CN101831115A - Ethylene propylene rubber insulation material for longitudinal high-voltage watertight cable of ships and warships and production method thereof - Google Patents
Ethylene propylene rubber insulation material for longitudinal high-voltage watertight cable of ships and warships and production method thereof Download PDFInfo
- Publication number
- CN101831115A CN101831115A CN 201010159882 CN201010159882A CN101831115A CN 101831115 A CN101831115 A CN 101831115A CN 201010159882 CN201010159882 CN 201010159882 CN 201010159882 A CN201010159882 A CN 201010159882A CN 101831115 A CN101831115 A CN 101831115A
- Authority
- CN
- China
- Prior art keywords
- parts
- rubber
- insulation material
- tac
- terpolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention discloses an ethylene propylene rubber insulation material for longitudinal high-voltage watertight cables of ships and warships and a production method thereof. The method comprises the following steps: adding the ethylen e-propylene-diene mischpolymere, age resister and fire retardant into a banbury for banburying for 3.5min; adding argil, white carbon black and paraffin wax for continued banburying for 2min; adding active agent, and discharging after banburying for 1.5min; filtering the rubber compound with a three-layer filter screen (namely a 60 mesh filter screen, a 60 mesh filter screen and a 80 mesh filter screen) on a rubber filter; and beating into cornucopla on a double-roller mill, adding vulcanizer and co-crosslinker, then beating into cornucopla for 7 times, grinding and slicing after finishing the steps, and then cooling, wherein the materials are as follows in parts by weight: 100 parts of ethylen e-propylene-diene mischpolymere, 1-5 parts of vulcanizer, 1-4 parts of age resister, 15-70 parts of fire retardant, 0.5-10 parts of active agent, 10-20 parts of argil and 2-4 parts of paraffin. The prepared insulation material has the characteristics of low smoke, no halogen, fire resistance, high machinery strengthen, and high insulation resistance, good flexibility, elasticity and viscosity, and can be used for the ships and warships.
Description
Technical field
The present invention relates to the Insulation Material that a kind of power cable is used, particularly a kind of naval vessel longitudinal high-pressure watertight cable ethylene propylene rubber insulation material.
Background technology
Terpolymer EP rubber is widely used as the wire cable insulating material because of having characteristics such as electrical property excellence, heat-resisting ageing-resisting performance high and low temperature snappiness be good.
On May 20th, 2009, publication number is the Chinese invention patent application of CN101434728, a kind of ultraviolet light crosslinked EPT rubber cable insulation material and preparation method thereof is disclosed, feature is by weight 100 parts of terpolymer EP rubbers, 100～120 parts of mineral fillers, 0.5～5.0 part of ultraviolet initiator, 0.5～5.0 part of multi-group crosslink agent, 5.0～10.0 parts of tenderizers, 0.8～1.2 part of silane coupling agent and 0.01～1.0 part of composite antioxidant mixingly evenly to be extruded at 100～150 ℃, obtains the ultraviolet light crosslinked EPT rubber cable material; On conductor wire core, melt extrude then and be overmolding to insulation layer or restrictive coating; At wavelength 200～400NM, light intensity 400～2000MW/cm
2Cross-linking radiation under the UV-light.This Insulation Material does not possess fire retardation, and it is fire-retardant with the category-A bunchy of cable requirement to satisfy the naval vessel.
Summary of the invention
The technical problem to be solved in the present invention is that a kind of naval vessel longitudinal high-pressure watertight cable ethylene propylene rubber insulation material of superior performance is provided.
For solving above technical problem, naval vessel provided by the present invention longitudinal high-pressure watertight cable ethylene propylene rubber insulation material, feed composition and weight content are as follows: virgin rubber: 100 parts of terpolymer EP rubbers; Vulcanizing agent: dicumyl peroxide DCP, 3～5 parts; Triallyl trimerization hydrocyanic ester TAC, 1～3 part; Anti-aging agent: 2-thiol group benzimidazolyl MB, 2～4 parts; Alkylated diphenylamine compound XH-1,1～2 part; Fire retardant: aluminium hydroxide, 50～70 parts; Zinc borate, 15～30 parts; Promoting agent: Zinic stearas, 1～3 part; Stearic acid, 0.5～2 part; Zinc oxide, 5～10 parts; Strengthening agent: potter's clay, 10～20 parts.
With respect to prior art, the present invention has obtained following beneficial effect: the naval vessel longitudinal high-pressure watertight cable ethylene-propylene rubber(EPR) that uses this Insulation Material to make has the characteristics of low cigarette, Halogen, fire-retardant, high mechanical strength, high insulation resistance; Can guarantee the snappiness of cable, having solved the finished cable bending radius is the technical problem of 5 times of outside diameters of cable; Especially have elasticity and viscosity preferably, realize seal gum and the bonding one of insulation double-layer coextrusion that watertight cable requires, realize the difficult problem of the high pressure resistant water longitudinally water blocking of cable, can satisfy the naval vessel and use.
As preferred version of the present invention, described fire retardant also comprises antimonous oxide, and weight ratio is 15～30 parts; Described strengthening agent also comprises 6～9 parts of white carbon blacks.
As preferred version of the present invention, also comprise softening softening agent in the feed composition of described Insulation Material: 2～4 parts in paraffin.
As preferred version of the present invention, the feed composition and the weight content of Insulation Material are as follows: virgin rubber: 100 parts of terpolymer EP rubbers; Vulcanizing agent: dicumyl peroxide DCP, 3 parts; Triallyl trimerization hydrocyanic ester TAC, 1 part; Anti-aging agent: 2-thiol group benzimidazolyl MB, 2 parts; Alkylated diphenylamine compound XH-1,1.5 parts; Fire retardant: aluminium hydroxide, 65 parts; Zinc borate, 20 parts; Promoting agent: Zinic stearas, 1.5 parts; Stearic acid, 1 part; Zinc oxide, 5 parts; Strengthening agent: potter's clay, 15 parts; White carbon black, 7.5 parts; Softening softening agent: 3.5 parts in paraffin.
As preferred version of the present invention, the feed composition and the weight content of Insulation Material are as follows: virgin rubber: 100 parts of terpolymer EP rubbers; Vulcanizing agent: dicumyl peroxide DCP, 3.5 parts; Triallyl trimerization hydrocyanic ester TAC, 1 part; Anti-aging agent: 2-thiol group benzimidazolyl MB, 4 parts; Alkylated diphenylamine compound XH-1,1.5 parts; Fire retardant: aluminium hydroxide, 60 parts; Zinc borate, 15 parts; Promoting agent: Zinic stearas, 1.5 parts; Stearic acid, 0.5 part; Zinc oxide, 6.5 parts; Strengthening agent: potter's clay, 20 parts; White carbon black, 6 parts; Softening softening agent: 2 parts in paraffin.
As preferred version of the present invention, the feed composition and the weight content of Insulation Material are as follows: virgin rubber: 100 parts of terpolymer EP rubbers; Vulcanizing agent: dicumyl peroxide DCP, 4 parts; Triallyl trimerization hydrocyanic ester TAC, 2 parts; Anti-aging agent: 2-thiol group benzimidazolyl MB, 3 parts; Alkylated diphenylamine compound XH-1,1 part; Fire retardant: aluminium hydroxide, 70 parts; Zinc borate, 25 parts; Promoting agent: Zinic stearas, 3 parts; Stearic acid, 1 part; Zinc oxide, 6 parts; Strengthening agent: potter's clay, 15 parts; White carbon black, 7 parts; Softening softening agent: 3 parts in paraffin.
Another technical problem that the present invention will solve is, the production method of a kind of naval vessel longitudinal high-pressure watertight cable with ethylene propylene rubber insulation material is provided, the Insulation Material that this method is made, superior performance has the characteristics of low cigarette, Halogen, fire-retardant, high mechanical strength, high insulation resistance.
For solving above technical problem, the naval vessel provided by the present invention longitudinal high-pressure watertight cable production method of ethylene propylene rubber insulation material, may further comprise the steps: terpolymer EP rubber, 2-thiol group benzimidazolyl MB, triallyl trimerization hydrocyanic ester TAC, aluminium hydroxide, zinc borate are added Banbury mixer, banburying 3.5 minutes; Add potter's clay and white carbon black then, add paraffin again, continue banburying 2 minutes; Then add Zinic stearas, stearic acid, zinc oxide, banburying discharging after 1.5 minutes; Rubber unvulcanizate is being filtered on the rubber machine with 60 orders+60 orders+80 mesh filter screens, three metafiltration glue; In two roller mills, play the triangle bag at last and add dicumyl peroxide DCP, triallyl trimerization hydrocyanic ester TAC and co-crosslinker, and then play the triangle bag 7 times, grind page or leaf section and cooling after finishing; Each raw material weight ratio is terpolymer EP rubber: 100 parts; Dicumyl peroxide DCP:3～5 part; Triallyl trimerization hydrocyanic ester TAC:1～3 parts; 2-thiol group benzimidazolyl MB:2～4 parts; Alkylated diphenylamine compound XH-1:1～2 part; Aluminium hydroxide: 50～70 parts; Zinc borate: 15～30 parts; Zinic stearas: 1～3 part; Stearic acid: 0.5～2 part; Zinc oxide: 5～10 parts; Potter's clay: 10～20 parts; White carbon black: 6～9 parts; Paraffin: 2～4 parts.
With respect to prior art, the present invention has obtained following beneficial effect: the Insulation Material of using this method to make, be used to make naval vessel longitudinal high-pressure watertight cable ethylene-propylene rubber(EPR), and have the characteristics of low cigarette, Halogen, fire-retardant, high mechanical strength, high insulation resistance; Can guarantee the snappiness of cable, having solved the finished cable bending radius is the technical problem of 5 times of outside diameters of cable; Especially have elasticity and viscosity preferably, realize seal gum and the bonding one of insulation double-layer coextrusion that watertight cable requires, realize the difficult problem of the high pressure resistant water longitudinally water blocking of cable, can satisfy the naval vessel and use.
As preferred version of the present invention, the naval vessel longitudinal high-pressure watertight cable production method of ethylene propylene rubber insulation material, may further comprise the steps: terpolymer EP rubber, 2-thiol group benzimidazolyl MB, triallyl trimerization hydrocyanic ester TAC, aluminium hydroxide, zinc borate are added Banbury mixer, banburying 3.5 minutes; Add potter's clay and white carbon black then, add paraffin again, continue banburying 2 minutes; Then add Zinic stearas, stearic acid, zinc oxide, banburying discharging after 1.5 minutes; Rubber unvulcanizate is being filtered on the rubber machine with 60 orders+60 orders+80 mesh filter screens, three metafiltration glue; In two roller mills, play the triangle bag at last and add dicumyl peroxide DCP, triallyl trimerization hydrocyanic ester TAC and co-crosslinker, and then play the triangle bag 7 times, grind page or leaf section and cooling after finishing; Each raw material weight ratio is terpolymer EP rubber: 100 parts; 2-thiol group benzimidazolyl MB:2 part; Triallyl trimerization hydrocyanic ester TAC:1 part; Aluminium hydroxide: 65 parts; Zinc borate: 20 parts; Potter's clay: 15 parts; White carbon black: 7.5 parts; Paraffin: 3.5 parts; Zinic stearas: 1.5 parts; Stearic acid: 1 part; Zinc oxide: 5 parts; Dicumyl peroxide DCP:3 part; Triallyl trimerization hydrocyanic ester TAC:1 part; Aluminium hydroxide: 65 parts; Zinc borate: 20 parts.
As preferred version of the present invention, the naval vessel longitudinal high-pressure watertight cable production method of ethylene propylene rubber insulation material, may further comprise the steps: earlier with terpolymer EP rubber and 2-thiol group benzimidazolyl MB, alkylated diphenylamine compound XH-1, aluminium hydroxide, zinc borate drops into two roller mill mixings, add potter's clay and white carbon black behind the bag roller, add paraffin then, powder stirs evenly the back fully and adds Zinic stearas, stearic acid, zinc oxide, draw and play the triangle bag again after thin and add dicumyl peroxide DCP, triallyl trimerization hydrocyanic ester TAC and co-crosslinker grind page or leaf section and cooling after drawing logical 7 times; Each raw material weight ratio is: terpolymer EP rubber: 100 parts, dicumyl peroxide DCP:3.5 part; Triallyl trimerization hydrocyanic ester TAC:1 part, 2-thiol group benzimidazolyl MB:4 part, alkylated diphenylamine compound XH-1:1.5 part, aluminium hydroxide: 60 parts, zinc borate: 15 parts, Zinic stearas: 1.5 parts, stearic acid: 0.5 part, zinc oxide: 6.5 parts, potter's clay: 20 parts, white carbon black: 6 parts, paraffin: 2 parts.
As preferred version of the present invention, the naval vessel longitudinal high-pressure watertight cable production method of ethylene propylene rubber insulation material, may further comprise the steps: terpolymer EP rubber is mixing in Banbury mixer, with Zinic stearas, stearic acid, zinc oxide, 2-thiol group benzimidazolyl, alkylated diphenylamine compound XH-1, aluminium hydroxide, zinc borate, that potter's clay is mixed and made into compound is standby, it is mixing together to treat that terpolymer EP rubber after mixing 2 minutes adds this compound Banbury mixer; Mixingly in the Banbury mixer fully evenly down beat behind the triangle bag again pulling-on piece and filter rubber to mill.Beat then and on three-roller open mill, beat triangle Bao Wuci, draw and get back to Banbury mixer after thin and add fines, after the banburying 1 minute, added vulcanizing agent dicumyl peroxide DCP, triallyl trimerization hydrocyanic ester TAC and co-crosslinker mixing again 2 minutes, then cutting slice and cooling; Each raw material weight ratio is terpolymer EP rubber: 100 parts; Dicumyl peroxide DCP:4 part; Triallyl trimerization hydrocyanic ester TAC:2 part; 2-thiol group benzimidazolyl MB:3 part; Alkylated diphenylamine compound XH-1:1 part; Aluminium hydroxide: 70 parts; Zinc borate: 25 parts; Zinic stearas: 3 parts; Stearic acid: 1 part; Zinc oxide: 6 parts; Potter's clay: 15 parts.
Embodiment
Naval vessel provided by the present invention longitudinal high-pressure watertight cable ethylene propylene rubber insulation material, feed composition and weight content are as follows: virgin rubber: 100 parts of terpolymer EP rubbers; Vulcanizing agent: dicumyl peroxide DCP, 3～5 parts; Triallyl trimerization hydrocyanic ester TAC, 1～3 part; Anti-aging agent: 2-thiol group benzimidazolyl MB, 2～4 parts; Alkylated diphenylamine compound XH-1,1～2 part; Fire retardant: aluminium hydroxide, 50～70 parts; Zinc borate, 15～30 parts; Antimonous oxide, 15～30 parts; Promoting agent: Zinic stearas, 1～3 part; Stearic acid, 0.5～2 part; Zinc oxide, 5～10 parts; Strengthening agent: potter's clay, 10～20 parts; White carbon black, 6～9 parts; Softening softening agent: 2～4 parts in paraffin.
Embodiment one
The feed composition and the weight content of Insulation Material are as follows: virgin rubber: 100 parts of terpolymer EP rubbers; Vulcanizing agent: dicumyl peroxide DCP, 3 parts; Triallyl trimerization hydrocyanic ester TAC, 1 part; Anti-aging agent: 2-thiol group benzimidazolyl MB, 2 parts; Alkylated diphenylamine compound XH-1,1.5 parts; Fire retardant: aluminium hydroxide, 65 parts; Zinc borate, 20 parts; Promoting agent: Zinic stearas, 1.5 parts; Stearic acid, 1 part; Zinc oxide, 5 parts; Strengthening agent: potter's clay, 15 parts; White carbon black, 7.5 parts; Softening softening agent: 3.5 parts in paraffin.
Embodiment two
The feed composition and the weight content of Insulation Material are as follows: virgin rubber: 100 parts of terpolymer EP rubbers; Vulcanizing agent: dicumyl peroxide DCP, 3.5 parts; Triallyl trimerization hydrocyanic ester TAC, 1 part; Anti-aging agent: 2-thiol group benzimidazolyl MB, 4 parts; Alkylated diphenylamine compound XH-1,1.5 parts; Fire retardant: aluminium hydroxide, 60 parts; Zinc borate, 15 parts; Promoting agent: Zinic stearas, 1.5 parts; Stearic acid, 0.5 part; Zinc oxide, 6.5 parts; Strengthening agent: potter's clay, 20 parts; White carbon black, 6 parts; Softening softening agent: 2 parts in paraffin.
Embodiment three
The feed composition and the weight content of Insulation Material are as follows: virgin rubber: 100 parts of terpolymer EP rubbers; Vulcanizing agent: dicumyl peroxide DCP, 4 parts; Triallyl trimerization hydrocyanic ester TAC, 2 parts; Anti-aging agent: 2-thiol group benzimidazolyl MB, 3 parts; Alkylated diphenylamine compound XH-1,1 part; Fire retardant: aluminium hydroxide, 70 parts; Zinc borate, 25 parts; Promoting agent: Zinic stearas, 3 parts; Stearic acid, 1 part; Zinc oxide, 6 parts; Strengthening agent: potter's clay, 15 parts; White carbon black, 7 parts; Softening softening agent: 3 parts in paraffin.
The naval vessel provided by the present invention longitudinal high-pressure watertight cable production method of ethylene propylene rubber insulation material, may further comprise the steps: terpolymer EP rubber, 2-thiol group benzimidazolyl MB, triallyl trimerization hydrocyanic ester TAC, aluminium hydroxide, zinc borate are added Banbury mixer, banburying 3.5 minutes; Add potter's clay and white carbon black then, add paraffin again, continue banburying 2 minutes; Then add Zinic stearas, stearic acid, zinc oxide, banburying discharging after 1.5 minutes; Rubber unvulcanizate is being filtered on the rubber machine with 60 orders+60 orders+80 mesh filter screens, three metafiltration glue; In two roller mills, play the triangle bag at last and add dicumyl peroxide DCP, triallyl trimerization hydrocyanic ester TAC and co-crosslinker, and then play the triangle bag 7 times, grind page or leaf section and cooling after finishing; Each raw material weight ratio is terpolymer EP rubber: 100 parts; Dicumyl peroxide DCP:3～5 part; Triallyl trimerization hydrocyanic ester TAC:1～3 parts; 2-thiol group benzimidazolyl MB:2～4 parts; Alkylated diphenylamine compound XH-1:1～2 part; Aluminium hydroxide: 50～70 parts; Zinc borate: 15～30 parts; Zinic stearas: 1～3 part; Stearic acid: 0.5～2 part; Zinc oxide: 5～10 parts; Potter's clay: 10～20 parts; White carbon black: 6～9 parts; Paraffin: 2～4 parts.
Naval vessel of the present invention longitudinal high-pressure watertight cable ethylene propylene rubber insulation material has the characteristics of low cigarette, Halogen, fire-retardant, high mechanical strength, high insulation resistance, can satisfy the naval vessel and use.Its preparation technology is banburying, filter rubber, compressing tablet, cooling, and banburying needs to guarantee each component uniform mixing; Owing to may have some impurity in the refining glue, need filter glue at filter rubber machine behind the refining glue, remove impurity; The filter rubber is finished the back rubber is carried out compressing tablet, cutting, forms strip film; Then that the film cooling is inter-adhesive to prevent between each film.
Performance of the present invention and existing ethylene-propylene rubber(EPR) performance relatively see the following form:
Embodiment one
Terpolymer EP rubber, 2-thiol group benzimidazolyl MB, triallyl trimerization hydrocyanic ester TAC, aluminium hydroxide, zinc borate are added Banbury mixer, banburying 3.5 minutes; Add potter's clay and white carbon black then, add paraffin again, continue banburying 2 minutes; Then add Zinic stearas, stearic acid, zinc oxide, banburying discharging after 1.5 minutes; Rubber unvulcanizate is being filtered on the rubber machine with 60 orders+60 orders+80 mesh filter screens, three metafiltration glue; In two roller mills, play the triangle bag at last and add dicumyl peroxide DCP, triallyl trimerization hydrocyanic ester TAC and co-crosslinker, and then play the triangle bag 7 times, grind page or leaf section and cooling after finishing; Each raw material weight ratio is terpolymer EP rubber: 100 parts; 2-thiol group benzimidazolyl MB:2 part; Triallyl trimerization hydrocyanic ester TAC:1 part; Aluminium hydroxide: 65 parts; Zinc borate: 20 parts; Potter's clay: 15 parts; White carbon black: 7.5 parts; Paraffin: 3.5 parts; Zinic stearas: 1.5 parts; Stearic acid: 1 part; Zinc oxide: 5 parts; Dicumyl peroxide DCP:3 part; Triallyl trimerization hydrocyanic ester TAC:1 part.
Embodiment two
Earlier terpolymer EP rubber and 2-thiol group benzimidazolyl MB, alkylated diphenylamine compound XH-1, aluminium hydroxide, zinc borate are dropped into two roller mill mixings, add potter's clay and white carbon black behind the bag roller, add paraffin then, powder stirs evenly the back fully and adds Zinic stearas, stearic acid, zinc oxide, draw and play the triangle bag again after thin and add dicumyl peroxide DCP, triallyl trimerization hydrocyanic ester TAC and co-crosslinker, grind page or leaf section and cooling after drawing logical 7 times; Each raw material weight ratio is: terpolymer EP rubber: 100 parts, dicumyl peroxide DCP:3.5 part; Triallyl trimerization hydrocyanic ester TAC:1 part, 2-thiol group benzimidazolyl MB:4 part, alkylated diphenylamine compound XH-1:1.5 part, aluminium hydroxide: 60 parts, zinc borate: 15 parts, Zinic stearas: 1.5 parts, stearic acid: 0.5 part, zinc oxide: 6.5 parts, potter's clay: 20 parts, white carbon black: 6 parts, paraffin: 2 parts.
Embodiment three
Terpolymer EP rubber is mixing in Banbury mixer, with Zinic stearas, stearic acid, zinc oxide, 2-thiol group benzimidazolyl, alkylated diphenylamine compound XH-1, aluminium hydroxide, zinc borate, that potter's clay is mixed and made into compound is standby, it is mixing together to treat that terpolymer EP rubber after mixing 2 minutes adds this compound Banbury mixer; Mixingly in the Banbury mixer fully evenly down beat behind the triangle bag again pulling-on piece and filter rubber to mill.Beat then and on three-roller open mill, beat triangle Bao Wuci, draw and get back to Banbury mixer after thin and add fines, after the banburying 1 minute, added vulcanizing agent dicumyl peroxide DCP, triallyl trimerization hydrocyanic ester TAC and co-crosslinker mixing again 2 minutes, then cutting slice and cooling; Each raw material weight ratio is terpolymer EP rubber: 100 parts; Dicumyl peroxide DCP:4 part; Triallyl trimerization hydrocyanic ester TAC:2 part; 2-thiol group benzimidazolyl MB:3 part; Alkylated diphenylamine compound XH-1:1 part; Aluminium hydroxide: 70 parts; Zinc borate: 25 parts; Zinic stearas: 3 parts; Stearic acid: 1 part; Zinc oxide: 6 parts; Potter's clay: 15 parts.
In addition to the implementation, the present invention can also have other embodiments.All employings are equal to the technical scheme of replacement or equivalent transformation formation, all drop on the protection domain of requirement of the present invention.
Claims (10)
1. naval vessel longitudinal high-pressure watertight cable ethylene propylene rubber insulation material is characterized in that the feed composition and the weight content of this Insulation Material are as follows:
Virgin rubber: 100 parts of terpolymer EP rubbers;
Vulcanizing agent: dicumyl peroxide DCP, 3～5 parts; Triallyl trimerization hydrocyanic ester TAC, 1～3 part;
Anti-aging agent: 2-thiol group benzimidazolyl MB, 2～4 parts; Alkylated diphenylamine compound XH-1,1～2 part;
Fire retardant: aluminium hydroxide, 50～70 parts; Zinc borate, 15～30 parts;
Promoting agent: Zinic stearas, 1～3 part; Stearic acid, 0.5～2 part; Zinc oxide, 5～10 parts;
Strengthening agent: potter's clay, 10～20 parts.
2. naval vessel according to claim 1 longitudinal high-pressure watertight cable ethylene propylene rubber insulation material is characterized in that described fire retardant also comprises antimonous oxide, and weight ratio is 15～30 parts; Described strengthening agent also comprises 6～9 parts of white carbon blacks.
3. naval vessel according to claim 1 longitudinal high-pressure watertight cable ethylene propylene rubber insulation material is characterized in that, also comprises softening softening agent in the feed composition of described Insulation Material: 2～4 parts in paraffin.
4. naval vessel according to claim 1 longitudinal high-pressure watertight cable ethylene propylene rubber insulation material is characterized in that the feed composition and the weight content of described Insulation Material are as follows:
Virgin rubber: 100 parts of terpolymer EP rubbers;
Vulcanizing agent: dicumyl peroxide DCP, 3 parts; Triallyl trimerization hydrocyanic ester TAC, 1 part;
Anti-aging agent: 2-thiol group benzimidazolyl MB, 2 parts; Alkylated diphenylamine compound XH-1,1.5 parts;
Fire retardant: aluminium hydroxide, 65 parts; Zinc borate, 20 parts;
Promoting agent: Zinic stearas, 1.5 parts; Stearic acid, 1 part; Zinc oxide, 5 parts;
Strengthening agent: potter's clay, 15 parts; White carbon black, 7.5 parts;
Softening softening agent: 3.5 parts in paraffin.
5. naval vessel according to claim 1 longitudinal high-pressure watertight cable ethylene propylene rubber insulation material is characterized in that the feed composition and the weight content of described Insulation Material are as follows:
Virgin rubber: 100 parts of terpolymer EP rubbers;
Vulcanizing agent: dicumyl peroxide DCP, 3.5 parts; Triallyl trimerization hydrocyanic ester TAC, 1 part;
Anti-aging agent: 2-thiol group benzimidazolyl MB, 4 parts; Alkylated diphenylamine compound XH-1,1.5 parts;
Fire retardant: aluminium hydroxide, 60 parts; Zinc borate, 15 parts;
Promoting agent: Zinic stearas, 1.5 parts; Stearic acid, 0.5 part; Zinc oxide, 6.5 parts;
Strengthening agent: potter's clay, 20 parts; White carbon black, 6 parts;
Softening softening agent: 2 parts in paraffin.
6. naval vessel according to claim 1 longitudinal high-pressure watertight cable ethylene propylene rubber insulation material is characterized in that the feed composition and the weight content of this Insulation Material are as follows:
Virgin rubber: 100 parts of terpolymer EP rubbers;
Vulcanizing agent: dicumyl peroxide DCP, 4 parts; Triallyl trimerization hydrocyanic ester TAC, 2 parts;
Anti-aging agent: 2-thiol group benzimidazolyl MB, 3 parts; Alkylated diphenylamine compound XH-1,1 part;
Fire retardant: aluminium hydroxide, 70 parts; Zinc borate, 25 parts;
Promoting agent: Zinic stearas, 3 parts; Stearic acid, 1 part; Zinc oxide, 6 parts;
Strengthening agent: potter's clay, 15 parts; White carbon black, 7 parts;
Softening softening agent: 3 parts in paraffin.
7. a naval vessel longitudinal high-pressure watertight cable is with the production method of ethylene propylene rubber insulation material, may further comprise the steps: terpolymer EP rubber, 2-thiol group benzimidazolyl MB, triallyl trimerization hydrocyanic ester TAC, aluminium hydroxide, zinc borate are added Banbury mixer, banburying 3.5 minutes; Add potter's clay and white carbon black then, add paraffin again, continue banburying 2 minutes; Then add Zinic stearas, stearic acid, zinc oxide, banburying discharging after 1.5 minutes; Rubber unvulcanizate is being filtered on the rubber machine with 60 orders+60 orders+80 mesh filter screens, three metafiltration glue; In two roller mills, play the triangle bag at last and add dicumyl peroxide DCP, triallyl trimerization hydrocyanic ester TAC and co-crosslinker, and then play the triangle bag 7 times, grind page or leaf section and cooling after finishing;
Each raw material weight ratio is terpolymer EP rubber: 100 parts; Dicumyl peroxide DCP:3～5 part; Triallyl trimerization hydrocyanic ester TAC:1～3 parts; 2-thiol group benzimidazolyl MB:2～4 parts; Alkylated diphenylamine compound XH-1:1～2 part; Aluminium hydroxide: 50～70 parts; Zinc borate: 15～30 parts; Zinic stearas: 1～3 part; Stearic acid: 0.5～2 part; Zinc oxide: 5～10 parts; Potter's clay: 10～20 parts; White carbon black: 6～9 parts; Paraffin: 2～4 parts.
8. the longitudinal high-pressure watertight cable production method of ethylene propylene rubber insulation material in naval vessel according to claim 5 may further comprise the steps:
Terpolymer EP rubber, 2-thiol group benzimidazolyl MB, triallyl trimerization hydrocyanic ester TAC, aluminium hydroxide, zinc borate are added Banbury mixer, banburying 3.5 minutes; Add potter's clay and white carbon black then, add paraffin again, continue banburying 2 minutes; Then add Zinic stearas, stearic acid, zinc oxide, banburying discharging after 1.5 minutes; Rubber unvulcanizate is being filtered on the rubber machine with 60 orders+60 orders+80 mesh filter screens, three metafiltration glue; In two roller mills, play the triangle bag at last and add dicumyl peroxide DCP, triallyl trimerization hydrocyanic ester TAC and co-crosslinker, and then play the triangle bag 7 times, grind page or leaf section and cooling after finishing;
Each raw material weight ratio is terpolymer EP rubber: 100 parts; 2-thiol group benzimidazolyl MB:2 part; Triallyl trimerization hydrocyanic ester TAC:1 part; Aluminium hydroxide: 65 parts; Zinc borate: 20 parts; Potter's clay: 15 parts; White carbon black: 7.5 parts; Paraffin: 3.5 parts; Zinic stearas: 1.5 parts; Stearic acid: 1 part; Zinc oxide: 5 parts; Dicumyl peroxide DCP:3 part; Triallyl trimerization hydrocyanic ester TAC:1 part; Aluminium hydroxide: 65 parts; Zinc borate: 20 parts.
9. the naval vessel according to claim 5 longitudinal high-pressure watertight cable production method of ethylene propylene rubber insulation material, may further comprise the steps: earlier with terpolymer EP rubber and 2-thiol group benzimidazolyl MB, alkylated diphenylamine compound XH-1, aluminium hydroxide, zinc borate drops into two roller mill mixings, add potter's clay and white carbon black behind the bag roller, add paraffin then, powder stirs evenly the back fully and adds Zinic stearas, stearic acid, zinc oxide, draw and play the triangle bag again after thin and add dicumyl peroxide DCP, triallyl trimerization hydrocyanic ester TAC and co-crosslinker grind page or leaf section and cooling after drawing logical 7 times;
Each raw material weight ratio is: terpolymer EP rubber: 100 parts, dicumyl peroxide DCP:3.5 part; Triallyl trimerization hydrocyanic ester TAC:1 part, 2-thiol group benzimidazolyl MB:4 part, alkylated diphenylamine compound XH-1:1.5 part, aluminium hydroxide: 60 parts, zinc borate: 15 parts, Zinic stearas: 1.5 parts, stearic acid: 0.5 part, zinc oxide: 6.5 parts, potter's clay: 20 parts, white carbon black: 6 parts, paraffin: 2 parts.
10. the naval vessel according to claim 5 longitudinal high-pressure watertight cable production method of ethylene propylene rubber insulation material, may further comprise the steps: terpolymer EP rubber is mixing in Banbury mixer, with Zinic stearas, stearic acid, zinc oxide, 2-thiol group benzimidazolyl, alkylated diphenylamine compound XH-1, aluminium hydroxide, zinc borate, that potter's clay is mixed and made into compound is standby, it is mixing together to treat that terpolymer EP rubber after mixing 2 minutes adds this compound Banbury mixer; Mixingly in the Banbury mixer fully evenly down beat behind the triangle bag again pulling-on piece and filter rubber to mill.Beat then and on three-roller open mill, beat triangle Bao Wuci, draw and get back to Banbury mixer after thin and add fines, after the banburying 1 minute, added vulcanizing agent dicumyl peroxide DCP, triallyl trimerization hydrocyanic ester TAC and co-crosslinker mixing again 2 minutes, then cutting slice and cooling;
Each raw material weight ratio is terpolymer EP rubber: 100 parts; Dicumyl peroxide DCP:4 part; Triallyl trimerization hydrocyanic ester TAC:2 part; 2-thiol group benzimidazolyl MB:3 part; Alkylated diphenylamine compound XH-1:1 part; Aluminium hydroxide: 70 parts; Zinc borate: 25 parts; Zinic stearas: 3 parts; Stearic acid: 1 part; Zinc oxide: 6 parts; Potter's clay: 15 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010159882 CN101831115B (en) | 2010-04-29 | 2010-04-29 | Ethylene propylene rubber insulation material for longitudinal high-voltage watertight cable of ships and warships and production method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010159882 CN101831115B (en) | 2010-04-29 | 2010-04-29 | Ethylene propylene rubber insulation material for longitudinal high-voltage watertight cable of ships and warships and production method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101831115A true CN101831115A (en) | 2010-09-15 |
| CN101831115B CN101831115B (en) | 2011-12-21 |
Family
ID=42715346
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010159882 Expired - Fee Related CN101831115B (en) | 2010-04-29 | 2010-04-29 | Ethylene propylene rubber insulation material for longitudinal high-voltage watertight cable of ships and warships and production method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101831115B (en) |
Cited By (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102176343A (en) * | 2010-12-24 | 2011-09-07 | 江苏远洋东泽电缆股份有限公司 | Cable for ship hydrophone equipment and manufacturing method thereof |
| CN102184757A (en) * | 2010-12-24 | 2011-09-14 | 江苏远洋东泽电缆股份有限公司 | Ship underwater sonar transducer cable and manufacturing method thereof |
| CN102250424A (en) * | 2011-08-17 | 2011-11-23 | 靡玥崎 | Low-smoke halogen-free flame-retardant ethylene-propylene-diene mischpolymere rubber |
| CN102276933A (en) * | 2011-08-16 | 2011-12-14 | 河北中联塑胶科技发展有限公司 | Medium-pressure insulated rubber with excellent performance and preparation method thereof |
| CN102344611A (en) * | 2011-06-28 | 2012-02-08 | 江苏远洋东泽电缆股份有限公司 | Cable insulating material for offshore petroleum device and production method thereof |
| CN102344612A (en) * | 2011-06-28 | 2012-02-08 | 江苏远洋东泽电缆股份有限公司 | Ethylene propylene rubber cable insulating material for ship and ocean use and manufacturing method thereof |
| CN102344613A (en) * | 2011-06-28 | 2012-02-08 | 江苏远洋东泽电缆股份有限公司 | Cable insulating material for slag car and manufacture method thereof |
| CN102344614A (en) * | 2011-06-28 | 2012-02-08 | 江苏远洋东泽电缆股份有限公司 | Insulating material of power cable for dredger underwater shovel arm, and production method thereof |
| CN102964699A (en) * | 2012-11-13 | 2013-03-13 | 安徽春辉仪表线缆集团有限公司 | Incinerated pottery clay modified ethylene propylene diene copolymer cable material |
| CN102964698A (en) * | 2012-11-13 | 2013-03-13 | 安徽春辉仪表线缆集团有限公司 | High cold-resistance ethylene propylene diene copolymer insulated cable material and preparation method thereof |
| CN102964696A (en) * | 2012-11-13 | 2013-03-13 | 安徽春辉仪表线缆集团有限公司 | Ethylene propylene diene copolymer flame retardant cable material and preparation method thereof |
| CN102964697A (en) * | 2012-11-13 | 2013-03-13 | 安徽春辉仪表线缆集团有限公司 | Nano-wollastonite powder modified ethylene propylene diene copolymer cable material |
| CN102977469A (en) * | 2012-11-13 | 2013-03-20 | 安徽春辉仪表线缆集团有限公司 | Ethylene propylene diene monomer cable material used for middle-high voltage cable and preparation method of ethylene propylene diene monomer cable material |
| CN103642130A (en) * | 2013-03-26 | 2014-03-19 | 江苏远洋东泽电缆股份有限公司 | Flame-retardant and fire-resistant cable insulation rubber for ships and production method therefor |
| CN104987530A (en) * | 2015-07-16 | 2015-10-21 | 山东阳谷华泰化工股份有限公司 | High-dispersion and low-zinc activator for rubber, and preparation method thereof |
| CN105086169A (en) * | 2015-08-31 | 2015-11-25 | 无锡华虹信息科技有限公司 | Low-smoke low-halogen fire resistant cable for mine |
| CN105255017A (en) * | 2015-07-10 | 2016-01-20 | 中广核三角洲（江苏）塑化有限公司 | Ethylene-propylene rubber insulating material for medium voltage power cable and preparation method thereof |
| CN105837960A (en) * | 2016-05-31 | 2016-08-10 | 李小涛 | Halogen-free flame-retardant ethylene propylene rubber cable material and preparation method thereof |
| CN105924807A (en) * | 2016-05-31 | 2016-09-07 | 李小涛 | Environment-friendly ethylene propylene rubber cable material and preparation method thereof |
| CN106317655A (en) * | 2016-09-22 | 2017-01-11 | 佛山市飞时达新材料科技有限公司 | Rat-proof EPDM (ethylene-propylene-diene monomer) cable material and preparation method thereof |
| CN106366466A (en) * | 2016-10-11 | 2017-02-01 | 佛山市飞时达新材料科技有限公司 | Antibacterial ethylene propylene diene monomer cable material and preparation method thereof |
| CN106380706A (en) * | 2016-11-04 | 2017-02-08 | 南京利德东方橡塑科技有限公司 | Environment-friendly type low-smoke flame-retardant insulated rubber composition, preparation method, use and product applying composition |
| CN106751071A (en) * | 2016-12-20 | 2017-05-31 | 安徽新立电缆材料有限公司 | A kind of impact resistance shipboard cable material |
| CN107057195A (en) * | 2016-12-23 | 2017-08-18 | 上海瑞孚管路系统有限公司 | A kind of EPDM rubber |
| CN107195359A (en) * | 2017-05-03 | 2017-09-22 | 安徽凌宇电缆科技有限公司 | A kind of new girdle banding coal mining machine flexible cable with metallic shielding rubber sleeve |
| CN107266798A (en) * | 2017-06-30 | 2017-10-20 | 上海蓝昊电气有限公司 | A kind of 45kv high pressures ethyl-propylene insulating materials |
| CN108929493A (en) * | 2018-07-06 | 2018-12-04 | 江苏上上电缆集团有限公司 | A kind of UL welding machine cable monolayer overlay layer material and preparation method thereof |
| CN109360680A (en) * | 2018-09-16 | 2019-02-19 | 江苏亨通电力电缆有限公司 | The environmentally protective DC traction cable of rail traffic high fire-retardance and its preparation process |
| CN109473198A (en) * | 2018-09-16 | 2019-03-15 | 江苏亨通电力电缆有限公司 | Preventing fraudulent use of electricity service entrance cable and its preparation process |
| CN110561633A (en) * | 2019-09-17 | 2019-12-13 | 安徽电缆股份有限公司 | rubber cable material open milling processing technology |
| CN116239843A (en) * | 2023-02-17 | 2023-06-09 | 浙江威格尔传动股份有限公司 | High-temperature-resistant composite rubber material, preparation method thereof and synchronous belt applied to high-temperature-resistant composite rubber material |
Citations (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004263169A (en) * | 2003-02-10 | 2004-09-24 | Toyo Ink Mfg Co Ltd | Production method for conductive resin composition, conductive resin composition and molded product |
| CN1787120A (en) * | 2004-12-06 | 2006-06-14 | 大连圣迈化学有限公司 | Thermoplastic non-halogen low fume fire resistant cable isolation material and processing tech. thereof |
| CN1929039A (en) * | 2006-09-11 | 2007-03-14 | 江苏上上电缆集团有限公司 | Cable insulating material for power station |
| CN100999598A (en) * | 2007-01-11 | 2007-07-18 | 上海交通大学 | Preparation process for cable material of radiation resisting low flue unhalogen flame-retarded ethylpropyl rubber |
| CN101093736A (en) * | 2006-06-21 | 2007-12-26 | 江苏中煤电缆集团有限公司 | Rubber insulation material and insulating sheath material for mine cable |
| CN101246761A (en) * | 2007-02-12 | 2008-08-20 | 深圳市沃尔核材股份有限公司 | Non-halogen flame-proof cross-linking copper-coated aluminum electric wire and method for producing the same |
| CN101245161A (en) * | 2007-02-13 | 2008-08-20 | 天津市振海橡胶科技发展有限公司 | Rubber material for producing alkali-fast battery reservoir |
| CN101281798A (en) * | 2008-05-08 | 2008-10-08 | 余纪炎 | Insulation material for cable and wire of nuclear power plant |
| CN101333307A (en) * | 2008-06-27 | 2008-12-31 | 南京固柏橡塑制品有限公司 | Cold resistant rubber |
| KR100878877B1 (en) * | 2007-11-02 | 2009-01-15 | (주)바이저 | Composition for making rubber gasket for the plate type heat exchanger and method for making the gasket in use of the compositon |
| CN101353443A (en) * | 2008-09-27 | 2009-01-28 | 中国铁道科学研究院金属及化学研究所 | Ternary flame retardant composition for rubber and ethylen-propylene rubber thereof |
| CN100487821C (en) * | 2006-11-17 | 2009-05-13 | 安徽新亚特电缆集团有限公司 | Cable insulation material against nuclear circumstance |
| CN101451005A (en) * | 2007-11-30 | 2009-06-10 | 王极超 | Antishock insulation rubber member for high-tension cable |
| CN101463166A (en) * | 2009-01-05 | 2009-06-24 | 天津鹏翎胶管股份有限公司 | Formula of environment protection type flame-retardant rubber pipe |
| CN101531789A (en) * | 2009-04-20 | 2009-09-16 | 宝胜科技创新股份有限公司 | Radiation-resistant halogen-free low smoke flame retardant insulating material for cables of nuclear power plants and preparation method |
| CN101585934A (en) * | 2008-05-23 | 2009-11-25 | 北京化工大学 | Low-smoke and halogen-free fire-retardant rubber material for covering layer of conveyor belt and preparation method thereof |
| CN101602868A (en) * | 2008-06-11 | 2009-12-16 | 比亚迪股份有限公司 | A kind of rubber combination and rubber and preparation method thereof |
| CN101613506A (en) * | 2009-07-25 | 2009-12-30 | 四川明星电缆股份有限公司 | High temperature resistance non halogen flame retardant cable sheath material and preparation method thereof |
-
2010
- 2010-04-29 CN CN 201010159882 patent/CN101831115B/en not_active Expired - Fee Related
Patent Citations (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004263169A (en) * | 2003-02-10 | 2004-09-24 | Toyo Ink Mfg Co Ltd | Production method for conductive resin composition, conductive resin composition and molded product |
| CN1787120A (en) * | 2004-12-06 | 2006-06-14 | 大连圣迈化学有限公司 | Thermoplastic non-halogen low fume fire resistant cable isolation material and processing tech. thereof |
| CN101093736A (en) * | 2006-06-21 | 2007-12-26 | 江苏中煤电缆集团有限公司 | Rubber insulation material and insulating sheath material for mine cable |
| CN1929039A (en) * | 2006-09-11 | 2007-03-14 | 江苏上上电缆集团有限公司 | Cable insulating material for power station |
| CN100487821C (en) * | 2006-11-17 | 2009-05-13 | 安徽新亚特电缆集团有限公司 | Cable insulation material against nuclear circumstance |
| CN100999598A (en) * | 2007-01-11 | 2007-07-18 | 上海交通大学 | Preparation process for cable material of radiation resisting low flue unhalogen flame-retarded ethylpropyl rubber |
| CN101246761A (en) * | 2007-02-12 | 2008-08-20 | 深圳市沃尔核材股份有限公司 | Non-halogen flame-proof cross-linking copper-coated aluminum electric wire and method for producing the same |
| CN101245161A (en) * | 2007-02-13 | 2008-08-20 | 天津市振海橡胶科技发展有限公司 | Rubber material for producing alkali-fast battery reservoir |
| KR100878877B1 (en) * | 2007-11-02 | 2009-01-15 | (주)바이저 | Composition for making rubber gasket for the plate type heat exchanger and method for making the gasket in use of the compositon |
| CN101451005A (en) * | 2007-11-30 | 2009-06-10 | 王极超 | Antishock insulation rubber member for high-tension cable |
| CN101281798A (en) * | 2008-05-08 | 2008-10-08 | 余纪炎 | Insulation material for cable and wire of nuclear power plant |
| CN101585934A (en) * | 2008-05-23 | 2009-11-25 | 北京化工大学 | Low-smoke and halogen-free fire-retardant rubber material for covering layer of conveyor belt and preparation method thereof |
| CN101602868A (en) * | 2008-06-11 | 2009-12-16 | 比亚迪股份有限公司 | A kind of rubber combination and rubber and preparation method thereof |
| CN101333307A (en) * | 2008-06-27 | 2008-12-31 | 南京固柏橡塑制品有限公司 | Cold resistant rubber |
| CN101353443A (en) * | 2008-09-27 | 2009-01-28 | 中国铁道科学研究院金属及化学研究所 | Ternary flame retardant composition for rubber and ethylen-propylene rubber thereof |
| CN101463166A (en) * | 2009-01-05 | 2009-06-24 | 天津鹏翎胶管股份有限公司 | Formula of environment protection type flame-retardant rubber pipe |
| CN101531789A (en) * | 2009-04-20 | 2009-09-16 | 宝胜科技创新股份有限公司 | Radiation-resistant halogen-free low smoke flame retardant insulating material for cables of nuclear power plants and preparation method |
| CN101613506A (en) * | 2009-07-25 | 2009-12-30 | 四川明星电缆股份有限公司 | High temperature resistance non halogen flame retardant cable sheath material and preparation method thereof |
Cited By (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102184757A (en) * | 2010-12-24 | 2011-09-14 | 江苏远洋东泽电缆股份有限公司 | Ship underwater sonar transducer cable and manufacturing method thereof |
| CN102176343A (en) * | 2010-12-24 | 2011-09-07 | 江苏远洋东泽电缆股份有限公司 | Cable for ship hydrophone equipment and manufacturing method thereof |
| CN102176343B (en) * | 2010-12-24 | 2012-07-25 | 江苏远洋东泽电缆股份有限公司 | Cable for ship hydrophone equipment and manufacturing method thereof |
| CN102184757B (en) * | 2010-12-24 | 2012-08-29 | 江苏远洋东泽电缆股份有限公司 | Ship underwater sonar transducer cable and manufacturing method thereof |
| CN102344612B (en) * | 2011-06-28 | 2013-03-13 | 江苏远洋东泽电缆股份有限公司 | Ethylene propylene rubber cable insulating material for ship and ocean use and manufacturing method thereof |
| CN102344611A (en) * | 2011-06-28 | 2012-02-08 | 江苏远洋东泽电缆股份有限公司 | Cable insulating material for offshore petroleum device and production method thereof |
| CN102344612A (en) * | 2011-06-28 | 2012-02-08 | 江苏远洋东泽电缆股份有限公司 | Ethylene propylene rubber cable insulating material for ship and ocean use and manufacturing method thereof |
| CN102344613A (en) * | 2011-06-28 | 2012-02-08 | 江苏远洋东泽电缆股份有限公司 | Cable insulating material for slag car and manufacture method thereof |
| CN102344614A (en) * | 2011-06-28 | 2012-02-08 | 江苏远洋东泽电缆股份有限公司 | Insulating material of power cable for dredger underwater shovel arm, and production method thereof |
| CN102344611B (en) * | 2011-06-28 | 2013-02-13 | 江苏远洋东泽电缆股份有限公司 | Cable insulating material for offshore petroleum device and production method thereof |
| CN102344613B (en) * | 2011-06-28 | 2013-02-13 | 江苏远洋东泽电缆股份有限公司 | Cable insulating material for slag car and manufacture method thereof |
| CN102276933A (en) * | 2011-08-16 | 2011-12-14 | 河北中联塑胶科技发展有限公司 | Medium-pressure insulated rubber with excellent performance and preparation method thereof |
| CN102250424B (en) * | 2011-08-17 | 2013-05-01 | 糜玥崎 | Low-smoke halogen-free flame-retardant ethylene-propylene-diene mischpolymere rubber |
| CN102250424A (en) * | 2011-08-17 | 2011-11-23 | 靡玥崎 | Low-smoke halogen-free flame-retardant ethylene-propylene-diene mischpolymere rubber |
| CN102964698B (en) * | 2012-11-13 | 2016-05-18 | 安徽春辉仪表线缆集团有限公司 | A kind of high cold-resistant ethylene propylene diene rubber insulated cable material and preparation method thereof |
| CN102964699A (en) * | 2012-11-13 | 2013-03-13 | 安徽春辉仪表线缆集团有限公司 | Incinerated pottery clay modified ethylene propylene diene copolymer cable material |
| CN102964696A (en) * | 2012-11-13 | 2013-03-13 | 安徽春辉仪表线缆集团有限公司 | Ethylene propylene diene copolymer flame retardant cable material and preparation method thereof |
| CN102964697A (en) * | 2012-11-13 | 2013-03-13 | 安徽春辉仪表线缆集团有限公司 | Nano-wollastonite powder modified ethylene propylene diene copolymer cable material |
| CN102977469A (en) * | 2012-11-13 | 2013-03-20 | 安徽春辉仪表线缆集团有限公司 | Ethylene propylene diene monomer cable material used for middle-high voltage cable and preparation method of ethylene propylene diene monomer cable material |
| CN102964697B (en) * | 2012-11-13 | 2016-07-06 | 安徽春辉仪表线缆集团有限公司 | The EPT rubber cable material that a kind of Nano wollastonite powder is modified |
| CN102964698A (en) * | 2012-11-13 | 2013-03-13 | 安徽春辉仪表线缆集团有限公司 | High cold-resistance ethylene propylene diene copolymer insulated cable material and preparation method thereof |
| CN102964696B (en) * | 2012-11-13 | 2016-05-18 | 安徽春辉仪表线缆集团有限公司 | A kind of ethylene propylene diene rubber fire-resistant cable material and preparation method thereof |
| CN102964699B (en) * | 2012-11-13 | 2016-05-18 | 安徽春辉仪表线缆集团有限公司 | A kind of EPT rubber cable material of calcinated argil modification |
| CN103642130A (en) * | 2013-03-26 | 2014-03-19 | 江苏远洋东泽电缆股份有限公司 | Flame-retardant and fire-resistant cable insulation rubber for ships and production method therefor |
| CN103642130B (en) * | 2013-03-26 | 2016-03-30 | 江苏远洋东泽电缆股份有限公司 | Flame-retardant shipboard cable electro-insulating rubber and manufacture method thereof |
| CN105255017A (en) * | 2015-07-10 | 2016-01-20 | 中广核三角洲（江苏）塑化有限公司 | Ethylene-propylene rubber insulating material for medium voltage power cable and preparation method thereof |
| CN105255017B (en) * | 2015-07-10 | 2018-09-21 | 中广核三角洲（江苏）塑化有限公司 | Medium-pressure power cable third Insulation Material of second and preparation method thereof |
| CN104987530A (en) * | 2015-07-16 | 2015-10-21 | 山东阳谷华泰化工股份有限公司 | High-dispersion and low-zinc activator for rubber, and preparation method thereof |
| CN105086169A (en) * | 2015-08-31 | 2015-11-25 | 无锡华虹信息科技有限公司 | Low-smoke low-halogen fire resistant cable for mine |
| CN105924807A (en) * | 2016-05-31 | 2016-09-07 | 李小涛 | Environment-friendly ethylene propylene rubber cable material and preparation method thereof |
| CN105837960A (en) * | 2016-05-31 | 2016-08-10 | 李小涛 | Halogen-free flame-retardant ethylene propylene rubber cable material and preparation method thereof |
| CN106317655A (en) * | 2016-09-22 | 2017-01-11 | 佛山市飞时达新材料科技有限公司 | Rat-proof EPDM (ethylene-propylene-diene monomer) cable material and preparation method thereof |
| CN106366466A (en) * | 2016-10-11 | 2017-02-01 | 佛山市飞时达新材料科技有限公司 | Antibacterial ethylene propylene diene monomer cable material and preparation method thereof |
| CN106380706A (en) * | 2016-11-04 | 2017-02-08 | 南京利德东方橡塑科技有限公司 | Environment-friendly type low-smoke flame-retardant insulated rubber composition, preparation method, use and product applying composition |
| CN106751071A (en) * | 2016-12-20 | 2017-05-31 | 安徽新立电缆材料有限公司 | A kind of impact resistance shipboard cable material |
| CN107057195A (en) * | 2016-12-23 | 2017-08-18 | 上海瑞孚管路系统有限公司 | A kind of EPDM rubber |
| CN107195359A (en) * | 2017-05-03 | 2017-09-22 | 安徽凌宇电缆科技有限公司 | A kind of new girdle banding coal mining machine flexible cable with metallic shielding rubber sleeve |
| CN107266798A (en) * | 2017-06-30 | 2017-10-20 | 上海蓝昊电气有限公司 | A kind of 45kv high pressures ethyl-propylene insulating materials |
| CN108929493A (en) * | 2018-07-06 | 2018-12-04 | 江苏上上电缆集团有限公司 | A kind of UL welding machine cable monolayer overlay layer material and preparation method thereof |
| CN109360680A (en) * | 2018-09-16 | 2019-02-19 | 江苏亨通电力电缆有限公司 | The environmentally protective DC traction cable of rail traffic high fire-retardance and its preparation process |
| CN109473198A (en) * | 2018-09-16 | 2019-03-15 | 江苏亨通电力电缆有限公司 | Preventing fraudulent use of electricity service entrance cable and its preparation process |
| CN110561633A (en) * | 2019-09-17 | 2019-12-13 | 安徽电缆股份有限公司 | rubber cable material open milling processing technology |
| CN116239843A (en) * | 2023-02-17 | 2023-06-09 | 浙江威格尔传动股份有限公司 | High-temperature-resistant composite rubber material, preparation method thereof and synchronous belt applied to high-temperature-resistant composite rubber material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101831115B (en) | 2011-12-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101831115B (en) | Ethylene propylene rubber insulation material for longitudinal high-voltage watertight cable of ships and warships and production method thereof | |
| CN101987902B (en) | Halogen-free thermoplastic elastomer and manufacturing method thereof and environment-friendly electric wires and cables using halogen-free thermoplastic elastomer | |
| JP6379776B2 (en) | Non-halogen flame retardant thermoplastic elastomer composition, method for producing the same, electric wire and cable | |
| EP2630187B1 (en) | A semiconductive polyolefin composition which contains epoxy-groups | |
| CN101781419B (en) | Organosilane crosslinked polyethylene insulation material for 20kV cable and preparation method thereof | |
| CN103205034A (en) | Butyronitrile-PVC (polyvinyl chloride) compound elastomer insulation material for wires and cables and preparation method of butyronitrile-PVC compound elastomer insulation material | |
| CN105086458A (en) | Semi-conducting silicon rubber shielding material for cables | |
| CN104087001B (en) | Medium pressure grade low-smoke non-halogen flame-retardant silicon rubber insulation material and manufacturing process thereof | |
| CN102618040B (en) | Method for preparing ceramifiable silicon rubber refractory material by adopting radiation crosslinking process | |
| CN103665825B (en) | Manufacture matrix material and the complete processing of high temperature resistant halogen-free flame-retardant PPE cable | |
| CN114933759A (en) | Preparation method of silane self-crosslinking low-halogen flame-retardant polyolefin cable material | |
| KR101318457B1 (en) | Insulating composition for dc power cable and dc power cable prepared by using the same | |
| CN103489525B (en) | Naval vessel high current-carrying capacity low surface temperature rise height protective cable and manufacture method thereof | |
| CN104072997A (en) | Fluorine-silicon para-position aramid fiber high-insulativity material, and production method and application thereof | |
| JP2016173918A (en) | Insulated wire and cable using the same | |
| CN103971826A (en) | Torsion-resistant cable | |
| CN110305396A (en) | A kind of dedicated cross-linked polyvinyl of cable and its preparation process | |
| CN105255017A (en) | Ethylene-propylene rubber insulating material for medium voltage power cable and preparation method thereof | |
| CN110982186A (en) | Insulating layer of electric appliance connecting wire and preparation method thereof | |
| CN102504421A (en) | Insulation rubber for oceaneering fireproof medium-voltage electric cables and manufacturing method thereof | |
| CN100514507C (en) | Screening material for medium voltage rubber insulation cable | |
| CN103554634A (en) | High-voltage cable structure with insulating layer with excellent performance | |
| CN104877228A (en) | Anti-pollution and self-cleaning halogen-free flame retardant insulating material for household appliance and preparation method of anti-pollution and self-cleaning halogen-free flame retardant insulating material | |
| CN110903545A (en) | Anti-aging acid-alkali-resistant cable material and preparation method thereof | |
| CN103928134B (en) | Intrinsic safety type composite cable with Y shape rubber skeleton |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20191107 Address after: Room 107, building 3, No.118, Kangbao Road, ganyao Town, Jiashan County, Jiaxing City, Zhejiang Province Patentee after: Jiaxing Junhong Optical Co., Ltd Address before: 225129 Jiangsu city of Yangzhou province Guazhou town Hanjiang District Stone Road No. 2 Patentee before: Jiangsu Yuanyang Dongze Cable Co., Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20111221 Termination date: 20210429 |