Background technology
The main raw material of soft ceramic mud is SE and lime carbonate, and binding property is bad under the normal temperature state, and prolonged preservation is prone to aging and fades; Bubble easily during the baking soft ceramic mud,, finished product is burnt and melt if when temperature surpasses 200 ℃; Even possibly cause burning; Generate chloride pungency toxic smog, the selling price of soft ceramic mud is higher, is unfavorable for promoting the use of.
The Chinese patent publication number is: CN 101186736; Open day: on May 28th, 2008; Name is called " a kind of soft ceramic mud and preparation method thereof "; Disclose: " a kind of soft ceramic mud and preparation method, it is prepared from following parts by weight of component: PVC paste resin 15~40, bizinc resin 20~55, lime carbonate 15~35, softening agent 0.1~0.4, toner 0.5~0.15, all the other are micro-moisture and impurity ".
The weak point of above-mentioned patent is that the soft ceramic mud main raw material that this technology is produced is PVC paste resin, bizinc resin and lime carbonate, and binding property is bad under the normal temperature state, is unfavorable for making moulding, and bizinc resin belongs to dangerous product.
The Chinese patent Granted publication number is: CN 1273531; Granted publication day: on September 6th, 2006; Name is called " a kind of method of manufacture of transparent texture resin clay ", disclose: " a kind of method of manufacture of transparent texture resin clay is characterized in that: it is at first mixed together by ethylene powder-vinyl acetate copolymer, starch, USP Kosher, sanitas, spices and adds water purification again and stir into mud shape thing; and then add whiteruss and mix and stir, vacuum packaging finished product ".
The weak point of above-mentioned patent is that the transparent texture resin clay main raw material that this technology is produced is ethylene powder-vinyl acetate copolymer and starch; Ethylene powder-vinyl acetate copolymer has hormesis to eyes and skin; Be not suitable for the raw material of manufacturing handicraft; Need a large amount of starch in this product, be unfavorable for promoting the use of.
Summary of the invention
The objective of the invention is to overcome weak point in the prior art, a kind of working method of orange Attapulgite soft ceramic mud is provided.
The working method of orange Attapulgite soft ceramic mud is: orange sand shape Attapulgite mixture is added in the horizontal dough mixer that has turned round; And the ZX-I gelating soln slowly added in the orange sand shape Attapulgite mixture, mix and stir and be orange clod shape Attapulgite mixture; Be sprayed on the orange clod shape Attapulgite mixture with methyl-silicone oil, kneading becomes the work in-process of orange Attapulgite soft ceramic mud, is pressed into the orange Attapulgite soft ceramic mud of tabular at last, packs to be finished product.
Orange Attapulgite soft ceramic mud by Concavo-convex stick after purifying stone clay powder, white bentonite in powder, sepiolite powder, anatase thpe white powder, iron orange piece together mix, pigment dyestuff is orange, ZX-I, Ucar 35, methyl-silicone oil and zero(ppm) water are formed.
Use the wet beneficiation craft of Attapulgite, the screening of mineral such as the hydromica in the attapulgite clay, quartz, pearl opal and carbonate is got rid of, obtain a kind of Concavo-convex stick after purifying stone clay; Concavo-convex stick after purifying stone clay soil property is fine and smooth, smooth surface, and quality is lighter; Be viscosity and plasticity-when moist, its viscosity can reach more than the 3000mPas, helps the bonding between the raw material; The dry post-shrinkage ratio of attapulgite clay is little, and does not produce be full of cracks; Said Concavo-convex stick after purifying stone clay powder is that Concavo-convex stick after purifying stone clay is carried out abrasive dust, the Concavo-convex stick after purifying stone clay powder particle fineness that the present invention selects for use≤0.074 millimeter.
The white wilkinite is the wilkinite of a kind of high whiteness and high brightness; Have excellent plasticity, cohesiveness and oilness; Help improving the intensity after property bright in luster, plasticity-and the seasoning of orange Attapulgite soft ceramic mud, the white bentonite in powder particle fineness that the present invention selects for use≤0.074 millimeter.
Sepiolite is a kind of rich fibrous magnesium silicate clay mineral; Be light white or pearl; Have fine and smooth soft, viscosity is strong, shrinking percentage is low and plasticity-the is good characteristics of satin luster, light weight; Help improving property bright in luster, gloss and the mouldability of orange Attapulgite soft ceramic mud, sepiolite powder particle fineness≤0.074 that the present invention selects for use millimeter.
Anatase thpe white powder has excellent water dispersible and remarkable optical property; Form and aspect stability; Size-grade distribution is good; Have the characteristics of high gloss, high reducing power, high covering power, anatase thpe white powder particle fineness≤0.005 that the present invention selects for use millimeter helps improving the property bright in luster of orange Attapulgite soft ceramic mud.
It is by red iron oxide that the orange assembly of iron mixes and yellow oxide of iron is assorted mixes, and has characteristics such as good tinting strength, opacifying power and lovely luster, the mixed particle fineness of iron orange assembly that the present invention selects for use≤0.045 millimeter.
The pigment dyestuff orange is a kind of orange powder, has lovely luster, strong coloring force, sun-proof excellent property, acidproof, alkaline-resisting and do not have characteristics of transport property, the pigment dyestuff orange particle fineness that the present invention selects for use≤0.045 millimeter.
The present invention selects for use the iron orange to piece together mixed pigment dyestuff orange simultaneously, can make full use of the advantage of two kinds of orange pigmentss, helps making the color of orange Attapulgite soft ceramic mud more bright-coloured.
ZX-I is a kind of white powder; Odorless, tasteless and nontoxic can be slowly soluble in water, forms utmost point heavy-gravity transparent gel; Have thickening, emulsification, figuration, multiple function such as expanded, stable, can improve the cohesiveness and the ductility of orange Attapulgite soft ceramic mud.
Ucar 35 is the stable water-absorbent liquid of a kind of water white transparency toughness, and is water-soluble, in the present invention as solvent, emulsifying agent, frostproofer and lubricant.
Methyl-silicone oil is a kind of water white thick liquid, has colourless, tasteless, not volatile and water-fast characteristics, in the present invention as skimmer, releasing agent, lubricant and glossing agent.
Zero(ppm) water is meant with the pure water of distillating method preparation, uses zero(ppm) water can effectively improve the viscosity of ZX-I gelinite in the present invention.
The present invention is achieved through following technical proposals:
1, the working method of orange Attapulgite soft ceramic mud is: 1. orange sand shape Attapulgite mixture is added in the horizontal dough mixer that has turned round; And the ZX-I gelating soln slowly added in the orange sand shape Attapulgite mixture, mix and stir and be orange clod shape Attapulgite mixture; 2. orange clod shape Attapulgite mixture is added in the kneader, be sprayed on the orange clod shape Attapulgite mixture with methyl-silicone oil, kneading becomes the work in-process of orange Attapulgite soft ceramic mud; 3. orange Attapulgite soft ceramic mud work in-process are added in the oodle maker and press repeatedly 2~4 times, be pressed into the orange Attapulgite soft ceramic mud of tabular at last, pack and be finished product.
2, the batching of orange Attapulgite soft ceramic mud is made up of following component by weight percentage: orange sand shape Attapulgite mixture 60~85%, ZX-I gelating soln 10~35% and methyl-silicone oil 0.1~5%.
The batching of said orange sand shape Attapulgite mixture is made up of following component by weight percentage: Concavo-convex stick after purifying stone clay powder 15~40%, white bentonite in powder 5~20%, sepiolite powder 5~15%, anatase thpe white powder 0.1~5%, iron orange piece together mix 0.01~5%, pigment dyestuff orange 0.01~5% and zero(ppm) water 25~65%;
The working method of said orange sand shape Attapulgite mixture is: earlier Concavo-convex stick after purifying stone clay powder, white bentonite in powder, sepiolite powder, anatase thpe white powder, iron orange are pieced together mixed pigment dyestuff and stir orange the adding in the stirrer; Be orange powdery attapulgite mixture after stirring; Slowly add in the orange powdery attapulgite mixture with zero(ppm) water again and stir; Orange powdery attapulgite mixture is carried out moistening, through stirring with moistening be orange sand shape Attapulgite mixture afterwards;
The batching of said ZX-I gelating soln is made up of following component by weight percentage: ZX-I 0.1~5%, Ucar 35 0.3~25% and zero(ppm) water 70~99.6%;
The compound method of said ZX-I gelating soln is: earlier ZX-I is added in the Ucar 35; When ZX-I in Ucar 35 after the moistening dispersion; The common adding in the zero(ppm) water; Slowly stir, be dissolved in fully in the zero(ppm) water, form heavy-gravity ZX-I gelating soln up to ZX-I.
Said Concavo-convex stick after purifying stone clay is with the Attapulgite ore deposit mixture that contains earth impurity, imports in the hydrolytic tank after crushed; Soak after 24 hours, dash with high-pressure pump and turn over, and remove the impurity more than 1 millimeter through the drum sieve sieve of processing with the stainless steel steel wire; Send in the acclive settling tank, continuation is dashed with high-pressure pump and is turned over, after 12 hours; Because the proportion in Attapulgite ore deposit is lighter, its superiors in whole throw out draws this part Attapulgite ore deposit with steam piano and sends in the flat settling tank; Emit unnecessary water after 15 hours,, take out this part Attapulgite ore deposit and be Concavo-convex stick after purifying stone clay through 2-3 days seasoning;
This technology is to adopt " the Attapulgite wet beneficiation craft " in application on September 18th, 2003 by the inventor, and the Chinese patent Granted publication number is: CN1224463, Granted publication day: on October 26th, 2005.
The orange Attapulgite soft ceramic mud viscosity that the present invention produces is high; Soft plasticity-is good, have that shrinking percentage is little, indeformable, hardening after seasoning, do not need to toast, do not produce be full of cracks, not mouldy, never degenerate, not Imidazolidinyl Urea, nontoxic, non-corrosiveness and do not have the characteristics of greasy feeling.
Orange Attapulgite soft ceramic mud mixes use with the Attapulgite soft ceramic mud of other color, can mould clear patterns, lovely luster and effect artwork true to nature.
Production technique of the present invention is simple, and is with low cost, helps promoting the use of.
Orange Attapulgite soft ceramic mud is applicable to moulds pattern, mould and artwork.
Embodiment
Below in conjunction with embodiment the present invention is done further description:
1, the working method of orange Attapulgite soft ceramic mud is: 1. orange sand shape Attapulgite mixture is added in the horizontal dough mixer that has turned round; And the ZX-I gelating soln slowly added in the orange sand shape Attapulgite mixture, mix and stir and be orange clod shape Attapulgite mixture; 2. orange clod shape Attapulgite mixture is added in the kneader, be sprayed on the orange clod shape Attapulgite mixture with methyl-silicone oil, kneading becomes the work in-process of orange Attapulgite soft ceramic mud; 3. orange Attapulgite soft ceramic mud work in-process are added in the oodle maker and press repeatedly 3 times, be pressed into the orange Attapulgite soft ceramic mud of tabular at last, pack and be finished product.
2, the batching of orange Attapulgite soft ceramic mud is made up of following component by weight percentage: orange sand shape Attapulgite mixture 72%, ZX-I gelating soln 26% and methyl-silicone oil 2%.
The batching of said orange sand shape Attapulgite mixture is made up of following component by weight percentage: Concavo-convex stick after purifying stone clay powder 34%, white bentonite in powder 16%, sepiolite powder 8%, anatase thpe white powder 1%, iron orange piece together mix 2%, pigment dyestuff orange 1% and zero(ppm) water 38%;
The working method of said orange sand shape Attapulgite mixture is: earlier Concavo-convex stick after purifying stone clay powder, white bentonite in powder, sepiolite powder, anatase thpe white powder, iron orange are pieced together mixed pigment dyestuff and stir orange the adding in the stirrer; Be orange powdery attapulgite mixture after stirring; Slowly add in the orange powdery attapulgite mixture with zero(ppm) water again and stir; Orange powdery attapulgite mixture is carried out moistening, through stirring with moistening be orange sand shape Attapulgite mixture afterwards;
The batching of said ZX-I gelating soln is made up of following component by weight percentage: ZX-I 1%, Ucar 35 3% and zero(ppm) water 96%;
The compound method of said ZX-I gelating soln is: earlier ZX-I is added in the Ucar 35; When ZX-I in Ucar 35 after the moistening dispersion; The common adding in the zero(ppm) water; Slowly stir, be dissolved in fully in the zero(ppm) water, form heavy-gravity ZX-I gelating soln up to ZX-I.