CN101946764B - Electrostatic spraying liquid formulation of emamectin benzoate and hexaflumuron binary composite and preparation method thereof - Google Patents
Electrostatic spraying liquid formulation of emamectin benzoate and hexaflumuron binary composite and preparation method thereof Download PDFInfo
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- CN101946764B CN101946764B CN 201010262512 CN201010262512A CN101946764B CN 101946764 B CN101946764 B CN 101946764B CN 201010262512 CN201010262512 CN 201010262512 CN 201010262512 A CN201010262512 A CN 201010262512A CN 101946764 B CN101946764 B CN 101946764B
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- hexaflumuron
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Abstract
The invention relates to an electrostatic spraying liquid formulation of a binary composite with effective constituents of emamectin benzoate and hexaflumuron and a preparation method thereof. The electrostatic spraying liquid formulation comprises the following components in parts by weight: 0.1-20.0 parts of emamectin benzoate, 0.1-20.0 parts of hexaflumuron, 1.0-8.0 parts of conductive agents, 1.0-10.0 parts of cosolvents and the balance of solvents. The electrostatic spraying liquid formulation has the advantages of convenient processing, low cost, good pesticide effect, long durative efficacy and high work efficiency and can reduce the environmental pollution, enhances the utilization rate of pesticides, decreases the pesticide consumption, and is suitable for electrostatic spraying.
Description
Technical field
The present invention relates to first dimension salt (hereinafter referred to as active ingredient I) and HEXAFLUMURON (hereinafter referred to as active ingredient II) and be the electrostatic spray liquor and preparation method thereof of the binary Pesticidal combination of active ingredient, belong to the pesticidal preparations field.
Background technology
First dimension salt (emamectin benzoate) as active ingredient I is a kind of new and effective semisynthetic antibiotics insecticide that begins to synthesize from the fermented product AVERMECTIN B1, has super-high-efficient, low toxicity, noresidue, the nuisanceless characteristics that wait biopesticide.Its mechanism of action is to hinder that the pest movements nerve information transmits and paralysis is dead, and the mode of action is take stomach toxicity, action of contace poison as main, without systemic action, but can effectively infiltrate crop epidermal tissue.It can be used for preventing and treating the various pests such as pear sucker, cabbage caterpillar, diamond-back moth, beet armyworm, cotton bollworm, oriental tobacco budworm, leaf miner, Liriomyza, Americal rice leaf miner.
HEXAFLUMURON (hexaflumuron) as active ingredient II belongs to the benzoyl urea insecticide, is chitin synthesis inhibitor.HEXAFLUMURON has very high desinsection and ovicidal activity and quick-acting, and its mechanism of action is effectively suppress insect chitin synthetic, hinders the insect growth of normally casting off a skin, and the mode of action has action of contace poison concurrently take stomach poison function as main.It can be used for preventing and treating the various pests such as wild cabbage diamond-back moth, prodenia litura, cabbage caterpillar, citrus leaf-miner, apple leaf miner, heart-eating worm, pine caterpillars, especially cotton bollworm is had special efficacy.
The existing preparation of above binary Pesticidal combination mainly contains missible oil, microemulsion, water dispersible granules and wetting powder etc.And first dimension salt and HEXAFLUMURON binary composition electrostatic spray liquor have no report both at home and abroad.
The mixing match of two kinds of active ingredients is I: II=1: 10 to 1: 100, be preferably the composition of 1: 10 to 1: 50.
The organic solvent that the electrostatic spray liquor is low by the screening volatility, flash-point is high, high to former medicine dissolubility, lower to chemical injury of crops, viscosity is low not to water, generally also not to other organic solvents, but is directly used with electrostatic sprayer during dispenser.Electrostatic spray makes the droplet of each ejection all with electrostatic charge, be easier to be caught by target, higher than general finish deposition, penetrability to target such as plant strain canopy is more superior, therefore efficient especially with economize medicine, it is one of present target hit rate is the highest, environmental pollution the is minimum formulations of pesticide and using method.And not containing the high volatile volatile composition in droplet, its size does not have significant change with quality from leave facility arrival target process, reduced volatilization and drift.Droplet is tiny and even, meets " biological optimum grain-diameter " requirement, has significantly improved deposition.The electrostatic spray liquor directly uses and need not be to water, is specially adapted to water scarcity, damage by disease and insect and belongs to fulminant and occur that area is large, occasion that must dispenser on a large scale in the short time.
The electrostatic spray technology is that applying high voltage static is set up an electrostatic field between shower nozzle and spraying target, and agricultural chemicals liquid is flowed through after shower nozzle atomizing, filled with electric charge by different charging methods, form colony's charged droplets, then under the synergy of electrostatic field force and other external force, droplet is done directed movement and is adsorbed on each position of target, reaches the good performances such as deposition efficiency is high, float of mist droplet scatters and disappears less, improve the ecological environment.Atomization of liquid mechanism more complicated under electrostatic field, it has been generally acknowledged that: electrostatic interaction can reduce surface tension of liquid, reduces the resistance that atomizes, simultaneously, repulsive interaction generation between the same sex electric charge additional external and internal pressure opposite with surface tension is poor, thereby improves fogging degree.
The droplet charging has three kinds of modes: (1) corona charging method, utilize the electrostatic high-pressure corona to make droplet charged; (2) contact mise-a-la-masse method directly is placed in liquid to the static high voltage, is Charged Droplet after the nozzle ejection; (3) inductive charging method is externally under the voltage electric field action, utilizes the electric field between electrode and medical liquid jet to make droplet charged.
The electrostatic spray technology has the following advantages:
1. electrostatic spray has the effect of outflanking, point effect, penetration effect, and even to the target vegetation, deposition is high.The droplet that electrostatic spray forms is with same sex electric charge, mutually repel in spatial movement, do not condense, the induction of Charged Droplet makes the outside of crop produce the charges of different polarity, under the effect of electric field force, the droplet quick adsorption has improved the deposition of agricultural chemicals on the target crop to the positive and negative of crop, has improved the uniformity of agricultural chemicals deposition.Agricultural chemicals improves more than 36% than conventional spraying at the deposition on crop surface, and leaf back side agricultural chemicals deposition is tens times of conventional spraying, and crop top, middle part and root agricultural chemicals deposition distributing homogeneity all are significantly increased.More much lower than conventional spraying at the deposition that vegetable protecting field adopts electrostatic spray, droplet to drop on the electrical insulator plastic film, can improve the deposition of droplet on plant, effectively utilize agricultural chemicals, reduce drift and be deposited in loss on plastic film.
2. improve the availability of agricultural chemicals, reduce the usage amount of agricultural chemicals, reduce cost accounting.The electrostatic spray droplet size generally about 45 μ m, can reduce mist droplet particle size effectively, improves the spectrum of fog drop uniformity, meets biological optimum grain-diameter theoretical, is easy to be caught by target.When electrostatic potential was 20KV, mist droplet particle size reduced approximately 10%, and the spectrum of fog drop uniformity improves approximately 5%.Significantly increase the chance that droplet contacts with damage by disease and insect, improved exponentially extermination of disease and insect pest effect (improving more than 2 times than conventional spraying under similarity condition).And finish has affinity to insect body wall, is easy to penetrate body wall and enters in pest body, make insect fast in HEXAFLUMURON.Dosage is saved more than 30% than conventional spraying.
3. little to water source, environmental influence, reduced the pollution of agricultural chemicals to environment.The electrostatic spray spouting liquid is few, and every mu is only 60~150mL, is only more than one percent of conventional spraying, and the suction-operated of electric field force reduced the drift of agricultural chemicals, makes the agricultural chemicals availability high, has avoided the agricultural chemicals loss, has reduced the pollution of agricultural chemicals to environment.
4. the electrostatic spray lasting period is long.Charged Droplet is high adsorption capacity on crop, and comprehensively evenly, dispenser efficient is high, and it is firm that agricultural chemicals adheres on leaf, resistance of rainwater washing against, and the high boiling solvent in finish can effectively delay the degraded of pesticide active ingredient, and drug effect is permanent.
5. work efficiency is high, and control in time.The hand-held electrostatic ultra low volume spray improves 10~20 times of work efficiency than conventional spraying, and Dongfanghong-18 type power knapsack electrostatic sprayer per hour can spray 20~30 mu.
6. electrostatic spray adopts supporting electrostatic spray liquor, need not to add water, is particularly suitable for drought and water shortage area use.
7. electrostatic spray is difficult for producing poisoning to crop, without obviously residual, can improve the quality of crop.
Summary of the invention
The purpose of this invention is to provide a kind of electrostatic spray liquor preparation take first dimension salt and HEXAFLUMURON binary composition as active ingredient.
Another object of the present invention is to provide the preparation method of described this electrostatic spray liquor.
This electrostatic spray liquor comprises the component of following weight proportion:
0.1 part~20.0 parts of first dimension salt
0.1 part~10.0 parts of HEXAFLUMURONs
1.0 parts~8.0 parts of conductive agents
1.0 parts~10.0 parts of cosolvents
Solvent complements to 100 parts.
The above composition weight proportion optimization:
1.0 parts~10.0 parts of first dimension salt
5.0 parts~8.0 parts of HEXAFLUMURONs
1.0 parts~5.0 parts of conductive agents
2.0 parts~8.0 parts of cosolvents
Solvent complements to 100 parts.
The cosolvent that is fit to is selected from C
4Above alcohols, cyclohexanone, methyl-sulfoxide, 1-METHYLPYRROLIDONE, preferred methyl-sulfoxide or 1-METHYLPYRROLIDONE.
The conductive agent that is fit to is anion surfactant, as neopelex or calcium dodecyl benzene sulfonate.
The solvent that is fit to is many Fluhyzons, as a line oil, two wires wet goods, heavy aromatics, vegetable oil such as turpentine oil or cottonseed oil, corn wet goods.Preferred two wires oil or the above aromatic hydrocarbons of C10.
Electrostatic spray liquor of the present invention adopts the manner known in the art preparation, normally active ingredient and conductive agent, cosolvent, solvent is fully mixed in proportion and forms.
The binary composition of two kinds of compositions, can not solve the single component result of use good enough and easily produce the problem of resistance, and because first dimension salt is different from action site and the mechanism of action of HEXAFLUMURON, both binary compositions can well reach the effect that mutually makes up with synergy.
The target crop that is fit to is the cereal crops such as paddy rice, wheat, the economic crops such as soybean, peanut, cotton, tea tree, tobacco, the vegetable crops such as tomato, eggplant, capsicum, wild cabbage, Kidney bean, broad bean, cowpea, pea, the fruit tree crops such as grape, oranges and tangerines, apple, pear tree, peach.
Electrostatic spray liquor of the present invention is fit to control rice leaf roller, striped rice borer, wheat mythimna separata, vegetables cabbage caterpillar, diamond-back moth, liriomyza bryoniae, beet armyworm, lima bean pod borer, tea geometrid, the thin moth of tea, tea caterpillar, beautiful green slug moth, tealeaves goitre mite, pink tea rust mite, privet mite, cotton bollworm, soybean pod borer, prodenia litura, beet armyworm, oriental tobacco budworm, phyllocnistis citrella stainton, two spotted spider mite, European red mite, pear sucker, peach fruit borer etc.
The method for optimizing of using electrostatic spray liquor of the present invention is electrostatic spray, and a situation arises determines suitable consumption according to controlling object, and formulation rate is 8~60g a.i./hm usually
2
Electrostatic spray liquor of the present invention is easy to process, with low cost, good drug efficacy, holding effect is long, work efficiency is high; Can reduce environmental pollution, improve the agricultural chemicals availability, reduce the agricultural chemicals usage amount, be suitable for electrostatic spray.
Embodiment
The present invention describes with the following example, but does not limit the scope of the invention.
Embodiment 1:
Prepare 0.2% first dimension salt HEXAFLUMURON electrostatic spray liquor
First dimension salt 0.1kg
HEXAFLUMURON 0.1kg
1-METHYLPYRROLIDONE 2.0kg
Calcium dodecyl benzene sulfonate 1.5kg
Two wires oil complements to 100kg.
First dimension salt and the former medicinal cosolvent of HEXAFLUMURON, solvent are that 1-METHYLPYRROLIDONE, two wires oil dissolve fully, then add other composition calcium dodecyl benzene sulfonates evenly to mix, and can be made into the electrostatic spray liquor after fully stirring.
Step according to identical with embodiment 1 can prepare following examples.
Embodiment 2:
Prepare 2.5% first dimension salt HEXAFLUMURON electrostatic spray liquor
First dimension salt 1.5kg
HEXAFLUMURON 1.0kg
1-METHYLPYRROLIDONE 4.0kg
Neopelex 3.0kg
Two wires oil complements to 100kg.
Embodiment 3:
Prepare 10% first dimension salt HEXAFLUMURON electrostatic spray liquor
First dimension salt 5.0kg
HEXAFLUMURON 5.0kg
Methyl-sulfoxide 4.0kg
Calcium dodecyl benzene sulfonate 4.0kg
C10 aromatic hydrocarbons complements to 100kg.
Embodiment 4:
Prepare 15% first dimension salt HEXAFLUMURON electrostatic spray liquor
First dimension salt 9.0kg
HEXAFLUMURON 6.0kg
1-METHYLPYRROLIDONE 4.0kg
Neopelex 4.0kg
Two wires oil complements to 100kg.
Embodiment 5:
Prepare 25% first dimension salt HEXAFLUMURON electrostatic spray liquor
First dimension salt 18.0kg
HEXAFLUMURON 7.0kg
Methyl-sulfoxide 6.5kg
Calcium dodecyl benzene sulfonate 5.0kg
C10 aromatic hydrocarbons complements to 100kg.
Embodiment 6:
Prepare 40% first dimension salt HEXAFLUMURON electrostatic spray liquor
First dimension salt 20.0kg
HEXAFLUMURON 20.0kg
1-METHYLPYRROLIDONE 10.0kg
Neopelex 5.0kg
Two wires oil complements to 100kg.
Prepared first dimension salt HEXAFLUMURON electrostatic spray liquor outward appearance is transparent homogeneous oily liquids; The low-temperature phase capacitive is good, and under-5 ℃, refrigeration 7d is crystallization or suspension not; Volatility is low, filter paper suspension method measurement result, and volatility is lower than 30%; To plant safety, without poisoning; The employing method of remaining silent is measured, and flash-point is greater than 70 ℃; Viscosity is below 10mPas; Electrical conductivity (μ Ω cm
-1) 1~10
-3Between.
Claims (4)
1. a first is tieed up salt and HEXAFLUMURON binary composition electrostatic spray liquor, it is characterized in that comprising the component of following weight proportion: 0.1 part~20.0 parts of first dimension salt; 0.1 part~20.0 parts of HEXAFLUMURONs; Conductive agent is selected from anion surfactant: 1.0 parts~8.0 parts of neopelex or calcium dodecyl benzene sulfonates; Cosolvent is selected from the above alcohols of C4, cyclohexanone, methyl-sulfoxide, or 1.0 parts~10.0 parts of 1-METHYLPYRROLIDONEs; Solvent is selected from many Fluhyzons, heavy aromatics, or vegetable oil complements to 100 parts.
2. first dimension salt according to claim 1 and HEXAFLUMURON binary composition electrostatic spray liquor, is characterized in that described composition weight proportioning: 1.0 parts~10.0 parts of first dimension salt; 5.0 parts~10.0 parts of HEXAFLUMURONs; Conductive agent is selected from anion surfactant: 1.0 parts~5.0 parts of neopelex or calcium dodecyl benzene sulfonates; Cosolvent is selected from the above alcohols of C4, cyclohexanone, methyl-sulfoxide, or 2.0 parts~8.0 parts of 1-METHYLPYRROLIDONEs; Solvent is selected from many Fluhyzons, heavy aromatics, or vegetable oil complements to 100 parts.
3. first according to claim 1 and 2 is tieed up salt and HEXAFLUMURON binary composition electrostatic spray liquor, and it is characterized in that: cosolvent is methyl-sulfoxide or 1-METHYLPYRROLIDONE.
4. first according to claim 1 and 2 is tieed up salt and HEXAFLUMURON binary composition electrostatic spray liquor, and it is characterized in that: described solvent is two wires oil or the above aromatic hydrocarbons of C10.
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1058505A (en) * | 1991-09-14 | 1992-02-12 | 中国国际科技促进会保康新技术研究所 | The prescription of electrostatically sprayed pesticide oil preparation |
CN1480040A (en) * | 2003-07-23 | 2004-03-10 | 福建新农大正生物工程有限公司 | Lethane of methylamino avermectin benzoate-Hexaflumuron |
-
2010
- 2010-08-25 CN CN 201010262512 patent/CN101946764B/en not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1058505A (en) * | 1991-09-14 | 1992-02-12 | 中国国际科技促进会保康新技术研究所 | The prescription of electrostatically sprayed pesticide oil preparation |
CN1480040A (en) * | 2003-07-23 | 2004-03-10 | 福建新农大正生物工程有限公司 | Lethane of methylamino avermectin benzoate-Hexaflumuron |
Non-Patent Citations (4)
Title |
---|
2.5%氟铃脲.甲氨基阿维菌素苯甲酸盐微乳剂的研制;王同涛等;《农药科学与管理》;20061231;第27卷(第6期);36-38 * |
应用静电喷雾技术防治小麦蚜虫;杨宝芳等;《天津农林科技》;20000430(第2期);第19-20页第2节 * |
杨宝芳等.应用静电喷雾技术防治小麦蚜虫.《天津农林科技》.2000,(第2期),第19-20页第2节. |
王同涛等.2.5%氟铃脲.甲氨基阿维菌素苯甲酸盐微乳剂的研制.《农药科学与管理》.2006,第27卷(第6期),36-38. |
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