CN101970627A - Water-soluble metal working lubricant - Google Patents
Water-soluble metal working lubricant Download PDFInfo
- Publication number
- CN101970627A CN101970627A CN2009801093744A CN200980109374A CN101970627A CN 101970627 A CN101970627 A CN 101970627A CN 2009801093744 A CN2009801093744 A CN 2009801093744A CN 200980109374 A CN200980109374 A CN 200980109374A CN 101970627 A CN101970627 A CN 101970627A
- Authority
- CN
- China
- Prior art keywords
- acid
- metal working
- soluble metal
- lubricant
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000314 lubricant Substances 0.000 title claims abstract description 65
- 238000005555 metalworking Methods 0.000 title claims abstract description 38
- -1 hydroxy fatty acid compound Chemical class 0.000 claims abstract description 71
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 38
- 239000000194 fatty acid Substances 0.000 claims abstract description 38
- 229930195729 fatty acid Natural products 0.000 claims abstract description 38
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 19
- 238000009833 condensation Methods 0.000 claims abstract description 11
- 230000005494 condensation Effects 0.000 claims abstract description 11
- 230000018044 dehydration Effects 0.000 claims abstract description 9
- 238000006297 dehydration reaction Methods 0.000 claims abstract description 9
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 6
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 6
- 239000002253 acid Substances 0.000 claims description 63
- 239000000203 mixture Substances 0.000 claims description 43
- 150000002632 lipids Chemical class 0.000 claims description 32
- 150000001875 compounds Chemical class 0.000 claims description 16
- 239000013543 active substance Substances 0.000 claims description 10
- 239000003963 antioxidant agent Substances 0.000 claims description 7
- 230000003078 antioxidant effect Effects 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 238000006386 neutralization reaction Methods 0.000 claims description 6
- 239000003643 water by type Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 abstract description 43
- 239000002184 metal Substances 0.000 abstract description 43
- 229910052782 aluminium Inorganic materials 0.000 abstract description 18
- 229910000831 Steel Inorganic materials 0.000 abstract description 17
- 239000010959 steel Substances 0.000 abstract description 17
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 9
- 238000002156 mixing Methods 0.000 abstract description 8
- 150000004665 fatty acids Chemical class 0.000 abstract description 6
- 229910052742 iron Inorganic materials 0.000 abstract description 5
- 239000011230 binding agent Substances 0.000 abstract description 3
- 229920000642 polymer Polymers 0.000 abstract description 3
- 150000002739 metals Chemical class 0.000 abstract description 2
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 150000007514 bases Chemical class 0.000 abstract 1
- 239000007859 condensation product Substances 0.000 abstract 1
- 150000004679 hydroxides Chemical class 0.000 abstract 1
- 239000002736 nonionic surfactant Substances 0.000 abstract 1
- 230000003245 working effect Effects 0.000 abstract 1
- 238000012545 processing Methods 0.000 description 34
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 21
- 239000004411 aluminium Substances 0.000 description 16
- 235000010210 aluminium Nutrition 0.000 description 16
- 238000012360 testing method Methods 0.000 description 14
- 239000000463 material Substances 0.000 description 13
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 150000008044 alkali metal hydroxides Chemical group 0.000 description 6
- GLUUGHFHXGJENI-UHFFFAOYSA-N diethylenediamine Natural products C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 6
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 6
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- BDERNNFJNOPAEC-UHFFFAOYSA-N n-propyl alcohol Natural products CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- WBHHMMIMDMUBKC-QJWNTBNXSA-M ricinoleate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O WBHHMMIMDMUBKC-QJWNTBNXSA-M 0.000 description 5
- 229940066675 ricinoleate Drugs 0.000 description 5
- 238000010008 shearing Methods 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 150000001735 carboxylic acids Chemical class 0.000 description 4
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- YLAXZGYLWOGCBF-UHFFFAOYSA-N 2-dodecylbutanedioic acid Chemical compound CCCCCCCCCCCCC(C(O)=O)CC(O)=O YLAXZGYLWOGCBF-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000003044 adaptive effect Effects 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 238000005238 degreasing Methods 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 3
- VLHZUYUOEGBBJB-UHFFFAOYSA-N hydroxy stearic acid Natural products OCCCCCCCCCCCCCCCCCC(O)=O VLHZUYUOEGBBJB-UHFFFAOYSA-N 0.000 description 3
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 description 2
- MUPUULLHJFCARW-UHFFFAOYSA-N 2-(16-methylheptadecanoyl)butanedioic acid Chemical compound C(CCCCCCCCCCCCCCC(C)C)(=O)C(C(=O)O)CC(=O)O MUPUULLHJFCARW-UHFFFAOYSA-N 0.000 description 2
- GHPVDCPCKSNJDR-UHFFFAOYSA-N 2-hydroxydecanoic acid Chemical compound CCCCCCCCC(O)C(O)=O GHPVDCPCKSNJDR-UHFFFAOYSA-N 0.000 description 2
- ZPJDFKVKOFGAFV-UHFFFAOYSA-N 2-octadecylbutanedioic acid Chemical compound CCCCCCCCCCCCCCCCCCC(C(O)=O)CC(O)=O ZPJDFKVKOFGAFV-UHFFFAOYSA-N 0.000 description 2
- WFCSWCVEJLETKA-UHFFFAOYSA-N 2-piperazin-1-ylethanol Chemical compound OCCN1CCNCC1 WFCSWCVEJLETKA-UHFFFAOYSA-N 0.000 description 2
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000002947 alkylene group Chemical class 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 2
- 239000012964 benzotriazole Substances 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 2
- 229940043276 diisopropanolamine Drugs 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 238000005242 forging Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- KEMQGTRYUADPNZ-UHFFFAOYSA-N heptadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(O)=O KEMQGTRYUADPNZ-UHFFFAOYSA-N 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 229960004232 linoleic acid Drugs 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N pentadecanoic acid Chemical compound CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- 238000006068 polycondensation reaction Methods 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 210000000582 semen Anatomy 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- 125000001273 sulfonato group Chemical class [O-]S(*)(=O)=O 0.000 description 2
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 2
- SZHOJFHSIKHZHA-UHFFFAOYSA-N tridecanoic acid Chemical compound CCCCCCCCCCCCC(O)=O SZHOJFHSIKHZHA-UHFFFAOYSA-N 0.000 description 2
- 229960004418 trolamine Drugs 0.000 description 2
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
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- XAKIZRLIXGLPBW-UHFFFAOYSA-N 1-piperazin-1-ylpropan-2-ol Chemical compound CC(O)CN1CCNCC1 XAKIZRLIXGLPBW-UHFFFAOYSA-N 0.000 description 1
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- SXNBVULTHKFMNO-UHFFFAOYSA-N 2,2-dihydroxyoctadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(O)(O)C(O)=O SXNBVULTHKFMNO-UHFFFAOYSA-N 0.000 description 1
- NXVZDSCEUVMQOC-UHFFFAOYSA-N 2,3-dihydroxyoctadec-2-enoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=C(O)C(O)=O NXVZDSCEUVMQOC-UHFFFAOYSA-N 0.000 description 1
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- FEXBEKLLSUWSIM-UHFFFAOYSA-N 2-Butyl-4-methylphenol Chemical group CCCCC1=CC(C)=CC=C1O FEXBEKLLSUWSIM-UHFFFAOYSA-N 0.000 description 1
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- 238000001035 drying Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 235000013861 fat-free Nutrition 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000008397 galvanized steel Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- QQHJDPROMQRDLA-UHFFFAOYSA-N hexadecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCC(O)=O QQHJDPROMQRDLA-UHFFFAOYSA-N 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- LMHJFKYQYDSOQO-UHFFFAOYSA-N hydroxydecanoic acid Natural products CCCCCC(O)CCCC(O)=O LMHJFKYQYDSOQO-UHFFFAOYSA-N 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- KHYKFSXXGRUKRE-UHFFFAOYSA-J molybdenum(4+) tetracarbamodithioate Chemical class C(N)([S-])=S.[Mo+4].C(N)([S-])=S.C(N)([S-])=S.C(N)([S-])=S KHYKFSXXGRUKRE-UHFFFAOYSA-J 0.000 description 1
- 150000007518 monoprotic acids Chemical class 0.000 description 1
- VJQGGZWPOMJLTP-UHFFFAOYSA-N octadecane-1,1-diol Chemical compound CCCCCCCCCCCCCCCCCC(O)O VJQGGZWPOMJLTP-UHFFFAOYSA-N 0.000 description 1
- CWFGKWQPVBFODR-UHFFFAOYSA-N octadecane-9,10-diol Chemical compound CCCCCCCCC(O)C(O)CCCCCCCC CWFGKWQPVBFODR-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- HZLFQUWNZMMHQM-UHFFFAOYSA-N piperazin-1-ylmethanol Chemical compound OCN1CCNCC1 HZLFQUWNZMMHQM-UHFFFAOYSA-N 0.000 description 1
- 150000004885 piperazines Chemical class 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- ABTOQLMXBSRXSM-UHFFFAOYSA-N silicon tetrafluoride Chemical compound F[Si](F)(F)F ABTOQLMXBSRXSM-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 1
- 229940095068 tetradecene Drugs 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
- WMYJOZQKDZZHAC-UHFFFAOYSA-H trizinc;dioxido-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S WMYJOZQKDZZHAC-UHFFFAOYSA-H 0.000 description 1
- 229960002703 undecylenic acid Drugs 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/02—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic oxygen-containing compound
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/02—Well-defined aliphatic compounds
- C10M2203/024—Well-defined aliphatic compounds unsaturated
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/128—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids containing hydroxy groups; Ethers thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/221—Six-membered rings containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/245—Soft metals, e.g. aluminum
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/246—Iron or steel
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The present invention provides a water-soluble metal working lubricant which is obtained by mixing at least one hydroxy fatty acid compound selected from hydroxy fatty acids, condensation polymers of hydroxy fatty acids, and dehydration condensation products of hydroxy fatty acids or condensation polymers of hydroxy fatty acids and fatty acids, (B) fatty acids having 8 to 20 carbon atoms, (C) at least one basic compound selected from hydroxides of alkali metals and aliphatic alcohol amines, (D) linear olefins having 8 to 20 carbon atoms, and (E) nonionic surfactants, and which has excellent working properties and good compatibility with a binder in metal working of nonferrous metals such as aluminum and iron metals such as steel.
Description
Technical field
The present invention relates to water-soluble metal working lubricant, at length, relate to the water-soluble metal working lubricant that can both suit to utilize in arbitrary metal processing of ferrous metals such as non-ferrous metal such as aluminium (being also referred to as non-ferrous metal) and steel.
Background technology
In recent years, in order to reach the purpose of improving oil consumption by the automobile lightweight, the consumption of employed alumina increases gradually in the automobile production.This kind changes expression, in the process of producing automobile, follows the parts that always use ferrous metals such as steel, aluminium with and the parts of non-ferrous metal such as alloy also need the metal-working plant and the metal manufacturing procedure of mold processing.
But forging and pressing processing waits metal to process employed Metalworking lubricant usually according to the kind of machined material, uses different lubricants.For example, machined material is a non-ferrous metal with for ferrous metal the time, because the desired processing characteristics difference of Metalworking lubricant is used different finishes usually respectively.In a word, the used for non-ferrous metal finish uses as the processing finish of ferrous metal, and ferrous metal adds man-hour with the metal that finish is used for non-ferrous metal, and their mold processed goods necessarily can not meet the demands.
In view of the above, in the factory that carries out the processing of non-ferrous metal such as automobile production and ferrous metal metal, ferrous metal need be set with processing units (processing line) and used for non-ferrous metal processing units respectively.Therefore, in the equipment and installation cost increase of necessity, the problem that also exists operating efficiency to descend.
For head it off, be necessary to develop a kind of no matter machined material and be non-ferrous metal might as well, ferrous metal might as well, can both show the finish of good processing properties (mold).As long as this kind finish is arranged, just might use common processing units (processing line) that ferrous metal and non-ferrous metal are processed.
In addition, in the metal processing, when having the processing characteristics of above-mentioned excellence, also need to satisfy other various performances in addition.For example, in the manufacturing of trolley part, and the adaptability between the tamanori, promptly, need to have excellent cohesiveness between them in order to make between the metal fabricated product (parts) or bonding combination between metal fabricated product and the other materials parts.Therefore, good cohesiveness (bonding adaptability) is obligato.
Certainly further, metal processing oil solution also requires to possess fundamental propertys such as rust-preventing characteristic, degreasing, storage stability.
Summary of the invention
The present invention just produces in these cases, and a kind of processing characteristics is all excellent in arbitrary metal processing of non-ferrous metal such as aluminium and ferrous metals such as iron and steel to provide, and the while is a purpose with tamanori adaptability good water-solubility Metalworking lubricant.
The inventor is in order to reach above-mentioned purpose, through the discovery of concentrating on studies repeatedly, can solve above-mentioned problem by mixing the lubricant that specific hydroxy aliphatic acid compound and special fatty acid etc. form.The present invention is based on this discovery and the invention finished.
That is, the invention provides:
(1) a kind ofly is selected from hydroxy fatty acid by (A), the polycondensate of hydroxy fatty acid, and at least a hydroxy aliphatic acid compound among the dehydration condensation of the polycondensate of hydroxy fatty acid or hydroxy fatty acid and lipid acid, (B) lipid acid of carbonatoms 8～20, (C) be selected from least a basic cpd among alkali-metal oxyhydroxide and the organic amine compound, (D) carbonatoms is 8～20 normal olefine, (E) nonionic is the water-soluble metal working lubricant that tensio-active agent mixes.
(2) above-mentioned (1) described water-soluble metal working lubricant, with the lubricant all-mass is benchmark, and (C) composition that mixes (A) composition 10～60 quality %, (B) composition 3～30 quality %, (D) composition 0.5～30 quality %, (E) composition 3～50 quality % and neutralization equivalent and than ((C)/((A)+(B))) be in 0.5～2.5 the scope forms.
(3) as above-mentioned (1) or (2) described water-soluble metal working lubricant, the number-average molecular weight of hydroxy aliphatic acid compound (A) is 300～2000.
(4) as above-mentioned (1) or (2) described water-soluble metal working lubricant, lipid acid (B) is the lipid acid of carbonatoms 8～10.
(5) as above-mentioned (1) or (2) described water-soluble metal working lubricant, basic cpd (C) is the mixture of alkali-metal oxyhydroxide and organic amine compound.
(6) as above-mentioned (1) or (2) described water-soluble metal working lubricant, normal olefine (D) is the 1-alkene of carbonatoms 8～20.
(7), mixed at least a the forming that is selected among rust-preventive agent, antioxidant and the sanitas as above-mentioned (1) or (2) described water-soluble metal working lubricant.And
(8) a kind of with 3～300 times of water-soluble metal working lubricants that form of above-mentioned (1) or (2) described water-soluble metal working lubricant dilute with water.
The effect of invention
According to the present invention, can provide in arbitrary metal processing of non-ferrous metal such as a kind of aluminium and ferrous metals such as iron and steel, processing characteristics is all excellent, simultaneously and tamanori adaptability good water-solubility Metalworking lubricant.
Embodiment
Water-soluble metal working lubricant of the present invention by the lipid acid of (A) hydroxy aliphatic acid compound, (B) carbonatoms 8～20, (C) basic cpd, (D) normal olefine and (E) nonionic be that tensio-active agent mixes.
The hydroxy aliphatic acid compound of above-mentioned (A) composition among the present invention is at least a hydroxy aliphatic acid compound that is selected among the dehydration condensation of the polycondensate of the polycondensate of hydroxy fatty acid, hydroxy fatty acid and hydroxy fatty acid or hydroxy fatty acid and lipid acid.
Above-mentioned hydroxy fatty acid can exemplify, for example, single oxidation of fat acid has hydroxyl n-nonanoic acid, hydroxydecanoic acid, hydroxylauric acid, hydroxyl tetradecane acid, hydroxy-palmitic acid, oxystearic acid, hydroxyarachidic acid, hydroxyl docosoic acid, ricinoleate acid, isorpcinoleic acid; Single oxidation di-carboxylic acid has hydroxyl sebacic acid, hydroxyl octyl group sebacic acid; Single oxidation tricarboxylic acid has tetradecyl citric acid (ノ Le カ ペ ラ one ト
), agaritine, titanium dioxide monocarboxylic acid have 3,11-ipurolic acid (iproicacid), ustilic acid A, dihydroxystearic acid, dihydroxyl octadecenoic acid, dihydroxyl octadecane diolefinic acid; The dihydroxyl di-carboxylic acid has dihydroxyl dodecanedioic acid, dihydroxyl Thapsic acid, 9,10-dihydroxy octadecane diacid (acid of Off ロ イ オ Application), dihydroxyl hexacosandiacid (ジ ヒ De ロ キ シ ヘ キ サ コ two
) etc.In addition, also can use Semen Ricini oil lipid acid and the sclerosis Semen Ricini oil lipid acid that obtains by natural fats and oils.
From the viewpoint of the effect and the easiness of starting with, preferred monohydroxy fatty acid, wherein, carbonatoms is 12～20 monohydroxy fatty acid, especially preferred oxystearic acid (12-oxystearic acid) and isorpcinoleic acid (ricinoleate acid).
Two～sexamer of the preferred above-mentioned hydroxy fatty acid of polycondensate of above-mentioned hydroxy fatty acid.Two～sexamer of preferred especially isorpcinoleic acid (ricinoleate acid) or hydroxyl 18 carbonic acid (12 oxystearic acid).
The employed lipid acid of the dehydration condensation of the dehydration condensation of above-mentioned hydroxy fatty acid or hydroxy fatty acid polycondensate and lipid acid can exemplify; for example, capric acid; undecanoic acid; undecylenic acid; dodecylic acid; tridecanoic acid; pentadecylic acid; margaric acid; nondecylic acid; lauric acid; tetradecanoic acid; palmitinic acid; stearic acid; eicosanoic acid; 22 (carbon) acid; Unimac 5680; elaidic acid; oleic acid; linolic acid; monoprotic acid such as linolenic acid; sebacic acid; dodecanedioic acid; the dodecyl Succinic Acid; the lauryl Succinic Acid; the stearyl-Succinic Acid; the isostearoyl Succinic Acid; dimeracid; linolic acid; diprotic acid such as methylpropenyl acid condenses.In addition, also can use lipid acid of obtaining by illustrative unsaturated fatty acids addition in lipid acid with unsaturated link(age) and the methylpropenyl acid etc.
Above-mentioned polycondensate be by above-mentioned hydroxy fatty acid or hydroxy fatty acid polycondensate and above-mentioned lipid acid through common polycondensation, for example, under the existence of catalyst-free or suitable catalyzer, reaction obtains under room temperature or heating condition.
The fatty acid cpds of the dehydration condensation of the polycondensate of above-mentioned hydroxy fatty acid used in the present invention, hydroxy fatty acid and the polycondensate of hydroxy fatty acid or hydroxy fatty acid and lipid acid, preferred molecular-weight average is 300～2000.Mean molecule quantity not sufficient 300, processing characteristics (mold) has inadequate situation, and on the other hand, molecular weight surpasses 2000 o'clock situations that have cohesiveness to descend.The molecular-weight average of hydroxy aliphatic acid compound more preferably 500～800, preferred especially 600～700.
Be mixed with at least a hydroxy aliphatic acid compound among the dehydration condensation of the polycondensate of the polycondensate that is selected from above-mentioned hydroxy fatty acid, hydroxy fatty acid and hydroxy fatty acid or hydroxy fatty acid and lipid acid among the present invention.The combined amount of this hydroxy aliphatic acid compound is a benchmark with the lubricant all wts, preferably at 10～60 quality %, more preferably at 30～45 quality %.The content of hydroxy aliphatic acid compound is more than 10 quality %, and processing characteristics (mold) is good, below 60 quality %, can guarantee the suitable combined amount of other compositions.
As the lipid acid of above-mentioned (B) composition among the present invention, use the lipid acid of carbonatoms 8～20.This lipid acid comprises and has the saturated of straight chain or side chain or unsaturated aliphatic monocarboxylic acid and aliphatic dicarboxylic acid.
In the middle of this kind lipid acid, from improving the adaptive aspect of bonding, the lipid acid of preferred carbonatoms 8～10, concrete example can be enumerated, aliphatic monocarboxylic acid, octane diacid (suberic acid), nonane diacid (nonane diacid), decane diacid aliphatic dicarboxylic acids such as (sebacic acid) such as various octanesulfonic acids, various nonane acid, various capric acid.Especially carbon 9 or 10 lipid acid wherein preferably have the carbon 9 of side chain or 10 lipid acid.
These lipid acid can use separately or mix more than 2 kinds and use.
Among the present invention, the combined amount of lipid acid is a benchmark with the lubricant all wts, preferably at 3～30 quality %, more preferably at 5～15 quality %.More than 3 quality %, can keep good bonding adaptability, and on the other hand, below 30 quality %, can guarantee the suitable combined amount of other compositions.
Among the present invention,, mix at least a basic cpd that is selected from alkali metal hydroxide and the organic amine compound as (C) composition.
Above-mentioned alkali metal hydroxide has been enumerated sodium hydroxide, potassium hydroxide, lithium hydroxide.In addition, can give an example alkanolamine and diethylenediamine compound of organic amine compound.
Above-mentioned alkanolamine can be enumerated, monoethanolamine, diethanolamine, trolamine, single n-propyl alcohol amine, two (n-propyl alcohol) amine, three (n-propyl alcohol) amine, monoisopropanolamine, diisopropanolamine (DIPA), tri-isopropanolamine, methyl isopropyl hydramine etc.In the middle of these alkanolamines, preferred total carbon atom number is 2～4 uncle or tertiary alkanolamine.
In addition,, can enumerate N-(2-hydroxyalkyl) piperazines such as N-(2-hydroxymethyl) piperazine, N-(2-hydroxyethyl) piperazine, N-(2-hydroxypropyl) piperazine as the typical example of above-mentioned diethylenediamine compound.
In the middle of these organic amine compounds, from this point of effect, preferred trolamine, monoisopropanolamine and N-(2-hydroxyalkyl) piperazine, preferred especially N-(2-hydroxyalkyl) piperazine.
Among the present invention, (C) combined amount of composition, consider above-mentioned (A) composition and (B) relation between the combined amount of composition, preferred neutralization equivalent is than (C)/((A)+(B))) be to mix in 0.5～2.5 scope, further preferred neutralization equivalent ratio is 0.6～2.0, in 0.7～1.7 scope.
Be selected from the combined amount of basic cpd at least a in the alkali metal hydroxide of (C) composition and the organic amine compound, words in above-mentioned scope, (A) hydroxy aliphatic acid compound and lipid acid (B) form good salt with (C) composition, pay excellent processing characteristics, bond the adaptive while, the effect that improves rust-preventing characteristic is also arranged.Particularly, for example, neutralization equivalent can suppress the corrosion to iron and aluminium than being more than 0.5, and neutralization equivalent can be brought into play good mold than below 2.5.
In addition, as (C) of the present invention composition, preferably mix a kind of or more than two kinds alkali metal hydroxide with a kind of or more than two kinds organic amine compound mix again.In such cases, the blending ratio of alkali-metal oxyhydroxide and organic amine compound is any, consider that from the viewpoints such as anti-variable color on aluminium surface alkali metal hydroxide (C1) is preferred below 1.0 with the ratio (equivalence ratio (C1)/(C2)) of organic amine compound (C2).
Among the present invention,, use carbonatoms 8～20, preferred 10～20 normal olefine as (D) composition.The carbonatoms of normal olefine was less than 8 o'clock, because flash-point is low not preferred, on the other hand, carbonatoms was a solid under the room temperature greater than 20 o'clock usually, operational difficulty.Among the present invention, preferred alpha-olefin, i.e. 1-alkene in the middle of this normal olefine.
As the concrete example of this normal olefine, can give an example 1-octene, 1-decene, tetradecene, cetene, 1-vaccenic acid, 1-eicosylene or their mixture etc.
These normal olefines can use, for example, and the ethylene low polymer that polymerising ethylene obtains.
Among the present invention, the combined amount of the normal olefine of above-mentioned carbonatoms 8～20 is a benchmark with the lubricant all-mass, preferably at 0.5～30 quality %, more preferably at 0.5～15 quality %.More than 0.5 quality %, can keep good processing properties, especially for the processing characteristics of non-ferrous metal, and on the other hand, below 30 quality %, degreasing is good, can also guarantee the suitable combined amount of other compositions.
Among the present invention, as (E) composition, mixing nonionic is tensio-active agent.
As nonionic is tensio-active agent, and can use various nonionics is tensio-active agent.For example, can enumerate, polyoxyalkylene glycol or this single, diether compounds, polyoxyethylene glycol such as glycerine or this alkylene oxidation affixture or ether compound are emulsifying agent, the ester of carboxylic acid and alcohols (especially polyvalent alcohol), the acid amides of alkanolamine and lipid acid or carboxylic acid, the alkylene oxidation affixture of alkylamine etc.In the middle of this, the ester of preferred polyethylene glycol alkyl ether or carboxylic acid and polyvalent alcohol is more than the preferred especially HLB4.
This nonionic is the combined amount of tensio-active agent, is benchmark with the lubricant all wts, preferably at 3～50 quality %, more preferably at 5～35 quality %.More than 3 quality %, the dispersiveness of lubricant or favorable solubility, and on the other hand, below 50 quality %, can guarantee the suitable combined amount of other compositions.
Among the present invention, when mixing above-mentioned nonionic and be tensio-active agent, also can mix negatively charged ion such as sulfuric acid, sulphonate salt, phosphate ester salt is that positively charged ions such as tensio-active agent and polyethylene polyamines are tensio-active agent.
Among the present invention, further mixing water.Glassware for drinking water has the effect that improves lubricant dispersion or steady dissolution.
But the dispersion of lubricant (dissolving) stability changes according to the content of the composition of above-mentioned (A)～(E) that exist in lubricant and their blending ratio.Therefore, also there is the situation that not necessarily needs water.Therefore the combined amount of water is a benchmark with the lubricant all-mass, preferred 0～50 quality %, more preferably 0～10 quality %.
In the water-soluble metal working lubricant of the present invention, preferred further the mixing is selected from least a among rust-preventive agent, antioxidant and the sanitas.
As above-mentioned rust-preventive agent, can enumerate, for example, succinate system, carboxylic acid amides etc. such as metal sulfonates such as petroleum sodium sulfonate system, lauryl Succinic Acid, stearyl Succinic Acid, isostearoyl Succinic Acid.The combined amount of this kind rust-preventive agent is a benchmark with the lubricant all-mass, preferably mixes in 0.0005～2 quality % scope usually, more preferably 0.001～1 quality %.
As above-mentioned antioxidant, can enumerate, for example, 2,6-two-tertiary butyl-4-methylphenol, 4,4 '-methylene radical-two-(2,6-two-tert.-butyl phenol) etc. phenol is antioxidant, 4,4 '-dioctyl diphenylamine, 4, and amine such as 4 '-dinonyldiphenylamine, phenyl-a-naphthylamine are antioxidant.
The combined amount of this kind antioxidant is a benchmark with the lubricant all-mass, preferably mixes in 0.01～3 quality % scope usually, more preferably 0.05～2 quality %.
Foregoing preservatives can be enumerated, and for example, triazine is that sanitas, alkyl benzimidazole are sanitas etc.The combined amount of this kind sanitas is a benchmark with the lubricant all-mass, preferably mixes in 0.0001～3 quality % scope usually, more preferably 0.001～2 quality %.
In the water-soluble metal working lubricant of the present invention, in the scope of not violating the object of the invention, can suitably mix other additives and solvent based.
As this additive, can enumerate, for example, various alcohols, ester class, lipid, vulcanized oil lipid, sulfuration ester class, olefine sulfide, sulfurized mineral oil, chlorine paraffinic hydrocarbons, phosphoric acid ester, phosphorous acid ester and their amine salt, dithiophosphates (zinc dithiophosphate, molybdenum dithiophosphate etc.), dithiocar-bamate oiliness improvers such as (molybdenum dithiocarbamates etc.) and withstand voltage dose, benzotriazole system, sanitass such as thiazole system, silicon system, defoamers such as silicon fluoride system, polymethacrylate system, viscosity index rising agents such as olefin-copolymerization system etc.
The combined amount of these additives can suitably be selected according to purpose, but the total amount of these additives is that benchmark makes it to mix below 20 quality % with the lubricant all-mass usually.
The present invention mixes the water-soluble metal working lubricant that above-mentioned each composition forms, but can behind the dilute with water, this diluent be used as water-soluble metal working lubricant with this lubricant as stoste again.Dilution ratio does not in the case have special restriction, but preferred 3～300 times, 5～100 times usually, further preferred about 10～50 times.
In addition, for the pH of water-soluble metal working lubricant, 30 times of diluents of water are preferably 7.5～10, and more preferably 8～9.5.30 times of diluents of water do not have variable color of various metallic surfaces and corrosive worry in this scope.
For the kinematic viscosity of water-soluble metal of the present invention processing, do not have especially and limit, but the kinematic viscosity under 40 ℃ is preferably probably at 20～20000mm with lubricating oil (contain dilution after lubricant)
2In/s the scope.Kinematic viscosity is probably at 20～20000mm
2In the time of in/s the scope, processibility is good, does not also have the problem of incendivity, and does not also have lubricant to be attached to the excessive problem of amount that machined object is pulled away.
Embodiment
Then, the present invention will be described in more detail by embodiment, but the present invention does any qualification by these examples.
Sample oil to each embodiment and comparative example gained is estimated by following method.
1. plasticity (bulb drawing test)
＜evaluation method 〉
Use following method to forge and press processing, carry out bulb drawing test.
(1) machined material
(a) steel (JSC270D), GA material (steel plate galvanized, JAC270D), thickness of slab is 0.8mm
(b) aluminium (AA5182 and AA6022), thickness of slab is 1.0mm
(2) processing conditions
Punch press bulb footpath: φ 100, chromium plated steel
Forming speed: 100mm/s
(3) assessment item
Measure the bulb drawing and cut apart the boundary line height (mm) of generation.
＜metewand 〉
◎: the boundary line height, aluminium and GA material are more than 36mm, and steel are more than 40mm
Zero: boundary line height, aluminium and GA material more than 30mm less than 36mm, steel more than 35mm less than 40mm
*: the boundary line height, aluminium and GA material are less than 30mm, and steel are less than 35mm
2. bonding compatibility test
＜evaluation method 〉
According to JASO specification M323,, measure shearing strength and peel off form (peeling off area occupation ratio) using 2 machined materials of following method agglutinating.
(1) adhesive method of machined material;
1. by the test film (rectangle of 25 * 100mm) of estimating the employed machined material of plasticity in each 2 one group preparation (1).To the wherein one side coat lubricant of these test films, making the coating amount is 1g/m
2Then, for coating a slice in each test film of 2 one group of lubricant, at its lubricant coating finishing coat tamanori, another sheet test film of this binder coating test film and above-mentioned 2 one group then bonds, it is middle that tamanori is sandwiched in by the lubricant coating face, makes the battery of tests sheet with this.
In such cases, can use dividing plate or granulated glass sphere to make the gap between the test film in the binding part is 0.05～0.15mm, adjusts the coating amount of tamanori with this.
With above-mentioned battery of tests sheet, heating is 20 minutes in 170 ± 2 ℃ drying oven, places 24 hours under standard state then.The battery of tests sheet that this method is obtained carries out shearing strength and peels off the form evaluation.
It is tamanori (サ Application ス タ one skill is ground society's system, trade(brand)name " #1085 ") that tamanori uses epoxy.
(2) shearing strength condition determination
When measuring shearing strength, draw speed is made as 50mm/min measures.
＜metewand 〉
Shearing strength
◎: more than the 15MPa
Zero: 10MPa is above less than 15MPa
*: less than 10MPa
Peel off form
Zero: cohesion damage area rate 100%
△: cohesion damage area rate more than 80% less than 100%
*: cohesion damage area rate is less than 80%
3. degreasing test
＜evaluation method 〉
With lubricant coating is 3.0g/m
2Aluminium plate (AA5182,70 * 150mm) at room temperature place washing after 1 hour.Through washing, try to achieve the area % of non-fat portion.
＜metewand 〉
More than zero: 95%
△: more than 50% less than 95%
*: less than 50%
4. rust-preventing characteristic test
＜evaluation method 〉
With lubricant coating is 3.0g/m
2Aluminium plate (AA5182,70 * 150mm) at room temperature expose the outward appearance of observing aluminium sheet after 14 days estimates.
＜metewand 〉
Zero: no variable color
△: variable color (the variable color area is below 5%) is arranged
*: variable color (the variable color area is surpassing 5%) is arranged
5. cryopreservation stability test
Each finish is purchased in-5 ℃ cryostat,, and observation has or not muddiness (cloud) after 5 days.
＜metewand 〉
Zero: do not have muddy
△: a little muddiness is only arranged, return transparent liquid under the normal temperature
*: muddy and with solid matter, can not return transparent liquid under the normal temperature
Embodiment 1～14, comparative example 1～7
The finish of forming shown in modulometer 1 and the table 2 is shown in this lubricant properties in table 1 and the table 2.
[notes]
1) compound of Mn=300 is a ricinoleate acid simple substance, and each compound of Mn=650～1650 is the polycondensation ricinoleate acid, again with this polycondensate further with the dodecyl acid dehydration condensation that (dehydrating condensation) obtain that reacts,
2) potassium hydroxide (purity: the mixture of the 50 quality % aqueous solution 80%) and N-(2-hydroxyethyl) piperazine
3) mixture of the 1-alkene of carbonatoms 10～18
4) hexene Diethylene Glycol (HLB=4)
5) rust-preventive agent (benzotriazole)
According to table 1 and table 2, use the lubricant of embodiments of the invention 1～14 as can be known, no matter be the processing of various steel (steel and galvanized steel etc.), still the processing of various aluminiums, mold is all excellent, simultaneously, all has good bonding adaptability for steel, aluminium.
Relative therewith, do not contain the B composition comparative example 1～3, do not contain the A composition comparative example 4, do not contain the D composition comparative example 5, do not contain the E composition comparative example 6, do not contain the lubricant in the comparative example 7 of C composition, can not satisfy in steel, aluminum profile extrusion mold and for the adaptive over-all properties of the bonding of steel, aluminium.
Utilizability on the industry
Water-soluble metal working lubricant of the present invention to various metals processing such as forging and pressing processing effectively especially, all shows significant processing characteristics in arbitrary metal processing of the non-ferrous metal such as aluminium and the ferrous metals such as iron or steel. In addition, also be the water-soluble metal working lubricant of binder adaptability excellence.
Therefore, the Metalworking lubricant in the time of can being effective as the multiple machined material such as processing automobile component uses.
Claims (8)
1. water-soluble metal working lubricant, be selected from by (A) at least a hydroxy aliphatic acid compound, the lipid acid of (B) carbonatoms 8～20, (C) among the dehydration condensation of the polycondensate of the polycondensate of hydroxy fatty acid, hydroxy fatty acid and hydroxy fatty acid or hydroxy fatty acid and lipid acid be selected from least a basic cpd, (D) carbonatoms among alkali-metal oxyhydroxide and the organic amine compound be 8～20 normal olefine and (E) nonionic be that tensio-active agent mixes.
2. water-soluble metal working lubricant according to claim 1, with the lubricant all-mass is benchmark, mixes (A) composition 10～60 quality %, (B) composition 3～30 quality %, (D) composition 0.5～30 quality %, (E) composition (C) composition in 3～50 quality % and neutralization equivalent than ((C)/((A)+(B))) are 0.5～2.5 scope and forms.
3. according to claim 1 or 2 described water-soluble metal working lubricants, the number-average molecular weight of hydroxy aliphatic acid compound (A) is 300～2000.
4. according to claim 1 or 2 described water-soluble metal working lubricants, lipid acid (B) is the lipid acid of carbonatoms 8～10.
5. according to claim 1 or 2 described water-soluble metal working lubricants, basic cpd (C) is the mixture of alkali-metal oxyhydroxide and organic amine compound.
6. according to claim 1 or 2 described water-soluble metal working lubricants, normal olefine (D) is the 1-alkene of carbonatoms 8～20.
7. according to claim 1 or 2 described water-soluble metal working lubricants, mixed at least a the forming that is selected among rust-preventive agent, antioxidant and the sanitas.
8. one kind with claim 1 or 3～300 times of water-soluble metal working lubricants that form of 2 described water-soluble metal working lubricant dilute with waters.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2008094078A JP5352107B2 (en) | 2008-03-31 | 2008-03-31 | Water-soluble metal processing lubricant |
| JP2008-094078 | 2008-03-31 | ||
| PCT/JP2009/054656 WO2009122875A1 (en) | 2008-03-31 | 2009-03-11 | Water-soluble metalworking lubricant |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101970627A true CN101970627A (en) | 2011-02-09 |
| CN101970627B CN101970627B (en) | 2013-10-09 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009801093744A Expired - Fee Related CN101970627B (en) | 2008-03-31 | 2009-03-11 | Water-soluble metal working lubricant |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP5352107B2 (en) |
| CN (1) | CN101970627B (en) |
| MY (1) | MY177023A (en) |
| WO (1) | WO2009122875A1 (en) |
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| CN103484226A (en) * | 2013-08-24 | 2014-01-01 | 天长市康和金属材料有限公司 | Microemulsion semi-synthetic copper wire drawing liquid composition |
| CN103827278A (en) * | 2011-05-06 | 2014-05-28 | 凯密特尔有限责任公司 | Amine-free voc-free metal working fluid |
| CN103923733A (en) * | 2014-04-30 | 2014-07-16 | 洛阳惠尔纳米科技有限公司 | Water-based lubricant based on dodecahydroxyl stearic acid and preparation method thereof |
| CN103946355A (en) * | 2011-11-17 | 2014-07-23 | 出光兴产株式会社 | Water-soluble metal working oil, metal working fluid, and metal working method |
| CN103958655A (en) * | 2011-11-17 | 2014-07-30 | 出光兴产株式会社 | Water-soluble metal working oil, metal working fluid, and metal working method |
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| CN106191871A (en) * | 2015-04-30 | 2016-12-07 | 富翔精密工业(昆山)有限公司 | Aluminium alloy protective agent and protective agent solution thereof |
| CN113993978A (en) * | 2019-06-28 | 2022-01-28 | 出光兴产株式会社 | Metal working oil |
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| CN101955844B (en) * | 2010-08-13 | 2013-04-10 | 武汉柏康科技有限责任公司 | Water-based dry film lubricant for chain conveyer belt and preparation method thereof |
| JP6051026B2 (en) * | 2012-11-20 | 2016-12-21 | 出光興産株式会社 | Water-soluble metalworking fluid, metalworking fluid, and metalworking method |
| CN105038926B (en) * | 2015-07-03 | 2017-07-18 | 上海尤希路化学工业有限公司 | Pure cation cold rolling of strip steel oil |
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| CN103958655A (en) * | 2011-11-17 | 2014-07-30 | 出光兴产株式会社 | Water-soluble metal working oil, metal working fluid, and metal working method |
| US9605232B2 (en) | 2011-11-17 | 2017-03-28 | Idemitsu Kosan Co., Ltd. | Water-soluble metalworking oil agent, metalworking fluid, and metalworking method |
| US9683189B2 (en) | 2011-11-17 | 2017-06-20 | Idemitsu Kosan Co., Ltd. | Water-soluble metalworking oil agent, metalworking fluid, and metalworking method |
| CN103946355A (en) * | 2011-11-17 | 2014-07-23 | 出光兴产株式会社 | Water-soluble metal working oil, metal working fluid, and metal working method |
| CN103484226A (en) * | 2013-08-24 | 2014-01-01 | 天长市康和金属材料有限公司 | Microemulsion semi-synthetic copper wire drawing liquid composition |
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| CN106191871A (en) * | 2015-04-30 | 2016-12-07 | 富翔精密工业(昆山)有限公司 | Aluminium alloy protective agent and protective agent solution thereof |
| CN106147976A (en) * | 2016-05-27 | 2016-11-23 | 中国兵器工业第五九研究所 | Cavity liner composite wax powder Plastic Forming is with lubricator and preparation method thereof |
| CN113993978A (en) * | 2019-06-28 | 2022-01-28 | 出光兴产株式会社 | Metal working oil |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5352107B2 (en) | 2013-11-27 |
| CN101970627B (en) | 2013-10-09 |
| JP2009242743A (en) | 2009-10-22 |
| MY177023A (en) | 2020-09-02 |
| WO2009122875A1 (en) | 2009-10-08 |
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