CN101868334A - Impregnation die for manufacturing long fiber reinforced thermoplastic resin molding material - Google Patents
Impregnation die for manufacturing long fiber reinforced thermoplastic resin molding material Download PDFInfo
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- CN101868334A CN101868334A CN200780101624A CN200780101624A CN101868334A CN 101868334 A CN101868334 A CN 101868334A CN 200780101624 A CN200780101624 A CN 200780101624A CN 200780101624 A CN200780101624 A CN 200780101624A CN 101868334 A CN101868334 A CN 101868334A
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- dipping former
- former according
- tapering
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/50—Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
- B29C70/52—Pultrusion, i.e. forming and compressing by continuously pulling through a die
- B29C70/525—Component parts, details or accessories; Auxiliary operations
- B29C70/526—Pultrusion dies, e.g. dies with moving or rotating parts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
- B29B15/08—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
- B29B15/10—Coating or impregnating independently of the moulding or shaping step
- B29B15/12—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
- B29B15/122—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length with a matrix in liquid form, e.g. as melt, solution or latex
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Moulding By Coating Moulds (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
An impregnation die, comprising: a housing including an internal processing chamber and a pultrusion aperture; and a nozzle carried on said housing, said nozzle including an opening having an inlet end, an outlet end and a central axis, said inlet end being in communication with said processing chamber by means of said pultrusion aperture; said impregnation die being characterized by said opening including a first tapered section adjacent said inlet end, a first straight section downstream from said first tapered section, a second tapered section downstream from said first straight section and a second straight section downstream from said second tapered section and adjacent said outlet end.
Description
Technical field
Present invention relates in general to the manufacturing of long fiber reinforced thermoplastic resin molding material, relate in particular to the method for this purpose.
Background technology
The method and apparatus that is used to make long fiber reinforced thermoplastic resin molding material is known in the art.JP-A-10-309756, JP-A-10-315341 and JP-A-2003-305779 are the typical documents of method and apparatus that is used for the prior art of this purpose.The method of disclosed prior art generally can be described to comprise a series of consecutive steps in these documents, described step comprises that (a) delivered to the continuous fiber material in the dipping former that is filled with the fusion thermoplastic resin, (b) squeeze from the crowded pulling eye of dipping former and draw continuous fiber material that is impregnated with thermoplastic resin and the pill that (c) after cooling, the rod-shaped articles that obtains is cut into expection length.
Usually, nozzle is attached to the crowded pulling eye of dipping former.The hole in its shape of nozzle and the nozzle or the size of perforate are selected as carrying out some functions, described function comprises: the removal of excessive fusion thermoplastic resin, make the resin of desired amount be impregnated in the crowded pull bar shape product and the shaping of squeezing the rod-shaped articles after drawing, make its cross section become anticipated shape.In fact, the design of nozzle has determined during processing fusion thermoplastic resin to be impregnated into efficient and the degree in the continuous fiber material to a great extent.
JP-A-11-042639 discloses a kind of fusion thermoplastic resin that prevents from the shaft-like method of drawing the product trickling of squeezing.This by be provided with use with nozzle in the value processing of the length in hole certain formula calculating relevant with cross-sectional area finish.
JP-A-2001-088223 discloses a kind of nozzle with conical portion and linear segment, this nozzle has specific dimensions and shape, be designed to prevent to cut filament and be accumulated near the nozzle as ball top, described ball top may disturb the efficient manufacturing of pill shape product potentially.
JP-A-05-050432 discloses and can remove nozzle and be located at notion on the dipping former.
JP-A-08-090659 discloses a kind of nozzle that comprises the refinement tip portion, and described refinement tip portion is designed to improve the dipping level of fusion thermoplastic resin in the continuous fiber material.
Although these prior art references have marked improvement in the art, further improve and remain possible.Particularly, when managing to squeeze the speed draw step when boosting productivity, still can run into such as the such problem that descends of the dipping level at the fibrous fracture of nozzle or fusion thermoplastic resin by increasing.These problems more likely appear when the long fiber content ratio is high.For example, when the long fiber content ratio be 60% (weight) or when above problem be significant.If layered product is impregnated into the long fiber reinforced thermoplastic resin molding material manufacturing of the level deficiency in the continuous fiber material by thermoplastic resin, then the mechanical performance of layered product and appearance reduce.The present invention provides a kind of uniqueness and therefore unknown solution for these problems.
Summary of the invention
According to purpose of the present invention as described herein, provide a kind of method that is used for making the long fiber reinforced thermoplastic resin pill at the dipping former that comprises Processing Room.Said method comprising the steps of: (a) fill Processing Room with the fusion thermoplastic resin, (b) at least one continuous tow is passed through Processing Room to sending, (c) at least one continuous tow that squeezes after drawing described at least one continuous tow that is impregnated with the fusion thermoplastic resin and (d) will being impregnated with crowded the drawing of fusion thermoplastic resin is cut into pill.Described method is characterised in that according to formula A=QLN/S
2The processing pill, wherein:
A=value processing≤5.0;
Q=squeeze the fusion thermoplastic resin that is applied to described at least one continuous tow during drawing and removes from described Processing Room with mm
3The total amount of/sec meter;
L=gives the length in mm of the described Processing Room that send direction along continuous tow;
N=squeezes the sum of the continuous tow that is impregnated with the fusion thermoplastic resin that draws from described dipping former; And
S=along the described Processing Room of giving the direction send direction perpendicular to described continuous tow with mm
2The cross-sectional area of meter.
In a useful especially embodiment, value processing A is between 0.5 to 3.5.
Described method can also comprise separates dipping former fully so that a plurality of Processing Rooms that separate fully are provided in single dipping former.In yet another embodiment, described method comprises part separation dipping former so that a plurality of Processing Rooms are provided in single dipping former, and wherein said a plurality of Processing Rooms communicate with each other.
Comprise in any method of a plurality of Processing Rooms at dipping former, described method comprises each of filling described a plurality of Processing Rooms with the fusion thermoplastic resin, continuous tow is sent by each chamber, squeeze and draw continuous tow that is impregnated with the fusion thermoplastic resin and the continuous tow that will be impregnated with the fusion thermoplastic resin to be cut into pill.
Described method can also comprise uses glass fiber bundle as continuous tow.Alternatively, described method can comprise that the use carbon fiber bundle is as continuous tow.In addition, described method can comprise that the use vistanex is as the fusion thermoplastic resin.In another alternative, described method can comprise the polyamide as the fusion thermoplastic resin.
Described method can also comprise a plurality of filaments that launch continuous tow, so that help fibre bundle impregnated with molten thermoplastic resin.
In the following description, only by being suitable for most realizing illustrating demonstration and having described some different embodiment of the present invention of patterns more of the present invention.Should be appreciated that the present invention can have other different embodiment and its some details to make amendment aspect various, tangible and do not break away from the present invention.Therefore, accompanying drawing and description will be considered to be exemplary and not restrictive in essence.
Description of drawings
The accompanying drawing that is included in herein and forms the part of specification show some aspects of the present invention and with describe one and be used from and explain some principle of the present invention.In the drawings:
Fig. 1 is the perspective view of dipping former of the present invention;
Fig. 2 is similar to Fig. 1 but the perspective view of alternative, and this embodiment comprises separator makes dipping former comprise a plurality of Processing Rooms;
Fig. 3 is the schematic and sectional view of part that the dipping former of Fig. 1 is shown;
Fig. 4 is the longitudinal cross-section detail drawing of nozzle of the dipping former of the preferred embodiments of the present invention; And
Fig. 5 is the similar view of the nozzle of prior art.
Now will be in detail with reference to currently preferred embodiments of the present invention, the example of described embodiment shown in the drawings.
The specific embodiment
With reference now to Fig. 1 and 3,, there is shown dipping former 10 according to instruction structure of the present invention.Dipping former 10 comprises main body or the shell 12 by suitable high-strength material structure.Shell 12 comprises interior Processing Room 14.As shown in fig. 1, dipping former 10 comprises single Processing Room 14.
With reference to figure 3, shell 12 comprises that supply perforate 18 is to allow in the fusion thermoplastic resin introducing Processing Room 14.In addition, shell 12 comprises and is used for giving the introducing perforate 20 of delivering to Processing Room 14 with continuous tow 50.Further, shell 12 comprises crowded the draw back hole 22 relative with introducing perforate 20.
Figure 2 illustrates an alternative of dipping former 10.In this embodiment, dipping former 10 comprises a series of separators 16 that form a plurality of Processing Rooms 14.Separator 16 all can extend on the whole length of the inner chamber of shell 12 and width, makes Processing Room 14 all separate fully.Alternatively, separator 16 can be partly extends on the length of the inner chamber of shell 12 and/or width, makes Processing Room 14 communicate with each other.In this embodiment, each of a plurality of chambers 14 comprises supply perforate 18, introduces perforate 20 and the crowded hole 22 of drawing back.
As shown in Figure 3, the bottom 26 of nozzle 24 is received in around squeezing and draws back hole 22 and be formed at one heart in the countersunk 28 in the shell 12.Back-up ring 30 engages the shoulder of bottom 26.Back-up ring 30 can be fixed to shell 12 by screw or other fastener (not shown)s, so that with nozzle 24 fix in position.
As among Fig. 4 best shown in, nozzle 24 comprises opening 32, described opening has arrival end 34, the port of export 36 and central axis A.Arrival end 34 draws back hole 22 and directly is communicated with Processing Room 14 by means of squeezing.
When describing in detail, opening 32 is characterised in that first tapering part 40 that comprises neighboring entry end 34, in the first straight part 42 in the positive downstream of first tapering part 40, at second tapering part 44 in the positive downstream of the first straight part 42 with in the positive downstream of second tapering part 44 and the second straight part 46 of the contiguous port of export 36.As shown in Figure 4, first tapering part 40 comprises crooked tapering (noting the curved wall of opening), and second tapering part 44 comprises linear taper (noting the straight sidewall of opening).Yet should be appreciated that if necessary first tapering part 40 can comprise linear taper and second tapering part 44 can comprise crooked tapering.Therefore, in a possible embodiment, both comprise linear taper first and second tapering parts 40,44.In another possible embodiment first and second tapering parts 40,44 both comprise crooked tapering.In another possible embodiment, first tapering part 40 can comprise linear taper, and second tapering part 44 can comprise crooked tapering.
In any one possible embodiment, first tapering part 40 is assembled towards the first straight part 42.Similarly, second tapering part 44 is assembled towards the second straight part 46.
As further shown in Figure 4, both arrange and symmetrically along the central axis A longitudinal extension of opening 32 to should be appreciated that the first straight part 42 and the second straight part 46.
The tip of nozzle 24 is typically from installing the stretch out length of 5-20mm of back-up ring 30.This distance helps to guarantee that squeezing the products that draw from nozzle 24 becomes stable, thus, when squeezing when drawing product to be cut into the pill of certain expection length, reduces any burr that breaks and fallen to producing by fiber of product.
First tapering part 40 of opening 32 has length L 1.The first straight part 42 of opening 32 has length L 2 and diameter D2.Second tapering part of opening 32 has length L 3.The second straight part of opening 32 has length L 4 and diameter D4.Typically, the length L 3 of the length L 1 of first tapering part 40 and second tapering part 44 is respectively between 0.5 to 5mm.In addition, the length L 2 of the first straight part 42 is longer than the length L 4 of the second straight part 46.The diameter D2 of the first straight part 42 is greater than the diameter D4 of the second straight part 46.In addition, first tapering part 40 has first, the diameter D1 of upstream or arrival end and second or the diameter D2 of downstream, wherein D2=D1/2.Further, ratio L4/D4 is typically between 1.4 to 3.4.
To describe the method for the long fiber reinforced thermoplastic resin molding material of making the pill shape now in detail.Described method comprises the step of filling Processing Room 14 by supply perforate 18 usefulness fusion thermoplastic resins continuously.For each Processing Room 14 that is located in the dipping former 10 provides at least one supply perforate 18.The known any thermoplastic resin that helps producing the long fiber reinforced thermoplastic resin pill be can utilize, vistanex, polyamide and their combination included but not limited to.
Described method also comprises is given at least one continuous tow 50 by Processing Room 14.More specifically, continuous tow 50 is entered Processing Room 14 from supply spool (not shown) to delivering on the director element 48 and by introducing perforate 20.Continuous tow 50 by pass squeeze draw back hole 22 and nozzle 24 squeezed draw with the thorough impregnation resin before contact with fusion thermoplastic resin in the Processing Room 14.Continuous tow 50 can be comprised such as glass fiber bundle and/or the such reinforcing material of carbon fiber bundle by any suitable material manufacturing.The optional spreader 54 that is known in the art type can be located at interval location in the Processing Room 14 with the single filament that launches continuous tow 50 and help dipping process.Comprise that the rod-shaped articles 56 after crowded the drawing of the continuous tow 50 that is impregnated with fusion thermoplastic resin 51 is extruded and is cut into by cutter sweep 52 then the pill 60 of expection length by nozzle 24.
Method of the present invention is characterised in that according to formula A=QLN/S
2The processing pill, wherein:
A=value processing≤5.0;
Q=squeeze the fusion thermoplastic resin that is applied to described at least one continuous tow during drawing and removes from described Processing Room with mm
3The total amount of/sec meter;
L=gives the length in mm of the described Processing Room that send direction along continuous tow;
N=squeezes the sum of the continuous tow that is impregnated with the fusion thermoplastic resin that draws from described dipping former; And
S=along the described Processing Room of giving the direction send direction perpendicular to described continuous tow with mm
2The cross-sectional area of meter.
More preferably, value processing A is located between 0.5 to 3.5.
In the dipping former that comprises a plurality of Processing Rooms 14 10 shown in Fig. 2, according to value processing A processing by pass those single chambers 14 each continuously with 50 pills of producing.Under these circumstances, when the value A in the calculating aforementioned formula, the respective cross section of each chamber 14 is amassed the cross-sectional area S of the total value of S1, S2, S3, S4 as dipping former 10.
Following example illustrates the present invention with help.
Experiment 1
Use the long fiber reinforced thermoplastic resin molding material of the dipping former acquisition pill shape of shape shown in Fig. 2; length L and cross-sectional area S (total value of the cross-sectional area of each Processing Room) are described in table 1; and the total N that squeezes the rod-shaped articles that draws from dipping former is set to 4; and the crowded pulling rate degree of rod-shaped articles is set, makes the total amount Q of the fusion thermoplastic resin removed from dipping former be described in table 1.
About fiber, using diameter is 4,080 filaments of glass packs glass fibre together of 16 μ m.Acrylic resin with 151 melt flow rates (MFR) of measuring according to the program described in the ISO-1133 is as thermoplastic resin.The content ratio of the glass fibre of the long fiber reinforced thermoplastic resin molding material that obtains is 50% (weight).
In following method, the long fiber reinforced thermoplastic resin molding material of assessment example 1-5 and comparative example 1-3 is to obtain acrylic resin to the dipping level of glass fibre and be displayed in Table 1 the result.
The evaluation method of dipping level
The long fiber reinforced thermoplastic resin molding material of 10g pill shape is immersed in one minute and taking-up in the water base red ink, in water, washes and wipe fluid.Lighter painted pill has the better dipping level of acrylic resin to glass fibre, and reason is that ink sees through (that is, in the small air gap of pill) in the part of not flooding acrylic resin.Relatively assess the dipping level by eyes based on the painted degree of depth.
As shown in table 1, have good resin dipping level as the pill of the example 1-5 of long fiber reinforced thermoplastic resin molding material of the present invention.
Table 1
Experiment 1 | |
Experiment 3 | |
Experiment 5 | Comparative experiments 1 | Comparative experiments 2 | Comparative experiments 3 | |
N (bar) | ??4 | ??4 | ??4 | ??4 | ??4 | ?4 | ??4 | ??4 |
?Q(mm 3/sec) | ??3,066 | ??3,528 | ??802 | ??1,604 | ??1,925 | ?2,245 | ??2,566 | ??3,208 |
?L(mm) | ??1,000 | ??1,000 | ??1,000 | ??1,000 | ??1,000 | ?1,000 | ??1,000 | ??1,000 |
?S(mm 2) | ??3,720 | ??2,360 | ??1,300 | ??1,300 | ??1,300 | ?1,300 | ??1,300 | ??1,300 |
?A=Q*L*N/S 2 | ??0.89 | ??2.53 | ??1.90 | ??3.80 | ??4.56 | ?5.31 | ??6.07 | ??7.59 |
The dipping level | Fine | Fine | Fine | Well | Well | Difference | Difference | Difference |
The dipping former as shown in Figure 3 10 that the plurality of nozzles of shape is attached to it shown in use Fig. 4 is made long fiber reinforced thermoplastic resin molding materials.Each of nozzle is of a size of D1=10mm, D2=5mm, D3=15mm, D4=2.2mm, D5=10mm, R (radius of curvature of the crooked tapering of first tapering part)=5mm, L1=2mm, L2=20mm, L3=2mm, L4=6mm, L4/D4=2.7 and its material are brass.About fiber, use the glass fiber bundle that 17 glass fibres are flocked together, described glass fibre is 600 filaments of glass acquisitions of 13.5 μ m by the pack diameter.And acrylic resin is as thermoplastic resin.
The speed of squeezing pull bar shape product is set to 15m/min, and is the N=4 bar with other condition setting, Q=1,747mm
3/ sec, L=1,000mm, S=2,360mm
2And A=1.3.Then, the content ratio of manufacturing glass fibre is the long fiber reinforced thermoplastic resin molding material of 70% (weight).In this manufacture process, around nozzle crowded draw, the fracture frequency of the breaks of rod-shaped articles each nozzle that is counted and is converted into a day in (24 hours).By the filaments of glass that comprises glass fibre partly the fracture that is accumulated in the glass fibre that causes in the nozzle of fracture and grain raising and burr be counted as the fracture of rod-shaped articles.Fracture frequency among the present invention is each nozzle 0.099 time every day.
For relatively, the nozzle (prior art) that uses shape shown in Fig. 5 with top identical condition under and in identical method the breaks of counting rod-shaped articles.Although nozzle 60 has shoulder 68, it has substantial cylindrical, has the hole 65 that penetrates it, and the cross section in described hole is circular.Hole 65 has tapering part 66 and parallel or straight part 67.Each of nozzle 60 is of a size of D6=9mm, D7=2.2mm, D8=15mm, D9=10mm, L6=25mm, L7=5mm.The fracture frequency of rod-shaped articles in the prior art is each nozzle 0.77 time every day.
As mentioned above, the fracture frequency of rod-shaped articles of the present invention is far smaller than fracture frequency of the prior art.So the productivity ratio that strengthens thermoplastic resin molding material at dipping former medium-length fibre of the present invention is higher.
The above description of the preferred embodiments of the present invention is provided for illustration and purpose of description.It is not to be intended to be exhaustive or limit the invention to disclosed exact form.It is possible significantly revising or change according to above instruction.Selecting and describing embodiment is for the best illustration of principle of the present invention and application in practice thereof is provided, allow thus those of ordinary skill in the art in various embodiments and be suitable for expecting special-purpose various modifications and utilize the present invention.All such modifications and variations are in the scope of being determined by accessory claim of the present invention when understanding according to the extension that gives claim by rights, legally and equitably.Accompanying drawing and preferred embodiment are not and be not to be intended to by any way at it its ordinary meaning of restriction claim in the proper and extensive interpretation.
Claims (18)
1. dipping former, this dipping former comprises:
Shell, Processing Room and the crowded hole of drawing back in comprising; With
Be carried on the nozzle on the described shell, described nozzle comprises opening, and described opening has arrival end, the port of export and central axis, and described arrival end draws back the hole and is communicated with described Processing Room by means of described squeeze;
Described dipping former is characterised in that, described opening comprises: first tapering part of contiguous described arrival end, the first straight part in the downstream of described first tapering part is at second tapering part in the downstream of the described first straight part with in the downstream of described second tapering part and the second straight part of the contiguous described port of export.
2. dipping former according to claim 1, wherein said first tapering part is assembled towards the described first straight part.
3. dipping former according to claim 2, wherein said first tapering part comprises linear taper.
4. dipping former according to claim 2, wherein said first tapering part comprises crooked tapering.
5. dipping former according to claim 1, wherein said second tapering part divide towards described second straight portion to be assembled.
6. dipping former according to claim 5, wherein said second tapering part comprises linear taper.
7. dipping former according to claim 5, wherein said second tapering part comprises crooked tapering.
8. dipping former according to claim 1, the wherein said first straight part and the described second straight part are arranged symmetrically along the described central axis of described opening.
9. dipping former according to claim 1, wherein said first tapering part has length L 1, and the described first straight part has length L 2, and described second tapering part has length L 3, and the described second straight part has length L 4, and L2>L4.
10. dipping former according to claim 9, wherein said length L 1 and described length L 3 are between 0.5 to 5.0mm.
11. dipping former according to claim 9, the wherein said first straight part have diameter D2 and the described second straight part has diameter D4, and D2>D4.
12. dipping former according to claim 11, wherein L4/D4=1.4 to 3.4.
13. dipping former according to claim 9, wherein said first tapering part has the diameter D at first end
1With diameter D at second end
2, D wherein
2=D
1/ 2.
14. dipping former according to claim 1, wherein said shell comprise the supply perforate that is used for the fusion thermoplastic resin.
15. dipping former according to claim 1, wherein said shell comprise the introducing perforate that is used for continuous tow.
16. dipping former according to claim 15, wherein said introducing perforate squeezes with described that to draw back the hole relative substantially.
17. dipping former according to claim 1 wherein is provided with the filament spreader in described Processing Room.
18. dipping former according to claim 1, wherein said shell comprise at least one separator that Processing Room in described is divided into a plurality of interior Processing Rooms.
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CN201510510607.9A CN105150561B (en) | 2007-10-02 | 2007-10-02 | Dipping former for manufacturing long fiber reinforced thermoplastic resin molding material |
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PCT/US2007/021204 WO2009045190A1 (en) | 2007-10-02 | 2007-10-02 | Impregnation die for manufacturing long fiber reinforced thermoplastic resin molding material |
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CN201510510607.9A Division CN105150561B (en) | 2007-10-02 | 2007-10-02 | Dipping former for manufacturing long fiber reinforced thermoplastic resin molding material |
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JP (1) | JP5027929B2 (en) |
KR (1) | KR101472618B1 (en) |
CN (1) | CN101868334A (en) |
WO (1) | WO2009045190A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111212714A (en) * | 2017-10-16 | 2020-05-29 | 费德玛有限责任两合公司 | Device and method for impregnating fiber bundles with polymer melt |
CN112793042A (en) * | 2021-04-08 | 2021-05-14 | 江苏国富氢能技术装备股份有限公司 | Fiber nondestructive dipping method for fiber wet winding process |
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JP5728077B2 (en) * | 2011-03-31 | 2015-06-03 | ポリプラスチックス株式会社 | Thermoplastic resin composition pellet manufacturing method, extruder and die plate |
RU2591988C1 (en) * | 2015-04-24 | 2016-07-20 | Федеральное казенное предприятие "Алексинский химический комбинат" (ФКП АХК) | Method of making granules reinforced polymer moulding material and plant for its implementation |
RU167566U1 (en) * | 2015-10-16 | 2017-01-10 | Общество с ограниченной ответственностью "Рекстром-М" | CONTINUOUS FIBER BINDER CAMERA |
KR101814055B1 (en) | 2015-10-16 | 2018-01-03 | 지에스칼텍스 주식회사 | Apparatus for producing long-fiber-reinforced thermoplastic resin pellet |
FR3098517B1 (en) * | 2019-07-09 | 2021-06-04 | Arkema France | PROCESS FOR PREPARING A FIBROUS MATERIAL IMPREGNATED BY REACTIVE PULTRUSION |
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- 2007-10-02 JP JP2010527919A patent/JP5027929B2/en active Active
- 2007-10-02 KR KR1020107007311A patent/KR101472618B1/en active IP Right Grant
- 2007-10-02 WO PCT/US2007/021204 patent/WO2009045190A1/en active Application Filing
- 2007-10-02 CN CN200780101624A patent/CN101868334A/en active Pending
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CN1417016A (en) * | 2001-11-01 | 2003-05-14 | 宝理塑料株式会社 | Mold unit and extrusion method for resin extruder |
US20070175570A1 (en) * | 2003-05-23 | 2007-08-02 | Sia Abrasives Industries Ag | Method for producing compressed, plastic-coated rovings |
EP1790448A1 (en) * | 2005-11-24 | 2007-05-30 | LATI Industria Termoplastici S.p.A. | Device for manufacturing a long-fiber polymeric compound |
WO2007074908A1 (en) * | 2005-12-28 | 2007-07-05 | Ocv Intellectual Capital, Llc | Impregnating die for long-fiber-reinforced thermoplastic resin molding material and process for production with the same |
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CN111212714A (en) * | 2017-10-16 | 2020-05-29 | 费德玛有限责任两合公司 | Device and method for impregnating fiber bundles with polymer melt |
CN111212714B (en) * | 2017-10-16 | 2022-05-10 | 费德玛有限责任两合公司 | Device and method for impregnating a fiber strand with a polymer melt |
CN112793042A (en) * | 2021-04-08 | 2021-05-14 | 江苏国富氢能技术装备股份有限公司 | Fiber nondestructive dipping method for fiber wet winding process |
Also Published As
Publication number | Publication date |
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JP2010540296A (en) | 2010-12-24 |
JP5027929B2 (en) | 2012-09-19 |
KR101472618B1 (en) | 2014-12-15 |
KR20100071053A (en) | 2010-06-28 |
WO2009045190A1 (en) | 2009-04-09 |
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