CN102021825B - Method for preparing multifunctional antibacterial mothproof compound preparation of plant source for wool product - Google Patents
Method for preparing multifunctional antibacterial mothproof compound preparation of plant source for wool product Download PDFInfo
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- CN102021825B CN102021825B CN2010105576156A CN201010557615A CN102021825B CN 102021825 B CN102021825 B CN 102021825B CN 2010105576156 A CN2010105576156 A CN 2010105576156A CN 201010557615 A CN201010557615 A CN 201010557615A CN 102021825 B CN102021825 B CN 102021825B
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Abstract
The invention relates to a method for preparing multifunctional compound preparation of a plant source antibacterial pigment for a wool product, comprising: (1) extracting smashed Chinese Gall by water, filtering, and evaporating in vacuum to obtain the raw concentrated solution of antibacterial agent; (2) extracting smashed kuh-seng by water, filtering, and evaporating in vacuum to obtain the raw concentrated solution of mothproofing agent; and (3) mixing the raw concentrated solution of the antibacterial agent with the raw concentrated solution of the mothproofing agent, stirring evenly, and concentrating in vacuum to obtain the multifunctional compound preparation. The preparation method is simple, has low cost and wide raw material sources and is suitable for industrial production, and the obtained compound preparation has everlasting antibiosis and mothproof effects, is harmless and nontoxic to human body and is environmentally-friendly.
Description
Technical field
The invention belongs to the preparation field of antibiotic mothproof compound formulation, particularly relate to a kind of preparation method who is used for the mothproof multi-functional compound formulation of plant-source antibacterial of wool product.
Background technology
At present, the antibiotic and mothproof finish to wool and goods thereof also mainly is to adopt chemical antiseptic, mothproofing agent., moth proofing agent antibiotic for these chemistry though some toxicity is low, still do not meet the standard of ecological textile.Occur some in recent years and had plants antimicrobial, the mothproofing agent of green, security concepts.Prepared natural antibacterial dye like the bacterial classification that extracts in a kind of deciduous species of CN 200710071404 usefulness and the compound of safflower pears; The CN 200710307517 usefulness roots of large-flowered skullcap, cordate houttuynia, tealeaves, honeysuckle, Asian puccoon extract a kind of antibacterial finishing agent; CN 200610042869 adopts golden cypress, the root of large-flowered skullcap, honeysuckle to make a kind of botanical antiseptic; CN 031512011 is a raw material with camphorwood powder, gum camphor oil, gum camphor and pyrethroid, has invented that a kind of safety-type is efficient, long-acting worm-eating preventer; CN 200410079636.6 utilizes Dalmatian chrysanthemum to invent a kind of natural pyrethrin clothes moth-proof agent etc.
But antibiotic, the mothproof finish to wool and goods thereof all is separately usually, separately puts in order at present, and patent and reported in literature can not make it have the multifunctional composite finishing agent of antibiotic mothproof effect simultaneously.
Study for many years and the related data report according to seminar of Donghua University's " vegetable colour "; Therefore multi-functional characteristics such as that some plants or dye yielding herb itself promptly has is antibiotic, expelling parasite, uvioresistant can further screen, develop antibiotic, the mothproof multifunctional ecological product of wool and goods thereof on this basis.
The main component in hundred worm storehouses is tannic acid, resin, fat, starch.Have two kinds of pharmacological actions of astriction and antibacterial action; And it has wider antimicrobial spectrum, and in vitro test shows all has significantly antibacterial or bactericidal action to staphylococcus aureus, streptococcus, pneumococcus and typhoid fever, dysentery, anthrax, diphtheria, Pseudomonas aeruginosa etc.
Contain alkaloid in the radix sophorae: d-matrine, d-oxymatrine, sophoranl, 1-anagyrine, 1-methylcytisine etc.Also contain multiple flavone compound in the root: Xanthohumol, isoxanthohumol, kuh-seng chalcone, formoononetin, kurarinone etc.Have heat-clearing, eliminating dampness, desinsection, antitumor, antiallergy, the effect such as eliminate the phlegm of relievining asthma.
Summary of the invention
Technical problem to be solved by this invention provides a kind of preparation method who is used for the mothproof multi-functional compound formulation of plant-source antibacterial of wool product, and this method is simple, and cost is low, and raw material sources are extensive, are suitable for suitability for industrialized production; The gained compound formulation is antibiotic, mothproof effect is lasting, to human non-toxic, harmless, environmental protection.
A kind of preparation method who is used for the mothproof multi-functional compound formulation of plant-source antibacterial of wool product of the present invention comprises:
(1) preparation of plant-source antibacterial agent
After hundred worm storehouses were cleaned, dry, pulverize, the water extraction obtained having the extract of antimicrobial component; Extract is filtered, and afterwards through vacuum evaporation, getting mass percentage concentration is the first concentrate of antiseptic of 10-12%;
(2) preparation of plant source mothproofing agent
After kuh-seng cleaned, dries, pulverizes, the water extraction obtained having the extract of mothproof composition; Extract is filtered, and afterwards through vacuum evaporation, getting mass percentage concentration is the first concentrate of mothproofing agent of 10-12%;
(3) preparation of compound formulation
First concentrate of above-mentioned antiseptic and the first concentrate of mothproofing agent are mixed with mass ratio 1: 0.5-2, stir, concentrate through vacuum again, promptly get at 40-55 ℃.
During said step (1) water extraction antimicrobial component, the mass ratio of hundred worm storehouses and water is 1: 30-45, and extraction temperature is 80-100 ℃, the extraction time is 75-90min.
It is 0.1 μ m micro-filtration membrane that the aperture is adopted in filtration in said step (1) or (2).
When said step (2) water extracted mothproof composition, the mass ratio of kuh-seng and water was 1: 25-45, and extraction temperature is 80-100 ℃, the extraction time is 60-90min.、
The mass percentage concentration of the multi-functional compound formulation of said step (3) preparation is 50%-65%.
The application of the mothproof multi-functional compound formulation concentrate of described plant-source antibacterial (hereinafter to be referred as compound formulation) on wool product; Be directly to use compound formulation solution-treated wool product, the ecological wool product that washing, drying obtain having the mothproof performance of natural antibacterial.
Describedly handle wool product with compound formulation; The mass percentage concentration that is the compound formulation concentrate is 50%-65%; Wool product and compound formulation concentrate are according to mass ratio 1: 0.1-0.15; Add water preparation and make that the mass ratio of final wool product and compound formulation solution is 1: 25-35 is warming up to 90-98 ℃ with the heating rate of 1-3 ℃/min, and is incubated 45-65min in this temperature.Arrangement back wool product is warming up to 90 ℃ and be incubated 30min with washing agent (composition comprises 209 washing agent of 4% (owf), the sodium carbonate of 3% (owf)) with 6 ℃/min heating rate.
With antiseptic and mothproofing agent wool product is handled respectively:
(1) with prepared mothproofing agent wool product is handled earlier, handled with prepared antiseptic again.
(2) with prepared antiseptic wool product is handled earlier, handled with prepared mothproofing agent again.
Handle the bacteriostasis rate of back wool product and see table 2.Mothproof performance test results shows through national wool spinning product quality supervision and test centers (Shanghai), and two kinds of scheme gained wool products are mothproof all qualified, satisfy the textile industry standard.Can find out that by table 1 and table 2 antibiotic the and mothproof performance after with compound formulation wool product being handled is better than when handling respectively.
Table 2
Bacteriostasis after with prepared antiseptic and mothproofing agent wool product being handled respectively
Chemical reaction can not take place after the antiseptic of the selected botanical material extraction of the present invention back gained and mothproofing agent mix, cause phenomenons such as deposition.Wool product after the mothproof multi-functional compound formulation of prepared plant-source antibacterial is handled will have antibiotic, mothproof and color three functions simultaneously, so compound formulation can not influence antiseptic, mothproofing agent and pigment group performance separately.The mothproof multi-functional compound formulation of prepared plant-source antibacterial will be controlled treatment temperature and time well when wool product is handled, prevent the decomposition of active ingredient group.
Beneficial effect
(1) preparation method of the present invention is simple, and cost is low, and raw material sources are extensive, is suitable for suitability for industrialized production;
(2) compound formulation of gained of the present invention is antibiotic, mothproof effect is lasting, to human non-toxic, harmless, environmental protection;
(3) compound formulation of gained of the present invention not only can obtain antibiotic mothproof function, can make fabric obtain natural color characteristics simultaneously;
(4) compound formulation of gained of the present invention is applied on the wool product, detects through national wool spinning product quality supervision and test centers (Shanghai), and its anti-microbial property reaches GB requirement and mothproof qualified.
The specific embodiment
Below in conjunction with specific embodiment, further set forth the present invention.Should be understood that these embodiment only to be used to the present invention is described and be not used in the restriction scope of the present invention.Should be understood that in addition those skilled in the art can do various changes or modification to the present invention after the content of having read the present invention's instruction, these equivalent form of values fall within the application's appended claims institute restricted portion equally.
All raw material of the present invention is all obtained by market purchasing.
Embodiment 1
After with disintegrating machine hundred worm storehouses being pulverized, being that 1: 30 ratio adds water in mass ratio, is the extract that extraction 80min obtains antimicrobial component under 85 ℃ of conditions in temperature; Using the aperture of film is that 0.1 μ m micro-filtrate membrane filtration obtains refined liquid; Refined liquid is evaporated under vacuum condition, obtain the first concentrate of antiseptic of the mass percentage concentration 12% of antimicrobial component.
After with disintegrating machine kuh-seng being pulverized, being that 1: 25 ratio adds water in mass ratio, is the extract that extraction 90min obtains mothproof composition under 90 ℃ of conditions in temperature; Using the aperture of film is that 0.1 μ m micro-filtrate membrane filtration obtains refined liquid; Refined liquid is evaporated under vacuum condition, obtain the first concentrate of mothproofing agent of the mass percentage concentration 10% of mothproof composition.
With the plant-source antibacterial agent of gained and mothproofing agent just concentrate be evenly to mix under 40 ℃ of conditions according to mass ratio 1: 1 in water temperature, it is 50% compound formulation 1# that vacuum evaporation obtains mass percentage concentration.
Embodiment 2
After with disintegrating machine hundred worm storehouses being pulverized, being that 1: 45 ratio adds water in mass ratio, is the extract that extraction 75min obtains antimicrobial component under 100 ℃ of conditions in temperature; Using the aperture of film is that 0.1 μ m micro-filtrate membrane filtration obtains refined liquid; Refined liquid is evaporated under vacuum condition, obtain the first concentrate of antiseptic of the mass percentage concentration 11% of antimicrobial component.
After with disintegrating machine kuh-seng being pulverized, being that 1: 30 ratio adds water in mass ratio, is the extract that extraction 80min obtains mothproof composition under 80 ℃ of conditions in temperature; Using the aperture of film is that 0.1 μ m micro-filtrate membrane filtration obtains refined liquid; Refined liquid is evaporated under vacuum condition, obtain the first concentrate of mothproofing agent of the mass percentage concentration 12% of mothproof composition.
With the plant-source antibacterial agent of gained and mothproofing agent just concentrate be evenly to mix under 50 ℃ of conditions according to mass ratio 1: 0.5 in water temperature, it is 60% compound formulation 2# that vacuum evaporation obtains mass percentage concentration.
Embodiment 3
After with disintegrating machine hundred worm storehouses being pulverized, being that 1: 35 ratio adds water in mass ratio, is the extract that extraction 90min obtains antimicrobial component under 80 ℃ of conditions in temperature; Using the aperture of film is that 0.1 μ m micro-filtrate membrane filtration obtains refined liquid; Refined liquid is evaporated under vacuum condition, obtain the first concentrate of antiseptic of the mass percentage concentration 10% of antimicrobial component.
After with disintegrating machine kuh-seng being pulverized, being that 1: 45 ratio adds water in mass ratio, is the extract that extraction 60min obtains mothproof composition under 100 ℃ of conditions in temperature; Using the aperture of film is that 0.1 μ m micro-filtrate membrane filtration obtains refined liquid; Refined liquid is evaporated under vacuum condition, obtain the first concentrate of mothproofing agent of the mass percentage concentration 11% of mothproof composition.
With the plant-source antibacterial agent of gained and mothproofing agent just concentrate be evenly to mix under 55 ℃ of conditions according to mass ratio 1: 2 in water temperature, it is 65% compound formulation 3# that vacuum evaporation obtains mass percentage concentration.
Embodiment 4
Directly pure wool knitting yarn is put in order with compound formulation 1#.Pure wool knitting yarn and compound formulation 1# add the water preparation and make that the mass ratio of final wool knitting yarn and compound formulation solution is 1: 25 according to mass ratio 1: 0.1, are warming up to 95 ℃ with the heating rate of 2 ℃/min, are incubated 60min; Use washing agent after handling, begin to heat up, be warming up to 90 ℃ with 6 ℃/min heating rate from room temperature, and insulation 30min; Wash, be drying to obtain the antibiotic mothproof wool knitting yarn that has rufous again.
Embodiment 5
Directly knitting woollen sweater is put in order with compound formulation 2#.Knitting woollen sweater and compound formulation 2# add the water preparation and make that the mass ratio of final woollen sweater and compound formulation solution is 1: 30 according to mass ratio 1: 0.13, are warming up to 98 ℃ with the heating rate of 3 ℃/min, are incubated 45min; Use washing agent after handling, begin to heat up, be warming up to 90 ℃ with 6 ℃/min heating rate from room temperature, and insulation 30min; Wash again, be drying to obtain and have khaki antibiotic mothproof knitting woollen sweater.
Embodiment 6
Directly the WORSTED lining is put in order with compound formulation 3#.WORSTED lining and compound formulation 3# add the water preparation and make that the mass ratio of final WORSTED lining and compound formulation solution is 1: 35 according to mass ratio 1: 0.15, are warming up to 90 ℃ with the heating rate of 1 ℃/min, are incubated 65min; Use washing agent after handling, begin to heat up, be warming up to 90 ℃ with 6 ℃/min heating rate from room temperature, and insulation 30min; Wash again, be drying to obtain and have filemot antibiotic mothproof WORSTED lining.
Three kinds of wool products of gained carry out anti-microbial property according to national standard and detect, and its bacteriostasis rate is seen table 1.Three kinds of its anti-microbial properties of wool product reach the GB requirement.Mothproof performance test results shows through national wool spinning product supervision and inspection center (Shanghai), and three kinds of wool products are mothproof all qualified, satisfy the textile industry standard.
Bacteriostasis after table 1 compound formulation of the present invention is handled wool product among the embodiment
Claims (5)
1. preparation method who is used for the mothproof multi-functional compound formulation of plant-source antibacterial of wool product comprises:
(1) with after the pulverizing of hundred worm storehouses, the water extraction obtains having the extract of antimicrobial component; Extract is filtered, vacuum evaporation afterwards, getting mass percentage concentration is the first concentrate of antiseptic of 10-12%;
(2) with after the kuh-seng pulverizing, the water extraction obtains having the extract of mothproof composition; Extract is filtered, vacuum evaporation afterwards, getting mass percentage concentration is the first concentrate of mothproofing agent of 10-12%;
(3) first concentrate of above-mentioned antiseptic and the first concentrate of mothproofing agent are mixed with mass ratio 1: 0.5-2, stir, concentrate through vacuum again, promptly get at 40-55 ℃.
2. a kind of preparation method who is used for the mothproof multi-functional compound formulation of plant-source antibacterial of wool product according to claim 1; It is characterized in that: during said step (1) water extraction antimicrobial component; The mass ratio of hundred worm storehouses and water is 1: 30-45; Extraction temperature is 80-100 ℃, and the extraction time is 75-90min.
3. a kind of preparation method who is used for the mothproof multi-functional compound formulation of plant-source antibacterial of wool product according to claim 1 is characterized in that: it is 0.1 μ m micro-filtration membrane that the aperture is adopted in the filtration in said step (1) or (2).
4. a kind of preparation method who is used for the mothproof multi-functional compound formulation of plant-source antibacterial of wool product according to claim 1; It is characterized in that: when said step (2) water extracts mothproof composition; The mass ratio of kuh-seng and water is 1: 25-45; Extraction temperature is 80-100 ℃, and the extraction time is 60-90min.
5. a kind of preparation method who is used for the mothproof multi-functional compound formulation of plant-source antibacterial of wool product according to claim 1 is characterized in that: the mass percentage concentration of the multi-functional compound formulation of said step (3) preparation is 50%-65%.
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| CN102021825B true CN102021825B (en) | 2012-10-31 |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103437174B (en) * | 2013-08-02 | 2015-07-01 | 苏州爱立方服饰有限公司 | Woolen sweater treatment fluid containing gellan gum |
| CN103422345B (en) * | 2013-08-02 | 2015-06-17 | 苏州爱立方服饰有限公司 | Anti-bacteria shrinkage-resisting woolen sweater treating liquid containing sodium palmitate |
| CN103422351B (en) * | 2013-08-02 | 2015-05-20 | 苏州爱立方服饰有限公司 | Woolen sweater treating liquid containing abietic acid polyoxyethylene ester |
| CN106012512A (en) * | 2016-05-18 | 2016-10-12 | 太仓协大申泰羊毛衫有限公司 | Antibacterial and mildew-resistant finishing liquid containing Chinese herbal medicine extracting solutions and used for woolen sweater and preparation method of finishing liquid |
| CN110129940A (en) * | 2019-05-29 | 2019-08-16 | 上海恋轩实业有限公司 | Mothproof, the easy arrangement composite filament of one kind and ready-made clothes fabric |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1043424A (en) * | 1990-01-24 | 1990-07-04 | 连云港市卫生防疫站 | Grain fibre packing materials Chinese medicine vermifuge and mouse-killing agent |
| CN1056396A (en) * | 1990-05-16 | 1991-11-27 | 王兹 | The Chinese herbal medicine anti-moth pesticide |
| CN1939468A (en) * | 2006-09-27 | 2007-04-04 | 西南大学 | Compound Chinese Gall antiseptic prescription for fishing |
| CN101816312A (en) * | 2010-04-27 | 2010-09-01 | 东华大学 | Method for preparing plant-source antibacterial pigment compound preparation for wool products |
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- 2010-11-24 CN CN2010105576156A patent/CN102021825B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1043424A (en) * | 1990-01-24 | 1990-07-04 | 连云港市卫生防疫站 | Grain fibre packing materials Chinese medicine vermifuge and mouse-killing agent |
| CN1056396A (en) * | 1990-05-16 | 1991-11-27 | 王兹 | The Chinese herbal medicine anti-moth pesticide |
| CN1939468A (en) * | 2006-09-27 | 2007-04-04 | 西南大学 | Compound Chinese Gall antiseptic prescription for fishing |
| CN101816312A (en) * | 2010-04-27 | 2010-09-01 | 东华大学 | Method for preparing plant-source antibacterial pigment compound preparation for wool products |
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