CN101946986A - Nanometer anion fabric seaman body-building working uniform with characteristics of ultra-oleophobic and ultra-hydrophilic properties, antifouling property and self-cleaning property - Google Patents

Nanometer anion fabric seaman body-building working uniform with characteristics of ultra-oleophobic and ultra-hydrophilic properties, antifouling property and self-cleaning property Download PDF

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CN101946986A
CN101946986A CN2010101897073A CN201010189707A CN101946986A CN 101946986 A CN101946986 A CN 101946986A CN 2010101897073 A CN2010101897073 A CN 2010101897073A CN 201010189707 A CN201010189707 A CN 201010189707A CN 101946986 A CN101946986 A CN 101946986A
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成进学
陈欣荣
成钢
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Abstract

The invention relates to a nanometer anion fabric seaman body-building working uniform with characteristics of ultra-oleophobic and ultra-hydrophilic properties, antifouling property and self-cleaning property, belonging to the technical field of the production of the textile engineering working uniform. When the working uniform is prepared, the lotus leaf effect of micro and nano structures on the lotus leaf surface is adopted to realize ultra-oleophobic and ultra-hydrophilic properties; TiO2 nanoparticles are sprayed on the surface of the fabric so that the oil and water can not contact with the fabric, or the non-porous polyurethane film prepared by thermoplastic polyurethane, the Ag-type nanometer inorganic antibacterial agent added in the spinning solution and the nanometer powder mixture of silver-loaded TiO2 (AT) antibacterial agent, medical stone, tourmaline and selenium element are used to prepare the anion fabric seaman body-building working uniform. The working uniform has multiple functions of increasing the strength and energy of the seaman, eliminating fatigue and changing the sub-healthy state.

Description

The anion fabric crewman body-building work clothes that the super water, oil and soil repellent of nanometer is self-cleaning
Technical field:
The anion fabric crewman body-building work clothes that the super water, oil and soil repellent of nanometer of the present invention is self-cleaning belongs to nano-textile engineering dress ornament work clothes production technical field.
Background technology:
In the last thirty years, Germany scientist is observed by the blade face microstructure of 20,000 various plants such as ESEM and atomic force microscope, has disclosed lotus leaf and has refused the self-cleaning principle of water.Lotus leaf surface has many micron-sized papillary bulges, and height of projection is 5-10um, is spaced apart 10-15um between projection, and the recess between projection is full of air, and projection and interval by many directly be the wax composition of 1nm.Crystal has formed special construction in growth course, because the size of wax crystalline substance is in the nanoscale scope, thereby genus nanostructured, scientist claims the lotus leaf surface structure for " micron "---the nano double weight structure be " lotus leaf effect " (lotus-effect) secret of principle mainly be its microstructure and nanostructured, and do not lie in its chemical analysis.The wax crystal of lotus leaf surface is at first refused water, and secondly its surperficial dual microtexture is coarse, and its ability of refusing water is significantly strengthened.The condition that lotus leaf is refused water is: 1. surfacing must be refused water, and water must be greater than 90 ° at its surface contact angle; 2. the surface must be coarse, and coarse degree must be nanometer level or near nanometer level, and the material on surface must be refused water.
Hence one can see that, desires to seek out the super surface of solids as a result of refusing water and must possess the water of refusing and coarse two conditions.Through the wax crystalline substance and the papillary bulge of lotus leaf surface as can be seen in the electron-microscope scanning picture of lotus leaf surface.Constituted the rough surface of refusing water, between projection, can keep air, thereby formed many little " air storage pools ".Water drops on by on the compound rough surface of forming with air of nipple projection the time.Very little with the contact area on blade face, only the adhesion for dripping thereon is easy to tumble from the blade face.Even solid dust is also very little at this surperficial adhesion.Water droplet is on the blade face time, and dust is can be by water institute wetting and be attached on the water droplet, in slight motion or in the gentle breeze, and the blade face slight inclination, water droplet just can be with dust to tumble together.For oily dirt, because blade face oleophobic not.Ought to be stain easilier by oily dirt, be difficult for being dashed by water, but surprisingly: oily dirt also is easy to washed away on the blade face, this be because oily dirt only with the blade face on brilliant contact of wax of bossing, contact area is very little, adhesion between blade face wax crystalline substance and oily dirt is less than the adhesion between water droplet and oily pollutant, even so oily dirt, still by water stick together all can with water droplet tumble and by flush away, the self-cleaning origin of the super water, oil and soil repellent of lotus leaf surface that Here it is.
To serve as the basis reach the super water, oil and soil repellent of nanometer, self-cleaning, deodorizing, antibacterial, microelement-supplementing, build up health, improve the health textile fabric with the research of lotus leaf bionics techniques is that crewman's work clothes of purpose is the present invention's a purpose.
Nanometer technology is applied to the principle that water and oil repellent finish is based on " lotus leaf effect ", the Nature gives that lotus leaf goes out mud and the conduct of not dying, but lotus leaf surface is not very smooth, the surface that can see lotus leaf at microscopically has dual microtexture, form the surface microstructure that lacteal tumor forms on the one hand by cell; Be the surface microstructure that forms by the surface wax crystal on the other hand.The diameter of lacteal tumor is 5-15um, highly is 1-20um, and lotus leaf effect mainly is its microstructure, and it is a kind of poroid institutional framework that is similar to sponge and Bird's Nest.Air is filled in the crack, has prevented that water and dirt are adsorbed in solid.The Nanosurface treatment technology can make fiber surface form (as recessed and protruding alternate) interface nano-structure of special geometric form complementation.Because the surface of nano-scale indentation can adsorption gas molecule, and it is stablized adhere to existence, so formed the stable gas membrane of one deck at macroscopical fabric face, make oil or water directly to contact, thereby make the surface of material present the function of unconventional two hydrophobic, two oleophobics with fabric face.A kind of oil, water and dirt all are difficult for penetrating into the work clothes that fiber makes to be eliminated the original spot of greasy dirt all over the body, dust and the dirt of personnel of aboard ship working for a long time, thereby keeps your clothes to clean for a long time, elegant in appearance, dignified in appearance.
Super two dredge (hydrophobic, oleophobics) by Chinese Academy of Sciences's river thunder research are directly fabric to be carried out Nanosurface to handle, with nano particle TiO 2Be sprayed at fabric face, make fiber surface form the concavo-convex alternate interface nano-structure of special geometric shape complementation.Because can adsorption gas molecule on the surface of nano-scale indentation, and make it stable adhere to and exist, so on macroscopical fabric face, formed the stable gas membrane of one deck, You Heshui can't directly be contacted with fabric face, thereby make fabric face present ultra-amphosphobic, at this moment the contact angle of water droplet or oil droplet and fabric face is tending towards maximum super-hydrophobic, the oleophobic function that realizes fabric, fabric through this " super two dredging " boundary material technical finesse, have the super thin property that water, wet goods liquid " are not stained with ", and keep original performance of fabric.With the clothes that this super two weaving face fabrics of dredging are made, its clothing surface forms the clothes just as water property of the hydrophobic grease proofing decontamination of rolling effect on lotus leaf.
The garment material of handling through the nanometer water and oil repellant has produced nanometer " binary is worked in coordination with interfacial structure " at the hydrophobic function of the surface of fabric formation just as lotus leaf at fiber surface, this " lotus leaf " has kink characteristics and self-cleaning action super-hydrophobic, oleophobic, promptly has super shielded, the critical surface tension of the fabric solid shape fiber of process nano finishing is less than the critical surface tension of aqueous greasy dirt, aqueous greasy dirt just can not wetting fiber, but also has antistatic property, stop the absorption of dust, thereby reach the purpose of anti-fouling and self-cleaning.The specific area effect that the big specific area of nano particle the produces airborne oxygen that can also dissociate generates negative aeroion, stops or kills organic matter, prevents that organic matter rubbish from generating.
Domestic comparatively successful product will belong to three anti-fleece fabrics of Erdos at present, fleece fabrics is through after the specially treated, form lotus leaf effect at fiber surface, fabric face tension force is reduced, form stable air layer on its surface,, be equivalent to the gas membrane that has one deck stable just as the hydrophobic function of lotus leaf, thereby make fabric have waterproof, grease proofing, anti-pollution function, make the globule and the animals and plants oil droplet that fall naturally under the normal temperature can not infiltrate fabric fibre inside.
The atresia polyurethane film is better than the compound fabric of many micropores PTFE film and Organic fluoride oil-repellent finiss formation, it is to remove the selectivity polymeric membrane that the water vapour molecule external enwergy stops other all liquid state, gaseous material to pass through, can overcome the pollution of human secretory and water proofing property that detergent surfactant causes again and descend, thereby improve the persistence that the Waterproof Breathable ability is used.The atresia polyurethane film is to be made by thermoplastic polyurethane (TPU) elastomeric material, belong to AB type line type copolymer, the principle of thermoplastic polyurethane film: at first be the moisture that hydrophilic segment absorption body surface distributes, borrow the motion of new water-based segment that moisture is spread (promptly being spread to low pressure by high pressure) to the outside rapidly by inside, then moisture is evaporated in ambient atmosphere by inside.Promptly utilize the special molecular structure of thermoplastic polyurethane, hydrone is passed one by one, reach the purpose of high poisture-penetrability by the hydrophily gene.Secondly because atresia, rainwater, wind and snow can not be infiltrated, and general water pressure resistance can reach more than the 10000mm (water column), can wash, low temperature resistant reaching-30 ℃, quality is soft not higher than price with PTFE.With this film be added on composite mixing in the fabric fibre after be added in the spinning solution, adopt laminating technology to make the body-building work clothes that our desirable nanometer is refused water, refused oily anti-fouling and self-cleaning again.The FC-921 fluorine carbon that clean your the refreshing High Seience Technology Co., Ltd. in also available Beijing produces is refused oily water repellent, has good water and oil repellant and water pressure resistance performance through the polyester-cotton fabric of its arrangement.Various fabrics all can make its base cloth as blending such as cotton, sticking glutinous fiber, polyamide fibre, terylene, acrylic fibers, polypropylene fibre and blend fabric.
Summary of the invention:
People can be polluted inside and outside in the clothes wearing process, underwear particularly, the sweat of human secretory, sebum, scurf, ight soil, urine, blood and milk etc. all can cause the pollution of underwear, and stink will take place time length, even skin disease or bring out the internal organs disease.The environment of the visual work of degree that work clothes pollutes; the place; job specification; occupation; age; sex is different and different with conditions such as health; because pollution such as numerous crewman that the relation of external condition job specification causes; worker on the ship; oil depot and oil field workman etc.; mainly contain oil stain; water droplet; iron rust; dust; sandy soil; paint; cigarette ash; multiple solia particle such as ickings or the inorganic solid particulate that contains; and all gases; steam; dyestuff; machine oil; medicine and bacterium; virus; mould; the pollution of fungi; the pollution level of clothes; also with fibrous material, fiber contains wet; fabric tissue; dyeing and finishing processing static situation when wearing is relevant.Say that generally level and smooth more being not easy more of fiber surface stain, the hydrophobic structure that the lining of putting in order through nano antifouling produces on the surface of fiber, be the surface of the globule at fabric, as the mercury people by a large amount of discovering, this " lotus leaf " effect has the micro-structure surface of rule, makes to keep air between drop and the lotus leaf surface and have unusual characteristic and self-cleaning action super-hydrophobic, oleophobic.Its super shielded comes from the critical surface tension of the critical surface tension of solid shape fiber less than liquid greasy dirt, thereby liquid greasy dirt can not wetting fiber.Fabric through nano finishing has antistatic property, can stop the absorption of dust and the purpose that organic decomposition reaches anti-fouling and self-cleaning.
With TiO 2Particle carries silver silver ion is embedded TiO 2Lattice constitutes with TiO 2With inertia silver be the short circuit micro cell of electrode, TiO 2The hole that electrode produced is with bacterium and oxidation operation, and silver ion is effective acceptor of electronics, with the reduction of oxidation shape component, thereby reduces the compound of hole and electronics, significantly improves TiO 2Light-catalyzed reaction efficient.On the other hand silver particularly Nano Silver be the potent antiseptic of wide spectrum, and antibacterial action is outstanding lastingly, to the harmful bacterium of kind more than 650 that comprises bacterium, fungi, trichomonad, mycoplasma, even now microorganism such as known all bacteriums, virus and various anti-medicine antibody-resistant bacterium flora all have and suppress and killing action, antibiotic rate reaches 99.99%, and this potent antimicrobial silver ion is at TiO 2Stable existence in the lattice can slowly constantly discharging of silver ion reach the durable antibiotic effect in implementation procedure.Silver is that nano inorganic antimicrobial agent and " Ag-carried nanometer titanium dioxide (AT) antiseptic " are added on the fabric clothes of making in the finishing technique behind the fabric and have the broad-spectrum antibacterial antiviral effect, and long action time and lasting, can also deodorization, to the healthy fabric work clothes of the weaving of human body safety non-toxic.
According to The World Health Organization (WHO) human beings'health is divided into three kinds of states, first kind of state of whole world true health only accounts for 5%, and diagnosis has second kind of state of disease to account for 20%, and most people is that the third state that is in inferior health accounts for 75%.Inferior health is meant that human body is in healthy and unsound rim condition, no organic disease, but there is function to change, people's fatiguability, feel bad, so oneself also could not explain individual, examine again to hospital and can not check disease, at ordinary times because work rhythm is fast, pressure is big, task is heavy, working environment is undesirable, the brain overload operation, hindered brain cell in time replenishing to oxygen and nutrition, make endocrine disturbance, sympathetic activation is excessive, the animals and plants nervous system disorder, cause brainfag, weak and feeble from head to foot, palpitation, the constipation of getting angry, there is not appetite, also some people self health consciousness is not strong at ordinary times, online excessively, diet is random, tobacco and wine are immoderate, treat with courtesy uncontrolled, live in for a long time in the environment of pollution, overdraw is healthy for a long time, make in the marsh of inferior health and sink deeper and deeper, health even life have been lost at last, so the development of sub-health population makes some rising young and middle-aged outstanding intellectuals trend that phenomenon has year by year to be increased of dying in youth, and major part occurs in blue or green strong 40-59 year, and the crowd of this part age bracket suffers from hyperlipemia, high cholesterol, obesity, cataract, hypertension, diabetes and cancer check that to 1866 intellectuals the statistics illness rate is unexpectedly up to 90.4% to Beijing not long ago.Therefore the inspection prevention of paying attention to sub-health population is very urgent.The present invention adds trace element from the fabric spinning solution of human body work clothes, people directly contact in the nano-element infiltration human body that makes through nanotechnology treatments by skin and fabric and enter blood, reach the in-vivo element balance, healthy, eliminate and alleviate the adverse effect of inferior health human body.
The various diseases of human body is relevant with the in-vivo element dysequilibrium, especially essential trace element is to keep the human body eubolism in the human body, the synthetic catabolism of the activity of various enzymes, fat, protein, carbohydrate, the drainage of body endoperoxide and toxin, the adjusting of immunologic function says that generally the necessary macro micro element of human body is mainly derived from the picked-up of food and water.The present invention is exactly that indispensable element with human body is added in the spinning solution of fabric, utilizes fabric to contact with the tight of skin, replenishes mediator's element of volume balance by skin pore, pore, comes body-building, and increase work is renderd a service, and improves the work effect.This be one by wearing the clothes and the tight contact friction of skin absorbs to replenish the new measure of regulating the antagonism human elementary.
The many dissolving out capability of medical stone micronutrient levels are good, powerful water purification effect is arranged, with the micro mist grain after the medical stone nanotechnology treatments after the high-tech PROCESS FOR TREATMENT, make each trace element all have the effect of center of positive charge, refine to then in the manufacture process of fiber, this trace element can be firm absorption and combination, trace element and the macromolecular hydroxyl generation of fiber bonding reaction are on cellulose macromolecule, make and have certain fastness and the functional first cellulose fiber of persistence, contain a large amount of multiple human body trace elements necessary on this first cellulose fiber.Because the medical stone nano particle has magical porous cave material, as microcapsules essential trace element is contained in this microcapsules like perforate, formed the warehouse of human body trace elements necessary.Human body needs just can constantly discharge to too many or too much for use as the cradle of trace element supply again at leisure from this warehouse to make endless, in time replenish the element that needed by human body is wanted, constantly regulate the element balance that replenishes in the antagonism human body, element on unit's cellulose fiber is crossed 800 mesh sieves, its particle diameter is between 0.5-2um, and the size of human body pore, skin, sweat pore is that 2um is far longer than nanometer scale.
The fine anatomy emerging according to human body proves: 3,000,000 cells are arranged approximately, 97 sweat glands, 22 excessive fat pores and 11 fine hairs on the skin of each square metre of human body.Here it is illustrates that the element in the element fiber can infiltrate the interior reason of human body very swimmingly.Unit's cellulose fiber work clothes is owing to directly contact by the energy that absorbs surrounding environment and human body self radiation in pore, the pore infiltration body with skin, blood circulation is accelerated, telangiectasis, strengthen microcirculatory self-disciplining motion, thereby improve microcirculation, promote normal metabolic level and physiological function, get rid of the various diseases that microcirculation does not freely cause at any time.
Detect through the Norman Bethune Medical University, after the human body dress contained the underwear of medical stone fibre, micro-amplification obviously increased in the human serum, and human body reaches 2.83% to the trace elements absorbed rate.The mouse of wearing the medical stone clothes improves 30.8% than the mouse arteriole CBF of not wearing, and the thin vein CBF improves 31.9%, and blood vessel arteriole bore increases by 6.87%, and blood vessel thin vein bore increases by 3.23%.
The Mount Taishan medical stone contains the Ga gallium after testing, Ge germanium, Se selenium, the Sr strontium, the V vanadium, Zn zinc, Cu copper, the Mo molybdenum, Cr chromium, Ni nickel, the Nb niobium, the Ta tantalum, the Co cobalt, Sn tin, the Fu europium, the Zr zirconium, 19 kinds of elements such as W tungsten, leachable Ca calcium is soaked in water, Mg magnesium, K potassium, Na sodium, the Sr strontium, Se selenium, Zn zinc, I iodine, element and mineral matters such as metasilicic acid, the composition that medical stone contains mainly contains ferrous oxide 1.29%, iron oxide 1.40%, anhydrous phosphorus (phosphoric anhydride) 0.26%, manganese oxide 0.02%, magnesium 3.55%, potassium 3.19%, calcium oxide 2.00%, sodium 3.16%, titanium 0.30%, adsorbed water 1.10%, in conjunction with water 0.90% (+), below the heavy metal 40ppm, below the arsenic 4ppm, all at the permissible value lower limit.Heavy metal ion such as the Cd cadmium that in the medical stone energy adsorbed water animals and plants is harmful to, Hg mercury, Pb lead, As arsenic, and odorous gas such as hydrogen sulfide, can also adsorb simultaneously microorganism, virus and other organic substances such as Escherichia coli, get rid of the harmful substance in the animal and plant body, have strengthening the spleen and stomach, protect the liver dirty, antifatigue, adjusting metabolism, strengthen biological effects such as blood circulation and immunity.Medical stone can make desalt, mineralising, activation through the immersion of water, medical stone is described as " cell cleaning agent " cell in the human body is unconsciously washed fully and removes by the people's of pesticide residue and harmful food additive agent pollution cell, thereby make contaminated cell be washed the cell that forms cleaning, and the tissue 65% in the human body is made up of water, the blood of human body is made up of 80% water, people's eyeball 99% is a water, and the vital movement that in a single day human body loses 20% moisture human body will terminate.The moisture of high-quality is the important channel that the human body macro micro element is supplied with in the human body, it is a human body conveying mineral matter, fat, nutritional labeling such as oxygen and hormone, water can play heat radiation again simultaneously, dilution, all effects such as drainage, we can say that all physiological activities of human body all be unable to do without the participation of water, so purifying has been arranged in the human body, mineralising, the high-quality water of activation, various diseases to the prevention human body, especially diseases of cardiovascular and cerebrovascular systems, the prophylactic treatment of various cancers, how important promote longevity is, it is very important to improving health transformation inferior health physique therefore to add the work clothes that contains the medical stone element fabric.
The unit of needed by human have 15 kinds, but what be subjected to most at present that people pay close attention to is selenium, zinc, chromium.Selenium is the element that Chinese generally lack, because content is very rare in soil, geology, water and the animals and plants, so human body is difficult to absorb in the driven vegetation foodstuff, the selenium element is a strong oxidizer, and it is very capable to remove human free radical.Again can antagonism lead, heavy metal element such as mercury, arsenic, exempt from the injury of disease and cancer, anti-cancer and cancer-preventing is anti-ageing again; strengthen immunity, scavenger-cell impurity is the heavy duty cleansing detergent of cell; repair the cell of infringement, multiple organs such as the heart, liver, spleen, swollen, kidney are had good protecting function etc.Zinc can be resisted the intrusion of virus, bacterium and fungi, and 200 plurality of enzymes all contain zinc in the human body, lacks the metabolism that zinc influences enzyme, increases the chance of disease infection, also can influence people's intelligence, eyesight, growth growth and sexual function.Scarce chromium just can cause sugar, lipometabolic unusual, is to cause diabetes and atherosclerotic pathogenic factor, mends decomposition and drainage that chromium can be regulated cholesterolemia, prevents and treats diabetes and atherosclerotic.
As everyone knows, air is by countless molecular under natural cosmic ray, ultraviolet ray, soil and radioactive influence, some air molecule can discharge electronics, the very fast and airborne again neutral molecule be combined into of these electronics is electronegative gas ion, promptly be called anion, someone calls anion " airborne vitamin ", think its vitamin as food, vital movement to human body and other biological has crucial influence, and anion is relevant with human body longevity, so be referred to as " long-lived plain " again.The environment quality mainly is owing to positive and negative ion concentration ratio in the air is unbalance in the air, contains pernicious gas and smog, dust, virus, bacterium, harmful heavy metal material etc. in the air.The effect of negative aeroion: one, reduction: anion can reduce from the active oxygen of generations such as the polluter of the Nature, oxynitrides, cigarette; Two, suction-operated: absorption biological suspension pollutant makes it become heavy ion and the effect that purifies air is played in sedimentation; Three, in and pernicious gas, absorption odor source molecule reacts, and effectively eliminates destructive stimulus gases such as finishing pollution and benzene, formaldehyde, ketone, nitrogen, use nature or the artificial negative aeroion that produces treat and prevent disease.The constitutional effective ways hot issue of health-care hospital that present health convalescence medical circle is just risen, because airborne anion has many medical care effects to human body: 1. airborne anion can be regulated the human body central nervous system function, makes its excited and inhibition; 2. promote the rehabilitation of diseases such as hypertension, coronary heart disease, high fat of blood; 3. have albumin in the blood of increasing, reduce globulin, increase red blood cell and red blood cell number, promote blood anatomic element and physical characteristic to recover normal effect; 4. airborne anion can promote ciliary movement on the mucous membrane, increases glandular secretion, improves the smooth muscle excitability, strengthens ventilatory, and respiratory tract, bronchial disease, rhinitis chronic, nasosinusitis etc. are all had the supplemental treatment effect, and without any side effects; 5. airborne anion can also improve the cellular immunity and the humoral immunity of body, increases antibody and complement r-globulin in the blood, improves the lymphopoiesis ability, and is useful to lymphocytic survival; 6. the function that airborne anion has depositing dust, antibacterial, degerming and deodorizing etc. to purify air; 7. airborne anion also has the effect tired and that regain one's strength of eliminating, can produce nanometer superfine powder and the silver that the tourmaline material of anion makes with modern superfine nanometer technology is nano inorganic antimicrobial agent and Ag-carried nanometer titanium dioxide (AT) antiseptic, medical stone, the trickle powder of tourmaline nanometer, nanometer selenium, atresia thin polyurethane membrane material thermoplastic polyurethane (TPU) elastomeric material nano powder body refine in the chemical fibre spinning solution, makes the anion textile fabric and makes our needed work clothes again or form covalent bond with the hydroxyl ammonia on novel negative ion material that has the active reaction gene and the fiber and obtain and hold ventilative soft anion fabric.The anion textile directly is through on one's body, and large tracts of land contacts with human body skin, utilize the heat energy of human body and the friction of human motion and skin to quicken the generation of anion, form an anion air layer at skin and check room, eliminated the multiple injury of oxygen radical to health, anion is easy to through skin, pore, sweat pore enters in the body, make human body contained moisture, body fluid is alkalescent, the water of body fluid is activated, purifying, mineralising, make it become the water of high-quality, make the cell cleaning, blood purification has thoroughly been eliminated the dirt in the body, foreign material, bacterium, virus and microorganism, promote human body metabolism, impel health strong.The nano-negative ion of producing with clean your the refreshing High Seience Technology Co., Ltd. in Beijing divides SL-900 to make multifunctional textile fabric work clothes.
The present invention is further described below in conjunction with examples of implementation:
Embodiment one: the Chinese medicine live part
(1) monkshood, flos caryophylli, Chinese cassia tree, genseng, the root of Chinese wild ginger, each 100g of Chinese honey locust respectively account for 15.9%; Borneol 30g accounts for 4.8%.
Cure mainly: the sub-health population apocamnosis
(2) tuber of pinellia, Southern Star, Radix Angelicae Sinensis, the root of Dahurain angelica, monkshood, radix aconiti agrestis, the rhizome of davallia, each 100g of turmeric respectively account for 9%; Realgar 15g accounts for 1.4%; Root of Chinese trichosanthes, rheum officinale, Herba Andrographitis, golden cypress, each 50g of cottonrose hibiscus leaf respectively account for 4.5%; Camphor, borneol, tooth soap, each 10g of silver-colored pearl respectively account for 0.9%.
Cure mainly: omoplate wall of the chest syndrome.Be to cause compressing or friction causes pain, can radiate neck, shoulder, chest, hand owing to synovial bursa between the omoplate and the wall of the chest or other tissue abnormalities, the cause of disease be since shoulder chest joint inharmonious due to.
(3) Radix Aconiti, Radix Aconiti Kusnezoffii, frankincense, myrrh, living cape jasmine, the root of Chinese wild ginger, each 100g of spina gleditsiae respectively account for 14.3%.
Cure mainly: the chronic injury of the tissues.Cause or the chronic wound of being overworked for a very long period into that by the acute injury of the tissues good sending out located in shoulder, waist, knee, heel etc., causes muscles and bones muscle contracture, pain, limitation of activity.
(4) cloves, evodia rutaecarpa, the root of Chinese wild ginger, rattletop, each 50g of Chinese gall respectively account for 6.5%; Galingal, corydalis tuber, each 100g of the dried immature fruit of citron orange respectively account for 12.9%; Tarragon 75g accounts for 9.7%; Wrinkled giant hyssop 150g accounts for 19.4%.
Cure mainly: stomach swashs syndrome.It is the function of intestinal canal disorder disease.
(5) Chinese gall, the seed of Chinese dodder, radix cyathulae, the bark of eucommia, river Radix Angelicae Sinensis, Chinese yam, lucid asparagus, the tuber of dwarf lilyturf, radix rehmanniae recen, each 100g of prepared rhizome of rehmannia respectively account for 5.6%; Saline cistanche 150g accounts for 8.3%; Genseng, PORIA ALBA, anise, rhizoma alismatis, the root bark of Chinese wolf-berry, pilose antler, calamus, Chinese prickly ash, crust halberd, polygala root, raspberry, the fruit of Chinese wolfberry, each 50g of the seed of Oriental arborvitae respectively account for 2.8%.
Cure mainly: all void and decreasing, the disease of dispelling in benefit year.
(6) Flos Chrysanthemi, the tuber of dwarf lilyturf, the fruit of Chinese wolfberry, the bighead atractylodes rhizome, genseng, PORIA ALBA, polygala root, calamus, each 300g of the osmanthus heart respectively account for 11.1%.
Cure mainly: make ailment said due to cold or exposure not invade treatment all kinds of diseases and ailments, benefiting essence-blood, increase energy, promote longevity.
(7) deer frost, deer horn glue, the seed of Chinese dodder, the seed of Oriental arborvitae, each 500g of prepared rhizome of rehmannia respectively account for 20%.
Cure mainly: reason all kinds of diseases and ailments, support the five internal organs, mend marrow, strengthen the bone, beneficial will, peace soul, make us preserving youthful looks and make light of one's life by commiting suicide, promote longevity.
(8) living dried rehamnnia root 250g accounts for 26.3%; Pericarpium zanthoxyli, the root of bidentate achyranthes, monkshood, deer horn glue, each 100g of the seed of Chinese dodder respectively account for 10.5%; Almond, each 150g of saline cistanche respectively account for 15.8%.
Cure mainly: mend marrow, beneficial color greatly, fill skin, cold-resistant heat, Qiang Zhili.
(9) ripe dried rehamnnia root 1500g accounts for 51.7%; Lucid asparagus 600g accounts for 20.7%; The fruit of Chinese magnoliavine, polygala root, each 200g of stone reed respectively account for 6.9%; PORIA ALBA, each 100g of the osmanthus heart respectively account for 3.4%.
Cure mainly: reinforcement, remove sick, make eye bright.
Embodiment two: nanometer selenium, medical stone, tourmaline, silver-series antibacterial agent and Chinese medicine mixing nano powder %
1. nanometer selenium or organic selenium drying mycelium nano powder 5%
2. medical stone nanometer fine powder 20%
3. tourmaline nano powder or SL-900 negative ion powder 22%
4. silver-based inorganic antibacterial agent 10%
5. Ag-carried nanometer titanium dioxide (AT) antiseptic 8%
6. a certain prescription mixing of Chinese medicine nano powder 35%
Embodiment three: water and oil repellant fabric proportioning %
1. nanometer selenium, medical stone, tourmaline, silver-series antibacterial agent and Chinese medicine admixed finepowder 25%
2. oil-repellent agent Fc-921 2%
3. durability water repellent (as pyridines) 2%
4. amino resins (as MF) or thermoplastic polyurethane 1%
5. cotton, fiber crops, wool, sticking fine, brocade, wash, nitrile, polypropylene fibre and blended ratio liquid 70%

Claims (4)

1. the self-cleaning anion fabric crewman body-building work clothes of the super water, oil and soil repellent of nanometer is characterized in that: add the nano powder body of being made up of following relevant Chinese medicinal formulae in spinning solution
(1) monkshood, flos caryophylli, Chinese cassia tree, genseng, the root of Chinese wild ginger, each 50-150g of Chinese honey locust respectively account for 10-21%; Borneol 20-40g accounts for 1-9%.
(2) tuber of pinellia, Southern Star, Radix Angelicae Sinensis, the root of Dahurain angelica, monkshood, radix aconiti agrestis, the rhizome of davallia, each 50-150g of turmeric respectively account for 4-15%; Realgar 10-20g accounts for 0.5-3%; Root of Chinese trichosanthes, rheum officinale, Herba Andrographitis, golden cypress, each 40-60g of cottonrose hibiscus leaf respectively account for 1-9%; Camphor, borneol, tooth soap, each 5-15g of silver-colored pearl respectively account for 0.4-1.4%.
(3) Radix Aconiti, Radix Aconiti Kusnezoffii, frankincense, myrrh, living cape jasmine, the root of Chinese wild ginger, each 50-150g of spina gleditsiae respectively account for 9-19%.
(4) cloves, evodia rutaecarpa, the root of Chinese wild ginger, rattletop, each 40-60g of Chinese gall respectively account for 1-12%; Galingal, corydalis tuber, each 8-120g of the dried immature fruit of citron orange respectively account for 7-18%; Tarragon 60-90g accounts for 5-14%; Wrinkled giant hyssop 120-180g accounts for 15-25%.
(5) Chinese gall, the seed of Chinese dodder, radix cyathulae, the bark of eucommia, river Radix Angelicae Sinensis, Chinese yam, lucid asparagus, the tuber of dwarf lilyturf, radix rehmanniae recen, each 80-120g of prepared rhizome of rehmannia respectively account for 1-10%; Saline cistanche 130-170g accounts for 5-14%; Genseng, PORIA ALBA, anise, rhizoma alismatis, the root bark of Chinese wolf-berry, pilose antler, calamus, Chinese prickly ash, crust halberd, polygala root, raspberry, the fruit of Chinese wolfberry, each 30-70g of the seed of Oriental arborvitae respectively account for 0.5-5%.
(6) Flos Chrysanthemi, the tuber of dwarf lilyturf, the fruit of Chinese wolfberry, the bighead atractylodes rhizome, genseng, PORIA ALBA, polygala root, calamus, each 250-350g of the osmanthus heart respectively account for 5-16%.
(7) deer frost, deer horn glue, the seed of Chinese dodder, the seed of Oriental arborvitae, each 400-600g of prepared rhizome of rehmannia respectively account for 10-30%.
(8) living dried rehamnnia root 200-300g accounts for 21-32%; Pericarpium zanthoxyli, the root of bidentate achyranthes, monkshood, deer horn glue, each 50-150g of the seed of Chinese dodder respectively account for 5-11%; Almond, each 100-200g of saline cistanche respectively account for 10-21%.
(9) ripe dried rehamnnia root 1400-1600g accounts for 40-60%; Lucid asparagus 500-700g accounts for 10-31%; The fruit of Chinese magnoliavine, polygala root, each 100-300g of stone reed respectively account for 1-12%; PORIA ALBA, each 50-150g of the osmanthus heart respectively account for 1-6%.
2. the anion fabric crewman body-building work clothes according to claims 1, that the super water, oil and soil repellent of nanometer is self-cleaning is characterized in that: add the mixing nano-powder % that is made up of nanometer selenium in spinning solution
1. the dry mycelium nano powder of nanometer selenium or organic selenium 1-10%
2. medical stone nanometer fine powder 15-25%
3. tourmaline nano powder or SL-900 negative ion powder 17-27%
4. silver-based inorganic antibacterial agent 5-15%
5. Ag-carried nanometer titanium dioxide (AT) antiseptic 3-13%
6. a certain prescription mixing of Chinese medicine nano powder 30-40%
3. the anion fabric crewman body-building work clothes according to claims 1,2, that the super water, oil and soil repellent of nanometer is self-cleaning is characterized in that: form % by following each material
1. nanometer selenium, medical stone, tourmaline, silver-series antibacterial agent and Chinese medicine admixed finepowder 20-30%
2. oil-repellent agent Fc-921 0.5-4%
3. durability water repellent (as pyridines) 0.5-4%
4. amino resins (as MF) or thermoplastic polyurethane 0.05-2%
5. cotton, fiber crops, wool, sticking fine, brocade, wash, nitrile, polypropylene fibre and blended ratio liquid 60-80%
4. the anion fabric crewman body-building work clothes according to claims 1,2,3, that the super water, oil and soil repellent of nanometer is self-cleaning, it is characterized in that: all mixed materials must be crossed the 700-900 mesh sieve through nanotechnology treatments, medium particle diameter 0.01-50 μ m.
CN2010101897073A 2010-06-02 2010-06-02 Nanometer anion fabric seaman body-building working uniform with characteristics of ultra-oleophobic and ultra-hydrophilic properties, antifouling property and self-cleaning property Pending CN101946986A (en)

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CN102733171B (en) * 2012-06-12 2014-10-29 南通全技纺织涂层有限公司 Green self-cleaning super-hydrophobic oleophobic coated fabric
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CN104762691A (en) * 2015-03-27 2015-07-08 安徽省含山县富强羽绒制品有限公司 Antimicrobial deodorizing down composite fiber and manufacturing method thereof
CN105249721A (en) * 2015-09-29 2016-01-20 屠明鑫 Health-care mattress capable of improving sleep and reducing blood fat and making method thereof
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CN106174777A (en) * 2016-07-08 2016-12-07 南通蛇类治疗研究所 The construction personnel open air winter protects clothes by multi-functional warming labor
CN107874332A (en) * 2016-09-30 2018-04-06 江阴林格科技有限公司 A kind of nanometer insulated cold wear
CN106987921A (en) * 2017-03-13 2017-07-28 南通蛇类治疗研究所 Snake Chinese medicine element fabric functional takes
CN106988117A (en) * 2017-03-13 2017-07-28 南通蛇类治疗研究所 Nano medication element health-care functional fabric underwear
CN108621481A (en) * 2017-03-22 2018-10-09 绍兴灵星健康科技有限公司 Antibacterial fabric containing silver ion and antibacterial fabric
CN108286108A (en) * 2018-04-23 2018-07-17 合肥云都棉花有限公司 A kind of textile fabric and preparation method thereof based on cotton stalk high-tensile
CN108741337A (en) * 2018-07-09 2018-11-06 苏州大学 Based on the bionical textile for dividing shape self-similar structure
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Application publication date: 20110119