CN102010681B - Glue with high permanent adhesive force - Google Patents
Glue with high permanent adhesive force Download PDFInfo
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- CN102010681B CN102010681B CN200910195111A CN200910195111A CN102010681B CN 102010681 B CN102010681 B CN 102010681B CN 200910195111 A CN200910195111 A CN 200910195111A CN 200910195111 A CN200910195111 A CN 200910195111A CN 102010681 B CN102010681 B CN 102010681B
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Abstract
The invention relates to glue with high permanent adhesive force, which is prepared from the following components in percentage by mass: 13-17 percent of natural rubber, 18-22 percent of petroleum rubber SIS, 18-22 percent of petroleum resin, 18-22 percent of naphthenic oil, 18-22 percent of natural terpene resin, 0.5-1.5 percent of antioxidant, and 3.5-4.5 percent of rubber accelerator. The glue has the beneficial effects that packed boxes are difficult to curl and permanent adhesive force is improved to above 100H from below 3H; the glue is difficult to age; the fusing property of molten raw materials is good; the temperature resistance and weather resistance of the glue are stable; and nationalized natural resources are fully utilized, production cost is effectively reduced and market competitiveness of products is improved.
Description
Technical field
The present invention relates to the technological innovation of a kind of adhesive tape adhesive material, prescription, relate in particular to the component that this height is held viscous force glue.
Background technology
It is exactly the adhesive tape that this height of coating is held viscous force glue that so-called height is held viscous force, in use, and the bounding force longer duration of adhesive tape and body surface, firmly, difficult drop-off, it has following function and purposes.
Function: after holding height viscous force glue and be coated onto on the base material with coating machine, make adhesive tape have superpower clinging power, it can be effectively and body surface bonding for a long time; Joint sealing and other bonding aspect effect remarkable, and adhesive tape long service life, being difficult for warping comes off, layering has guaranteed client's product quality.
Purposes: scribble the adhesive tape that height is held viscous force glue, be applicable to mainly that joint sealing, weight are tied up, refrigeration equipment piping insulation, high-altitude object be adhesively fixed etc.
And the low viscous force of holding makes adhesive tape when in use, and the surface can be bonding, but the time of being unable to undergo 3 hours will warp, this is the most important reason that influences this adhesive tape result of use.
Common glue of the prior art, the component formula of this glue is: oil rubber SIS 32-38%, petroleum resin 40-44%, changed oily 18-22%, oxidation inhibitor 2.5-3.5%.
Oil rubber SIS is a SIS, has rubber and plastic nature concurrently.The SIS clinging power is strong, is the main raw material of hot-fusible pressure-sensitive adhesive tackiness agent, coating, Solvent Adhesive, modifying plastics goods etc.The product performance of its preparation are better, and like packing bag, sanitary napkin, double-sided belt and oil resistant label or the like, but his amalgamation is with to hold viscous force poor with respect to tree elastomer.
What use in the prior art is the glue that material such as oil rubber and petroleum resin form, and it is low that it holds viscous force, in general, has following many defectives.
The first, joint sealing is prone to the problem of warping; Since during glue water, main raw material(s)s such as general oil rubber and petroleum resin, unstable properties; Have a strong impact on the three force balance of glue, clinging power is poor, and adhesive tape and object are difficult for pasting the jail; Occur soon after sticking warping, bring very big puzzlement and inconvenience to the client.
The second, glue is prone to aging; Existing glue material PetroChina Company Limited.'s rubber and petroleum resin, when heating was dissolved, very easily oxidation made them lose original performance, causes glue to lose viscosity.
The 3rd, amalgamation is poor; Existing starting material oil rubber and petroleum resin are after heating is dissolved, and kind is few, and performance is single, can not multiple performance complement, and cause glue to merge the performance one-sided, have a strong impact on the adhesive tape quality.
The 4th, cost is high; At present the oil price in the world is extremely unstable, fluctuatedly is difficult to prediction, and is in the high price operating state basically, and causes holding at high price of petroleum products, causes great pressure to enterprise.
Summary of the invention
The technical issues that need to address of the present invention have provided a kind of high viscous force glue of holding, and are intended to solve the above problems.
In order to solve the problems of the technologies described above, the present invention realizes through following technical scheme:
The present invention is made up of tree elastomer, oil rubber SIS, NO, petroleum resin, natural terpenes resin, rubber accelerator and oxidation inhibitor; Its mass percent is: tree elastomer 13%-17%, oil rubber SIS 18%-22%, petroleum resin 18%-22%, NO 18%-22%, natural terpenes resin 18%-22%, oxidation inhibitor 0.5%-1.5%, rubber accelerator 3.5%-4.5%.
Compared with prior art, the invention has the beneficial effects as follows: joint sealing is difficult for warping, and holds viscous force by being increased to more than the 100H less than 3H; Glue is difficult for aging; It is good that each starting material dissolves the back amalgamation; Glue heatproof weather resistance is stable; Fully sharp state-owned natural resource effectively reduce production costs, and improve the competitiveness of product in market.
Embodiment
Below in conjunction with embodiment the present invention is described in further detail:
Embodiment 1
Tree elastomer 15%, oil rubber SIS 20%, NO 20%, petroleum resin 20%, terpine resin 20%, oxidation inhibitor 1%, rubber accelerator 4%.
Embodiment 2
Tree elastomer 17%, oil rubber SIS 18%, NO 20%, petroleum resin 18%, terpine resin 22%, oxidation inhibitor 1.5%, rubber accelerator 3.5%.
Embodiment 3
Tree elastomer 13%, oil rubber SIS 22%, NO 19.5%, petroleum resin 22%, terpine resin 18%, oxidation inhibitor 1.5%, rubber accelerator 4%.
Embodiment 4
Tree elastomer 17%, oil rubber SIS 22%, NO 18%, petroleum resin 19%, terpine resin 20%, oxidation inhibitor 0.5%, rubber accelerator 3.5%.
Embodiment 5
Tree elastomer 13%, oil rubber SIS 18%, NO 20%, petroleum resin 22%, terpine resin 22%, oxidation inhibitor 1%, rubber accelerator 4%.
Rubber has and has good adhesive effect after dissolving, and NO has good flowing property, and material is well stirred in reaction kettle, fully dissolves to mix; Have good viscosity after resin dissolves, the effect of rubber accelerator is to make its maximum adhesive effect of rubber performance, and inhibitor then is in order to make the starting material in the reaction kettle be difficult for deterioration by oxidation.
Compare existing rubber technology and increased natural terpenes resin, tree elastomer, rubber accelerator (commercially available prod) newly; The natural turps of natural terpenes resin system processes (being produced by safe general chemical plant, Ganzhou); Have superperformances such as transparent, nontoxic, neutral, electrical insulating property, hydrophobic, non-crystallizable, the diluted alkaline of anti-diluted acid the, heat-resisting, fast light, anti-aging and bonding force be strong; And various synthetics are had good intermiscibility, be soluble in aromatic hydrocarbon and vegetables oil; Tree elastomer (round trip flight light tyre factory buys in the Wuxi) performance has ageing-resistant efficiently and high molecular cohesive force; It is a kind of active elastomerics; Be soluble in multiple petroleum resin, natural terpenes resin, 138 modified resin, make again and play a fusion and stable effect in the sizing agent; Rubber accelerator (production of Lian Kangming chemical plant, Shanghai) is the performance of condensing of giving full play to rubber, and rubber better is scattered among the material of various sizing agents, simultaneously the time of the fusion of catalysis rubber and resin.
Its concrete glue making processes is following: during temperature to 200 ℃, added NO earlier and added tree elastomer, oil rubber, promotor, inhibitor then in the reaction kettle; Build the reaction kettle cover and stirred about 1 hour, treat after rubber dissolves fully the temperature of reaction kettle to be set to 180 ℃.The adding resin is also built the reaction kettle cover and is stirred about 30 minutes, and glue is accomplished.
Claims (6)
1. hold viscous force glue for one kind high, form by tree elastomer, oil rubber SIS, NO, petroleum resin, natural terpenes resin, rubber accelerator and oxidation inhibitor;
Its mass percent is: tree elastomer 13%-17%, oil rubber SIS 18%-22%, petroleum resin 18%-22%, NO 18%-22%, natural terpenes resin 18%-22%, oxidation inhibitor 0.5%-1.5%, rubber accelerator 3.5%-4.5%; And,
It is following that this height is held viscous force glue making processes: during temperature to 200 ℃, added NO earlier and added tree elastomer, oil rubber SIS, rubber accelerator, inhibitor then in the reaction kettle; Build the reaction kettle cover and stirred 1 hour, treat after rubber dissolves fully the temperature of reaction kettle to be set to 180 ℃, add petroleum resin and natural terpenes resin and also build the reaction kettle cover and stirred the glue completion 30 minutes.
2. height according to claim 1 is held viscous force glue, wherein: tree elastomer 15%, oil rubber SIS 20%, NO 20%, petroleum resin 20%, natural terpenes resin 20%, oxidation inhibitor 1%, rubber accelerator 4%.
3. height according to claim 1 is held viscous force glue, wherein: tree elastomer 17%, oil rubber SIS 18%, NO 20%, petroleum resin 18%, natural terpenes resin 22%, oxidation inhibitor 1.5%, rubber accelerator 3.5%.
4. height according to claim 1 is held viscous force glue, wherein: tree elastomer 13%, oil rubber SIS 22%, NO 19.5%, petroleum resin 22%, natural terpenes resin 18%, oxidation inhibitor 1.5%, rubber accelerator 4%.
5. height according to claim 1 is held viscous force glue, wherein: tree elastomer 17%, oil rubber SIS 22%, NO 18%, petroleum resin 19%, natural terpenes resin 20%, oxidation inhibitor 0.5%, rubber accelerator 3.5%.
6. height according to claim 1 is held viscous force glue, wherein: tree elastomer 13%, oil rubber SIS 18%, NO 20%, petroleum resin 22%, natural terpenes resin 22%, oxidation inhibitor 1%, rubber accelerator 4%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910195111A CN102010681B (en) | 2009-09-04 | 2009-09-04 | Glue with high permanent adhesive force |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910195111A CN102010681B (en) | 2009-09-04 | 2009-09-04 | Glue with high permanent adhesive force |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102010681A CN102010681A (en) | 2011-04-13 |
| CN102010681B true CN102010681B (en) | 2012-08-29 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN200910195111A Active CN102010681B (en) | 2009-09-04 | 2009-09-04 | Glue with high permanent adhesive force |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103074013A (en) * | 2013-02-07 | 2013-05-01 | 宁波申山新材料科技有限公司 | Hot-melt pressure-sensitive adhesive |
| CN103102854B (en) * | 2013-02-07 | 2014-12-24 | 宁波申山新材料科技有限公司 | High temperature resistance hot-melt pressure-sensitive adhesive |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1813646A (en) * | 2005-02-02 | 2006-08-09 | 上海稳健医疗器械有限公司 | Self-sticking bandage and its manufacturing method |
| CN1827177A (en) * | 2006-04-05 | 2006-09-06 | 刘福民 | Self-sticking elastic bandage and method for manufacturing the same |
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2009
- 2009-09-04 CN CN200910195111A patent/CN102010681B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1813646A (en) * | 2005-02-02 | 2006-08-09 | 上海稳健医疗器械有限公司 | Self-sticking bandage and its manufacturing method |
| CN1827177A (en) * | 2006-04-05 | 2006-09-06 | 刘福民 | Self-sticking elastic bandage and method for manufacturing the same |
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| CN102010681A (en) | 2011-04-13 |
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Owner name: SHANGHAI YONGGUAN ADHESIVE PRODUCTS CO., LTD. Free format text: FORMER NAME: SHANGHAI YONGGUAN ADHESIVE CO., LTD. |
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Address after: 201713 Zhujiajue Industrial Park, Qingpu District, No. Kang Road, industrial park, No. 15 Patentee after: SHANGHAI YONGGUAN ADHESIVE PRODUCTS CO., LTD. Address before: 201713 Zhujiajue Industrial Park, Qingpu District, No. Kang Road, industrial park, No. 15 Patentee before: Shanghai Yongguan Adhesive Products Co., Ltd. |
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Address after: 201713 Zhujiajue Industrial Park, Qingpu District, No. Kang Road, industrial park, No. 15 Patentee after: Shanghai Yongguan Zhongcheng new material science and Technology (Group) Limited by Share Ltd Address before: 201713 Zhujiajue Industrial Park, Qingpu District, No. Kang Road, industrial park, No. 15 Patentee before: SHANGHAI YONGGUAN ADHESIVE PRODUCTS CO., LTD. |
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Effective date of registration: 20170302 Address after: 331800 Fuzhou, Dongxiang Province Economic Development Zone, the Industrial Park Hill Patentee after: Jiangxi Yongguan Technology Development Co., Ltd. Address before: 201713 Zhujiajue Industrial Park, Qingpu District, No. Kang Road, industrial park, No. 15 Patentee before: Shanghai Yongguan Zhongcheng new material science and Technology (Group) Limited by Share Ltd |