CN101696364A - Metallurgical lump coke bonding agent manufactured by using coke powder and preparation method thereof - Google Patents
Metallurgical lump coke bonding agent manufactured by using coke powder and preparation method thereof Download PDFInfo
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- CN101696364A CN101696364A CN200910070888A CN200910070888A CN101696364A CN 101696364 A CN101696364 A CN 101696364A CN 200910070888 A CN200910070888 A CN 200910070888A CN 200910070888 A CN200910070888 A CN 200910070888A CN 101696364 A CN101696364 A CN 101696364A
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- 239000000571 coke Substances 0.000 title claims abstract description 21
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000007767 bonding agent Substances 0.000 title 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 26
- 239000011230 binding agent Substances 0.000 claims abstract description 24
- 238000003756 stirring Methods 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000440 bentonite Substances 0.000 claims abstract description 16
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 16
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002802 bituminous coal Substances 0.000 claims abstract description 13
- 239000000843 powder Substances 0.000 claims abstract description 13
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 13
- 235000017550 sodium carbonate Nutrition 0.000 claims abstract description 13
- 229920002261 Corn starch Polymers 0.000 claims abstract description 9
- 239000008120 corn starch Substances 0.000 claims abstract description 9
- 238000010438 heat treatment Methods 0.000 claims abstract description 7
- 239000006072 paste Substances 0.000 claims abstract description 7
- 229940099112 cornstarch Drugs 0.000 claims abstract 6
- 239000000203 mixture Substances 0.000 claims description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims 1
- 238000002485 combustion reaction Methods 0.000 abstract description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 4
- 238000003723 Smelting Methods 0.000 abstract description 2
- 229910000831 Steel Inorganic materials 0.000 abstract description 2
- 229910052742 iron Inorganic materials 0.000 abstract description 2
- 239000010959 steel Substances 0.000 abstract description 2
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 description 9
- 230000001070 adhesive effect Effects 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 229920002472 Starch Polymers 0.000 description 5
- 239000008107 starch Substances 0.000 description 5
- 235000019698 starch Nutrition 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 239000010426 asphalt Substances 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 238000004939 coking Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000011398 Portland cement Substances 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910001570 bauxite Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- -1 sodium fluorosilicate Chemical compound 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
本发明涉及一种以焦炭碎末制造冶金块焦的粘结剂及其制备方法,属于制备冶金焦炭的粘结剂技术。所述的粘结剂组成为:玉米淀粉2%~5%;膨润土10%~20%;烟煤粉20%~32%;纯碱0.03%~0.05%;水30%~45%。其制备方法,按玉米淀粉与膨润土、烟煤、纯碱和水的质量比,在常温下把水、玉米淀粉和纯碱混合搅拌均匀,然后加热至50℃~80℃。在加热过程中不断搅拌,使之成为浆糊;然后用搅拌机把浆糊、膨润土和烟煤粉搅拌,使之混合均匀成膏泥状,即成为以焦炭碎末制造冶金块焦的粘结剂。本发明的优点在于,制备过程简单,原料易得,制得的粘结剂中不含对钢铁冶炼有害的成分,用于粘结焦炭碎末制得的冶金块焦,固定炭含量高、耐温强度好和燃烧性能佳。The invention relates to a binder for producing metallurgical lump coke from coke powder and a preparation method thereof, belonging to the binder technology for preparing metallurgical coke. The binder is composed of: 2%-5% cornstarch; 10%-20% bentonite; 20%-32% bituminous coal powder; 0.03%-0.05% soda ash; 30%-45% water. According to the mass ratio of cornstarch, bentonite, bituminous coal, soda ash and water, the water, cornstarch and soda ash are mixed and stirred uniformly at normal temperature, and then heated to 50°C-80°C. Stir continuously during the heating process to make it into a paste; then use a mixer to stir the paste, bentonite and bituminous coal powder to make it evenly mixed into a paste, which becomes the binder for making metallurgical lump coke from coke powder . The advantages of the present invention are that the preparation process is simple, the raw materials are easy to obtain, and the prepared binder does not contain harmful ingredients for iron and steel smelting. Good temperature strength and good combustion performance.
Description
技术领域 technical field
本发明涉及一种以焦炭碎末制造冶金块焦的粘结剂及其制备方法,属于制备冶金焦炭的粘结剂技术领域。The invention relates to a binder for producing metallurgical lump coke from coke powder and a preparation method thereof, belonging to the technical field of binders for preparing metallurgical coke.
背景技术 Background technique
焦炭是冶金行业的重要原料,在运输装卸过程中,约有10%~15%的焦炭会变成碎焦末。据有关资料介绍,我国每年的碎焦末产量在5000万吨以上。受冶金焦炭的质量和粒度限制,大量的碎焦末只能做为低级燃料处理,或做为炼焦原料进行二次焦化。Coke is an important raw material in the metallurgical industry. During transportation and loading and unloading, about 10% to 15% of coke will become coke powder. According to relevant information, my country's annual output of crushed coke powder is more than 50 million tons. Limited by the quality and particle size of metallurgical coke, a large amount of crushed coke powder can only be treated as low-grade fuel, or used as coking raw materials for secondary coking.
利用碎焦末成型冶金块焦,是一项技术含量高,附加值大的煤炭深加工技术,也是煤化学等领域研究攻关的重要课题之一,具有重要的社会效益和经济效益。其技术关键之一是粘结剂的组成。The use of crushed coke powder to form metallurgical lump coke is a coal deep-processing technology with high technical content and high added value. It is also one of the important research topics in the fields of coal chemistry and other fields, and has important social and economic benefits. One of its technical keys is the composition of the binder.
中国实用技术市场网(www.kjchina.com/mtlj02.htm)介绍了几种利用碎焦末成型冶金块焦的专利技术。成型方法主要有静压成型和挤压成型两种,所用粘结剂主要有:China Practical Technology Market Network (www.kjchina.com/mtlj02.htm) introduces several patented technologies for forming metallurgical lump coke by using crushed coke powder. The molding methods mainly include static pressure molding and extrusion molding, and the binders used mainly include:
(1)以沥青和煤焦油为主要材料制造的粘结剂;(1) Adhesives made of asphalt and coal tar as main materials;
(2)以膨润土和纸浆废液为主要材料制造的粘结剂;(2) A binder made of bentonite and pulp waste liquid as main materials;
(3)以硅酸盐水泥、水和添加剂为主要材料制造的粘结剂;(3) Adhesives made of Portland cement, water and additives as main materials;
(4)以水、腐植酸钠、阳离子淀粉、膨润土、硅酸钠、ZCM-1型水溶性絮凝剂和一氧化碳助燃剂为主要材料制造的粘结剂;(4) Binder made of water, sodium humate, cationic starch, bentonite, sodium silicate, ZCM-1 water-soluble flocculant and carbon monoxide combustion enhancer as main materials;
(5)以钠水玻璃、十二烷基硫酸钠、氟硅酸钠和水为主要材料制造的粘结剂;(5) Adhesives made of sodium silicate, sodium lauryl sulfate, sodium fluorosilicate and water as main materials;
(6)以羟甲基纤维素、膨润土和调和剂为主要材料制造的粘结剂;(6) Adhesives made of hydroxymethyl cellulose, bentonite and blending agent as main materials;
(7)以氧化镁、氯化镁、水玻璃、尿素、水泥和水为主要材料制造的粘结剂;(7) Adhesives made of magnesium oxide, magnesium chloride, water glass, urea, cement and water as main materials;
(8)以沥青、氢氧化铝、高岭土和铝矾土为主要材料制造的粘结剂。(8) Binders made of asphalt, aluminum hydroxide, kaolin and bauxite as main materials.
采用上述粘结剂所制得的块焦,或存在着固定炭含量低、或存在着常温强度低、或存在着高温强度低、或存在着燃烧性能不佳的问题。The lump coke prepared by using the above-mentioned binder has the problems of low fixed carbon content, low strength at room temperature, low strength at high temperature, or poor combustion performance.
发明内容 Contents of the invention
本发明的目的在于提供一种以焦炭碎末制造冶金块焦的粘结剂及其制备方法。所述的粘结剂用以制备冶金块焦,具有固定炭含量高、耐温强度好和燃烧性能佳的特点。所述的制备方法过程简单。The object of the present invention is to provide a binder for producing metallurgical lump coke from coke powder and a preparation method thereof. The binder is used to prepare metallurgical lump coke, and has the characteristics of high fixed carbon content, good temperature resistance strength and good combustion performance. The preparation method is simple in process.
本发明是通过以下技术方案加以实现的,一种以焦炭碎末制造冶金块焦的粘结剂,其特征在于,该粘结剂由下列组分及各组分质量百分数组成:The present invention is achieved through the following technical scheme, a binder for producing metallurgical lump coke from coke powder, characterized in that the binder is composed of the following components and the mass percentages of each component:
玉米淀粉为2%~5%;膨润土为10%~20%;粘结指数(GR.I.)75的烟煤粉为20%~32%;纯碱NaOH为0.03%~0.05%;水为30%~45%,且各组分质量百分数之和为百分之百。2% to 5% of corn starch; 10% to 20% of bentonite; 20% to 32% of bituminous coal powder with a caking index (G RI ) of 75; 0.03% to 0.05% of soda ash NaOH; 30% to 30% of water 45%, and the sum of the mass percentages of each component is 100%.
上述粘结剂的制备方法,其特征在于包括以下过程:The preparation method of above-mentioned binding agent is characterized in that comprising following process:
按玉米淀粉∶膨润土∶粘结指数75的烟煤粉∶纯碱∶水的质量比为2~5∶20~32∶30~45∶0.0003~0.0005∶30~45,在常温下把水、玉米淀粉和纯碱混合搅拌均匀,然后加热至50℃~80℃。在加热过程中以搅拌速度20~30转/分钟搅拌30~40分钟,使之成为浆糊。然后用搅拌机把浆糊、膨润土和烟煤煤粉以搅拌速度30转/分钟搅拌5~8分钟,使之混合均匀成膏泥状,即成为以焦炭碎末制造冶金块焦的粘结剂。According to the mass ratio of corn starch: bentonite: bituminous coal powder with a cohesive index of 75: soda ash: water is 2~5: 20~32: 30~45: 0.0003~0.0005: 30~45, water, corn starch Mix and stir evenly with soda ash, then heat to 50°C~80°C. Stir at a stirring speed of 20-30 rpm for 30-40 minutes during the heating process to make it into a paste. Then use a mixer to stir the paste, bentonite and bituminous coal powder at a stirring speed of 30 rpm for 5-8 minutes, so that they are evenly mixed into a paste, which becomes a binder for making metallurgical lump coke from coke powder.
本发明的优点在于,制备过程简单,原料易得,制得的粘结剂中不含对钢铁冶炼有害的成分,用于粘结焦炭碎末制得的冶金块焦,具有固定炭含量高、耐温强度好和燃烧性能佳的特点。The advantages of the present invention are that the preparation process is simple, the raw materials are easy to obtain, and the prepared binder does not contain harmful components for iron and steel smelting. It is used for bonding metallurgical lump coke made from coke powder, and has high fixed carbon content, It has the characteristics of good temperature resistance strength and good combustion performance.
具体实施方式 Detailed ways
实施例1Example 1
把50kg水、6kg淀粉和0.06kg纯碱混合均匀,加热至60℃,在加热过程中不断搅拌30分钟,搅拌速度为20转/分钟,使之成为浆糊。然后再把所制浆糊与30kg膨润土、粘结指数为75的烟煤粉(大于100目)50kg混合,并以30转/分钟的转速搅拌5分钟,使混合物充分均匀成膏状,得到块焦粘结剂。Mix 50kg of water, 6kg of starch and 0.06kg of soda ash evenly, heat to 60°C, stir continuously for 30 minutes during the heating process, and the stirring speed is 20 rpm to make it into a paste. Then mix the prepared paste with 30 kg of bentonite and 50 kg of bituminous coal powder (greater than 100 mesh) with a cohesive index of 75, and stir at a speed of 30 rpm for 5 minutes to make the mixture fully uniform into a paste and obtain a lump Burnt adhesive.
实施例2Example 2
把50kg水、6kg淀粉和0.06kg纯碱混合均匀,加热至60℃,在加热过程中不断搅拌30分钟,搅拌速度为20转/分钟,使之成为浆糊。然后再把所制浆糊与40kg膨润土、粘结指数为75的烟煤粉(大于100目)60kg混合,并以30转/分钟的转速搅拌5分钟,使混合物充分均匀成膏状,得到块焦粘结剂。Mix 50kg of water, 6kg of starch and 0.06kg of soda ash evenly, heat to 60°C, stir continuously for 30 minutes during the heating process, and the stirring speed is 20 rpm to make it into a paste. Then mix the prepared paste with 40kg of bentonite and 60kg of bituminous coal powder (greater than 100 mesh) with a cohesive index of 75, and stir for 5 minutes at a speed of 30 rpm to make the mixture fully uniform into a paste and obtain a lump Burnt adhesive.
实施例3Example 3
把50kg水、6kg淀粉和0.06kg纯碱混合均匀,加热至60℃,在加热过程中不断搅拌30分钟,搅拌速度为30转/分钟,使之成为浆糊。然后再把所制浆糊与50kg膨润土、粘结指数为75的烟煤粉(大于100目)40kg混合,并以30转/分钟的速度搅拌5分钟,使混合物充分均匀成膏状,得到块焦粘结剂。Mix 50kg of water, 6kg of starch and 0.06kg of soda ash evenly, heat to 60°C, and stir continuously for 30 minutes during the heating process at a stirring speed of 30 rpm to make a paste. Then mix the prepared paste with 50kg of bentonite and 40kg of bituminous coal powder (greater than 100 mesh) with a cohesive index of 75, and stir for 5 minutes at a speed of 30 rpm to make the mixture fully uniform into a paste and obtain a lump Burnt adhesive.
实施例4Example 4
把50kg水、8kg淀粉和0.08kg纯碱混合均匀,加热至60℃,在加热过程中不断搅拌30分钟,搅拌速度为20转/分钟,使之成为浆糊。然后再把所制浆糊与30kg膨润土、粘结指数为75的烟煤粉(大于100目)40kg混合,并以30转/分钟的速度搅拌5分钟,使混合物充分均匀成膏状,得到块焦粘结剂。Mix 50kg of water, 8kg of starch and 0.08kg of soda ash evenly, heat to 60°C, and stir continuously for 30 minutes during the heating process at a stirring speed of 20 rpm to make a paste. Then mix the prepared paste with 30 kg of bentonite and 40 kg of bituminous coal powder (greater than 100 mesh) with a cohesive index of 75, and stir for 5 minutes at a speed of 30 rpm to make the mixture fully uniform into a paste and obtain a lump Burnt adhesive.
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2009
- 2009-10-21 CN CN200910070888A patent/CN101696364A/en active Pending
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CN108300531A (en) * | 2018-02-07 | 2018-07-20 | 福建工程学院 | A kind of composite coal binder and preparation method thereof |
CN108300531B (en) * | 2018-02-07 | 2020-05-19 | 福建工程学院 | Composite briquette adhesive and preparation method thereof |
CN111363599A (en) * | 2020-04-15 | 2020-07-03 | 宁夏中润工贸有限公司 | Novel formed coke adhesive and method for preparing formed coke by using same |
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