CN101973744B - Red attapulgite polymer clay powder - Google Patents
Red attapulgite polymer clay powder Download PDFInfo
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- CN101973744B CN101973744B CN2010102404552A CN201010240455A CN101973744B CN 101973744 B CN101973744 B CN 101973744B CN 2010102404552 A CN2010102404552 A CN 2010102404552A CN 201010240455 A CN201010240455 A CN 201010240455A CN 101973744 B CN101973744 B CN 101973744B
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Abstract
The invention discloses red attapulgite polymer clay powder, and the key points of the technical scheme are as follows: the red attapulgite polymer clay powder consists of attapulgite clay after purification, white bentonite, sepiolite, everbright fast red, anatase titanium dioxide, calcium chloride, sodium polyacrylate, sodium carboxymethyl cellulose and sodium stearyl lactylate. A finished product of the red attapulgite polymer clay powder is prepared by mixing ingredients of the red attapulgite polymer clay powder, inputting into a crushing machine for crushing, further inputting the mixed materials after crushing into a pulverizing mill for pulverizing and packaging. Red attapulgite polymer clay produced by adding water in the red attapulgite polymer clay powder has the characteristics of high viscosity, softness, good plasticity, small shrinkage rate, hardening after natural drying, no need of baking, no production of cracks, no skin irritation, no toxicity, no corrosion and no greasy feeling. The red attapulgite polymer clay powder has simple production process, low cost and convenient use, and is conductive to popularization, and the red attapulgite polymer clay powder is applicable to field production of the red attapulgite polymer clay.
Description
Technical field
The present invention relates to the mud of making pottery, be specifically related to the soft pottery powder of a kind of red attapulgite.
Background technology
The soft ceramic mud of supplying on the market is through the block soft ceramic mud after the batching processing, the main raw material of soft ceramic mud is polyvinyl chloride and lime carbonate, binding property is bad under the normal temperature state, and prolonged preservation easily wears out and fades, and bubbles easily during the baking soft ceramic mud, when if temperature surpasses 200 ℃, finished product is burnt and melt, even may cause burning, generate chloride pungency toxic smog, the selling price of soft ceramic mud is higher, is unfavorable for promoting the use of.
The Chinese patent publication number is: CN 101186736, open day: on May 28th, 2008, name is called " a kind of soft ceramic mud and preparation method thereof ", disclose: " a kind of soft ceramic mud and preparation method; it is prepared from by following parts by weight of component: polyvinyl chloride (PVC) paste resin 15～40, bizinc resin 20～55, lime carbonate 15～35, softening agent 0.1～0.4, toner 0.5～0.15, all the other are micro-moisture and impurity ".
The weak point of above-mentioned patent is that the soft ceramic mud main raw material that this technology is produced is polyvinyl chloride (PVC) paste resin, bizinc resin and lime carbonate, and binding property is bad under the normal temperature state, is unfavorable for making moulding, and bizinc resin belongs to dangerous product.
The Chinese patent Granted publication number is: CN 1273531, Granted publication day: on September 6th, 2006, name is called " a kind of manufacture method of transparent texture resin clay ", disclose: " a kind of manufacture method of transparent texture resin clay; it is characterized in that: it is at first mixed together by ethylene powder-vinyl acetate copolymer, starch, glycerol, sanitas, spices and adds water purification again and stir into mud shape thing; and then add whiteruss and mix and stir, vacuum-packed finished product ".
The weak point of above-mentioned patent is that the transparent texture resin clay main raw material that this technology is produced is ethylene powder-vinyl acetate copolymer and starch, ethylene powder-vinyl acetate copolymer has hormesis to eyes and skin, be not suitable for being used to manufacture the raw material of handicraft, need a large amount of starch in this product, be unfavorable for promoting the use of.
Summary of the invention
The objective of the invention is to overcome weak point in the prior art, provide a kind of red attapulgite soft pottery powder.
The soft pottery powder of red attapulgite is made up of Concavo-convex stick after purifying stone clay, white wilkinite, sepiolite, everbright fast red, anatase thpe white powder, calcium chloride, sodium polyacrylate, Xylo-Mucine and stearoyl lactate.After the batch mixes with the soft pottery powder of red attapulgite, pulverize in the input pulverizer, carry out abrasive dust in the mixture input pulverizing mill after will pulverizing again, be packaged as the finished product of the soft pottery powder of red attapulgite.
Use the wet beneficiation craft of Attapulgite, the screening of mineral such as the hydromica in the attapulgite clay, quartz, opal and carbonate is got rid of, obtain a kind of Concavo-convex stick after purifying stone clay, Concavo-convex stick after purifying stone clay soil property exquisiteness, smooth surface, quality is lighter, be viscosity and plasticity-when moist, its viscosity can reach more than the 3000mPas, helps the bonding between the raw material, the dry post-shrinkage ratio of attapulgite clay is little, and does not produce be full of cracks.
The white wilkinite is the wilkinite of a kind of high whiteness and high brightness, has excellent plasticity, cohesiveness and oilness.
Sepiolite is a kind of rich fibrous magnesium silicate clay mineral, has fine and smooth soft, viscosity is strong, shrinking percentage is low and plasticity-the is good characteristics of satin luster, light weight, helps improving the gloss and the mouldability of the soft pottery powder of red attapulgite.
Everbright fast red is the bright red powder, has the characteristics of lovely luster, strong coloring force, steady quality and good fluidity.
Anatase thpe white powder has excellent water dispersible and remarkable optical property, form and aspect stability, and size-grade distribution is good, has the characteristics of high gloss, high reducing power, high covering power.
Calcium chloride is water-soluble, is a kind of siccative commonly used, has in the present invention to improve the soft pottery powder of red attapulgite and add hardness after water is made into the red attapulgite soft ceramic mud, and can increase the anti-ability of freezing of red attapulgite soft ceramic mud.
Sodium polyacrylate is a kind of white powder, odorless, tasteless and nontoxic can be slowly soluble in water, forms utmost point heavy-gravity transparent gel, have thickening, emulsification, figuration, multiple function such as expanded, stable, can improve the cohesiveness and the ductility of the soft pottery powder of red attapulgite.
Xylo-Mucine is white fiber shape or particle powder, and odorless is tasteless, and water absorbability is arranged, and easily is scattered in to be swelled into colloidal solution in the water, has good emulsifying stablizer and thickening material.
Stearoyl lactate is a kind of off-white powder or chip solid, can be scattered in the hot water, has effects such as emulsification, anti-aging and increase plasticity in the present invention.
Selecting sodium polyacrylate, stearoyl lactate and Xylo-Mucine in the present invention simultaneously for use, is to add water and make cohesiveness, flexibility, the ductility behind the red attapulgite soft ceramic mud and prevent that the red attapulgite soft ceramic mud is aging in order further to increase the soft pottery powder of red attapulgite.
The present invention is achieved by following technical proposals:
1, the batching of the soft pottery powder of red attapulgite is made up of following component by weight percentage: Concavo-convex stick after purifying stone clay 30～55%, white wilkinite 15～35%, sepiolite 5～25%, everbright fast red 1～8%, calcium chloride 1～5%, anatase thpe white powder 0.1～5%, sodium polyacrylate 0.1～5%, Xylo-Mucine 0.1～5% and stearoyl lactate 0.1～5%.
2, the production method of the soft pottery powder of red attapulgite: after the batch mixes with the soft pottery powder of red attapulgite, pulverize in the input pulverizer, compound particles fineness after the pulverizing is less than 0.250 millimeter, carry out abrasive dust in the mixture input pulverizing mill after will pulverizing again, compound particles fineness behind the abrasive dust is packaged as the finished product of the soft pottery powder of red attapulgite less than 0.045 millimeter.
Described Concavo-convex stick after purifying stone clay, it is the Attapulgite ore deposit mixture that will contain earth impurity, import in the hydrolytic tank after crushed, soak after 24 hours, dash with high-pressure pump and to turn over, and the sieve of the drum by making with stainless steel steel wire sieve removes the impurity more than 1 millimeter, send in the acclive settling tank, continuation is dashed with high-pressure pump and is turned over, after 12 hours, because the proportion in Attapulgite ore deposit is lighter, its the superiors in whole throw out draws this part Attapulgite ore deposit with slush pump and sends in the flat settling tank, emits unnecessary water after 15 hours, through 2-3 days seasoning, take out this part Attapulgite ore deposit and be Concavo-convex stick after purifying stone clay;
This technology is to adopt " the Attapulgite wet beneficiation craft " in application on September 18th, 2003 by the inventor, and the Chinese patent Granted publication number is: CN1224463, Granted publication day: on October 26th, 2005.
The using method of the soft pottery powder of red attapulgite: 1. the soft pottery powder of red attapulgite is placed in the container, slowly in the soft pottery powder of red attapulgite, added 50～60 ℃ hot water, and in time mix and crumple red into strips clod thoroughly, left standstill subsequently 30～60 minutes; 2. methyl-silicone oil is spread upon the red clod outside surface of strip and crumple once more, be pressed into softish red attapulgite soft ceramic mud, promptly can be used for moulding clear patterns, lovely luster, the artwork that effect is true to nature.
The separate case application of above-mentioned using method patent of invention, number of patent application is 201010240164.3.
Use the soft pottery powder of red attapulgite to add the red attapulgite soft ceramic mud viscosity height that water is made, soft plasticity-is good, have that shrinking percentage is little, indeformable, hardening after seasoning, do not need to toast, do not produce be full of cracks, not mouldy, never degenerate, not skin irritation, nontoxic, non-corrosiveness and do not have the characteristics of greasy feeling.
Production technique of the present invention is simple, and is with low cost, easy to use, helps promoting the use of.
The soft pottery powder of red attapulgite is applicable to the Attapulgite soft ceramic mud of field fabrication redness.
Embodiment
The invention will be further described below in conjunction with embodiment:
1, the batching of the soft pottery powder of red attapulgite is made up of following component by weight percentage: Concavo-convex stick after purifying stone clay 38%, white wilkinite 28%, sepiolite 19%, everbright fast red 5%, calcium chloride 3%, anatase thpe white powder 3%, sodium polyacrylate 2%, Xylo-Mucine 1.5% and stearoyl lactate 0.5%.
2, the production method of the soft pottery powder of red attapulgite: after the batch mixes with the soft pottery powder of red attapulgite, pulverize in the input pulverizer, compound particles fineness after the pulverizing is less than 0.250 millimeter, carry out abrasive dust in the mixture input pulverizing mill after will pulverizing again, compound particles fineness behind the abrasive dust is packaged as the finished product of the soft pottery powder of red attapulgite less than 0.045 millimeter.
Claims (1)
1. soft pottery powder of red attapulgite, it is characterized in that the batching of the soft pottery powder of red attapulgite is made up of following component by weight percentage: Concavo-convex stick after purifying stone clay 30～55%, white wilkinite 15～35%, sepiolite 5～25%, everbright fast red 1～8%, calcium chloride 1～5%, anatase thpe white powder 0.1～5%, sodium polyacrylate 0.1～5%, Xylo-Mucine 0.1～5% and stearoyl lactate 0.1～5%;
The production method of the soft pottery powder of described red attapulgite: after the batch mixes with the soft pottery powder of red attapulgite, pulverize in the input pulverizer, compound particles fineness after the pulverizing is less than 0.250 millimeter, carry out abrasive dust in the mixture input pulverizing mill after will pulverizing again, compound particles fineness behind the abrasive dust is packaged as the finished product of the soft pottery powder of red attapulgite less than 0.045 millimeter;
Described Concavo-convex stick after purifying stone clay, it is the Attapulgite ore deposit mixture that will contain earth impurity, import in the hydrolytic tank after crushed, soak after 24 hours, dash with high-pressure pump and to turn over, and the sieve of the drum by making with stainless steel steel wire sieve removes the impurity more than 1 millimeter, send in the acclive settling tank, continuation is dashed with high-pressure pump and is turned over, after 12 hours, because the proportion in Attapulgite ore deposit is lighter, its the superiors in whole throw out draws this part Attapulgite ore deposit with slush pump and sends in the flat settling tank, emits unnecessary water after 15 hours, through 2-3 days seasoning, take out this part Attapulgite ore deposit and be Concavo-convex stick after purifying stone clay.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102404552A CN101973744B (en) | 2010-07-30 | 2010-07-30 | Red attapulgite polymer clay powder |
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| CN2010102404552A CN101973744B (en) | 2010-07-30 | 2010-07-30 | Red attapulgite polymer clay powder |
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| CN101973744A CN101973744A (en) | 2011-02-16 |
| CN101973744B true CN101973744B (en) | 2011-10-26 |
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| CN2010102404552A Expired - Fee Related CN101973744B (en) | 2010-07-30 | 2010-07-30 | Red attapulgite polymer clay powder |
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| WO2013007558A2 (en) * | 2011-07-08 | 2013-01-17 | Purac Biochem Bv | Active formulation for use in feed products |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5008226A (en) * | 1989-05-16 | 1991-04-16 | Engelhard Corporation | Process for making acid activated bleaching earth using high susceptibility source clay and novel bleaching earth product |
| CN1167478A (en) * | 1995-08-04 | 1997-12-10 | 総合粘土窯业株式会社 | Synthetic clay for ceramics and process for preparing the same |
| US6130179A (en) * | 1998-11-12 | 2000-10-10 | Itc, Inc. | Purified attapulgite clay |
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2010
- 2010-07-30 CN CN2010102404552A patent/CN101973744B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5008226A (en) * | 1989-05-16 | 1991-04-16 | Engelhard Corporation | Process for making acid activated bleaching earth using high susceptibility source clay and novel bleaching earth product |
| CN1167478A (en) * | 1995-08-04 | 1997-12-10 | 総合粘土窯业株式会社 | Synthetic clay for ceramics and process for preparing the same |
| US6130179A (en) * | 1998-11-12 | 2000-10-10 | Itc, Inc. | Purified attapulgite clay |
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| CN101973744A (en) | 2011-02-16 |
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