CN101962225A - External anaerobic ammonia oxidation membrane bioreactor - Google Patents

External anaerobic ammonia oxidation membrane bioreactor Download PDF

Info

Publication number
CN101962225A
CN101962225A CN2010105234163A CN201010523416A CN101962225A CN 101962225 A CN101962225 A CN 101962225A CN 2010105234163 A CN2010105234163 A CN 2010105234163A CN 201010523416 A CN201010523416 A CN 201010523416A CN 101962225 A CN101962225 A CN 101962225A
Authority
CN
China
Prior art keywords
communicated
pump
anaerobic
water
membrane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN2010105234163A
Other languages
Chinese (zh)
Other versions
CN101962225B (en
Inventor
高大文
陶彧
侯国凤
任南琪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Harbin Institute of Technology
Original Assignee
Harbin Institute of Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Harbin Institute of Technology filed Critical Harbin Institute of Technology
Priority to CN2010105234163A priority Critical patent/CN101962225B/en
Publication of CN101962225A publication Critical patent/CN101962225A/en
Application granted granted Critical
Publication of CN101962225B publication Critical patent/CN101962225B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • Y02W10/12

Landscapes

  • Separation Using Semi-Permeable Membranes (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)

Abstract

The invention discloses an external anaerobic ammonia oxidation membrane bioreactor and relates to an external membrane bioreactor, which aim to solve the problems of serious sludge run-off of the current anaerobic ammonia oxidation reactors and adverse living environment of anaerobic ammonia oxidation bacteria due to frequent extraction of membrane components in built-in anaerobic ammonia oxidation membrane bioreactors. In the external anaerobic ammonia oxidation membrane bioreactor, a plurality of membrane filaments are arranged in an organic glass pipe along the direction of a central axis; a water inlet tank is communicated with the inlet end of a water inlet pump; the water inlet pump is electrically connected with an electronic ball float valve; the electronic ball float valve is arranged in an anaerobic tank; the water inlet pump is communicated with the anaerobic tank; a stirring paddle and a connecting pipe of a moisture flowmeter are arranged in the anaerobic tank; the anaerobic tank is communicated with an organic glass cylinder; each membrane filament is communicated with a water outlet pump; the organic glass cylinder is communicated with a reflux pump; the reflux pump is communicated with the anaerobic tank; the water outlet pump is communicated with a water outlet cylinder; a pressure sensor is connected with a data acquisition module; the data acquisition module is connected with a computer; a liquid level meter is arranged in the water outlet cylinder; and the liquid level meter is connected with the data acquisition module. The external anaerobic ammonia oxidation membrane bioreactor is used for sewage treatment.

Description

External placed type Anammox membrane bioreactor
Technical field
The present invention relates to a kind of external membrane bioreactor.
Background technology
Bio-denitrification technology is widely used in the production practice having obtained develop rapidly over nearly 20 years.But using maximum still is traditional nitration denitrification technology.But there are problems in traditional nitration denitrification technology: flow process is longer, and floor space is big, the initial cost height; For obtaining higher sludge concentration and nitric efficiency, need carry out mud backflow and nitrification liquid and reflux, power consumption is big; Add in the alkali He in the nitrifying process and produce acidity, denitrification process additional carbon, running cost height; A little less than the mud capacity of resisting impact load; May cause secondary pollution etc.
Therefore, seek less energy-consumption, high efficiency novel denitride technology is imperative.In novel biological denitrification process, the anaerobic ammonia oxidation process advantage significantly receives much concern.Compare with complete nitrification-denitrification process, it can save 62.5% aeration rate and 50% alkali consumption in theory, and need not to add organic carbon source; In addition, because the cell yield of anaerobic ammonia oxidizing bacteria is well below denitrifying bacteria, the sludge yield of anaerobic ammonia oxidation process has only 15% of traditional denitrification process, alleviates the processing and the disposal of excess sludge in a large number.
The Anammox phenomenon in nineteen ninety-five since Holland is found and names, a lot of scholars utilize the laboratory scale reactor by the different kind mud success enrichment of inoculation anaerobic ammonia oxidizing bacteria, and its characteristic carried out many-sided research.But some countries and the Japanese sewage disposal practical engineering project that has based on anaerobic ammonia oxidation process of having only Europe.And anaerobic ammonia oxidizing bacteria characteristics long, that cell yield is low generation time have seriously limited anaerobic ammonia oxidation process widespread use in actual engineering.
Therefore, keep the sludge concentration of anaerobism ammonia oxygen bacterium in reactor most important to improving the Anammox nitric efficiency.The principal mode of the reactor of laboratory study at present and practical engineering application is sequence intermittent activated sludge process and upflow anaerobic sludge blanket process, but sludge loss is a big problem.For existing built-in membrane bioreactor,, very unfavorable to the living environment of the anaerobism ammonia oxygen bacterium in the reactor because of membrane module needs often to change to cause oxygen to enter in the system.
Summary of the invention
The purpose of this invention is to provide a kind of external placed type Anammox membrane bioreactor, often take out the living environment very disadvantageous problem of membrane module anaerobism ammonia oxygen bacterium to solve the serious and built-in Anammox membrane bioreactor of present anaerobic ammonia oxidation reactor sludge loss.
The present invention solves the problems of the technologies described above the technical scheme of taking to be: described bio-reactor comprises inlet chest, intake pump, the electronic float valve, anaerobic jar, stirring rake, wet test meter, go out water pump, reflux pump, water output cylinder, pressure transmitter, data acquisition module, membrane module and liquid level instrument, membrane module is by cylindrical synthetic glass tube, barometric pipe and a plurality of film silk constitute, the top of synthetic glass tube is provided with barometric pipe, a plurality of film silks are located in the synthetic glass tube along central axial direction, inlet chest is communicated with the entrance end of intake pump, intake pump is electrically connected with the electronic float valve, the electronic float valve is located in the anaerobic jar, the exit end of intake pump is communicated with first entrance end of anaerobic jar, the pipe connecting of stirring rake and flux of moisture meter is located in the anaerobic jar, the exit end of anaerobic jar is communicated with the entrance end of synthetic glass tube, the water side of each film silk is communicated with the entrance end that goes out water pump, second exit end of synthetic glass tube is communicated with the entrance end of reflux pump, the exit end of reflux pump is communicated with second entrance end of anaerobic jar, water outlet pump outlet end is communicated with water output cylinder, pressure transmitter is located at membrane module and goes out between the water pump, the signal output part of pressure transmitter is connected with first signal input part of data acquisition module, be provided with the liquid level instrument in the water output cylinder, the signal output part of liquid level instrument is connected with the second signal input terminus of data acquisition module.
The present invention has following beneficial effect: 1. the present invention has the effect of efficiently holding back mud, makes the concentration of anaerobic ammonia oxidizing bacteria in the reactor reach maximum, avoids sludge loss, influences effluent quality; Sludge yield minimum (remove unartificial bat mud, do not produce otherwise do not have mud basically), high sludge concentration achieves denitrogenation efficiently.2. the present invention is located at the outside of anaerobic jar with membrane module, does not influence the coenocorrelation in the anaerobic jar when changing membrane module, has farthest protected the concentration of anaerobic ammonia oxidizing bacteria, guarantees anaerobic environment.3. referring to Fig. 2, anaerobic ammonia oxidizing bacteria is housed in anaerobic jar, through after the reactor for treatment of the present invention, ammonia-N removal rate reaches more than 85% in the sewage, and the nitrite nitrogen removal efficiency reaches more than 90%.
Description of drawings
Fig. 1 is an one-piece construction synoptic diagram of the present invention, Fig. 2 be contain the ammonia nitrogen of different concns and nitrate nitrogen sewage after reactor for treatment of the present invention, contain the experiment effect figure of the concentration of ammonia nitrogen and nitrate nitrogen in the sewage, wherein MBR is a reactor of the present invention.
Embodiment
Embodiment one: present embodiment is described in conjunction with Fig. 1, the bio-reactor of present embodiment comprises inlet chest 1, intake pump 2, electronic float valve 3, anaerobic jar 4, stirring rake 5, wet test meter 6, go out water pump 7, reflux pump 8, water output cylinder 9, pressure transmitter 10, data acquisition module 11, membrane module 12 and liquid level instrument 13, membrane module 12 is by cylindrical synthetic glass tube 12-1, barometric pipe 12-2 and a plurality of film silk 12-3 constitute, the top of synthetic glass tube 12-1 is provided with barometric pipe 12-2, a plurality of film silk 12-3 are located in the synthetic glass tube 12-1 along central axial direction, inlet chest 1 is communicated with the entrance end of intake pump 2, intake pump 2 is electrically connected with electronic float valve 3, electronic float valve 3 is located in the anaerobic jar 4, intake pump 2 exit end are communicated with first entrance end of anaerobic jar 4, the pipe connecting of stirring rake 5 and flux of moisture meter 6 is located in the anaerobic jar 4, the exit end of anaerobic jar 4 is communicated with the entrance end of synthetic glass tube 12-1, the water side of each film silk 12-3 is communicated with the entrance end that goes out water pump 7, second exit end of synthetic glass tube 12-1 is communicated with the entrance end of reflux pump 8, the exit end of reflux pump 8 is communicated with second entrance end of anaerobic jar 4, the exit end that goes out water pump 7 is communicated with water output cylinder 9, pressure transmitter 10 is located at membrane module 12 and goes out between the water pump 7, the signal output part of pressure transmitter 10 is connected with first signal input part of data acquisition module 11, be provided with liquid level instrument 13 in the water output cylinder 9, the signal output part of liquid level instrument 13 is connected with the second signal input terminus of data acquisition module 11.
Electronic float valve 3 is located at the 5-7cm place, top cover below of anaerobic jar 4, is used to regulate and control water inlet switch, and the liquid level in anaerobic jar 4 surpasses electronic float valve 3, and intake pump 2 quits work; Wherein the signal output part of data acquisition module 11 is connected with computer 14, and membrane module 12 is detachable, and lays in a plurality of film silks.When the degradation of existing film silk and can't be by the back flushing pollution abatement time, the then timely film silk that more renews, and old film silk carried out matting with recycle; The rotating speed of stirring arm 5 is set to 120rpm to keep jar suspended state of interior mud, and the reflux pump flow velocity is 170mL/min, and mud mean residence time in membrane module is about 1.1min; The PVC hollow fiber microfiltration membrane that the film silk adopts MIT to produce, film silk surface apertures is 4 μ m, theoretical maximum membrane flux is 0.27m 3M -2D -1
Embodiment two: in conjunction with Fig. 1 present embodiment is described, the low side of the pressure transmitter 10 of present embodiment is higher than the water side of each film silk 12-3, and the difference between the two is 2-3cm.Other compositions and annexation are identical with embodiment one.
Embodiment three: present embodiment is described in conjunction with Fig. 1, the bio-reactor of present embodiment also comprises water bath containers 15 and temperature control rod 16, anaerobic jar 4 is located in the water bath containers 15, is provided with temperature control rod 16 in the water bath containers 15, and this structure guarantees that temperature maintenance is at 35 ℃ in the anaerobic jar 4.Other compositions and annexation are identical with embodiment one.
Principle of work: the sewage in the inlet chest 1 is continuously pumped in the anaerobic jar 4 by intake pump 2, and electronic float valve 3 rises when water level reaches definite value in the anaerobic jar, and closes intake pump 2, to avoid the too high sludge loss that causes of liquid level; Be provided with anaerobic ammonia oxidizing bacteria in the anaerobic jar 4, stirring rake 5 is with sewage and the abundant mixing of anaerobic ammonia oxidizing bacteria in the anaerobic jar 4, form mud mixture, in mud mixture flows into the synthetic glass tube 12-1 in anaerobic jar 4 by gravity, mud mixture is through the millipore filtration on film silk 12-3 surface, clear water enters a plurality of film silk 12-3 inside, and enters into water output cylinder 9 through going out water pump 7; Remaining mud mixture is back in the anaerobic jar 4 through reflux pump 8 among the synthetic glass tube 12-1;
Pressure transmitter 10 is used for monitoring transmembrane pressure TMP; After the water outlet that goes out water pump 7 is collected in the water output cylinder 9, per 10 seconds given data acquisition module 11 with the liquid level signal transmission primaries of water output cylinder 9 by the liquid level instrument, data acquisition module 11 is aggregated on the computer, computer is according to the internal diameter and the liquid level lift velocity of water output cylinder 9, adjust out real fluxes, transmembrane pressure write down once in per 5 minutes, and per 30 minutes records of the real fluxes of film once.

Claims (3)

1. external placed type Anammox membrane bioreactor, it is characterized in that described bio-reactor comprises inlet chest (1), intake pump (2), electronic float valve (3), anaerobic jar (4), stirring rake (5), wet test meter (6), go out water pump (7), reflux pump (8), water output cylinder (9), pressure transmitter (10), data acquisition module (11), membrane module (12) and liquid level instrument (13), membrane module (12) is by cylindrical synthetic glass tube (12-1), barometric pipe (12-2) and a plurality of film silk (12-3) constitute, the top of synthetic glass tube (12-1) is provided with barometric pipe (12-2), a plurality of film silks (12-3) are located in the synthetic glass tube (12-1) along central axial direction, inlet chest (1) is communicated with the entrance end of intake pump (2), intake pump (2) is electrically connected with electronic float valve (3), electronic float valve (3) is located in the anaerobic jar (4), the exit end of intake pump (2) is communicated with first entrance end of anaerobic jar (4), the pipe connecting of stirring rake (5) and flux of moisture meter (6) is located in the anaerobic jar (4), the exit end of anaerobic jar (4) is communicated with the entrance end of synthetic glass tube (12-1), the water side of each film silk (12-3) is communicated with the entrance end that goes out water pump (7), second exit end of synthetic glass tube (12-1) is communicated with the entrance end of reflux pump (8), the exit end of reflux pump (8) is communicated with second entrance end of anaerobic jar (4), the exit end that goes out water pump (7) is communicated with water output cylinder (9), pressure transmitter (10) is located at membrane module (12) and goes out between the water pump (7), the signal output part of pressure transmitter (10) is connected with first signal input part of data acquisition module (11), be provided with liquid level instrument (13) in the water output cylinder (9), the signal output part of liquid level instrument (13) is connected with the second signal input terminus of data acquisition module (11).
2. according to the described external placed type Anammox of claim 1 membrane bioreactor, it is characterized in that the low side of pressure transmitter (10) is higher than the water side of each film silk (12-3), the difference between the two is 2-3cm.
3. according to claim 1 or 2 described external placed type Anammox membrane bioreactors, it is characterized in that described bio-reactor also comprises water bath containers (15) and temperature control rod (16), anaerobic jar (4) is located in the water bath containers (15), is provided with temperature control rod (16) in the water bath containers (15).
CN2010105234163A 2010-10-28 2010-10-28 External anaerobic ammonia oxidation membrane bioreactor Expired - Fee Related CN101962225B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2010105234163A CN101962225B (en) 2010-10-28 2010-10-28 External anaerobic ammonia oxidation membrane bioreactor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2010105234163A CN101962225B (en) 2010-10-28 2010-10-28 External anaerobic ammonia oxidation membrane bioreactor

Publications (2)

Publication Number Publication Date
CN101962225A true CN101962225A (en) 2011-02-02
CN101962225B CN101962225B (en) 2012-07-25

Family

ID=43515317

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2010105234163A Expired - Fee Related CN101962225B (en) 2010-10-28 2010-10-28 External anaerobic ammonia oxidation membrane bioreactor

Country Status (1)

Country Link
CN (1) CN101962225B (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102153251A (en) * 2011-05-11 2011-08-17 上海膜达克环保工程有限公司 External anaerobic membrane bioreactor and waste water purification technology thereof
WO2013185350A1 (en) * 2012-06-15 2013-12-19 乐金电子研发中心(上海)有限公司 Internal-circulation aeration anammox-membrane bioreactor
CN104710005A (en) * 2015-03-25 2015-06-17 苏州苏科环保科技有限公司 External anaerobic membrane bioreactor
CN104961231A (en) * 2015-06-25 2015-10-07 南昌大学 Anaerobic ammonia oxidation reactor device
CN106365373A (en) * 2015-07-24 2017-02-01 王玮 Method and apparatus for treating municipal sludge anaerobic digestion solution
CN108191055A (en) * 2018-01-30 2018-06-22 哈尔滨工业大学 A kind of separated type anaerobism ceramic membrane bioreactor that can effectively alleviate fouling membrane

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1480408A (en) * 2003-07-18 2004-03-10 浙江大学 Up-flow type response operator for anaerobic ammoxidation biomembrane
CN2900509Y (en) * 2006-06-08 2007-05-16 浙江大学 Film anaerobic ammonia oxidizing biological reactor
CN201003013Y (en) * 2007-01-19 2008-01-09 华南理工大学 UASB-biological film anaerobic ammoxidation apparatus
CN101704576A (en) * 2009-11-13 2010-05-12 江南大学 Method for realizing synchronous denitrification in membrane bioreactor

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1480408A (en) * 2003-07-18 2004-03-10 浙江大学 Up-flow type response operator for anaerobic ammoxidation biomembrane
CN2900509Y (en) * 2006-06-08 2007-05-16 浙江大学 Film anaerobic ammonia oxidizing biological reactor
CN201003013Y (en) * 2007-01-19 2008-01-09 华南理工大学 UASB-biological film anaerobic ammoxidation apparatus
CN101704576A (en) * 2009-11-13 2010-05-12 江南大学 Method for realizing synchronous denitrification in membrane bioreactor

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102153251A (en) * 2011-05-11 2011-08-17 上海膜达克环保工程有限公司 External anaerobic membrane bioreactor and waste water purification technology thereof
WO2013185350A1 (en) * 2012-06-15 2013-12-19 乐金电子研发中心(上海)有限公司 Internal-circulation aeration anammox-membrane bioreactor
CN104350012A (en) * 2012-06-15 2015-02-11 乐金电子研发中心(上海)有限公司 Internal-circulation aeration anammox-membrane bioreactor
CN104710005A (en) * 2015-03-25 2015-06-17 苏州苏科环保科技有限公司 External anaerobic membrane bioreactor
CN104961231A (en) * 2015-06-25 2015-10-07 南昌大学 Anaerobic ammonia oxidation reactor device
CN106365373A (en) * 2015-07-24 2017-02-01 王玮 Method and apparatus for treating municipal sludge anaerobic digestion solution
CN108191055A (en) * 2018-01-30 2018-06-22 哈尔滨工业大学 A kind of separated type anaerobism ceramic membrane bioreactor that can effectively alleviate fouling membrane

Also Published As

Publication number Publication date
CN101962225B (en) 2012-07-25

Similar Documents

Publication Publication Date Title
CN101962225B (en) External anaerobic ammonia oxidation membrane bioreactor
CN101759323B (en) Treatment combined process for pig farm waste water with high nitrogen content
CN103588352B (en) Two-stage backflow simultaneous nitrogen and phosphorus removal device and technology for denitrification phosphorus removal, shortcut nitrification and anaerobic ammonia oxidation of municipal sewage
CN105540846B (en) The application method of low carbon source urban sewage improvement UCT autotrophic denitrification dephosphorization apparatus
CN103304105B (en) Deep treatment process of coked wastewater
CN103936145B (en) A kind of MBR is for starting the method for CANON technique
CN109896629B (en) Method and device for strengthening AOMBR process sludge in-situ reduction
CN112811719A (en) Autotrophic denitrification treatment system and method for urban sewage
CN103936231A (en) Energy-saving type inverted AAO-MBR (anaerobic/anoxic/oxic-membrane bioreactor) sewage treatment method
CN109336256B (en) Half-short-cut nitrification-anaerobic ammonia oxidation serial sewage treatment system and method
CN110877926A (en) Device and method for rapidly culturing autotrophic-heterotrophic organism denitrification granular sludge
CN216141333U (en) Carbon source adding optimization control system of AOA + MABR coupling process
CN110217887A (en) A kind of the substep water inlet sequencing batch reactor and method of processing waste water of livestock poultry anaerobic digestion solution
CN101880080B (en) Airlift multi-stage loop membrane bioreactor with worm bed
CN209835885U (en) Rural sewage treatment plant of little ecological integration of many units
CN206616064U (en) Membrane bioreactor
CN105384249A (en) Sewage treatment method and sewage treatment device integrating deep nitrogen and phosphorus removing and sludge-water gravitational separation
CN202148221U (en) Integrated A-O biological denitrification reactor with buffer zone
CN205258129U (en) Low discharge sewage degree of depth nitrogen and phosphorus removal device
CN111484137B (en) High-concentration wastewater treatment system and process adopting AnMBR membrane
CN110668581B (en) Suspended anaerobic ammonium oxidation bacteria continuous flow reactor and automatic control method
CN209193639U (en) A kind of half short distance nitration-anaerobic ammoxidation series connection sewage disposal system
CN114014436A (en) Sludge discharge system
CN108178300B (en) Automatic high-efficient nitrogen and phosphorus removal device of integration MBR method
CN109437398A (en) A kind of doughnut aeration film sewage treatment system

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120725

Termination date: 20131028