CN101914246A - Regenerated butyl mixing rubber for high-speed vacuum tyre airtight layer and process method thereof - Google Patents

Regenerated butyl mixing rubber for high-speed vacuum tyre airtight layer and process method thereof Download PDF

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Publication number
CN101914246A
CN101914246A CN 201010259160 CN201010259160A CN101914246A CN 101914246 A CN101914246 A CN 101914246A CN 201010259160 CN201010259160 CN 201010259160 CN 201010259160 A CN201010259160 A CN 201010259160A CN 101914246 A CN101914246 A CN 101914246A
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China
Prior art keywords
rubber
butyl
regenerated
mixing
airtight layer
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CN 201010259160
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Chinese (zh)
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孙晓冬
焦红梅
郭夕军
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JIANGSU DONGXU TECHNOLOGY Co Ltd
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JIANGSU DONGXU TECHNOLOGY Co Ltd
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Abstract

The invention relates to regenerated butyl mixing rubber for a high-speed vacuum tyre airtight layer and a process method thereof. The regenerated butyl mixing rubber is characterized by comprising the following raw materials in percentage by weight: 45-60 percent of vulcanized butyl rubber, 20-35 percent of halogenated butyl rubber, 5-10 percent of resin and 1-5 percent of softening agent. The process method for producing the regenerated butyl mixing rubber for the high-speed vacuum tyre airtight layer comprises the steps of pretreating, crushing, regenerating, tabletting, matching and mixing, filtering, refining, forming and packaging the raw materials; and the process regeneration step comprises the following specific steps of: pouring the weighted rubber granules into a kneading chamber; starting a host machine to rotate a rotor for stirring and shearing; and maintaining the temperature of the kneading chamber at 200-250DEG C, and controlling the stirring time for 25-40 minutes. The rubber granules are the vulcanized butyl rubber and the halogenated butyl rubber, the softening agent is paraffin softening oil and the regeneration process is carried out for one time.

Description

High-speed vacuum tyre airtight layer regenerated butyl mixing rubber and processing method thereof
Technical field
The present invention relates to a kind of rubber, the regenerated butyl mixing rubber that especially a kind of high-speed vacuum tyre airtight layer is used.
The invention still further relates to the production method of a kind of high-speed vacuum tyre airtight layer with regenerated butyl mixing rubber.
Background technology
The develop rapidly of Domestic Automotive Industry, increasing to the demand of rubber tyre.Because the vacuum tire is all even better than conventional tyre on security, reliability, but also has characteristics in light weight, good heat dissipation, comprehensive cost is also low, therefore also obtains more and more people's approval.Along with the raising of China's road conditions and perfecting of vacuum tire adequate and systematic service facility, the vacuum tire will be more widely used.To guide Truck Market to step into " lightweight " and control a series of policies such as super, fuel oil tax, in " fuel-economizingization " epoch, the advantage of vacuum tire will be more obvious, and market potential will be excavated gradually, and popularizing the vacuum tire will be the megatrend of development.
The vacuum tire is compared conventional tire, because of its structure has following advantage: the one, it is slow to leak gas, and safe vacuum tire is pierced back gas leakage slowly, still can adhere to reaching the place under repair of repairing point; The conventional tyre inner tube of a tyre is full of gas rapidly after being pierced through by foreign matter between the inner tube of a tyre and cover tire, flat tire even moment can take place immediately might blow out.The 2nd, thermal diffusivity is good, life-span, long vacuum tire did not have the inner tube of a tyre and rim strip, the inner tube of a tyre and the tyre cavity frictional heat of tire have been reduced effectively, inner air directly contacts with wheel rim, heat also can directly distribute by wheel rim, the too high phenomenon of tyre temperature can not occur, can reduce and blow out, prolong tire work-ing life.The 3rd, weight reduction, oil consumption reduces owing to reduced the inner tube of a tyre and rim strip, the weight saving of tire, and the spare part of wheel rim has also reduced retainer, weight further alleviates, a whole set of tire all changes the vacuum tire into can light good hundreds of jin, and the running resistance of vacuum tire is less, can save 3% fuel oil, the travel deadweight and the minimizing of oil consumption are exactly extra profit concerning the truck driver.The 4th, wear-resisting, be fit to long-distance running at high speed in addition, the vacuum tire is more wear-resisting, and has better dynamic balance performance, and driver comfort also can improve, and therefore is more suitable for long-distance high speed and travels for a long time.
Summary of the invention
The purpose of this invention is to provide a kind of high-speed vacuum tyre airtight layer regenerated butyl mixing rubber, this rubber has that resistance to air loss is good, bond properties is good, feature that can covulcanization during tyre vulcanization.
The technical solution used in the present invention is:
A kind of high-speed vacuum tyre airtight layer regenerated butyl mixing rubber, its raw materials by weight is: vulcanized butyl rubber 45-60%; Halogenated butyl rubber 20-35%; Resin 5-10%; Tenderizer 1-5%.
Produce the processing method of high-speed vacuum tyre airtight layer with regenerated butyl mixing rubber, comprise that raw materials pretreatment, pulverizing, regeneration, compressing tablet, cooperation are mixing, filtration, concise and formed package, described technology regenerated step is: it is indoor that the rubber grain of weighing is poured into kneading, start the main frame rotary rotor and stir shearing, the indoor temperature of kneading remains on 200-250 ℃, and churning time was controlled at 25-40 minute.
Described rubber grain is vulcanized butyl rubber and halogenated butyl rubber, and described tenderizer is the paraffin wax softening oil, and described technology regenerated number of times is for once.
The invention has the advantages that: by the adjustment of prescription, proportioning, realization can be satisfied the bubble-tight requirement of vacuum tire, with natural rubber, synthetic rubber good bond properties is arranged, can covulcanization high-speed vacuum tyre airtight layer regenerated butyl mixing rubber during tyre vulcanization.
Description of drawings
Below in conjunction with the drawings and specific embodiments the present invention is described in further detail.
Fig. 1 is a normal conventional rubber for tire damping curve.
Fig. 2 is a vacuum tire rubber damping curve of the present invention.
Embodiment
Embodiment 1
Regenerated butyl mixing rubber, its raw materials by weight proportioning is: vulcanized butyl rubber 50%; Halogenated butyl rubber 35%; Resin 10%; Tenderizer paraffin wax softening oil 5%.
Produce the processing method of high-speed vacuum tyre airtight layer, at first carry out raw materials pretreatment: will reject the non-butyl rubber composition as the waste butyl rubber of raw material, and classify then, clean, and remove impurity such as silt with regenerated butyl mixing rubber.The 2nd, pulverize: the waste butyl rubber raw material after will clearing up, carry out fragmentation with the open rubber breaker of a ditch one light, fineness is the 5-10 order.The 3rd, regeneration: it is indoor that the rubber grain of weighing is poured into kneading, closes upper top cover, starts main frame, and rotary rotor stirs, shearing.200-250 ℃ of kneading chambers temp, the time was at 25-40 minute.Open top cover, upset kneading chamber is poured the good rubber of regeneration in the pond into, and the pond is removed in the kneading chamber that resets, and continues reinforced next machine sizing material of producing.The 4th, compressing tablet: the sizing material after the regeneration is cooled in water below 100 ℃, proposes sizing material and overturning and goes on the conveying belt, is delivered to mill and wraps roller and turn refining, and treats after the sizing material surfacing sheet down.The 5th, cooperate mixing: the sizing material after compressing tablet is parked is according to above-mentioned formula rate weighing and proportioning, at mixer mixing, add resin and paraffin wax softening oil, on rubber mixing machine, turn refining after the discharging, about turn over glue, play the triangle bag, the 6th, filter: the sizing material after turning refining is delivered to the feed mill of rubber strainer, 5-8mm left and right sides roll spacing bag roller heat refining, be split into the adhesive tape of 15-20mm simultaneously, supply with rubber strainer continuously, according to the filter screen that different meshes is installed on the customer requirement rubber strainer head by conveying belt.This operation be before concise impurity in the rubber after the regeneration (grains of sand that unclear assorted glue, metal, the cleaning of desulfurization is unclear etc.), prevent some impurity pulverized by scouring machine after more difficult leaching.The 7th, concise: the rubber after the filtration is delivered to mill, 5-8mm left and right sides roll spacing bag roller heat refining.The adhesive tape that is split into then about 5mm is transported to the concise slice of batching of each scouring machine continuously, and the roll spacing of refiner is at 0.1-0.2mm.The 8th, formed package: this operation is divided two kinds, and a kind of is that scouring machine batches moulding, and weighing and bagging is put on the shelf; Another kind is that fineness requirement is higher, do not batch after concise, send the mill bag roller of feed again to by conveying belt, 5-8mm left and right sides roll spacing heat refining, be split into the adhesive tape of 15-20mm, supply with rubber strainer continuously, filter glue once more with 80-100 purpose filter screen by conveying belt, head is extruded the blob of viscose into square, at conveying belt cooling back cutting weighing and bagging.
Embodiment 2
Regenerated butyl mixing rubber, its raw materials by weight proportioning is: vulcanized butyl rubber 55%; Halogenated butyl rubber 33%; Resin 8%; Tenderizer paraffin wax softening oil 4%.Producing high-speed vacuum tyre airtight layer uses the processing method of regenerated butyl mixing rubber with shown in the embodiment 1.
Embodiment 3
Regenerated butyl mixing rubber, its raw materials by weight proportioning is: vulcanized butyl rubber 60%; Halogenated butyl rubber 28%; Resin 7%; Tenderizer paraffin wax softening oil 5%.Producing high-speed vacuum tyre airtight layer uses the processing method of regenerated butyl mixing rubber with shown in the embodiment 1.
Carry out moulding, end properties that is drawn such as following table according to embodiment 1,2 and 3 by above technology:
According to GB GB/P13460-2003 test rating:
Figure BSA00000237923500051
By last Biao Kede, by the high-speed vacuum tyre airtight layer regenerated butyl mixing rubber that the present invention makes, tensile strength at yield than GB exceed 0.5MPa, tensile yield exceeds 70% than GB, density is than the low 0.01g/CM of GB 3, water content is lower by 0.3% than GB, and the ash rate GB is hanged down 3 left and right sides %, and the acetone extracting is than GB low 6.5%.Above digital proof: the present invention has the advantage that resistance to air loss is good, bond properties is good.
The present invention has carried out air retaining wall isoprene-isobutylene rubber buffering subsidence ratio, and the present invention and normal conventional rubber for tire are compared.Fig. 1 is a normal conventional rubber for tire damping curve, and Fig. 2 is a vacuum tire rubber damping curve of the present invention.
Normal conventional rubber for tire damping curve, damping peak value dissipation factor tan δ is 1.0, after 40 ℃, tan δ is 0.3; Vacuum tire rubber damping curve of the present invention, damping peak value dissipation factor tan δ is 1.4, after 40 ℃, tan δ reaches 0.5.Above digital proof: the present invention has the advantage that resistance to air loss is good, bond properties is good.

Claims (4)

1. a high-speed vacuum tyre airtight layer regenerated butyl mixing rubber is characterized in that its raw materials by weight is: vulcanized butyl rubber 45-60%; Halogenated butyl rubber 20-35%; Resin 5-10%; Tenderizer 1-5%.
2. produce the processing method of high-speed vacuum tyre airtight layer with regenerated butyl mixing rubber, comprise that raw materials pretreatment, pulverizing, regeneration, compressing tablet, cooperation are mixing, filtration, concise and formed package, it is characterized in that described technology regenerated step is: it is indoor that the rubber grain of weighing is poured into kneading, start the main frame rotary rotor and stir shearing, the indoor temperature of kneading remains on 200-250 ℃, and churning time was controlled at 25-40 minute.
3. production high-speed vacuum tyre airtight layer according to claim 2 is characterized in that with the processing method of regenerated butyl mixing rubber described rubber grain is vulcanized butyl rubber and halogenated butyl rubber, and described tenderizer is the paraffin wax softening oil.
4. production high-speed vacuum tyre airtight layer according to claim 2 is with the processing method of regenerated butyl mixing rubber, and the number of times that it is characterized in that described regenerative process is for once.
CN 201010259160 2010-08-23 2010-08-23 Regenerated butyl mixing rubber for high-speed vacuum tyre airtight layer and process method thereof Pending CN101914246A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106188906A (en) * 2016-08-30 2016-12-07 昆明云仁轮胎制造有限公司 A kind of rubber composition and preparation method and application

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0711642A2 (en) * 1994-09-28 1996-05-15 The Goodyear Tire & Rubber Company Tire curing bladder with improved release from the tire innerliner
CN101239493A (en) * 2006-10-19 2008-08-13 固特异轮胎和橡胶公司 Curing bladder with release layer
CN101376719A (en) * 2007-08-27 2009-03-04 江苏东旭科技有限公司 Isobutene-diene rubber regeneration process

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0711642A2 (en) * 1994-09-28 1996-05-15 The Goodyear Tire & Rubber Company Tire curing bladder with improved release from the tire innerliner
CN101239493A (en) * 2006-10-19 2008-08-13 固特异轮胎和橡胶公司 Curing bladder with release layer
CN101376719A (en) * 2007-08-27 2009-03-04 江苏东旭科技有限公司 Isobutene-diene rubber regeneration process

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106188906A (en) * 2016-08-30 2016-12-07 昆明云仁轮胎制造有限公司 A kind of rubber composition and preparation method and application
CN106188906B (en) * 2016-08-30 2018-08-14 昆明云仁轮胎制造有限公司 A kind of rubber composition and the preparation method and application thereof

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Application publication date: 20101215