CN101898924A - Starting mix of solid oxygen generator - Google Patents

Starting mix of solid oxygen generator Download PDF

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Publication number
CN101898924A
CN101898924A CN2009102270540A CN200910227054A CN101898924A CN 101898924 A CN101898924 A CN 101898924A CN 2009102270540 A CN2009102270540 A CN 2009102270540A CN 200910227054 A CN200910227054 A CN 200910227054A CN 101898924 A CN101898924 A CN 101898924A
Authority
CN
China
Prior art keywords
powder
starting mix
oxygen generator
zirconium
solid oxygen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN2009102270540A
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Chinese (zh)
Other versions
CN101898924B (en
Inventor
王海云
周祯德
雷勇涛
刘燕
许炳
黄求安
黄果
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangnan Industries Group Co Ltd
Original Assignee
JIANGNAN MACHINERY (GROUP) CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JIANGNAN MACHINERY (GROUP) CO Ltd filed Critical JIANGNAN MACHINERY (GROUP) CO Ltd
Priority to CN2009102270540A priority Critical patent/CN101898924B/en
Publication of CN101898924A publication Critical patent/CN101898924A/en
Application granted granted Critical
Publication of CN101898924B publication Critical patent/CN101898924B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Abstract

The invention discloses a starting mix of a solid oxygen generator, belonging to the technical field of explosives. The starting mix of the invention is mainly suitable for quickly igniting an oxygen generating grain to generate oxygen when the solid oxygen generator is impacted and ignited, and has the main technical characteristic of comprising the following components in percentage by weight: 40-70 of ferric oxide, 5-25 of zirconium powder, 10-30 of zirconium hydride, 1-15 of kieselguhr and 1-10 of shellac varnish, wherein the zirconium powder is substituted for magnesium powder, and the ferric oxide is substituted for barium nitrate and barium peroxide as oxidizers. The starting mix has the characteristics of moisture protection, water resistance, oxidation protection and the like, has good ignition property and safety, and can meet the requirement of long-term storage of products.

Description

Starting mix of solid oxygen generator
Technical field
The present invention relates to a kind of starting mix of solid oxygen generator, belong to fiery explosive technical field, quick igniting system oxygen powder column produced oxygen when it mainly was applicable to solid oxygen generator percussion igniting.
Background technology
In background technology, starting mix in the present domestic solid oxygen generator generally all is to be main raw material with the magnesium powder, oxygenant adopts nitrate of baryta and barium peroxide, owing to limited by its composition, cause it to have the unsettled major defect of ignition characteristic, nitrate of baryta as oxygenant exists the easy moisture absorption rotten simultaneously, and there is problems such as easily decomposing instability in barium peroxide, can not satisfy the requirement of product standing storage.For overcoming these defectives, starting mix of solid oxygen generator is developed.
Summary of the invention
Technical problem to be solved by this invention provides a kind of starting mix of solid oxygen generator, it substitutes the magnesium powder with zirconium powder, makes oxygenant with alternative nitrate of baryta of ferric oxide and barium peroxide, and it can effectively improve the static sparking sensitivity, ignition characteristic and security are good, can satisfy the requirement of standing storage.
The technical scheme that the present invention solves its technical problem employing is that it is by following composition
Ferric oxide 40~70
Zirconium powder 5~25
Zircoium hydride 10~30
Diatomite 1~15
Shellac varnish 1~10
Weight percent form.
The present invention compares the beneficial effect that is produced with prior art
1, because with the alternative magnesium powder of zirconium powder, the zircoium hydride that contains in the zirconium powder can reduce the mechanical sensitivity of starting mix, the flare point of raising zirconium powder is beneficial to burning and difficult the generation exploded, and security is good.
2,,, can satisfy the long storage of product requirement so starting mix of solid oxygen generator of the present invention has moisture proof, waterproof, anti-oxidation characteristics because of ferric oxide stable in properties as oxygenant.
3, because the mechanical sensitivity of starting mix of solid oxygen generator of the present invention is lower, the static flame sensitivity is reduced, ignition characteristic is good.
Description of drawings
Fig. 1 is a process flow sheet of making starting mix of solid oxygen generator tablet of the present invention.
Embodiment
Prescription one
Chemical name English name Molecular formula State Weight percent %
Ferric oxide Ferric?oxide? Fe 2O 3 Powder 52?
Zirconium powder Zirconium?powder Zr? Ultrafine powder 18?
Zircoium hydride Zirconium?hydride ZrH 2 Ultrafine powder 16?
Diatomite diatomite? /? Powder 8?
Shellac varnish Shellac?paint? /? Liquid 6?
Prescription two
Chemical name English name Molecular formula State Weight percent %
Ferric oxide Ferric?oxide? Fe 2O 3 Powder 58?
Zirconium powder Zirconium?powder Zr? Ultrafine powder 12?
[0019]?
Zircoium hydride Zirconium?hydride ZrH 2 Ultrafine powder 18?
Diatomite diatomite? /? Powder 10?
Shellac varnish Shellac?paint? /? Liquid 2?
Prescription three
Chemical name English name Molecular formula State Weight percent %
Ferric oxide Ferric?oxide? Fe 2O 3 Powder 60?
Zirconium powder Zirconium?powder Zr? Ultrafine powder 14?
Zircoium hydride Zirconium?hydride ZrH 2 Ultrafine powder 18?
Diatomite diatomite? /? Powder 6?
Shellac varnish Shellac?paint? /? Liquid 2?
Prescription four
Chemical name English name Molecular formula State Weight percent %
Ferric oxide Ferric?oxide? Fe 2O 3 Powder 65?
Zirconium powder Zirconium?powder Zr? Ultrafine powder 6?
Zircoium hydride Zirconium?hydride ZrH 2 Ultrafine powder 20?
Diatomite diatomite? /? Powder 5?
Shellac varnish Shellac?paint? /? Liquid 4?
Make the technical process of starting mix of solid oxygen generator tablet of the present invention and see accompanying drawing 1.
In the above-mentioned prescription one, two, three, four, when carrying out the starting material processing, zirconium powder and zircoium hydride at first dewater, dry under 80 ℃ of temperature, ferric oxide is dried under 100 ℃ of temperature, and zirconium powder, zircoium hydride, ferric oxide, diatomite mix by the formula rate requirement, its mean particle size is 0.15~0.85mm behind the overmulling sieve, add 8~10% shellac varnish spirituous solutions, stir, baking is 3 hours under 60 ℃ of temperature.

Claims (5)

1. a starting mix of solid oxygen generator is characterized in that it is by following composition
Ferric oxide 40~70 zirconium powders 5~25
Zircoium hydride 10~30 diatomite 1~15
Shellac varnish 1~10
Weight percent form.
2. starting mix of solid oxygen generator according to claim 1 is characterized in that it is by following composition
Ferric oxide 52 zirconium powders 18
Zircoium hydride 16 diatomite 8
Shellac varnish 6
Weight percent form.
3. starting mix of solid oxygen generator according to claim 1 is characterized in that it is by following composition
Ferric oxide 58 zirconium powders 12
Zircoium hydride 18 diatomite 10
Shellac varnish 2
Weight percent form.
4. starting mix of solid oxygen generator according to claim 1 is characterized in that it is by following composition
Ferric oxide 60 zirconium powders 14
Zircoium hydride 18 diatomite 6
Shellac varnish 2
Weight percent form.
5. starting mix of solid oxygen generator according to claim 1 is characterized in that it is by following composition
Ferric oxide 65 zirconium powders 6
Zircoium hydride 20 diatomite 5
Shellac varnish 4
Weight percent form.
CN2009102270540A 2009-11-30 2009-11-30 Ignitor of solid oxygen generator Expired - Fee Related CN101898924B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2009102270540A CN101898924B (en) 2009-11-30 2009-11-30 Ignitor of solid oxygen generator

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2009102270540A CN101898924B (en) 2009-11-30 2009-11-30 Ignitor of solid oxygen generator

Publications (2)

Publication Number Publication Date
CN101898924A true CN101898924A (en) 2010-12-01
CN101898924B CN101898924B (en) 2012-01-11

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN2009102270540A Expired - Fee Related CN101898924B (en) 2009-11-30 2009-11-30 Ignitor of solid oxygen generator

Country Status (1)

Country Link
CN (1) CN101898924B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103204755A (en) * 2012-12-21 2013-07-17 湖北航天化学技术研究所 Ignition drug for lifesaving solid oxygen and preparation method thereof
CN103755504A (en) * 2013-12-09 2014-04-30 中国人民解放军理工大学 High-energy ignition agent and preparation method thereof
CN105324550A (en) * 2013-06-06 2016-02-10 国际壳牌研究有限公司 Propellant driven accumulator

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1640858A (en) * 2004-01-12 2005-07-20 刘青春 Fireworks and fire cracker rapid ignition charge without chlorate and perchlorate

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103204755A (en) * 2012-12-21 2013-07-17 湖北航天化学技术研究所 Ignition drug for lifesaving solid oxygen and preparation method thereof
CN103204755B (en) * 2012-12-21 2015-05-13 湖北航天化学技术研究所 Ignition drug for lifesaving solid oxygen and preparation method thereof
CN105324550A (en) * 2013-06-06 2016-02-10 国际壳牌研究有限公司 Propellant driven accumulator
CN105324550B (en) * 2013-06-06 2018-01-12 国际壳牌研究有限公司 Propellant actuated formula accumulator
CN103755504A (en) * 2013-12-09 2014-04-30 中国人民解放军理工大学 High-energy ignition agent and preparation method thereof
CN103755504B (en) * 2013-12-09 2017-03-22 中国人民解放军理工大学 High-energy ignition agent and preparation method thereof

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Publication number Publication date
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Owner name: JIANGNAN INDUSTRIES GROUP CO., LTD.

Free format text: FORMER NAME: JIANGNAN MACHINERY (GROUP) CO., LTD.

CP03 Change of name, title or address

Address after: Bamboo town Yuhu District 411207 Hunan city of Xiangtan Province

Patentee after: Jiangnan Industries Group Co., Ltd.

Address before: Bamboo Jiangnan Machine Yuhu District 411207 in Hunan province Xiangtan city (Group) Co. Ltd.

Patentee before: Jiangnan Machinery (Group) Co., Ltd.

CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120111

Termination date: 20151130

EXPY Termination of patent right or utility model