CN101994166A - Negative ion polyvinyl chloride fiber for wig and preparation method thereof - Google Patents

Negative ion polyvinyl chloride fiber for wig and preparation method thereof Download PDF

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Publication number
CN101994166A
CN101994166A CN2009101682327A CN200910168232A CN101994166A CN 101994166 A CN101994166 A CN 101994166A CN 2009101682327 A CN2009101682327 A CN 2009101682327A CN 200910168232 A CN200910168232 A CN 200910168232A CN 101994166 A CN101994166 A CN 101994166A
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China
Prior art keywords
polyvinyl chloride
anion
wig
chloride fibre
wig according
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Pending
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CN2009101682327A
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Chinese (zh)
Inventor
郑有全
吴学丙
王依民
郭林峰
郭楠
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HENAN REBECCA HAIR PRODUCTS Inc
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HENAN REBECCA HAIR PRODUCTS Inc
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Priority to CN2009101682327A priority Critical patent/CN101994166A/en
Publication of CN101994166A publication Critical patent/CN101994166A/en
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Abstract

The invention provides negative ion polyvinyl chloride fiber for wig and a preparation method thereof. The negative ion fiber uses polyvinyl chloride resin as a base body, negative ion powder with the grain diameter between 0.1 and 3mu m, CPVC (chlorinated polyvinyl chloride) and PVC (polyvinyl) resin, stabilizing agents, auxiliary stabilizing agents, inner lubricating agents, outer lubricating agents, impact resistance modifying agents and pigment are added into the base body, the mixture is uniformly mixed in a mixing groove according to a certain proportion, and is fused into fused mass through a screw extruder, the fused mass is compressed and homogenized, then enters a spinning box body through a bended pipe to be distributed to each spinning position, and is finally sprayed out through a metering pump and a spinning assembly, fine flows of the sprayed fused mass are slowly cooled after being heated by a heating sleeve, and are then wound on a sleeve pipe after being oiled and moistened, the fiber is then stretched, retracted, cooled and formed to be made into finished fiber products, and the finished fiber products are used for preparing the wig after being packed.

Description

A kind of anion polyvinyl chloride fibre that is used for wig and preparation method thereof
Technical field:
The present invention relates to a kind of technology of preparing of functional form fiber, particularly a kind of technology of preparing that is used for the anion polyvinyl chloride fibre of wig.
Background technology:
Current, the hair products of being described as " fashionable dress on the head " by people have become " the new product gang " of fashional consumption, but present wig generally all only has decoration function, the wig product of functional form is also few in number, and the prepared negative-ion fiber of the present invention can be made anion far-infrared functional health wig.
Anion is meant atom, the atomic group (comprising molecule) that has negative electrical charge.Said anion is meant the oxonium ion that has negative electrical charge, hydration hydroxyl ion etc. among the present invention.A large amount of anions is contained in general waterfall, forest, high mountain, wilderness, and these places generally can make the people feel relaxed and joyful, and are happy.This is because anion has been brought into play its effect.For human body, anion has the cell metabolism of promotion, increases body's immunity, improves pulmonary function; Adjust blood pH, decompose cholesterol, make blood flow happy; Stable nerve, improvement are slept, are lessened fatigue; Anti-inflammatory analgetic impels multiple disease spontaneous recovery.For environment, anion has very high activity, very strong redox is arranged, can destroy the activity of bacterium or other material, therefore can purify air, adsorb micronic dust, eliminate peculiar smell (noxious odor that cigarette stink, chemicals or art work come out) etc.So sanatorium is arranged near high mountain, flowing water or the forest more.
The selected anion powder of the present invention has pyroelectricity and piezoelectricity, therefore under the situation that has temperature and pressure to change (even small variation), cause the electrical potential difference between the anion crystal, this static is up to 1,000,000 electron-volts, thereby make gas molecule generation ionization in the air, in near water and oxygen molecule, and made it be converted into negative aeroion by the electron attachment hit.
Anion powder also has far-infrared transmitting function, anion powder is because of its pyroelectricity and piezoelectricity, make its polarity ion cause that in the equilbrium position vibration dipole moment changes the electromagnetic radiation that produces far infrared band, and the anion powder polar molecule of blending by a certain percentage can fully be mixed in the texture of organic matter fiber, form uniform island structure with the nonpolar molecule group of fiber, have stronger radiation broadband, according to test negative ion health fiber to far emissivity more than 82%.Far infrared has excellent health care to human body.
The foreign study personnel find, when polyvinyl chloride fibre and human body rub mutually, can make negative electricity on the moisture subband floating in the surrounding air, quantity in every cubic centimetre can reach 880 to 2020, the reason that produces this phenomenon may be that the chlorosity in the polyvinyl chloride easily loses electronics, and very little energy just can make airborne particulate charged.But this anion quantity is equivalent to the level of town park to the greatest extent, is the level of keeping health, does not have treatment and function of health care.The present invention has overcome the complexity of polyvinyl chloride high pressure melt-spun, successfully the nano-negative ion powder is added in the polyvinyl chloride fibre, has prepared the anion far infrared health care type wig that can really be referred to as " Forest Bath ".
Use this health anion wig, to having cardiovascular and cerebrovascular disease, respiratory disease, the bad people of pulmonary function to have the fabulous function of improving, can eliminate human-body fatigue in addition, improve breathing environment, the people easily irritated to face also has fabulous prevention effect.
The anion polyvinyl chloride fibre of this method preparation is brought into play its effect except that being used for wig, and suitable adjusting process is prepared the negative ion health fiber of different fiber numbers.Can be made into fabric with this negative-ion fiber, be used for clothes, bedding, towel etc.; Also can make indoor ornament, as the wallpaper, carpet, slip cover, mat etc. of decoration usefulness; Can make short fiber, the preparation down toy; Can be used as medical woven cloths, as operating coat, nursing clothes, sick bed articles for use etc.; Filtering material be can prepare, air filtration, water filtration and water treatment aspect are used in.Thereby more fully bring into play its excellent anion far infrared health care function.
Summary of the invention:
The purpose of this invention is to provide a kind of preparation method who is used for the anion polyvinyl chloride fibre of wig, the anion far infrared wig that uses this fiber to make to have health care.This invention is achieved by the following technical solution.
A kind of anion polyvinyl chloride fibre that is used for wig provided by the invention, with the Corvic is matrix, adds anion powder, CPVC, polyvinyl chloride resin, stabilizing agent, auxiliary stabilizer, in-lubricant, external lubricant, impact modifier, the pigment of particle diameter at 0.1-3 μ m.
Described anion powder, particle diameter is at 0.1-3 μ m, and anion powder can comprise one or more anion materials, adds 1-10 (wt) % that total amount accounts for total mixture.
Described CPVC is meant extrusion grade CPVC resin, and addition is 8-15 (wt) %.
Described polyvinyl chloride resin is meant the loose type of suspension method production, and addition is 70-90 (wt) %.
Described stabilizing agent is meant calcium-zinc composite stabilizer, comprises liquid or powder calcium-zinc stabilizer, and addition is 2-5 (wt) %.
Described auxiliary stabilizer is meant two or three in beta-diketon stabilizing agent, epoxidized soybean oil, the metaphosphate, adds total amount at 0.02-0.2 (wt) %.
Described in-lubricant is meant one or both in aliphatic acid, fatty acid ester, the fatty alcohol, and addition is at 0.01-0.1 (wt) %.
Described external lubricant is meant natural or synthetic paraffin, comprises polyolefin-wax and paraffin, and addition is 0.02-0.2 (wt) %.
Described impact modifier is meant one or more the combination in the mentioned reagent of CPE, the MBS, ACR, ABS, NBR and the nano modification that are fit to the hard PVC goods, and addition is 0.5-3 (wt) %.
A kind of anion polyvinyl chloride fibre preparation method who is used for wig provided by the invention may further comprise the steps:
(1) anion powder, CPVC, polyvinyl chloride resin, stabilizing agent, auxiliary stabilizer, in-lubricant, external lubricant, impact modifier, pigment were evenly mixed 15-30 minute at the high-speed mixing groove, temperature 100-110 ℃, rotating speed 600-900rpm, use mixed on low speed groove low-temperature mixed 5-10 minute again, temperature 50-80 ℃, rotating speed 100-200rpm evenly mix.
(2) step (1) gained mixed material is melt into melt through screw extruder, 160-175 ℃ of screw extruder temperature, rotating speed 15-20rpm, pressure 250-450kg, 6-8kg/Hr.Melt is compressed, homogenizing enters spinning manifold by the screw rod head through bend pipe, be assigned to each spinning part, behind measuring pump, filament spinning component and spray, the melt thread of ejection heats and slow cooling through heating jacket, 350-400 ℃ of heating muff temperature, winding speed 20-80 rice/minute, be wound on the bobbin through the oil supply dewing then.
(3) fiber of step (2) gained is finalized the design through hot-stretch, retraction, cooling again, thereby make finished fiber, finished fiber is used for preparing wig after packing.Heat treatment temperature 95-110 ℃, draw ratio can be regulated according to the purposes difference, scope at 3-6 doubly, 100-110 ℃ of heat retraction temperature, hot relaxation shrinkage 25-30%.
The specific embodiment
Below in conjunction with specific embodiment, further set forth the present invention.Should be understood that these embodiment only to be used to the present invention is described and be not used in the scope of the present invention that limits.Should be understood that in addition those skilled in the art can make various changes or modifications the present invention after the content of reading the present invention's instruction, these equivalent form of values fall within the application's appended claims institute restricted portion equally.
Embodiment 1
With polyvinyl chloride resin, CPVC (8wt%), particle diameter is at the anion powder (3wt%) of 0.1-3 μ m, stabilizing agent (liquid Ca-Zn stabilizing agent, 3wt%), auxiliary stabilizer (beta-diketon stabilizing agent, epoxidized soybean oil, each 0.1wt%), in-lubricant (fatty acid ester, 0.05wt%), and external lubricant (oxidized paraffin wax, 0.1wt%), impact modifier (MBS, 1wt%), dark-brown pigment (2wt%) etc., the high-speed mixing groove evenly mix 30 minutes (temperature 105-110 ℃, rotating speed 650rpm) after, uses (temperature 60-70 ℃ of mixed on low speed groove low temperature again, rotating speed 150rpm) mixed 10 minutes.
Compound is melt into melt through screw extruder, melt is compressed, homogenizing enters spinning manifold by the screw rod head through bend pipe, be assigned to each spinning part, behind measuring pump, filament spinning component and spray, the melt thread of ejection is through heating jacket heating and slow cooling is wound on the bobbin through the oil supply dewing then.Fiber is finalized the design through hot-stretch, retraction, cooling again.160 ℃ of screw extruder temperature, screw speed 20rpm, pressure 300-450kg, 6.5kg/Hr, 350 ℃ of heating muff temperature, 30 meters/minute of winding speeds, heat treatment temperature 95-105 ℃, 3.5 times of draw ratios, 100-105 ℃ of heat retraction temperature, hot relaxation shrinkage about 25%.
Embodiment 2
With polyvinyl chloride resin, CPVC (12wt%), particle diameter is at the anion powder (8wt%) of 0.1-3 μ m, stabilizing agent (powder Ca-Zn stabilizing agent, 3.5wt%), auxiliary stabilizer (beta-diketon stabilizing agent, epoxidized soybean oil, metaphosphate, each 0.08wt%), in-lubricant (aliphatic acid, fatty acid ester, each 0.04wt%), and external lubricant (polyolefin-wax, 0.1wt%), impact modifier (MBS, 2wt%), black pigment (1.5wt%) etc., the high-speed mixing groove evenly mix 20 minutes (temperature 105-110 ℃, rotating speed 800rpm) after, uses (temperature 50-60 ℃ of mixed on low speed groove low temperature again, rotating speed 100rpm) mixed 5 minutes.
Compound is melt into melt through screw extruder, melt is compressed, homogenizing enters spinning manifold by the screw rod head through bend pipe, be assigned to each spinning part, behind measuring pump, filament spinning component and spray, the melt thread of ejection is through heating jacket heating and slow cooling is wound on the bobbin through the oil supply dewing then.Fiber is finalized the design through hot-stretch, retraction, cooling again.170 ℃ of screw extruder temperature, screw speed 18rpm, pressure 250-350kg, 7.5kg/Hr, 400 ℃ of heating muff temperature, 60 meters/minute of winding speeds, heat treatment temperature 100-110 ℃, 4 times of draw ratios, 105-110 ℃ of heat retraction temperature, hot relaxation shrinkage about 30%.

Claims (17)

1. anion polyvinyl chloride fibre that is used for wig, it is characterized in that: be matrix with the Corvic, add nano-negative ion powder, CPVC, polyvinyl chloride resin, stabilizing agent, auxiliary stabilizer, in-lubricant, external lubricant, impact modifier, the pigment of particle diameter at 0.1-3 μ m.
2. a kind of anion polyvinyl chloride fibre that is used for wig according to claim 1, it is characterized in that: wherein said anion powder particle diameter is at 0.1-3 μ m, anion powder can comprise one or more anion materials, adds 1-10 (wt) % that total amount accounts for total mixture.
3. a kind of anion polyvinyl chloride fibre that is used for wig according to claim 1, it is characterized in that: wherein said CPVC is meant extrusion grade CPVC resin, addition is 8-15 (wt) %.
4. a kind of anion polyvinyl chloride fibre that is used for wig according to claim 1 is characterized in that: wherein said polyvinyl chloride resin is meant the loose type of suspension method production, and addition is 70-90 (wt) %.
5. a kind of anion polyvinyl chloride fibre that is used for wig according to claim 1, it is characterized in that: wherein said stabilizing agent is meant calcium-zinc composite stabilizer, comprises liquid or powder calcium-zinc stabilizer, addition is 2-5 (wt) %.
6. a kind of anion polyvinyl chloride fibre that is used for wig according to claim 1, it is characterized in that: auxiliary stabilizer is meant two or three in beta-diketon stabilizing agent, epoxidized soybean oil, the metaphosphate, adds total amount at 0.02-0.2 (wt) %.
7. a kind of anion polyvinyl chloride fibre that is used for wig according to claim 1, it is characterized in that: in-lubricant is meant one or both in aliphatic acid, fatty acid ester, the fatty alcohol, addition is at 0.01-0.1 (wt) %.
8. a kind of anion polyvinyl chloride fibre that is used for wig according to claim 1 is characterized in that: external lubricant is meant natural or synthetic paraffin, comprises polyolefin-wax and paraffin, and addition is 0.02-0.2 (wt) %.
9. a kind of anion polyvinyl chloride fibre that is used for wig according to claim 1, it is characterized in that: impact modifier is meant one or more the combination in the mentioned reagent of CPE, the MBS, ACR, ABS, NBR and the nano modification that are fit to the hard PVC goods, and addition is 0.5-3%.
10. anion polyvinyl chloride fibre preparation method who is used for wig is characterized in that: may further comprise the steps:
(1) with anion powder, CPVC, polyvinyl chloride resin, stabilizing agent, auxiliary stabilizer, in-lubricant, external lubricant, impact modifier, pigment after the high-speed mixing groove evenly mixes 15-30 minute, use mixed on low speed groove low-temperature mixed 5-10 minute again, evenly mix.
(2) step (1) gained mixed material is melt into melt through screw extruder, melt is compressed, homogenizing enters spinning manifold by the screw rod head through bend pipe, be assigned to each spinning part, behind measuring pump, filament spinning component and spray, the melt thread of ejection is through heating jacket heating and slow cooling is wound on the bobbin through the oil supply dewing then.
(3) fiber of step (2) gained is finalized the design through hot-stretch, retraction, cooling again, thereby makes finished fiber, and finished fiber is used for preparing wig after packing.
11. a kind of anion polyvinyl chloride fibre preparation method who is used for wig according to claim 9 is characterized in that: the temperature 100-110 of described high-speed mixing groove ℃, rotating speed 600-900rpm.
12. a kind of anion polyvinyl chloride fibre preparation method who is used for wig according to claim 9 is characterized in that: the temperature 50-80 of described mixed on low speed groove ℃, rotating speed 100-200rpm.
13. a kind of anion polyvinyl chloride fibre preparation method who is used for wig according to claim 9 is characterized in that: 160-175 ℃ of described screw extruder temperature, screw speed 15-20rpm, pressure 250-450kg, 6-8kg/Hr.
14. a kind of anion polyvinyl chloride fibre preparation method who is used for wig according to claim 9 is characterized in that: 350-400 ℃ of heating muff temperature, winding speed 20-80 rice/minute.
15. a kind of anion polyvinyl chloride fibre preparation method who is used for wig according to claim 9 is characterized in that: described heat treatment temperature 95-110 ℃.
16. a kind of anion polyvinyl chloride fibre preparation method who is used for wig according to claim 9, it is characterized in that: draw ratio can be regulated according to the purposes difference, and scope at 3-6 doubly.
17. a kind of anion polyvinyl chloride fibre preparation method who is used for wig according to claim 9 is characterized in that: 105-110 ℃ of heat retraction temperature, hot relaxation shrinkage 25-30%.
CN2009101682327A 2009-08-17 2009-08-17 Negative ion polyvinyl chloride fiber for wig and preparation method thereof Pending CN101994166A (en)

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Application Number Priority Date Filing Date Title
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102677276A (en) * 2012-05-29 2012-09-19 蔡紫林 Fabric
CN102778374A (en) * 2012-07-10 2012-11-14 东华大学 Method for preparing polyvinyl chloride standard fiber sample
CN103504677A (en) * 2012-06-21 2014-01-15 保利源(南通)实业有限公司 Raw hair buckling technology for artificial hair
CN104674364A (en) * 2015-03-04 2015-06-03 佛山市迭蓓丝生物科技有限公司 Profile fiber and preparation method thereof
CN105361310A (en) * 2015-03-25 2016-03-02 株式会社松风 Manufacturing method of grafting eyelashes, grafting eyelashes and installation method of grafting eyelashes
CN107587200A (en) * 2017-07-19 2018-01-16 宜宾运通塑料助剂有限公司 A kind of fusion method spinning-drawing machine, chlorinated polyvinyl chloride fibre and preparation method thereof
CN110079885A (en) * 2019-05-23 2019-08-02 佳莱科技有限公司 A kind of iodine system antibacterial fabric and its processing technology and application
CN111549394A (en) * 2020-05-15 2020-08-18 许昌鸿洋生化实业发展有限公司 Antibacterial optically variable polyvinyl chloride wig fiber and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1278026A (en) * 1999-06-16 2000-12-27 尤诺纤维有限公司 Poly vinyl chloride fiber with improved thermal shrinkage
JP2003293217A (en) * 2002-03-29 2003-10-15 Denki Kagaku Kogyo Kk Polyvinyl chloride-based fiber
CN101173078A (en) * 2006-10-31 2008-05-07 天津百龙塑钢门窗异型材制品有限公司 Health care polyvinyl chloride master batch capable of releasing negative ion

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1278026A (en) * 1999-06-16 2000-12-27 尤诺纤维有限公司 Poly vinyl chloride fiber with improved thermal shrinkage
JP2003293217A (en) * 2002-03-29 2003-10-15 Denki Kagaku Kogyo Kk Polyvinyl chloride-based fiber
CN101173078A (en) * 2006-10-31 2008-05-07 天津百龙塑钢门窗异型材制品有限公司 Health care polyvinyl chloride master batch capable of releasing negative ion

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102677276A (en) * 2012-05-29 2012-09-19 蔡紫林 Fabric
CN103504677A (en) * 2012-06-21 2014-01-15 保利源(南通)实业有限公司 Raw hair buckling technology for artificial hair
CN102778374A (en) * 2012-07-10 2012-11-14 东华大学 Method for preparing polyvinyl chloride standard fiber sample
CN104674364A (en) * 2015-03-04 2015-06-03 佛山市迭蓓丝生物科技有限公司 Profile fiber and preparation method thereof
CN105361310A (en) * 2015-03-25 2016-03-02 株式会社松风 Manufacturing method of grafting eyelashes, grafting eyelashes and installation method of grafting eyelashes
CN107587200A (en) * 2017-07-19 2018-01-16 宜宾运通塑料助剂有限公司 A kind of fusion method spinning-drawing machine, chlorinated polyvinyl chloride fibre and preparation method thereof
CN110079885A (en) * 2019-05-23 2019-08-02 佳莱科技有限公司 A kind of iodine system antibacterial fabric and its processing technology and application
CN111549394A (en) * 2020-05-15 2020-08-18 许昌鸿洋生化实业发展有限公司 Antibacterial optically variable polyvinyl chloride wig fiber and preparation method thereof
CN111549394B (en) * 2020-05-15 2021-08-31 许昌鸿洋生化实业发展有限公司 Antibacterial optically variable polyvinyl chloride wig fiber and preparation method thereof

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Application publication date: 20110330