CN101913773A - Ultra-white float glass plated with anti-reflective coating and used for packaging solar battery assembly - Google Patents

Ultra-white float glass plated with anti-reflective coating and used for packaging solar battery assembly Download PDF

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Publication number
CN101913773A
CN101913773A CN 201010242331 CN201010242331A CN101913773A CN 101913773 A CN101913773 A CN 101913773A CN 201010242331 CN201010242331 CN 201010242331 CN 201010242331 A CN201010242331 A CN 201010242331A CN 101913773 A CN101913773 A CN 101913773A
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CN
China
Prior art keywords
ultra
float glass
white float
antireflection coatings
light antireflection
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Pending
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CN 201010242331
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Chinese (zh)
Inventor
林金锡
唐敦乙
林书铨
王国祥
丁怀欣
贾磊
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CHANGZHOU ALMADEN STOCK Co Ltd
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CHANGZHOU ALMADEN STOCK Co Ltd
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Priority to CN 201010242331 priority Critical patent/CN101913773A/en
Publication of CN101913773A publication Critical patent/CN101913773A/en
Pending legal-status Critical Current

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Abstract

The invention relates to a solar battery, in particular to ultra-white float glass plated with an anti-reflective coating and used for packaging a solar battery assembly, which is suitable for manufacturing crystalline silicon solar battery assemblies. The ultra-white float glass comprises an ultra-white float glass substrate (1), the upper surface and the lower surface of the ultra-white float glass substrate (1) are planes, and the upper surface of the ultra-white float glass substrate (1) is provided with a light anti-reflective coating (2). The invention has the advantages of low cost, simple manufacturing process, high cost performance, favorable weathering resistance and favorable transmission of light and can ensure that the power increment of a solar assembly is higher. When one layer of the light anti-reflective coating is arranged on the upper surface of the ultra-white float glass substrate, the light transmittance can be increased by more than 1.8% based on 91-91.5%; and when two layers of the light anti-reflective coating are arranged on the upper surface of the ultra-white float glass substrate, the light transmittance can be increased by more than 2.5% based on 91-91.5%. The invention has very high cost performance.

Description

The ultra-white float glass of plated with anti-reflective coating and used for packaging solar battery assembly
Technical field
The present invention relates to a kind of solar cell, particularly a kind of ultra-white float glass of plated with anti-reflective coating and used for packaging solar battery assembly is the cover-plate glass of encapsulation usefulness in the crystal silicon solar battery component, is suitable for the manufacturing of crystal silicon solar battery component.
Background technology
Solar utilization technique is a popular direction of energy science emphasis research and development in this century, and the photovoltaic industry is just increasing with bigger speed, but the practical problems that present photovoltaic generation is difficult to promote the use of is that price is too high.Therefore, reduce the cost of solar electrical energy generation, the wherein crucial cost that just reduces solar module promptly needs research how reasonably to select material therefor, improves generating efficiency.Utilize sun power to generate electricity now in the world, the element that carries out opto-electronic conversion is a solar cell, and solar cell making process technology comparative maturity, the photovoltaic energy conversion efficiency ratio is higher, generally adopt at present and scale operation mainly be crystal silicon solar energy battery.Crystal silicon solar cell sheet will be assembled into assembly, could set up into large-scale solar power plant.Large-sized solar module encapsulation must be used cover-plate glass.The cover-plate glass that generally uses is that one side is pressed with than the deep-treaded energy ultrawhite figured glass now, in order further to increase the transmittance of sunlight, generally is coated with the light antireflection coatings on the no decorative pattern surface of energy ultrawhite figured glass.But there is following defective in the cover-plate glass of making of energy ultrawhite figured glass at present: complex manufacturing technology, and the cost height, cost performance is low.The manufacturing of energy ultrawhite figured glass is after sheet glass control moulding, but glass rolls glass surface with the steel rider that has special decorative pattern when still unhardened, forms the glass that is pressed with decorative pattern with definite shape, complex manufacturing technology, cost height.The original idea that makes glass surface form decorative pattern is to want to utilize the multiple reflection of sunlight in decorative pattern to increase the incident total amount of light, and this sets up in theory fully.But, now in the production of solar module, on the sheet glass that face of embossing not towards the sun, but towards cell panel, and and the EVA film bond together.Heat when battery panel components passes through the lamination stove, EVA melts, and both merge, the existence that this moment, basic naked eyes can not differentiated the glass decorative pattern, so the due extraordinary light transmission of energy ultrawhite figured glass is had a greatly reduced quality, and the light transmission reduction, cost performance descends.And another dull and stereotyped ultra-white float glass is compared with energy ultrawhite figured glass, though manufacture craft is simple, cost is low, but because dull and stereotyped ultra-white float glass transmittance is low, the power increasing amount is not high, global index is than energy ultrawhite figured glass difference, exist a lot of deficiencies, thereby dull and stereotyped ultra-white float glass is being made on the encapsulation cover plate and can't applied.Thereby will develop the used for packaging solar battery assembly cover-plate glass that a kind of manufacture craft is simple, cost is low, cost performance is high, transmittance is good is a very urgent and long-term insoluble technical barrier.
Summary of the invention
The objective of the invention is at the deficiencies in the prior art, provide that a kind of cost is low, manufacture craft is simple, cost performance is high, the ultra-white float glass of good weatherability, plated with anti-reflective coating and used for packaging solar battery assembly that light transmission power increasing amount good, that can make solar components is higher.
The technical scheme that realizes above-mentioned purpose is: a kind of ultra-white float glass of plated with anti-reflective coating and used for packaging solar battery assembly, comprise the ultra-white float glass substrate, the upper surface and the lower surface of ultra-white float glass substrate are the plane, are provided with the light antireflection coatings on the upper surface of ultra-white float glass substrate.
Further, the light antireflection coatings material of outermost one deck is a nano silicon in the light antireflection coatings.
Further, described light antireflection coatings is one deck, and the thickness of one deck light antireflection coatings is 50nm~250nm.
Further, described light antireflection coatings is two-layer, and the thickness of two-layer light antireflection coatings is 20nm~250nm.
Further, the material of the light antireflection coatings of middle one deck is any in nano titanium oxide or the nano zirconium dioxide, perhaps is the mixture of nano titanium oxide and nano zirconium dioxide.
Adopt technical scheme of the present invention, have the following advantages: cost of the present invention is low, and manufacture craft is simple, the cost performance height, and good weatherability, light transmission is good, can make the power increasing amount of solar components higher.The present invention has remedied widely used energy ultrawhite figured glass cost height in the existing solar module packaged glass, complex manufacturing technology, the deficiency that cost performance is high, also avoided existing dull and stereotyped ultra-white float glass transmittance low, the not high defective of power increasing amount, the present invention is the ultra-white float glass substrate that adopts the flat board of not embossing, the upper surface and the lower surface that are the ultra-white float glass substrate are the plane, not embossing, this ultra-white float glass substrate transmittance is 91%~91.5%, raw material is easy to get, raw materials cost is low, the present invention is that the upper surface at the ultra-white float glass substrate is provided with the light antireflection coatings, light antireflection coatings hardness height, adhere to firmly good weatherability with the ultra-white float glass substrate.With the present invention during as the packaged glass of solar module, the present invention not only can be bonding well with the EVA film, and the light antireflection coatings above the upper surface of ultra-white float glass substrate plays antireflective effect to light among the present invention, has improved transmittance.The present invention has saved a lot of operations of embossing ultra-clear glasses embossing in the prior art, and manufacture craft is simple, and cost is low, thereby the cost of solar module is also reduced thereupon greatly.When the upper surface of ultra-white float glass substrate is installed towards sunlight, it is the plane of incidence of light, after the light antireflection coatings is set on the upper surface of ultra-white float glass substrate, the light antireflection coatings is one deck, transmittance of the present invention can increase more than 1.8% on 91%~91.5% basis, the light antireflection coatings is two layers, and transmittance can increase more than 2.5% on 91%~91.5% basis.Encapsulate solar module with the present invention, can so that battery panel components in the horsepower output increasing amount after the opto-electronic conversion more than 2.5%.For powerful solar module, its power increasing amount has bigger value.Cost performance of the present invention is very high, is convenient to realize industrialization, large-scale production.
Description of drawings
Accompanying drawing is a structural representation of the present invention.
Embodiment
The present invention is further detailed explanation below by embodiment.
Embodiment one
As shown in drawings, a kind of ultra-white float glass of plated with anti-reflective coating and used for packaging solar battery assembly, comprise ultra-white float glass substrate 1, the upper surface a face of ultra-white float glass substrate 1 and lower surface b face are the plane, but not embossing face applies on the upper surface a of ultra-white float glass substrate 1 face and is set with light antireflection coatings 2.The upper surface a face of ultra-white float glass substrate 1 is towards sunlight during installation.Light antireflection coatings 2 is one deck, and the thickness of one deck light antireflection coatings 2 is 140nm, and the material of one deck light antireflection coatings 2 is a nano silicon.Because have only one deck light antireflection coatings 2, so light antireflection coatings 2 is the light antireflection coatings 2-1 of outermost one deck.
Embodiment two
As shown in drawings, a kind of ultra-white float glass of plated with anti-reflective coating and used for packaging solar battery assembly, comprise ultra-white float glass substrate 1, the upper surface a face of ultra-white float glass substrate 1 and lower surface b face are the plane, but not embossing face applies on the upper surface of ultra-white float glass substrate 1 and is set with light antireflection coatings 2.The upper surface a face of ultra-white float glass substrate 1 is towards sunlight during installation.Light antireflection coatings 2 is two-layer, the thickness of two-layer light antireflection coatings 2 is 120nm, the light antireflection coatings 2-1 material of outermost one deck is a nano silicon in the light antireflection coatings 2, and the material of the light antireflection coatings 2-2 of middle one deck is a nano titanium oxide.
Embodiment three
As shown in drawings, basic identical with embodiment one, the thickness of different is one deck light antireflection coatings 2 is 50nm.
Embodiment four
As shown in drawings, basic identical with embodiment one, the thickness of different is one deck light antireflection coatings 2 is 90nm.
Embodiment five
As shown in drawings, basic identical with embodiment one, the thickness of different is one deck light antireflection coatings 2 is 200nm.
Embodiment six
As shown in drawings, basic identical with embodiment one, the thickness of different is one deck light antireflection coatings 2 is 250nm.
Embodiment seven
As shown in drawings, basic identical with embodiment two, different is in the two-layer light antireflection coatings 2 in the light antireflection coatings 2, and the thickness of the light antireflection coatings 2-1 of outermost one deck is 20nm, and the thickness of the light antireflection coatings 2-2 of middle one deck is 250nm.The material of the light antireflection coatings 2-2 of middle one deck is a nano zirconium dioxide.
Embodiment eight
As shown in drawings, basic identical with embodiment two, different is in the two-layer light antireflection coatings 2 in the light antireflection coatings 2, and the thickness of the light antireflection coatings 2-1 of outermost one deck is 95nm, and the thickness of the light antireflection coatings 2-2 of middle one deck is 160nm.The material of the light antireflection coatings 2-2 of middle one deck is the mixture of nano titanium oxide and nano zirconium dioxide.
Embodiment nine
As shown in drawings, basic identical with embodiment two, different is in the two-layer light antireflection coatings 2 in the light antireflection coatings 2, and the thickness of the light antireflection coatings 2-1 of outermost one deck is 180nm, and the thickness of the light antireflection coatings 2-2 of middle one deck is 50nm.
Embodiment ten
As shown in drawings, basic identical with embodiment two, different is in the two-layer light antireflection coatings 2 in the light antireflection coatings 2, and the thickness of the light antireflection coatings 2-1 of outermost one deck is 250nm, and the thickness of the light antireflection coatings 2-2 of middle one deck is 20nm.The material of the light antireflection coatings 2-2 of middle one deck is a nano zirconium dioxide.
When the present invention makes, apply light antireflection coatings 2 and get final product in the upper surface of ultra-white float glass substrate 1 thickness and material and the number of plies on request.
Light antireflection coatings 2 of the present invention is at least one deck, in addition to the implementation, can also make other any numbers of plies such as four layers, five layers, but generally with one deck or two-layer be the best, cost performance is the highest.And when light antireflection coatings 2 is one deck, the best when thickness of light antireflection coatings 2 is 50nm~250nm, when light antireflection coatings 2 is two-layer, the thickness of two-layer light antireflection coatings 2 is the best with 20nm~250nm all, and the thickness of light antireflection coatings 2 can be selected arbitrarily in the optimum value scope and make up.
Embodiments of the invention are a lot, can't be exhaustive, and the technical scheme that all employings are equal to replacement or equivalence replacement formation all belongs to the claimed scope of invention.

Claims (5)

1. the ultra-white float glass of a plated with anti-reflective coating and used for packaging solar battery assembly, comprise ultra-white float glass substrate (1), the upper surface and the lower surface of ultra-white float glass substrate (1) are the plane, it is characterized in that: be provided with light antireflection coatings (2) on the upper surface of ultra-white float glass substrate (1).
2. the ultra-white float glass of plated with anti-reflective coating and used for packaging solar battery assembly according to claim 1 is characterized in that: light antireflection coatings (2-1) material of outermost one deck is a nano silicon in the light antireflection coatings (2).
3. the ultra-white float glass of plated with anti-reflective coating and used for packaging solar battery assembly according to claim 1, it is characterized in that: described light antireflection coatings (2) is one deck, and the thickness of one deck light antireflection coatings (2) is 50nm~250nm.
4. the ultra-white float glass of plated with anti-reflective coating and used for packaging solar battery assembly according to claim 1 is characterized in that: described light antireflection coatings (2) is for two-layer, and the thickness of two-layer light antireflection coatings (2) is 20nm~250nm.
5. the ultra-white float glass of plated with anti-reflective coating and used for packaging solar battery assembly according to claim 4, it is characterized in that: the material of the light antireflection coatings (2-2) of middle one deck is any in nano titanium oxide or the nano zirconium dioxide, perhaps is the mixture of nano titanium oxide and nano zirconium dioxide.
CN 201010242331 2010-08-02 2010-08-02 Ultra-white float glass plated with anti-reflective coating and used for packaging solar battery assembly Pending CN101913773A (en)

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CN 201010242331 CN101913773A (en) 2010-08-02 2010-08-02 Ultra-white float glass plated with anti-reflective coating and used for packaging solar battery assembly

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108321217A (en) * 2018-02-23 2018-07-24 晶科能源科技(海宁)有限公司 Photovoltaic glass and preparation method thereof, solar double-glass assemblies

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101110451A (en) * 2007-06-27 2008-01-23 常州市亚玛顿科技有限公司 Glass plate used for solar cell module packaging
CN101431110A (en) * 2008-10-06 2009-05-13 上海电力学院 Nano-material anti-reflection film with low refractive index
CN201336310Y (en) * 2009-01-26 2009-10-28 河南华美新材料科技有限公司 Single matte surface solar cell glass
CN201424435Y (en) * 2009-05-19 2010-03-17 信义超薄玻璃(东莞)有限公司 super-white photovoltaic glass
CN201825867U (en) * 2010-08-02 2011-05-11 常州亚玛顿股份有限公司 Super-white float glass with plated anti-reflection coating for encapsulating solar battery pack

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101110451A (en) * 2007-06-27 2008-01-23 常州市亚玛顿科技有限公司 Glass plate used for solar cell module packaging
CN101431110A (en) * 2008-10-06 2009-05-13 上海电力学院 Nano-material anti-reflection film with low refractive index
CN201336310Y (en) * 2009-01-26 2009-10-28 河南华美新材料科技有限公司 Single matte surface solar cell glass
CN201424435Y (en) * 2009-05-19 2010-03-17 信义超薄玻璃(东莞)有限公司 super-white photovoltaic glass
CN201825867U (en) * 2010-08-02 2011-05-11 常州亚玛顿股份有限公司 Super-white float glass with plated anti-reflection coating for encapsulating solar battery pack

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108321217A (en) * 2018-02-23 2018-07-24 晶科能源科技(海宁)有限公司 Photovoltaic glass and preparation method thereof, solar double-glass assemblies

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Application publication date: 20101215