CN101806020A - Anti-mould and anti-moth formula of special paper for files and use method - Google Patents
Anti-mould and anti-moth formula of special paper for files and use method Download PDFInfo
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- CN101806020A CN101806020A CN201010127851A CN201010127851A CN101806020A CN 101806020 A CN101806020 A CN 101806020A CN 201010127851 A CN201010127851 A CN 201010127851A CN 201010127851 A CN201010127851 A CN 201010127851A CN 101806020 A CN101806020 A CN 101806020A
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Abstract
The invention relates to and discloses an anti-mould and anti-moth formula of special paper for files and a use method. The anti-mould and anti-moth formula of special paper for files is characterized in that the used medicine is a chemical product with high effect, broad spectrum and low toxicity. The use method comprises the following steps of respectively dissolving 0.5% to 15% of isothiazolinone, 0.5% to 15% of chamomile, 0.002% to 10% of TLC (Bronopol), 0.04% to 10% of LY-A310 and 0.1% to 10% of 75 industrial anti-mould agent in water and uniformly stirring the mixed solution; filling a paper pulp flume with the mixed solution so that finished products manufactured through a paper making machine meet requirements of long-tern storage as well as mould and moth prevention of paper for files.
Description
Technical field
The present invention relates to disclose a kind of archives special mildewproof mothproof prescription and using method.
Background technology
Abroad to the problem of the long preservation of archives paper, pay much attention to, a lot of countries have all dropped into great amount of manpower and material resources and finance, adopt various ways, make paper deacidification, the mothproof method of sterilization, make the paper can long preservation, as Sweden's paper protection project; The project of Holland's air pollution effect; The Europe pollutant is write low ageing research plan or the like to the project that influences of paper quick aging and the U.S. about printing and has been dropped into a large amount of funds.But these researchs are also just from the ambient influnence and the protection of paper, fail fundamentally to solve the long preservation problem of paper.This paper price is more expensive, adds freight charges, can't be in the domestic use of China.
Domestic research to the archives paper was that units such as Jiamusi, Heilungkiang papermaking company exploitation " anacidity archival paper ", archives, Shandong Province in 2000 have developed " the neutral series paper of durable office archives ", Changde gold lotus (special type) Paper Co., Ltd in 2002 has developed " anacidity waterproof archives are low " since 1998.From above several examples special paper of archives of domestic production as can be known, rest on the neutralized paper.These archives paper can not moth-proof and mould-proof, certainly can not long preservation.As everyone knows, paper is wanted long preservation, the condition that must possess is that paper is wanted neutrality, it has been possessed to make non-yellowing, the embrittlement and can not wearing out not of paper, but be not equal to and possess the energy long preservation, because in the environment of long preservation except constant temperature, constant humidity, prevent to also have a large amount of moulds the strong illumination, as aspergillus niger, Paecilomyces varioti, high mucor mucedo, bread mold, cured leaf wood is mould and Chaetomium globosum or the like.In addition also have a large amount of moths, as piebald leather bag, casting skin capsule, Silvefish and book death watch beetle or the like, so be not difficult to find out and will solve moth and mould, the insecticidal bactericide that must will add efficient, wide spectrum and low toxicity in paper can reach above-mentioned requirement.
Summary of the invention
We searched the home and abroad all efficiently, the medicine of wide spectrum and Pesticidal and sterilizing low toxicity, find out an assembly side, its content can not be too many, can cause the toxicity on the residual paper too big too much, both caused the wasting of resources, too expensive influence to promote.Constitute again the virulent danger of paper.Can not reach the effect of desinsection, sterilization very little again.So this assembly side must possess and reach 100% and kill moth and 100% and kill mould, through our up to a hundred tests, finds one group of prescription that can solve above-mentioned requirements finally.Contain following several medicine in this assembly side: (one) thiazolinone 0.5～15%; (2) chrysanthemum fat 0.5～15%; (3) TL (cloth sieve bohr) 0.002～10%; (4) LY-A310 high-efficiency low-toxicity mould inhibitor; (5) No. 75 industrial fungicides 0.1～10%.(1) and (two) in above-mentioned five kinds of medicines dissolved in simultaneously becomes first kind mixed liquor in the water.Again the medicine of (three) and (four) is dissolved in the water also the time, become second kind mixed liquor.Remaining medicine with (five) also dissolves in the water, becomes third kind of liquid.At last above-mentioned first, second and the third three kinds of liquid are mixed into a kind of solution fully.We are referred to as the ZS68 anti-mould and moth-proof agent.Put into the ZS68 anti-mould and moth-proof agent in paper-making process, resultant paper is a special paper for files.Certainly also need to store constraint such as constant temperature, the constant humidity of paper and prevent the strong light irradiation that is listed as or the like good achive keeping condition, could realize above-mentioned long preservation special paper for files.We have carried out mothproof and two kinds of tests of mildew-resistant for this reason.
(1) test sample
1, bacterial classification: aspergillus niger, aspergillus versicolor, Paecilomyces varioti, bread mold, high mucor mucedo, cured leaf wood are mould, Chaetomium globosum, cladosporium herbarum.
Above-mentioned bacterial classification is purchased from Shanghai City industrial microorganism thing research institute bacterial classification chamber.
2, anti-mould and moth-proof agent code name:
BCM, composite A, composite B, composite C, ZS68 anti-mould and moth-proof agent.
(2) experimental technique
1, with filter paper inhibition zone screening medicament
(1) five kinds of medicaments is diluted to 1% concentration, is contained in the vial respectively.With every kind of medicament is unit, and being cut into diameter is each three of 2cm disk shape filter paper, is infiltrated on various medicaments taking-ups respectively and dries, and perform medicament title and numbering.
(2) to institute's use culture dish, apparatus, instrument culture medium and 100CC sterilized water, all high pressure sterile sterilizations.
(3) produce the mixing spore suspension on the sterile working platform: with each strains tested of oese picking, immigration is equipped with in the triangular flask of sterilized water, and several branch kinds of vibrating are uniformly dispersed the interior thalline of suspension, spore.
(4) dispensing of bacterium liquid and dull and stereotyped preparation: on the sterile working platform, carry out.Earlier 0.2ml bacterium liquid is moved into each culture dish, the culture medium that will be cooled to 45 ℃ is then poured into respectively in the culture dish that fills bacterium liquid with every ware 10ml, and horizontal positioned is to solidifying.With 3 samples of every kind of concentration medicament is one group.And perform medicament title, concentration, numbering in advance, be provided with corresponding blank sample.
(5) with tweezers (aseptic) preprepared is soaked into different medicaments, variable concentrations sample scraps of paper correspondence be positioned over each culture dish central authorities, cover lid is inverted, and puts into bio-incubator, cultivates and observes its fungistatic effect.The anti-mould and anti-moth archival paper is cut into the central authorities that the disk (5 parts on sample) of 3 * 3cm is put into the culture dish that fills culture medium respectively, on disk, spray and mix spore suspension, build lid, be upside down in the temperature and humidity regulator, the control temperature is at 28 ℃, relative humidity 98% is cultivated and was observed 7-28 days, mildew situation on the archives scraps of paper.
Its fungistatic effect sees anti-mould and anti-moth archival paper anti-mold effect summary sheet () for details
(3) experimental result and analysis
1, five kinds of medicament fungistatic effect summary sheets ()
The anti-mould and moth-proof agent fungistatic effect summary sheet (two) of variable concentrations
2, with filter paper inhibition zone screening drug concentration
On above-mentioned test method basis, five kinds of medicament fungistatic effects are compared, and drawing the ZS68 anti-mould and moth-proof agent is desirable medicament, then it are diluted to 1%, 2%, 3%, 4% solution, further make mould proof test, and test method and process are the same.
This fungistatic effect sees the anti-program agent variable concentrations fungistatic effect summary sheet of ZS68 mildew-resistant for details
(2) insect protected of mildew and insect proof medicament test
For two kinds of concentration of screening ZS68 mildew and insect proof agent prevention and the toxic action of insect are launched test, found out comparatively desirable drug concentration.
One, instrument and material
1, big mouthful vial;
2, measuring cup;
3, analytical balance;
4, for examination worm kind: the piebald leather bag
5, for test agent: woolen cloth;
Two, test procedure:
1, sample preparation: woolen cloth is cut into square 16 of 4 * 4cm, wherein gets 8, be placed on respectively in the Vermins-proof mildew-proof agent solution of 2% and 4% concentration and soaked 2 hours, take out dry standby.Specimen coding is A
1With B
1
2, clean and to dry big mouthful of vial, and put on insect protected test A
1, B
1With blank W
1And blank W
2Printed words.
3, with A
1, B
1The Vermins-proof mildew-proof woolen cloth is put into respectively and is cleaned the weighing of oven dry measuring cup (as A before the insect protected test
1, B
1Weight), be placed on then in the big mouthful vial.Drop into simultaneously tested worm kind casting skin capsule each 8 in measuring cup.For preventing tested worm hungry to death, in big mouthful glass, discharge a little woollen bits, bottleneck covers with 3 layers of gauze and tightens.
4, with 4 blank W
1Woolen cloth is put into clean oven dry measuring cup and is weighed (as the blank W before the test
1Weight), be placed on then in the jar, drop into 8 of tested worm kind attagenus piceuses simultaneously in measuring cup, bottleneck covers with 3 layers of gauze and tightens.
5, increase (subtracting) heavily rate (V) naturally for calculating woolen cloth, blank W is set
2, in big mouthful vial, only emptying contrasts W in vain
2Woollen four, do not put test worm kind.Equally woolen cloth is put into measuring cup in advance and weigh, claim to such an extent that weight is the preceding blank W of test
2Weight.
6, the insect protected test is carried out at normal temperatures.After observing for two weeks, will test the worm kind with writing brush and transfer to weighing disk outward in jar.Take out weighing disk and weigh once more, divide to have another name called to such an extent that weight is test back A
1, B
1Woollen and the blank W of Vermins-proof mildew-proof
1Woollen weight.Also take by weighing simultaneously blank W
2Woollen weight.
Three, calculate
1, calculates blank W
2Woollen (subtracting) the heavily rate (V) that increases naturally.
Blank W before the V=test
2Woollen weight/test back blank W
2Woollen heavy
2, calculate tested 2% and 4% mothproofing agent woolen cloth and blank W
1Woollen weightless value (R).
Woollen weight * V one test back is woollen heavy before the test of R=2% mothproofing agent;
Woollen weight * V one test back is woollen heavy before the test of R=4% mothproofing agent;
Blank sample R=blank W
1Woollen weight * V one test back is woollen heavy before the test
3, calculate the weightless protective rate (P) of 2% and 4% mothproofing agent woolen cloth;
P (%)=(the weightlessness value R/ blank test R of 1-4% mothproofing agent woolen cloth) * 100
P (%)=(the weightlessness value R/ blank test R of 1-2% mothproofing agent woolen cloth) * 100
Four, insect protected test results and analysis:
1, ZS68 anti-mould and moth-proof agent insect protected result of the test summary sheet (three)
Table four ZS68 anti-mould and anti-moth result of the test summary sheet (three) interpretation of result:
The insect protected testing record sheet (four) of mildew and insect proof medicament
(1) after insecticidal test observed for two weeks.2%, 4%, the ZS68 anti-mould and moth-proof agent all has same toxic action to attagenus piceus, each 8 of test worm kinds are all dead.8 attagenus piceuses then do not have death in the blank test.
(2) according to formula, calculate 2% respectively, the weightless protective rate of 4%ZS68 anti-mould and moth-proof agent is 92%, 94% all greater than 90%, vermins-proof effect is evaluated as qualified.
ZS68 anti-mould and moth-proof agent fungistatic effect summary sheet (one) interpretation of result:
(1) have two kinds of medicaments of composite A, composite B not see inhibition zone in visible five kinds of compound drugs from table (), anti-mold effect is not good enough.The medicament that inhibition zone occurs has three kinds of BCM, composite C, ZS68 anti-mould and moth-proof agents, but inhibition zone is not of uniform size, and that maximum is BCM, and the inhibition zone average is 4.37cm, secondly is the agent of ZS68 antimould and antiborer, and inhibition zone smuggling average is 3.7.
(2) this test considers that ZS68 anti-mould and moth-proof agent function is multinomial, and existing mildew-resistant has mothproof function again, and the BCM function singleness only has antimildew function.Two kinds of medicaments are compared, and select the ZS68 anti-mould and moth-proof agent to be advisable.
ZS68 anti-mould and moth-proof agent variable concentrations fungistatic effect summary sheet (two)
(1) illustrate that from table (two) ZS68 anti-mould and anti-moth agent concentration is high more, anti-mold effect is good more, and no matter from the inhibition zone size, still effective antibacterial time all is directly proportional with the solution concentration size, meets the antibacterial rule of medicament.
(2) the mildew-resistant effective ingredient is a thiazolinone in the ZS68 anti-mould and moth-proof agent, LY-A310, No. 75 industrial fungicides and TLC cloth sieve bohr, and mothproof effective ingredient is the chrysanthemum ester, considers that the chrysanthemum ester is a kind of broad spectrum insecticide, toxic action is bigger.Simultaneously, also eating into evidence 2% concentration ZS68 anti-mould and moth-proof agent can all kill test worm kind equally.
Specific embodiments
The first step must be neutral to wood pulp liquid at first, can not alkalescence, can not be acid, this be can long preservation prerequisite.Second step, reserve its concentration to depositing wooden oar groove planted agent putting into wood pulp liquid, promptly improve concentration because need put into the ZS68 anti-mould and moth-proof agent, it is a kind of mixing material, it put into the concentration that can water down wood pulp, put into the ZS68 anti-mould and moth-proof agent of 50,000 CC if desired, will detain the water of 50,000 CC so in the wood pulp liquid, to guarantee the concentration of wood pulp liquid.Whether the 3rd step also will be tested it to the water that uses is neutral water, to guarantee the neutrality of wood pulp liquid.The 4th step is with (1) thiazolinone 0.5～15%.(2) chrysanthemum fat 0.5～15%.(3) TLC cloth sieve bohr 0.002～10%.(4) LY-A310 (efficiently low mould mould inhibitor) 0.01～8%.(5) No. 75 industrial fungicide 0.1～10% 5 kind of medicine dissolves in (1) and (2), (3) and (4) medicine respectively and is stored in the Plastic Drum in the water respectively, also dissolve in (5) medicine in the water in addition, because be that total agent must stir before use, dissolve in the water again.Make from above-mentioned 3 kinds and extract 2% (wooden oar liquid gross weight) the soup, if wooden oar liquid has one ton in the interior wooden oar liquid of wood pulp groove, the total heavy-fluid of so above-mentioned five kinds of medicines is extracted 20 kilograms.At last the liquid of above-mentioned three kinds of medicines is injected in the wood pulp liquid bath, stir, check whether the concentration of wooden oar liquid normal, when normally just beginning coated paper, coating is finished, the paper of receiving be can long preservation special paper for files.
Claims (1)
1. the prescription of a special paper for files moth-proof and mould-proof and using method is characterized in that forming Z568 anti-mould and moth-proof agent optimum efficiency by thiazolinone 0～15%, chrysanthemum fat 0.5～15%, TLC cloth sieve bohr 0.002～10%, LY-A310 (paper sterilization antiseptic) and No. 75 industrial fungicides is 2% ZS68 mothproof mildew preventive.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010127851A CN101806020A (en) | 2010-03-19 | 2010-03-19 | Anti-mould and anti-moth formula of special paper for files and use method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010127851A CN101806020A (en) | 2010-03-19 | 2010-03-19 | Anti-mould and anti-moth formula of special paper for files and use method |
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| Publication Number | Publication Date |
|---|---|
| CN101806020A true CN101806020A (en) | 2010-08-18 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102608113A (en) * | 2012-03-30 | 2012-07-25 | 上海三爱思试剂有限公司 | Mildew-proof pH test paper and preparation method thereof |
| CN105344510A (en) * | 2015-12-16 | 2016-02-24 | 青岛大学 | Paper document quality guarantee processing device |
| CN105568756A (en) * | 2015-12-16 | 2016-05-11 | 青岛大学 | Preparation method of paper document quality keeping liquid |
| CN107513881A (en) * | 2017-08-30 | 2017-12-26 | 山东秦世集团有限公司 | A kind of antibacterial archival paper and preparation method thereof |
-
2010
- 2010-03-19 CN CN201010127851A patent/CN101806020A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102608113A (en) * | 2012-03-30 | 2012-07-25 | 上海三爱思试剂有限公司 | Mildew-proof pH test paper and preparation method thereof |
| CN102608113B (en) * | 2012-03-30 | 2014-08-13 | 上海三爱思试剂有限公司 | Mildew-proof pH test paper and preparation method thereof |
| CN105344510A (en) * | 2015-12-16 | 2016-02-24 | 青岛大学 | Paper document quality guarantee processing device |
| CN105568756A (en) * | 2015-12-16 | 2016-05-11 | 青岛大学 | Preparation method of paper document quality keeping liquid |
| CN107513881A (en) * | 2017-08-30 | 2017-12-26 | 山东秦世集团有限公司 | A kind of antibacterial archival paper and preparation method thereof |
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Application publication date: 20100818 |