CN101946762A - Nitenpyram and imidacloprid binary composition electrostatic spray liquid agent and preparation method thereof - Google Patents
Nitenpyram and imidacloprid binary composition electrostatic spray liquid agent and preparation method thereof Download PDFInfo
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- CN101946762A CN101946762A CN2010102625038A CN201010262503A CN101946762A CN 101946762 A CN101946762 A CN 101946762A CN 2010102625038 A CN2010102625038 A CN 2010102625038A CN 201010262503 A CN201010262503 A CN 201010262503A CN 101946762 A CN101946762 A CN 101946762A
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Abstract
The invention relates to an electrostatic spray liquid agent with a nitenpyram and imidacloprid binary composition as the active ingredient and a preparation method thereof. The electrostatic spray liquid agent comprises the following components by weight: 0.1-50.0 parts of nitenpyram, 0.1-70.0 parts of imidacloprid, 1.0-8.0 parts of conductive agents, 1.0-10.0 parts of cosolvents and the balance solvents, wherein the number of the total part is 100. The electrostatic spray liquid agent is convenient to process, has low cost, good effect, long persistence and high efficiency, can reduce the environmental pollution, improve the utilization ratio of the pesticides and reduce the dosage of the pesticides and is suitable for electrostatic spray.
Description
Technical field
The present invention relates to Nitenpyram (active ingredient I hereinafter referred to as) and Imidacloprid (active ingredient II hereinafter referred to as) for electrostatic spray liquor of the binary Pesticidal combination of active ingredient and preparation method thereof, belong to the pesticidal preparations field.
Background technology
Nitenpyram as active ingredient I is an anabasine insecticide, has unique chemical and biological property.Mainly act on the insect nerve, insect cynapse acceptor is had the nerve block effect.Have efficient, low toxicity, interior suction and do not have four big advantages such as cross resistance, and insecticidal spectrum extensively, the lasting period is longer.Safe in utilization, insect is difficult for producing resistance.Be the desirable substitute products of conventional pesticides such as Imidacloprid, Acetamiprid.Nitenpyram can be widely used in paddy rice, fruit tree, vegetables and tea, prevent and treat various plant hoppers, aphid, thrips, trialeurodes vaporariorum, Bemisia tabaci, leafhopper etc., the insect that conventional pesticides has been produced resistance has remarkable control efficiency, is one of nicotinoids agricultural chemicals last word.
Imidacloprid as active ingredient II is the nitro-methylene-type systemic insecticide, is the acting body of nicotinic acid acetylcholinesterase acceptor, and it is malfunctioning to disturb the pest movements nervous system that chemical signal is transmitted, no cross resistance problem.Be used to prevent and treat sucking pest and resistant strain thereof.Imidacloprid is a chloro nicotine insecticide of new generation, has wide spectrum, efficient, low toxicity, low-residual, and insect is difficult for producing resistance, to characteristics such as people, animal, plant and natural enemies securities, and have tag, stomach toxicity and the multiple drug effect of interior suction.Behind the insect contact medicament, the nervous centralis normal conduction is obstructed, and makes its paralysis dead.Quick-acting is good, higher preventive effect is promptly arranged in 1 day behind the medicine, and residual life reached about 25 days.Be mainly used in the control sucking pest.Can be used for preventing and treating insects such as spiraea aphid, apple leaf curling aphid, black peach aphid, pear sucker, leaf roller, aleyrodid, liriomyza bryoniae.
The existing preparation of the binary Pesticidal combination that the present invention relates to mainly contains missible oil, aqueous emulsion, microemulsion and wetting powder etc.And the electrostatic spray liquor of Nitenpyram and Imidacloprid binary composition does not appear in the newspapers both at home and abroad.
Two kinds of mixing active ingredients proportionings are I: II=1: 10 to 1: 200, be preferably 1: 10 to 1: 100 composition.
The electrostatic spray liquor is low by the screening volatility, flash-point is high, to former medicine dissolubility height,, organic solvent that viscosity low lower to chemical injury of crops, not to water,, but directly use during dispenser with electrostatic sprayer generally also not to other organic solvents.Electrostatic spray makes the droplet of each ejection all have electrostatic charge, be easier to be caught by target, than general finish deposition height, penetrability to target such as plant strain canopy is more superior, so efficient especially with economize medicine, it is one of present target hit rate is the highest, environmental pollution the is minimum formulations of pesticide and using method.And not containing the high volatile volatile composition in the droplet, its size does not have significant change with quality from leave facility arrival target process, reduced volatilization and drift.Droplet is tiny and even, meets " biological optimum grain-diameter " requirement, has significantly improved deposition.The electrostatic spray liquor directly uses and need not be to water, is specially adapted to water scarcity, damage by disease and insect and belongs to fulminant and big, the occasion that must dispenser on a large scale in the short time of area takes place.
The electrostatic spray technology is that applying high voltage static is set up an electrostatic field between shower nozzle and spraying target, and agricultural chemicals liquid is flowed through after the shower nozzle atomizing, filled with electric charge by different charging methods, form colony's charged droplets, then under the synergy of electrostatic field force and other external force, droplet is done directed movement and is adsorbed on each position of target, reaches good performances such as deposition efficiency height, float of mist droplet scatter and disappear less, improve the ecological environment.Atomization of liquid mechanism more complicated under the electrostatic field, it has been generally acknowledged that: electrostatic interaction can reduce surface tension of liquid, reduces the resistance that atomizes, simultaneously, repulsive interaction generation between the same sex electric charge additional external and internal pressure opposite with surface tension is poor, thereby improves fogging degree.
The droplet charging has three kinds of modes: (1) corona charging method, utilize the electrostatic high-pressure corona to make droplet charged; (2) contact mise-a-la-masse method directly places soup to the static high voltage, is charged droplet after the nozzle ejection; (3) inductive charging method is externally under the voltage electric field action, utilizes the electric field between electrode and soup jet to make droplet charged.
The electrostatic spray technology has the following advantages:
1. electrostatic spray has the effect of outflanking, point effect, penetration effect, the target crop is covered evenly the deposition height.The droplet that electrostatic spray forms has same sex electric charge, in spatial movement, repel mutually, do not condense, the induction of charged droplet makes the outside of crop produce the charges of different polarity, under the effect of electric field force, droplet is adsorbed onto the positive and negative of crop fast, has improved the deposition of agricultural chemicals on the target crop, has improved the uniformity of agricultural chemicals deposition.Agricultural chemicals improves more than 36% than conventional spraying at the deposition on the crop surface, and leaf back side agricultural chemicals deposition is tens times of conventional spraying, and crop top, middle part and root agricultural chemicals deposition distributing homogeneity all are significantly increased.More much lower at the deposition that vegetable protecting field adopts electrostatic spray, droplet to drop on the electrical insulator plastic film than conventional spraying, can improve the deposition of droplet on plant, effectively utilize agricultural chemicals, reduce drift and be deposited in loss on the plastic film.
2. improve the availability of agricultural chemicals, reduce the usage amount of agricultural chemicals, reduce the control cost.The footpath generally about 45 μ m, can reduce mist droplet particle size effectively in the electrostatic spray droplet volume, improves the spectrum of fog drop uniformity, meets biological optimum grain-diameter theory, is easy to be caught by target.When electrostatic potential was 20KV, it is about 10% that mist droplet particle size reduces, and the spectrum of fog drop uniformity improves about 5%.Significantly increase the chance that droplet contacts with damage by disease and insect, improved extermination of disease and insect pest effect (similarity condition improves more than 2 times than conventional spraying down) exponentially.And finish has affinity to insect body wall, is easy to penetrate body wall and enters in the pest body, and insect is poisoned fast.Dosage is saved more than 30% than conventional spraying.
3. little to water source, environmental influence, reduced the pollution of agricultural chemicals to environment.The electrostatic spray spouting liquid is few, and every mu only is 60～150mL, only is more than one percent of conventional spraying, and the suction-operated of electric field force reduced the drift of agricultural chemicals, makes agricultural chemicals availability height, has avoided the agricultural chemicals loss, has reduced the pollution of agricultural chemicals to environment.
4. the electrostatic spray lasting period is long.Charged droplet high adsorption capacity on crop, and comprehensively evenly, dispenser efficient height, it is firm that agricultural chemicals adheres on leaf, resistance of rainwater washing against, and the high boiling solvent in the finish can effectively delay the degraded of pesticide active ingredient, and drug effect is permanent.
5. the work efficiency height is prevented and treated in time.The hand-held electrostatic ultra low volume spray improves 10～20 times of work efficiency than conventional spraying, and Dongfanghong-18 type power knapsack electrostatic sprayer per hour can spray 20～30 mu.
6. electrostatic spray adopts supporting electrostatic spray liquor, need not to add water, is particularly suitable for the drought and water shortage area and uses.
7. electrostatic spray be difficult for to produce poisoning to crop, does not have obviously residually, can improve the quality of crop.
Summary of the invention
The purpose of this invention is to provide a kind of is the electrostatic spray liquor preparation of active ingredient with Nitenpyram and Imidacloprid binary composition.
Another object of the present invention provides the preparation method of described this electrostatic spray liquor.
This electrostatic spray liquor comprises the component of following weight proportion:
0.1 part～50.0 parts of Nitenpyrams
0.1 part～70.0 parts of Imidacloprids
1.0 parts～8.0 parts of conductive agents
1.0 parts～10.0 parts of cosolvents
Solvent complements to 100 parts.
The above composition weight proportion optimization:
1.0 parts～15.0 parts of Nitenpyrams
2.0 parts～20.0 parts of Imidacloprids
1.0 parts～5.0 parts of conductive agents
2.0 parts～8.0 parts of cosolvents
Solvent complements to 100 parts.
Cosolvent is selected from cyclohexanone, methyl-sulfoxide or N-Methyl pyrrolidone, preferred methyl-sulfoxide or N-Methyl pyrrolidone.
Conductive agent is an anion surfactant, as neopelex or calcium dodecyl benzene sulfonate.
Solvent is many Fluhyzons, and as a line oil, two wires oil, heavy aromatics, or vegetable oil are as turpentine oil or cottonseed oil, corn oil.Preferred two wires oil or the above aromatic hydrocarbons of C10.
Electrostatic spray liquor of the present invention adopts the manner known in the art preparation, normally active ingredient and conductive agent, cosolvent, solvent is fully mixed in proportion and forms.
The binary composition of two kinds of compositions, it is good enough and be easy to generate the problem of resistance to solve the single component result of use, and because the Nitenpyram lasting period is long, the characteristics that Imidacloprid quick-acting is strong, and both action sites and mechanism of action difference, both binary compositions can well reach the effect that remedies mutually with synergy.
The target crop that is fit to is cereal crops such as paddy rice, wheat, economic crops such as soybean, peanut, cotton, tea tree, vegetable crops such as tomato, eggplant, capsicum, lettuce, celery, wild cabbage, Kidney bean, broad bean, cowpea, pea, ground family crops such as cucumber, pumpkin, watermelon, fruit tree crops such as grape, oranges and tangerines, apple, pear tree, peach.
Electrostatic spray liquor of the present invention is fit to the various plant hoppers of control, aphid, thrips, trialeurodes vaporariorum, Bemisia tabaci, leafhopper, spiraea aphid, apple leaf curling aphid, black peach aphid, pear sucker, leaf roller, aleyrodid, liriomyza bryoniae etc.
The method for optimizing of using electrostatic spray liquor of the present invention is an electrostatic spray, and a situation arises determines suitable consumption according to controlling object, and formulation rate is 90～450g a.i./hm usually
2
Electrostatic spray liquor of the present invention is easy to process, with low cost, good drug efficacy, hold imitate long, work efficiency is high; Can reduce environmental pollution, improve the agricultural chemicals availability, reduce the agricultural chemicals usage amount, be suitable for electrostatic spray.
Embodiment
The present invention describes with the following example, but does not limit the scope of the invention.
Embodiment 1:
Prepare 1.5% Nitenpyram imidacloprid electrostatic spraying liquor
Nitenpyram 0.5kg
Imidacloprid 1.0kg
N-Methyl pyrrolidone 2.0kg
Calcium dodecyl benzene sulfonate 1.5kg
Two wires oil complements to 100kg.
The former medicinal cosolvent of Nitenpyram and Imidacloprid, solvent dissolve fully, add other compositions again, evenly mix, and can be made into the electrostatic spray liquor after fully stirring.
Step according to identical with embodiment 1 can prepare following examples.
Embodiment 2:
Prepare 5% Nitenpyram imidacloprid electrostatic spraying liquor
Nitenpyram 1.0kg
Imidacloprid 4.0kg
N-Methyl pyrrolidone 3.0kg
Calcium dodecyl benzene sulfonate 3.0kg
Two wires oil complements to 100kg.
Embodiment 3:
Prepare 15% Nitenpyram imidacloprid electrostatic spraying liquor
Nitenpyram 5.5kg
Imidacloprid 9.5kg
Methyl-sulfoxide 4.0kg
Calcium dodecyl benzene sulfonate 4.0kg
C10 aromatic hydrocarbons complements to 100kg.
Embodiment 4:
Prepare 25% Nitenpyram imidacloprid electrostatic spraying liquor
Nitenpyram 10.5kg
Imidacloprid 14.5kg
N-Methyl pyrrolidone 6.5kg
Neopelex 4.0kg
Two wires oil complements to 100kg.
Embodiment 5:
Prepare 35% Nitenpyram imidacloprid electrostatic spraying liquor
Nitenpyram 17.5kg
Imidacloprid 16.5kg
Methyl-sulfoxide 7.5kg
Calcium dodecyl benzene sulfonate 5.0kg
C10 aromatic hydrocarbons complements to 100kg.
Embodiment 6:
Prepare 45% Nitenpyram imidacloprid electrostatic spraying liquor
Nitenpyram 20.5kg
Imidacloprid 24.5kg
N-Methyl pyrrolidone 9.5kg
Neopelex 5.0kg
Two wires oil complements to 100kg.
Prepared Nitenpyram and imidacloprid electrostatic spraying liquor outward appearance are transparent homogeneous oily liquids; Low temperature compatibility is good, and under-5 ℃, refrigeration 7d does not separate out crystallization or suspension; Volatility is low, filter paper suspension method measurement result, and volatility is lower than 30%; To plant safety, no poisoning; The employing method of remaining silent is measured, and flash-point is greater than 70 ℃; Viscosity is below 10mPas; Electrical conductivity (μ Ω cm
-1) 1～10
-3Between.
Claims (8)
1. Nitenpyram and Imidacloprid binary composition electrostatic spray liquor is characterized in that comprising the component of following weight proportion:
0.1 part～50.0 parts of Nitenpyrams
0.1 part～70.0 parts of Imidacloprids
1.0 parts～8.0 parts of conductive agents
1.0 parts～10.0 parts of cosolvents
Solvent complements to 100 parts.
2. Nitenpyram according to claim 1 and Imidacloprid binary composition electrostatic spray liquor is characterized in that described composition weight proportion optimization:
1.0 parts～15.0 parts of Nitenpyrams
2.0 parts～20.0 parts of Imidacloprids
1.0 parts～5.0 parts of conductive agents
2.0 parts～8.0 parts of cosolvents
Solvent complements to 100 parts.
3. Nitenpyram according to claim 1 and 2 and Imidacloprid binary composition electrostatic spray liquor, it is characterized in that: conductive agent is selected from anion surfactant.
4. Nitenpyram according to claim 3 and Imidacloprid binary composition electrostatic spray liquor, it is characterized in that: conductive agent is neopelex or calcium dodecyl benzene sulfonate.
5. Nitenpyram according to claim 1 and 2 and Imidacloprid binary composition electrostatic spray liquor, it is characterized in that: cosolvent is selected from cyclohexanone, methyl-sulfoxide, or N-Methyl pyrrolidone.
6. Nitenpyram according to claim 5 and Buprofezin binary composition electrostatic spray liquor is characterized in that: preferred methyl-sulfoxide of cosolvent or N-Methyl pyrrolidone.
7. Nitenpyram according to claim 5 and Imidacloprid binary composition electrostatic spray liquor, it is characterized in that: solvent is selected from many Fluhyzons, heavy aromatics, or vegetable oil.
8. Nitenpyram according to claim 7 and Imidacloprid binary composition electrostatic spray liquor is characterized in that: solvent preferred two wires oil or the above aromatic hydrocarbons of C10.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN 201010262503 CN101946762B (en) | 2010-08-25 | 2010-08-25 | Nitenpyram and imidacloprid binary composition electrostatic spray liquid agent and preparation method thereof |
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| CN 201010262503 CN101946762B (en) | 2010-08-25 | 2010-08-25 | Nitenpyram and imidacloprid binary composition electrostatic spray liquid agent and preparation method thereof |
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| CN101946762A true CN101946762A (en) | 2011-01-19 |
| CN101946762B CN101946762B (en) | 2013-11-06 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102379299A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Ultralow volume liquid containing spirotetramat |
| CN106954650A (en) * | 2017-03-24 | 2017-07-18 | 合肥云都棉花有限公司 | A kind of cotton Pesticidal combination containing Nitenpyram and preparation method thereof |
| CN110384010A (en) * | 2019-08-20 | 2019-10-29 | 淮安市植保植检站 | The method that top spray applies root-pouring method prevention and treatment Snakegourd Fruit thrips in conjunction with punching |
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| CN1058505A (en) * | 1991-09-14 | 1992-02-12 | 中国国际科技促进会保康新技术研究所 | The prescription of electrostatically sprayed pesticide oil preparation |
| CN101524083A (en) * | 2009-04-27 | 2009-09-09 | 江苏辉丰农化股份有限公司 | Insecticidal composition containing nitenpyram and imidacloprid |
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2010
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1058505A (en) * | 1991-09-14 | 1992-02-12 | 中国国际科技促进会保康新技术研究所 | The prescription of electrostatically sprayed pesticide oil preparation |
| CN101524083A (en) * | 2009-04-27 | 2009-09-09 | 江苏辉丰农化股份有限公司 | Insecticidal composition containing nitenpyram and imidacloprid |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102379299A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Ultralow volume liquid containing spirotetramat |
| CN106954650A (en) * | 2017-03-24 | 2017-07-18 | 合肥云都棉花有限公司 | A kind of cotton Pesticidal combination containing Nitenpyram and preparation method thereof |
| CN110384010A (en) * | 2019-08-20 | 2019-10-29 | 淮安市植保植检站 | The method that top spray applies root-pouring method prevention and treatment Snakegourd Fruit thrips in conjunction with punching |
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| CN101946762B (en) | 2013-11-06 |
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Effective date of registration: 20210609 Address after: 276100 Ma Tou Zhen Dong AI Guo Cun, Tancheng County, Linyi City, Shandong Province Patentee after: Tancheng xiangwanjia Food Co.,Ltd. Address before: 530007, No. 1, west section, Chuangxin Road, Nanning, the Guangxi Zhuang Autonomous Region Patentee before: Guangxi Tianyuan Biochemical Co.,Ltd. |
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Granted publication date: 20131106 Termination date: 20200825 |