Summary of the invention
Goal of the invention: main purpose of the present invention is to overcome the deficiencies in the prior art, a kind of outer lead of ceramic small outline shell and the combined process of base of ceramic are provided, by via metal increasing stacked solder area, thereby strengthen the technology of base of ceramic and outer lead adhesion, the problem of tearing appears in solution outer lead root easily.
Technical scheme: in order to solve the problems of the technologies described above, the present invention has adopted following technical scheme:
The skill that combines of a kind of outer lead of ceramic small outline shell and base of ceramic, it comprises the steps:
(1) position of outer lead to be installed drills through the hole on the pedestal of ceramic package, and through hole is vertical with outer lead;
(2) the lead-in wire installation site forms metallized area with the printing of metallization slurry on base of ceramic;
(3) through hole is metallized;
(4) the ceramic package pedestal is carried out the green cutting, make through hole become the semicolumn groove;
(5) ceramic member and metal line are carried out high temperature co-firing, burning temperature altogether is 1600~1700 ℃, and the burning time is 8~10h altogether;
(6) utilize scolder to weld together outer lead and base of ceramic and get final product, brazing temperature is 800~900 ℃, weld time 1~2h.
The cross section of the through hole in the step (1) is circular, forms the semicolumn groove through step (4).
The diameter of through hole is smaller or equal to the pin widths of outer lead described in the step (1); Width between the outer lead pin itself is very little, if through-hole diameter greater than the pin widths of outer lead, the one, influence the electric capacity of adjacent two lead-in wires between the pins, the 2nd, scolder is excessive during soldering, causes the pins interconnection of adjacent two lead-in wires easily, influences rate of finished products.Described through hole is by numerical control drilling machine or program control puncher moulding.
In the step (2), described metallization slurry is mixed together by the tungsten powder solubilizer of 1.1~1.4 microns of fineness, and tungsten powder accounts for 70~90% of metallization slurry total weight, and solvent accounts for 10~30% of metallization slurry total weight; Described solvent comprises the component of following content: the polyvinyl butyral resin that accounts for solvent total weight 5~15%, account for the butyl carbitol of solvent total weight 30~50%, account for the surfactant of solvent total weight 5~15%, account for the terpineol of solvent total weight 30~50%.
Wherein, described surfactant is the surfactant of N-10 for the model that U.S. Union Carbide Corp produces; Described terpineol is that the model that U.S. imperial crown chemical industry Co., Ltd produces is the terpineol of #318.
In the step (3), to the method realization of via metal employing aperture filler.
In the step (6), the fusing point of described scolder is lower than the fusing point of ceramic member and metal lead wire; Described scolder is for being yellow gold, and content is Ag72Cu28.
Beneficial effect: advantage of the present invention:
(1) the present invention is when soldering, and solid-state scolder is molten into liquid state, trickles at metallized area along outer lead, and in the semicolumn groove, form certain stacked solder, because of its stacked area bigger than existing technology, so when adopting the method, the tensile strength of outer lead is about 3 times of existing combination.
(2) hole wall metallization also plays that bonding region is corresponding with outer lead to be electrically connected effect simultaneously, omits side printing process in the former technology, has improved production efficiency.
(3) the side printing in the existing technology adopts manual mode para-linkage district and outer lead to be electrically connected, and all adopts automation equipment among the present invention, has improved finished product rate and efficient.
Embodiment:
It is base-material that the base of ceramic of ceramic small outline shell adopts 92% aluminium oxide, through operation moulding such as ball milling, batch mixing, curtain coating, punching, forming through holes, printing, hole wall metallization, lamination, cutting, cutting, sintering; Outer lead adopts 4J42 iron-nickel alloy material, through mould punching or etching method moulding; Base of ceramic soldering and outer lead weld with the Ag72Cu28 silver-copper brazing alloy.
Among the following embodiment, surfactant N-10 is available from U.S. Union Carbide Corp (U.S. Union Carbide), and the #318 terpineol is available from U.S. imperial crown chemical industry Co., Ltd (U.S. Crown chemica).
Embodiment 1:
(1) position of outer lead to be installed drills through the hole on the pedestal of ceramic package, and through hole is vertical with outer lead, and through hole is a manhole, and the diameter of through hole is smaller or equal to the pin widths of outer lead; Through hole is by numerical control drilling machine or program control puncher moulding, and the through hole hole wall is smooth, does not have broken porcelain particle.
(2) the lead-in wire installation site forms metallized area with the printing of metallization slurry on base of ceramic.In the step (2), described metallization slurry is mixed together by the tungsten powder solubilizer of 1.3 microns of fineness, and tungsten powder accounts for 80% of metallization slurry total weight, and solvent accounts for 20% of metallization slurry total weight;
Described solvent comprises the component of following content: account for the polyvinyl butyral resin of solvent total weight 10%, account for the butyl carbitol of solvent total weight 40%, account for the surfactant of solvent total weight 10%, account for the terpineol of solvent total weight 40%.
(3) through hole is metallized; Via metal employing aperture filler is realized that uniformity is answered in the through-hole wall hanging, should not have too much damaged (causing disconnection or formation layering between the levels), do not have and obviously pile up or the obstruction through hole; Should avoid the pollution between the two adjacent through holes simultaneously in order to avoid cause short circuit or decreasing insulating.
(4) the ceramic package pedestal is carried out the green cutting, make through hole become the semicolumn groove;
(5) ceramic member and metal line are carried out high temperature co-firing, burning temperature altogether is 1640 ℃, and the time is 8 hours.
(6) outer lead and base of ceramic are utilized the yellow gold welding, yellow gold content is Ag72Cu28.Brazing temperature is 850 ℃, and the time is 1 hour.In welding process, the semicolumn groove that melting solder trickles naturally and forms to through hole.
Embodiment 2:
(1) position of outer lead to be installed drills through the hole on the pedestal of ceramic package, and through hole is vertical with outer lead, and through hole is a manhole, and the diameter of through hole is smaller or equal to the pin widths of outer lead; Through hole is by numerical control drilling machine or program control puncher moulding, and the through hole hole wall is smooth, does not have broken porcelain particle.
(2) the lead-in wire installation site forms metallized area with the printing of metallization slurry on base of ceramic.In the step (2), described metallization slurry is mixed together by the tungsten powder solubilizer of 1.2 microns of fineness, and tungsten powder accounts for 70% of metallization slurry total weight, and solvent accounts for 30% of metallization slurry total weight;
Described solvent comprises the component of following content: account for the polyvinyl butyral resin of solvent total weight 5%, account for the butyl carbitol of solvent total weight 45%, account for the surfactant of solvent total weight 8%, account for the terpineol of solvent total weight 42%.
(3) through hole is metallized; Via metal employing aperture filler is realized that uniformity is answered in the through-hole wall hanging, should not have too much damaged (causing disconnection or formation layering between the levels), do not have and obviously pile up or the obstruction through hole; Should avoid the pollution between the two adjacent through holes simultaneously in order to avoid cause short circuit or decreasing insulating.
(4) the ceramic package pedestal is carried out the green cutting, make through hole become the semicolumn groove;
(5) ceramic member and metal line are carried out high temperature co-firing, burning temperature altogether is 1600 ℃, and the time is 9 hours;
(6) outer lead and base of ceramic are utilized the yellow gold welding, yellow gold content is Ag72Cu28.Brazing temperature is 800 ℃, and the time is 1.5 hours.In welding process, the semicolumn groove that melting solder trickles naturally and forms to through hole.
Embodiment 3:
(1) position of outer lead to be installed drills through the hole on the pedestal of ceramic package, and through hole is vertical with outer lead, and through hole is a manhole, and the diameter of through hole is smaller or equal to the pin widths of outer lead; Through hole is by numerical control drilling machine or program control puncher moulding, and the through hole hole wall is smooth, does not have broken porcelain particle.
(2) the lead-in wire installation site forms metallized area with the printing of metallization slurry on base of ceramic.In the step (2), described metallization slurry is mixed together by the tungsten powder solubilizer of 1.4 microns of fineness, and tungsten powder accounts for 90% of metallization slurry total weight, and solvent accounts for 10% of metallization slurry total weight;
Described solvent comprises the component of following content: account for the polyvinyl butyral resin of solvent total weight 12%, account for the butyl carbitol of solvent total weight 43%, account for the surfactant of solvent total weight 15%, account for the terpineol of solvent total weight 30%.
(3) through hole is metallized; Via metal employing aperture filler is realized that uniformity is answered in the through-hole wall hanging, should not have too much damaged (causing disconnection or formation layering between the levels), do not have and obviously pile up or the obstruction through hole; Should avoid the pollution between the two adjacent through holes simultaneously in order to avoid cause short circuit or decreasing insulating.
(4) the ceramic package pedestal is carried out the green cutting, make through hole become the semicolumn groove;
(5) ceramic member and metal line are carried out high temperature co-firing, burning temperature altogether is 1700 ℃, and the time is 10 hours;
(6) outer lead and base of ceramic are utilized the yellow gold welding, yellow gold content is Ag72Cu28.Brazing temperature is 900 ℃, and the time is 2 hours.In welding process, the semicolumn groove that melting solder trickles naturally and forms to through hole.