CN101854750A - Electric heating tube made of hexagonal boron nitride and mixed heat conducting material thereof - Google Patents

Electric heating tube made of hexagonal boron nitride and mixed heat conducting material thereof Download PDF

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CN101854750A
CN101854750A CN201010165153A CN201010165153A CN101854750A CN 101854750 A CN101854750 A CN 101854750A CN 201010165153 A CN201010165153 A CN 201010165153A CN 201010165153 A CN201010165153 A CN 201010165153A CN 101854750 A CN101854750 A CN 101854750A
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boron nitride
hexagonal boron
resistance wire
heat conducting
electric heating
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CN101854750B (en
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李廷勇
姜仕虎
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QINGDAO EASYTOUSE ELECTRONICS CO Ltd
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QINGDAO EASYTOUSE ELECTRONICS CO Ltd
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Abstract

The invention belongs to the technical field of electric heating tube manufacture, and relates to an electric heating tube using hexagonal boron nitride or mixture of hexagonal boron nitride and magnesium oxide as a heat conducting material, in particular to a mixed heat conducting material for a novel electric heating tube. A main body structure comprises a metal tube body, a mixed filler, a resistance wire and accessories comprising a fixed plate, porcelain beads, sealant, a plastic plug, a leading-out bar, a terminal electrodes and screws; a cavity structure of the metal tube body is invariantly bent into a circular, elliptical or spiral geometric structure; parallel structures at two end sections of the metal tube body are fixed on the fixed plate in an interval penetration mode, and fixed screws are arranged at two ends of the fixed plate; and the resistance wire is fixed and electrically connected on the central axis of the cavity of the metal tube body and parallel to two end points on two sides of the tube wall, and the mixed filler is filled between the resistance wire and the side wall of the metal tube body. The electric heating tube has the advantages of high stability and heat conducting efficiency, high-temperature softening prevention in inert gas, long service life, high quality, good insulating property, low dielectric constant and dielectric loss, and safe use.

Description

The electrothermal tube of a kind of hexagonal boron nitride and mixed heat conducting material thereof
Technical field:
The invention belongs to electrothermal tube manufacturing technology field, relate to and a kind ofly mix electrothermal tube as Heat Conduction Material, the effective mixed heat conducting material of particularly a kind of new electrically heating with magnesium oxide with hexagonal boron nitride or its.
Background technology:
The tubular electrothermal element that existing electric heating occasion is used claims electrothermal tube again, it generally is shell (stainless steel) with the metal tube, pipe interior central shaft in edge is to the distributing auger lectrothermal alloy wire or be called resistance wire, its space padding and compacting has the magnesium oxide sand of good insulation heat conductivility, mouth of pipe two ends silica gel sealing, this metal armouring electric heating element can heated air or metal die and various liquid medium, have simple in structure, the mechanical strength height, heat efficiency height, safe and reliable, simple installation, characteristics such as long service life, because its low price, use, easy for installation, pollution-free, particularly be widely used in various heating occasions owing to the magnesium oxide price is low.But there is outstanding shortcoming in existing this class electrothermal tube: the one, and the magnesium oxide sand thermal coefficient of expansion is ‖ 15.46*10 under 25 ℃ experimental condition -6, ⊥-0.65*10 -6When the Heat Conduction Material thermal coefficient of expansion is big more, the temperature distortion amount is big more in the heating use, the pipe internal pressure is big more, high more to the sealed at both ends performance requirement of electrothermal tube, easily gas sprays booster and sealed at both ends leakage in the generator tube, and indivedual positions Heat Conduction Material is assembled and caused the personal safety that the too high generation electrothermal tube of temperature damaged and endangered the user in the small size; The 2nd, on the market in the general magnesium oxide sand product content of pure zirconia magnesium be about 85%, all the other 15% silicon dioxide, calcium oxide, bright alkali and impurity, content of magnesia is high more in the magnesium oxide sand, heat conductivility is good more, general magnesium oxide sand purity is subjected to the restriction purity of processing conditions and production cost not high on the market, influences the heat conductivility of electrothermal tube; The 3rd, magnesium oxide sand product magnesium oxide particle fineness (mesh) general on the market is≤140, the size of particle coefficient has determined the size that Heat Conduction Material is interspaced between its particle in filling process, air and moisture that the space is not got rid of in the bassoon more are many more, if moisture and air are discharged not exclusively when making, easy oxidation resistance wire of moisture and inwall, gas expand booster take place easily; The 4th, under the situation of the general same grain fineness of magnesium oxide sand product, its coating of particles is irregular on the market, and the slit is bigger between the particle of filling back, inner air tube and moisture can't be got rid of to greatest extent.Seeking the novel mixed high performance heat conduction packing material that a kind of electrothermal tube is used, is to prepare the technical problem that the electric heating tool is demanded urgently seeking at present.
Summary of the invention:
The objective of the invention is to overcome the deficiency that prior art exists, seek to provide a kind of electrothermal device that uses novel mixed Heat Conduction Material, with six side's boron oxides or its composite material as heat conduction, insulation filling material, hexagonal boron nitride (BN) is an isoelectronic species with graphite, title with white graphite, the layer structure of similar graphite, excellent electric insulating, thermal conductivity and chemical resistance are arranged, the neutron absorbability is good, chemical property is stable, and all motlten metal chemistry are inertia, have higher moisture-proof.
To achieve these goals, agent structure of the present invention comprises metal body, mixed fillers and resistance wire, and auxiliary stator, porcelain bead, fluid sealant, plastic plug, eduction rod, terminal electrode and screw, metal tube intracoelomic cavity structure invariant is bent into round shape, ellipticity or helical form geometry, metal body two ends section parallel construction compartment runs through and is fixed on the stator, is shaped on fixed screw on the stator both end sides; Be parallel to two-end-point fixing also electric connection in tube wall both sides on the metal tube intracoelomic cavity central axis and be shaped on resistance wire, fill full mixed fillers between the sidewall of resistance wire and metal body; Connect on the metal body two-end-point and be shaped on the external terminal electrode, be shaped on fluid sealant and porcelain bead successively in the metal body of terminal electrode, be shaped on the terminal electrode and the eduction rod electric connection of porcelain bead, penetration type is shaped on fluid sealant and porcelain bead on the eduction rod, fixedly connected resistance wire on the inner terminal of eduction rod; The related mixed fillers that uses is the mixture of hexagonal boron nitride or hexagonal boron nitride and magnesium oxide and impurity, and the weight percentage of mixture is a hexagonal boron nitride 50~100%, magnesium oxide 0~50%, impurity 0~10%; Wherein impurity comprises silicon dioxide, calcium oxide and bright alkali, and the percentage by weight total content of impurity is not higher than 10%; The fineness of grind of mixture is 60~150 orders (mesh); Specific insulation (25 ℃)>10 13Ω * cm; Dielectric constant is 4~5, dielectric loss (6~7) * 10 -4, conductive coefficient (W/m.k) is higher than 30; Fusing point is 3000 ℃ under nitrogen pressure, and under atmospheric pressure with 2500 ℃ of distillations, its solid density is 2.29 gram/cubic centimetres, Mohs' hardness 2, and 900 ℃ of antioxygen temperature, high temperature resistant 2000 ℃, using fusing point in nitrogen and argon is 3000 ℃.
The present invention compared with prior art has the following advantages: with hexagonal boron nitride or its mixture is main packing material, its stability is high, heat transfer efficiency is high, good heat resistance, 2800 ℃ are not softened in inert gas, long quality height of the life-span of electrothermal tube, electrical insulating property is good, the consume of dielectric constant and dielectric is low, and the safety in utilization under the moment overload situations is strong; Hexagonal boron nitride mixes the back performance complement with magnesia powder, make under the inserts capability and performance permanence condition, and price descends; Hexagonal boron nitride is a chemical inert material, the grain shape rule, and moisture resistance is good, and interior moisture of electrothermal tube and air are discharged not exclusively the problem of moisture oxidation resistance wire and metal inner surface in the time of can effectively solving manufacturing; The slit is little between the mixed fillers particle, is easy to discharge unnecessary air and moisture in the electric heating body; Thermal coefficient of expansion (25 ℃) ‖ 11.82*10 -6, ⊥-0.36*10 -6Be better than using separately magnesium oxide sand ‖ 15.46*10 -6, ⊥-0.65*10 -6, the coefficient of expansion is little, the pressure to inwall behind the expanded by heating is lower, can solve because of the pipe internal pressure excessive, the sealed at both ends leakage of electrothermal tube, gas ejection booster, each position uneven temperature problem of electrothermal tube, fail safe is good.
Description of drawings:
Fig. 1 is the electrothermal tube agent structure principle schematic that the present invention relates to.
Fig. 2 is the electrothermal tube overall structure principle schematic that the present invention relates to.
Embodiment:
Also be further described in conjunction with the accompanying drawings below by embodiment.
Embodiment:
The mixture that present embodiment uses hexagonal boron nitride or itself and magnesia powder is prepared into electrothermal tube as the Heat Conduction Material of electrothermal tube; Its agent structure comprises metal body 1, mixed fillers 2, resistance wire 3, stator 4, porcelain bead 5, fluid sealant 6, plastic plug 7, eduction rod 8, terminal electrode 9 and screw 10, metal body 1 inner-cavity structure invariant is bent into round shape, ellipticity or spiral helicine geometry, metal body 1 two ends section parallel construction compartment runs through and is fixed on the stator 4, is shaped on fixing screw 10 on stator 4 both end sides; Be parallel to two-end-point fixing also electric connection in both sides on the metal body 1 lumen centers axis and be shaped on resistance wire 3, fill full and compacting mixed fillers 2 between resistance wire 3 and metal body 1 wall; Connect on metal body 1 two-end-point and be shaped on external terminal electrode 9, be shaped on fluid sealant 6 and porcelain bead 5 in the metal body 1 of terminal electrode 9 successively, be shaped on the terminal electrode 9 and electric polarity eduction rod 8 electric connections of porcelain bead 5, penetration type is shaped on fluid sealant 6 and porcelain bead 5 on the eduction rod 8, fixedly connected resistance wire 3 on the inner terminal of eduction rod 8.
The process of the preparation electrothermal tube of present embodiment is: with the metal body 1 usefulness bender bending and molding of stainless steel tubular type is the geometry of design, on wheel axis in the resistance wire 3 insertion stainless steel tubular type metal tube bodies 1, resistance wire 3 two ends connect eduction rod 8, fill and compacting mixed fillers 2 around the resistance wire 3 in the stainless steel tubular type metal tube body 1, be pressed into porcelain bead 5 again, use fluid sealant 6 sealing stainless steel tubular type metal tube bodies 1 inwall to prevent inner mixed fillers leakage, plastic plug 7 is installed again, at the two ends of eduction rod 8 mounting terminal electrode 9; Installation fixing piece 4 and screw 10 on stainless steel tubular type metal tube body 1 are formed the electrothermal tube main body at last; When employed mixed fillers prepares, select commercially available hexagonal boron nitride powder and magnesium oxide sand, both are mixed by weight ratio or select the hexagonal boron nitride powder separately for use, it is standby to be ground into 60-150 purpose fine powder again, various impurity level summations in its mixed fillers are not higher than 10% of mixed fillers or independent hexagonal boron nitride total weight, usually to be lower than 5% for good.
Present embodiment selects the prescription and the effect of 4 concrete proportioning mixed fillers of common raw material to see the following form 1:
Table 1: the mixed fillers of different proportionings (by weight percentage)
Figure GSA00000092336200041
The selected impurities in raw materials of present embodiment mainly comprises silicon dioxide, calcium oxide, alkali and sand etc. burn.Every after testing performance index of electrothermal tube that its four ratios are filled the back preparation all are better than using separately magnesium oxide sand, with pure hexagonal boron nitride filler mutually roughly the same.

Claims (2)

1. the electrothermal tube of hexagonal boron nitride and mixed heat conducting material thereof, agent structure comprises metal body, mixed fillers and resistance wire, and auxiliary stator, porcelain bead, fluid sealant, plastic plug, eduction rod, terminal electrode and screw, metal tube intracoelomic cavity structure invariant is bent into round shape, ellipticity or helical form geometry, metal body two ends section parallel construction compartment runs through and is fixed on the stator, is shaped on fixed screw on the stator both end sides; Be parallel to two-end-point fixing also electric connection in tube wall both sides on the metal tube intracoelomic cavity central axis and be shaped on resistance wire, fill full mixed fillers between the sidewall of resistance wire and metal body; It is characterized in that mixed fillers is the mixture of hexagonal boron nitride or hexagonal boron nitride and magnesium oxide and impurity, the weight percentage of mixture is a hexagonal boron nitride 50~100%, magnesium oxide 0~50%, impurity 0~10%; Wherein impurity comprises silicon dioxide, calcium oxide and bright alkali.
2. the electrothermal tube of hexagonal boron nitride according to claim 1 and mixed heat conducting material thereof, the fineness of grind that it is characterized in that mixture is 60~150 orders; Specific insulation (25 ℃)>10 13Ω * cm; Dielectric constant is 4~5, dielectric loss (6~7) * 10 -4, conductive coefficient (W/m.k) is higher than 30; Fusing point is 3000 ℃ under nitrogen pressure, and solid density is 2.29 gram/cubic centimetres, Mohs' hardness 2, and 900 ℃ of antioxygen temperature, high temperature resistant 2000 ℃, using fusing point in nitrogen and argon is 3000 ℃.
CN2010101651533A 2010-04-11 2010-04-11 Electric heating tube made of hexagonal boron nitride and mixed heat conducting material thereof Active CN101854750B (en)

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