CN101845283B - Method for preparing adhesive special for flexible veneers or bricks - Google Patents
Method for preparing adhesive special for flexible veneers or bricks Download PDFInfo
- Publication number
- CN101845283B CN101845283B CN2010101787660A CN201010178766A CN101845283B CN 101845283 B CN101845283 B CN 101845283B CN 2010101787660 A CN2010101787660 A CN 2010101787660A CN 201010178766 A CN201010178766 A CN 201010178766A CN 101845283 B CN101845283 B CN 101845283B
- Authority
- CN
- China
- Prior art keywords
- aqueous latex
- performed polymer
- flexible
- brick
- adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims abstract description 40
- 239000011449 brick Substances 0.000 title claims abstract description 39
- 239000000853 adhesive Substances 0.000 title claims abstract description 29
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 29
- 239000004816 latex Substances 0.000 claims abstract description 31
- 229920000126 latex Polymers 0.000 claims abstract description 31
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000004814 polyurethane Substances 0.000 claims abstract description 26
- 229920002635 polyurethane Polymers 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 230000008569 process Effects 0.000 claims abstract description 11
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000463 material Substances 0.000 claims description 38
- 229920000642 polymer Polymers 0.000 claims description 38
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 30
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 20
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 15
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 15
- 229920000570 polyether Polymers 0.000 claims description 15
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 14
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 13
- 230000008719 thickening Effects 0.000 claims description 13
- 239000007822 coupling agent Substances 0.000 claims description 12
- 239000003112 inhibitor Substances 0.000 claims description 12
- 230000003647 oxidation Effects 0.000 claims description 12
- 238000007254 oxidation reaction Methods 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 229910000831 Steel Inorganic materials 0.000 claims description 10
- 239000010959 steel Substances 0.000 claims description 10
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 9
- 239000000839 emulsion Substances 0.000 claims description 8
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 8
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- 238000006116 polymerization reaction Methods 0.000 claims description 7
- 230000004048 modification Effects 0.000 claims description 4
- 238000012986 modification Methods 0.000 claims description 4
- 230000008878 coupling Effects 0.000 claims description 3
- 238000010168 coupling process Methods 0.000 claims description 3
- 238000005859 coupling reaction Methods 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 238000004945 emulsification Methods 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 238000010992 reflux Methods 0.000 claims description 2
- 239000006087 Silane Coupling Agent Substances 0.000 claims 1
- 238000010276 construction Methods 0.000 abstract description 5
- 230000009974 thixotropic effect Effects 0.000 abstract description 3
- 238000003825 pressing Methods 0.000 abstract description 2
- 238000005507 spraying Methods 0.000 abstract description 2
- 239000011468 face brick Substances 0.000 abstract 1
- 238000004898 kneading Methods 0.000 abstract 1
- 238000004513 sizing Methods 0.000 abstract 1
- 238000010345 tape casting Methods 0.000 abstract 1
- 239000004568 cement Substances 0.000 description 9
- 229920001971 elastomer Polymers 0.000 description 4
- 238000006073 displacement reaction Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000009825 accumulation Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- 239000011414 polymer cement Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 description 1
- 238000013138 pruning Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- -1 titanic acid ester Chemical class 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Abstract
The invention relates to a method for preparing an adhesive special for flexible veneers or flexible bricks. In the method, acrylic acid aqueous latex is modified by using polyurethane aqueous latex to improve the low-temperature flexibility of the acrylic acid aqueous latex, so the acrylic acid aqueous latex is not hardened at a low temperature and is not softened at a high temperature, and the water resisting property and the binding strength are improved. The method for preparing the adhesive special for the flexible veneers or the flexible bricks has the advantages that: 1, the adhesive is ready for use after a can is opened, does not need field mixing, and is convenient and efficient; 2, a sizing process of the adhesive can adopt a spray coating method or a knife coating method, and has high construction efficiency; 3, the adhesive has high thixotropic property and sag resisting property, the bricks can be adsorbed by applying light pressure instead of kneading and pressing brick bodies, so time and labor are saved; and 4, as the adhesive is semitransparent after being sprayed on a wall body, no influence on observing a snapped control line is generated, the face bricks can be glued along the control line which is snapped on a wall in advance, and the operation is simple and convenient.
Description
One, technical field:
The present invention relates to a kind of building special-purpose adhesive and making method, the making method of the special-purpose adhesive of particularly a kind of flexible veneers or brick.
Two, background technology:
The tackiness agent and the jointing agent of flexible veneers (or brick) are to adopt the single-component polymer dry powder mortar that can divide loose again rubber powder and auxiliary agents such as cement, fine sand to process at present, and the scene adds uses after water stirs.Also have and adopt polymer emulsion to be equipped with the on-the-spot two-component polymer rubber cements that stir of auxilliary material such as cement sand.Often there are following eight big problems in constructing operation:
1, field mix, metering, stir aspects such as homogeneous, slurry viscosity because of the manual operation quality not, with the physicals that influences material.2, when pasting flexible veneers (or brick), though be that the employing thin-layer method is the construction of trowel method, more (the general consumption 4Kg/m of polymer bonding rubber cement consumption
2), thereby increased the load of heavy pruning moment for the external wall outer insulation core.Will hang level and vertical wire when 3, constructing, wire is in the way when plastering, and also wants continuous mobile and horizontal wire during patch block, causes speed of application slowly (can't adopt the method for preparatory bullet wire), thereby prolongs construction period increase construction cost.4, polymer cement rubber cement binder material rigidity is had a surplus flexible not enough; And (thixotropic property is poor for slurry; To rub pressing plate (brick) body during patch block and just can stick brick) poor to the penetrating quality of flexible veneers (brick); Its bonding interface is prone to be subjected to displacement under frequent temperature change condition, causes flexible decorative facing brick to come off.5, the in the initial stage of that bonding tensile strength is low, in 168 hours, can take flexible veneers (brick) off with have gentle hands power, sharply descends like cohesive strength when the cement initial setting time displacement flexible veneers (brick), causes hidden danger of quality.6, during flexible veneers (brick) sticking construction, cement slurry pollutes facing plate surface, and cleaning work is wasted time and energy and strengthened cost.7, pasting operation finishes the back and waits for 24 hours and carry out plate seam jointing operation (employing jointing when pasting is also arranged, but seriously polluted to flexible veneers (brick)) with the jointing mortar again that working procedure is many, pitch time is long.8, because polymer cement sticker its accumulation of salt in the surface soil problem after jointing can't be eradicated, the salt wash rice phenomenon of white influences the attractive in appearance of decorative engineering.
Three, summary of the invention:
The object of the invention is exactly the above-mentioned defective that exists to prior art; The making method of the special-purpose adhesive of a kind of flexible veneers or brick is provided; The special-purpose adhesive that adopts this method to make can solve the problem that flexible veneers (brick) exists when constructing operation.
The making method of the special-purpose adhesive of flexible veneers of the present invention or brick adopts following method to process:
Adopt polyurethane aqueous latex to acrylic acid aqueous latex modified, wherein, the making method of polyurethane aqueous latex is: 1. make performed polymer, performed polymer is made up of following materials of weight proportions: DL2000 polyether glycol 52-65%; N310 polyether glycol 15-20%; Hexamethylene diisocyanate 20-30%; 2. the hydrophilic grafting body of performed polymer is made up of following materials of weight proportions: performed polymer 45-64%; Acetone 35-50%; Dimethylol propionic acid 0.5-8%; 3. polyurethane aqueous latex is made up of following materials of weight proportions: the hydrophilic grafting body of performed polymer 40-60%; Deionized water 60-40%;
Above-mentioned polyurethane aqueous latex adopts following method to the modification of acrylic acid aqueous latex:
The couplet of a urethane and XPA; Form by following materials of weight proportions: polyurethane aqueous latex 6-10%; Acroleic acid polymerization emulsion 89-93%; Coupling agent 0.02-1%;
The making of the special-purpose adhesive of b flexible veneers or brick; Process by following materials of weight proportions: the couplet 94-98% of above-mentioned urethane and XPA, oxidation inhibitor 0.1-1.5%, thickening material 1-5%.
Above-mentioned polyether glycol DL2000, N310 are the commercially available prod.
Above-mentioned hexamethylene diisocyanate HDI, acetone, dimethylol propionic acid (DMPA) are the commercially available prod.
Above-mentioned thickening material be the synthetic macromolecule class can be the commercially available prod: at least a among esters of acrylic acid TE-936, TT935, ASE-60, the polyurethanes UH-420,410,440.
Above-mentioned coupling agent can be existing commercially available prod: titanate coupling agent TC-F (staple belongs to plant acid type monoalkoxy class titanic acid ester), silane resin acceptor kh-550, DL-602's is at least a.
Above-mentioned oxidation inhibitor can be the commercially available prod like oxidation inhibitor 1098 (N; N '-hexylidene-1; [3-(3 for 6-two; 5-di-t-butyl-4-phenylor) propionic acid amide] molecular formula: three (2, the 4-di-tert-butyl-phenyl)), at least a in antioxidant 300, antioxidant 1076 etc. C40H64N2O4), oxidation inhibitor 168 (chemical name:.
According to method of the present invention, the flexible veneers of producing (brick) special-purpose adhesive is the low paste of viscosity of cutting, and solidifies the back and be water white transparency, tasteless, nontoxic high-strength lastics.
The invention has the beneficial effects as follows: 1. this tackiness agent is opened the i.e. usefulness of jar, does not need field mix convenient and swift; 2. the photoresist coating process of this tackiness agent can adopt spraying method (also can adopt blade coating), and operating efficiency is high; 3. have outstanding thixotropic property and sagging resistance, only need light pressure just can brick be adsorbed during patch block, needn't rub and press the brick body time saving and energy saving; 4. because this tackiness agent is sprayed in the body of wall basic unit and is translucent, do not influence observation post's bullet wire, only need get final product during patch block by institute's wire that plays stickup in advance on the wall, easy and simple to handle; 5. behind this adhesive solidification the water white transparency body, even pickup can not cause " visual pollution " yet on flexible veneers (brick); 6. it is similar to have the not glutinous low temperature same flexible veneers of not crisp its snappiness (brick) of high temperature after this adhesive solidification film forming, and it is high under temperature change situation, can not to be subjected to displacement the sticking intensity of cracking, the same life-span of waterproof, ageing-resistant performance and flexible veneers (brick); 7. the sticking intensity of this tackiness agent is high, unit weight is little, consumption is few (0.5-0.7Kg/m only
2) can satisfy the requirement of its tensile bond strength, patch block speed fast (brick sticks wall and gets final product, no jointing technology); 8. this tackiness agent is dehydrating and curing (the tack-free initial adhesive strength of internal surface was high in 1.5 hours) film forming in 72 hours at normal temperatures, stops the cement basic layer accumulation of salt in the surface soil phenomenon of body of wall; 9. the intravital coupling agent of this tackiness agent structure will be in the OH of cement basal plane
-The ionic reaction coupling increases its cohesive strength; 10. this tackiness agent is that solvent belongs to ep-type material with water.
Four, embodiment:
For the present invention is detailed, the present invention is done further describing below in conjunction with the example of practical implementation:
Polyurethane aqueous latex making method: 1. make performed polymer; Press column weight amount proportioning: be warmed up to 80 ℃-95 ℃ in DL2000 polyether glycol 52%, N310 polyether glycol 20%, the hexamethylene diisocyanate HDI28% metering back adding standard glassed steel reaction vessels, the performed polymer of 3-5 hour system of reaction is subsequent use under this temperature; 2. the hydrophilic grafting body of performed polymer is pressed column weight amount proportioning metering performed polymer 45%; Acetone 50%; Dimethylol propionic acid (DMPA) 5% adds with being warmed up to 65 ℃-75 ℃ in the glassed steel reaction vessels of condensing surface and carries out the solvent refluxing grafting to make the hydrophilic grafting body of performed polymer in 2 hours subsequent use; 3. polyurethane aqueous latex is measured by following weight proportion: the hydrophilic grafting body 40% of performed polymer; Deionized water 60% is carrying out body emulsification and is distilling out acetone obtaining polyurethane aqueous latex with in the glassed steel reaction vessels of condensing surface.
The making method of flexible veneers (brick) special-purpose adhesive:
1. the couplet of urethane and XPA: press the metering of column weight amount proportioning: polyurethane aqueous latex 10%; Acroleic acid polymerization emulsion 89%; Coupling agent 1% carries out normal temperature coupling modification and makes low viscous tackiness agent in glassed steel reaction vessels.
2. thickening adds oxidation inhibitor: press column weight amount proportioning metering: the couplet 94% of urethane and XPA, oxidation inhibitor 1%, thickening material 5% hang down to be cut the viscosity thickening and makes flexible veneers (brick) special-purpose adhesive.
Enumerate 3 common enforcement prescription examples
1., performed polymer is made up of following materials of weight proportions: DL2000 polyether glycol 60%; N310 polyether glycol 15%; Hexamethylene diisocyanate HDI25%; The hydrophilic grafting body of performed polymer is made up of following materials of weight proportions: performed polymer 63.5%; Acetone 36%; Dimethylol propionic acid (DMPA) 0.5%; Polyurethane aqueous latex is made up of following materials of weight proportions: the hydrophilic grafting body 60% of performed polymer; Deionized water 40%.
The couplet of urethane and XPA: form: polyurethane aqueous latex 10% by following materials of weight proportions; Acroleic acid polymerization emulsion 89.5%; Coupling agent 0.5%.The making of flexible veneers (brick) special-purpose adhesive: process: the couplet 98% of urethane and XPA, oxidation inhibitor 0.5%, thickening material 1.5% by following materials of weight proportions.
2., performed polymer is made up of following materials of weight proportions: DL2000 polyether glycol 55%; N310 polyether glycol 15%; Hexamethylene diisocyanate HDI30%; The hydrophilic grafting body of performed polymer is made up of following materials of weight proportions: performed polymer 50%; Acetone 49.2%; Dimethylol propionic acid (DMPA) 0.8%; Polyurethane aqueous latex is made up of following materials of weight proportions: the hydrophilic grafting body 50% of performed polymer; Deionized water 50%.
The couplet of urethane and XPA: form: polyurethane aqueous latex 7% by following materials of weight proportions; Acroleic acid polymerization emulsion 92%; Coupling agent 1%.The making of flexible veneers (brick) special-purpose adhesive: process: the couplet 95% of urethane and XPA, oxidation inhibitor 1%, thickening material 4% by following materials of weight proportions.
3., performed polymer is made up of following materials of weight proportions: DL2000 polyether glycol 57%; N310 polyether glycol 17%; Hexamethylene diisocyanate HDI26%; The hydrophilic grafting body of performed polymer is made up of following materials of weight proportions: performed polymer 60%; Acetone 38%; Dimethylol propionic acid (DMPA) 2%; Polyurethane aqueous latex is made up of following materials of weight proportions: the hydrophilic grafting body 55% of performed polymer; Deionized water 45%.
The couplet of urethane and XPA: form: polyurethane aqueous latex 8% by following materials of weight proportions; Acroleic acid polymerization emulsion 91.2%; Coupling agent 0.8%.The making of flexible veneers (brick) special-purpose adhesive: process: the couplet 96% of urethane and XPA, oxidation inhibitor 1.2%, thickening material 2.8% by following materials of weight proportions.The equipment that the present invention produces flexible veneers (brick) special-purpose adhesive is universal glassed steel reaction vessels.
Claims (4)
1. the making method of the special-purpose adhesive of flexible veneers or brick is characterized in that adopting following method to process:
Adopt polyurethane aqueous latex to acrylic acid aqueous latex modified, wherein, the making method of polyurethane aqueous latex is: 1. make performed polymer, performed polymer is made up of following materials of weight proportions: DL2000 polyether glycol 52-65%; N310 polyether glycol 15-20%; Hexamethylene diisocyanate 20-30%; 2. the hydrophilic grafting body of performed polymer is made up of following materials of weight proportions: performed polymer 45-64%; Acetone 35-50%; Dimethylol propionic acid 0.5-8%; 3. polyurethane aqueous latex is made up of following materials of weight proportions: the hydrophilic grafting body of performed polymer 40-60%; Deionized water 60-40%;
Described polyurethane aqueous latex adopts following method to the modification of acrylic acid aqueous latex:
The couplet of a urethane and XPA; Form by following materials of weight proportions: polyurethane aqueous latex 6-10%; Acroleic acid polymerization emulsion 89-93%; Coupling agent 0.02-1%;
The making of the special-purpose adhesive of b flexible veneers or brick; Process by following materials of weight proportions: the couplet 94-98% of above-mentioned urethane and XPA, oxidation inhibitor 0.1-1.5%, thickening material 1-5%.
2. the making method of the special-purpose adhesive of flexible veneers according to claim 1 or brick is characterized in that: described thickening material is esters of acrylic acid or polyurethanes.
3. the making method of the special-purpose adhesive of flexible veneers according to claim 1 or brick is characterized in that: described coupling agent is titanate coupling agent or silane coupling agent.
4. the making method of the special-purpose adhesive of flexible veneers according to claim 1 or brick is characterized in that: adopt following method to process:
1. make performed polymer, DL2000 polyether glycol, N310 polyether glycol, hexamethylene diisocyanate are metered into by prescription are warmed up to 80 ℃-95 ℃ in the standard glassed steel reaction vessels, to make performed polymer in 3-5 hour subsequent use in reaction under this temperature; 2. the hydrophilic grafting body of performed polymer behind prescription metering performed polymer, acetone, dimethylol propionic acid, adds with being warmed up to 65 ℃-75 ℃ in the glassed steel reaction vessels of condensing surface and carries out the solvent refluxing grafting to make the hydrophilic grafting body of performed polymer in 2 hours subsequent use; 3. polyurethane aqueous latex is carrying out body emulsification and is distilling out acetone obtaining polyurethane aqueous latex with in the glassed steel reaction vessels of condensing surface by prescription metering hydrophilic grafting body of performed polymer and deionized water; 4. the couplet of urethane and XPA makes low viscous tackiness agent by prescription with carrying out normal temperature coupling modification in polyurethane aqueous latex, acroleic acid polymerization emulsion, the coupling agent metering back adding glassed steel reaction vessels; 5. thickening adds oxidation inhibitor: cut the viscosity thickening and process hanging down in the couplet of urethane and XPA, oxidation inhibitor, the thickening material metering back adding glassed steel reaction vessels by prescription.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101787660A CN101845283B (en) | 2010-05-12 | 2010-05-12 | Method for preparing adhesive special for flexible veneers or bricks |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101787660A CN101845283B (en) | 2010-05-12 | 2010-05-12 | Method for preparing adhesive special for flexible veneers or bricks |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101845283A CN101845283A (en) | 2010-09-29 |
| CN101845283B true CN101845283B (en) | 2012-05-23 |
Family
ID=42770104
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010101787660A Expired - Fee Related CN101845283B (en) | 2010-05-12 | 2010-05-12 | Method for preparing adhesive special for flexible veneers or bricks |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101845283B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104194687A (en) * | 2014-08-26 | 2014-12-10 | 安徽神舟飞船胶业有限公司 | Formula and preparation process of styrene and polyether urethane copolymer adhesive |
| CN105504195A (en) * | 2016-02-01 | 2016-04-20 | 潘浩升 | Adhesive for flexible decorative panel and production method for adhesive |
-
2010
- 2010-05-12 CN CN2010101787660A patent/CN101845283B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN101845283A (en) | 2010-09-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101863631B (en) | Stone aggregate wrapped by microfine fibre polymer mortar thin layer and preparation method thereof | |
| CN109575310A (en) | A kind of anionic emulsified modified asphalt and preparation method thereof and a kind of high binding type soluble asphalt water-repellent paint of anion | |
| CN107868616A (en) | One kind spraying rapid hardening rubber asphalt waterproof coating and preparation method thereof | |
| CN107162502A (en) | A kind of fiber reinforced type polymer cement waterproof paint | |
| CN105110716A (en) | Binding mortar for flexible facing bricks and preparation method thereof | |
| CN101544856A (en) | External wall putty | |
| CN104774513B (en) | There is VAE cement waterproof paints and its preparation of self-leveling energy for ramped surfaces | |
| CN108753022A (en) | A kind of UV-LED solidification repairing putty and preparation method thereof | |
| CN101701138B (en) | Cohesive glue for flexible decorative tile and manufacturing method thereof | |
| CN101792641B (en) | Environment-friendly adhesive for quickly adhering aluminum alloy and PVC thin film, preparation and application thereof | |
| CN101372565A (en) | High adhesion strength porcelain-based coating | |
| CN101845283B (en) | Method for preparing adhesive special for flexible veneers or bricks | |
| CN201826400U (en) | Fast curing waterproof structure | |
| CN102618199B (en) | Anti-cracking green adhesive for ceiling decoration seams | |
| CN102816501B (en) | Use modified fatty amine as the joint mixture of epoxy curing agent | |
| CN103539411A (en) | Preparation technology of polymer cement waterproof coating | |
| CN101613193B (en) | Material for repairing building cracks and splicing prefabricated wallboard | |
| CN1583915A (en) | Reacting polymer cement waterproof coating and preparing method thereof | |
| CN108892993A (en) | A kind of environmental protection anti-crack mastic powder and preparation method thereof | |
| CN102796432A (en) | High-molecular nanometer elastic mud | |
| EP1361255B1 (en) | Coating material, use thereof and process for applying it | |
| CN109401514B (en) | Thick-coating type water-based emulsified asphalt waterproof coating and preparation method thereof | |
| CN102464473A (en) | High-efficiency water-proof paint and preparation method thereof | |
| CN105368225A (en) | Polymer cement waterproof paint having good adhesion performance | |
| CN102731045A (en) | Waterproof adhesive for building outer wall |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: DONGYING RUIYUAN SPECIAL TYPE ARCHITECTURAL MATERI Free format text: FORMER OWNER: LI JINNUO Effective date: 20110816 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20110816 Address after: 257335, Shandong Dongying Economic Development Zone, Guangrao Province Road, No. 760 Rui source company Applicant after: DONGYING RUIYUAN SPECIAL BUILDING MATERIALS Co.,Ltd. Address before: 257335, unity Road, Guangrao Economic Development Zone, Shandong, Dongying 760, China Applicant before: Li Jinnuo |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190212 Address after: 257335 Han Tuan Village, Le'an Street, Guangrao Economic Development Zone, Guangrao County, Dongying City, Shandong Province Patentee after: Dongying Yida New Materials Co.,Ltd. Address before: 257335 Ruiyuan Company, No. 760 Unity Road, Guangrao Economic Development Zone, Dongying City, Shandong Province Patentee before: DONGYING RUIYUAN SPECIAL BUILDING MATERIALS Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120523 |