CN101810549B

CN101810549B - Black hair dye and hair dyeing method

Info

Publication number: CN101810549B
Application number: CN2010101538051A
Authority: CN
Inventors: 范黎明
Original assignee: Individual
Current assignee: Individual
Priority date: 2010-04-16
Filing date: 2010-04-16
Publication date: 2012-07-18
Anticipated expiration: 2030-04-16
Also published as: CN101810549A

Abstract

The invention discloses a black hair dye and a hair dyeing method. The black hair dye is a two-agent hair dye taking pyrogallic acid and ferrous sulfate as main components. The hair dyeing method comprises the following steps: spreading a first agent on hairs; uniformly combing; standing for 15-20 minutes; scraping residual first agent on the surface of the hairs; directly spreading a second agent on the hairs without washing; uniformly combing; standing for 5-8 minutes; washing the hair dye of the hairs with clean water; and washing the hairs. The hair dye has the advantages of no aniline dye intermediate having anaphylactic reaction on human body, strong dyeing power, saturated coloring matter, durable dyeing effect, less possibility of fade, simple operation and no time consumption.

Description

A kind of black hair dye and hair colouring methods

Technical field

The invention belongs to the cosmetics industry field, specifically, the present invention relates to a kind of black hair dye and hair colouring methods.

Background technology

At present on the market the Color of circulation best, to keep the most permanent black hair dye be to adopt the aniline dyes intermediate in dyeing, through developing the color with the hydrogen peroxide coupling reaction.But the aniline dyes intermediate can cause part crowd skin allergy, untoward reaction such as skin Pruritus, redness even the water of suppurating occur.A large amount of both at home and abroad study carefully and report is pointed out: the aniline dyes intermediate has zest and causes anaphylaxis skin, and contacting skin can accumulate poisoning, and brings out various cancers.

P-phenylenediamine (PPD) is the dyestuff intermediate that is used for Permanent Hair Dyeing Agent; The highest working concentration is 6%; Relevant p-phenylenediamine (PPD) and the data of animal toxicity test widely that contain the Permanent Hair Dyeing Agent of p-phenylenediamine (PPD) show, its toxicity is with working concentration, test system and animal species and change.P-phenylenediamine (PPD) has stronger sensitization; But to skin even to the equal sensitization of whole machine body; Groups of people with after the puffiness of the eyes, skin rubefaction can appear, even unbearably the little rash of can occurring very itching, long-term contact can cause allergic disease; Mainly be respiratory system, gastrointestinal tract and liver damage, also anemia can take place.The hair dye that contains p-phenylenediamine (PPD) is not useable for dying eyebrow and eyelash, otherwise possibly cause blind or inpairment of vision.

M-diaminobenzene. and m-diaminobenzene. salt are aromatic amines, once in cosmetics, are used as hair coloring agent.M-diaminobenzene. belongs to moderate toxicity; Skin, eye there is zest; The tool sensitization; Mammalian cell, antibacterial, yeast are had mutagenic action, and in the test that mice and rat are carried out, m-diaminobenzene. (oral and contact skin) and the hair dye prescription goods (only contact skin) that contain m-diaminobenzene. all are non-carcinogenecitys.In " the cosmetics health standard " of China's version in 2007, classified as banned substance.

Below two prescriptions are that present Cosmetics Plant generally adopts is the oxidized form black cream rinse technology of main constituent with the aniline dyes intermediate.The method for using of two doses of formula black hair dyes of oxidized form is that (normally 1: 1) spreads upon on the hair behind first dose and second dose of mix homogeneously according to a certain percentage; It is clean with flushing with clean water to stop regular hour (about 30 minutes) back, and the flushing of reuse shampoo once gets final product.

Prescription 1

First dose:

16-18 alcohol 8～10%

Aliphatic alcohol polyether-20 2～3%

Hexadecyltrimethylammonium chloride 2～3%

White mineral oil 2～3%

Propylene glycol 1～2%

Sodium erythorbate 0.3～0.5%

Disodiumedetate 0.15%

P-phenylenediamine (PPD) 1.5～2.5%

Resorcinol 0.3～0.7%

M-aminophenol 0.2～0.5%

2,4-diaminobenzene oxyethanol hydrochlorate 0.1～0.3%

Ammonia 2～5%

Essence 0.3～0.5%

Pure water adds to 100%

Second dose:

16-18 alcohol 2～3%

Peregal 1～2%

Hexadecyltrimethylammonium chloride 0.5～1%

Hydroxyl phosphoric acid 0.2～0.5%

Sodium hydrogen phosphate 0.2～0.5%

35% hydrogen peroxide 14～17%

Pure water adds to 100%

Prescription 2

First dose:

16-18 alcohol 8～10%

Aliphatic alcohol polyether-20 2～3%

Hexadecyltrimethylammonium chloride 2～3%

White mineral oil 2～3%

Propylene glycol 1～2%

Sodium erythorbate 0.3～0.5%

Disodiumedetate 0.15%

2,5-diaminotoluene sulphate 2～3%

Resorcinol 0.3～0.7%

M-aminophenol 0.2～0.5%

The amino orthoresol 0.1～0.3% of 5-

Ammonia 2～5%

Essence 0.3～0.5%

Pure water adds to 100%

Second dose:

16-18 alcohol 2～3%

Peregal 1～2%

Hexadecyltrimethylammonium chloride 0.5～1%

Hydroxyl phosphoric acid 0.2～0.5%

Sodium hydrogen phosphate 0.2～0.5%

35% hydrogen peroxide 14～17%

Pure water adds to 100%

Also have in the prior art and adopt the acid black hair dye of single agent formula, it is electronegative under acid condition through acid stain, and hair is positively charged under acid condition, the principle that positive and negative charge is inhaled mutually and make hair coloring.The acid black hair dye method for using of single agent formula is fairly simple, spreads upon hair dye on the hair, stops regular hour (about 35 minutes) afterflush and totally gets final product.

It below is the prescription example of the single agent formula of semipermanent black hair dye.

Hydroxyethyl-cellulose 0.5～1.5%

Ethanol 8～10%

Benzyl alcohol 3～5%

Black 401 0.1～0.2%

Purple 401 0.1～0.2%

Orange 205 0.15～0.25%

Citric acid 0.1～0.2%

Pure water adds to 100%.

Though single agent formula acidic hair coloring preparation does not contain the aniline dyes intermediate; Safer to human body; But because the molecular weight of the acid stain of the acid black hair dye of single agent formula is big; Can not infiltrate into hair inside easily, can only rely on the help of inorganic solvents such as benzyl alcohol to be penetrated into the cortical layer of hair slightly, cause that colouring power is poor, color is not full; The negative charge of the positive charge of hair and acid stain is all more weak in addition, absorption affinity each other also a little less than, therefore be easy to fade.

Also having employing in the prior art is three doses of formula natural hair dyes of main constituent with DL-cysteine hydrochlorate, iron sulfate and gallic acid.Its prescription is:

First dose:

DL-cysteine hydrochlorate 5～10%

MEA 3～5%

16-18 alcohol 1～3%

White mineral oil 1～5%

Emulsifying agent 2～6%

Pure water adds to 100%

Second dose:

Iron sulfate 2～10%

Hydroxyethyl-cellulose 2～5%

Pure water adds to 100%

The 3rd dose:

Gallic acid 3～10%

MEA 2～6%

Thickening agent 2～5%

Pure water adds to 100%.

The method for using of these three doses of formula natural hair dyes is:

1. be coated in forehead earlier with first dose, the place that temples and poliosis are more, and be coated with several times repeatedly.Be coated onto a tip with first dose by root of hair then,, all soaked into by hair dye until all hairs by evenly spreading upon behind the forward direction on the hair.Put on plastic cap, and on plastic cap, cover dry towel,, keep temperature a little more than body temperature (about 38 degree) with the interrupted even heating of hair dryer (or cover heating towel).With a small amount of warm water washing hair, wipe after 20-30 minute to not dripping.

2. according to first dose method, second dose is evenly spread upon on the hair, and be coated with several times repeatedly.Need not to heat, stop 15-20 minute (observing the obvious flavescence of poliosis), use a small amount of warm water washing hair then, wipe to not dripping.

3. according to second dose method, the 3rd dose is evenly spread upon on the hair, and be coated with several times repeatedly.Put hair in order original hair style, stopped 10 minutes.With a large amount of warm water hair is dashed clearly then, with shampoo the hair wash clean is got final product at last to water.

Three doses of formula natural hair dyes have following defective:

1. the method for using complicacy of three doses of formula natural hair dyes is cumbersome, and whole operation process need long time.

2. because to contain dyeing the 3rd dose of main constituent be last use, fail to infiltrate into hair inside fully, cause the fast consequence that fades.

3. because a little less than the activity of iron sulfate, can not be fully and the gallic acid reaction, the color that dyes is not full, can be with the hair dyeing effect of the satisfaction that reaches consumer.

Summary of the invention

The objective of the invention is to overcome the defective of above-mentioned prior art, a kind of new black hair dye is provided.

For realizing above-mentioned purpose, the technical scheme below the present invention has taked:

A kind of black hair dye, this black hair dye is formed by first dose and second dose; In weight percentage, said first dose and second dose comprises following component respectively:

First dose:

16-18 alcohol 6～8%

Aliphatic alcohol polyether-20 3～4%

Hexadecyltrimethylammonium chloride 0.5～1%

Oleic alcohol 0.5～1%

Propylene glycol 0.5～1%

PEG-40 castor oil hydrogenated 0.5～1%

Disodiumedetate 0.05～0.1%

Pyrogallic acid 3～4% (hair dyeing main constituent)

Extender 2～3%

Antioxidant 1～2%

Pure water adds to 100%

Said extender is MEA or ammonia; Said antioxidant is TGA, sodium erythorbate or L-NAC hydrochlorate.

Second dose:

16-18 alcohol 2～4%

Aliphatic alcohol polyether-20 1～2%

Hexadecyltrimethylammonium chloride 0.5～1%

Oleic alcohol 0.5～1%

Propylene glycol 0.5～1%

PEG-40 castor oil hydrogenated 0.5～1%

Ferrous sulfate heptahydrate 3～5% (developer)

Pure water adds to 100%.

Preferably, said extender is a MEA; Said antioxidant is a TGA.

Preferably, said first dose and second dose comprises respectively that also weight percentage is the essence of 0.1-0.3%.

Preferably, in weight percentage, said first dose and second dose of difference are composed of the following components:

First dose:

16-18 alcohol 6.5%

Aliphatic alcohol polyether-20 3.5%

Hexadecyltrimethylammonium chloride 0.8%

Oleic alcohol 0.8%

Propylene glycol 0.8%

PEG-40 castor oil hydrogenated 0.8%

Disodiumedetate 0.07%

Pyrogallic acid 3.4%

MEA 2.8%

TGA 1.4%

Essence 0.2%

Pure water adds to 100%

Second dose:

16-18 alcohol 3%

Aliphatic alcohol polyether-20 1.5%

Hexadecyltrimethylammonium chloride 0.8%

Oleic alcohol 0.8%

Propylene glycol 0.8%

PEG-40 castor oil hydrogenated 0.8%

Ferrous sulfate heptahydrate 4.2%

Essence 0.2%

Pure water adds to 100%.

In first dose, pyrogallic acid is as the dyeing main constituent; In second dose, ferrous sulfate heptahydrate makes hair-dyeing as developer with the pyrogallic acid reaction.

The present invention also provides a kind of hair colouring methods, has taked following technical scheme:

A kind of hair colouring methods uses above-mentioned black hair dye, may further comprise the steps:

1. first dose is coated on the hair, combing is even, stops 15～20 minutes;

2. scrape off unnecessary first dose of hair surface, need not wash directly and be coated in second dose on the hair, combing is even, stops 5～8 minutes;

3. wash the hair dye on the hair off with clear water, hair is cleaned got final product.

The present invention contacts with ferrous ion and shows blue-black principle through pyrogallic acid (pyrogallol), through optimized formula combination, can hair be dyed ideally blackly, and compared with prior art, the present invention has following beneficial effect:

1. said hair dye does not contain fully can cause human body skin aniline dyes intermediate hypersensitive, the aniline dyes intermediate is anaphylactoid can beautifies hair securely with the crowd who pursues healthy living;

2. said hair dye, can be penetrated into the inside of hair fast, fully, thereby make Color lasting in conjunction with pyrogallic acid through extender (like the MEA) hair that expands, and is difficult for fading;

3. to a little less than the permeability of ferrous sulfate, the shortcoming that can not contact fully with pyrogallic acid, adopt the method for " scrape and be coated with two " make ferrous sulfate can with pyrogallic acid haptoreaction fully, order full dye the color of coming;

4. use the hair colouring methods of said hair dye simple and convenient, the used time of operating process is few.

The specific embodiment

Below through embodiment the present invention is described.

Embodiment 1

A kind of black hair dye, this black hair dye is formed by first dose and second dose; In weight percentage, said first dose and second dose of difference are composed of the following components:

First dose:

16-18 alcohol 6%

Aliphatic alcohol polyether-20 3%

Hexadecyltrimethylammonium chloride 0.5%

Oleic alcohol 0.5%

Propylene glycol 0.5%

PEG-40 castor oil hydrogenated 0.5%

Disodiumedetate 0.05%

Pyrogallic acid 3% (dyeing main constituent)

MEA 2% (hair extender)

TGA 1% (antioxidant)

Essence 0.1%

Pure water adds to 100%

Second dose:

16-18 alcohol 2%

Aliphatic alcohol polyether-20 1%

Hexadecyltrimethylammonium chloride 0.5%

Oleic alcohol 0.5%

Propylene glycol 0.5%

PEG-40 castor oil hydrogenated 0.5%

Ferrous sulfate heptahydrate 3% (developer)

Essence 0.1%

Pure water adds to 100%.

Use the hair colouring methods of the black hair dye of embodiment 1: first dose is coated on the hair, and combing is even, stops 15～20 minutes; Scrape off first dose unnecessary on the hair surface with comb, need not wash directly and be coated in second dose on the hair, combing is even, stops after 5～8 minutes, washes the hair dye on the hair off with clear water, with shampoo the hair wash clean is dried then to get final product.

Black hair dye with embodiment 1 can dye the corvinus close with black, and can keep the black effect more than two months.

Embodiment 2

First dose:

16-18 alcohol 6%

Aliphatic alcohol polyether-20 3%

Hexadecyltrimethylammonium chloride 0.5%

Oleic alcohol 0.5%

Propylene glycol 0.5%

PEG-40 castor oil hydrogenated 0.5%

Disodiumedetate 0.05%

Pyrogallic acid 3% (dyeing main constituent)

Ammonia 2% (hair extender)

Sodium erythorbate 1.2% (antioxidant)

Pure water adds to 100%

Second dose:

16-18 alcohol 2%

Aliphatic alcohol polyether-20 1%

Hexadecyltrimethylammonium chloride 0.5%

Oleic alcohol 0.5%

Propylene glycol 0.5%

PEG-40 castor oil hydrogenated 0.5%

Ferrous sulfate heptahydrate 3% (developer)

Pure water adds to 100%.

Use the hair colouring methods of the black hair dye of embodiment 2: first dose is coated on the hair, and combing is even, stops 15～20 minutes; Scrape off first dose unnecessary on the hair surface with comb, need not wash directly and be coated in second dose on the hair, combing is even, stops after 5～8 minutes, washes the hair dye on the hair off with clear water, with shampoo the hair wash clean is dried then to get final product.

Black hair dye with embodiment 2 can dye the corvinus close with black, and can keep the black effect more than two months.

Embodiment 3

First dose:

16-18 alcohol 8%

Aliphatic alcohol polyether-20 4%

Hexadecyltrimethylammonium chloride 1%

Oleic alcohol 1%

Propylene glycol 1%

PEG-40 castor oil hydrogenated 1%

Disodiumedetate 0.1%

Pyrogallic acid 4% (dyeing main constituent)

MEA 3% (hair extender)

TGA 2% (antioxidant)

Essence 0.3%

Pure water adds to 100%

Second dose:

16-18 alcohol 4%

Aliphatic alcohol polyether-20 2%

Hexadecyltrimethylammonium chloride 1%

Oleic alcohol 1%

Propylene glycol 1%

PEG-40 castor oil hydrogenated 1%

Ferrous sulfate heptahydrate 5% (developer)

Essence 0.3%

Pure water adds to 100%.

Use the hair colouring methods of the black hair dye of embodiment 3: first dose is coated on the hair, and combing is even, stops 15～20 minutes; Scrape off first dose unnecessary on the hair surface with comb, need not wash directly and be coated in second dose on the hair, combing is even, stops after 5～8 minutes, washes the hair dye on the hair off with clear water, with shampoo the hair wash clean is dried then to get final product.

Black hair dye with embodiment 3 can dye the corvinus close with black, and can keep the black effect more than two months.

Embodiment 4

First dose:

16-18 alcohol 6.5%

Aliphatic alcohol polyether-20 3.5%

Hexadecyltrimethylammonium chloride 0.8%

Oleic alcohol 0.8%

Propylene glycol 0.8%

PEG-40 castor oil hydrogenated 0.8%

Disodiumedetate 0.07%

Pyrogallic acid 3.4% (dyeing main constituent)

MEA 2.8% (hair extender)

TGA 1.4% (antioxidant)

Essence 0.2%

Pure water adds to 100%

Second dose:

16-18 alcohol 3%

Aliphatic alcohol polyether-20 1.5%

Hexadecyltrimethylammonium chloride 0.8%

Oleic alcohol 0.8%

Propylene glycol 0.8%

PEG-40 castor oil hydrogenated 0.8%

Ferrous sulfate heptahydrate 4.2% (developer)

Essence 0.2%

Pure water adds to 100%.

Use the hair colouring methods of the black hair dye of embodiment 4: first dose is coated on the hair, and combing is even, stops 15～20 minutes; Scrape off first dose unnecessary on the hair surface with comb, need not wash directly and be coated in second dose on the hair, combing is even, stops after 5～8 minutes, washes the hair dye on the hair off with clear water, with shampoo the hair wash clean is dried then to get final product.

Black hair dye with embodiment 4 can dye the corvinus close with black, and can keep the black effect more than two months, and effect is better than the black hair dye of embodiment 1-3.

Claims

1. black hair dye, this black hair dye is formed by first dose and second dose, it is characterized in that, and in weight percentage, said first dose and second dose of difference are composed of the following components:

First dose:

Said extender is MEA or ammonia; Said antioxidant is TGA, sodium erythorbate or L-NAC hydrochlorate;

Second dose:

2. black hair dye as claimed in claim 1 is characterized in that, said extender is a MEA; Said antioxidant is a TGA.

3. according to claim 1 or claim 2 black hair dye is characterized in that, in weight percentage, said first dose and second dose of difference are composed of the following components:

First dose:

Second dose:

4. a hair colouring methods is characterized in that, uses like each described black hair dye of claim 1-3, may further comprise the steps:

1. first dose is coated on the hair, combing is even, stops 15～20 minutes;