CN101868164A - Mascara composition and dry-coated method thereof - Google Patents
Mascara composition and dry-coated method thereof Download PDFInfo
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- CN101868164A CN101868164A CN200880116669A CN200880116669A CN101868164A CN 101868164 A CN101868164 A CN 101868164A CN 200880116669 A CN200880116669 A CN 200880116669A CN 200880116669 A CN200880116669 A CN 200880116669A CN 101868164 A CN101868164 A CN 101868164A
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- eyelashes
- cosmetic composition
- applicator system
- mascara applicator
- mascara
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- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D40/00—Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
- A45D40/26—Appliances specially adapted for applying pasty paint, e.g. using roller, using a ball
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- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D40/00—Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
- A45D40/30—Masks for marking lips or eyelashes
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Abstract
Basically the mascara formulation of doing, mascara spread compositions and the method for smearing said preparation are disclosed.The mascara formulation of doing is deposited on the surface of carrier matrix and by mascara is contacted with eyelashes with matrix to be smeared on the eyelashes.Can randomly use dauber to help said preparation is smeared on the eyelashes.The present invention allows to give the various required color gradients of eyelashes, pattern or design.
Description
Invention field
The present invention generally relates to cosmetic composition that is used for eyelashes and the method that this cosmetic composition is applied in eyelashes.
Background of invention
Conventional mascara formulation is that wet or moistening suspension, and the form that it is normally dense and burned must use brush or comb applicator just can be applied on people's the eyelashes.The mascara composition of prior art is characterised in that under environmental condition: according to required product attribute can be newton's or non newtonian (to comprise pseudoplastic behavior and thin property (dilitant) fluid).These mascara formulation may be trouble and difficulty for smearing.Mascara loads on the brush applicator, and it is contacted so that mascara is transferred on the eyelashes with eyelashes.Usually, this process of smearing repeated repeatedly or combing to obtain required effect, this process is loaded down with trivial details and time-consuming, usually causes product unexpectedly to stick in the eyes or on the skin of eyelid or on the face, therefore needs remedial measure.When correctly smearing, make mascara dry on eyelashes then.In drying or solidification process, if contact, then said composition may and will shift from eyelashes, cause the further remedial measure of needs, and in some cases, need spread product again.
This smearing method needs hand stable, and must carry out under static environment, to avoid mascara make dirty other parts or the clothes of face.In addition, use the brush applicator to smear mascara, bristle may produce and coerce sense very near eyes, and may make some abandon using mascara.The people of weak-eyed or hand-eye coordination difference when using the mascara product be very difficulty or abandon using such product.Use conventional mascaras product and smearing method, can not or be very difficult to give eyelashes required visual effect, as pattern or design.Therefore, need a kind of improved mascara formulation and mascara smearing method of having avoided these problems.
Summary of the invention
The invention provides a kind of mascara formulation composition dried or solid and it is applied in method on the eyelashes.The purpose of this invention is to provide a kind of improved dried mascara formulation composition and it is applied in method on the eyelashes, to send instant effect.The invention provides a kind of simple and effective dry-coated technology, it has avoided conventional mascaras to smear the defective of preparation and paint-on technique.Described method and composition makes mascara to be applied on the eyelashes with various patterns or design, and this is to use conventional mascaras preparation or smearing method to be difficult to maybe can not realize.In addition, this method and composition can produce immediate effect.
In another embodiment, provide a kind of dried mascara formulation, it has been deposited on the planar substrate and by preparation is contacted with eyelashes it is transferred on the eyelashes from matrix.
In one embodiment, provide a kind of mascara applicator system, it comprises first host material as the mascara formulation carrier, dried mascara formulation and second host material that places the mascara formulation top.
In a further embodiment, provide a kind of mascara applicator system by hierarchical system, it comprises egative film, and one or more adhesives form the ink layer of pattern and shift backsheet layer and a plurality of optional layer.
In another embodiment, provide a kind of dried mascara has been smeared to method on the eyelashes, it comprises that the dried mascara formulation on making eyelash and placing carrier matrix contacts, and randomly give mascara formulation or matrix is exerted pressure, heat, light or its combination, mascara is transferred on the eyelashes.
The present invention can make mascara be applied on the eyelashes easily and effectively with various patterns, design or effect, to obtain required eyelashes outward appearance.In addition, pattern and design can influence each other, to send Space.
The accompanying drawing summary
Fig. 1. Fig. 1 has described to be pressed in the dauber on the secondary eyelashes, eyelashes is placed on the surface of applicator, makes when cosmetic composition or other compositions are present on the applicator surface, when exerting pressure it is transferred on the eyelashes.Various obtainable non-limiting effects also have been described.
Fig. 2. Fig. 2 has shown that a kind of possible being used to is coated with the example of the dauber that dries mascara formulation.
Fig. 3. Fig. 3 has shown the various dried mascara pattern that can be deposited on the carrier matrix.
Fig. 4. Fig. 4 has shown by doing mascara formulation and the attainable various mascara effects of smearing method.
Fig. 5. Fig. 5 has illustrated by doing the attainable a series of eyelashes of mascara formulation and smearing method and has covered and special effect.
Fig. 6. Fig. 6 has illustrated the eyelashes of having smeared the mascara that is mixed with glittering material.
Fig. 7. Fig. 7 has illustrated an embodiment that is used to send according to the single-layer system of mascara of the present invention.
Fig. 8. Fig. 8 has illustrated an embodiment according to mascara delivery system of the present invention.
Fig. 9. Fig. 9 has shown a kind of SEM (SEM) scanning of possible some configuration.The scanning on right side is the amplification of a point in the scanning of left side.The diameter of this point is approximately 0.2mm (or 200 μ m).
Figure 10. Figure 10 has illustrated according to one embodiment of the invention, lining paper and transfer film is provided wherein for this product, and wherein cosmetics are clipped in or are placed on this two-layer centre.Lining paper and transfer film are drawn round about, make lining paper is peeled off, and when removing, expose the adhesion layer that has a plurality of particulates.When contacting with eyelashes, this adhesion layer is attached to adhering on the eyelashes on the eyelashes and with particulate.Peel transfer film off from eyelashes then, make particle deposition on above-mentioned eyelashes.
Figure 11. Figure 11 has illustrated according to the present invention a kind of utensil of product, and it comprises paper folding, has deposited cosmetics at least one inner surface.This product can comprise the presser sensor ink on the outer surface, and this expression is transferred to cosmetics on the eyelashes when applying enough pressure.
Figure 12. Figure 12 has illustrated the various patterns that wherein cosmetic composition can be smeared or is imprinted on the product.As directed, the flush system hexagon pattern of hexagon " point " provides the most effective transfer to eyelashes, and the transfer of line style cosmetics is not too effective.
Figure 13. Figure 13 has illustrated two embodiments according to application device of the present invention.In embodiment " a ", product is loaded in the groove that forms between two rigid plate sample films, it has according to the curved configuration of the summary of eyelid profile.In operation, the user exerts oneself to action bars, and this makes plate bump together, to be transferred to the pressure that provides essential on the eyelashes to cosmetics.In embodiment " b ", product is placed at the terminal of device and is placed in slidably in the groove that forms between the solid film edge in the device, make that slidably film can move towards the device edge,, cosmetics are transferred on the eyelashes to obtain product and to form enough pressure.
Figure 14. Figure 14 has illustrated four embodiments of the present invention, wherein cosmetics placed on the backing layer as a plurality of particulates, along the color gradient of line I-I, the color gradient vertical and along the many lines of line I-I with line I-I.
Detailed Description Of The Invention
The invention provides a kind of new being used for is applied in method on the eyelashes with cosmetic applying in the composition on the eyelashes and product and with said composition.This product comprises the cosmetics (for example, mascara) that are used for eyelashes, and it is different from the conventional cosmetics of the type, because they provide with the form of doing basically.Composition of the present invention will offer the consumer as tearing sticking type (peel and sticktype) product.Such composition can use powder, solid, semisolid or its combination, rather than uses thick liquid or paste as conventional mascara product.
In the difference of further and conventional products, can produce the present invention by one or more printing processes.That is, the present invention in fact can be any size and or the design printed patterns.In addition, the present invention can be by being used to send a single point of required effect or the point of one group of combination constitutes, or self be rendered as and be used to send a single point of required effect or the point of one group of combination.From viewpoint before, the term point should be used as general descriptive term, yet the term point can be represented countless possible shapes.For example, these shapes will include but not limited to circle, triangle, star of being made up of at least two points, square, rectangle, rhombus, pentagon, hexagon, octagon etc.Printing process includes but not limited to litho, aniline printing, electrostatic printing or laser printing, release coat, digital printed, ink-jet printing and rotogravure or serigraphy.Think that composition of the present invention is instant, promptly do not need operation or obtain required effect drying time.
For example, can realize the compositions and methods of the invention in the following manner.Referring now to Fig. 7, an embodiment of product of the present invention can be described as simple layer system.Cosmetics of the present invention can comprise substrate film or protective layer, have placed adhesion layer thereon.Ensuing one deck will be to mix or be embedded in the colouring agent in the above-mentioned adhesion layer or the pattern of printing fully, and last one deck will be the transfer membrane material of being made by suitable material (as paper, plastics or its combination).In this structure, substrate layer protects adhesive to avoid before use polluting or too early killing as disposable material.Use adhesive that the pattern of colouring agent or printing is sticked on the eyelashes, and cosmetic composition is sticked on substrate film and the transfer film.Transfer film maintains cosmetic composition and as a kind of applicator, composition is applied on the eyelashes.In the position of having determined composition and after having triggered adhesion mechanism, transfer film is divested then.Can be by any suitable method, as printing etc., cosmetic composition is put on adhesion/backing material, and can be used as uniform coating and provide, or arranged in patterns that can be certain is thereon.
Usually, substrate film is as the protection barrier of adhesive.It comprises the material that adhesive is had certain compatibility, make adhesive stick on the substrate film, but substrate film is removed easily.Transfer film or paper are before use as cosmetic composition one side or a part of anchor.In addition, adhesive is used in use cosmetic composition being adhered on the eyelashes, and pressure-sensitive adhesive normally, and it provides enough sensitiveness, so that cosmetic composition is remained on the eyelashes, reaches the duration of the desired effect of consumer.
This product also comprises the substrate film of thin plastics or paper material usually, the preferably clear plastics, as limpid polypropylene or
This covers and protects cosmetic composition before use.Substrate film should can be removed by peeling off, and does not have substantially destroying compositions.Cover layer keeps in position by the adhesive on substrate layer edge or the angle or by any other suitable manner.
Referring now to Fig. 8, can be in more detail an embodiment of product of the present invention be described as more complicated layer system.Carrier layer or protectiveness non-adhesive layer directly contact one or more layers adhesive phase.This carrier layer can be as biaxially oriented PET polyester film
Such material.Being sealant, with the printed layer of protection colouring agent or printing with the direct carrier that contacts of relative adhesive phase.Comprise that the surface preparation layer of polyvinyl alcohol, polyvinylpyrrolidone, gelatin or its composition and ink or coloring agent layer that second sealant will be formed pattern are clipped in the middle.These sealants can be the vernixs that is made of drying oil, resin and solvent.The then release cover layer of being made up of non-sticky siloxanes or mixture of siloxanes, it makes composition and substrate layer or second carrier separate.Can use optional adhesive to change hardness or quality by paper, plastics or its substrate that constitutes or second carrier.Two carriers all are designed to peel off, and first carrier is a protectiveness in fact, and exposes when being removed composition is fixed on adhesive on the eyelashes.Second carrier peeled off it behind target substance (being eyelashes under this situation) as a kind of applicator and in composition stable.
For composition is applied on the eyelashes, the user at first removes protective layer (if existence) from product, to expose cosmetic composition.Cover on the eyelashes substrate layer is folding then, make composition be deposited on the top and/or the bottom of eyelashes, as shown in Figure 2.Can be roughly provide perforation or folding line to fold helping to substrate layer in the centre of described film.Composition was transferred on the eyelashes from substrate layer in when contact, preferably by exerting pressure, as by push the substrate layer that folds with finger or with the special arrangement that is suitable for the receiving folding product.Randomly, self can contain indicator substrate layer, dauber or composition, when has reached appropriate condition to remind the user for suitable deposition.Described indicator can show self by vision or sense of touch pattern.Can improve transfer by applying heat, expect that this can reduce from substrate layer to remove composition and be transferred to the power that eyelashes need.Can use hair-dryer etc. with the product preheating, or can in the process of smearing, use special device to come the heated substrate material.By discharging used pressure, remove backing material then from eyelashes.Randomly, can product or eyelashes is wetting, to help removal.
The present invention described herein is applied in the defective of having avoided conventional mascaras preparation and smearing method on the eyelashes by using a kind of new dried transfer smearing method with the mascara formulation of doing.Dried mascara smearing method described herein does not comprise that using conventional brush applicator to smear eyelashes by brush smears wet or moistening mascara formulation.In addition, the present invention can produce multiple aesthetic effect (pattern, design etc.), and this is to use conventional mascaras to be difficult to maybe can not realize.
Adhesive can also inject the part of cosmetic composition or formation cosmetic composition or combination is sprayed on the cosmetics and the part of injection composition or formation composition.
Referring now to Fig. 1, an embodiment of product of the present invention is described, its part under is stacked on the eyelashes.To the shape of substrate layer basically without limits,, make product when eyelashes are placed, obtain maximum coverage, as shown in fig. 1 although the concave curvature that is fit to eyelid curvature basically is provided preferably at least one edge.The opposite edges of product also can be carried out similar structure, make that the top of eyelashes and bottom are accepted maximum coverage separately when product being folded with the parcel eyelashes.
Substrate layer can be made of any suitable material, makes can to fold and can not break, and these materials include but not limited to, polypropylene, acetate, polystyrene or paper.In the preferred embodiment of the invention, substrate layer is transparent, resilient material.
Substrate layer can be with adhesion layer covering or stacked, to improve cosmetic composition and its adhesiveness.Can use any adhesive that is suitable for cosmetics or medicine use.Adhesive includes but not limited to silicone adhesive, caoutchouc adhesive, phenylethylene/butadiene latex based adhesive, butyl rubber and polyisobutylene adhesives, acryloid cement, vinethene adhesive, glue, bioadhesive, thermoplastic adhesives, resinoid, elastomer, reactive adhesive etc.For example, adhesive can be a pressure-sensitive adhesive, includes but not limited to heat or ultraviolet-curing polymeric material.Rubber-based adhesive comprises U.S. Patent number 3,289, and those described in 478 are incorporated herein by reference its disclosure at this.Acryloid cement comprises U.S. Patent number 3,008,850 and U.S. Patent number 3,924, and those described in 044 are incorporated herein by reference its disclosure at this.Adhesive can further comprise tackifier, to improve cohesive.The acrylate pressure sensitive adhesive comprises those that can obtain with trade name 3M 9472 laminating adhesives from 3M.
Adhesive can or design on the surface that covers substrate layer equably with pattern and maybe can be printed on the substrate layer, makes that its major part sticked on the adhesive when cosmetics were deposited on the thorough layer, and therefore mirrors the pattern of adhesive transfer printing.Can obtain various aesthetic effects by this way.
The key component of product of the present invention is a cosmetic composition, with the form of substantially dry it is provided on the substrate layer.Cosmetic composition can contain routine and be included in any composition in the cosmetics (particularly mascara), and additional conditions are to select used composition and/or content to make the cosmetics of finished product do basically.Therefore, cosmetic composition can comprise colouring agent (pigment, color lake, dyestuff and ink), pearling agent, glitter, filler, film forming agent, emollient, wetting agent, surfactant, oil, solvent, thickener, structural agent, viscosity modifier etc.
The cosmetic composition of doing can comprise adhesion (bonding) composition, and the mascara formulation that its promotion is done is transferred on the eyelashes and with cosmetic composition from matrix and is fixed on the eyelashes.Suitable adhesion composition includes but not limited to that solvent, oil, adhesive, wax, resin or other do the material of mascara formulation with adhesion characteristics.
Used solvent can be volatile or nonvolatile in the Cosmetic Manufacture of the present invention.Such solvent may reside in the residual cavity of finished product, but should state that whole composition is to do or solid form.Be that solvent can not flow in the finished product structure under environmental condition.Volatile solvent includes but not limited to organic solvent, as hydrocarbon solvent, pure and mild siloxane solvent.That will mention especially is made by cyclomethicone, as for example, and the linear dimethyl polysiloxane of hexamethyl cyclotrisiloxane, octamethylcy-clotetrasiloxane, decamethylcyclopentaandoxane and volatility.The expection non-volatile silicone oil, water miscible and water-insoluble, also be suitable.Preferred nonvolatile oil is a high molecular weight siloxane, as dimethyl polysiloxane (dimethyl siloxane), the poly-trimethicone of phenyl, diphenyl dimethyl siloxane.Suitable water-insoluble siloxanes comprises amine functionality siloxanes, as amino-terminated dimethyl silicone polymer; The siloxanes that phenyl replaces, as diphenyl hexamethyl siloxanes, poly-trimethicone of phenyl or polyphenyl methyl siloxane; Dimethyl polysiloxane; The dimethyl polysiloxane that alkyl replaces; Or its mixture.Other solvents or medium include, but not limited to water, lower alcohol, fatty alcohol, aliphatic ether, fatty acid ester, Permethyl 99A, polyalcohol, glycerine, liposome, stratiform matrix material or its any combination.Expection polybutene and polyisobutene also are useful.When existing, solvent or medium constitute usually the mummification cosmetic compositions about 0.001% to about 20% weight, preferred about 0.01% to about 10% weight, more preferably from about 0.01% to about 5%, or 0.1% to about 1% weight.In some embodiments, cosmetic composition is solvent-free basically, and promptly they contain and are lower than about 1% weight, preferably are lower than the solvent of about 0.5% weight.
Wax can maybe can be used for providing structure to composition as the adhesive in the composition.The wax of the cosmetic formulations that can be used for doing comprises various fractions, synthetic wax, pertroleum wax, alkene polymer chloroflo (as Fischer-Tropsch wax), siloxane wax of animal wax, vegetable wax, mineral wax, native paraffin and composition thereof.Especially, the wax that is used for dried mascara formulation includes but not limited to beeswax, Brazil wax, paraffin, lanolin wax, shellac wax (animal wax), bayberry wax (vegetable wax), ceresine, ceresin(e)wax, microwax (paraffin), polyethylene, Fischer-Tropsch wax, alkyl-dimethyl radical siloxane (siloxane wax), ceresin(e)wax, chaff wax, rice wax and jojoba wax, and composition thereof.
Synthetic wax also comprises, for example, the polyethylene polyalcohol, as PEG-18, PEG-20, PEG-32, PEG-75, PEG-90, PEG-100 and PEG-180, it is with trade name
(The Dow Chemical Company) sells.Can mention Carbowax 1000, it has molecular weight and about 38 ℃ fusing point of 950 to 1,050 scopes, Carbowax 1450, and it has about 1,305 to 1, the molecular weight of 595 scopes and about 56 ℃ fusing point, Carbowax3350, it has about 3,015 to 3, the molecular weight of 685 scopes and about 56 ℃ fusing point, and Carbowax 8000, it has about 7, the molecular weight of 000 to 9,000 scope and about 61 ℃ fusing point.Expecting the wax sample material of natural or synthetic resin or resin derivative, as rosinate, hydrogenated rosins acid esters, polyamide, rubber and latex, also is suitable.
When existing, wax is common, although optional, constitute cosmetic composition about 0.001% to about 90% weight.More commonly, wax constitute cosmetic composition about 0.001% to about 50%, or about 0.001% to about 20% weight.
Polymer, copolymer or terpolymer also can be as adhesive or the film forming agents in the cosmetic composition.Used polymer, copolymer or terpolymer can be water miscible or water-insoluble polymer, and can be natural or synthetic.
The particular instance of polymer comprises hydrogenation dicyclopentadiene, latex-based polyalcohol or copolymer, diethyl phthalate, polyvinylpyrrolidone (PVP), polyethylene, polypropylene, polydialkysiloxane polymer, ethylene/propene copolymer, PVP/ icosa alkene copolymer, polycarboxylic acids based polyalcohol, comprises alkyl acrylate or (methyl) acrylate, acrylic acid (methyl) acrylic acid or acrylamide or (methyl) acrylamide polymer or copolymer; Polyvinyl ester, polyvinyl alcohol, paraffin oxidation thing polymer are as PEO or PPOX; Polyisobutene, polyisoprene, polybutadiene, polyvinyl chloride, polychloroprene, polyacrylonitrile, imide polymer, urethane or poly-urethane, nylon polymer, polystyrene, polyterpene and copolymer thereof.Natural polymer comprises cellulose derivative, alginic acid and derivative thereof, starch and derivative thereof, guar gum and derivative thereof and shellac polymer.Polymer can with the mummification cosmetic compositions about 0.1% to about 50% weight, more commonly about 1% exists to about 10% weight.
Cosmetic composition can comprise the film forming agent of abundant anti-water.A kind of so anti-MJPZ polymer is with trade name
Vinylpyrrolidone/icosa alkene copolymer that V-220 sells (selling) by I SP.Other anti-MJPZ agent comprise polyolefin, polyvinyl pyrrolidone polymers and copolymer, polyethylene, poly-alkyl, polystyrene, triglycerides, epoxy resin, shellac and any combination thereof.
Composition can also contain water-soluble or the water dispersible film forming agent.These comprise, but be not limited to, butylation PVP, it can buy (by the ISP distribution) with trade name GANEX P-904, the 2-butenoic acid, can obtain (by the ISP distribution) with GANTREZ S-97-BF, diethylene glycol (DEG)/CHDM (cyclohexanedimethanol)/different adjacent phenyl dicarboxylic acid esters/SIP (vulcanizing different adjacent phenyl dicarboxylic acid esters) copolymer, it can buy (Eastman) with trade name AQ-55S, the acrylic copolymer emulsion (for example, COVACRYL A15 and COVACRYL E14, by the LCW distribution), acrylate/ammonio methacrylate copolymer in the water (for example, ULTRASOL 2000C, by the Presperse distribution), modified starch (for example, PURE COAT B793, by Grain Processing distribution), sulfonated polystyrene (for example, FLEXAN II, by National Starch distribution), acrylate/C12-22 alkylmethacrylate copolymer (for example, ALLIANZ OPT, by the ISP distribution), ethene carbamyl/acrylic acid aminomethyl propane sulfonic acid/methacrylic acid (for example, ACUDYNE SCP is by Rohm and Haas distribution), acrylate/the ethylhexyl acrylate copolymer (for example, DAITASOL SJ, by Daito Kasei Kogyo Co., the Ltd distribution) or its any combination.
Can also comprise water absorbing agent or hypersorption polymer in the composition.When it was contacted with water, the water absorbing agent polymer provided expansion effect, and therefore it can be advantageously comprised, so that dense (volumizing) to be provided effect to eyelashes.When comprising these polymer, make the dense method of eyelashes comprise the step that at first composition described herein is applied in eyelashes, then second step that eyelashes are wetting.The water absorbing agent polymer comprises that partial cross-linked neutrality gathers (acrylic acid), polyacrylamide, poly-(ethylene oxide,1,2-epoxyethane), poly-(vinyl alcohol), sodium carboxymethylcellulose, sodium alginate or its any combination.Other suitable water-absorbent agent compositions comprise, but be not limited to, PAA (for example, AQUA KEEP, by Kobo Products, Inc distributes) and acrylamide/sodium acrylate copolymer (for example, WATER LOCK G series and WATER LOCK A series are by Grain Processing Corp. distribution).
Expection cationic polymerization film forming agent also is useful.Must mention cationic polymerization film forming agent polyquaternium-7 (Polyquaternium-7), it is the quaternary ammonium salt of acrylamide/dimethyl diallyl ammonium chloride copolymer, with trade name
Super 7 sells (by CibaSpecialty Chemicals, Inc. sells).Other suitable cationic polymers include, but not limited to polyquaternium-4, polyquaternium-5, polyquaternium-6, polyquaternium-7, polyquaternium-10, polyquaternium-22, polyquaternium-37, polyquaternium-47 or its any combination.
Composition can also comprise anti-oily film forming agent.Suitable anti-oily film forming agent comprises, but be not limited to acrylic resin (acrylate), polyacrylate, acrylamide polymer and copolymer and quaternary salt thereof, urethane, poly-urethane, polyester, polysaccharide, polyamide, polyalcohol, polyethers, cellulosics, protein, polyaminoacid, the ester that is derived from rosin, latex or its any combination.
Silicone resin can be used as adhesive or film forming agent is included in the composition.Expect that a useful especially class silicone resin is the silicone resin (that is T-resin) with secondary position connection of siloxy monomer.Such silicone T-resin comprises alkyl and/or aryl siloxy, but preferably includes the aryl siloxy, as the phenyl siloxy, to improve the refractive index of resin.The example of this resin is aminomethyl phenyl silsesquioxane or poly-phenyl silsesquioxane.Other suitable silicone T-resins include, but not limited to the C described in the U.S. Patent Publication No. 2004/0180011
2-20The alkyl phenyl silsesquioxane resin is incorporated herein by reference its disclosure at this.Expection propyl group phenyl silsesquioxane resin (Wacker
SPR 45 VP can be from Wacker Chemical, Adrian, Mich obtains) particularly useful.When measuring down for 82 ℃, this polymer has 1.55 refractive index as liquid, when measuring down for 25 ℃, has 1.57 refractive index as film.Have the high index of refraction resin of (for example, being higher than 1.47) by use, will provide high glaze to eyelashes.
Also plasticizer can be included in the composition, suitable manufacturing methods includes but not limited to ethylene glycol and ethylene glycol derivative (ether and ester), acid esters, as citrate, phthalic acid ester, adipate ester, carbonic ester, tartrate, phosphate and sebacate; With the oxyethylation derivative, as oxyethylation oil (for example, castor oil and silicone oil).
Other viscosity modifiers or gelling agent can be used for doing mascara formulation.These comprise bentonite, triglycerides, aluminum stearate, C
18-C
36Acid glycol ester, stearine, glycerol tri-docosanoic acid ester etc.Expection solid gelling agent is suitable, includes but not limited to the ester of aliphatic acid gelling agent, aliphatic acid gelling agent and the acid amides gelling agent of acid amides, hydroxy acid, hydroxy fatty acid and other types.Mention that especially the ester end-blocking gathers (ester-acid amide) gelling agent.Other viscosity modifiers or gelling agent comprise alginate, carbomer, natural gum, carragheen, starch or silicate etc.
Composition of the present invention contains one or more colouring agents usually.Suitable colouring agent comprises pigment, color lake, dyestuff and ink, as known in the art with C.T.F.A.CosmeticIngredient Handbook, and front page, described in 1988, at this its content is incorporated herein by reference.Organic pigment comprises, for example, and carbon pigment, FD﹠amp; C dyestuff, D﹠amp; The C dyestuff comprises D﹠amp; C red number 2,5,6,7,10,11,12,13,30 and 34, D﹠amp; C yellow number 5, FD﹠amp; C blue number 1 and purple number 2.Other colouring agents comprise FD﹠amp; C red number 3, FD﹠amp; C red number 40 (AlluraRed AC), FD﹠amp; C red number 19, FD﹠amp; C red number 9, FD﹠amp; C red number 21, FD﹠amp; C red number 27, FD﹠amp; C red number 13, FD﹠amp; C red number 7, FD﹠amp; C red number 6, FD﹠amp; C red number 30, FD﹠amp; C red number 36, FD﹠amp; C orange number 4, FD﹠amp; C orange number 5, FD﹠amp; C orange number 10, FD﹠amp; C yellow number 5, FD﹠amp; C yellow number 6, FD﹠amp; C green number 5, and composition thereof.The exemplary inorganic pigment includes, but not limited to metal oxide and metal hydroxides, as magnesia, magnesium hydroxide, calcium oxide, calcium hydroxide, aluminium oxide, aluminium hydroxide, iron oxide (α-Fe
2O
3, y-Fe
2O
3, Fe
3O
4, FeO), red iron oxide, yellow iron oxide, black iron oxide, iron hydroxide, titanium dioxide, rudimentary peptide oxide, zirconia, chromium oxide, chromium hydroxide, manganese oxide, cobalt oxide, cerium oxide, nickel oxide and zinc oxide, and composite oxides and complex hydroxide, as iron titanate, cobalt titanate and cobalt aluminate.Other suitable colouring agents comprise ultramarine (that is sulfur-bearing sodium silicoaluminate), Prussian blue, manganese violet, bismuth oxybromide, talcum, mica, sericite, magnesium carbonate, calcium carbonate, magnesium silicate, Magnesiumaluminumsilicate, silica, titanizing mica, iron oxide titanizing mica, bismoclite etc.
Colouring agent can be the surface of for example modifying with fluoropolymer, to regulate one or more features of colouring agent, and as for example U.S. Patent number 6,471,950,5,482,547 and 4,832, described in 944, at this its content is incorporated herein by reference.Pigment and/or filler can cover with silicon fluoride, to improve water-resistance and/or grease resistance, and as U.S. Patent number 6,315, described in 990, at this its disclosure is incorporated herein by reference.
Colouring agent can exist with any content of sending required effect needs.Possible colouring agent load will for composition about 0.001% to about 95% weight, more commonly about 0.001% to about 50% weight, or composition about 0.01% to about 25% weight.In other embodiments, cosmetic composition is transparent, therefore will not contain colouring agent.
Composition can also contain coloured polymer, and it contains the color development figure that is grafted on the polymer chain or it contains the copolymer that is comprising chromophoric monomer.Suitable polymeric colorant includes but not limited to U.S. Patent number 4,804,719; U.S. Patent number 4,999,418; U.S. Patent number 5,030,708; U.S. Patent number 5,032,670; U.S. Patent number 5,043,376; U.S. Patent number 5,102,980; U.S. Patent number 5,106,942 and U.S. Patent number 5,194, those described in 463 are incorporated herein by reference its disclosure at this.
Pearling agent can be present in the composition to about 50wt% with about 0wt%, based on the gross weight of composition.Suitable pearling agent comprises the mica that is covered by titanium oxide, iron oxide, natural colouring matter or bismoclite, as painted odenite.Suitable pearlescent colorants includes but not limited to bismoclite, guanine and titanium composite material, contains titanium composition, titanium dioxide, titanium lower oxyde or oxynitriding titanium, and is disclosed in 569 as U.S. Patent number 5,340, at this its content is incorporated herein by reference.Preferably, pearling agent exists to about 20wt% with about 1wt%, based on the gross weight of composition.
In some embodiments, wish in composition, to comprise glitter, to obtain unique visual effects.The limiting examples of these glitters comprises the covering/PET of handling and the mica of titanium dioxide covering.Such covering/limiting examples of the PET handled can be with trade name 0.008 " square Dark Goldpoly
*Flake obtains from Glitterex Corp..The limiting examples of the mica that titanium dioxide covers can obtain from Presperse Inc. according to trade name Flonac ME 10C.Other materials as glitter comprises, for example, metallic particles, as aluminium, copper, silver, gold and brass, the particle of transparent or coloured solid organic material, comprise poly-(ethylene terephthalate), PMA and poly-(vinyl butyral), and the particle of plated film or paper, as poly-(ethylene terephthalate) film of aluminium covering.
Can also comprise and disturb vision to dodge the look pigment,, its disclosure is incorporated herein by reference at this as disclosed in the U.S. Patent Publication 2004/0076650 to give the iridescence effect.Such pigment can be buied with trade name Such Infinite Colors (Shiseido), SicopearlFantastico (BASF), Colorstream (Merck), Colorglitter (3M) and Chromaflair (Flex).Can also comprise the interference fiber, as U.S. Patent number 5,472, described in 798, at this its content is incorporated herein by reference.Can add other compositions that give the required visual effect of eyelashes.
Dried cosmetic formulations can also randomly comprise filler.Term " filler " should be understood to colourless or white, and is inorganic or synthetic, stratiform or non-laminate granular.Filler comprises silica, poly-methyl methacrylate base (PMMA), alumina, barium sulfate, talcum, zinc stearate, mica, kaolin, nylon powder, polyethylene powder, Teflon, starch, boron nitride etc.The concentration of filler can be for about 1% to about 50% weight, and about 1% to about 20% or about 1% to about 10% weight.Suitable filler also comprises the copolymer microsphere body, as EXPANCEL (Nobel Industries), POLYTRAP (Dow Corning) and silicone resin microballon (from the TOSPEARL of Toshiba).
Composition of the present invention can be chosen wantonly and comprise a plurality of fibers that are scattered in wherein, to increase the volume of eyelashes, that is, improves its thickness and length.Fiber can be the known any kind of cosmetic field, and can be natural or synthetic.The preferred thermoplastic fiber is as those of polyethylene, polypropylene or nylon.
In addition, composition can comprise conditioning agent and emollient/NMF.Conditioning agent can include but not limited to marine algae extract, wheat amino acid, wheat gluten, hydrolyzed vegetable protein and derivative, keratin amino acid, albumin, yeast extract, hydrolysis mucopolysaccharide, HAP, shitosan, phytantriol, hydrolysis zein, hydrolytic soya bean protein, hydrolysis breast, newborn amino acid and composition thereof.Emollient/the oil of preserving moisture that can mix in the present composition includes but not limited to Jojoba Oil, lanolin oil, coconut oil, palm kernel glyceride, grape-kernel oil, evening primrose oil, sesame oil, castor oil, Bai Manghua seed oil, fat of Oromaius norvaehollandeae, dimethicone copolyol Bai Chihua seed oleate, wheat-germ oil, Macadamia nut oil, avocado oil and composition thereof.Other emollients comprise cetostearyl alcohol caprylate, octyl palmitate, butanediol, propane diols, glycerine, glycerin monostearate, paraffin oil, Trivent OCG, Triglyceride DDD, sher butter and silicone oil.
Composition may further include one or more and is selected from other following compositions: anesthetic, anti-allergic agent, antifungal agent, antiinflammatory, antimicrobial, antiseptic, chelating agent, emollient, emulsifying agent, spices, wetting agent, lubricant, masking agent, medicament, NMF, pH conditioning agent, anticorrisive agent, protective agent, smoothing preparation, stabilizing agent, opacifier, surfactant, thickener, viscosity-control additive, vitamin, pigment, bioactivator and any combination thereof.
In the preferred embodiment of the invention, cosmetic composition contains Acronal V 215 (BASF), the aqueous polymer dispersion that this is based on acrylate, be dissolved among the Dowanol contain ink phenol resin and cellulose derivative and/or by the acrylic acid that is dissolved in the water, Yi Xi ﹠amp; Pigment in the solution of cellulose derivative/ink of dyestuff composition and optional carbon black are as colouring agent.
Can cosmetic composition be put on substrate layer by any suitable manner, comprise that routine is used to prepare the method for cosmetics " sample ".For example, thin film forming application technology in bulk as extruding or spray technique, has been used to prepare the cosmetics sample, as U.S. Patent number 6,691, described in 872, at this its disclosure is incorporated herein by reference.Such technology makes cosmetic composition can be evenly distributed on the surface of substrate layer.In addition, can be by industrial printing process, (include but not limited to Redd Europe by industrial printing machine, Main Titles and LetraSet) or by medical adhesives and tape manufacturers (as Mactac, ScapaGroup Plc, Adhesives Research Ltd and Tape Specialties), produce the present invention.
In other embodiments, cosmetic composition is imprinted on the substrate layer.The method that cosmetics are imprinted on the matrix also is known usually, and is disclosed in 386 as U.S. Patent number 5,192, at this its disclosure is incorporated herein by reference.Printing process makes cosmetic composition accurately be deposited on the matrix with required content and pattern.In addition, use printing process, can print out product, unique effect is provided with on being applied in eyelashes the time with two or more different cosmetic colors.
In addition, pattern can be mixed and cooperatively interact or match with above-mentioned any shape, lines or wherein contained other structures.Such combination can be used with the single application situation, promptly on the opposite face of identical layer, or uses according to the order of sequence with two or more single application situations.For example, use for the first time and circle can be deposited on the eyelashes, ensuing use will complete lines, dotted line or a shape or one group of shape of being different from use for the first time be deposited on the eyelashes.
With reference to Fig. 1, the limiting examples of the type of effect that explanation can obtain.In a main embodiment, product can contain the uniform coating of coloured mascara, makes when smearing on the eyelashes, and coloured mascara is transferred on the eyelashes in uniform relatively mode, to produce the appearance suitable with the conventional mascaras product.Mascara composition can be applied in the upside of eyelashes, the downside of eyelashes, or both.
Fig. 1 and 14 has also illustrated the special pattern effect that can obtain, for example, and by two or more colors are imprinted on the substrate layer.In various variations according to this embodiment, mention especially color gradient is applied on the substrate layer those, make when being transferred to cosmetic composition on the eyelashes, on eyelashes, form color gradient.Color gradient can be along the major axis of substrate layer (promptly, along line I-I) use, make root from every eyelashes to the pointed one-tenth color gradient of eyelashes, or can from left to right stride across substrate layer and form color gradient (promptly, I-I is vertical with line), make that from left to right striding across eyelashes forms color gradient.Except color gradient, can use two or more colors in the band separately to obtain similar effect, for example, make that the eyelashes near root partly are a kind of colors, and be different color etc. near the part of tip.To aesthetic effect in essence without limits, the aesthetic effect that can obtain includes but not limited to, rainbow pattern, wave pattern and sunrise pattern.
As shown in Fig. 1 and 14, substrate layer can further comprise a plurality of tack particulates, and it can use separately, or uses together in conjunction with cosmetics.Particulate self can contain the mummification cosmetic compositions or can be made by polymeric material etc., and generally includes adhesive, is transferred on the eyelashes promoting.Particulate can constitute any pattern, and point can be uniform, also can be with different size and shape, and it is placed with any direction in space that obtains specific or required effect needs.Such particulate can form complete lines, dotted line, above-mentioned arbitrary bigger shape, or any design that can print by one or more above-mentioned printing technologies.
With reference to Fig. 9, limiting examples is rendered as arrays of microparticles with the present invention.Particulate can be any size, although not must, be generally about 10 μ m (micron) to about 2mm diameter, more common be extremely about 1mm diameters of about 50 μ m, or about 500 μ m about 0.5mm diameter extremely.A plurality of particulates can be same colors, maybe can be different colours.Have been found that when dried mascara product is particulate form, obtained to thicken effect, if particularly particulate is supported on above on the eyelashes with suitable size.
Illustrated also among Fig. 1 that transparent composition gives the purposes of eyelashes matrix, its support has also separated eyelashes.This transparent composition can comprise transparent adhesiveness polymer, for example, it is imprinted on the substrate layer with certain pattern (as, many rows).When composition was transferred on the eyelashes, that row's transparent composition substantially perpendicularly was deposited on the eyelashes, to form matrix.Perhaps, can be used as uniform film covers transparent composition on the substrate layer.By this way, the eyelashes of whole length, or its part will be wrapped in the polymeric membrane.Film can be a certain size, makes it prolong and slightly surpasses the eyelashes tip, and so that continuous " firmly " edge to be provided, can be another kind of size maybe, make the eyelashes tip surpass edge, the edge that " featheriness " outward appearance is provided to provide.In addition, the present invention can adopt the similar pattern shown in lines or Fig. 3, makes the eyelashes tip prolong, to give the effect of eyelash growing.
In another main embodiment, provide and to have done mascara formulation and be applied in method on the eyelashes, it comprises eyelashes contacts is deposited on dried mascara formulation on the carrier matrix, and optional change the temperature of mascara or give eyelashes and mascara formulation is exerted pressure, light or its combination, so that mascara formulation is sticked on the eyelashes.In another embodiment, exert pressure for mascara formulation and matrix.In another embodiment, when the contact eyelashes, apply heat for mascara formulation and matrix.In another embodiment, by keeping the regular hour section that mascara is sticked on the eyelashes contacting of preparation and eyelashes, and do not exert pressure, heat or light.Carrier matrix is not the conventional brush applicator that is used to smear mascara.In one embodiment, carrier matrix is a thin-film material.In another embodiment, using dauber will do mascara formulation is transferred on the eyelashes.This dauber is stained with dried mascara on one or two surface of contact eyelashes.Fig. 1 has described with Fig. 2 and has speckled with the dauber example of doing mascara formulation on the surface that contacts eyelashes.
The method of smearing mascara makes the mascara that will have various patterns, design or effect be applied on the eyelashes, to obtain required eyelashes outward appearance.According to the present invention, required pattern or effect can optionally spread upon on eyelashes upper surface or the eyelashes downside.In one embodiment, the mascara that will have a required colouring agent pattern smears on the eyelashes.Fig. 4 has described several color patterns or gradient, and this uses the present invention is possible.In another embodiment, the mascara that will have little pattern or a pattern smears on the eyelashes.In another embodiment, the mascara that will contain reflecting material such as glitter smears on the eyelashes.Fig. 6 has illustrated the eyelashes that used the mascara that contains glitter.As limiting examples, the finished product of mascara product of the present invention can be mute light, half mute light, Gao Guang, half Gao Guang's and combination.In another embodiment, the mascara that will have required visual effect such as rigidity " hard eyelashes " effect or have " black make mute luminous point " pattern smears on the eyelashes.Fig. 5 has presented the eyelashes with " hard eyelashes " effect.Fig. 6 has illustrated and has had the eyelashes of " black make mute luminous point " pattern.In another embodiment, can smear on the eyelashes having the mascara of single key element as " mute light stain ".This method can easily be controlled the eyelashes oil mass to eyelashes to be applied by the dried eyelashes oil mass that control is deposited on the carrier matrix.The present invention can give vividness, length, visual effect, comprises holographic and volume, and combination.In addition, use the present invention can easily obtain to have the eyelashes of thin or thick mascara coating.
Figure 10 illustrated according to one embodiment of the invention, wherein with a plurality of cosmetics particulates and binder deposition on the transfer film substrate layer.Substrate layer covers product, is removed with exposed adhesive and cosmetics particulate.When the adhesive that exposes pressed facing to eyelashes, it adhered on the eyelashes and with particulate and is transferred on the eyelashes from the transfer film substrate layer.Particulate only faintly is attached on the transfer film, and therefore easily is transferred on the eyelashes with adhesive.
In an interesting embodiment, product can have the pressure sensibility ink on the surface of the transfer printing layer on cosmetics opposite, as shown in Figure 11.When applying enough pressure when being transferred to cosmetics on the eyelashes, the pressure sensibility ink will change color, and therefore as the product success and the indication of evenly smearing.In another embodiment, product can use sense of touch indication, as when applying enough pressure and be transferred to cosmetics on the eyelashes, changes the outstanding protuberance of transfer layer, to remind the consumer.
Some pattern that has been found that the printing cosmetics is preferably for obtaining covering uniformly and cosmetics to the good transfer on the eyelashes.As shown in Figure 12, for the cosmetics (printing along line I-I) of line style, the efficient of transfer is low relatively, and this is because eyelashes are not arranged with the spacing identical with the cosmetics line.The hexagon pattern of the hexagon form point that expection is tilted has good adhesive force efficient to eyelashes.Yet, the invention is not restricted to print any specific pattern of cosmetics.
Illustrated among Figure 13 according to exemplary application device of the present invention.In embodiment " a ", folding product is loaded in the groove that forms between two rigid plate sample films, it has according to the curved configuration of the summary of eyelid profile.In operation, the user exerts oneself to action bars, and this makes plate bump together, to be transferred to the pressure that provides essential on the eyelashes to cosmetics.Expect that the mechanism that any such action bars is controlled will be applicable to the pressure that generation is enough, so that cosmetics are transferred on the eyelashes.In embodiment " b ", explanation is also arranged in Figure 13, product is placed the internal recess of clavate type device.This groove is at the terminal of device and be placed in slidably between the solid film edge in the device and form, make that slidably film can move towards the device edge, by extruding such as thumbs,, cosmetics are transferred on the eyelashes to obtain product and to form enough pressure.Yet, do not need specific application device with understanding, and can wait by the extruding between forefinger and the thumb and use this product simply.
Be appreciated that term " substrate " and " transfer " when being used for modifying " film " or " layer ", do not plan to be used for limits product to construct, but be used to help the non-limiting embodiments shown in reader understanding's accompanying drawing.
Claims (21)
1. mascara applicator system, it comprises:
Folding transfer film is configured to curvature near eyelashes with the concave curvature at its at least one edge, makes that with described edge described transfer film is maximized to the covering of described eyelashes when eyelashes are placed.
Be deposited on solid or semi-solid cosmetic composition on described transfer film at least a portion simultaneously;
Wherein described collapsible transfer film is constructed to be permeable to fold and encases eyelashes, make when putting on pressure on the folding transfer film, be transferred to described cosmetic composition on the eyelashes and thereon by described adhesive.
2. according to the mascara applicator system of claim 1, wherein said transfer film comprises paper.
3. according to the mascara applicator system of claim 1, wherein said transfer film comprises that roughly perforation in the middle of described film or folding line cover eyelashes to help folding.
4. according to the mascara applicator system of claim 1, wherein said cosmetic composition comprises a plurality of cosmetics particulates.
5. according to the mascara applicator system of claim 1, wherein said cosmetics particulate has about 50 microns diameters to about 0.5mm.
6. according to the mascara applicator system of claim 4, wherein described cosmetics particle alignment is become the hexagon pattern of inclination.
7. according to the mascara applicator system of claim 1, wherein said cosmetic composition comprises carbon black.
8. according to the device of claim 1, wherein said cosmetic composition is included in lip-deep color gradient of described transfer film or pattern.
9. according to the mascara applicator system of claim 1, wherein said cosmetic composition is transparent.
10. according to the mascara applicator system of claim 1, wherein by printing process described cosmetic composition is put on the described transfer film, described printing process is selected from lithographic printing, aniline printing, electrostatic printing, laser printing, release coat, digital printed, ink-jet printing, rotogravure and serigraphy.
11. the mascara applicator system according to claim 1 further comprises the release coat that is deposited on the described transfer film, to promote separating of in use described cosmetic composition and described transfer film.
12. according to the mascara applicator system of claim 1, wherein said release coat comprises non-sticky siloxanes or mixture of siloxanes.
13. mascara applicator system according to claim 1; further comprise by adhesion layer and be layered in substrate film on the described transfer film; and cover described cosmetic composition; to protect described cosmetic composition before use; described substrate film can be removed before use, to expose described cosmetic composition and described adhesion layer.
14. according to the mascara applicator system of claim 13, wherein said substrate film comprises transparent plastic material.
15. according to the mascara applicator system of claim 14, wherein said substrate film comprises biaxially oriented PET polyester film.
16. according to the mascara applicator system of claim 1, wherein said adhesive comprises pressure-sensitive adhesive.
17. according to the mascara applicator system of claim 1, wherein said transfer film comprises that indicator reminds the user when successfully smearing on the eyelashes at this product.
18. according to the mascara applicator system of claim 1, wherein said indicator is included in the lip-deep pressure sensibility ink of transfer film on cosmetic composition opposite.
19., comprising with the method for cosmetic applying to the eyelashes:
(i) provide matrix with binding compositions and the cosmetic composition of doing or doing basically that is deposited on the one surface;
(ii) cover on the eyelashes matrix is folding, make at least a portion of described eyelashes contact with cosmetic composition with described adhesive; With
Exert pressure (iii) for the offside of described folding matrix, so that cosmetic composition is transferred on the eyelashes.
20. according to the method for claim 18, further comprise, be transferred on the eyelashes to promote it with the composition heating.
21., wherein use application device to carry out described step of exerting pressure for described folding matrix offside according to the method for claim 18.
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| EP2211661A4 (en) | 2015-01-07 |
| EP2211661A1 (en) | 2010-08-04 |
| CA2705756C (en) | 2016-02-16 |
| BRPI0820084A2 (en) | 2015-06-30 |
| US20100218781A1 (en) | 2010-09-02 |
| TW200936073A (en) | 2009-09-01 |
| CA2705756A1 (en) | 2009-05-28 |
| JP2011504120A (en) | 2011-02-03 |
| MX2010005474A (en) | 2010-09-24 |
| JP5539215B2 (en) | 2014-07-02 |
| WO2009067396A1 (en) | 2009-05-28 |
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