CN102010213A - Method for producing baking-free magnesia carbon brick - Google Patents
Method for producing baking-free magnesia carbon brick Download PDFInfo
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- CN102010213A CN102010213A CN201010538496XA CN201010538496A CN102010213A CN 102010213 A CN102010213 A CN 102010213A CN 201010538496X A CN201010538496X A CN 201010538496XA CN 201010538496 A CN201010538496 A CN 201010538496A CN 102010213 A CN102010213 A CN 102010213A
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- carbon brick
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Abstract
The invention discloses a method for producing a baking-free magnesia carbon brick. The method comprises the following steps of: adding 5 to 20 percent of normal-temperature curing agent into thermoset phenolic resin, and uniformly stirring; preparing particle raw materials and powder raw materials used for preparing the magnesia carbon brick according to the conventional proportion; putting the particle raw materials into a mill, adding a binding agent for mixing, and adding the powder raw materials into the mill and continuously mixing to form pug; molding the mixed pug within 60 minutes; placing the molded magnesia carbon brick at room temperature for 36 hours; and performing the conventional test on the magnesia carbon brick to obtain a finished product brick after the magnesia carbon brick is qualified. The method has the advantages that the normal temperature curing agent such as NL or hydrochloric acid and the like are added into the thermoset phenolic resin according to a certain proportion and used as a special binding agent of the magnesia carbon brick, so that the magnesia carbon brick pug can be molded within 60 minutes, and the strength can be built at room temperature within 36 hours; and the magnesia carbon brick can be cured without the conventional method of coal burning, gas burning or electrical heating, so that energy is saved, consumption is lowered and the pollution to atmospheric environment is avoided.
Description
Technical field
The present invention relates to the production method of magnesia carbon brick, especially relate to a kind of production method of exempting to toast magnesia carbon brick.
Background technology
Used magnesia carbon brick on the Thermal Equipments such as steel-making ladle, hot metal ladle, electric furnace, its conventional production method generally need be carried out drying treatment under 160～245 ℃ temperature, through 48～80 hours, after making resin solidification and setting up intensity, place again about 12 hours and just can choose, pack.This method not only the production cycle long, labor strength is big, when dry need with methods such as fire coal, combustion gas or electrically heated also can waste energy contaminate environment.
Summary of the invention
The object of the present invention is to provide a kind of high efficiency, labor strength is low and the production method of exempting to toast magnesia carbon brick of save energy.
For achieving the above object, the present invention can take following technical proposals:
Production method of exempting to toast magnesia carbon brick of the present invention, it comprises the steps:
The first step adds 5～20% ambient cure agent in heat-reactive phenolic resin, it is standby as wedding agent to stir;
Second the step, routinely ratio prepare the used particulate material of magnesia carbon brick and powder raw material standby;
The 3rd step, the magnesia carbon brick particulate material is put into the stone roller machine, add the wedding agent that the first step prepares according to 3.2% of total raw material, mixing 2～5 minutes, powder raw material is added continue to become in mixing 7～15 minutes the magnesia carbon brick pug in the stone roller machine again;
In the 4th step, the 3rd magnesia carbon brick pug that mix of step is transported to the moulding in 60 minutes of pressure board finishes;
In the 5th step, the room temperature after visual testing of the magnesia carbon brick after the moulding was placed 36 hours;
The 6th step, will place 36 hours magnesia carbon brick by batch carrying out conventional physics, Chemical Analysis, be finished bricks after qualified.
Used ambient cure agent is NL or hydrochloric acid.
The invention has the advantages that ambient cure agent such as NL or hydrochloric acid are added in the heat-reactive phenolic resin into (Re solidity Fen aldehyde Shu Zhi ﹕ ambient cure agent=100 ﹕ 5～20) by a certain percentage as the extraordinary wedding agent of magnesia carbon brick, can guarantee the moulding in 60 minutes of magnesia carbon brick pug, set up intensity in room temperature in 36 hours, do not need to adopt ordinary methods such as fire coal, combustion gas or electrically heated to impel magnesia carbon brick to solidify, not only accomplished to save energy and reduce the cost, also avoided pollution atmospheric environment.
Embodiment
Embodiment 1:
Production method of exempting to toast magnesia carbon brick of the present invention, it is characterized in that: it comprises the steps:
The first step, the NL ambient cure agent of adding 5% in heat-reactive phenolic resin, it is standby as wedding agent to stir;
Second step, used particulate material and the powder raw material of preparation magnesia carbon brick:
Particulate material: 30 parts of the 98# electrosmelted magnesite clinkers of granularity 5～3mm, 25 parts of the 98# electrosmelted magnesite clinkers of granularity 3～1mm, 10 parts of the 98# electrosmelted magnesite clinkers of granularity 1～0.1mm;
Powder raw material: 14 parts in 95# graphite; 1 part in hard pitch powder, 180 orders; 2 parts of 98# metallic aluminiums, 200 orders; 1 part of 98# metallic silicon power, 200 orders; 17 parts in 98# electric molten magnesite powder, 200 orders;
The 3rd step, above-mentioned particulate material is put into the stone roller machine, add the wedding agent that the first step prepares according to 3.2% of total raw material, mixing 2～5 minutes, powder raw material is added continue to become in mixing 7～15 minutes the magnesia carbon brick pug in the stone roller machine again;
In the 4th step, the 3rd magnesia carbon brick pug that mix of step is transported to the moulding in 60 minutes of pressure board finishes;
In the 5th step, the magnesia carbon brick after the moulding is placed more than 36 hours through room temperature after the visual testing;
The 6th step, will place 36 hours magnesia carbon brick by batch carrying out conventional physics, Chemical Analysis, be finished bricks, the packing shipping after qualified.
Embodiment 2:
Production method of exempting to toast magnesia carbon brick of the present invention, it comprises the steps:
The first step, the hydrochloric acid of adding 15% in heat-reactive phenolic resin, it is standby as wedding agent to stir;
Second step, used particulate material and the powder raw material of preparation magnesia carbon brick:
Particulate material: granularity is 30 parts of the 97# highly-purity magnesites of 5～3mm, and granularity is 25 parts of the 97# highly-purity magnesites of 3～1mm, and granularity is 10 parts of the 97# highly-purity magnesites of 1～0.1mm;
Powder raw material: 10 parts in 95# graphite; 1.5 parts of hard pitches, 180 orders; 1 part of 98# metallic aluminium, 200 orders; 1 part of 98# metallic silicon power, 200 orders; 17 parts in 97# highly-purity magnesite powder, 200 orders;
The 3rd step, above-mentioned particulate material is put into the stone roller machine, add the wedding agent that the first step prepares according to 3.2% of total raw material, mixing 2～5 minutes, powder raw material is added continue to become in mixing 7～15 minutes the magnesia carbon brick pug in the stone roller machine again;
In the 4th step, the 3rd magnesia carbon brick pug that mix of step is transported to the moulding in 60 minutes of pressure board finishes;
In the 5th step, the room temperature after visual testing of the magnesia carbon brick after the moulding was placed 36 hours;
The 6th step, will place 36 hours magnesia carbon brick by batch carrying out conventional physics, Chemical Analysis, be finished bricks, the packing shipping after qualified.
Embodiment 3:
Production method of exempting to toast magnesia carbon brick of the present invention, it comprises the steps:
The first step, the NL ambient cure agent of adding 20% in heat-reactive phenolic resin, it is standby as wedding agent to stir;
Second step, used particulate material and the powder raw material of preparation magnesia carbon brick:
Particulate material: granularity is 30 parts of the 97# highly-purity magnesites of 5～3mm, and granularity is 25 parts of the 97# highly-purity magnesites of 3～1mm, and granularity is 10 parts of the 97# highly-purity magnesites of 1～0.1mm;
Powder raw material: 10 parts in 95# graphite; 1.5 parts of hard pitches, 180 orders; 1 part of 98# metallic aluminium, 200 orders; 1 part of 98# metallic silicon power, 200 orders; 17 parts in 97# highly-purity magnesite powder, 200 orders;
The 3rd step, above-mentioned particulate material is put into the stone roller machine, add the wedding agent that the first step prepares according to 3.2% of total raw material, mixing 2～5 minutes, powder raw material is added continue to become in mixing 7～15 minutes the magnesia carbon brick pug in the stone roller machine again;
In the 4th step, the 3rd magnesia carbon brick pug that mix of step is transported to the moulding in 60 minutes of pressure board finishes;
In the 5th step, the room temperature after visual testing of the magnesia carbon brick after the moulding was placed 36 hours;
The 6th step, will place 36 hours magnesia carbon brick by batch carrying out conventional physics, Chemical Analysis, be finished bricks, the packing shipping after qualified.
Claims (2)
1. production method of exempting to toast magnesia carbon brick, it is characterized in that: it comprises the steps:
The first step adds 5～20% ambient cure agent in heat-reactive phenolic resin, it is standby as wedding agent to stir;
Second the step, routinely ratio prepare the used particulate material of magnesia carbon brick and powder raw material standby;
The 3rd step, the magnesia carbon brick particulate material is put into the stone roller machine, add the wedding agent that the first step prepares according to 3.2% of total raw material, mixing 2～5 minutes, powder raw material is added continue to become in mixing 7～15 minutes the magnesia carbon brick pug in the stone roller machine again;
In the 4th step, the 3rd magnesia carbon brick pug that mix of step is transported to the moulding in 60 minutes of pressure board finishes;
In the 5th step, the room temperature after visual testing of the magnesia carbon brick after the moulding was placed 36 hours;
The 6th step, will place 36 hours magnesia carbon brick by batch carrying out conventional physics, Chemical Analysis, be finished bricks after qualified.
2. production method of exempting to toast magnesia carbon brick according to claim 1 is characterized in that: described ambient cure agent is NL or hydrochloric acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010538496XA CN102010213A (en) | 2010-11-10 | 2010-11-10 | Method for producing baking-free magnesia carbon brick |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010538496XA CN102010213A (en) | 2010-11-10 | 2010-11-10 | Method for producing baking-free magnesia carbon brick |
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| CN102010213A true CN102010213A (en) | 2011-04-13 |
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| CN201010538496XA Pending CN102010213A (en) | 2010-11-10 | 2010-11-10 | Method for producing baking-free magnesia carbon brick |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102276271A (en) * | 2011-06-29 | 2011-12-14 | 江苏苏嘉集团新材料有限公司 | Preparation method of normal temperature solidified magnesium carbon brick |
| CN102503483A (en) * | 2011-11-03 | 2012-06-20 | 三门峡三键炭材料科技有限公司 | Carbon brick |
| CN111807850A (en) * | 2020-07-21 | 2020-10-23 | 郑州长虹耐火材料有限公司 | Baking-free low-energy-consumption regenerated ladle brick and preparation method thereof |
| CN114149250A (en) * | 2021-12-16 | 2022-03-08 | 江苏鑫驰新材料有限公司 | Non-baking environment-friendly magnesia-calcium brick and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1048695A (en) * | 1990-08-25 | 1991-01-23 | 鞍山市特种耐火材料集团 | The normal temperature rapid concretion technology for making Mg-C brick |
| CN101333089A (en) * | 2008-08-06 | 2008-12-31 | 郑州振东耐磨材料有限公司 | Process for producing MgO-C Bricks by using waste MgO-C Bricks as main raw material |
-
2010
- 2010-11-10 CN CN201010538496XA patent/CN102010213A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1048695A (en) * | 1990-08-25 | 1991-01-23 | 鞍山市特种耐火材料集团 | The normal temperature rapid concretion technology for making Mg-C brick |
| CN101333089A (en) * | 2008-08-06 | 2008-12-31 | 郑州振东耐磨材料有限公司 | Process for producing MgO-C Bricks by using waste MgO-C Bricks as main raw material |
Non-Patent Citations (3)
| Title |
|---|
| 《浙江化工》 19860829 张婷婷 新产品－NL固化剂简介 50，62－63 2 , 第4期 * |
| 张婷婷: "新产品－NL固化剂简介", 《浙江化工》 * |
| 江禹雄等: "镁碳砖生产工艺的改进", 《钢铁研究》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102276271A (en) * | 2011-06-29 | 2011-12-14 | 江苏苏嘉集团新材料有限公司 | Preparation method of normal temperature solidified magnesium carbon brick |
| CN102503483A (en) * | 2011-11-03 | 2012-06-20 | 三门峡三键炭材料科技有限公司 | Carbon brick |
| CN111807850A (en) * | 2020-07-21 | 2020-10-23 | 郑州长虹耐火材料有限公司 | Baking-free low-energy-consumption regenerated ladle brick and preparation method thereof |
| CN114149250A (en) * | 2021-12-16 | 2022-03-08 | 江苏鑫驰新材料有限公司 | Non-baking environment-friendly magnesia-calcium brick and preparation method thereof |
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Application publication date: 20110413 |