

Description

A kind of rice direct seeding field ternary weeding composition containing bentazone
Technical field
The invention belongs to pesticide herbicide technical field, more particularly to a kind of rice direct seeding field ternary weeding containing bentazone Compositionss.
Background technology
Oryza sativa L. is one of staple food crop of China, and its sown area accounts for the 18.5% of national total sown area, rice Paddy yield accounts for the 39.23% of total grain output, therefore the very important impact of the increase and decrease tool of the yield of Oryza sativa L..But all the time, respectively Class weeds have impact on the yield of Oryza sativa L., according to investigations, field its Rice Yield Loss Caused of weed encroachment typically in 10-20%, seriously Loss 40-50%.In recent years, a kind of saving of labor, the planting patternss direct seading rice of water saving rise rapidly, and its management of weeds is more aobvious Must be even more important, wherein affect larger and comparison difficult anti-be the grassy weeds such as barnyard grass, Semen Euphorbiae, next to that Herba monochoriae vaginaliss, section The broad leaved weeds such as section dish, potamogeton grass.Herbicide for paddy field development is more delayed, and kind is few, and the wider of application is the phonetic sulphur of benzyl Grand, Acetochlor, MCPA,MCP,methoxone etc., but as these service life of the products are longer, weeds generate drug resistance, and they are to barnyard grass The effect of careless, Semen Euphorbiae is unsatisfactory.
Cyhalofop-butyl is that there is tight security to Oryza sativa L. (transplanting and live) uniquely in fragrant phenoxy phenoxy propionic acid herbicide Kind, to Oryza sativa L. etc. with excellent selectivity, selectivity is based on different accretion rates.In Oryza sativa L. body, cyhalofop-butyl Can be degraded quickly being two acid-state inactive to acetyl-CoA carboxylase, thus there is to Oryza sativa L. the safety of height.Because of which In soil and in typical paddy field water, degraded is rapid, therefore makees safety to rear.It is mainly used in preventing and kill off important grassy weed.Cyanogen Fluorine grass ester is not only efficient to various barnyard grasses (including above the average age for marriage barnyard grass), can also prevent and kill off Semen Euphorbiae, Herba Digitariae, Paspalum distichum, Herba Setariae Viridis, cattle Muscle grass, amur foxtail etc..
It is red that bentazone is called bentazone, Herba lysimachiae capillipedis.It is a kind of selective killing type herbicide after seedling, for weeds seedling stage stem Leaf process.It is mainly used in the crops such as Oryza sativa L., Semen sojae atricolor, Semen arachidis hypogaeae, Semen Tritici aestivi, prevents and kill off broad leaved weed and sedge weed, miscellaneous to grass family Grass is invalid.
Pyribenzoxim is a kind of novel oxime ester compound, wide spectrum selective post-emergence herbicide.Mechanism of action and sulphur Sulfonylurea herbicide is similar, belongs to acetolactate synthestase (ALS) inhibitor.There is selectivity to Oryza sativa L., common wheat, Korea lawn grass Activity of weeding after ultra high efficiency bud, without activity of weeding before bud, miscellaneous for preventing and kill off the various grass family such as barnyard grass, big fringe amur foxtail, Herba polygoni hydropiperis Grass and miscellaneous stroke of effect of broad-leaved are distinguished, to Oryza sativa L., common wheat safety.
Content of the invention
The purpose of the present invention be just be to provide a kind of potentiation significantly, the rice direct seeding field containing bentazone of broad weed-killing spectrum Ternary weeding composition.
The below scheme of taking of the present invention is realized:
A kind of rice direct seeding field ternary weeding composition containing bentazone, the Herbicidal combinations include effective ingredient, institute Effective ingredient is stated for cyhalofop-butyl, bentazone and pyribenzoxim, the quality of the cyhalofop-butyl, bentazone and pyribenzoxim Than for 1~20: 10~50: 1~10.
Further scheme, the mass ratio of the cyhalofop-butyl, bentazone and pyribenzoxim is 4~20: 12~50: 2~ 10, optimum for 8:20:2.
Further scheme, the Herbicidal combinations are also containing agriculturally acceptable surfactant and carrier.
Further scheme, the dosage form of the Herbicidal combinations are wettable powder, dispersible oil-suspending agent or water dispersible Granule.
In Herbicidal combinations of the present invention, active component is cyhalofop-butyl, bentazone and pyribenzoxim, and its consumption depends on Respective amount of application and three's portfolio ratio and potentiation degree during exclusive use, special protection of the present invention cyhalofop-butyl, go out The mass ratio of careless pine and pyribenzoxim is 1~20: 10~50: 1~10, and optimal proportioning is 8:20:2.
The Herbicidal combinations of the present invention, can add agriculturally acceptable surfactant and carrier, be made into wettability Powder, dispersible oil-suspending agent, water dispersible granules etc..Wherein surfactant is alkylphenol polyoxyethylene, fatty alcohol polyoxy Vinyl Ether, phenethyl phenol polyethenoxy ether, phenethyl phenol polyoxyethylene poly-oxygen propylene aether, Oleum Ricini ethylene oxide adduct, alkane Base phenol polyethenoxy ether formaldehyde condensation products, alkylphenol polyoxyethylene phosphate ester, phenethyl phenol polyethenoxy ether phosphate ester, benzyl Phenol polyethenoxy ether, polyoxyethylene carboxylate, calcium dodecyl benzene sulfonate, dodecylbenzene sodium sulfonate, lignosulfonates, NNO, NO, MF, ZS 1, sodium lauryl sulphate, pull open powder, N- Methyl fatty acyl taurines sodium, alkylphenol polyoxyethylene Formaldehyde condensation products sulfate, tea seed cake powder, Saponin, lignosulfite, aliphatic alcohol sulfate, penetrant t, penetrating agent OT, JFC, fatty acid amide N N-methyltaurine sodium salts, polyoxyethylenated alcohol sodium sulfate, pull open powder etc..
Carrier is divided into solid carrier and solvent, and solid carrier has bentonite, White Carbon black, Kaolin, precipitated calcium carbonate, sulphuric acid Sodium, ammonium sulfate, kieselguhr, starch, potter's clay etc.;Solvent have toluene, dimethylbenzene, chlorobenzene, solvent naphtha, α methyl naphthalenes, Oleum Terebinthinae, Dichloromethane, chloroform, methanol, ethanol, glycerol, ethylene glycol, butanol, isoamyl alcohol, Propylene Glycol, Ketohexamethylene, isophorone, 1-Phenylethanone., ethyl acetate, propyl acetate, butyl acetate, DMF, DMSO, cellosolve etc., above-mentioned can be used alone, also can two kinds with Upper compound use.
Any of the above auxiliary agent or carrier are commercially available.
The Herbicidal combinations of the rice direct seeding field of the present invention have addition or potentiation, are mainly used in rice direct seeding field shifting Sprayed within 10 days or so after load, prevented and kill off the grassy weeds such as rice direct seeding field barnyard grass prevailing, Semen Euphorbiae, also and other can be prevented The sedge weed such as broad leaved weed and Herba Eleocharitis aciculariies, Herba Cyperi Difformiss such as mexicana, Herba sagittariae pygmaeae, Herba Euphorbiae Helioscopiae grass.There is activity of weeding height, herbicide Spectrum is wide, the characteristics of convenient use, and to rice safety, belongs to environmentally friendly herbicide.
Specific embodiment
The present invention is further illustrated with the specific embodiment of several different dosage forms below.But the present invention is only limitted to absolutely not this A little examples.In all formula, percentage ratio is weight fraction.
First, form formula example:
Embodiment 1,22% dispersible oil-suspending agent:
Cyhalofop-butyl 4%
Bentazone 16%
Pyribenzoxim 2%
Castor oil polyoxyethylene ether 10%
Methyl oleate polishing is to 100%.
Embodiment 2,25% dispersible oil-suspending agent:
Cyhalofop-butyl 6%
Bentazone 15%
Pyribenzoxim 4%
Calcium lignosulfonate 5%
Sorbester p17 7%
Methyl oleate polishing is to 100%.
Embodiment 3,30% dispersible oil-suspending agent:
Embodiment 4,40% wettable powder
Embodiment 5,60% wettable powder
Embodiment 6,80% wettable powder
Embodiment 7,50% water dispersible granules
Embodiment 8,45% water dispersible granules
Embodiment 9,75% water dispersible granules
2nd, indoor biological determination of activity:
Paddy field weed indoor biological is lived below by way of cyhalofop-butyl, bentazone, pyribenzoxim compositionss herbicide Property determine to verify the reasonability of formula.
In the present composition, cyhalofop-butyl (97% active compound) is produced by Jiangsu Zhongqi Chemical Industry Co., Ltd, bentazone (95% active compound) is produced by Lulilai Co., Ltd., Jiangsu, and pyribenzoxim (95% active compound) is had by Korea's LG life sciences Limit company produces.
Test method is using greenhouse pot culture method, sows quantitative weeds (per 40 plants of basin) and rice paddy seed, treat in basin When weeds are grown to the 2-4 leaf phases after being unearthed, stem and leaf spraying treatment is carried out with spraying machine, be placed in greenhouse and continue after process after 6 hours Culture observation, investigates the preventive effect to weeds and the safety to Oryza sativa L. after 15 days.Investigation method adopts absolute value survey method, The fresh weight of per basin remaining weeds, then the fresh weight preventive effect that by following equation calculate each process are first investigated:E=(C-T)/C × 100%, In formula, E is fresh weight preventive effect, and for compareing weeds fresh weight, T is process weeds fresh weight to C.Then weeds activity is examined with Colby methods Survey the co-toxicity to weeds to act on, by Colby methods, work as E0-E>10% is potentiation;Work as E0-E<- 10% is antagonism; As -10%≤E0- E≤10% is addition.
Wherein:1. cyhalofop-butyl, bentazone, pyribenzoxim compound the E to barnyard grass0- E value for 11.92---33.78 it Between, its synergy type be potentiation, with cyhalofop-butyl, bentazone, pyribenzoxim weight ratio as 8:20:2 effect Fruit is most obvious, E0- E values are 33.78, and concrete data are as shown in table 1:
Table 1:Co-toxicity effect (nebulization) of the Herbicidal combinations to barnyard grass
2. cyhalofop-butyl, bentazone, pyribenzoxim compounding are as shown in table 2 to the co-toxicity effect of Semen Euphorbiae, its E0- Between 14.18~29.86, synergy type is potentiation to E, with cyhalofop-butyl, bentazone, pyribenzoxim weight Than for 8:20:2 effect is most obvious, E0- E values 29.86.
Table 2:Herbicidal combinations are acted on to the co-toxicity of Semen Euphorbiae
Note:In upper table 1,2, proportioning is weight ratio.
3rd, test examples:
1. trial crops and object:For studying thing for rice direct seeding field, subjects are based on barnyard grass, Semen Euphorbiae etc. Grassy weed and small part Herba Caricis Phacotae and Herba monochoriae vaginaliss etc..
Test medicine:3 Chinese medicine of embodiment:30% cyanogen fluorine goes out, and (8% cyhalofop-butyl 20% goes out pyrimidine oil-suspending agent Loose 2% pyribenzoxim of grass) (our company's production);
Comparison medicament:480 grams per liters bentazone water preparation (Lulilai Co., Ltd., Jiangsu);
100 grams per liter cyhalofop-butyl missible oils (Nong Ke limited companies of Guangdong CTC (Centell Technology Corporation));
5% pyribenzoxim cream (Shanghai Lvze Bio-technology Co., Ltd.).
Spraying time and method:The test then dispenser of June 25 in 2015, one heart stage of 3~4 leaf of Oryza sativa L. at that time, barnyard grass 4~ One heart stage of 5 leaf, one heart stage of 2~3 leaf of Semen Euphorbiae, routinely every mu of preparating liquid 15KG sprayed, after dispenser within 6 hours not See there is rainfall.
Control time and number of times:Before dispenser investigate weeds radix, after dispenser 2,3 days observation treatment region rice shoot leaf color, Upgrowth situation, is itemized record if any exception.7 days after dispenser, (on July 2nd, 2015), 10 days (on July 5th, 2015) adjust respectively Look into plant preventive effect and weeds overground part fresh weight.
Investigation method:Using 5 point samplings, each cell random selection 5 point of investigation, every area 0.25m2, dispenser 7 Investigate the strain number of two kinds of main weeds and total weed after it respectively, simultaneously investigate after 10 days the strain number of all kinds of weeds and total weed with And overground part fresh weight, calculate decline rate and anti-efficiency.
Drug effect computational methods are as follows:
In above formula, CK represents that clear water is compareed.
Table 3:Prevent and kill off rice direct seeding field Weed-control effect table
Interpretation of result:30% cyanogen fluorine goes out pyrimidine oil-suspending agent direct sowing of rice field weed to total weed preventive effect effect, medicine After 10 days, 30% cyanogen fluorine goes out the preventive effect highest of pyrimidine oil-suspending agent, and average decline rate is up to 90.55%, averagely prevents and kill off rate For 91.78%.The average decline rate of 5% pyribenzoxim cream and 100 grams per liter cyhalofop-butyl missible oils be 75.37%, 72.21%, both averagely prevent and kill off rate difference 71.82%, 66.08%, and the average decline rate of 480 grams per liter bentazone water preparations is only Up to 63.17%, rate is averagely prevented and kill off for 57.56%.Illustrate that 30% cyanogen fluorine goes out pyrimidine oil-suspending agent to direct sowing of rice field weed Prevention effect apparently higher than cyhalofop-butyl, bentazone, pyribenzoxim single dose effect, therefore have preferable popularization and application Prospect.
2nd, trial crops and object:For studying thing for rice direct seeding field, subjects are based on barnyard grass, Semen Euphorbiae etc. Grassy weed and small part Herba Caricis Phacotae and Herba monochoriae vaginaliss etc..
Test medicine:5 Chinese medicine of embodiment:60% wettable powder (20% cyhalofop-butyl, 30% bentazone 10% Pyribenzoxim) (our company's production);
Comparison medicament:480 grams per liters bentazone water preparation (Lulilai Co., Ltd., Jiangsu);
100 grams per liter cyhalofop-butyl missible oils (Nong Ke limited companies of Guangdong CTC (Centell Technology Corporation));
5% pyribenzoxim cream (Shanghai Lvze Bio-technology Co., Ltd.).
Spraying time and method:Test in the dispenser of June 25 in 2015, at that time one heart stage of 3~4 leaf of Oryza sativa L., barnyard grass 4~5 One heart stage of leaf, one heart stage of 2~3 leaf of Semen Euphorbiae, routinely every mu of preparating liquid 15KG sprayed, after dispenser within 6 hours not See there is rainfall.
Control time and number of times:Before dispenser investigate weeds radix, after dispenser 2,3 days observation treatment region rice shoot leaf color, Upgrowth situation, is itemized record if any exception.7 days after dispenser, (on July 2nd, 2015), 10 days (on July 5th, 2015) adjust respectively Look into plant preventive effect and weeds overground part fresh weight.
Investigation method:Using 5 point samplings, each cell random selection 5 point of investigation, every area 0.25m2, dispenser 7 Investigate the strain number of two kinds of main weeds and total weed after it respectively, simultaneously investigate after 10 days the strain number of all kinds of weeds and total weed with And overground part fresh weight, calculate decline rate and anti-efficiency.
Drug effect computational methods are as follows:
In above formula, CK represents that clear water is compareed.
Table 4:Prevent and kill off rice direct seeding field Weed-control effect table
Interpretation of result:60% wettable powder direct sowing of rice field weed is to total weed preventive effect effect, anti-after medication 10 days Effect highest, average decline rate are up to 87.49%, averagely prevent and kill off rate for 90.26%.100 grams per liter cyhalofop-butyl missible oil % and 5% The average decline rate of pyribenzoxim cream be 72.36%, 68.55%, both averagely prevent and kill off rate difference 83.24%, 81.27%, and the average decline rate only up to 52.78% of 480 grams per liter bentazone water preparations, rate is averagely prevented and kill off for 73.83%.Explanation The prevention effect of the live field weed of 60% WP on Rice is apparently higher than bentazone, cyhalofop-butyl, pyribenzoxim Single dose effect, therefore has preferable popularizing application prospect.
3rd, trial crops and object:For studying thing for rice direct seeding field, subjects are based on barnyard grass, Semen Euphorbiae etc. Grassy weed and small part Herba monochoriae vaginaliss and Herba Caricis Phacotae etc..
Test medicine:8 Chinese medicine of embodiment:45% water dispersible granules (15% cyhalofop-butyl, 20% bentazone 10% Pyribenzoxim) (our company's production);
Comparison medicament:480 grams per liters bentazone water preparation (Lulilai Co., Ltd., Jiangsu);
100 grams per liter cyhalofop-butyl missible oils (Nong Ke limited companies of Guangdong CTC (Centell Technology Corporation));
5% pyribenzoxim cream (Shanghai Lvze Bio-technology Co., Ltd.).
Spraying time and method:The test then dispenser of June 25 in 2015, one heart stage of 3~4 leaf of Oryza sativa L. at that time, barnyard grass 4~ One heart stage of 5 leaf, one heart stage of 2~3 leaf of Semen Euphorbiae, routinely every mu of preparating liquid 15KG sprayed, after dispenser within 6 hours not See there is rainfall.
Control time and number of times:Before dispenser investigate weeds radix, after dispenser 2,3 days observation treatment region rice shoot leaf color, Upgrowth situation, is itemized record if any exception.7 days after dispenser, (on July 2nd, 2015), 10 days (on July 5th, 2015) adjust respectively Look into plant preventive effect and weeds overground part fresh weight.
Investigation method:Using 5 point samplings, each cell random selection 5 point of investigation, every area 0.25m2, dispenser 7 Investigate the strain number of two kinds of main weeds and total weed after it respectively, simultaneously investigate after 10 days the strain number of all kinds of weeds and total weed with And overground part fresh weight, calculate decline rate and anti-efficiency.
Drug effect computational methods are as follows:
In above formula, CK represents that clear water is compareed.
Table 5:Prevent and kill off rice direct seeding field Weed-control effect table
Interpretation of result:45% water dispersible granules direct sowing of rice field weed is to total weed preventive effect effect, anti-after medication 10 days Effect highest, average decline rate are up to 88.21%, averagely prevent and kill off rate for 90.52%.100 grams per liter cyhalofop-butyl missible oils are phonetic with 5% The average decline rate of pyridine oxime grass ether cream is 75.74%, 68.89%, and both averagely prevent and kill off rate difference 75.49%, 77.01%. And the average decline rate only up to 55.48% of 480 grams per liter bentazone water preparations, rate is averagely prevented and kill off for 67.07%.45% moisture is described Shot agent to the prevention effect of direct sowing of rice field weed apparently higher than bentazone, cyhalofop-butyl, pyribenzoxim single dose effect, Therefore there is preferable popularizing application prospect.
The invention is not restricted to embodiment here, announcement of the those skilled in the art according to the present invention, without departing from the present invention The improvement and modification made by category all should be within protection scope of the present invention.

Claims (4)

1. a kind of rice direct seeding field ternary weeding composition containing bentazone, the Herbicidal combinations include effective ingredient, and which is special Levy and be:The effective ingredient be cyhalofop-butyl, bentazone and pyribenzoxim, the cyhalofop-butyl, bentazone and pyrimidine oxime The mass ratio of careless ether is 1~20: 10~50: 1~10.
2. Herbicidal combinations according to claim 1, it is characterised in that:The cyhalofop-butyl, bentazone and pyrimidine oxime grass The mass ratio of ether is 4~20: 12~50: 2~10.
3. Herbicidal combinations according to claim 1, it is characterised in that:The Herbicidal combinations are also containing can agriculturally connect The surfactant that receives and carrier.
4. Herbicidal combinations according to claim 1, it is characterised in that:The dosage form of the Herbicidal combinations is wettable powder Agent, dispersible oil-suspending agent or water-dispersible granules.
CN201610862101.9A 2016-09-28 2016-09-28 A kind of rice direct seeding field ternary weeding composition containing bentazone Pending CN106489957A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107517976A (en) * 2017-08-04 2017-12-29 安徽圣丰生化有限公司 A kind of herbicidal composition containing pyribenzoxim, cyhalofop-butyl and bentazone
CN109997864A (en) * 2018-01-04 2019-07-12 段绕绕 A kind of ternary built herbicide

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006065094A1 (en) * 2004-12-17 2006-06-22 Lg Life Sciences Ltd. Synergistic herbicidal compositions
CN102027942A (en) * 2010-12-30 2011-04-27 苏州富美实植物保护剂有限公司 Compounded herbicide composition for rice field
CN104519740A (en) * 2012-01-12 2015-04-15 陶氏益农公司 Herbicidal compositions containing bentazon and ALS inhibitor and ACCase inhibitor

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006065094A1 (en) * 2004-12-17 2006-06-22 Lg Life Sciences Ltd. Synergistic herbicidal compositions
CN102027942A (en) * 2010-12-30 2011-04-27 苏州富美实植物保护剂有限公司 Compounded herbicide composition for rice field
CN104519740A (en) * 2012-01-12 2015-04-15 陶氏益农公司 Herbicidal compositions containing bentazon and ALS inhibitor and ACCase inhibitor

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107517976A (en) * 2017-08-04 2017-12-29 安徽圣丰生化有限公司 A kind of herbicidal composition containing pyribenzoxim, cyhalofop-butyl and bentazone
CN109997864A (en) * 2018-01-04 2019-07-12 段绕绕 A kind of ternary built herbicide

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