CN101816979A - Flotation activating agent of marmatite and blende and preparation method thereof - Google Patents
Flotation activating agent of marmatite and blende and preparation method thereof Download PDFInfo
- Publication number
- CN101816979A CN101816979A CN201010124710.7A CN201010124710A CN101816979A CN 101816979 A CN101816979 A CN 101816979A CN 201010124710 A CN201010124710 A CN 201010124710A CN 101816979 A CN101816979 A CN 101816979A
- Authority
- CN
- China
- Prior art keywords
- solution
- marmatite
- activator
- activating agent
- quality
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000005188 flotation Methods 0.000 title claims abstract description 24
- 230000003213 activating effect Effects 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000010949 copper Substances 0.000 claims abstract description 16
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 14
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052802 copper Inorganic materials 0.000 claims abstract description 11
- 239000012190 activator Substances 0.000 claims description 37
- 229910052984 zinc sulfide Inorganic materials 0.000 claims description 37
- WGPCGCOKHWGKJJ-UHFFFAOYSA-N sulfanylidenezinc Chemical compound [Zn]=S WGPCGCOKHWGKJJ-UHFFFAOYSA-N 0.000 claims description 35
- 238000006243 chemical reaction Methods 0.000 claims description 31
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 24
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 238000001914 filtration Methods 0.000 claims description 12
- 238000007605 air drying Methods 0.000 claims description 6
- 239000012043 crude product Substances 0.000 claims description 6
- 230000003292 diminished effect Effects 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 238000001556 precipitation Methods 0.000 claims description 6
- 239000000047 product Substances 0.000 claims description 6
- 239000013049 sediment Substances 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 6
- 239000003446 ligand Substances 0.000 claims description 4
- 239000011701 zinc Substances 0.000 abstract description 35
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 34
- 229910052725 zinc Inorganic materials 0.000 abstract description 34
- 230000004913 activation Effects 0.000 abstract description 13
- 238000011084 recovery Methods 0.000 abstract description 13
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 abstract description 11
- 235000008733 Citrus aurantifolia Nutrition 0.000 abstract description 9
- 235000011941 Tilia x europaea Nutrition 0.000 abstract description 9
- 239000003795 chemical substances by application Substances 0.000 abstract description 9
- 239000004571 lime Substances 0.000 abstract description 9
- 239000012141 concentrate Substances 0.000 abstract description 7
- 239000002184 metal Substances 0.000 abstract description 7
- 229910052751 metal Inorganic materials 0.000 abstract description 7
- 229910052569 sulfide mineral Inorganic materials 0.000 abstract description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 150000001875 compounds Chemical class 0.000 abstract 2
- 230000005764 inhibitory process Effects 0.000 abstract 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 abstract 1
- 229910000510 noble metal Inorganic materials 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 37
- 238000000034 method Methods 0.000 description 22
- 229910052742 iron Inorganic materials 0.000 description 18
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 12
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 9
- 239000005864 Sulphur Substances 0.000 description 8
- 229910052500 inorganic mineral Inorganic materials 0.000 description 8
- 239000011707 mineral Substances 0.000 description 8
- 229910052738 indium Inorganic materials 0.000 description 7
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 7
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229910052709 silver Inorganic materials 0.000 description 5
- 239000004332 silver Substances 0.000 description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000003825 pressing Methods 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 239000011135 tin Substances 0.000 description 4
- 229910052718 tin Inorganic materials 0.000 description 4
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 4
- GZCWPZJOEIAXRU-UHFFFAOYSA-N tin zinc Chemical compound [Zn].[Sn] GZCWPZJOEIAXRU-UHFFFAOYSA-N 0.000 description 4
- 239000003513 alkali Substances 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 239000010970 precious metal Substances 0.000 description 3
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 238000006477 desulfuration reaction Methods 0.000 description 2
- 230000023556 desulfurization Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229910052733 gallium Inorganic materials 0.000 description 2
- 229910052732 germanium Inorganic materials 0.000 description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000010310 metallurgical process Methods 0.000 description 2
- 238000005065 mining Methods 0.000 description 2
- 229910052683 pyrite Inorganic materials 0.000 description 2
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 2
- 239000011028 pyrite Substances 0.000 description 2
- 241000283690 Bos taurus Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000784732 Lycaena phlaeas Species 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- MJLGNAGLHAQFHV-UHFFFAOYSA-N arsenopyrite Chemical compound [S-2].[Fe+3].[As-] MJLGNAGLHAQFHV-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910052951 chalcopyrite Inorganic materials 0.000 description 1
- DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000009429 distress Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 238000009854 hydrometallurgy Methods 0.000 description 1
- NJWNEWQMQCGRDO-UHFFFAOYSA-N indium zinc Chemical compound [Zn].[In] NJWNEWQMQCGRDO-UHFFFAOYSA-N 0.000 description 1
- NNIPDXPTJYIMKW-UHFFFAOYSA-N iron tin Chemical compound [Fe].[Sn] NNIPDXPTJYIMKW-UHFFFAOYSA-N 0.000 description 1
- JQJCSZOEVBFDKO-UHFFFAOYSA-N lead zinc Chemical compound [Zn].[Pb] JQJCSZOEVBFDKO-UHFFFAOYSA-N 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000009304 pastoral farming Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- AFNRRBXCCXDRPS-UHFFFAOYSA-N tin(ii) sulfide Chemical compound [Sn]=S AFNRRBXCCXDRPS-UHFFFAOYSA-N 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Manufacture And Refinement Of Metals (AREA)
Abstract
The invention provides a flotation activating agent of marmatite and blende, which is a coordination compound of copper and ammonia and is characterized in that the molecular formula of the coordination compound is [Cu(NH3)x]2+, wherein X=1-8. The activating agent of the invention solves the problem of selected activation and inhibition of marmatite, overcomes the problems of low activation selection, low zinc concentrate grade, serious metal mutual containing and the like of common activating agent copper sulphate and solves the problems of high-efficiency enrichment and comprehensive recovery of concomitant rare and noble metal. The activating agent is activated under the condition that pH value is as low as 7-11, provides necessary guarantee for reducing lime dosage in production, reasonably and effectively recovers other sulfide minerals and comprehensively recovers rare metal, and has the advantages of high activation efficiency, low production cost and the like. The invention also applies a preparation method for the flotation activating agent.
Description
Technical field
The present invention relates to ore dressing engineering and rare precious metal comprehensive utilization technique field, particularly a kind of efficient activator that is used for marmatite and zincblende flotation and its production and use.
Background technology
China's zinc metal reserves account for 15% of world's gross reserves, occupy the second in the world, and China also is a zinc big producing country simultaneously, and zinc metal output reached 374.9 ten thousand tons in 2007, ranked first in the world, and export volume reaches 27.56 ten thousand tons.Along with development and national economy, increase to zinc metal demand, press for the resource of complicated difficult choosing is developed and utilized, it is more domestic that leaded, zinc, sulphur, iron or zinc, copper, tin, iron, the plumbous zinc ore mountain of sulphur and zinc-tin mine etc. are in various degree the marmatite that contains choosing in distress all, for example, the big factory in Guangxi, river three plumbous zinc ores, the yellow sand level ground in Hunan, Pan Jiachong, the plumbous zinc ore of HERBA ONYCHII, the plumbous zinc ore in the Hezhang in Guizhou, the plumbous zinc ore in the tin iron mountain in Qinghai, the plumbous zinc ore in the XiLin in Heilungkiang, the ditch of grazing cattle in Jilin, so ox is washed in a pan plumbous zinc ore, the plumbous zinc ore of thick mother-in-law's col in Guangdong, all Long Xinxikuang in Yunnan and billows deep blue lead ore etc.The marmatite iron content in these mines is generally 8-12%, have up to 26%, therefore, adopt suitable marmatite ore-dressing technique, marmatite is developed and utilized significant.
Zincblende, marmatite and wurtzite are three kinds of common zinc sulfide minerals.Zincblende (ZnS) belongs to isometric system, and crystalline form often is a tetrahedron; Natural cleiophane contains zinc 67.1%, 32.9% sulphur.Wurtzite is general similar to the physical property of zincblende, generally rare in practice.The zincblende of iron content more than 6% is called marmatite [(Zn
XFe
1-XS)], zinc blend lattice is often sneaked into isomorph by Tie Tong, and the quantity of infiltrating iron is generally 6～12% (Gao Shida 26%).
In actual process, marmatite than zincblende show not easily-activated, floatability is poor, to characteristics such as medium sensitivities, it is difficult to separate with mineral such as magnetic iron ore, pyrite and mispickel.Simultaneously, compare with other sulfide mineral, the floatability of marmatite or zincblende is far smaller than other sulfide minerals, the general not activated marmatite or the flotation of zincblende need need the above xanthate of 4 carbon with hybrid collector or chain length, make the flotation of the zincblende comparison difficulty that seems.Therefore, activation is the important step in the marmatite ore dressing.Main in producing at present with the activator of copper sulphate as marmatite, however copper sulphate has following defective as activator:
(1) select marmatite for difficulty, the activation of copper sulphate is unsatisfactory, does not reach good index.
(2) activity function of copper sulphate strengthens along with the enhancing of alkalescence, therefore, the activation of copper sulphate generally is to carry out under a high-alkali environment, thereby certainly will need to add a large amount of lime aborning, so just suppress the flotation of the relatively poor zincblende of floatability, marmatite and oxidized mineral such as chalcopyrite.
(3) rolling up of lime consumption not only increases beneficiation cost, increases workman's workload, and from ore dressing and comprehensive the recovery and the angle of utilizing, the lime of big consumption also is worthless.In selecting the zinc process, adjust the pH value and suppress after other sulfide minerals with a large amount of lime, during next step flotation must come with a large amount of sulfuric acid and the lime in the ore pulp, to reduce the pH value, perhaps add a large amount of activator activation and other sulfide minerals of flotation, this has not only further increased beneficiation cost, and the calcium sulfate that lime and sulfuric acid reaction generate is easy to blocking pipe, at the gravitational separation equipment surface scale, seriously influences the continuity of mineral processing circuit and the rate of recovery of gravity treatment; In addition, sulfuric acid also can produce etching problem to pipeline and preparation equipment.
(4) copper sulphate and combination activator thereof also can activate difficult floating magnetic iron ore in the activation marmatite, increase the iron content in the zinc concentrate, to follow-up hydrometallurgy process, zinc and indium further separated with enrichment very unfavorable.In order to suppress magnetic iron ore, the often possible and large usage quantity of the kind of inhibitor, flow process are also complicated more.If the activator that is adopted is under low alkali condition, do not activate magnetic iron ore or pyrite and only activate marmatite and zincblende, then can simplify the deironing sulfur removal technology, save production cost, improve the grade and the rate of recovery of zinc concentrate zinc, indium, silver etc., reduce the content of iron and sulphur in the zinc concentrate, reduce the adverse effect of element such as iron in the zinc concentrate follow-up metallurgical process; Simultaneously, can also improve the rate of recovery of reselection operation significantly.
As seen, there are a lot of defectives in conventional activator of the at present domestic and international marmatite that adopts and inhibitor, and its activation is not high with the efficient and the selectivity that suppress, causes the rate of recovery of zinc and zinc concentrate grade not high, and metal contains seriously mutually.
Summary of the invention
The objective of the invention is: overcome the deficiency of existing activator copper sulphate, the dressing activator of high marmatite of a kind of activation efficiency and zincblende is provided.This activator has characteristics such as selectivity height, rate of recovery height, environmental friendliness.Because the pH value that needs is lower, the scope of application is wider.
Technical scheme of the present invention is: the dressing activator of making marmatite and zincblende with the complex of copper and ammonia is.Activator of the present invention can use under the low alkalinity environmental condition, according to the concrete condition of ore, is to use under 7～11 the environment in the pH value, and is respond well.
The flotation activating of marmatite of the present invention and zincblende is the complex of copper and ammonia, it is characterized in that, the molecular formula of said complex is: [Cu (NH
3)
x]
2+, X=1 in the formula～8.
The preparation method of the flotation activating of marmatite of the present invention and zincblende, it is characterized in that, preparation section is as follows, said in the operation of following a～c " by the suitable metered proportions of chemical reaction " is meant the completeness in order to react, the additional proportion of central ion, ligand must satisfy the corresponding conditions of chemical reaction at least, under the principle of not wasting, excessive 0.5～10.0 quality % of the comparable central ion of ligand;
A, by the suitable metered proportions of chemical reaction ammonia is dissolved in a kind of solvent of selecting from the second alcohol and water, obtains first kind of solution (A), the concentration of solution is 0.5～25 quality %;
B, press the suitable metered proportions of chemical reaction with Cu (NO
3)
23H
2O or CuSO
45H
2O is dissolved in a kind of solvent of selecting from the second alcohol and water, obtains second kind of solution (B), and the concentration of solution is 0.5～50 quality %;
C, press the suitable metered proportions of chemical reaction with NaOH and Na
2CO
3Be dissolved in a kind of solvent of selecting from the second alcohol and water, obtain the third solution (C), the concentration of solution is 5～40 quality %;
D, stirring gently join A solution in the B solution down, under 150～200 rev/mins mixing speed, reacted under the room temperature 2～30 minutes, add C solution again, continue reaction 3～25 minutes under the room temperature, add a kind of solution of selecting from the second alcohol and water at last, reaction generates the crude product of solid precipitation;
E, with the reacted solution filtration under diminished pressure, use C
2H
5The sediment that the OH washing and filtering obtains blots with filter paper, then at air drying, promptly obtains the pure product of flotation activating.
This activator can adopt common copper to cooperate technology to be prepared with ammonia etc., in the ore dressing process in plumbous zinc ore that contains marmatite and zincblende and zinc-tin ore deposit, as activator marmatite in the ore and zincblende are activated, improve the floatability of marmatite and zincblende.The ratio of copper and ammonia etc. can be according to the situation of concrete ore dressing raw material in the complex, uses in lower pH value scope and certain consumption, need not operate under high alkali environment.
This activator all can use in the flotation of marmatite and zincblende polymetallic ore and gravity separation technology.
The present invention adopts the complex of copper and ammonia etc. as activator, because the effect of copper and ammonia etc., strengthened the hydrophobicity of surface of marmatite, make this activator only optionally activate marmatite, the selectivity that has overcome conventional activator is not high, the zinc concentrate grade is not high and cause disadvantageous technical bottleneck for follow-up metallurgical process recovery zinc and indium etc., has solved the problem of marmatite floatation process activation efficiency well.
Compare with prior art, the present invention has following advantage or good effect:
1, solved a difficult difficult problem of selecting the marmatite activation;
2, activator of the present invention need not activate under high pH value condition, mainly uses under neutrality, low alkalinity environment, and employed ore pulp environment pH value is 7～11.This just provides necessary assurance for reducing lime consumption, reasonable effectively recovery other sulfide minerals, cassiterite in producing and comprehensively reclaiming rare precious metal.
3, the production cost of activator is lower than the cost of copper sulphate, also be that enterprise is under low basicity condition, realize the efficient separation and the enrichment of zinc-sulphur, tin-sulphur, lead-zinc etc., and can create condition for carrying out effective desulfurization, reduction sulfuric acid consumption, raising zinc indium grade and the rate of recovery before the reselection operation.
The specific embodiment:
The present invention is further elaborated below in conjunction with embodiment.
Embodiment 1
Get an amount of ammonia and be dissolved in the ethanol, obtain first kind of solution (A), the concentration of solution is 0.5 quality %; Get proper C u (NO
3)
23H
2O is dissolved in the ethanol, obtains second kind of solution (B), and the concentration of solution is 0.5 quality %; The suitable metered proportions of pressing chemical reaction is with NaOH and Na
2CO
3Be dissolved in the ethanol, obtain the third solution (C), the concentration of solution is 5 quality %; Under stirring A solution is gently joined in the B solution, under 150 rev/mins mixing speed, reaction is 2 minutes under the room temperature, adds C solution again, continues reaction 3 minutes under the room temperature, adds entry at last, the crude product of reaction generation solid precipitation; With the reacted solution filtration under diminished pressure, use C
2H
5The sediment that the OH washing and filtering obtains blots with filter paper, then at air drying, promptly obtains the pure product of flotation activating, is the novel dressing activator of marmatite and zincblende.
Treat that ore dressing is the ore of Guangxi Da Chang, elements such as leaded in the ore, antimony, zinc, sulphur, iron, indium and silver, wherein mineral content contains 0.7～10.5% marmatite and 0.4% above zincblende, and the content of iron reaches about 11% in the marmatite.Adopt common ore-dressing technique, add this activator in floatation process, add common collecting agent, through conventional flotation, ore dressing environment pH value is 7.
Adopt this activator,, can reclaim marmatite and zincblende well through above-mentioned technical process.
Embodiment 2
Get an amount of ammonia and be dissolved in the water, obtain first kind of solution (A), the concentration of solution is 6.25 quality %; Get proper C uSO
45H
2O is dissolved in the water, and obtains second kind of solution (B), and the concentration of solution is 25 quality %; The suitable metered proportions of pressing chemical reaction is with NaOH and Na
2CO
3Be dissolved in the water, obtain the third solution (C), the concentration of solution is 20 quality %; Under stirring A solution is gently joined in the B solution, under 200 rev/mins mixing speed, reaction is 15 minutes under the room temperature, adds C solution again, continues reaction 10 minutes under the room temperature, adds ethanol at last, the crude product of reaction generation solid precipitation; With the reacted solution filtration under diminished pressure, use C
2H
5The sediment that the OH washing and filtering obtains blots with filter paper, then at air drying, promptly obtains the pure product of flotation activating, is the novel dressing activator of marmatite and zincblende.
Treat that ore dressing is the ore in all imperial zinc-tin mining area, wherein contain elements such as zinc, copper, tin, iron, sulphur, indium, gallium, germanium, gold and silver, wherein mineral content contains 0.7～11.8% marmatite and 0.5% above zincblende, and the content of iron reaches more than 20% in the marmatite.Adopt common ore-dressing technique, add this activator in floatation process, add common collecting agent then, through conventional flotation, ore dressing environment pH value is 9.
Adopt this activator, through above-mentioned technical process, sub-elect marmatite and the 50% above zincblende of grade more than 46%, the rate of recovery can reach more than 90% respectively.
Embodiment 3
Get an amount of ammonia and be dissolved in the water, obtain first kind of solution (A), the concentration of solution is 25 quality %; Get proper C u (NO
3)
2Be dissolved in the water, obtain second kind of solution (B), the concentration of solution is 50 quality %; The suitable metered proportions of pressing chemical reaction is with NaOH and Na
2CO
3Be dissolved in the water, obtain the third solution (C), the concentration of solution is 40 quality %; Under stirring A solution is gently joined in the B solution, under 150 rev/mins mixing speed, reaction is 30 minutes under the room temperature, adds C solution again, continues reaction 25 minutes under the room temperature, adds ethanol at last, the crude product of reaction generation solid precipitation; With the reacted solution filtration under diminished pressure, use C
2H
5The sediment that the OH washing and filtering obtains blots with filter paper, then at air drying, promptly obtains the pure product of flotation activating, is the novel dressing activator of marmatite and zincblende.
Treat that ore dressing is the ore of billows Cang Qiankuangqu, contain elements such as zinc, copper, iron, sulphur, indium, gold and silver in the ore, wherein mineral content contains 0.5～9.8% marmatite and 0.6% above zincblende.Adopt common ore-dressing technique, add this activator in floatation process, add common collecting agent then, with the conventional flotation of process, ore dressing environment pH value is 11.
Adopt this activator,, sub-elect marmatite and the 46% above zincblende of grade more than 40% through above-mentioned technical process.
Embodiment 4
Get an amount of ammonia and be dissolved in the ethanol, obtain first kind of solution (A), the concentration of solution is 5 quality %; Get proper C uSO
45H
2O is dissolved in the ethanol, obtains second kind of solution (B), and the concentration of solution is 40%; The suitable metered proportions of pressing chemical reaction is with NaOH and Na
2CO
3Be dissolved in the ethanol, obtain the third solution (C), the concentration of solution is 10 quality %; Under stirring A solution is gently joined in the B solution, under 180 rev/mins mixing speed, reaction is 20 minutes under the room temperature, adds C solution again, continues reaction 15 minutes under the room temperature, adds entry at last, the crude product of reaction generation solid precipitation; With the reacted solution filtration under diminished pressure, use C
2H
5The sediment that the OH washing and filtering obtains blots with filter paper, then at air drying, promptly obtains the pure product of flotation activating, is the novel dressing activator of marmatite and zincblende.
Treat that ore dressing is the ore in all imperial zinc-tin mining area, contain elements such as zinc, copper, tin, iron, sulphur, indium, gallium, germanium, gold and silver in the ore, wherein mineral content contains 0.7～11.8% marmatite and 0.5% above zincblende.Adopt common ore-dressing technique, add this activator in floatation process, add common collecting agent then, with the conventional flotation of process, ore dressing environment pH value is 8.
Adopt this activator, through above-mentioned technical process, sub-elect marmatite and 50% above zincblende more than 45%, the rate of recovery can reach more than 90% respectively.
Comparison by activator of the present invention and copper sulphate, this novel activator has very big advantage, it is not only better to the activation effect of marmatite, and need under high pH value condition, not activate, this is significant aborning, it reduces lime and sulfuric acid consumption significantly in producing, reclaiming other sulfide minerals, cassiterite efficiently and comprehensively reclaiming rare precious metal provides necessary assurance.
The cost of activator of the present invention is lower than copper sulphate, also be that enterprise is under low basicity condition, carry out the grade and the rate of recovery of metals such as effective desulfurization, reduction sulfuric acid consumption, raising zinc and tin before realization zinc-sulfur highly effective separation and enrichment, the reselection operation, market prospects are fine.
Claims (2)
1. the flotation activating of marmatite and zincblende, said activator is the complex of copper and ammonia, it is characterized in that, the molecular formula of said complex is: [Cu (NH
3)
x]
2+, X=1 in the formula～8.
2. the preparation method of the activator of claim 1, it is characterized in that, preparation section is as follows, said in following 2.1～2.3 operation " by the suitable metered proportions of chemical reaction " is meant the completeness in order to react, the additional proportion of central ion, ligand must satisfy the corresponding conditions of chemical reaction at least, under the principle of not wasting, excessive 0.5～10.0 quality % of the comparable central ion of ligand;
2.1, by the suitable metered proportions of chemical reaction ammonia is dissolved in a kind of solvent of selecting from the second alcohol and water, obtain first kind of solution (A), the concentration of solution is 0.5～25 quality %;
2.2, press the suitable metered proportions of chemical reaction with Cu (NO
3)
23H
2O or CuSO
45H
2O is dissolved in a kind of solvent of selecting from the second alcohol and water, obtains second kind of solution (B), and the concentration of solution is 0.5～50 quality %;
2.3, press the suitable metered proportions of chemical reaction with NaOH and Na
2CO
3Be dissolved in a kind of solvent of selecting from the second alcohol and water, obtain the third solution (C), the concentration of solution is 5～40 quality %;
2.4, stir down A solution gently joined in the B solution, mixing speed at 150～200 rev/mins, reacted under the room temperature 2～30 minutes, add C solution again, continue reaction 3～25 minutes under the room temperature, add a kind of solution of selecting from the second alcohol and water at last, reaction generates the crude product of solid precipitation;
2.5, with the reacted solution filtration under diminished pressure, use C
2H
5The sediment that the OH washing and filtering obtains blots with filter paper, then at air drying, promptly obtains the pure product of flotation activating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010124710.7A CN101816979B (en) | 2010-03-16 | 2010-03-16 | Flotation activating agent of marmatite and blende and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010124710.7A CN101816979B (en) | 2010-03-16 | 2010-03-16 | Flotation activating agent of marmatite and blende and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101816979A true CN101816979A (en) | 2010-09-01 |
| CN101816979B CN101816979B (en) | 2013-05-08 |
Family
ID=42652340
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201010124710.7A Expired - Fee Related CN101816979B (en) | 2010-03-16 | 2010-03-16 | Flotation activating agent of marmatite and blende and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101816979B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105772226A (en) * | 2016-03-16 | 2016-07-20 | 云南缘矿科技开发有限公司 | Flotation activating agent for fine-grain cassiterite and preparing method of flotation activating agent |
| CN108940604A (en) * | 2018-07-27 | 2018-12-07 | 攀枝花学院 | Marmatite flotation activating and its preparation method and application |
| CN111659529A (en) * | 2020-06-16 | 2020-09-15 | 昆明理工大学 | Method for separating and utilizing micro-fine particle embedded lead-zinc oxide ore by dressing and smelting |
| CN111659531A (en) * | 2020-06-16 | 2020-09-15 | 昆明理工大学 | Method for flotation separation of lead-zinc sulfide ore containing intergrowth |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3936294A (en) * | 1974-08-28 | 1976-02-03 | Childress Kenneth A | Reagent for zinc ore and method of utilizing same |
| US6484883B1 (en) * | 2000-10-18 | 2002-11-26 | Phibro-Tech Inc. | Use of cupric chloride in zinc flotation |
| CN1680042A (en) * | 2004-04-05 | 2005-10-12 | 黎东明 | Step-by-step flotation technology for tin-lead-zinc sulfide ore |
| CN1817468A (en) * | 2006-03-13 | 2006-08-16 | 昆明理工大学 | Coal-dressing activator of ferrous blende and blende |
-
2010
- 2010-03-16 CN CN201010124710.7A patent/CN101816979B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3936294A (en) * | 1974-08-28 | 1976-02-03 | Childress Kenneth A | Reagent for zinc ore and method of utilizing same |
| US6484883B1 (en) * | 2000-10-18 | 2002-11-26 | Phibro-Tech Inc. | Use of cupric chloride in zinc flotation |
| CN1680042A (en) * | 2004-04-05 | 2005-10-12 | 黎东明 | Step-by-step flotation technology for tin-lead-zinc sulfide ore |
| CN1817468A (en) * | 2006-03-13 | 2006-08-16 | 昆明理工大学 | Coal-dressing activator of ferrous blende and blende |
Non-Patent Citations (1)
| Title |
|---|
| 《湿法冶金》 20080331 薛丽华等 铜、金浸出过程中铜氨配合物的作用机理 10-14 1-2 第27卷, 第1期 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105772226A (en) * | 2016-03-16 | 2016-07-20 | 云南缘矿科技开发有限公司 | Flotation activating agent for fine-grain cassiterite and preparing method of flotation activating agent |
| CN108940604A (en) * | 2018-07-27 | 2018-12-07 | 攀枝花学院 | Marmatite flotation activating and its preparation method and application |
| CN111659529A (en) * | 2020-06-16 | 2020-09-15 | 昆明理工大学 | Method for separating and utilizing micro-fine particle embedded lead-zinc oxide ore by dressing and smelting |
| CN111659531A (en) * | 2020-06-16 | 2020-09-15 | 昆明理工大学 | Method for flotation separation of lead-zinc sulfide ore containing intergrowth |
| CN111659529B (en) * | 2020-06-16 | 2021-02-19 | 昆明理工大学 | Method for separating and utilizing micro-fine particle embedded lead-zinc oxide ore by dressing and smelting |
| CN111659531B (en) * | 2020-06-16 | 2021-03-23 | 昆明理工大学 | Method for flotation separation of lead-zinc sulfide ore containing intergrowth |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101816979B (en) | 2013-05-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110465411B (en) | Preferential flotation method for copper-lead sulfide minerals | |
| CN103350033B (en) | Mineral separation method for separating chalcopyrite from galena, sphalerite and pyrite | |
| CN101723391B (en) | Bleaching production method for washing iron-dyed kaolin | |
| CN103334007B (en) | The method of liquid recycling more than baking acid immersion extraction process output extraction copper | |
| CN101961673A (en) | Combined concentration and smelting method for mixed copper ore | |
| CN105772226A (en) | Flotation activating agent for fine-grain cassiterite and preparing method of flotation activating agent | |
| CN105170309A (en) | Lead and zinc separation method for polymetal gold-bearing ores | |
| CN111495608A (en) | Flotation process for efficiently recovering lead, zinc and sulfur in multi-metal sulfide ore | |
| CN101816979B (en) | Flotation activating agent of marmatite and blende and preparation method thereof | |
| CN1817468A (en) | Coal-dressing activator of ferrous blende and blende | |
| CN105268558B (en) | A kind of method of the valuable component comprehensive utilization of the low cuprate complex copper-sulphide ores association of high-sulfur | |
| CN104815762B (en) | A kind of preparation method of tennantite collecting agent | |
| CN101003029A (en) | Method for floating inhibited iron sulfide minerals | |
| CN113102115A (en) | Beneficiation process for zinc mineral in low-grade lead-zinc sulfide ore and inhibitor thereof | |
| CN103252290B (en) | Process for selecting marmatite from high ferric sulphide ore | |
| CN101224443A (en) | Comprehensive utilization method of iron sulfide minerals | |
| CN1035683C (en) | Method for extracting gold and silver by using thiourea | |
| CN105567992A (en) | Method for reducing neutralization cost of refractory gold ore hot-pressing oxidation acid | |
| CN114011581B (en) | Preparation method and application of inhibitor for copper-sulfur separation under weak acidic condition | |
| CN103157560B (en) | Flotation method of vulcanizing lead and zinc by weak acid full pulp | |
| CN114011582B (en) | Flotation method for improving beneficiation index of gold-bearing copper sulfide ore | |
| CN105642449B (en) | A kind of method that tungsten mine water cycle and collecting agent recycle | |
| CN104772229B (en) | Silver ore middle-low grade association copper recovery process | |
| CN102784721B (en) | Enrichment and recovery method for selenium and mercury in toxic smelting fume | |
| CN108160310B (en) | A kind of comprehensive reutilization method of the Coal-pyrite containing vanadium |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130508 Termination date: 20140316 |