CN101970621A - Formulation of a metalworking fluid - Google Patents

Formulation of a metalworking fluid Download PDF

Info

Publication number
CN101970621A
CN101970621A CN2008801264885A CN200880126488A CN101970621A CN 101970621 A CN101970621 A CN 101970621A CN 2008801264885 A CN2008801264885 A CN 2008801264885A CN 200880126488 A CN200880126488 A CN 200880126488A CN 101970621 A CN101970621 A CN 101970621A
Authority
CN
China
Prior art keywords
acid
composition
aforementioned
oil
volume
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2008801264885A
Other languages
Chinese (zh)
Inventor
L·E·孔德利
J·崔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chemetall Corp
Original Assignee
Chemetall Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemetall Corp filed Critical Chemetall Corp
Priority to CN201610971935.3A priority Critical patent/CN106635320A/en
Publication of CN101970621A publication Critical patent/CN101970621A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/045—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution and non-macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M103/00—Lubricating compositions characterised by the base-material being an inorganic material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • C23F11/12—Oxygen-containing compounds
    • C23F11/124—Carboxylic acids
    • C23F11/126—Aliphatic acids
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • C23F11/14—Nitrogen-containing compounds
    • C23F11/141—Amines; Quaternary ammonium compounds
    • C23F11/143—Salts of amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C10M2201/082—Inorganic acids or salts thereof containing nitrogen
    • C10M2201/083—Inorganic acids or salts thereof containing nitrogen nitrites
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/087—Boron oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/122—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/16—Naphthenic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol or ester thereof; bound to an aldehyde, ketonic, ether, ketal or acetal radical
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C10M2209/1045—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
    • C10M2209/1055—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/107—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106
    • C10M2209/1075—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106 used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/109—Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C10M2215/224—Imidazoles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/024—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/026—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrile group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/028—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrogen-containing hetero ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/043—Ammonium or amine salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C10M2227/066—Organic compounds derived from inorganic acids or metal salts derived from Mo or W
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/02—Groups 1 or 11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/055—Particles related characteristics
    • C10N2020/06—Particles of special shape or size
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/09—Characteristics associated with water
    • C10N2020/091—Water solubility
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/24—Emulsion properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01—Emulsions, colloids, or micelles

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Lubricants (AREA)

Abstract

Non-oil containing metalworking fluids, also known as synthetic metalworking fluids having an engineered particle size of greater than 120 nanometers upon dilution. The expansive particle size results in a substantial increase in lubricity, suitable for the heavy-duty operations previously attainable only with oil-containing products. Additionally, this non-oil containing metalworking lubricant optionally incorporates positive attributes of oil-containing products, including excellent corrosion inhibition and heavy-duty operation capable lubricity.

Description

The metal working fluids preparaton
Related application
[inapplicable]
Research that federal government sponsors or exploitation
[inapplicable]
[microfilm/copyright authorization scope]
[inapplicable]
Background of invention
The present invention relates to not butyraceous metal processing (metalworking) fluid, be also referred to as the synthetic metal working fluids.
Metal processing is defined as metal works is shaped so that it meets one group of geometric specifications of expectation.Metal processing comprises two basic classes: cutting and moulding.Cutting operation comprises grinding, turning, milling, tapping, broaching and hobbing.Forming operation comprises that hot and cold rolls, and stretches, and forges punching press and die-cut.
Metal working fluids is that cutting and forming operation are all essential in the two.They must provide lubricated between workpiece and instrument, and provide cooling by remove the heat that produces in metal process operation process.
The lubricated reduction that is defined in two frictional force between the translational surface.The lubricated of two main types is that hydrokinetics is lubricated lubricated with border or extreme pressure (EP) in the metal process operation.Hydrokinetics lubricates to relate to by the fluid lubricant film and separates translational surface.When the surface rubs together, the lubricated minimise wear that is suffered that makes of border or EP.Polymeric lubricant can provide this two types lubricated.
Metal working fluids is divided into two kinds of main kinds, butyraceous and butyraceous not.The butyraceous kind comprises straight chain oil, soluble oil and semi-synthetic oil, and it has utilized mineral oil as main lubricant all.The kind that does not conform to oil is known as synthetic process fluid, and it is included in the composition that produces the additive of oilness in moisture transmission system or the thinner.Soluble oil and semi-synthetic product have occupied 80% the market share, and the reducible straight chain oil kind of non-water has 10% share, and the synthetic process fluid has occupied 10% the market share.
The metal working fluids of existing type has relative merits.The advantage that contains oil production is excellent oilness, wide range of applications and the erosion-resisting barrier action of protection storage tank (sump).The shortcoming of butyraceous metal working fluids is that the water hardness often influences this fluidic stability, foam is a kind of regular problem, this has comprised the emulsifying agent of more senior detergency owing to them, they have carried bigger dirt load, their disposal and the cost that they are cleaned from groove are higher, and they have bigger microorganism problem.
Because all multifactor from environmental problem to the microorganism advantage uses synthetic process fluid to be encouraged.But most of human consumer continues to use and contains oil production, and this is because they have good lubricity under low relatively cost situation, and because the increase relevant with synthetic process fluid safeguard etching problem.The protective barrier film that is provided by oil is provided the storage tank of synthetic process fluid, can corrode and " freezing " machining system bolt, makes maintenance become difficulty.In addition, the high lubricity sintetics contains the oil production costliness than similar oilness.Semi-synthetic process fluid has limited their purposes in the heavy loading operation in the reduction of the physics oilness on the cost basis
Summary of the invention
An aspect of of the present present invention relates to a kind of metal working fluids product of brand-new kind.These new chemical product have been incorporated the synergy blend of carboxylate salt, boundary lubricant lipid acid and EO/PO polymkeric substance into, its reaction is to form such part (moiety), it can randomly have the granularity of increase in certain embodiments, and excellent oilness or the two have concurrently.In addition, the thinner that some embodiment is used is opaque, and has simulated the outward appearance of oil base solution.
In certain embodiments, the volume average particle sizes of this metal working fluids composition when being diluted to 0.1-50 volume % can be 125nm or bigger.Said composition comprises:
(a) one or more polymeric lubricants;
(b) one or more carboxylate salts;
(c) one or more emulsifying agents or dispersion agent; With
(d) transmit component.
Some embodiment can be the synthetic metal working fluids, and its through engineering approaches that shows oilness increases, and corrosion protection and microbiological manipulation still are provided simultaneously.
Description of drawings
[inapplicable]
Embodiment
In one embodiment, the volume average particle sizes of metal working lubricant of the present invention when being diluted to 0.1-50 volume % can be 125nm or bigger.In one embodiment, said composition can comprise:
(a) one or more polymeric lubricants;
(b) one or more carboxylate salts;
(c) one or more emulsifying agents or dispersion agent; With
(d) transmit component.
More specifically, said composition can comprise:
(a) one or more segmented copolymers of 1-80 volume % are as polymeric lubricant;
(b) one or more carboxylate salts of 1-40 volume %;
(c) one or more emulsifying agents or the dispersion agent of 1-20 volume %; With
(d) the transmission component of 1-97 volume %.
In another embodiment, said composition can comprise:
(a) one or more segmented copolymers of 5-40 volume % are as polymeric lubricant;
(b) one or more carboxylate salts of 3-30 volume %;
(c) one or more emulsifying agents of 2-12 volume %; With
(d) the transmission component of 18-90 volume %.
In another embodiment, said composition can comprise:
(a) one or more segmented copolymers of 15-25 volume % are as polymeric lubricant;
(b) one or more carboxylate salts of 5-15 volume %;
(c) one or more emulsifying agents or the dispersion agent of 3-8 volume %; With
(d) the transmission component of 52-77 volume %.
The every kind of component and the example are further described below.
Polymeric lubricant
This polymeric lubricant can be an EO/PO multipolymer for example.Below this EO/PO polymkeric substance for example can comprise one or more.This EO/PO multipolymer can be to have at the polyoxypropylene block at center with at the segmented copolymer of the polyoxyethylene chain of arbitrary end.This EO/PO multipolymer can be included in the polyoxyethylene blocks at center and at the segmented copolymer of the polyoxypropylene chains of arbitrary end.This EO/PO multipolymer can be to the 1 Tetrablock copolymer of addition in succession derived from oxyethane and propylene oxide.This EO/PO multipolymer can be the ethylene oxide/propylene oxide multipolymer with at least one terminal hydroxy group.This EO/PO multipolymer can be the soluble oil base-material (base stock) of oxyethane and propylene oxide random copolymers.This EO/PO multipolymer can be the water-soluble carboxyl acid esters of the pure or such alcohol of water-soluble polyoxyethylene alcohol or polyoxypropylene.This EO/PO multipolymer can be the pure initial base-material that whole polyoxypropylene groups have a terminal hydroxy group.This EO/PO multipolymer can be monobasic or diester, polyol ester, the polyalkylene glycol ester, the polyalkylene glycol of the copolymer grafted of usefulness organic acid, phosphoric acid ester, polyisobutene, polyacrylonitrile, polyacrylamide, polyvinylpyrrolidone, polyvinyl alcohol and acrylic or methacrylic acid and acrylate.
The polymkeric substance that clearly it is contemplated that comprises the polypropylene glycol segmented copolymer, polyethyleneglycol block copolymer, perhaps polyethylene/polypropylene glycol segmented copolymer.
Carboxylate salt
The lipotropy that part neutral carboxylate salt plans to be used for to be used for polymeric lubricant partly offers network with volume particle size more and the bigger granularity that through engineering approaches is provided.This salt can be for example by using described in this manual any alkaline reagents (alkaline agent) to come in the part and the free carboxy acid, fat or oil and make.Clearly the positively charged ion of She Xiang this salt comprises basic metal or alkanol amine salt, for example sodium salt (for example by making with sodium-hydroxide treatment acid).This part neutral pH depends on employed alkaline reagents.Many these carboxylate salts also provide their boundary lubrications own in addition.
The carboxylic acid that uses as raw material can be line style or branching, saturated or undersaturated free carboxy acid.This acid can be saturated or undersaturated, and undersaturated position can be cis or trans structure.This acid can be dicarboxylic acid, tricarboxylic acid, the perhaps ester of carboxylic acid, amine, the derivative of acid amides or ethoxylation.Alternative is that the fat of animal or plant origin or oil can directly neutralize carboxylate salt is provided.
Following is the carboxylic acid of some imaginations or the example in its source: caproic acid (caproic acid) (being also referred to as caproic acid (hexanoic acid)), enanthic acid (enanthic acid) is also referred to as enanthic acid (heptanoic acid)), sad (caprylic acid) is also referred to as sad (octanoic acid)), n-nonanoic acid (pelargonic acid) is also referred to as n-nonanoic acid (nonanoic acid)), different n-nonanoic acid, capric acid (capric acid) is also referred to as capric acid (decanoic acid)), neodecanoic acid, lauric acid (being also referred to as dodecylic acid), stearic acid (being also referred to as octadecanoic acid), eicosanoic acid (being also referred to as arachic acid), palmitinic acid (being also referred to as hexadecanoic acid), erucic acid, oleic acid, arachidonic acid, linolic acid, linolenic acid, tetradecanoic acid (is also referred to as tetradecanoic acid) ， docosoic (being also referred to as docosoic acid), alpha-linolenic acid, hexacosanoic acid, ricinolic acid, butyric acid, lard, butter, butter, Oleum Cocois, plam oil, Oleum Gossypii semen, wheatgerm oil, soybean oil, sweet oil, Semen Maydis oil, Trisun Oil R 80 and rape seed oil or Tower rape oil.
Emulsifying agent or dispersion agent
This metal working fluids composition of dilute with water has formed opaque emulsion.When the concentration that is higher than 10%, this emulsion can need stabilization.Emulsifying agent or dispersion agent plan to be used to provide stablizing for through engineering approaches macrobead emulsion.
This emulsifying agent or dispersion agent can be following one or more: alkanolamide, alkylaryl sulphonate, alkyl aryl sulphonic acid, amine oxide, acid amides soap and amine soap, segmented copolymer, carboxylated alcohol, carboxylic acid or lipid acid, the alcohol of ethoxylation, the alkylphenol of ethoxylation, the amine of ethoxylation or acid amides, the lipid acid of ethoxylation, the fatty ester of ethoxylation and oil, the phenol of ethoxylation, aliphatic amide and ester, glyceryl ester, binary alcohol esters, imidazolines and imidazolidine derivatives, xylogen and lignin derivative, maleic anhydride or succinyl oxide, methyl ester, monoglyceride and derivative, naphthenic acid, alkene sulfonate, phosphoric acid ester, polyalkylene glycol, polyoxyethylene glycol, polyvalent alcohol, polymeric (polysaccharide, vinylformic acid, acrylamide), the lipid acid of propenoxylated and ethoxylation, alcohol or alkylphenol, quaternary surfactant, sarcosine derivative, the soap class, sorbitanic derivative, the ester of sucrose and glucose and derivative, the vitriol of oil ﹠ fat acid and sulfonate, the vitriol of the alkylphenol of ethoxylation and sulfonate, the vitriol of alcohol, the vitriol of the alcohol of ethoxylation, the perhaps vitriol of fatty ester, the sulfonate of dodecyl and tridecyl benzene, the sulfonate of naphthalene, the sulfonate of alkylnaphthalene, the sulfonate of oil, sulphosuccinamate, sulfosuccinate and derivative, perhaps tridecyl and Witco 1298 Soft Acid.
The corrosion-inhibiting component
Containing oil production relies on this oil itself to form the barrier coatings of corrosion protection to a great extent.The butyraceous product randomly can not obtain this corrosion protection by chemical means.Corrosion inhibitor is a chemical compound, and it adds the fashionable corrosion that can stop or delay metal and alloy at lower concentration.
Some mechanism of corrosion inhibitor is to form passivation layer (film on material surface, it stops corrosives near this metal), and the oxidation or the reduction part (anode and cathodic inhibitor) of inhibited oxidation reduction corrosion system are perhaps removed dissolved oxygen.
The many different material that falls into this group is arranged here.Some examples are an alkali metal salt and alkanol amine salts of carboxylic acid, undecanoic acid or dodecylic acid or their salt, C 4-22Carboxylic acid or their salt, boric acid and salt thereof, tolyl-triazole and salt thereof, benzotriazole category and salt thereof, imidazolines and salt thereof, alkanolamine and acid amides, sulfonate, an alkali metal salt of naphthenic acid and alkanol amine salt, phosphate amine salt, alkali metal nitrites salts, alkaline carbonate, carboxylic acid derivative, the alkyl sulfonamide carboxylic acid, the aryl sulfonic acid amides carboxylic acid, fatty sarkosine (fatty sarkoside), derivatives containing phenoxy group and Sodium orthomolybdate.
Basifier (ALKALINITY AGENT)
Basifier provides the pH of expectation for product, and has kept basicity and pH buffering in some cases.The example of basifier includes but not limited to alkanol primary amine, secondary amine and tertiary amine, amino methyl propyl alcohol (AMP-95), diglycolamine (DGA), monoethanolamine (MBA), monoisopropanolamine (MIPA), butylethanolamine (NBEA), dicyclohexylamine (DCHA), diethanolamine (DEA), butyl diethanolamine (NBDEA), trolamine (TEA), alkali metal hydroxide, potassium hydroxide, sodium hydroxide, magnesium hydroxide, lithium hydroxide, the carbonate of metal and supercarbonate, yellow soda ash, sodium bicarbonate, salt of wormwood and saleratus.The preferred basifier that is used for some embodiment is an alkali metal hydroxide.
The pH of described composition imagination randomly is 3 or bigger, randomly is 3-10, randomly is 4-9, randomly is 4-8.
Other composition
Said composition can also comprise defoamer and/or biocide or mycocide, and additive any other routine or new.
Transmit component (TRANSPORT COMPONENT)
Preferably transmitting the most of ground of component (it may also be referred to as dispersion medium or carrier), choosing wantonly all is water.But randomly, said composition can comprise one or more oil, preferably less than the oil of 10 volume %.These components can be the lubricating oil of any routine.If imagination is that compound oil and water transmit component, then emulsifying agent can be used for making the stable emulsion of oil and water.
At present the positive performance of utilizable non-oil production randomly remains in this composition and randomly comprises following a kind of, greater than a kind of or over-all properties: environment compliance (environmental compliance), good cooling, good chip removal or settling character, long storage tank life-span and good biological resistance.
In the present invention who asks for protection, this metal working fluids composition can have less than 8000 newton-cm when being diluted to 0.1-50 volume % -1Oilness, this oilness is measured with tapping torque rating instrument.
Said composition is at low oil (that is, being not more than the oil of 10 volume %) or do not have one or more the following favourable performances that have that can choose wantonly in the oily preparaton basically or fully:
The oilness that contains oil production,
Approach to contain the oilness/cost-performance point of oil production,
Minimizing is to workman's pungency (pungency is relevant with high pH product),
Contain getting rusty or other corrosion protection of oil production, perhaps
The chemical of no alkanolamine.
Granularity
As the general was being seen in the following embodiments, the composition of the present invention that is disposed comprised particle.Bigger particle is planned to be used to provide bigger oilness, though the present invention is not limited to the exactness of this theory.The imagination particle of any embodiment randomly has following volume mean diameter: 120-100000 nanometer (nm), alternative is (alternatively) 120-100000nm, alternative is 120-10000nm, alternative is 120-5000nm, alternative is 125-10000nm, alternative is 125-5000nm, alternative is 125-2000nm, alternative is 140-10000nm, alternative is 140-5000nm, alternative is 140-2000nm, alternative is 200-10000nm, and alternative is 200-5000nm, and alternative is 200-2000nm, alternative is 220-10000nm, alternative is 220-5000nm, and alternative is 220-2000nm, and alternative is 350-10000nm, alternative is 350-5000nm, and alternative is 350-2000nm.
Embodiment
Can better understand aforesaid content by the reference the following examples, the following examples purpose is that the method that the present invention uses is implemented in explanation, and purpose is not to limit the scope of the invention.
Embodiment 1
Table 1
Figure BPA00001195248800071
Materials A-the E of table 1 is used in the tapping torque operation, and this tapping torque operation relates to the tapping of 6061 aluminium.Before test, this enriched material at first is diluted to the solution of 7.5 volume %.This tapping torsion-testing is the quantitative measurment of the oilness of metal working fluids.Its ASTM standard method name is called D5619.The tapping moment of torsion has reflected industrial machining process to test better mode than other, and it is normally undertaken by two metallic surfaces that rub together.It is an excellent process of distinguishing metal working fluids (MWF) product machinability in the laboratory.It is closely-related with on-the-spot (field) machinability that tapping moment of torsion result has been proved to be.
This tapping torque rating instrument is designed to measure the oilness of MWF, carries out actual cutting simultaneously.In the tapping operating process, when tapping is advanced by depth of cut, this tapping torque rating instrument measured 250 times moment moment of torsion.Special software has promoted the analysis for data then.The tapping moment of torsion is represented with N-m (Newton meter (n.m.)) or N-cm (newton-centimetre) unit.The high lubricity product will produce low torque value.On the contrary, low oilness product will produce high torque value.In this way, this instrument has quantized the oilness difference between the product.
A shortcoming of tapping torque rating instrument is that measured absolute torque value depends on and will change along with the diameter of used tapping.So, in order to eliminate these how much influences, effectively oilness is expressed as the moment of torsion on the per unit area, the energy that tapping rotates a circle and consumed is described.The equation that is used for this is
E/A＝(2’r)/r2，
Here t=torque value, r=tapping radius, the energy of E/A=per unit area, and unit is N-m -1(Newton/meter) or N-cm -1(newton/centimetre).
The oilness data are illustrated in the table 1, are defined as E/A.The E/A value is low more, and oilness and machinability are good more.Whole samples is diluted with water to 7.5 volume % before test.
Embodiment 2:
The material of table 1 is used for the granularity operation, and it is the measurement of the volume average particle sizes of unit that this granularity operation relates to the nanometer.Before test, at first this enriched material is diluted with water to the solution of 7.5 volume %.Particulate measurement instrument (particle-sizing instrument) uses the high-efficiency dynamic scattering of light to quantize the granularity of 20-100000 nanometer.
The test before with whole diluted samples to 7.5 volume %.Formed granularity is illustrated in the table 1.
Embodiment 3
The material C of table 1 two different concentration determination granularities, and is estimated outward appearance and stability of emulsion in each concentration.The result is illustrated in the table 2, and it demonstrates big mean particle size in each concentration, opaque outward appearance and excellent stability.Bigger granularity is the feature of better lubricant.Typical synthetic MWF has formed the settled solution of granularity less than 100 nanometers when dilution.The granularity of the sample C of dilution is doubly big to the typical synthetic viewed maximum sized 3.5-20 of MWF.
Table 2
Figure BPA00001195248800081
Figure BPA00001195248800091
Obtained best oilness and granularity with sample C as can be seen from embodiment 1-3, sample C merges 10% carboxylic acid-an alkali metal salt (carboxylic acid-alkali salt) and 20%Pluronic " R " segmented copolymer.This ratio has obtained maximum volume average particle sizes and maximum oilness.
The oilness that it should be apparent that composition from this embodiment equally is the function of its volume average particle sizes to a great extent.Improve volume average particle sizes and produced the oilness that improves.
The increase of sample C concentration has caused obviously bigger volume average particle sizes as can be seen from embodiment 3.This has explained the necessity of emulsifying agent for stable high concentrations sample C.When not having emulsifying agent, it is believed that the granularity of high density is agglomerated into unsure state with successive.
Should be understood that the difference variation of the preferred embodiments of the invention as herein described and change will be conspicuous to those skilled in the art.The target advantage that can carry out such changes and improvements and not break away from the spirit and scope of the invention and do not reduce it.Therefore be intended to cover such variation and change with appended claim.

Claims (24)

1. metal working fluids composition, it has 125nm or bigger volume average particle sizes when being diluted to 0.1-50 volume %, and said composition comprises:
(a) one or more polymeric lubricants;
(b) one or more carboxylate salts;
(c) one or more emulsifying agents or dispersion agent; With
(d) transmit component.
2. the composition of claim 1, it comprises one or more oil less than 10 volume %.
3. each composition of aforementioned claim, wherein this transmission component comprises water.
4. each composition of aforementioned claim, it comprises the corrosion-inhibiting component.
5. each composition of aforementioned claim, wherein this corrosion-inhibiting component comprises following one or more: an alkali metal salt of carboxylic acid and alkanol amine salt, undecanoic acid or dodecylic acid and their salt, C 4-22Carboxylic acid and their salt, boric acid class, boron-containing compound and their salt, tolyl-triazole and salt thereof, benzotriazole category and salt thereof, imidazolines and salt thereof, alkanolamine and acid amides, sulfonate, an alkali metal salt of naphthenic acid and alkanol amine salt, phosphate amine salt, alkali metal nitrites salts, alkaline carbonate, carboxylic acid derivative, the alkyl sulfonamide carboxylic acid, the aryl sulfonic acid amides carboxylic acid, fatty sarkosine, derivatives containing phenoxy group and Sodium orthomolybdate.
6. each composition of aforementioned claim, wherein pH is 3-9.
7. each composition of aforementioned claim, it comprises basifier.
8. the composition of claim 7, wherein this basifier is following one or more: alkanol primary amine, secondary amine and tertiary amine, amino methyl propyl alcohol (AMP-95), diglycolamine (DGA), monoethanolamine (MBA), monoisopropanolamine (MIPA), butylethanolamine (NBEA), dicyclohexylamine (DCHA), diethanolamine (DEA), butyl diethanolamine (NBDEA), trolamine (TEA), alkali metal hydroxide, potassium hydroxide, sodium hydroxide, magnesium hydroxide, lithium hydroxide, the carbonate of metal and supercarbonate, yellow soda ash, sodium bicarbonate, salt of wormwood and saleratus.
9. claim 7 or 8 composition, wherein this basifier is an alkali metal hydroxide.
10. each composition of aforementioned claim, it comprises defoamer.
11. each composition of aforementioned claim, it comprises biocide and/or mycocide.
12. each composition of aforementioned claim, wherein this polymeric lubricant is a segmented copolymer.
13. each composition of aforementioned claim, wherein this polymeric lubricant is following one or more: be included in the polyoxypropylene block at center and at the segmented copolymer of the polyoxyethylene chain of arbitrary end, be included in the polyoxyethylene blocks at center and at the segmented copolymer of the polyoxypropylene chains of arbitrary end, derived from oxyethane and propylene oxide to 1, the 2-quadrol is the Tetrablock copolymer of addition in succession, ethylene oxide/propylene oxide multipolymer with at least one terminal hydroxy group, the soluble oil base-material of oxyethane and propylene oxide random copolymers, the water-soluble carboxyl acid esters of the alcohol that water-soluble polyoxyethylene alcohol or polyoxypropylene are pure or such, all polyoxyethylene group has the pure initial base-material of a terminal hydroxy group, monobasic and diester, polyol ester, the polyalkylene glycol ester is used organic acid, phosphoric acid ester, polyisobutene, polyacrylonitrile, polyacrylamide, polyvinylpyrrolidone, polyvinyl alcohol, and the polyalkylene glycol of the copolymer grafted of acrylic or methacrylic acid and acrylate.
14. each composition of aforementioned claim, wherein this polymeric lubricant is the polypropylene glycol segmented copolymer.
15. each composition of aforementioned claim, wherein this polymeric lubricant is a polyethyleneglycol block copolymer.
16. each composition of aforementioned claim, wherein this polymeric lubricant is the polyethylene/polypropylene glycol segmented copolymer.
17. each composition of aforementioned claim, wherein this carboxylate salt comprises C 4-C 22An alkali metal salt of carboxylic acid or lipid acid and ester and/or alkanol amine salt.
18. each composition of aforementioned claim, wherein this carboxylate salt comprises following one or more: butyric acid, caproic acid, enanthic acid, sad, n-nonanoic acid, different n-nonanoic acid, capric acid, neodecanoic acid, dodecylic acid, tetradecanoic acid, hexadecanoic acid, octadecanoic acid, oleic acid, linolic acid, linolenic acid, alpha-linolenic acid, ricinolic acid, arachic acid, docosoic acid, hexacosanoic acid, erucic acid, arachidonic acid, lard, butter, butter, Oleum Cocois, plam oil, Oleum Gossypii semen, wheatgerm oil, soybean oil, sweet oil, Semen Maydis oil, Trisun Oil R 80 and rape seed oil or Tower rape oil.
19. each composition of aforementioned claim, wherein this emulsifying agent or dispersion agent are following one or more: alkanolamide, alkylaryl sulphonate, alkyl aryl sulphonic acid, amine oxide, the soap of acid amides and amine, segmented copolymer, carboxylated alcohol, carboxylic acid or lipid acid, the alcohol of ethoxylation, the alkylphenol of ethoxylation, the amine of ethoxylation or acid amides, the lipid acid of ethoxylation, the fatty ester of ethoxylation and oil, the phenol of ethoxylation, aliphatic amide and ester, glyceryl ester, binary alcohol esters, imidazolines and imidazolidine derivatives, xylogen and lignin derivative, maleic anhydride or succinyl oxide, methyl ester, monoglyceride and derivative, naphthenic acid, alkene sulfonate, phosphoric acid ester, polyoxyethylene glycol, polyvalent alcohol, polymeric (polysaccharide, vinylformic acid, acrylamide), the lipid acid of propenoxylated and ethoxylation, alcohol or alkylphenol, quaternary surfactant, sarcosine derivative, the soap class, the sorbitanic derivative, the ester of sucrose and glucose and derivative, the vitriol of oil ﹠ fat acid and sulfonate, the vitriol of the alkylphenol of ethoxylation and sulfonate, the vitriol of alcohol, the vitriol of the alcohol of ethoxylation, the vitriol of fatty ester, the sulfonate of dodecyl and tridecyl benzene, the sulfonate of naphthalene and alkylnaphthalene, the sulfonate of oil, sulphosuccinamate, sulfosuccinate and derivative, tridecyl and Witco 1298 Soft Acid.
20. each composition of aforementioned claim, wherein this metal working fluids composition has less than 8000 newton-cm when being diluted to 0.1-50 volume % -1Oilness, this oilness is measured with tapping torque rating instrument.
21. each metal working fluids composition of aforementioned claim, it comprises:
(a) one or more segmented copolymers of 1-80 volume %;
(b) one or more carboxylate salts of 1-40 volume %;
(c) one or more emulsifying agents of 1-20 volume %; With
(d) transmit component.
22. each metal working fluids composition of aforementioned claim, it comprises:
(a) one or more segmented copolymers of 5-40 volume %;
(b) one or more carboxylate salts of 3-30 volume %;
(c) one or more emulsifying agents of 2-12 volume %; With
(d) transmit component.
23. each metal working fluids composition of aforementioned claim, it comprises:
(a) one or more segmented copolymers of 15-25 volume %;
(b) one or more carboxylate salts of 5-15 volume %;
(c) one or more emulsifying agents of 3-8 volume %;
(d) transmit component.
24. each metal working fluids composition of aforementioned claim, it has following volume mean diameter: 120-100000 nanometer (nm), alternative 125-10000nm, 140-10000nm, alternative 220-10000nm, alternative 350-5000nm, alternative 350-2000nm.
CN2008801264885A 2007-12-10 2008-12-04 Formulation of a metalworking fluid Pending CN101970621A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610971935.3A CN106635320A (en) 2007-12-10 2008-12-04 Formulation of a metalworking fluid

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/953502 2007-12-10
US11/953,502 US20090149359A1 (en) 2007-12-10 2007-12-10 Formulation of a metal working fluid
PCT/US2008/085483 WO2009076151A1 (en) 2007-12-10 2008-12-04 Formulation of a metalworking fluid

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN201610971935.3A Division CN106635320A (en) 2007-12-10 2008-12-04 Formulation of a metalworking fluid

Publications (1)

Publication Number Publication Date
CN101970621A true CN101970621A (en) 2011-02-09

Family

ID=40364329

Family Applications (2)

Application Number Title Priority Date Filing Date
CN201610971935.3A Pending CN106635320A (en) 2007-12-10 2008-12-04 Formulation of a metalworking fluid
CN2008801264885A Pending CN101970621A (en) 2007-12-10 2008-12-04 Formulation of a metalworking fluid

Family Applications Before (1)

Application Number Title Priority Date Filing Date
CN201610971935.3A Pending CN106635320A (en) 2007-12-10 2008-12-04 Formulation of a metalworking fluid

Country Status (9)

Country Link
US (1) US20090149359A1 (en)
EP (1) EP2075319A1 (en)
JP (1) JP5704921B2 (en)
KR (2) KR20100135218A (en)
CN (2) CN106635320A (en)
BR (1) BRPI0822063A2 (en)
CA (1) CA2708595C (en)
MX (1) MX360113B (en)
WO (1) WO2009076151A1 (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102191121A (en) * 2011-03-22 2011-09-21 无锡市高润杰化学有限公司 Multifunctional cutting fluid
CN102585987A (en) * 2011-12-28 2012-07-18 烟台大学 Water suspension cutting agent for crystal cutting
CN103627491A (en) * 2013-11-27 2014-03-12 常熟市劲力工具有限公司 Grinding fluid for processing cutter disk
CN103827278A (en) * 2011-05-06 2014-05-28 凯密特尔有限责任公司 Amine-free voc-free metal working fluid
CN105001949A (en) * 2015-06-05 2015-10-28 上海贝能环保科技有限公司 Biodegradation environmentally-friendly quasi-dry cutting fluid and preparation method thereof
CN106279568A (en) * 2016-08-31 2017-01-04 广州米奇化工有限公司 Long-chain alcohol ether polycarboxylic acids and its preparation method and application
CN110305728A (en) * 2019-08-07 2019-10-08 上海工程技术大学 A kind of macromolecule Plastic Forming is with lubricator and preparation method
CN111286395A (en) * 2020-03-23 2020-06-16 上海问浪科技有限公司 Cutting fluid for metal processing
TWI716030B (en) * 2018-08-31 2021-01-11 日商日化精工股份有限公司 Preparation and processing liquid for cutting processing
CN115247096A (en) * 2021-10-25 2022-10-28 哈尔滨市力安特科技发展有限责任公司 High-safety harmless cutting fluid and preparation method thereof

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5394691B2 (en) * 2008-08-22 2014-01-22 出光興産株式会社 Water-soluble metalworking fluid and metalworking coolant
EP2331666A2 (en) * 2008-08-28 2011-06-15 BASF Corporation Hydraulic fluid and method of preventing vapor corrosion
DE102009030409A1 (en) * 2009-06-25 2011-01-05 Clariant International Limited Water-mixed metalworking fluids containing etherpyrrolidonecarboxylic acids
JP5420498B2 (en) * 2010-08-03 2014-02-19 ユシロ化学工業株式会社 Water-soluble machining fluid for fixed abrasive wire saws
CN102757852B (en) * 2011-04-29 2014-04-23 中国石油化工股份有限公司 Rolling lubricant composition and usage thereof
RU2461610C1 (en) * 2011-06-23 2012-09-20 Общество с ограниченной ответственностью "Научное предприятие "Высокие технологии" Lubricant coolant
MX2014006721A (en) * 2011-12-09 2014-10-13 Robert D Evans Metalworking fluid composition and method for its use in the machining of compacted graphite iron.
CN103361152A (en) * 2012-04-06 2013-10-23 王沛龙 Water-soluble super-lubrication anti-wear agent
CN102766517B (en) * 2012-07-24 2014-01-15 东莞市安美润滑科技有限公司 Full-synthetic water-based high-silicon aluminum alloy cutting fluid and preparation method and application method thereof
CN104927998B (en) * 2014-03-20 2017-12-22 中国石油化工股份有限公司 Micro-emulsion cutting fluid composition
EP3130654A1 (en) * 2015-08-14 2017-02-15 Sasol Performance Chemicals GmbH Composition comprising 2-alkyl carboxylic acid salts and use thereof as anti-corrosion additive
CN105695069A (en) * 2016-02-25 2016-06-22 天津高盛钢丝绳有限公司 Lubricant for wet-type wire-drawing technology for steel wire ropes
AU2017227532B2 (en) 2016-03-01 2019-06-20 Ecolab Usa Inc. Sanitizing rinse based on quat-anionic surfactant synergy
CA3124631A1 (en) 2016-08-11 2018-02-15 Ecolab USA, Inc. Interaction between antimicrobial quaternary compounds and anionic surfactants
CA3085059A1 (en) * 2017-12-08 2019-06-13 The Lubrizol Corporation Maleated soybean oil derivatives as additives in metalworking fluids
US10640723B2 (en) 2018-03-16 2020-05-05 Afton Chemical Corporation Lubricants containing amine salt of acid phosphate and hydrocarbyl borate
CN108949332B (en) * 2018-08-06 2021-08-10 广州市方川润滑科技有限公司 Preparation method of environment-friendly tapping liquid for cover plate of filter of automobile air conditioner and environment-friendly tapping liquid
CN109097176A (en) * 2018-08-30 2018-12-28 江苏欧仕达润滑油有限公司 A kind of micro-lubricating cutting liquid and preparation method thereof
CN109370715A (en) * 2018-09-07 2019-02-22 苏州安美润滑科技有限公司 A kind of multiple-effect punching oil and preparation method thereof
CN109536251B (en) * 2018-11-09 2021-06-01 上海金兆节能科技有限公司 Lubricating oil composition, preparation method thereof and trace lubricating oil prepared from lubricating oil composition
CN109337733B (en) * 2018-11-09 2021-06-25 上海金兆节能科技有限公司 Lubricant composition, preparation method thereof and trace cutting fluid prepared from same
CN110846118A (en) * 2019-11-29 2020-02-28 蓝思科技（长沙）有限公司 Environment-friendly water-based cutting fluid and preparation method thereof
CN114736729A (en) * 2022-04-22 2022-07-12 杭州金固环保设备科技有限公司 Environment-friendly water-based antirust agent and preparation method thereof
GB2619938A (en) * 2022-06-21 2023-12-27 Metalube Ltd Metalworking fluid concentrate

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4212470A (en) * 1977-09-14 1980-07-15 Trio Kabushiki Kaisha Head shell for pick-up arms and method of making same
JPS5714696A (en) * 1980-07-01 1982-01-25 Cosmo Co Ltd Flame retardant lubricating oil
US4452711A (en) * 1983-01-20 1984-06-05 Aluminum Company Of America Aqueous metalworking lubricant containing polyoxypropylene-polyoxyethylene-polyoxypropylene block copolymers
JPS62195040A (en) * 1986-02-21 1987-08-27 Mitsui Toatsu Chem Inc Production of aqueous suspension of polyvalent metallized salicylic acid resin
JPS6395295A (en) * 1986-10-09 1988-04-26 Kao Corp Water dispersion type processing oil composition for drawing-ironing molded can
JPH02117993A (en) * 1988-10-26 1990-05-02 Kao Corp Processed oil composition for di can
US4927550A (en) * 1989-01-27 1990-05-22 Castrol Industrial Inc. Corrosion preventive composition
JPH07258680A (en) * 1994-03-24 1995-10-09 Cosmo Oil Co Ltd Method for controlling particle diameter distribution of oil-in-water type emulsion
US5501815A (en) * 1994-09-26 1996-03-26 Ecolab Inc. Plasticware-compatible rinse aid
JPH08225795A (en) * 1995-02-20 1996-09-03 Sumitomo Metal Ind Ltd Rolling oil for stainless steel sheet
JP3244996B2 (en) * 1995-02-24 2002-01-07 ユシロ化学工業株式会社 Water-soluble metalworking oil
JP3391930B2 (en) * 1995-03-07 2003-03-31 新日本石油株式会社 Water-soluble cutting oil stock solution composition and water-soluble cutting oil composition
US5706684A (en) * 1995-10-03 1998-01-13 Cincinnati Milacron Inc. Metalworking process
BR9713464A (en) * 1996-08-30 2000-05-23 Solutia Inc New water-soluble metal machining fluids.
US5716917A (en) * 1996-09-24 1998-02-10 Cincinnati Milacron Inc. Machining fluid composition and method of machining
JP3933748B2 (en) * 1997-05-27 2007-06-20 株式会社ネオス Water-soluble cutting fluid for wire saw
JPH1150083A (en) * 1997-07-30 1999-02-23 Sugimura Kagaku Kogyo Kk Lubricant for metal plastic working
GB2350371B (en) * 1998-02-28 2002-06-12 Great Lakes Chemical Corp Metal working lubricant composition
EP1063280A1 (en) * 1999-06-21 2000-12-27 Quaker Chemical Corporation Metal working fluids
US6596674B2 (en) * 2000-02-29 2003-07-22 Henkel Corporation Metal working lubricants and their use
US20030181340A1 (en) * 2000-09-22 2003-09-25 Botz Frank K. Lubricants suitable for hydroforming and other metal manipulating applications
US6316394B1 (en) * 2001-01-29 2001-11-13 Milacron Inc. Machining fluid and method of machining
JP3947664B2 (en) * 2001-05-16 2007-07-25 株式会社Ａｄｅｋａ Water based lubricant
JP4916630B2 (en) * 2001-08-23 2012-04-18 株式会社Ａｄｅｋａ Water based lubricant
TW575660B (en) * 2001-09-07 2004-02-11 Dai Ichi Kogyo Seiyaku Co Ltd Nonflammable water-based cutting fluid composition and nonflammable water-based cutting fluid
JP3833578B2 (en) * 2002-06-19 2006-10-11 ユシロ化学工業株式会社 Water-soluble lubricant composition for warm and hot plastic working
JP4456817B2 (en) * 2003-02-03 2010-04-28 本田技研工業株式会社 Water-soluble metal processing lubricant
JP2004359813A (en) * 2003-06-04 2004-12-24 Honda Motor Co Ltd Water-soluble lubricant film-forming agent and method of molding processing
ATE552328T1 (en) * 2005-11-03 2012-04-15 Infineum Int Ltd LINEAR DIBLOCK COPOLYMERS AS ANTI-WEAR ADDITIVES FOR LUBRICANTS IN COMBUSTION ENGINE CRANKCASES
JP2007204603A (en) * 2006-02-01 2007-08-16 Yushiro Chem Ind Co Ltd Water-soluble oil composition for metal processing

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102191121A (en) * 2011-03-22 2011-09-21 无锡市高润杰化学有限公司 Multifunctional cutting fluid
CN102191121B (en) * 2011-03-22 2013-02-06 无锡市高润杰化学有限公司 Multifunctional cutting fluid
CN103827278A (en) * 2011-05-06 2014-05-28 凯密特尔有限责任公司 Amine-free voc-free metal working fluid
CN109401810B (en) * 2011-05-06 2022-03-18 凯密特尔有限责任公司 Amine-free and VOC-free metal working fluid
CN109401810A (en) * 2011-05-06 2019-03-01 凯密特尔有限责任公司 Metal working fluid without amine VOC free
CN102585987A (en) * 2011-12-28 2012-07-18 烟台大学 Water suspension cutting agent for crystal cutting
CN102585987B (en) * 2011-12-28 2013-12-25 烟台大学 Water suspension cutting agent for crystal cutting
CN103627491A (en) * 2013-11-27 2014-03-12 常熟市劲力工具有限公司 Grinding fluid for processing cutter disk
CN105001949B (en) * 2015-06-05 2018-04-24 上海贝能环保科技有限公司 A kind of biodegradation environmental protection near dry cutting liquid and preparation method thereof
CN105001949A (en) * 2015-06-05 2015-10-28 上海贝能环保科技有限公司 Biodegradation environmentally-friendly quasi-dry cutting fluid and preparation method thereof
CN106279568B (en) * 2016-08-31 2019-01-08 广州米奇化工有限公司 Long-chain alcohol ether polycarboxylic acids and its preparation method and application
CN106279568A (en) * 2016-08-31 2017-01-04 广州米奇化工有限公司 Long-chain alcohol ether polycarboxylic acids and its preparation method and application
TWI716030B (en) * 2018-08-31 2021-01-11 日商日化精工股份有限公司 Preparation and processing liquid for cutting processing
CN110305728A (en) * 2019-08-07 2019-10-08 上海工程技术大学 A kind of macromolecule Plastic Forming is with lubricator and preparation method
CN110305728B (en) * 2019-08-07 2021-12-17 上海工程技术大学 Lubricant for polymer plastic forming and preparation method thereof
CN111286395A (en) * 2020-03-23 2020-06-16 上海问浪科技有限公司 Cutting fluid for metal processing
CN111286395B (en) * 2020-03-23 2022-04-22 东莞市英思漫润滑科技有限公司 Cutting fluid for metal processing
CN115247096A (en) * 2021-10-25 2022-10-28 哈尔滨市力安特科技发展有限责任公司 High-safety harmless cutting fluid and preparation method thereof

Also Published As

Publication number Publication date
US20090149359A1 (en) 2009-06-11
WO2009076151A1 (en) 2009-06-18
CA2708595A1 (en) 2009-06-18
EP2075319A1 (en) 2009-07-01
CA2708595C (en) 2017-08-15
KR20100135218A (en) 2010-12-24
BRPI0822063A2 (en) 2015-06-23
JP5704921B2 (en) 2015-04-22
JP2011506683A (en) 2011-03-03
KR20160120787A (en) 2016-10-18
MX2010006315A (en) 2010-10-05
MX360113B (en) 2018-10-23
CN106635320A (en) 2017-05-10

Similar Documents

Publication Publication Date Title
CN101970621A (en) Formulation of a metalworking fluid
ES2935302T3 (en) metalworking fluid
RU2133666C1 (en) New water soluble liquids for metal treatment
US3980571A (en) Synthetic lubricant for machining and chipless deformation of metals
CN108431191A (en) metal working fluid
KR900005104B1 (en) Water-soluble additives having extreme pressure effect for aqueous functional fluids and concentrated aqueous compositions containing the said addtives
JP6009378B2 (en) Water-soluble metalworking fluid and metalworking coolant
JP4808855B2 (en) Lubricant composition
JP4531882B2 (en) Water-soluble metalworking fluid
WO2014000166A1 (en) Emulsifier for lubricatiing oil concentrate
JP2004256771A (en) Water-soluble cutting and grinding oil agent composition and method for using the same
CN110684585B (en) Micro-emulsion type cutting fluid and preparation method thereof
Canter The chemistry of metalworking fluids
JP3148395B2 (en) Lubricant composition
JP4235020B2 (en) Lubricant composition
Brown et al. Metalworking fluids
GB2619938A (en) Metalworking fluid concentrate
JPH07316575A (en) Lubricating oil composition for metal plastic-processing
Rehbein Influence of EP-Additives on the Efficiency and ecological Aspects of Metalworking Fluids
JPH06234987A (en) Cooling lubricant containing partially neutralized phosphoric ester as ep additive
RO125312B1 (en) Processing fluid with advanced tribological properties
Kandile et al. 1 Stability of Cutting Fluids Emulsions

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20110209