CN101983916B - Method for production of calcium chlorate and coproduction of ultra-fine calcium carbonate and sodium chloride by using acetylene sludge - Google Patents
Method for production of calcium chlorate and coproduction of ultra-fine calcium carbonate and sodium chloride by using acetylene sludge Download PDFInfo
- Publication number
- CN101983916B CN101983916B CN2010101690720A CN201010169072A CN101983916B CN 101983916 B CN101983916 B CN 101983916B CN 2010101690720 A CN2010101690720 A CN 2010101690720A CN 201010169072 A CN201010169072 A CN 201010169072A CN 101983916 B CN101983916 B CN 101983916B
- Authority
- CN
- China
- Prior art keywords
- calcium
- chlor
- sodium
- chlorate
- carbide slag
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- YALMXYPQBUJUME-UHFFFAOYSA-L calcium chlorate Chemical compound [Ca+2].[O-]Cl(=O)=O.[O-]Cl(=O)=O YALMXYPQBUJUME-UHFFFAOYSA-L 0.000 title claims abstract description 40
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 title claims abstract description 22
- 229910000019 calcium carbonate Inorganic materials 0.000 title claims abstract description 11
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 title abstract description 4
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 title abstract description 4
- 238000004519 manufacturing process Methods 0.000 title abstract description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 title abstract 8
- 239000011780 sodium chloride Substances 0.000 title abstract 4
- 239000010802 sludge Substances 0.000 title abstract 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 29
- 239000001110 calcium chloride Substances 0.000 claims abstract description 29
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 29
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 22
- 239000007787 solid Substances 0.000 claims abstract description 19
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims abstract description 16
- 239000000920 calcium hydroxide Substances 0.000 claims abstract description 16
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims abstract description 16
- 239000003513 alkali Substances 0.000 claims abstract description 14
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 11
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 9
- 239000004094 surface-active agent Substances 0.000 claims abstract description 9
- 238000005260 corrosion Methods 0.000 claims abstract description 7
- 230000007797 corrosion Effects 0.000 claims abstract description 7
- 239000012535 impurity Substances 0.000 claims abstract description 6
- 238000005660 chlorination reaction Methods 0.000 claims description 42
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims description 37
- 239000002893 slag Substances 0.000 claims description 35
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 20
- 238000006243 chemical reaction Methods 0.000 claims description 16
- 239000000047 product Substances 0.000 claims description 16
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 14
- 239000000460 chlorine Substances 0.000 claims description 14
- 229910052801 chlorine Inorganic materials 0.000 claims description 14
- 239000000126 substance Substances 0.000 claims description 11
- 238000005406 washing Methods 0.000 claims description 11
- 239000012065 filter cake Substances 0.000 claims description 10
- 235000017550 sodium carbonate Nutrition 0.000 claims description 10
- 239000002002 slurry Substances 0.000 claims description 9
- 239000011575 calcium Substances 0.000 claims description 7
- 238000004062 sedimentation Methods 0.000 claims description 7
- 238000004380 ashing Methods 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 238000000643 oven drying Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 5
- ZHLKXBJTJHRTTE-UHFFFAOYSA-N Chlorobenside Chemical compound C1=CC(Cl)=CC=C1CSC1=CC=C(Cl)C=C1 ZHLKXBJTJHRTTE-UHFFFAOYSA-N 0.000 claims description 5
- 239000013543 active substance Substances 0.000 claims description 5
- 229910052791 calcium Inorganic materials 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 claims description 5
- 238000010298 pulverizing process Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 239000004495 emulsifiable concentrate Substances 0.000 claims description 4
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 4
- 229920000053 polysorbate 80 Polymers 0.000 claims description 4
- 238000001914 filtration Methods 0.000 abstract description 4
- 239000000706 filtrate Substances 0.000 abstract 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 abstract 1
- 239000011259 mixed solution Substances 0.000 abstract 1
- 239000002244 precipitate Substances 0.000 abstract 1
- 230000001376 precipitating effect Effects 0.000 abstract 1
- 238000002156 mixing Methods 0.000 description 6
- 239000007788 liquid Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 239000005997 Calcium carbide Substances 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 1
- CLZWAWBPWVRRGI-UHFFFAOYSA-N tert-butyl 2-[2-[2-[2-[bis[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]amino]-5-bromophenoxy]ethoxy]-4-methyl-n-[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]anilino]acetate Chemical compound CC1=CC=C(N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)C(OCCOC=2C(=CC=C(Br)C=2)N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)=C1 CLZWAWBPWVRRGI-UHFFFAOYSA-N 0.000 description 1
Images
Landscapes
- Processing Of Solid Wastes (AREA)
Abstract
The invention discloses a method for production of calcium chlorate and coproduction of ultra-fine calcium carbonate and sodium chloride by using acetylene sludge, which comprises the following steps: generating reaction products containing the calcium chlorate and calcium chloride by leading calcium hydroxide in chlor-alkali acetylene sludge to be reacted with chlorine gas; filtering the reaction products, removing impurities, reducing temperature, settling, then precipitating calcium chlorate solids, further filtering, and obtaining the calcium chlorate solids and calcium chloride filtrate; and carrying out treatment on the calcium chloride filtrate by using a surfactant, then being reacted with sodium carbonate in a corrosion-resistant reactor, obtaining calcium carbonate precipitate and sodium chloride mixed solution, filtering and separating the calcium carbonate and the sodium chloride.
Description
Technical field
The present invention relates to chlor-alkali carbide slag comprehensive utilization field, particularly, relate to a kind of method of producing calcium chlorate co-producing ultra-fine lime carbonate and sodium-chlor with carbide slag.
Background technology
The waste residue that carbide slag produces when being calcium carbide production acetylene, staple is Ca (OH)
2, also contain small amount of Fe
2O
3, SiO
2And Al
2O
3Oxide compound, oxyhydroxide and a small amount of organism on metal.Carbide slag is the important channel that utilizes carbide slag in a large number as cement producting material, has not only solved carbide slag exhaust emission problem of environment, has realized the comprehensive cyclic utilization of resource, has also practiced thrift limestone resource simultaneously, has also reduced emission amount of carbon dioxide.Yet along with the industrialized development of China, the carbide slag YO enlarges day by day.Press knowhow, 1 ton of polyvinyl chloride product of every production will be discharged about 20 tons of carbide slag slurries.The carbide slag water ratio reaches 40%～50%, is starchiness, and easy to leak pollutes the road surface in transit, and long-term accumulation not only takies a large amount of soils, and there is serious erosion action in the soil.Want to tackle the problem at its root, have only and seek technically to break through, seek new improvement technology, comprehensive utilization turns harm into good, and turns waste into wealth.
Summary of the invention
To the problems referred to above; The invention provides a kind of method of producing calcium chlorate co-producing ultra-fine lime carbonate and sodium-chlor with carbide slag; This method is utilized the calcium hydroxide in the chlor-alkali carbide slag, has generated calcium chlorate and coproduction Potcrate and calcium chloride, for Comprehensive Utilization for Carbide Slag provides new approach.
The present invention realizes through following technical scheme: a kind of method of producing calcium chlorate co-producing ultra-fine lime carbonate and sodium-chlor with carbide slag comprises the steps:
A: the chlor-alkali carbide slag is dropped into ashing pond (1), and water reconciles into emulsion, and makes the content of calcium hydroxide reach 120g/L;
B: steps A gained carbide slag is delivered to chlorination tower (2), simultaneously, according to calcium hydroxide and chlorine pure substance mass ratio be 1: 0.70～1.16 in chlorination tower (2) input chlorine, carry out chlorination reaction, obtain the reaction product of chloracid calcium and calcium chloride;
C: step B gained reaction product is filtered with first strainer (4), remove solid impurity, filtrating is filtered through second strainer (6) after slurry tank (5) cooling sedimentation again, obtains calcium chlorate solid and the filtrating that contains calcium chloride;
D: the calcium chlorate solid obtains calcium chlorate product (13) through the oven dry down of oven drying at low temperature machine (7) low temperature;
E: the calcium chloride that step C obtains is filtrated with 4～8% surfactant treatment, and stir speed (S.S.) is 200～320r/min;
F: the filtrating of the calcium chloride after the surfactant treatment of step e gained is dropped in the corrosion-resistant reactor (8); Mass ratio 1: 0.66～0.95 according to calcium chloride and yellow soda ash pure substance drops into yellow soda ash simultaneously; Carry out chemical reaction, obtain the mixture of ZG 301 and sodium-chlor;
G: just the mixture of the ZG 301 of step F gained and sodium-chlor filters through the 3rd strainer (9), obtains white filter cake and clarifying sodium-chlor filtrating (14);
H: white filter cake obtains light calcium carbonate finished product (15) through washing whizzer (10) washing, dry, kibbler (12) pulverizing of drying machine (11);
I: clarifying sodium-chlor filtrating is returned the chlor-alkali workshop and is recycled.
Among the step B, the control chlorination reaction temperature keeps reaction soln not seethe with excitement.
Among the step B, show reaction end, when the indicator of chlorination table (3) is fixed, show that solution no longer absorbs chlorine, reach degree of depth chlorination, be chlorination and finish with chlorination table (3).
Among the step C, slurry tank cools to 60 ℃ promptly has the sedimentation of solid calcium chlorate, and 1～2 hour begins to filter after settling temperature reaches normal temperature.
Said tensio-active agent is selected from emulsifiable concentrate, tween 80 and the mixture of the two.
The chemical equation of aforesaid method is:
6Ca(OH)
2+6Cl
2＝＝＝Ca(ClO
3)
2+5CaCl
2+6H
2O
CaCl
2+Na
2CO
3＝＝＝CaCO
3+2NaCl
Beneficial effect of the present invention is: method of producing calcium chlorate co-producing ultra-fine lime carbonate and sodium-chlor with carbide slag of the present invention; Make full use of the calcium hydroxide in the chlor-alkali carbide slag, generated calcium chlorate coproduction light calcium carbonate and sodium-chlor, for Comprehensive Utilization for Carbide Slag provides new approach; This method can be accomplished through reaction for several times and filtration; Operation steps is simple, and facility investment is lower, is a cost-effective method of ten minutes.
Description of drawings
Fig. 1 showed and of the present inventionly produced the technical process of the method for calcium chlorate co-producing ultra-fine lime carbonate and sodium-chlor with carbide slag, wherein:
(1) ashing pond, (2) chlorination tower, (3) chlorination table, (4) first strainers, (5) slurry tank,
(6) second strainers, (7) oven drying at low temperature machine, (8) corrosion-resistant reactor, (9) the 3rd strainers,
(10) washing whizzer, (11) drying machine, (12) kibbler, (13) calcium chlorate product,
(14) sodium-chlor filtrating, (15) lime carbonate finished product.
Embodiment
Describedly for a better understanding of the present invention produce the essence of the method for calcium chlorate co-producing ultra-fine lime carbonate and sodium-chlor, below will combine specific embodiment that the present invention is done further description and explanation with carbide slag.
A kind of method of producing calcium chlorate coproduction fine calcium carbonate and sodium-chlor with carbide slag comprises the steps:
A: the chlor-alkali carbide slag that will contain 100kg calcium hydroxide drops into ashing pond (1), and water reconciles into emulsion, and makes the content of calcium hydroxide reach every liter 120 gram;
B: steps A gained carbide slag is delivered to chlorination tower (2) with first pressure pump; Simultaneously; Input chlorine in chlorination tower (2), making calcium hydroxide and chlorine pure substance mass ratio is to carry out chlorination reaction at 1: 1.16, controls chlorination reaction temperature; Keep reaction soln not seethe with excitement, chlorination reaction generates the reaction product of chloracid calcium and calcium chloride; Show reaction end with chlorination table (3), when the indicator of chlorination table (3) is fixed, show that solution no longer absorbs chlorine, reach degree of depth chlorination, be chlorination and finish;
C: step B gained liquid reacting product is filtered with first strainer (4), remove solid impurity, filtrating is filtered through second strainer (6) after slurry tank (5) cooling sedimentation again, obtains calcium chlorate solid and calcium chloride filtrating;
D: the calcium chlorate solid obtains calcium chlorate product (13) through the oven dry down of oven drying at low temperature machine (7) low temperature;
E: the calcium chloride filtrating use mass concentration that step C is obtained is that 4% tensio-active agent emulsifiable concentrate is handled, and stir speed (S.S.) is 200r/min;
F: the filtrating of the calcium chloride after the surfactant treatment of step e gained is dropped in the corrosion-resistant reactor (8), and the mass ratio 0.95 according to calcium chloride and yellow soda ash pure substance drops into yellow soda ash simultaneously, carries out chemical reaction, generates lime carbonate and sodium-chlor mixing solutions;
G: lime carbonate and sodium-chlor mixing solutions are filtered through the 3rd strainer (9), obtain white filter cake and clarifying sodium-chlor filtrating (14);
H: white filter cake obtains light calcium carbonate finished product (15) through washing whizzer (10) washing, dry, kibbler (12) pulverizing of drying machine (11);
I: clarifying sodium-chlor filtrating is returned the chlor-alkali workshop and is recycled.
A kind of method of producing calcium chlorate co-producing ultra-fine lime carbonate and sodium-chlor with carbide slag comprises the steps:
A: the chlor-alkali carbide slag that will contain 100kg calcium hydroxide drops into ashing pond (1), and water reconciles into emulsion, and makes the content of calcium hydroxide reach every liter 120 gram;
B: deliver to chlorination tower (2) with first pressure pump; Simultaneously; Input chlorine in chlorination tower (2), making calcium hydroxide and chlorine pure substance mass ratio is to carry out chlorination reaction at 1: 0.76, controls chlorination reaction temperature; Keep reaction soln not seethe with excitement, chlorination reaction generates the reaction product of chloracid calcium and calcium chloride; Show reaction end with chlorination table (3), when the indicator of chlorination table (3) is fixed, show that solution no longer absorbs chlorine, reach degree of depth chlorination, be chlorination and finish;
C: step B gained liquid reacting product is filtered with first strainer (4), remove solid impurity, filtrating is filtered through second strainer (6) after slurry tank (5) cooling sedimentation again, obtains calcium chlorate solid and calcium chloride filtrating;
D: the calcium chlorate solid obtains calcium chlorate product (13) through the oven dry down of oven drying at low temperature machine (7) low temperature;
E: it is 8% surfactant treatment that the calcium chloride filtrating that step C is obtained is used mass concentration, and wherein to contain mass concentration be that 4% emulsifiable concentrate and mass concentration are 2% tween 80 to tensio-active agent, and stir speed (S.S.) is 250r/min;
F: the filtrating of the calcium chloride after the surfactant treatment of step e gained is dropped in the corrosion-resistant reactor (8); Mass ratio according to calcium chloride and yellow soda ash pure substance drops into yellow soda ash at 1: 0.66 simultaneously; Carry out chemical reaction, generate lime carbonate and sodium-chlor mixing solutions;
G: lime carbonate and sodium-chlor mixing solutions are filtered through the 3rd strainer (9), obtain white filter cake and clarifying sodium-chlor filtrating (14);
H: white filter cake obtains light calcium carbonate finished product (15) through washing whizzer (10) washing, dry, kibbler (12) pulverizing of drying machine (11);
I: clarifying sodium-chlor filtrating is returned the chlor-alkali workshop and is recycled.
A kind of method of producing calcium chlorate co-producing ultra-fine lime carbonate and sodium-chlor with carbide slag comprises the steps:
A: the chlor-alkali carbide slag that will contain 100kg calcium hydroxide drops into ashing pond (1), and water reconciles into emulsion, and makes the content of calcium hydroxide reach every liter 120 gram;
B: deliver to chlorination tower (2) with first pressure pump; Simultaneously; Input chlorine in chlorination tower (2), making calcium hydroxide and chlorine pure substance mass ratio is to carry out chlorination reaction at 1: 1.00, controls chlorination reaction temperature; Keep reaction soln not seethe with excitement, chlorination reaction generates the reaction product of chloracid calcium and calcium chloride; Show reaction end with chlorination table (3), when the indicator of chlorination table (3) is fixed, show that solution no longer absorbs chlorine, reach degree of depth chlorination, be chlorination and finish;
C: step B gained liquid reacting product is filtered with first strainer (4), remove solid impurity, filtrating is filtered through second strainer (6) after slurry tank (5) cooling sedimentation again, obtains calcium chlorate solid and calcium chloride filtrating;
D: the calcium chlorate solid obtains calcium chlorate product (13) through the oven dry down of oven drying at low temperature machine (7) low temperature;
E: it is that 8% tensio-active agent tween 80 is handled that the calcium chloride filtrating that step C is obtained is used mass concentration, and stir speed (S.S.) is 320r/min;
F: the filtrating of the calcium chloride after the surfactant treatment of step e gained is dropped in the corrosion-resistant reactor (8); Mass ratio according to calcium chloride and yellow soda ash pure substance drops into yellow soda ash at 1: 0.86 simultaneously; Carry out chemical reaction, generate lime carbonate and sodium-chlor mixing solutions;
G: lime carbonate and sodium-chlor mixing solutions are filtered through the 3rd strainer (9), obtain white filter cake and clarifying sodium-chlor filtrating (14);
H: white filter cake obtains light calcium carbonate finished product (15) through washing whizzer (10) washing, dry, kibbler (12) pulverizing of drying machine (11);
I: clarifying sodium-chlor filtrating is returned the chlor-alkali workshop and is recycled.
The foregoing description is preferred embodiment of the present invention, is not to be used for limiting practical range of the present invention, so all equivalences of being done with described characteristic of claim of the present invention and principle change or modify, all should be included within the claim scope of the present invention.
Claims (5)
1. a method of producing calcium chlorate co-producing ultra-fine lime carbonate and sodium-chlor with carbide slag is characterized in that, comprises the steps:
A: the chlor-alkali carbide slag is dropped into ashing pond (1), and water reconciles into emulsion, and makes the content of calcium hydroxide reach 120g/L;
B: steps A gained carbide slag is delivered to chlorination tower (2), simultaneously, according to calcium hydroxide and chlorine pure substance mass ratio be 1: 0.70～1.16 in chlorination tower (2) input chlorine, carry out chlorination reaction, obtain the reaction product of chloracid calcium and calcium chloride;
C: step B gained reaction product is filtered with first strainer (4), remove solid impurity, filtrating is filtered through second strainer (6) after slurry tank (5) cooling sedimentation again, obtains calcium chlorate solid and the filtrating that contains calcium chloride;
D: the calcium chlorate solid obtains calcium chlorate product (13) through the oven dry down of oven drying at low temperature machine (7) low temperature;
E: the calcium chloride filtrating use mass concentration that step C is obtained is 4～8% surfactant treatment, and stir speed (S.S.) is 200～320r/min;
F: the filtrating of the calcium chloride after the surfactant treatment of step e gained is dropped in the corrosion-resistant reactor (8); Mass ratio 1: 0.66～0.95 according to calcium chloride and yellow soda ash pure substance drops into yellow soda ash simultaneously; Carry out chemical reaction, obtain the mixture of ZG 301 and sodium-chlor;
G: the ZG 301 of step F gained and the mixture of sodium-chlor are filtered through the 3rd strainer (9), obtain white filter cake and clarifying sodium-chlor filtrating (14);
H: white filter cake obtains light calcium carbonate finished product (15) through washing whizzer (10) washing, dry, kibbler (12) pulverizing of drying machine (11);
I: clarifying sodium-chlor filtrating is returned the chlor-alkali workshop and is recycled.
2. method of producing calcium chlorate co-producing ultra-fine lime carbonate and sodium-chlor with carbide slag as claimed in claim 1 is characterized in that, among the step B, the control chlorination reaction temperature keeps reaction soln not seethe with excitement.
3. method of producing calcium chlorate co-producing ultra-fine lime carbonate and sodium-chlor with carbide slag as claimed in claim 1 is characterized in that, among the step B, shows reaction end with chlorination table (3).
4. method of producing calcium chlorate co-producing ultra-fine lime carbonate and sodium-chlor with carbide slag as claimed in claim 1; It is characterized in that; Among the step C, slurry tank cools to 60 ℃ promptly has the sedimentation of solid calcium chlorate, and 1～2 hour begins to filter after settling temperature reaches normal temperature.
5. method of producing calcium chlorate co-producing ultra-fine lime carbonate and sodium-chlor with carbide slag as claimed in claim 1 is characterized in that said tensio-active agent is selected from emulsifiable concentrate, tween 80 and the mixture of the two.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101690720A CN101983916B (en) | 2010-04-30 | 2010-04-30 | Method for production of calcium chlorate and coproduction of ultra-fine calcium carbonate and sodium chloride by using acetylene sludge |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101690720A CN101983916B (en) | 2010-04-30 | 2010-04-30 | Method for production of calcium chlorate and coproduction of ultra-fine calcium carbonate and sodium chloride by using acetylene sludge |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101983916A CN101983916A (en) | 2011-03-09 |
| CN101983916B true CN101983916B (en) | 2012-06-20 |
Family
ID=43641084
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010101690720A Expired - Fee Related CN101983916B (en) | 2010-04-30 | 2010-04-30 | Method for production of calcium chlorate and coproduction of ultra-fine calcium carbonate and sodium chloride by using acetylene sludge |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101983916B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3064473A1 (en) * | 2015-03-02 | 2016-09-07 | Solvay SA | Process for manufacturing an aqueous sodium chloride solution |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101580258A (en) * | 2009-04-08 | 2009-11-18 | 王嘉兴 | Method for preparing nano active calcium carbonate series products and ammonium chloride by carbide slag |
-
2010
- 2010-04-30 CN CN2010101690720A patent/CN101983916B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN101983916A (en) | 2011-03-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106044799B (en) | Titanium chloride slag and its method for comprehensive utilization of filtrate in chloride process titanium dioxide powder craft | |
| UA123164C2 (en) | Molten-salt chlorinated-slag resource processing method | |
| CN104016398A (en) | Method of producing sulfate by using dilute sulphuric acid in industrial wastewater | |
| CN110078108A (en) | A method of precipitated calcium carbonate is prepared by raw material of carbide slag | |
| CN109607572A (en) | A method of comprehensive utilization subsurface brine production refined brine and calcium and magnesium compound | |
| CN101823745B (en) | Method for producing super-fine light-weighted calcium carbonate, ammonium chloride and carbon powder with waste associated alkali solution and acetylene sludge | |
| CN101823736B (en) | Method for co-production of calcium carbonate and sodium silicate in preparation of light magnesium carbonate by chlor-alkali brine sludge | |
| CN101983916B (en) | Method for production of calcium chlorate and coproduction of ultra-fine calcium carbonate and sodium chloride by using acetylene sludge | |
| CN101229925A (en) | Method for preparing magnesium hydroxide with coproduction of calcium chloride | |
| CN107337216A (en) | A kind of method that potassium feldspar hydro-thermal alkaline process prepares potassium hydroxide | |
| CN102086026A (en) | Method for producing potassium chlorate and co-producing superfine calcium carbonate and ammonium chloride by utilizing carbide slag | |
| CN102101652A (en) | Method for producing calcium chlorate and co-producing fine calcium carbonate and sodium chloride by using carbide slag | |
| CN101823695A (en) | Method for co-production of light calcium carbonate and ammonium chloride in preparation of potassium chlorate by carbide slag | |
| CN101823737B (en) | Method for co-production of ultra-fine calcium carbonate and sodium silicate in preparation of light magnesium carbonate by chlor-alkali brine sludge | |
| CN101823696B (en) | Method for co-production of ultra-fine calcium carbonate and ammonium chloride in preparation of potassium chlorate by carbide slag | |
| CN101823738B (en) | Method for co-production of fine calcium carbonate and sodium silicate, in preparation of light magnesium carbonate by chlor-alkali brine sludge | |
| CN105236403A (en) | Method for preparing high-specific-surface-area active carbon by virtue of ultrasonic auxiliary dispersion | |
| CN101935061B (en) | Method for removing impurity of mother liquid in preparation process of calcium carbonate crystal whisker | |
| CN109354051A (en) | A method of calcium carbonate is prepared in Galuber's salt type brine cleaning procedure using carbide slag substitution lime | |
| US4012297A (en) | Mercury recovery and recycle process | |
| CN101624204B (en) | Four-great circulation method formed by waste gypsum mud and chlor-alkali industry | |
| CN112174093B (en) | Method for producing bleaching powder by using carbide slag | |
| CN102070126A (en) | Method for co-producing calcium chlorate, light calcium carbonate and sodium chloride from chlor-alkali carbide slag | |
| CN102086027A (en) | Method for preparation of calcium chlorate and co-production of potassium chlorate and calcium chloride using chlor-alkali calcium carbide slag | |
| CN101823744A (en) | Method for producing light-weighted calcium carbonate, ammonium chloride and carbon powder with waste associated alkali solution and acetylene sludge |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: WANG JINGYU Free format text: FORMER OWNER: WANG JINQIANG Effective date: 20130905 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 523000 DONGGUAN, GUANGDONG PROVINCE TO: 315000 NINGBO, ZHEJIANG PROVINCE |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20130905 Address after: 58 No. 315000 Zhejiang City Renhe Center City of Ningbo province Haishu District Daqi Gate Street in front of the building Patentee after: Wang Jingyu Address before: 523000 CITIC triumph city A11, Dongguan, Guangdong, Dongcheng District Patentee before: Wang Jinqiang |
|
| ASS | Succession or assignment of patent right |
Owner name: RUGAO YONGXING CASING CO., LTD. Free format text: FORMER OWNER: WANG JINGYU Effective date: 20131111 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 315000 NINGBO, ZHEJIANG PROVINCE TO: 226500 NANTONG, JIANGSU PROVINCE |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20131111 Address after: 226500, Jiangsu City, Rugao Province, such as town Huimin Road No. 666 (Economic Development Zone, sausage city) Patentee after: Rugao Yongxing Casing Co., Ltd. Address before: 58 No. 315000 Zhejiang City Renhe Center City of Ningbo province Haishu District Daqi Gate Street in front of the building Patentee before: Wang Jingyu |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120620 Termination date: 20180430 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |