CN101885953A - Acid-resisting rubber reinforcing and metal binding agent and preparation method thereof - Google Patents
Acid-resisting rubber reinforcing and metal binding agent and preparation method thereof Download PDFInfo
- Publication number
- CN101885953A CN101885953A CN 201010230674 CN201010230674A CN101885953A CN 101885953 A CN101885953 A CN 101885953A CN 201010230674 CN201010230674 CN 201010230674 CN 201010230674 A CN201010230674 A CN 201010230674A CN 101885953 A CN101885953 A CN 101885953A
- Authority
- CN
- China
- Prior art keywords
- rubber
- binding agent
- acid
- metal binding
- terpolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to an acid-resisting rubber reinforcing and metal binding agent which is prepared by mixing and using ethyl acetate to dissolve 16-26% of ethylene propylene terpolymer rubber, 27-37% of oil-filled ethylene propylene terpolymer rubber, 1-3% of chlorine vulcanizing polyethylene, 0.3-0.7% of accelerating agent TMTD, 0.6-1.2% of accelerating agent MBT, 1-3.2% of zinc oxide, 6.0-10.9% of high wear resistance carbon black, 17-27.4% of non-pollution and high elongation semi-reinforcing carbon black, 5-10.9% of paraffin oil and 0.1-0.4% of sulphur by mass ratio. Meanwhile, the invention also discloses a preparation method of the binding agent. The product is not easily layered, firm in binding and convenient for use.
Description
Technical field
The present invention relates to that sour rubber rollers is invaded in pickling and rubber rollers and the anticorrosion poly-field of anti-strong acid are extracted in pickling, relate in particular to acid-resisting rubber and strengthen and metal binding agent and preparation method thereof.
Background technology
The rubber of current use and the tackiness agent of metal are invaded sour rubber rollers and pickling is extracted in rubber rollers and the corrosion preventing production process of anti-strong acid in pickling, often can not well-bondedly merge, and keep away the quality problems that unavoidable entrained air bubbles causes insecure, the anti-detachment differences of bonding such as layering, the product of producing like this is not long with regard to layering duration of service, break away from metallic framework, influence product work-ing life.
Summary of the invention
Technical problem to be solved by this invention provides a kind of layering, the enhancing of bonding firm acid-resisting rubber and metal binding agent of being difficult for.
Another technical problem to be solved by this invention provides a kind of acid-resisting rubber enhancing simple to operate, easy to use and the preparation method of metal binding agent.
For addressing the above problem, a kind of acid-resisting rubber of the present invention strengthens and metal binding agent, it is characterized in that: this caking agent is after sulphur that 16～26% terpolymer EP rubber, 27～37% oil extended EPDM, 1～3% chlorine vulcanized polyethylene, 0.3～0.7% TM monex TD, 0.6～1.2% accelerant MBT, 1～3.2% zinc oxide, 6.0～10.9% high wear-resistant carbon black, 17～27.4% uncontamination height are stretched semi-reinforcing hydrocarbon black, 5～10.9% paraffin oil and 0.1～0.4% surely mixes, to form with acetic acid ethyl dissolution by mass ratio.
A kind of aforesaid acid-resisting rubber strengthens the preparation method with metal binding agent, may further comprise the steps:
(1) according to each component of proportioning weighing;
(2) small-sized internal mixer is warmed up to 90～110 ℃ after, add successively terpolymer EP rubber, oil extended EPDM, chlorine vulcanized polyethylene, TM monex TD, accelerant MBT, zinc oxide, high wear-resistant carbon black, uncontamination height stretch semi-reinforcing hydrocarbon black, paraffin oil surely, under this temperature, be incubated pressurization banburying 5～10 minutes, obtain the terpolymer EP rubber master batch after the banburying with the pressure of 0.5～0.6MPa;
(3) the terpolymer EP rubber master batch after the described banburying is carried out mixing under 50～70 ℃ of temperature, and adds sulphur, mixing evenly after, obtain mixing materials; After described mixing materials at room temperature cooled off, being cut into wide was 5 millimeters strip material;
(4) ethyl acetate of 3～5 times of described strip material and its quality is mixed to dissolving after, promptly get acid-resisting rubber and strengthen and metal binding agent.
The present invention compared with prior art has the following advantages:
1, because the component mixing that the present invention adopts the carrier master batch and has vulcanization system, and products obtained therefrom of the present invention is liquid, therefore, can be after brushing equably attached to the metallic surface, and can invade in the tiny recessed joint, can vulcanize with acid-resisting rubber, form one integrated mass, be difficult for delamination, thereby prolonged work-ing life.
2, because product of the present invention is a liquid, therefore, easy to use, save labor.
3, because product of the present invention only adopts banburying, the mode of production mixing and that stir just can obtain, and therefore, preparation technology is simple, not only easy handling is convenient and safe, and has saved production cost effectively.
Embodiment
1 one kinds of acid-resisting rubbers of embodiment strengthen and metal binding agent, by mass ratio is after sulphur that 21% terpolymer EP rubber, 33% oil extended EPDM, 2% chlorine vulcanized polyethylene, 0.5% TM monex TD, 0.9% accelerant MBT, 2.2% zinc oxide, 8.9% high wear-resistant carbon black, 22.4% uncontamination height are stretched semi-reinforcing hydrocarbon black, 8.9% paraffin oil and 0.2% surely mixes, to form with acetic acid ethyl dissolution.
This acid-resisting rubber strengthens the preparation method with metal binding agent, may further comprise the steps:
(1) according to each component of proportioning weighing;
(2) small-sized internal mixer is warmed up to 90～110 ℃ after, add successively terpolymer EP rubber, oil extended EPDM, chlorine vulcanized polyethylene, TM monex TD, accelerant MBT, zinc oxide, high wear-resistant carbon black, uncontamination height stretch semi-reinforcing hydrocarbon black, paraffin oil surely, under this temperature, be incubated pressurization banburying 5～10 minutes, obtain the terpolymer EP rubber master batch after the banburying with the pressure of 0.5～0.6MPa;
(3) the terpolymer EP rubber master batch after the banburying is carried out mixing under 50～70 ℃ of temperature with mill, and adds sulphur, mixing evenly after, obtain mixing materials; After mixing materials at room temperature cooled off, being cut into wide was 5 millimeters strip material;
(4) the strip material is put into agitation vat, the ethyl acetate that adds 3～5 times of its quality is mixed, and stirs with 20～40 rpms speed, stirs dissolving fully after 30 minutes, promptly gets acid-resisting rubber and strengthens and metal binding agent.
2 one kinds of acid-resisting rubbers of embodiment strengthen and metal binding agent, by mass ratio is after sulphur that 16% terpolymer EP rubber, 37% oil extended EPDM, 2% chlorine vulcanized polyethylene, 0.5% TM monex TD, 0.9% accelerant MBT, 3.2% zinc oxide, 8.9% high wear-resistant carbon black, 22.4% uncontamination height are stretched semi-reinforcing hydrocarbon black, 8.9% paraffin oil and 0.2% surely mixes, to form with acetic acid ethyl dissolution.
The preparation method of this acid-resisting rubber enhancing and metal binding agent is with embodiment 1.
3 one kinds of acid-resisting rubbers of embodiment strengthen and metal binding agent, by mass ratio is after sulphur that 26% terpolymer EP rubber, 27% oil extended EPDM, 2% chlorine vulcanized polyethylene, 0.5% TM monex TD, 0.9% accelerant MBT, 2.2% zinc oxide, 8.9% high wear-resistant carbon black, 22.4% uncontamination height are stretched semi-reinforcing hydrocarbon black, 9.9% paraffin oil and 0.2% surely mixes, to form with acetic acid ethyl dissolution.
The preparation method of this acid-resisting rubber enhancing and metal binding agent is with embodiment 1.
4 one kinds of acid-resisting rubbers of embodiment strengthen and metal binding agent, by mass ratio is after sulphur that 21% terpolymer EP rubber, 33% oil extended EPDM, 2% chlorine vulcanized polyethylene, 0.5% TM monex TD, 0.9% accelerant MBT, 3.2% zinc oxide, 8% high wear-resistant carbon black, 22.4% uncontamination height are stretched semi-reinforcing hydrocarbon black, 8.9% paraffin oil and 0.1% surely mixes, to form with acetic acid ethyl dissolution.
The preparation method of this acid-resisting rubber enhancing and metal binding agent is with embodiment 1.
5 one kinds of acid-resisting rubbers of embodiment strengthen and metal binding agent, by mass ratio is after sulphur that 21% terpolymer EP rubber, 32% oil extended EPDM, 1% chlorine vulcanized polyethylene, 0.3% TM monex TD, 1.2% accelerant MBT, 1% zinc oxide, 6.0% high wear-resistant carbon black, 27.4% uncontamination height are stretched semi-reinforcing hydrocarbon black, 9.7% paraffin oil and 0.4% surely mixes, to form with acetic acid ethyl dissolution.
The preparation method of this acid-resisting rubber enhancing and metal binding agent is with embodiment 1.
6 one kinds of acid-resisting rubbers of embodiment strengthen and metal binding agent, by mass ratio is after sulphur that 21% terpolymer EP rubber, 33% oil extended EPDM, 3% chlorine vulcanized polyethylene, 0.7% TM monex TD, 0.6% accelerant MBT, 2.7% zinc oxide, 10.9% high wear-resistant carbon black, 17% uncontamination height are stretched semi-reinforcing hydrocarbon black, 10.9% paraffin oil and 0.2% surely mixes, to form with acetic acid ethyl dissolution.
The preparation method of this acid-resisting rubber enhancing and metal binding agent is with embodiment 1.
7 one kinds of acid-resisting rubbers of embodiment strengthen and metal binding agent, by mass ratio is after sulphur that 26% terpolymer EP rubber, 27% oil extended EPDM, 3% chlorine vulcanized polyethylene, 0.5% TM monex TD, 0.9% accelerant MBT, 3.2% zinc oxide, 8.9% high wear-resistant carbon black, 25.4% uncontamination height are stretched semi-reinforcing hydrocarbon black, 5% paraffin oil and 0.1% surely mixes, to form with acetic acid ethyl dissolution.
The preparation method of this acid-resisting rubber enhancing and metal binding agent is with embodiment 1.
Claims (2)
1. an acid-resisting rubber strengthens and metal binding agent, it is characterized in that: this caking agent is after sulphur that 16～26% terpolymer EP rubber, 27～37% oil extended EPDM, 1～3% chlorine vulcanized polyethylene, 0.3～0.7% TM monex TD, 0.6～1.2% accelerant MBT, 1～3.2% zinc oxide, 6.0～10.9% high wear-resistant carbon black, 17～27.4% uncontamination height are stretched semi-reinforcing hydrocarbon black, 5～10.9% paraffin oil and 0.1～0.4% surely mixes, to form with acetic acid ethyl dissolution by mass ratio.
2. an acid-resisting rubber as claimed in claim 1 strengthens the preparation method with metal binding agent, may further comprise the steps:
(1) according to each component of proportioning weighing;
(2) small-sized internal mixer is warmed up to 90～110 ℃ after, add successively terpolymer EP rubber, oil extended EPDM, chlorine vulcanized polyethylene, TM monex TD, accelerant MBT, zinc oxide, high wear-resistant carbon black, uncontamination height stretch semi-reinforcing hydrocarbon black, paraffin oil surely, under this temperature, be incubated pressurization banburying 5～10 minutes, obtain the terpolymer EP rubber master batch after the banburying with the pressure of 0.5～0.6MPa;
(3) the terpolymer EP rubber master batch after the described banburying is carried out mixing under 50～70 ℃ of temperature, and adds sulphur, mixing evenly after, obtain mixing materials; After described mixing materials at room temperature cooled off, being cut into wide was 5 millimeters strip material;
(4) ethyl acetate of 3～5 times of described strip material and its quality is mixed to dissolving after, promptly get acid-resisting rubber and strengthen and metal binding agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102306742A CN101885953B (en) | 2010-07-16 | 2010-07-16 | Acid-resisting rubber reinforcing and metal binding agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102306742A CN101885953B (en) | 2010-07-16 | 2010-07-16 | Acid-resisting rubber reinforcing and metal binding agent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101885953A true CN101885953A (en) | 2010-11-17 |
| CN101885953B CN101885953B (en) | 2011-10-05 |
Family
ID=43072055
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010102306742A Expired - Fee Related CN101885953B (en) | 2010-07-16 | 2010-07-16 | Acid-resisting rubber reinforcing and metal binding agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101885953B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103275650A (en) * | 2013-06-17 | 2013-09-04 | 贵州贵航汽车零部件股份有限公司 | Split joint viscose and preparation method thereof |
| CN107033825A (en) * | 2017-04-20 | 2017-08-11 | 合肥民众亿兴软件开发有限公司 | A kind of novel mechanical processing metal binding agent and its processing technology |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1314979A (en) * | 1998-09-10 | 2001-09-26 | 艾罗奎普有限公司 | Refrigerant hose |
| CN1316459A (en) * | 2001-05-15 | 2001-10-10 | 南开大学 | Modified polyolefine elastomer and its preparing process |
| KR100637655B1 (en) * | 2005-08-09 | 2006-10-24 | 위덕찬 | Composition of flame retardant epdm rubber compound and its preparing method |
| JP2009013296A (en) * | 2007-07-05 | 2009-01-22 | Kureha Elastomer Co Ltd | Gasket material for electrolytic cell |
-
2010
- 2010-07-16 CN CN2010102306742A patent/CN101885953B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1314979A (en) * | 1998-09-10 | 2001-09-26 | 艾罗奎普有限公司 | Refrigerant hose |
| CN1316459A (en) * | 2001-05-15 | 2001-10-10 | 南开大学 | Modified polyolefine elastomer and its preparing process |
| KR100637655B1 (en) * | 2005-08-09 | 2006-10-24 | 위덕찬 | Composition of flame retardant epdm rubber compound and its preparing method |
| JP2009013296A (en) * | 2007-07-05 | 2009-01-22 | Kureha Elastomer Co Ltd | Gasket material for electrolytic cell |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103275650A (en) * | 2013-06-17 | 2013-09-04 | 贵州贵航汽车零部件股份有限公司 | Split joint viscose and preparation method thereof |
| CN107033825A (en) * | 2017-04-20 | 2017-08-11 | 合肥民众亿兴软件开发有限公司 | A kind of novel mechanical processing metal binding agent and its processing technology |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101885953B (en) | 2011-10-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5647128B2 (en) | Tires containing recycled materials | |
| EP2909240B1 (en) | Devulcanizing agent for production of reclaim rubber powder | |
| CN100348656C (en) | Super strong acid resistant rubber material and its preparation method | |
| CN102443214B (en) | Preparation method for high foaming ratio polyethylene foaming material | |
| CN102585732B (en) | Intermediate adhesive for high-heat-resistant conveying belt and preparation method thereof | |
| AU2002322876B2 (en) | Process for regeneration of rubber from scrap | |
| CN113150578A (en) | Novel modified pyrolysis carbon black and preparation method thereof | |
| CN104761794A (en) | Gutta percha shape memory polymer composite material and preparation method thereof | |
| CN101885953B (en) | Acid-resisting rubber reinforcing and metal binding agent and preparation method thereof | |
| CN102161788B (en) | Preparation method of reinforced anti-aging nitrile elastomer | |
| AU2002322876A1 (en) | Process for regeneration of rubber from scrap | |
| CN107903524A (en) | A kind of plastic processing toughener and its preparation process | |
| CN105237891A (en) | Anti-corrosion high-strength wear-resistant high polymer material and preparation method | |
| CN107057092A (en) | Improve the compounding process of carbon black dispersed homogeneous degree in masterbatch | |
| CN103849292A (en) | Self-sealed tire adhesive and preparation method thereof | |
| CN110591261B (en) | Pre-dispersed masterbatch of vulcanization crosslinking activator of acrylate rubber and preparation method thereof | |
| CN104419022A (en) | Modified low-resistance tire rubber compound and preparation method thereof | |
| CN108084520B (en) | Zinc-free nitrile rubber and preparation method thereof | |
| CN103865100B (en) | A kind of rubber processing aids and preparation method thereof | |
| CN106519346A (en) | NBR+PVC rubber mixing method | |
| CN103059361B (en) | Rubber and production method thereof | |
| CN109852078A (en) | A kind of environment protection modified pitch and its processing method | |
| CN109957154B (en) | Preparation method of graphene modified rubber composite material and rubber composite material | |
| CN106496689A (en) | A kind of preparation method of NBR60 degree epithelium elastomeric compound | |
| CN105131331A (en) | Modified precipitated white carbon black and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20111005 Termination date: 20170716 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |