CN102020921A - Low-carbon humidity controlling functional coating - Google Patents
Low-carbon humidity controlling functional coating Download PDFInfo
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- CN102020921A CN102020921A CN2010105951556A CN201010595155A CN102020921A CN 102020921 A CN102020921 A CN 102020921A CN 2010105951556 A CN2010105951556 A CN 2010105951556A CN 201010595155 A CN201010595155 A CN 201010595155A CN 102020921 A CN102020921 A CN 102020921A
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Abstract
The invention relates to a low-carbon humidity controlling functional coating which comprises component A, component B and component C in parts by weight, wherein the component A comprises a thickening agent, a dispersing agent, a defoaming agent, a solvent, a bactericide, a wetting agent and water; the component B comprises powder, titanium white, kaolin and heavy calcium carbonate powder; and the component C comprises an emulsion, a defoaming agent and a film forming agent. Compared with the traditional inside wall emulsion coatings, the coating has the advantages that hydrophilic porous inorganic minerals are added to ensure that a coating film has excellent pollution resistance; after an ordinary coating film absorbs 40g of water in per square meter, the coating film reaches a saturation state, and most part on the surface of the coating film has a dew formation phenomenon, however, after one square meter of the humidity controlling coating film absorbs 60g of water, the surface of the film has no dew formation phenomenon; when the indoor humidity is too high, the porous structure of the film can automatically absorb water in the air and stores the water, and when the room is dry, the water in the film can be released so as to automatically regulate the indoor humidity; and due to the porous structure, the film also has the functions of absorbing sound, insulating heat and deodorizing.
Description
Technical field
The present invention relates to a kind of coating, especially a kind of humidity controlling coating.
Background technology
Present prior art, the humidity of air is crossed the low or too high orthobiosis that all can influence people.When indoor humidity was lower than 40%, people's xerosis cutis, respiratory system resistibility descended, and bacterium, virus can be taken advantage of a weak point, and furniture can be out of shape explosion, and coating, mural painting efflorescence are quickened, and easily cause static electric fire again; Be higher than at 65% o'clock, environment is too moist, and microbial reproduction is accelerated, and article easily go mouldy, rot or corrosion.Therefore can improve the quality of production environment and life by the adjusting indoor air humidity, especially to humidity and arid area, adjusting humidity is particularly important.Regulate humidity with air-conditioning, the energy consumption height, easily produce noise pollution, not environmental protection, unsuitable life-time service.Utilizing the moisture adsorption and releasing characteristic of renewable energy source or material to regulate humidity, need not to consume any artificial energy source, is that a kind of ecological property is regulated the humidity method, its purposes extensively become one of modern architecture and house fitting indispensable material.
Summary of the invention
The objective of the invention is: a kind of low-carbon (LC) humidity conditioning function coating is provided, and it not only has not dewfall of film coated surface, and the function of filming and having water storage and discharging water.
The present invention is achieved in that a kind of low-carbon (LC) humidity conditioning function coating, and it comprises the moiety of following weight part:
The A component:
Thickening material 0.2～0.5 dispersion agent 0.3～1.2
Defoamer 0.1～0.8 solvent 0.5～3
Sterilant 0.05～0.1 wetting agent 0.1～0.6
Water 20～25
The B component:
Powder 5～30 titanium dioxides 10～30
Kaolin 8～15 heavy calcium carbonates 5～35
The C component:
Emulsion 10～30 defoamers 0.2～0.8
Membrane-forming agent 0.3～1.
Described low-carbon (LC) humidity conditioning function coating, its special character is: also comprise the D component:
Whitening agent 0.1～0.3 thickening material 0.1～1 water 1～3 mould inhibitor 0.1～0.5
Described low-carbon (LC) humidity conditioning function coating, its special character is: the defoamer in the described A component is the siliceous thing of mineral oil based, the siliceous thing CF38 of non-silicone organosilane ester mineral oil based or non-silicone organosilane ester SN-DEFOAMER JK;
Thickening material in the described A component is: Natvosol or hydroxypropylcellulose;
Sterilant in the described A component is: sterilant HF or sterilant KSG-105S;
Dispersion agent in the described A component is: polycarboxylate, sodium polyacrylate or ammonium polyacrylate;
Wetting agent in the described A component is: X-405 or WET-991;
Solvent in the described A component is: ethylene glycol or propylene glycol;
Powder in the described B component is: diatomite
Emulsion in the described C component is: organic silicon emulsion RS996AD, KD9, ACRYLIC EMULSION RS2806 or AC-261P;
Membrane-forming agent in the described C component is: propylene glycol butyl ether or alcohol ester 12;
Defoamer in the described C component is: contain hydrophobic particles mineral oil CF-246,681F, NXZ, the siliceous thing CF38 of mineral oil based, A10, non-silicone organosilane ester SN-DEFOAMER 399 or SN-DEFOAMER JK.
Described low-carbon (LC) humidity conditioning function coating, its special character is: the thickening material in the described D component is: alkali swelling thickening material TT-935, ASE-60, polyurethane thickener SN-THICKENER 612 or RM-8W;
Whitening agent in the described D component is: powdered whitening agent CBS-126, whitening fluid Y-06 or whitening fluid DA-2;
Mould inhibitor in the described D component is: SKANE
M-8 or CN22.
A kind of low-carbon (LC) humidity conditioning function of the present invention coating has following advantage with existing interiro wall latex paint:
1, add hydrophilic porous inorganic mineral, making films has excellent anti-contamination;
2, common coating is filmed every square and is absorbed 40 gram moisture content and be state of saturation, the most of dewfall phenomenon of film coated surface, and humidity controlling coating is filmed every square to film and is absorbed 60 gram moisture content, film coated surface does not have the dewfall phenomenon.Test method: see appendix 1
3, when indoor humidity is too high, the vesicular structure of filming will absorb airborne moisture content automatically and store, and during indoor seasoning, moisture content can be put again in filming, thus the humidity automatically in the surge chamber.Test method: see appendix 2
4, owing to have vesicular structure, film also have sound-absorbing, heat insulation and deodorization functions.
Embodiment
Embodiment 1
The A component:
Thickening material 0.2 dispersion agent 0.3 defoamer 0.1 solvent 0.5
Sterilant 0.05 wetting agent 0.1 water 20
Defoamer is the siliceous thing of mineral oil based; By test also can be siliceous thing CF38 of non-silicone organosilane ester mineral oil based or non-silicone organosilane ester SN-DEFOAMER JK;
The siliceous thing CF38 of non-silicone organosilane ester mineral oil based England Blackburn chemical industry produces
Non-silicone organosilane ester SN-DEFOAMER JK Japan Nuo Puke chemical industry produces
Thickening material is: Natvosol 250HBR;
Also can adopt Xylo-Mucine FVH9 by test;
The Natvosol 250HBR U.S. strides the Asia imperial chemical industry and produces
The north, Xylo-Mucine FVH9 Luzhou emigrant Feng Huagong produces
Sterilant is: sterilant HF, also can adopt sterilant KSG-105S by test;
Sterilant HF Britain Sol chemical industry produces
Enlightening U.S. biotechnology in sterilant KSG-105S Guangzhou produces;
Dispersion agent is: polycarboxylate SN5027, also can adopt sodium polyacrylate SN5040 or ammonium polyacrylate 1124 by test;
Polycarboxylate SN5027 Japan Nuo Puke chemical industry produces
Sodium polyacrylate SN5040 Japan Nuo Puke chemical industry produces
Ammonium polyacrylate 1124 U.S.'s ROHM AND HAAS chemical industry produce
Wetting agent is: X-405; Also can adopt WET-991 by test;
The X-405 Dow Chemical produces
WET-991 Japan Nuo Puke chemical industry
Solvent is: ethylene glycol; Also can adopt propylene glycol by test;
The B component:
Powder 5 titanium dioxides 10 kaolin 8 heavy calcium carbonates 5
Described powder is: diatomite;
Diatomite U.S. Celite Celite company produces
The C component:
Emulsion 10 defoamers 0.2 membrane-forming agent 0.3.
Emulsion is: organic silicon emulsion RS996AD; Also can adopt KD9, ACRYLIC EMULSION RS2806 or AC-261P by evidence;
Ahmedabad enrichment worker in organic silicon emulsion RS996AD Foshan produces
KD9 Henkel KGaA chemical industry produces
Ahmedabad enrichment worker in ACRYLIC EMULSION RS2806 Foshan produces
AC-261P U.S. ROHM AND HAAS chemical industry produces;
Membrane-forming agent is: the propylene glycol butyl ether; Also can adopt alcohol ester 12 by evidence;
Propylene glycol butyl ether Dow Chemical produces
Alcohol ester 12 U.S. Yi Siman chemical industry
Defoamer is: contain hydrophobic particles mineral oil CF-246; Also can adopt 681F, NXZ, the siliceous thing CF38 of mineral oil based, A10, non-silicone organosilane ester SN-DEFOAMER 399 or SN-DEFOAMER JK by evidence.
Containing hydrophobic particles mineral oil CF-246 England Blackburn chemical industry produces
The 681F France inferior chemical industry in sieve ground produces NXZ Japan Nuo Puke chemical industry and produces
The siliceous thing CF38 of mineral oil based England Blackburn chemical industry produces
A10 Shenzhen Hai Chuan chemical industry produces
Non-silicone organosilane ester SN-DEFOAMER 399 Japanese Nuo Puke chemical industry produce
SN-DEFOAMER JK Japan Nuo Puke chemical industry produces.
Its preparation method is as follows: (1) stirs the thickening material in the A component, dispersion agent, defoamer, sterilant, wetting agent, solvent and water;
(2) be added into powder, titanium dioxide, kaolin and heavy calcium carbonate in the B component while stirring successively in step (1) stirs the material of gained, the fineness of high speed dispersion material avoids causing the accumulation of material;
(3) in stirring the material of gained, step (2) is added into emulsion, defoamer, membrane-forming agent in the C component while stirring;
The fineness with material in the described step (3) is dispersed in 60～70 micrometer ranges, or the time of the fineness of the dispersed material in described step (3) was controlled at about 30-40 minute.Make powder reach the ideal dispersion effect, improve opacifying power.
Embodiment 2
The A component:
Thickening material 0.5 dispersion agent 1.2 defoamers 0.8 solvent 3
Sterilant 0.1 wetting agent 0.6 water 25
The B component:
Powder 30 titanium dioxides 30 kaolin 15 heavy calcium carbonates 35
The C component:
Emulsion 30 defoamers 0.8 membrane-forming agent 1.
Embodiment 3
The A component:
Thickening material 0.3 dispersion agent 0.6 defoamer 0.4 solvent 2
Sterilant 0.08 wetting agent 0.3 water 22
The B component:
Powder 18 titanium dioxides 20 kaolin 11 heavy calcium carbonates 20
The C component:
Emulsion 20 defoamers 0.4 membrane-forming agent 0.7.
Embodiment 4
The A component:
Thickening material 0.3 dispersion agent 0.6 defoamer 0.4 solvent 2
Sterilant 0.08 wetting agent 0.3 water 22
The B component:
Powder 18 titanium dioxides 20 kaolin 11 heavy calcium carbonates 20
The C component:
Emulsion 20 defoamers 0.4 membrane-forming agent 0.7.
The D component
Whitening agent 0.2 thickening material 0.6 water 2 mould inhibitors 0.3.
Thickening material in the described D component is: alkali swelling thickening material TT-935;
Also can adopt ASE-60, polyurethane thickener SN-THICKENER 612 or RM-8W by evidence;
Alkali swelling thickening material TT-935 U.S. ROHM AND HAAS chemical industry produces
ASE-60 U.S. ROHM AND HAAS chemical industry produces
Polyurethane thickener SN-THICKENER 612 Japanese Nuo Puke chemical industry produce
RM-8W U.S. ROHM AND HAAS chemical industry) produces
Whitening agent in the described D component is: powdered whitening agent CBS-126; Also can adopt whitening fluid Y-06 or whitening fluid DA-2 by evidence;
Powdered whitening agent CBS-126 Quanzhou three waffle workers produce;
The gloomy triumphant chemical industry in whitening fluid Y-06 Guangzhou produces whitening fluid DA-2 Foshan ancient cooking vessel letter chemical industry and produces;
Mould inhibitor in the described D component is: SKANE
M-8; Also can adopt CN22 by evidence.
SKANE
M-8 U.S. ROHM AND HAAS chemical industry produces CN22 Foshan ancient cooking vessel letter chemical industry and produces
Its preparation method is as follows: (1) stirs the thickening material in the A component, dispersion agent, defoamer, sterilant, wetting agent, solvent and water;
(2) be added into powder, titanium dioxide, kaolin and heavy calcium carbonate in the B component while stirring successively in step (1) stirs the material of gained, the fineness of high speed dispersion material avoids causing the accumulation of material;
(3) in stirring the material of gained, step (2) is added into emulsion, defoamer, membrane-forming agent in the C component while stirring;
What (4) the alkali swelling thickening material in the D group and remainder water are mixed obtains D1 solution, in step (3), slowly add the whitening agent in D1 solution and the D group then in the material of gained while stirring successively, mix stirring and promptly obtain low-carbon (LC) humidity conditioning function coating after 10～15 minutes.
The fineness with material in the described step (3) is dispersed in 60～70 micrometer ranges, or the time of the fineness of the dispersed material in described step (3) was controlled at about 30-40 minute.Make powder reach the ideal dispersion effect, improve opacifying power.
Above-described only is preferential embodiment of the present invention.Should be pointed out that for the person of ordinary skill of the art under the situation that does not break away from the principle of the invention, can also make some improvement and modification, this also is considered as protection scope of the present invention.
Appendix 1
Humidity controlling coating moisture absorption testing method
One, the preparation of test plate (panel);
Prepare common interior wall coating of 200 ɡ and 200 ɡ low-carbon (LC) humidity conditioning function coating, and convert 20% water, go up to spray to do solid work in twice, 7 day at sheet glass (size 30 ㎝ * 40 ㎝) and weigh.
Two, test chamber
Test should be carried out in the flat-bottomed bin of adding a cover (plastic material).Case is of a size of 60 ㎝ * 50 ㎝ * 100 ㎝, placing porous dividing plate in the case, and (porosity is greater than 50%) porous barrier should fill up, and having filled up highly is 30 ㎝-40 ㎝.
Three, testing sequence
1, adds a part of water to test chamber, make the interior humidity of case reach 100% and be advisable.
2, with after the drying and the test plate (panel) of weighing place vertically in case.
3, test plate (panel) is placed after 15 days, 25 days, 35 days, and the weight of weighing test plate (panel) draws the film result of moisture absorption of test plate (panel).
Appendix 2
Humidity controlling coating moisture releasing testing method
One, the preparation of test plate (panel);
Prepare common interior wall coating of 200 ɡ and 200 ɡ low-carbon (LC) humidity conditioning function coating, and convert 20% water, go up at sheet glass (size 30 ㎝ * 40 ㎝) and weigh after spraying was done solid work in twice, 7 day and write down weight, place in the case of 100% humidity, test plate (panel) is filmed absorb reach capacity state and weighing of moisture content.
Two, test chamber
Test should be carried out in the flat-bottomed bin of adding a cover (plastic material).Case is of a size of 60 ㎝ * 50 ㎝ * 100 ㎝, placing porous dividing plate in the case, and (porosity is greater than 50%) porous barrier should fill up, and having filled up highly is 30 ㎝-40 ㎝.
Three, testing sequence
1, contains one kilogram of dewatering agent to test chamber with screen cloth, make the interior humidity of case keep 40%-50% to be advisable.
2, with after the moisture absorption and the test plate (panel) of weighing place vertically in case.
3, test plate (panel) is placed after 2 days, 4 days, and the weight of weighing test plate (panel) draws the film result of moisture releasing of test plate (panel).
Claims (10)
1. low-carbon (LC) humidity conditioning function coating, it comprises the moiety of following weight part:
The A component:
Thickening material 0.2～0.5 dispersion agent 0.3～1.2
Defoamer 0.1～0.8 solvent 0.5～3
Sterilant 0.05～0.1 wetting agent 0.1～0.6
Water 20～25
The B component:
Powder 5～30 titanium dioxides 10～30
Kaolin 8～15 heavy calcium carbonates 5～35
The C component:
Emulsion 10～30 defoamers 0.2～0.8
Membrane-forming agent 0.3～1.
2. low-carbon (LC) humidity conditioning function coating according to claim 1 is characterized in that: also comprise the D component:
Whitening agent 0.1～0.3 thickening material 0.1～1 water 1～3
Mould inhibitor 0.1～0.5.
3. low-carbon (LC) humidity conditioning function coating according to claim 1 is characterized in that:
Defoamer in the described A component is the siliceous thing of mineral oil based;
Thickening material in the described A component is: Natvosol;
Sterilant in the described A component is: sterilant HF;
Dispersion agent in the described A component is: polycarboxylate;
Solvent in the described A component is: ethylene glycol;
Powder in the described B component is: diatomite;
Emulsion in the described C component is: organic silicon emulsion RS996AD
Membrane-forming agent in the described C component is: the propylene glycol butyl ether;
Defoamer in the described C component is: contain hydrophobic particles mineral oil CF-246.
4. low-carbon (LC) humidity conditioning function coating according to claim 1 is characterized in that: the defoamer in the described A component is the siliceous thing CF38 of non-silicone organosilane ester mineral oil based
Thickening material in the described A component is: hydroxypropylcellulose;
Sterilant in the described A component is: sterilant KSG-105S;
Dispersion agent in the described A component is: sodium polyacrylate;
Wetting agent in the described A component is: WET-991;
Solvent in the described A component is: propylene glycol;
Emulsion in the described C component is: KD9;
Membrane-forming agent in the described C component is: alcohol ester 12;
Defoamer in the described C component is: 681F.
5. low-carbon (LC) humidity conditioning function coating according to claim 1 is characterized in that: the defoamer in the described A component is: non-silicone organosilane ester SN-DEFOAMER;
Dispersion agent in the described A component is: ammonium polyacrylate;
Emulsion in the described C component is: ACRYLIC EMULSION RS2806;
Defoamer in the described C component is: NXZ.
6. low-carbon (LC) humidity conditioning function coating according to claim 1 is characterized in that: the defoamer in the described A component is: JK;
Emulsion in the described C component is: AC-261P;
Defoamer in the described C component is: the siliceous thing CF38 of mineral oil based.
7. low-carbon (LC) humidity conditioning function coating according to claim 1 is characterized in that: the defoamer in the described C component is: A10.
8. low-carbon (LC) humidity conditioning function coating according to claim 2 is characterized in that:
Thickening material in the described D component is: alkali swelling thickening material TT-935;
Whitening agent in the described D component is: powdered whitening agent CBS-126;
Mould inhibitor in the described D component is: SKANE
M-8.
9. low-carbon (LC) humidity conditioning function coating according to claim 2 is characterized in that:
Thickening material in the described D component is: ASE-60;
Whitening agent in the described D component is: whitening fluid DA-2;
Mould inhibitor in the described D component is: CN22.
10. low-carbon (LC) humidity conditioning function coating according to claim 2 is characterized in that:
Thickening material in the described D component is: polyurethane thickener SN-THICKENER 612;
Whitening agent in the described D component is: whitening fluid DA-2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105951556A CN102020921A (en) | 2010-12-20 | 2010-12-20 | Low-carbon humidity controlling functional coating |
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| CN2010105951556A CN102020921A (en) | 2010-12-20 | 2010-12-20 | Low-carbon humidity controlling functional coating |
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| CN102925018A (en) * | 2012-11-30 | 2013-02-13 | 刘凯 | Indoor decoration coating |
| CN103073966A (en) * | 2013-01-15 | 2013-05-01 | 贺佑康 | Super anti-stain soft-light wall paint |
| CN103709870A (en) * | 2013-12-31 | 2014-04-09 | 中国建筑材料科学研究总院 | Breathable and humidity-adjustable diatom emulsion paint for inner wall and preparation method thereof |
| CN103770561A (en) * | 2013-12-24 | 2014-05-07 | 无锡凤凰画材有限公司 | Mimeographed wood engraving board |
| CN104327647A (en) * | 2014-11-21 | 2015-02-04 | 苏州大乘环保建材有限公司 | Ultralow-temperature roofing reflective, heat insulation and waterproof coating and preparation method thereof |
| CN104804567A (en) * | 2015-05-12 | 2015-07-29 | 重庆市品胜涂料有限公司 | High-grade interior wall paint and preparation method thereof |
| CN111154341A (en) * | 2020-01-17 | 2020-05-15 | 美巢集团股份公司 | Water-based composite slurry and preparation method thereof |
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| CN112812637A (en) * | 2020-12-31 | 2021-05-18 | 苏州佳固士新材料科技有限公司 | Anti-dewing coating and preparation method thereof |
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| CN104804567A (en) * | 2015-05-12 | 2015-07-29 | 重庆市品胜涂料有限公司 | High-grade interior wall paint and preparation method thereof |
| CN111154341A (en) * | 2020-01-17 | 2020-05-15 | 美巢集团股份公司 | Water-based composite slurry and preparation method thereof |
| CN111154341B (en) * | 2020-01-17 | 2022-05-17 | 美巢集团股份公司 | Water-based composite slurry and preparation method thereof |
| CN111500193A (en) * | 2020-04-28 | 2020-08-07 | 四川景文材料科技有限公司 | High-performance self-cleaning organic silicon coating composition and preparation method thereof |
| CN111500193B (en) * | 2020-04-28 | 2021-08-27 | 四川景文材料科技有限公司 | High-performance self-cleaning organic silicon coating composition and preparation method thereof |
| CN112812637A (en) * | 2020-12-31 | 2021-05-18 | 苏州佳固士新材料科技有限公司 | Anti-dewing coating and preparation method thereof |
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Application publication date: 20110420 |