CN101864207A - Dye type sunproof ink-jet spraying printing ink - Google Patents
Dye type sunproof ink-jet spraying printing ink Download PDFInfo
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- CN101864207A CN101864207A CN 201010195746 CN201010195746A CN101864207A CN 101864207 A CN101864207 A CN 101864207A CN 201010195746 CN201010195746 CN 201010195746 CN 201010195746 A CN201010195746 A CN 201010195746A CN 101864207 A CN101864207 A CN 101864207A
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Abstract
The invention relates to dye type sunproof ink-jet spraying printing ink, which is prepared through the following steps: respectively weighing C.I. active red 21 or C.I. acid yellow 18 or C.I. direct blue 79 or C.I. active black 8 dye, CSS-4 sunscreen preparations, isopropanol, trolamine, N-methyl-2-ketopyrrolidine, dodecyl benzene sodium sulfate, glycol, NN-dimethylformamide and the balance of deionized water; placing the materials into a stirring container to be stirred and uniformly mixed; standing and filtration to obtain finished products of dye type sunproof ink-jet spraying printing ink. The invention has the advantages of good quality and low price, is applicable to spraying printing machines in different types, has rich and showy colors, strong stability, strong tinting strength, tiny undissolved substances, capability of automatically cleaning a spraying head, no blockage, good flowability, smooth spraying effect, no wrinkle and no proliferation of the direct spraying images in textile products, high color fastness and ultraviolet irradiation resistance. Images can be stored for 20 years without color degradation, and the head can not be blocked within half a year when the spraying printing machine is in a power-off state.
Description
Technical field
The present invention relates to a kind of consumptive material of ink-jet air brushing, particularly a kind of dye type sunproof ink-jet spraying printing ink, the while also relates to the preparation method of this dye type sunproof ink-jet spraying printing ink.
Background technology
In the prior art, there is two types ink-jet jet ink in market: a kind of is the ink-jet jet ink of pigment style; Another kind is the ink-jet jet ink of dye-type; Their difference of ink-jet jet ink of the ink-jet jet ink of pigment style and dye-type is: wherein the advantage of pigment jetting jet ink is a sun-proof, reason is that the tinting material of pigment jetting jet ink is selected mineral pigment for use, owing to be mineral pigment, the particles of ink that it is made is thicker, causes printhead to be blocked easily; The ink-jet jet ink cost height of pigment style, pigment style jet ink chromatogram is incomplete, and print image is not bright-coloured, and image is difficult to go back the original image realistic colour, therefore is difficult to a large amount of uses.Dye-type ink-jet jet ink wherein, its advantage is that cost is low, and chromatogram is complete, and it is bright-coloured to print image, can go back the original image realistic colour, is accepted by people easily.But the defective of dye-type ink-jet jet ink is a sun-proof not, is difficult for the prolonged preservation image.Dye-type ink-jet jet ink only obtains sun-proof could be fairly perfect, could penetration and promotion use.At present, the dye-type ink-jet jet ink colour fastness to light grade on the market reaches colour fastness to light class 5 level seldom generally below 5 grades.The light industry standard QB/T 2730.2-2005 of People's Republic of China (PRC) colour fastness to light class requirement: 〉=4 grades (indoor); 〉=6 grades (family); At present, dye-type ink-jet jet ink colour fastness to light grade does not generally reach requirement.
Chinese patent application number: 200510136809 disclose " ink-jet dye of anti-oscillate and ink thereof " this invention is used for the digital ink-jet printed ink-jet dye of computer ink-jet printing, color painting and yarn fabric, the ink for ink-jet print of forming by this dyestuff and low-boiling point alcohol, wetting Agent for Printing Inks and high boiling organic solvent and water, because the special construction of ink-jet dye, make formed writings and image under the warm on ground such as China south, have the anti-characteristics of vacillating, keep sharpness.
Chinese patent application number: 200910111585 disclose " dye formulation of color painting and dyeing is determined method " this invention provides a kind of dye formulation of color painting and dyeing to determine method, described definite method is: will need painted dyestuff earlier according to an initial volume concentration, with the direct Freehandhand-drawing of the dyestuff of this initial volume concentration or dyeing on white sample cloth, treatment samples cloth, sample cloth after the dyeing and the sample that need dye estimated check colors, when color is consistent, determine that then the volumetric concentration of this dyestuff is the volumetric concentration of color matching.
Chinese patent application number: 200810055294 disclose " dye-type Neutral writing ink and preparation method thereof " this invention provides a kind of dye-type Neutral writing ink, comprise red, yellow, blue-black, orange, green five kinds of colors, its component comprises: water-soluble dye, condensing agent, copolymer fluid, glycerine, lubricant, moisture adsorbent and distilled water.Preparation method: get the mixed condensing agent that gets of the vitriol oil, formaldehyde and water; Get sulphosalicylic acid and add dissolved in distilled water, add formaldehyde again, the acetate condensation makes copolymer fluid; Condensation reaction formation high molecular dye is taken place in formaldehyde in water-soluble dye and the condensing agent and copolymer fluid under the effect of acid, add other component again and make the dye-type Neutral writing ink.Its preparation technology is simple, cost is low, prepared dye-type Neutral writing ink fluent writing, not stifled pen, and stable performance, water resisting property is good.
Chinese patent application number: 200710002807 disclose a kind of ink composition of black dyes constituent allotment.Be used for the textile number printing and dyeing.
Chinese patent application number: disclose 200,810,081,322 1 kinds of ink compositions and made, be applicable to the cellulosic fibre ink-jet cloth printing by chemically-reactive dyes or its salt or organic buffer agent or its esters.
In recent years, fail to circulate on market though disclose type of dye ink on the document, the inventor is according to being engaged in ink undergoing analysis research in twenties years, and may there be such or such problem in the prematurity still of above-mentioned type of dye ink.Do not find the sun-proof type of dye ink of obvious results by inquiry.
Summary of the invention
An object of the present invention is to provide a kind of superior in quality, cheap dye type sunproof ink-jet spraying printing ink, this dye type sunproof ink-jet spraying printing ink is suitable for the air brushing printer of different type of machines, adopts circulation to fill, economical with materials, rich color, gorgeous, stability is strong, strong coloring force, insolubles is small, far below the shower nozzle aperture, can clean shower nozzle automatically, do not stop up, spray smoothly, directly spray the textile images indiffusion of not wrinkling, the color fixation fastness height, ultraviolet radiation resisting, image preserve 20 years colour-fast, print the DPI height, the ink good fluidity, can be in half a year, air brushing machine plug not under off-mode.
Dye type sunproof ink-jet spraying printing ink of the present invention, this dye type sunproof ink-jet spraying printing ink is made up of following component by weight percentage:
Dyestuff 3-10%, CSS-4 sun-screening agent 3--6%, Virahol 8--12%, trolamine 1-3%, N-N-methyl-2-2-pyrrolidone N-1-5%, dodecyl phenenyl sulfate 1-5%, ethylene glycol 8-10%, NN one dimethylformamide 1-5%, its surplus of deionized water;
Wherein dyestuff is C.I. reactive red 21 (C.I.Reactive Red21) or C.I. turmeric yellow 18 (C.I.Acid yellow18) or C.I. sun blue 79 (C.I.Direct Blue79) or C.I. reactive black 8 (C.I.Reactive black8).
Preferably, described dye type sunproof ink-jet spraying printing ink comprises red ink/yellow ink/blue ink/black ink, and this dye type sunproof ink-jet spraying printing ink is made up of following component:
Wherein: red ink is made up of following component by weight percentage:
C.I. reactive red 21 dyestuffs 6.2%, CSS-4 sun-screening agent 3%, Virahol 10%, trolamine 1%, N-N-methyl-2-2-pyrrolidone N-3%, dodecyl phenenyl sulfate 3%, ethylene glycol 10%, NN one dimethylformamide 3%, its surplus of deionized water;
Wherein: yellow ink is made up of following component by weight percentage:
C.I. turmeric yellow 18 dyestuffs 4%, CSS-4 sun-screening agent 3%, Virahol 10%, trolamine 1%, N-N-methyl-2-2-pyrrolidone N-3%, dodecyl phenenyl sulfate 3%, ethylene glycol 10%, NN one dimethylformamide 3%, its surplus of deionized water;
Wherein: blue ink is made up of following component by weight percentage:
C.I. sun blue 79 dyestuffs 6%, CSS-4 sun-screening agent 3%, Virahol 10%, trolamine 1%, N-N-methyl-2-2-pyrrolidone N-3%, dodecyl phenenyl sulfate 3%, ethylene glycol 10%, NN one dimethylformamide 3%, its surplus of deionized water;
Wherein: black ink is made up of following component by weight percentage:
C.I. reactive black 8 dyestuffs 3%, CSS-4 sun-screening agent 3%, Virahol 10%, trolamine 1%, N-N-methyl-2-2-pyrrolidone N-3%, dodecyl phenenyl sulfate 3%, ethylene glycol 10%, NN one dimethylformamide 3%, its surplus of deionized water.
Described CSS-4 sun-screening agent (No. 4, sun-screening agent), molecular formula: C
14H
12O
6S, CSS-4 sun-screening agent (No. 4, sun-screening agent) is the beige particle powder (Benzophenone), and water-soluble, maximal ultraviolet absorption peak 288nm/325nm ± 1 is provided by Liri Science and Technology Development Co Ltd, Shanghai.
Described Virahol, another name:
DimethylcarbinolThe 2-propyl alcohol, also do in the industry:
IPA
Name of commodity in English: iso-Propyl alcohol; Isopropanol; Dimethylcarbinol;
2-Propanol is commonly called as IPA molecular formula: C3H8O; (CH3) 2CHOH
Described trolamine: molecular formula: C6H15O3N structural formula: N (CH2CH2OH)
English name: Triethanolamine (TEA)
Described N-methyl-2 pyrrolidone: chemical name: N-Methyl pyrrolidone; 1-methyl-2 pyrrolidone; N-N-methyl-2-2-pyrrolidone N-molecular formula: C
5H
9NO molecular weight: 95 ℃ of molecular structural formulas of 202 ℃ of flash-points of 99.134 boiling points:
Described Sodium dodecylbenzene sulfonate, molecular formula C18H29SO3Na, molecular weight 348.48, solid, white or pale yellow powder can be water-soluble.
Described ethylene glycol (ethylene glycol) has another name called " glycol ", " 1,2 ethylene glycol ", is called for short EG.Chemical formula is (HOCH2)
2
Described N.N-dimethyl formamide: chemical name N.N-dimethyl formamide, molecular formula: C3H7NO, product specification: be used for chemical industry, content 99 (%).
Described deionized water is that impurity yin, yang ion is all removed, so be called deionized water through the later water of yin, yang ion exchange column.
Above-mentioned raw materials of the present invention is all commercially available.
Another object of the present invention provides a kind of preparation method of dye type sunproof ink-jet spraying printing ink, may further comprise the steps:
By weight percentage with described dyestuff, CSS-4 sun-screening agent, Virahol, trolamine, the N-N-methyl-2-2-pyrrolidone N-, dodecyl phenenyl sulfate, ethylene glycol, NN one dimethylformamide, its surplus of deionized water is weighed respectively, insert mix in the stirred vessel after, leave standstill, filter, get the dye type sunproof ink-jet spraying printing ink finished product.
Preferably, the preparation method of this dye type sunproof ink-jet spraying printing ink is characterized in that: may further comprise the steps:
By weight percentage with described C.I. reactive red 21 (C.I.Reactive Red21) or C.I. turmeric yellow 18 (C.I.Acid yellow18) or C.I. sun blue 79 (C.I.Direct Blue79) or C.I. reactive black 8 (C.I.Reactive black8) dyestuff 5-10%, CSS-4 sun-screening agent 3--6%, Virahol 8--12%, trolamine 1-3%, N-N-methyl-2-2-pyrrolidone N-1-5%, dodecyl phenenyl sulfate 1-5%, ethylene glycol 8-10%, NN one dimethylformamide 1-5%, its surplus of deionized water is weighed respectively, insert mix in the stirred vessel after, leave standstill, filter, packing gets the printing and dyeing ink that finished product directly sprays textiles.
Preferably, the preparation method of this dye type sunproof ink-jet spraying printing ink is characterized in that: may further comprise the steps:
By weight percentage with described C.I. reactive red 21 (C.I.Reactive Red21) or C.I. turmeric yellow 18 (C.I.Acid yellow18) or C.I. sun blue 79 (C.I.Direct Blue79) or C.I. reactive black 8 (C.I.Reactive black8) dyestuff 5-10%, CSS-4 sun-screening agent 3--6%, Virahol 8-12%, trolamine 1-3%, N-N-methyl-2-2-pyrrolidone N-1-5%, dodecyl phenenyl sulfate 1-5%, ethylene glycol 8-10%, NN one dimethylformamide 1-5%, its surplus of deionized water is weighed respectively, inserting in the stirred vessel stirring at normal temperature mixed 0.5 hour-1 hour, left standstill 12 hours-24 hours, filter filters, and packing gets the dye type sunproof ink-jet spraying printing ink finished product.
Preferably, the preparation method of the red ink of this dye type sunproof ink-jet spraying printing ink is characterized in that: may further comprise the steps:
By weight percentage with described C.I. reactive red 21 dyestuffs 6.2%, CSS-4 sun-screening agent 3%, Virahol 10%, trolamine 1%, N-N-methyl-2-2-pyrrolidone N-3%, dodecyl phenenyl sulfate 3%, ethylene glycol 10%, NN one dimethylformamide 3%, deionized water 60.8% is weighed respectively, inserts in the stirred vessel stirring at normal temperature and mixes 1 hour, left standstill 12 hours, filter filters, and packs, and gets the red ink finished product of dye type sunproof ink-jet spraying printing ink.
Preferably, the preparation method of the yellow ink of this dye type sunproof ink-jet spraying printing ink is characterized in that: may further comprise the steps:
By weight percentage with described C.I. turmeric yellow 18 dyestuffs 4%, CSS-4 sun-screening agent 3%, Virahol 10%, trolamine 1%, N-N-methyl-2-2-pyrrolidone N-3%, dodecyl phenenyl sulfate 3%, ethylene glycol 10%, NN one dimethylformamide 3%, deionized water 63% is weighed respectively, inserts in the stirred vessel stirring at normal temperature and mixes 1 hour, left standstill 12 hours, filter filters, and packs, and gets the yellow ink finished product of dye type sunproof ink-jet spraying printing ink.
Preferably, the preparation method of the blue ink of this dye type sunproof ink-jet spraying printing ink is characterized in that: may further comprise the steps:
By weight percentage with described C.I. sun blue 79 dyestuffs 6%, CSS-4 sun-screening agent 3%, Virahol 10%, trolamine 1%, N-N-methyl-2-2-pyrrolidone N-3%, dodecyl phenenyl sulfate 3%, ethylene glycol 10%, NN one dimethylformamide 3%, its surplus of deionized water; Deionized water 61% is weighed respectively, inserts in the stirred vessel stirring at normal temperature and mixes 1 hour, leaves standstill 12 hours, and filter filters, packing, the blue ink finished product of dye type sunproof ink-jet spraying printing ink.
Preferably, the preparation method of the black ink of this dye type sunproof ink-jet spraying printing ink is characterized in that: may further comprise the steps:
By weight percentage with described C.I. reactive black 8 dyestuffs 3%, CSS-4 sun-screening agent 3%, Virahol 10%, trolamine 1%, N-N-methyl-2-2-pyrrolidone N-3%, dodecyl phenenyl sulfate 3%, ethylene glycol 10%, NN one dimethylformamide 3%, its surplus of deionized water; Deionized water 64% is weighed respectively, inserts in the stirred vessel stirring at normal temperature and mixes 1 hour, leaves standstill 12 hours, and filter filters, packing, the black ink finished product of dye type sunproof ink-jet spraying printing ink.
Above-mentioned different colours dye type sunproof ink-jet spraying printing ink compound method is identical, and only the kind of pigment is different with the weight part of weight part and other raw materials.
Compared with the prior art, the present invention has following characteristics: 1, energy-conservation: need not to heat normal temperature and just can produce environmental protection: zero release, and the air brushing printer of suitable different type of machines adopts circulation to fill, and economical with materials is convenient and swift; 2, rich color, gorgeous, stability is strong, strong coloring force; 3, insolubles is small, far below the shower nozzle aperture; 4, can clean shower nozzle automatically, not stop up, spray smooth; 5, the image indiffusion of not wrinkling, the color fixation fastness height; 6, ultraviolet radiation resisting, image preserve 20 years colour-fast.Production cost is lower, and it is higher to print DPI; The ink good fluidity can be in half a year, air brushing machine plug not under off-mode.
Below with reference to national leading indicator and product index of the present invention relatively, see Table 1 and table 2.
Table 1 is the comparison sheet of ink-jet printer with the ink the key technical indexes
Table 2 is air brushing printer comparison sheets with the ink the key technical indexes
Environmental protection is analyzed
Whether environmental protection of ink-jet air brushing, key issue has two; The one, whether product is in process of production to aerial and ground down blow; The 2nd, produce products material and whether meet formulation " water-base ink industry standard " requirement of national environmental protection portion.Can whether satisfy these requirements and be related to person with foresight's condition that enter country's buying, also be the sign of access market green channel.
Product of the present invention is in process of production to atmosphere and water nonpollution, ordorless and discharge of poisonous waste etc.Through national quality supervision and inspection center check character standardization, be unique in the industry the project of China by check, the environmental protection check of printing branch's tissue through Chinese Association of Computing Machinery is domestic first product by the environmental protection check.
2, limits of harmful substances requires and product of the present invention in the national environmental protection portion ink
Limits of harmful substances requires relatively to see Table 3:
| Country's demand test item | The national environmental protection controlling index | Product of the present invention detects controlling index |
| Plumbous Pb | ??＜60mg/kg | ??＜0.7mg/kg |
| Cadmium Cd | ??＜75mg/kg | ??＜0.01mg/kg |
| Chromium Cr | ??＜60mg/kg | ??＜0.01mg/kg |
| The azo colouring agent of amine | ??＜3％ | Of no use |
| Biological biocide | ??＜0.4％ | Of no use |
| Formaldehyde content | ??≤5PPm | Of no use |
| Phenol content | ??≤10ppm | Of no use |
Technical target of the product of the present invention and environmental protection index see also the annex survey report.
Product of the present invention and like product price comparison are analyzed:
The ink quality is whether a printing consumables manufacturer can carry out the key problem of running business into strong one, and ink has been carried out and could have been guaranteed the print cartridge quality; Could guarantee to print the quality of air brushing.
The price comparison of product of the present invention and like product is as follows, and import ink market value is 300 yuan-1000 yuan/kilogram, and production cost of products of the present invention is 8-12 unit/kilogram.Not only cheap, and effect is better than like product, also has great market competition advantage.Dye type sunproof ink-jet spraying printing ink can carry out air brushing to textiless such as cotton, viscose fiber, numb machine silks with general air brushing machine, again through the heating after, the various required images of fixation on textiles.
Purposes: the image that air brushing goes out can be widely used as advertisement indoor and outdoor near the photograph effect, cloth and numb Bed linens etc.
Characteristics: 1. compare with hot transfer technique: hot transfer technique needs first air brushing pass through heating sublimation on the paper again to textiles, and this sampling technology produces distillation can not the distillation of 100% ground, and image will distortion; 2, hot transfer printing can not be used on cotton goods; 3, the hot transfer ink water capacity is easily printed No.1 obstruction to the air brushing machine; 4, air brushing machine costliness.Straight spray textiles ink cost in printing and dyeing is lower, and it is higher to print DPI; The ink good fluidity.Can be in half a year, air brushing machine plug not under off-mode.
Dye type sunproof ink-jet spraying printing ink sun-proof grade of the present invention effect analysis:
Red ink with dye type sunproof ink-jet spraying printing ink is example (seeing Table 4):
Table 4: the colour fastness to light grade of the red ink of dye type sunproof ink-jet spraying printing ink detects comparison sheet
Feeler mechanism---quality of item supervision and inspection center is decorateed in country's printing
Detected result sees Table 4
Examination criteria---the light industry standard QB/T 2730.2-2005 of the People's Republic of China (PRC)
Colour fastness to light class requirement: 〉=4 grades (indoor); 〉=6 grades (family)
Dye type sunproof ink-jet spraying printing ink of the present invention meets the light industry standard QB/T 2730.2-2005 of People's Republic of China (PRC) colour fastness to light class requirement: the colour fastness to light grade is 7 grades.
The present invention penetrates into antiultraviolet CSS-4 sun-screening agent and makes sunproof ink-jet spraying printing ink in the dyestuff, can on the former sun-proof of dyestuff basis, improve the 2-3 grade, ink as dyestuff jet ink commonly used, general sun-proof has only 5 grades, after adding the agent of antiultraviolet sun-proof, can improve the colour fastness to light grade to the 7-8 level, be met basically, (in dyestuff, highest level is 8 grades).
The ink-jet air brushing sprays image on sensitive paper, after adopting antiultraviolet CSS-4 sun-screening agent, image on sensitive paper has a kind of energy reflection and strong selectivity absorption ultraviolet ray is arranged and can carry out energy transformation, penetrate with heat energy or other harmless low energy width of cloth, energy is discharged or run out, thereby reach sun-proof ink-jet jet ink.
Embodiment
Embodiment 1
The method of the red ink of disposable preparation 100kg dye type sunproof ink-jet spraying printing ink:
With C.I. reactive red 21 dyestuff 6.2kg, CSS-4 sun-screening agent 3kg, Virahol 10kg, trolamine 1kg, N-N-methyl-2-2-pyrrolidone N-3kg, dodecyl phenenyl sulfate 3kg, ethylene glycol 10kg, NN one dimethylformamide 3kg, deionized water 60.8kg weighs respectively, inserts in the stirred vessel stirring at normal temperature and mixes 1 hour, left standstill 12 hours, filter filters, and packs, and gets the red ink finished product of dye type sunproof ink-jet spraying printing ink.
Embodiment 2
The method of the yellow ink of disposable preparation 100kg dye type sunproof ink-jet spraying printing ink:
With C.I. turmeric yellow 18 dyestuff 4kg, CSS-4 sun-screening agent 3kg, Virahol 10kg, trolamine 1kg, N-N-methyl-2-2-pyrrolidone N-3kg, dodecyl phenenyl sulfate 3kg, ethylene glycol 10kg, NN one dimethylformamide 3kg, deionized water 63kg weighs respectively, inserts in the stirred vessel stirring at normal temperature and mixes 1 hour, left standstill 12 hours, filter filters, and packs, and gets the yellow ink finished product of dye type sunproof ink-jet spraying printing ink.
Embodiment 3
The method of the blue ink of disposable preparation 100kg dye type sunproof ink-jet spraying printing ink:
With C.I. sun blue 79 dyestuff 6kg, CSS-4 sun-screening agent 3kg, Virahol 10kg, trolamine 1kg, N-N-methyl-2-2-pyrrolidone N-3kg, dodecyl phenenyl sulfate 3kg, ethylene glycol 10kg, NN one dimethylformamide 3kg, deionized water 61kg weighs respectively, inserts in the stirred vessel stirring at normal temperature and mixes 1 hour, left standstill 12 hours, filter filters, and packs, and gets the blue ink finished product of dye type sunproof ink-jet spraying printing ink.
Embodiment 4
The method of the black ink of disposable preparation 100kg dye type sunproof ink-jet spraying printing ink:
With C.I. reactive black 8 dyestuff 3kg, CSS-4 sun-screening agent 3kg, Virahol 10kg, trolamine 1kg, N-N-methyl-2-2-pyrrolidone N-3kg, dodecyl phenenyl sulfate 3kg, ethylene glycol 10kg, NN one dimethylformamide 3kg, deionized water 64kg weighs respectively, inserts in the stirred vessel stirring at normal temperature and mixes 1 hour, left standstill 12 hours, filter filters, and packs, and gets the black ink finished product of dye type sunproof ink-jet spraying printing ink.
Embodiment 5
Stability and effect
More than embodiments of the invention are had been described in detail, but described content only is preferred embodiment of the present invention, can not be considered to be used to limit practical range of the present invention.All equalizations of doing according to the present patent application scope change and improve etc., all should still belong within the patent covering scope of the present invention.
Claims (8)
1. dye type sunproof ink-jet spraying printing ink, it is characterized in that: this dye type sunproof ink-jet spraying printing ink is made up of following component by weight percentage:
Dyestuff 3-10%, CSS-4 sun-screening agent 3--6%, Virahol 8-12%, trolamine 1-3%, N-N-methyl-2-2-pyrrolidone N-1-5%, dodecyl phenenyl sulfate 1-5%, ethylene glycol 8-10%, NN one dimethylformamide 1-5%, its surplus of deionized water;
Wherein dyestuff is C.I. reactive red 21 or C.I. turmeric yellow 18 or C.I. sun blue 79 or C.I. reactive black 8.
2. dye type sunproof ink-jet spraying printing ink according to claim 1, it is characterized in that: described dye type sunproof ink-jet spraying printing ink comprises red ink/yellow ink/blue ink/black ink, and this dye type sunproof ink-jet spraying printing ink is made up of following component:
Wherein: red ink is made up of following component by weight percentage:
C.I. reactive red 21 dyestuffs 6.2%, CSS-4 sun-screening agent 3%, Virahol 10%, trolamine 1%, N-N-methyl-2-2-pyrrolidone N-3%, dodecyl phenenyl sulfate 3%, ethylene glycol 10%, NN one dimethylformamide 3%, its surplus of deionized water;
Wherein: yellow ink is made up of following component by weight percentage:
C.I. turmeric yellow 18 dyestuffs 4%, CSS-4 sun-screening agent 3%, Virahol 10%, trolamine 1%, N-N-methyl-2-2-pyrrolidone N-3%, dodecyl phenenyl sulfate 3%, ethylene glycol 10%, NN one dimethylformamide 3%, its surplus of deionized water;
Wherein: blue ink is made up of following component by weight percentage:
C.I. sun blue 79 dyestuffs 6%, CSS-4 sun-screening agent 3%, Virahol 10%, trolamine 1%, N-N-methyl-2-2-pyrrolidone N-3%, dodecyl phenenyl sulfate 3%, ethylene glycol 10%, NN one dimethylformamide 3%, its surplus of deionized water;
Wherein: black ink is made up of following component by weight percentage:
C.I. reactive black 8 dyestuffs 3%, CSS-4 sun-screening agent 3%, Virahol 10%, trolamine 1%, N-N-methyl-2-2-pyrrolidone N-3%, dodecyl phenenyl sulfate 3%, ethylene glycol 10%, NN one dimethylformamide 3%, its surplus of deionized water.
3. the preparation method of a dye type sunproof ink-jet spraying printing ink is characterized in that: may further comprise the steps:
By weight percentage with C.I. reactive red 21 or C.I. turmeric yellow 18 or C.I. sun blue 79 or C.I. reactive black 8 dyestuffs, CSS-4 sun-screening agent, Virahol, trolamine, the N-N-methyl-2-2-pyrrolidone N-, dodecyl phenenyl sulfate, ethylene glycol, NN one dimethylformamide, its surplus of deionized water is weighed respectively, insert mix in the stirred vessel after, leave standstill, filter, get the dye type sunproof ink-jet spraying printing ink finished product.
4. the preparation method of dye type sunproof ink-jet spraying printing ink according to claim 3 is characterized in that: may further comprise the steps:
By weight percentage with C.I. reactive red 21 or C.I. turmeric yellow 18 or C.I. sun blue 79 or C.I. reactive black 8 dyestuff 5-10%, CSS-4 sun-screening agent 3--6%, Virahol 8-12%, trolamine 1-3%, N-N-methyl-2-2-pyrrolidone N-1-5%, dodecyl phenenyl sulfate 1-5%, ethylene glycol 8-10%, NN one dimethylformamide 1-5%, its surplus of deionized water is weighed respectively, inserts in the stirred vessel stirring at normal temperature and mixes 0.5 hour-1 hour, left standstill 12 hours-24 hours, filter filters, and packing gets the dye type sunproof ink-jet spraying printing ink finished product.
5. the preparation method of dye type sunproof ink-jet spraying printing ink according to claim 3, the preparation method of red ink wherein is characterized in that: may further comprise the steps:
By weight percentage with described C.I. reactive red 21 dyestuffs 6.2%, CSS-4 sun-screening agent 3%, Virahol 10%, trolamine 1%, N-N-methyl-2-2-pyrrolidone N-3%, dodecyl phenenyl sulfate 3%, ethylene glycol 10%, NN one dimethylformamide 3%, deionized water 60.8% is weighed respectively, inserts in the stirred vessel stirring at normal temperature and mixes 1 hour, left standstill 12 hours, filter filters, and packs, and gets the red ink finished product of dye type sunproof ink-jet spraying printing ink.
6. the preparation method of dye type sunproof ink-jet spraying printing ink according to claim 3, the preparation method of yellow ink wherein is characterized in that: may further comprise the steps:
By weight percentage with described C.I. turmeric yellow 18 dyestuffs 4%, CSS-4 sun-screening agent 3%, Virahol 10%, trolamine 1%, N-N-methyl-2-2-pyrrolidone N-3%, dodecyl phenenyl sulfate 3%, ethylene glycol 10%, NN one dimethylformamide 3%, deionized water 63% is weighed respectively, inserts in the stirred vessel stirring at normal temperature and mixes 1 hour, left standstill 12 hours, filter filters, and packs, and gets the yellow ink finished product of dye type sunproof ink-jet spraying printing ink.
7. the preparation method of dye type sunproof ink-jet spraying printing ink according to claim 3, the preparation method of blue ink wherein is characterized in that: may further comprise the steps:
By weight percentage with described C.I. sun blue 79 dyestuffs 6%, CSS-4 sun-screening agent 3%, Virahol 10%, trolamine 1%, N-N-methyl-2-2-pyrrolidone N-3%, dodecyl phenenyl sulfate 3%, ethylene glycol 10%, NN one dimethylformamide 3%, its surplus of deionized water; Deionized water 61% is weighed respectively, inserts in the stirred vessel stirring at normal temperature and mixes 1 hour, leaves standstill 12 hours, and filter filters, packing, the blue ink finished product of dye type sunproof ink-jet spraying printing ink.
8. the preparation method of dye type sunproof ink-jet spraying printing ink according to claim 3, the preparation method of black ink wherein is characterized in that: may further comprise the steps:
By weight percentage with described C.I. reactive black 8 dyestuffs 3%, CSS-4 sun-screening agent 3%, Virahol 10%, trolamine 1%, N-N-methyl-2-2-pyrrolidone N-3%, dodecyl phenenyl sulfate 3%, ethylene glycol 10%, NN one dimethylformamide 3%, its surplus of deionized water; Deionized water 64% is weighed respectively, inserts in the stirred vessel stirring at normal temperature and mixes 1 hour, leaves standstill 12 hours, and filter filters, packing, the black ink finished product of dye type sunproof ink-jet spraying printing ink.
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| CN 201010195746 CN101864207A (en) | 2010-06-09 | 2010-06-09 | Dye type sunproof ink-jet spraying printing ink |
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| CN 201010195746 CN101864207A (en) | 2010-06-09 | 2010-06-09 | Dye type sunproof ink-jet spraying printing ink |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105482549A (en) * | 2016-01-20 | 2016-04-13 | 江西统百利彩印包装股份有限公司 | Environment-friendly, sun-resistant and wear-proof water-based ink and preparation method thereof |
| CN107012697A (en) * | 2016-12-11 | 2017-08-04 | 北京恒隆泉科技有限公司 | Auxiliaries for textile dyeing and printing, printing and dyeing ink and its integrated apparatus and preparation method |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101457040A (en) * | 2007-12-10 | 2009-06-17 | 珠海赛纳科技有限公司 | Ink composition for improving fastness of ink jet ink ultraviolet light resistance and ozone gas resistance |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101457040A (en) * | 2007-12-10 | 2009-06-17 | 珠海赛纳科技有限公司 | Ink composition for improving fastness of ink jet ink ultraviolet light resistance and ozone gas resistance |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105482549A (en) * | 2016-01-20 | 2016-04-13 | 江西统百利彩印包装股份有限公司 | Environment-friendly, sun-resistant and wear-proof water-based ink and preparation method thereof |
| CN107012697A (en) * | 2016-12-11 | 2017-08-04 | 北京恒隆泉科技有限公司 | Auxiliaries for textile dyeing and printing, printing and dyeing ink and its integrated apparatus and preparation method |
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Application publication date: 20101020 |