CN101947368B - Flame-retardant body strengthening safety clothing of nano-element fiber fabric - Google Patents
Flame-retardant body strengthening safety clothing of nano-element fiber fabric Download PDFInfo
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Abstract
The invention discloses flame-retardant body strengthening safety clothing of nano-element fiber fabric, and belongs to the field technology of production of the safety clothing of functional textile, namely flame-retardant textile. Experiments prove that the time for a person with flame-retardant clothing to escape from a fire disaster caused by a sudden accident is increased by 10 to 15 times compared with the normal person, the heat energy released by burning is only 25 percent of that of the unburned textile so as to reduce half the loss of the fire disaster, the toxic gas released by the burning is only one third of the unburned textile so as not to produce severe dense smoke, so that the life of the person can be effectively protected. Once burn and scald occur, the working clothing can effectively show an antibacterial effect, diminish inflammation, sterilize, clear away heat and toxic material, promote blood circulation and remove blood stasis, diminish swelling and promote tissue regeneration, release various macro trace elements, enhance the immunity of human body and resist against diseases.
Description
Technical field:
Flame-retardant body strengthening safety clothing of nano-element fiber fabric of the present invention, belong to functional textile flame-retardant textile dress ornament safety clothes production technical field.
Background technology:
Along with the continuous progress of industrial technology development, improving constantly of people's living standard, be more and more higher to the demand of Fire Retardant Industry and human health safety both at home and abroad, and developed country quite payes attention to the industry of fire retardant, and new fire retardant emerges in an endless stream.The scientist of China is actively developing the various new fire retardant at present, and total development roughly has following several trend.
(1) develop efficiently, nontoxic, material property is affected to little fire retardant, thus the exploitation that causes the exploitation of reactive flame retardant and there is the interpolation fire retardant of excellent compatibility;
(2) exploitation has synergistic fire retardant, as phosphorus, nitrogen, the combination of bromine between molecule or molecule;
(3) the fire-retardant agent that exploitation has the different application scope;
(4) develop various blend fabric durable flame retardants;
(5) with the flame-retardant clothing of health.
The flame resistant method of fiber and textile roughly has the flame-retardant modified and flame-proof treatment of two kinds of fibers, only have and adopt the rear flame resistant method arranged for natural fibers such as cotton, fiber crops, hairs, by absorption deposit, chemical bonding, nonpolar Van der Waals force in conjunction with and the effect such as bonding, make fire retardant anchor at fabric or spin above, thereby obtaining flame retardant effect.For terylene, acrylic fibers, the synthetic fibers such as polyvinyl can add fire retardant in spinning process, by the improved method of blend, make fiber there is anti-flammability, perhaps by flame-retardant after-finishing, obtain the method for flame-retardant after-finishing, with the fire retardant uniform dispersion, synthetic fabrics is carried out to coating, fire retardant is attached on fiber, perhaps with blending method, produce fire resistance fibre, being about to fire retardant adds in the spinning melt spinning solution, the spinning fire resistance fibre, the method requires fire retardant can stand the high temperature of melt spinning, and the compatibility of requirement and polymer is good, do not affect normally carrying out of spinning and post processing, do not make the main performance of fiber and its products that larger variation occurs, nontoxic, the BACN of good endurance.
China has obtained larger progress in the application study of spinning product flame-retarded technology in recent years, China Textile Academy has successively succeeded in developing polypropylene fibre fire-retardant master granule etc., the Shanghai Textile academy of sciences has successively developed phenolic fibre, polyimide fiber, virtue sulfone synthetic fibre, FRC, heat resistance fiber, Shanghai giant dragon textile science research institute has successively completed fire prevention, waterproof, the cotton drop cloth finishing technique of mildew-resistant, polyester blended fabric flame-proof treatment and fire retardant SCJ-969 are synthetic, fire prevention, waterproof fire-entry suit fabric, the cotton waterproof anti-static inflaming-retarding of synthetic fibre canvas, wool textile product flame-retardant finishing, the anti-strong acid that Beijing Jie Ershuan High Seience Technology Co., Ltd. succeeds in developing, anti-highly basic, anti-oxidant, anti-going mouldy, Anti-moth-eating, antistatic, anti-Exposure to Sunlight, laundry-resistant permanent flame-retardant textile appears on the market, this is that China becomes in the world and can produce one of a few countries of permanent flame retardant products.The polyester waste material bottle that can reclaim that also has China to succeed in developing is primary raw material, add that the fire-retardant master granule blend is spun in silk liquid and the fire-retardant short fiber of producing, as the raw material of the non-weaving cloths such as carpet, wall paper, because of price low, the raw material abundance, have wide market prospects and good social benefit.
Summary of the invention:
At present China produces and uses maximum FLAME RETARDANT FINISH FABRICs to comprise cotton textiles, pure terylene, pure wool, wash/the durable flame-retardant fabric of cotton and various blending.Improving constantly and improving along with people's lives and environmental condition, people are more and more higher to the flame retardant textiles performance requirement, we not only rest on fire resistance fibre and flame-retardant textile only has flame retardant effect and function, not only luminous energy flame-retardant water-repellent, the fire-retardant oil of refusing, flame-retardant and anti-static, antiultraviolet, antibacterial deodourizing, high temperature resistant, low cigarette, low toxicity, corrosion-free, without drippage, persistent high efficiency, the flame retardant effect safety coefficient is large outer also to consider this flame-retarding clothes how with the organic combination of the health of human body, especially organic with the sub-health state of human body is combination, " sub-health state " refers to the new ideas that international medical community proposes in recent years, that is to say the rim condition of human body in Health and Disease, without organic disease, but Functional change is arranged, this and work fatigue are in close relations, also can be called burnout syndrome, that is to say that the various inspections of hospital are all normal, can not check any disease, oneself feel to feel bad add not there emerged a the institute since, the World Health Organization (WHO) shows a global survey: the mankind's health is divided into three kinds of states, the first state of whole world true health only accounts for 5%, diagnosis has the second state of disease to account for 20%, and 75% crowd is in " the third sub-health state ", inferior health has been classified together with AIDS as to the maximum enemy of 21 century human health at United States Medicine circle, therefore change mankind's sub-health state, reducing sub-health population is also suddenly to wait to change at present urgent task certainly.We know, the various diseases of human body is all relevant with the in-vivo element dysequilibrium, especially the essential trace element of human body is the synthetic catabolism of the activity that maintains human normal metabolism, various enzymes, fat, protein, carbohydrate, the eliminating of body endoperoxide and toxin, the adjusting institute of immunologic function is indispensable, and cardiovascular and cerebrovascular disease, cancer, diabetes etc. are all relevant with Trace Element Imbalance.And these diseases in early days all can with have some trace elements uneven, malnutritive and the uncomfortable performance of various inferior healths that occur, the macro micro element of needed by human mainly comes from food and water, as the diet insufficiency of intake or dietary structure unreasonable, lack appropriate exercise, tobacco and wine are uncontrolled, the pollution that adds environment all may make the human elementary dysequilibrium, early stage element imbalance, malnutritive and the uncomfortable symptom grouping of inferior health occurred, at this time immunologic function descends, resistance reduces, normal flu, minor illness is continuous, permanent development goes down just likely to suffer from cardiovascular and cerebrovascular, cancer, the diseases such as diabetes.
The present invention is by choosing the medical stone of high-quality, by the specially treated of the process of the trace element in medical stone high-tech technique, make each trace element all there is central role of positive charge, then refine in the manufacture process of fiber, these trace elements can firmly adsorb and in conjunction with the trace element with cellulose macromolecule on hydroxyl generation bonding reaction on cellulose macromolecule, make the fabric that first cellulose fiber with certain fastness and persistence function is made into, be through with it the thermal friction that adds after skin body temperature, make these through nanometers first cellulose fiber in various trace elements pass through skin pore, sweat gland, the capillary osmotic absorption enters the circulation of body inner blood, thereby constantly supplement, regulate, antagonist interior element balance.By the contrast experiment who element fabric is worn to human body front and back Trace Elements In Serum, can draw the following conclusions: one, in element fabric, contain the necessary various trace elements of human body.Each trace element all has the effect of center of positive charge, there is the required micro-effect of supplementing, also there is good adsorption capacity simultaneously, can adsorb metabolism various harmful peroxide and human body multiple harmful substances on every side out on skin, thereby can produce health-care effect to human body; Two, human body is worn after element fabric two weeks and is measured trace element in human serum and be significantly increased, this just illustrates by storing in fiber in the nano fabrics of nanotechnology treatments, can carry out the added body interior element by wearing these clothes, this just illustrates that supplementing not only of macro micro element in human body can absorb by eating and drinking, wear at ordinary times from people that special element fabric work clothes also can be regulated, supplements, antagonism human elementary balance, strengthen the health of human body, reduce or eliminate inferior health physique.The element fabric safety clothes that another is more important question is that made by medical stone, medical stone itself has magical water purification effect, containing in the solution of 1ppm cadmium the medical stone that adds 10% through experimental study, after 3h, mensuration is adsorbable removes 43.2%, after after 24h, 61.4%, 48h is removed in absorption, absorption removes 84%.The water polluted because of phthalic acid fat carries out adsorption treatment with medical stone, and absorption affinity is 50% left and right.The Chinese medicinal pill be modulated into medical stone can be deposited very long a period of time and by the breeding because of mould, do not affected the quality of Chinese medicine.According to reported in literature, that medical stone has is for cancer, all swollen sores, running sore, skin disease, analgesic effect, medical stone can make desalt, mineralising, activation through the immersion of water, this glassware for drinking water of long-term drinking has the effect of antifatigue, anti-anoxic, and the free oxygen in water and impurity organic matter and miscellaneous bacteria virus etc. can effectively be adsorbed, be decomposed, the activity of various bacteriums, virus and pathogenic microorganisms is suppressed, play the effect of the movable and propagation of bacteriums such as stopping bacterium, viral micro-organisms.In the absorption to coliform and inhibition test: be to use in bacterium liquid and put into 2g medical stone absorption 5min at 10ml, swashed and reduced to 8000 bacterium colonies by 76000 bacterium colonies in primary 1ml bacterium liquid, swashed and reduced to 13000 bacterium colonies by 61000 bacterium colonies for the second time, medical stone has Cd cadmium harmful in magical adsorbed water thus, Hg mercury, Pb lead, the odorous gas such as the heavy metal ion such as As arsenic and hydrogen sulfide, can also adsorb the microorganisms such as Escherichia coli simultaneously, virus and other organic matters, discharge noxious material in animal body, has the enhanced machine body immunity function, improves the body anti-infection ability, and diuresis is arranged, strengthening the spleen and stomach, protect the liver dirty, antifatigue, regulate metabolism, strengthen blood circulation, to hypertension, hyperglycaemia, high blood viscosity, high fat of blood, enterogastric diseases, the nervous system disease, lithiasis, cardiovascular and cerebrovascular disease, skin disease, the various systemic diseases of the human bodies such as illness in eye all have much relations, trace it to its cause and be: contain in these two kinds of human bodies of Ge germanium and Se selenium in the composition of medical stone and two kinds of very important elements that all lack on the earth, Ge germanium is a kind of have multiple bioactive trace element, Ga gallium, the Sr strontium, Zn zinc, Cu copper, the Mo molybdenum, Cr chromium, Ni nickel, the Nb niobium, the Ta tantalum, the Co cobalt, Sn tin, the Fu europium, the Zr zirconium, 19 kinds of elements such as W tungsten, main chemical analysis silica SiO
2, iron oxide, ferrous oxide, calcium oxide, magnesia, titanium oxide, manganese oxide etc., and dissolving out capability is good, just element and the mineral matters such as energy stripping Ca calcium, Mg magnesium, K potassium, Na sodium, Sr strontium, Se selenium, Zn zinc, I iodine, metasilicic acid are soaked in water, this multiple element be rich in can enter skin blood circulation whole body after element fabric safety clothes and human body skin close contact, and by 65% water, formed in people's body tissue, in human body, blood is comprised of 80% water, and people's eyeball is comprised of 99% moisture content.These water are able to purifying, mineralising, activation, dispel bacterium, impurity, pollutant etc., histocyte in human body is cleaned, in human body numerous macro micro elements obtain effectively supplement, the various diseases of adjusting, antagonism human body will be controlled effectively and disappear, thereby the mankind's the general level of the health is further enhanced, and sub-health state is controlled effectively.
Medical stone contains even rare Ge germanium, Se selenium element on the earth of human body, and the health of human body is had to very important effect, and they have the people such as antitumor, anti-inflammatory, anti-ageing, antiviral, Green Tea Extract, Japanese water island, Taro Aso.Show that by experiment Ge-132 is not only immunopotentiator, but also be a kind of immunomodulator, Ge-132 is anticancer, anti-hypertension, anti-aging effects is to bring out interferon and strengthen self killer cell (NK) cytoactive by human body, macrophage activation realizes, Ge germanium can bring out interferon, the cell of defendance self is responsible in activation, thereby adjusting immune system, so various cancers have significant effect, experimental results show that organic germanium has the effect of very strong removing free radical, very remarkable to the Senile intelligence disturbance effect, ability of learning and memory obstacle due to lead is had to obvious antagonism.The generation of free radical is constantly arranged in the organism metabolism process, as ultra-oxygen anion free radical and hydroxyl radical free radical, organic germanium can effectively improve the activity of superoxide dismutase (SOD) in body, thereby the active oxygen that brings out peroxide reactions becomes ground state oxygen and hydrogen peroxide.Hydrogen peroxide further decomposes, and toxicity is removed, and has stoped the murder by poisoning of active oxygen to cell, has delayed the aging of cell.Zoopery confirms, germanium, selenium, zinc have collaborative effect, and germanium and selenium can be antitumor, prevent and treat hepatopathy, artery sclerosis and anti-ageing.
In order effectively to supplement, adjusting, antagonist interior element balance, obtain selenium, the germanium of needed by human, these two kinds of important biological elements of rareness in the earth and animals and plants, we can use rich selenium, germanium, glossy ganoderma edible mushroom microbial conversion culture technique to obtain our needed Organic Selenium, organic germanium, through the supersonic freeze drying technology extract its Organic Selenium, organic germanium mycelium dried powder is added on the fire-retardant work clothes of fabric that obtains high-load, many macro micro elements in our required flame-retardant textile spinning solution.
By silver-carrying nano TiO
2(AT) the medical stone nano powder of photocatalysis antibacterial agent and Organic Selenium, organic germanium, dry mycelium powder or the commercial nanometer selenium of cultivating through microbial conversion, germanium and process nanotechnology treatments, Chinese medicine nanometer mixed powder, fire retardant mixes rear mistake 800 mesh sieves according to a certain ratio, medium particle diameter 0.5-10 μ m, then these are mixed to nano powders and add in spinning melt or spinning solution and make fire resistance fibre, then be sewn into the strong body safety clothes of nano-element fabrics flame resistance that our vast safety in production department needs.For high-temperature operation and burst major break down, this kind of fire that safety clothes cause burst accident through a large amount of practical studies proofs, the personnel that wear the flame-retardant textile clothes allow the escape time to increase 10-15 doubly than general personnel, the heat that burning discharges only has 25% of unburned fabric, the loss that can make fire cause reduces half, what burning discharged only has not 1/3 (using the CO value representation) of flame-retardant textile with toxic gas, do not produce violent dense smoke, can effectively protect people's life, someone has done the comparative test of two ornamental chairs: one the flame-proof treatment of the chair cover of chair process, and another does not do flame-proof treatment, under the condition be equal to fully, with burning things which may cause a fire disaster, contact, test finds that the chair cover through flame-proof treatment allows the escape time of 22min, and only has escape time of 2min without the chair cover of flame-proof treatment, once occurring, this kind of work clothes of burn and scald can discharge effective anti-inflammation, sterilization, clearing heat and detoxicating, promoting blood circulation and removing blood stasis, the pharmaceutical compositions of detumescence and promoting granulation, and release and the multiple macro micro element of stripping, strengthen immunity and the human body resistance of human body, thereby avoid various bacteriums, the injury of the various diseases such as microorganism to human body.
Below in conjunction with examples of implementation, the present invention is further described:
Embodiment mono-: Chinese medicinal formulae
(1) monkshood, flos caryophylli, Chinese cassia tree, ginseng, the root of Chinese wild ginger, each 100g of Chinese honey locust, respectively account for 15.9%; Borneol 30g, account for 4.8%.
Cure mainly: the sub-health population apocamnosis
(2) Asian puccoon, each 100g of rheum officinale, respectively account for 30.3%; Purslane 40g, account for 12.1%; Climbing groundsel 60g, account for 18.2%; Alumen 20g, account for 6%; Borneol 10g, account for 3%.
Cure mainly: burn and scald
(3) dandelion 500g, account for 37%; Giant knotweed 250g, account for 18.5%; Bletilla striata 200g, account for 14.8%; Rheum officinale 100g, account for 7.4%; The root of large-flowered skullcap, each 150g of golden cypress, respectively account for 11.1%.
Cure mainly: burn and scald is had to clearing heat and detoxicating, promoting blood circulation and removing blood stasis, astringing to arrest bleeding, dispel rotten apocenosis, detumescence and promoting granulation, rapidly the effect of wound repairing
(4) coptis 200g, account for 27%; Golden cypress, the root of Dahurain angelica, Asian puccoon, caulis lonicerae, each 100g of pappy shell, respectively account for 13.5%; Borneol 40g, account for 5.4%.
Cure mainly: the effect of clearing heat-fire removing toxic substances, cooling and activating blood pain relieving, moisturizing regenerating tissue to heal wond
(5) root of large-flowered skullcap, golden cypress, the coptis, rheum officinale, gypsum rubrum, the root bark of tree peony, the radix paeoniae rubrathe, cortex albiziae, giant knotweed, each 50g of frankincense, respectively account for 5.2%; Propolis 30g, account for 3.1%; Radix Angelicae Sinensis 75g, account for 7.9%; The dried rhizome of rehmannia, each 150g of the red sage root, respectively account for 15.7%; Borneol 20g, account for 2%.
Cure mainly: burn and scald, cure rate 98.29%
(6) give birth to Radix Astragali 140g, account for 18.9%; Radix Angelicae Sinensis, giant knotweed, each 80g of corydalis tuber, respectively account for 10.8%; Coptis 240g, account for 32.4%; Pseudo-ginseng 60g, account for 8.1%; Borneol, the bletilla striata, each 20g of dragon's blood, respectively account for 2.7%.
Cure mainly: burn
Embodiment bis-: antimicrobial nano element Chinese medicinal mixed powder %
1. silver-carrying nano TiO
2(AT) the photocatalysis antibacterial agent 5%
2. the dry mycelium nano powder 8% of nanometer selenium or Organic Selenium
3. organic germanium drying mycelium nano powder 7%
4. medical stone nanometer fine powder 45%
5. the effective a certain prescription mixed powder 35% of Chinese medicine
Embodiment tri-: antimicrobial nano element Chinese medicinal and JLSUN
flame-retardant textile mixture %
1. antimicrobial nano element Chinese medicinal mixed powder 16%
2. JLSUN
fabric flame-retardant agent series 4%
3. cotton, fiber crops, wool, hair velvet, terylene, acrylic fibers, polyvinyl 80%
Embodiment tetra-: antimicrobial nano element Chinese medicinal mixed powder and SCJ-969 type fire retardant blending %
1. antimicrobial nano element Chinese medicinal mixed powder 15%
2. SCJ-969 type fire retardant 5%
3. wool, cotton, fiber crops, terylene and blending 80%
Embodiment five: antimicrobial nano element Chinese medicinal mixed powder and JHF-9 efficient flame-retarding agent blending %
1. antimicrobial nano element Chinese medicinal mixed powder 15%
2. the JHF-9 efficient flame-retarding agent 5%
3. cotton, cotton wash, wool, regenerated fiber and synthetic fibers 80%
Embodiment six: antimicrobial nano element Chinese medicinal and JLSUN
sCJ-968 type fire retardant blending %
1. antimicrobial nano element Chinese medicinal mixed powder 15%
2. JLSUN
sCJ-968 type fire retardant 5%
3. cotton fiber, acetate fiber, polyester fiber, viscose rayon, polyamide fibre 80%
Claims (4)
1. flame-retardant body strengthening safety clothing of nano-element fiber fabric is characterized in that: the safety clothes will be comprised of following wherein one group of effective Chinese medicinal formulae proportion by weight
(1) monkshood, flos caryophylli, Chinese cassia tree, ginseng, the root of Chinese wild ginger, each 100g of Chinese honey locust, respectively account for 15.9%; Borneol 30g, account for 4.8%;
(2) Asian puccoon, each 100g of rheum officinale, respectively account for 30.3%; Purslane 40g, account for 12.1%; Climbing groundsel 60g, account for 18.2%; Alumen 20g, account for 6%; Borneol 10g, account for 3%;
(3) dandelion 500g, account for 37%; Giant knotweed 250g, account for 18.5%; Bletilla striata 200g, account for 14.8%; Rheum officinale 100g, account for 7.4%; The root of large-flowered skullcap, each 150g of golden cypress, respectively account for 11.1%;
(4) coptis 200g, account for 27%; Golden cypress, the root of Dahurain angelica, Asian puccoon, caulis lonicerae, each 100g of pappy shell, respectively account for 13.5%; Borneol 40g, account for 5.4%;
(5) give birth to Radix Astragali 140g, account for 18.9%; Radix Angelicae Sinensis, giant knotweed, each 80g of corydalis tuber, respectively account for 10.8%; Coptis 240g, account for 32.4%; Pseudo-ginseng 60g, account for 8.1%; Borneol, the bletilla striata, each 20g of dragon's blood, respectively account for 2.7%.
2. flame-retardant body strengthening safety clothing of nano-element fiber fabric according to claim 1, it is characterized in that: also comprise antimicrobial nano element Chinese medicinal mixed powder, its proportion by weight forms
3. flame-retardant body strengthening safety clothing of nano-element fiber fabric according to claim 2, it is characterized in that: antimicrobial nano element Chinese medicinal and each group flame-retardant textile mixture proportion by weight form
(1) 1. antimicrobial nano element Chinese medicinal mixed powder, the i.e. described material 16% of claim 2;
2.
fabric flame-retardant agent series 4%;
3. cotton, fiber crops, wool, hair velvet, terylene, acrylic fibers, polyvinyl 80%;
(2) 1. antimicrobial nano element Chinese medicinal mixed powder, the i.e. described material 15% of claim 2;
2. SCJ-969 type fire retardant 5%;
3. wool, cotton, fiber crops, terylene and blending 80%;
(3) 1. antimicrobial nano element Chinese medicinal mixed powder, the i.e. described material 15% of claim 2;
2. the JHF-9 efficient flame-retarding agent 5%;
3. cotton, cotton wash, wool, regenerated fiber and synthetic fibers 80%;
(4) 1. antimicrobial nano element Chinese medicinal mixed powder, the i.e. described material 15% of claim 2;
2.
sCJ-968 type fire retardant 5%;
3. cotton fiber, acetate fiber, polyester fiber, viscose rayon, polyamide fibre 80%.
4. flame-retardant body strengthening safety clothing of nano-element fiber fabric according to claim 3, it is characterized in that: all materials are crossed 800 mesh sieves through nano processing technology, medium particle diameter 0.5-10 μ m.
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103230110B (en) * | 2013-04-19 | 2015-03-25 | 成进学 | Superactive inflame-retarding body building protection suit |
| CN103397532B (en) * | 2013-08-06 | 2016-05-11 | 陈欣荣 | Build ship personnel unit in winter cellulose fiber body-building safety clothes |
| CN105286120B (en) * | 2015-10-15 | 2017-01-25 | 佛山市维晨科技有限公司 | Nano protective material having synergistic function and preparation method of protective material |
| CN105999578A (en) * | 2016-05-23 | 2016-10-12 | 李宝 | Traffic police mask filter disc with anti-contamination repairing function |
| CN110725037A (en) * | 2019-10-31 | 2020-01-24 | 江苏金荣泰新材料科技有限公司 | Flame-retardant yarn and multifunctional composite yarn prepared from same |
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|---|---|---|---|---|
| CN2335659Y (en) * | 1998-06-29 | 1999-09-01 | 高长德 | Flame-retardant waterproof thermal insulation microporous five-fighter garment |
| CN1381285A (en) * | 2002-05-16 | 2002-11-27 | 仲维波 | Flame-retarding clothes and its making method |
| CN2799596Y (en) * | 2005-11-11 | 2006-07-26 | 北京英特莱技术公司 | Outside fabric for flame-retardant fire-fighting suit |
| US20080098503A1 (en) * | 2006-10-27 | 2008-05-01 | Illinois Tool Works Inc. | Accessory attachments for a welding garment |
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2010
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2335659Y (en) * | 1998-06-29 | 1999-09-01 | 高长德 | Flame-retardant waterproof thermal insulation microporous five-fighter garment |
| CN1381285A (en) * | 2002-05-16 | 2002-11-27 | 仲维波 | Flame-retarding clothes and its making method |
| CN2799596Y (en) * | 2005-11-11 | 2006-07-26 | 北京英特莱技术公司 | Outside fabric for flame-retardant fire-fighting suit |
| US20080098503A1 (en) * | 2006-10-27 | 2008-05-01 | Illinois Tool Works Inc. | Accessory attachments for a welding garment |
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