CN101830614A - Biological treatment method for waste mud in petroleum and natural gas exploration drilling operation - Google Patents

Biological treatment method for waste mud in petroleum and natural gas exploration drilling operation Download PDF

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CN101830614A
CN101830614A CN 201010148295 CN201010148295A CN101830614A CN 101830614 A CN101830614 A CN 101830614A CN 201010148295 CN201010148295 CN 201010148295 CN 201010148295 A CN201010148295 A CN 201010148295A CN 101830614 A CN101830614 A CN 101830614A
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treatment layer
waste mud
water content
soil
discarded slurry
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CN101830614B (en
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陈立荣
范有余
陈强
黄敏
蒋学彬
李辉
张敏
易畅
叶茂
廖玲
徐柄科
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China National Petroleum Corp
CNPC Chuanqing Drilling Engineering Co Ltd
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CNPC Chuanqing Drilling Engineering Co Ltd
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Abstract

The invention discloses a biological treatment method for waste mud in petroleum and natural gas exploration drilling operation, which is characterized by comprising the following steps: a. a microorganism treatment layer, wherein special microorganism strains are inoculated into the waste slurry according to the weight ratio of 3-5: 100 and are uniformly mixed; according to the density condition of the waste mud and the water content of 10-15%, fully and uniformly stirring the natural soil with the grain size less than 0.5cm in the following way to form a microorganism treatment layer; adding the waste mud with the density of 1-1.5kg/L into the natural soil according to 2.5-3 times of the weight of the waste mud; adding the waste mud with the density of 1.5-2.5kg/L into the natural soil according to the weight of 2-2.5 times; controlling the water content of the microbial treatment layer to be kept between 25% and 30%; b. treating soil; c. and (4) treating the plants. By adopting the method, the technical problem that in the prior art, under the condition that pollutants in the mixture at the early stage of treatment are not effectively degraded, natural soil with overlarge water content and particle size is easily washed by heavy rain, so that leakage liquid enters underground water to pollute water sources can be solved.

Description

Biological treatment method for waste mud in petroleum and natural gas exploration drilling work
Technical field
The present invention relates to oil and gas exploration drilling well Pollution abatement technical field, exactly relate to a kind of treatment process that is applied in the oil and gas well drilling operation discarded slurry.
Background technology
The drilling well discarded slurry is a component part important in the oil and gas well drilling process, it often is referred to as " blood " of drilling well in the sector, it just becomes discarded slurry after drilling operation is finished, general a bite well is because of the difference of institute's drilling depth, with the discarded slurry that produces 300~400 cubic metres, it mainly is by clay, drilling cuttings, high-density weighting material, various chemical additives (generally reaching 40~50 kinds of inorganic and organic chemistry treatment additives), inorganic salt, the heterogeneous stable suspersion liquid mixture that oil is formed, its composition is complicated especially, pollution hazard is big, the pH value is high: be generally 8.5~10.0, have up to 11.0; COD is up to 10000~100000mg/L; Oil-contg is also higher.
At present, domestic when disposing the oil and gas well drilling discarded slurry, mainly adopt the mode of direct landfill or solidification treatment.Because discarded slurry contains a large amount of organic and inorganic pollutants, directly landfill can produce serious pollution and harm to surface water, underground water and soil; Solidification processing method can solve the pollution hazard of discarded slurry substantially in the short period of time, but in the long run, cured block is embedded in the underground for a long time, and a series of variations will take place its inner drilling well discarded slurry, thereby cause the pollution of edatope; And the soil after solidifying has also lost cultivates value.Therefore; in order to realize to the recycle truly of oilfield drilling operation discarded slurry; preserve the ecological environment, guarantee the Sustainable development of oil-gas drilling exploitation, it is extremely urgent to explore enforcement oil and gas well drilling discarded slurry harmlessness disposing new technology.
At this situation, there are indivedual companies to adopt the technology of microorganism, soil and plant combined processing oil and gas exploration drilling well discarded slurry at present, the concrete technical scheme of this technology comprises:
A kind of waste mud in petroleum and natural gas exploration drilling work treatment process is characterized in that step comprises:
A, microbiological treatment: the weight ratio of special microorganism strain by 5: 100 is added in the discarded slurry, mixes; And the weight ratio of natural soils by 2: 1 be added in the discarded slurry of having sneaked into special microorganism strain, mix, thereby form the microbiological treatment layer; Described special microorganism strain is the bacillus megaterium (Bacillus megaterium) in Halomonas ventosae bacterium, Halomonas campisalis bacterium and the bacillus in the salt zygosaccharomyces;
B, soil treatment: at the microbiological treatment laminar surface that a step forms, cover the natural soils of 10-15cm, form the soil treatment layer;
C, plant treatment: on the surface of soil treatment layer, plantation pulse family class and non-pulse family parasymbiosis nitrogen fixing tree are perhaps planted herbaceous plant, form the plant treatment layer.
In the described c step, described pulse family class and non-pulse family parasymbiosis nitrogen fixing tree are Leucaena leucocephala (L.) or alder.
In the described c step, described herbaceous plant is Chinese silvergrass or trifolium.
In the described a step, Halomonas ventosae bacterium is 4 strains, and Halomonas campisalis bacterium is 1 strain, and bacillus megaterium (Bacillus megaterium) also is 1 strain.
In the described a step, the natural soils of adding through airing after, and to be adjusted to water content be that 15-20%, particle diameter are the soil of 0.5-1cm.
In the described a step, the water content of microbiological treatment layer is 20-30%.
In the described b step, natural soils are through after the airing, and to be adjusted to water content be that 15-20%, particle diameter are the soil of 0.5-1cm.
This technology is with respect to existing direct landfill or solidification treatment mode, on the one hand, is applicable in the drilling operation scene the direct processing to discarded slurry more; On the other hand, this method utilizes the effect of microbial strains that COD index, Oil index etc. in the drilling operation waste are effectively reduced, most of organic matter degradations are become simple inorganics, thereby make the pollutent in the mud obtain removing, finally realized the purpose that the pollutent harmless biological is handled in the drilling operation discarded slurry, even directly landfill also can not produce pollution and harm to surface water, underground water and soil; Again on the one hand; this method does not need to adopt cement etc. for the cured block that the solidify material of main body forms, and protects discarded slurry, has kept the value of cultivating in soil; the needs that adapt to national energy saving policy have fully also been guaranteed the Sustainable development of oil-gas drilling exploitation.
But above-mentioned technology, the process applicant is test of many times in actual use, still there are a lot of problems, for example: because the density of the post-job discarded slurry of oil gas well drilling is had nothing in common with each other, if without exception natural soils being added to density by 2: 1 weight ratio has nothing in common with each other and has sneaked in the discarded slurry of special microorganism strain, obtained microbiological treatment effect is unsatisfactory, microbic activity is not in full use, not obvious to the difficult degradation organic double compound action effect in the discarded slurry, thereby the pollutent in the mud is effectively removed, can not be reached innoxious purpose.Again for example: the soil moisture content that is adopted among step a and the b is that 15-20%, particle diameter are the soil of 0.5-1cm, water content is too high, particle diameter is excessive, cause with the mixed water content of discarded slurry that has added microbial strains bigger than normal, cause the microbic activity influence, not obvious to the difficult degradation organic double compound action effect in the discarded slurry, thus the pollutent in the mud is effectively removed, can not reach innoxious purpose; And the water content of soil treatment layer is excessive, and under the situation that pollutent is not effectively degraded as yet in handling the mixture in early stage, thereby the excessive natural soils of this water content and particle diameter are washed away by heavy rain easily and cause effusion to enter underground water and cause pollution of waterhead.
Summary of the invention
For solving the problems of the technologies described above, the present invention proposes a kind of Different Weight of carrying out at the discarded slurry of different densities than the mixing natural soils, thereby really bring into play microbic activity, organic double compound in the discarded slurry is effectively degraded, reach innoxious purpose biological treatment method for waste mud in petroleum and natural gas exploration drilling work, simultaneously, adopt present method, can also solve under the above-mentioned prior art situation that pollutent is not effectively degraded as yet in handling the mixture in early stage, thereby the excessive natural soils of water content and particle diameter are washed away the technical problem that causes effusion to enter underground water and cause pollution of waterhead by heavy rain easily.
The present invention realizes by adopting following technical proposals:
A kind of biological treatment method for waste mud in petroleum and natural gas exploration drilling work is characterized in that step comprises:
A, microbiological treatment layer, with special microorganism strain by 3-5: 100 weight ratio is seeded in the discarded slurry, mixes; Press the density situation and the water content 10%-15% of discarded slurry, the natural soils of particle diameter<0.5cm stir by following mode, form the microbiological treatment layer:
Density is to add described natural soils by 2.5-3 times of weight in the discarded slurry of 1-1.5kg/L;
Density is to add described natural soils by 2-2.5 times of weight in the discarded slurry of 1.5-2.5kg/L;
The water content of controlling described microbiological treatment layer remains between the 25%-30%;
Described special microorganism strain is anti-high pH salt zygosaccharomyces bacterium, comprises 1 strain bacillus megaterium Bacillus megaterium in 4 strain Halomonasventosae bacteriums, 1 strain Halomonas campisalis bacterium and the bacillus;
B, soil treatment: the microbiological treatment layer heap that a step is formed is embedded in handling and excavates in the tunnel that forms, and covers the topsoil gong of 10-15cm at the microbiological treatment laminar surface, forms the soil treatment layer;
C, plant treatment: on the surface of soil treatment layer, plantation pulse family class and non-pulse family parasymbiosis nitrogen fixing tree are perhaps planted herbaceous plant, form the plant treatment layer.
In the described c step, described pulse family class and non-pulse family parasymbiosis nitrogen fixing tree are Leucaena leucocephala (L.) or alder.
In the described c step, described herbaceous plant is Chinese silvergrass or trifolium.
In the described a step, the natural soils of adding through airing after.
In the described b step, topsoil gong is through after the airing, and to be adjusted to water content be 10%-15%, the natural soils of particle diameter<0.5cm.
The beneficial effect that the present invention reached shows:
1, owing to adopt in a step of the present invention " press the density situation and the water content 10%-15% of discarded slurry; the natural soils of particle diameter<0.5cm stir by following mode, formation microbiological treatment layer: density is to add described natural soils by 2.5-3 times of weight in the discarded slurry of 1-1.5kg/L; Density is to add described natural soils by 2-2.5 times of weight in the discarded slurry of 1.5-2.5kg/L; " such technical scheme; compared with prior art; through repeatedly experiment; find; it can give full play to the activity of the special microorganism of inoculating, and obtained microbiological treatment effect is very good, and is particularly evident to the difficult degradation organic double compound action effect in the discarded slurry; thus the pollutent in the mud is effectively removed, reach innoxious purpose; In addition, because the soil that the present invention adopts is water content 10%-15%, the natural soils of particle diameter<0.5cm or topsoil gong, it is suitable to make with the mixed water content of discarded slurry that has added microbial strains, suitable microbic activity is given full play to, more obvious to the difficult degradation organic double compound action effect in the discarded slurry, thus the pollutent in the mud is effectively removed, reached innoxious purpose; And, the water content of soil treatment layer is chosen in 10-15%, and particle diameter is controlled at less than 0.5cm, water content is suitable, find under its situation that pollutent is not effectively degraded as yet in handling the mixture in early stage through repeatedly testing, the effect that the uprising rain of the natural soils of this water content and particle diameter directly washes away is very good, thereby avoids causing effusion to enter underground water and cause the situation of pollution of waterhead to take place.
2, because the present invention adopts the method for the triple associating repair processes of microbiological treatment, soil treatment and plant treatment, on the one hand, present method adopt in discarded slurry, add special microorganism strain, on soil the mode of serike, be applicable in the drilling operation scene direct processing more to discarded slurry; On the other hand, present method utilizes the effect of microbial strains that COD index, Oil index etc. in the drilling operation waste are effectively reduced, most of organic matter degradations are become simple inorganics, thereby make the pollutent in the mud obtain removing, finally realized the purpose that the pollutent harmless biological is handled in the drilling operation discarded slurry, even directly landfill also can not produce pollution and harm to surface water, underground water and soil; On the other hand; adopt present method not need to adopt cement etc., protect discarded slurry, kept the value of cultivating in soil for the cured block that the solidify material of main body forms; the needs that adapt to national energy saving policy have fully also been guaranteed the Sustainable development of oil-gas drilling exploitation.
3, the Leucaena leucocephala (L.) of planting in present method, alder are pulse family and non-pulse family parasymbiosis nitrogen fixing tree, transform the nitrogen (N in the atmosphere 2) be ammonia (NH 3) provide plant-growth required nitrogenous source, also provide nitrogen nutrition simultaneously for mud degraded microorganism.In the herbaceous plant of plantation, Chinese silvergrass has barren-resistant, arid characteristics, and trifolium can symbiotic nitrogen fixation.The effect of draft class plant is mulching soil top layer preferably, prevent and treat heavy rain in summer washing away effectively to shallow soil, it is underground also can to avoid a large amount of rainwater to enter, and has guaranteed that system for handling that this treatment process forms can not produce effusion and enter underground water and cause pollution of waterhead.
Description of drawings
The present invention is described in further detail below in conjunction with specification drawings and specific embodiments, wherein:
Fig. 1 is the structural representation of the system for handling that this treatment process constituted
Mark among the figure:
1, microbiological treatment layer, 2, the soil treatment layer, 3, the plant treatment layer.
Embodiment
Embodiment 1
The invention discloses a kind of biological treatment method for waste mud in petroleum and natural gas exploration drilling work, its step comprises:
A, microbiological treatment layer 1, with special microorganism strain by 3-5: 100 weight ratio is seeded in the discarded slurry, mixes; Press the density situation and the water content 10%-15% of discarded slurry, the natural soils of particle diameter<0.5cm stir by following mode, form microbiological treatment layer 1:
Density is to add described natural soils by 2.5-3 times of weight in the discarded slurry of 1-1.5kg/L;
Density is to add described natural soils by 2-2.5 times of weight in the discarded slurry of 1.5-2.5kg/L;
The water content of controlling described microbiological treatment layer 1 remains between the 25%-30%;
Described special microorganism strain is anti-high pH salt zygosaccharomyces bacterium, comprises 1 strain bacillus megaterium Bacillus megaterium in 4 strain Halomonasventosae bacteriums, 1 strain Halomonas campisalis bacterium and the bacillus;
B, soil treatment: microbiological treatment layer 1 heap that a step is formed is embedded in handling and excavates in the tunnel that forms, and at the topsoil gong of microbiological treatment layer 1 surface coverage 10-15cm, formation soil treatment layer 2;
C, plant treatment: on the surface of soil treatment layer 2, plantation pulse family class and non-pulse family parasymbiosis nitrogen fixing tree are perhaps planted herbaceous plant, form plant treatment layer 3.
Embodiment 2
As a better embodiment of the present invention, on the basis of embodiment 1, in the described c step, described pulse family class and non-pulse family parasymbiosis nitrogen fixing tree are Leucaena leucocephala (L.) or alder.In the described c step, described herbaceous plant is Chinese silvergrass or trifolium.In the described a step, the natural soils of adding through airing after.In the described b step, topsoil gong is through after the airing, and to be adjusted to water content be 10%-15%, the natural soils of particle diameter<0.5cm.The per-cent of described water content is weight ratio.Said COD is meant in the drilling well field among the present invention, the COD index during castaway slag mud is handled, and promptly chemical oxygen demand (COD), Oil are oil index.
Embodiment 3
As the another better embodiment of the present invention, step comprises:
A, microbiological treatment layer 1 are seeded to the weight ratio of special microorganism strain by 5: 100 in the discarded slurry, mix; Press the density situation and the water content 12% of discarded slurry, particle diameter is that the natural soils of 0.3cm stir by following mode, forms microbiological treatment layer 1:
Density is to add described natural soils by 2.8 times of weight in the discarded slurry of 1.2kg/L;
The water content of controlling described microbiological treatment layer 1 remains on 28%;
Described special microorganism strain is anti-high pH salt zygosaccharomyces bacterium, comprises 1 strain bacillus megaterium Bacillus megaterium in 4 strain Halomonasventosae bacteriums, 1 strain Halomonas campisalis bacterium and the bacillus;
B, soil treatment: microbiological treatment layer 1 heap that a step is formed is embedded in handling and excavates in the tunnel that forms, and at the topsoil gong of microbiological treatment layer 1 surface coverage 13cm, formation soil treatment layer 2;
C, plant treatment: on the surface of soil treatment layer 2, plantation pulse family class and non-pulse family parasymbiosis nitrogen fixing tree are perhaps planted herbaceous plant, form plant treatment layer 3.
In the described c step, described pulse family class and non-pulse family parasymbiosis nitrogen fixing tree are Leucaena leucocephala (L.) or alder.
In the described c step, described herbaceous plant is Chinese silvergrass or trifolium.
In the described a step, the natural soils of adding through airing after.
In the described b step, topsoil gong is through after the airing, and to be adjusted to water content be 13%, and particle diameter is the natural soils of 0.4cm.
Embodiment 4
As the another better embodiment of the present invention, density is to add described natural soils by 2.2 times of weight in the discarded slurry of 2kg/L; All the other steps are identical with embodiment 3.
Embodiment 5
Technical scheme of the present invention is: the peculiar microorganism bacterial classification that inoculation has Degradation in the drilling operation discarded slurry, again with the soil of water content 10%-15% (mud: mixing soil=1: 2 ratio) by a certain percentage, soil mixture is stacked, serike thereon, utilize microorganism-soil-plant associating system to handle the complicated pollutent in the drilling well discarded slurry, finally realize the purpose that the pollutent harmless biological in the drilling well discarded slurry is handled.
The peculiar microorganism that the present invention adopts is the salt zygosaccharomyces bacterium of anti-high pH, comprise Halomonas ventosae and Halomonas campisalis, these bacterial strains can be bought from Institute of Micro-biology of Chinese Academy of Sciences bacterial classification preservation center, and drilling well discarded slurry component is had good Degradation.Utilize these special bacteriums that the complex material part in the Oil and Gas Exploration Drilling discarded slurry is converted into the agron component, a part is degraded to simple organic-inorganic compound, utilizes for other microorganism in the soil and the plant of being planted.It is pulse family and non-pulse family class seeds that the plant of plantation has Leucaena leucocephala (L.), alder, the twigs of the chaste tree, but symbiotic nitrogen fixation is drought-resistant and barren.The herbaceous plant of plantation comprises Chinese silvergrass, trifolium, and Chinese silvergrass has barren-resistant, arid characteristics, and trifolium can symbiotic nitrogen fixation.The effect of draft class plant is mulching soil top layer preferably, prevent and treat heavy rain in summer washing away effectively to the soil mixture top layer, it is underground to prevent effectively that also a large amount of rainwater from entering, under the situation that pollutent is not effectively degraded as yet in handling the mixture in early stage, can guarantee that this system for handling can not form effusion and enter underground water and cause pollution of waterhead.
The amount inoculation bacterium for degrading microbial inoculum of pressing 3%-5% (weight ratio) is in the oilfield drilling discarded slurry, mix with mixing machine, the density situation of pressing discarded slurry is again with after abundant airing, water content 10%-15%, the soil of particle diameter<0.5cm fully stirs by a certain percentage, generally, mud density is 2.5~3 times of (weight ratio) soil of adding of 1~1.5kg/l, mud density is 2~2.5 times of soil of adding of 1.5~2.5kg/l, and this mixed system water content remains between the 25%-30%.
Near the drilling well field, select to be difficult for form the place of runoff, around build headrace, handle the field to prevent that rainwash from entering.Excavate into the tunnel that the degree of depth is 0.8-1.2m with handling the field, length and width are determined according to physical features, and soil mixture is stacked in the disposal field, cover 10~15cm topsoil gong in the above, and plant plants such as Leucaena leucocephala (L.), alder, the twigs of the chaste tree, Chinese silvergrass, trifolium.
The invention has the beneficial effects as follows: utilize the effect of special microorganism strain that COD, Oil etc. in the drilling operation discarded slurry are effectively removed, most of organic matter degradations are become simple inorganics, thereby make the pollutent in the mud obtain removing, make it reach innoxious purpose.To stablizing drilling operation area peripheral edge environmental quality, promote the coordinated development of oil and gas exploration drilling operation and local environment protection to be of great practical significance.Compare with existing solidification processing method, present method meets the energy-conservation and Sustainable development policy (can save a large amount of curing cements and curing place agent) of country more.
Embodiment 6
With reference to Figure of description, the present invention includes microbiological treatment layer 1, soil treatment layer 2, plant treatment layer 3, drilling well discarded slurry, microbial strains.At first be to handle the natural soils of usefulness, regulate its water content and particle directly earlier through airing.Ratio in 3%-5% (weight ratio) is added on special microorganism strain in the oilfield drilling discarded slurry then, after utilizing mixing machine to mix, add 2 times of (with the weight ratio of drilling well discarded slurry) natural soils and thorough mixing that airing is good, the mixed system water content is about 25%-30%, after mixing this mixture placed and handle, as microbiological treatment layer 1, on microbiological treatment layer 1, cover 10~15cm anthropogenic soil, and plant some local common view and admire or the fuel wood plant as plant treatment layer 3, to prevent rainwater directly washing away to processing layer.

Claims (5)

1. biological treatment method for waste mud in petroleum and natural gas exploration drilling work is characterized in that step comprises:
A, microbiological treatment layer (1), with special microorganism strain by 3-5: 100 weight ratio is seeded in the discarded slurry, mixes; Press the density situation and the water content 10%-15% of discarded slurry, the natural soils of particle diameter<0.5cm stir by following mode, form microbiological treatment layer (1):
Density is to add described natural soils by 2.5-3 times of weight in the discarded slurry of 1-1.5kg/L;
Density is to add described natural soils by 2-2.5 times of weight in the discarded slurry of 1.5-2.5kg/L;
The water content of controlling described microbiological treatment layer (1) remains between the 25%-30%;
Described special microorganism strain is anti-high pH salt zygosaccharomyces bacterium, comprises 1 strain bacillus megaterium Bacillus megaterium in 4 strain Halomonasventosae bacteriums, 1 strain Halomonas campisalis bacterium and the bacillus;
B, soil treatment: microbiological treatment layer (1) heap that a step is formed is embedded in handling and excavates in the tunnel that forms, and at the topsoil gong of microbiological treatment layer (1) surface coverage 10-15cm, forms soil treatment layer (2);
C, plant treatment: the surface in soil treatment layer (2), plantation pulse family class and non-pulse family parasymbiosis nitrogen fixing tree are perhaps planted herbaceous plant, form plant treatment layer (3).
2. biological treatment method for waste mud in petroleum and natural gas exploration drilling work according to claim 1 is characterized in that: in the described c step, described pulse family class and non-pulse family parasymbiosis nitrogen fixing tree are Leucaena leucocephala (L.) or alder.
3. biological treatment method for waste mud in petroleum and natural gas exploration drilling work according to claim 1 is characterized in that: in the described c step, described herbaceous plant is Chinese silvergrass or trifolium.
4. according to claim 1 or 2 or 3 described biological treatment method for waste mud in petroleum and natural gas exploration drilling work, it is characterized in that: in the described a step, the natural soils of adding through airing after.
5. biological treatment method for waste mud in petroleum and natural gas exploration drilling work according to claim 4, it is characterized in that: in the described b step, topsoil gong is through after the airing, and to be adjusted to water content be 10%-15%, the natural soils of particle diameter<0.5cm.
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CN102865047A (en) * 2012-10-10 2013-01-09 杨德敏 Bioremediation method for abandoned drilling fluids of oil and gas fields and shale gas fields
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CN104086065A (en) * 2014-06-18 2014-10-08 中国石油集团川庆钻探工程有限公司 Microorganism treatment process for waste mud in petroleum and natural gas drilling operation
CN106186357A (en) * 2016-08-15 2016-12-07 中石化石油工程技术服务有限公司 A kind of rejected well drilling liquid microbial treatment method
CN107956436A (en) * 2017-12-04 2018-04-24 中国石油集团川庆钻探工程有限公司 Method for treating oil-based drilling cuttings in drilling operation
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CN102865047B (en) * 2012-10-10 2015-04-29 重庆地质矿产研究院 Bioremediation method for waste drilling mud of oil and gas field and shale gas field
CN103435241A (en) * 2013-09-18 2013-12-11 中国石油集团川庆钻探工程有限公司 Oil-gas field drilling waste mud treatment process
CN103435241B (en) * 2013-09-18 2015-12-09 中国石油集团川庆钻探工程有限公司 Oil-gas field drilling waste mud treatment process
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CN106186357B (en) * 2016-08-15 2022-06-03 中石化石油工程技术服务有限公司 Microbiological treatment method for waste drilling fluid
CN107956436A (en) * 2017-12-04 2018-04-24 中国石油集团川庆钻探工程有限公司 Method for treating oil-based drilling cuttings in drilling operation
CN110340116A (en) * 2019-07-29 2019-10-18 中国石油集团川庆钻探工程有限公司 Solid waste recycling treatment and utilization process of water-based drilling fluid system
CN110449446A (en) * 2019-07-29 2019-11-15 中国石油集团川庆钻探工程有限公司 Water-based drilling soft solid waste recycling treatment and utilization process
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CN111360029A (en) * 2020-03-18 2020-07-03 中国石油天然气集团有限公司 Classification treatment and utilization method of water-based solid waste of petroleum and natural gas exploration drilling
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