CN101792590A - Polyphenyl ether resin material used for processing charger case - Google Patents
Polyphenyl ether resin material used for processing charger case Download PDFInfo
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Abstract
The invention discloses a polyphenyl ether resin material used for processing a charger case, which consists of polyphenyl ether resin, polystyrene resin, an elastic body, fire retardants, polyolefin, silicone masterbatch, main antioxidants and auxiliary antioxidants. Through adding proper auxiliary agents into a polyphenyl ether resin composition, the invention improves the surface lubricating effect of manufactured elements, reduces the pressure required during welding, and solves the problems of impression, scratches and the like occurring during the ultrasonic welding of products. The products are mainly applied to the fields requiring the ultrasonic welding, such as charger cases, wiring cases and the like.
Description
Technical field:
The present invention relates to a kind of polyphenyl ether resin material that is used for processing charger case.
Background technology:
Polyphenyl ether resin composition has superior mechanical property, electric durability energy, resistance toheat, good dimensional stability, is widely used in industries such as household electrical appliance, auto parts machinery.These industry requirement materials have high strength, high tenacity, high flame retardant, high heat-resisting etc., as charger case, terminal box, dashboard and automotive air intake assembly etc.But many these identical assemblies are made into a plurality of products, and these products need be assembled into goods to meet the demands according to certain method, and using maximum at present is to adopt the supersonic welding connection technology, makes goods reach application target.
Ultrasonic welding be a kind of under frequency electromagnetic waves vibration, make the electromagnetism wave energy change into heat energy and make plastic part contact surface adhere welding process together.Ultrasonic welding is mainly relevant with welding frequency, welding pressure, weld interval etc.The goods contact surface is under the high-frequency vibration fusion, and needing provides certain pressure that it is combined together at product surface, and after ultrasonic wave stopped, pressure still need continue several seconds, made it solidify typing.For satisfying welding strength, the enough pressure and residence time need be provided during welding, this requires the goods contact position that enough intensity and low frictional coefficient need be arranged, and does not have impression, scratches phenomenon to guarantee the product surface.For satisfying the apparent requirement of product, welding pressure is low more, and it is few more with the probability that scratches phenomenon that impression appears in product surface.The polyphenyl ether resin composition material impression occurs and scratches phenomenon through regular meeting when carrying out the charger case welding at present.
Summary of the invention:
The object of the present invention is to provide a kind of polyphenyl ether resin material that is used for processing charger case that can effectively solve the impression that goods occur and scratch problem when carrying out ultrasonic welding.
Technical solution of the present invention is:
A kind of polyphenyl ether resin material that is used for processing charger case is characterized in that: the component by following weight is formed:
50～100 parts of polyphenylene oxide resins
20～40 parts of polystyrene resins
2～10 parts on elastomerics
4～15 parts of fire retardants
1～10 part of polyolefine
0.5～5 part of silicone master batch
0.2～0.5 part of primary antioxidant
0.2～0.5 part of auxiliary antioxidant.
Polyphenylene oxide resin is 2, the polymkeric substance of 6-xylenol and 2, and 6-xylenol and 2,3, the multipolymer of 6-pseudocuminol, its limiting viscosity is 0.2-0.6dl/g.
Described polystyrene resin is a polystyrene.
Elastomerics is styrene-butadiene rubber(SBR), HSBR, ethylene-propylene rubber(EPR) or polyolefine.
Fire retardant is triphenylphosphate (TPP), tetraphenyl (bisphenol-A) bisphosphate (BDP), tetraphenyl resorcinol diphosphate (RDP) or fragrant alkene condensed phosphoric acid esters (PX-200).
Polyolefine is high density polyethylene(HDPE), new LDPE (film grade), linear low density polyethylene, ethylene-propylene copolymer, ethylene-butene copolymer or polypropylene.
Described silicone master batch is to be dimethyl silicone oil, methyl phenyl silicone oil, ethyl hydroxy silicon oil, methyl phenyl vinyl silicone rubber or the silicone resin of carrier with the new LDPE (film grade).Content of siloxane is at 40-60%.
Described primary antioxidant is 3,5-di-tert-butyl-hydroxy phenyl propionic acid stearyl alcohol ester, β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid stearyl alcohol ester or 2,2 methylene-biss (4-methyl-6-tert butyl phenol); Auxiliary antioxidant is tricresyl phosphite (nonyl phenyl) or tricresyl phosphite (2, the 4-di-tert-butyl-phenyl) ester.
The present invention improved the surface lubrication of product by add proper auxiliary agent in polyphenyl ether resin composition, required pressure when having reduced welding, problem such as solved the impression that goods occur and scratch when carrying out ultrasonic welding.This product is mainly used in the field that charger case, terminal box etc. need be carried out ultrasonic welding.
The invention will be further described below in conjunction with embodiment:
Embodiment:
Test and estimate the performance of composition in embodiment and the Comparative Examples by the following method.
(1) tensile strength
Described tensile strength is pressed ASTM D-638 test.
(2) flexural strength
Described flexural strength is pressed ASTM D-790 test.
(3) Izod notch shock
Described Izod notch shock is pressed ASTM D-256 test.
(4) flame retardant resistance
Described flame retardant resistance is pressed the UL-94 standard testing.
(5) ultrasonic welding
Make shell by injection moulding, under the constant situation of other processing condition, by adjusting the requirement that the welding pressure size satisfies the shell welding strength, promptly the goods (having installed certain electronic component in the goods) that welding is good are undertaken freely falling by the direction of six faces in the eminence of 1m, fall six times after excellent (no scratch) even if welding strength pass through.
The ultrasonic welding parameter: welding frequency 20KHZ, weld interval 8s, ultrasonic welding pressure (1-2.5MPa).
Each raw material weight umber sees Table 1.
Comparative Examples 1:
75 parts polyphenylene oxide resin (PPE), 8 parts of hydrogenated styrene-butadiene-styrenes (SEBS) and 0.2 part of primary antioxidant and 0.2 part of auxiliary antioxidant add from the first weight-loss type feeder mouth after height mixes, 25 parts of polystyrene resins (PS) add from the second weight-loss type feeder mouth, 10 parts of liquid flame retardants add from the liquid charging opening through liquor pump, twin screw extruder plasticizing, fusion then, extrude, tie rod, cooling, pelletizing.Pellet prepares test bars and goods by injection moulding machine then at 110 ℃ of dry 2h of air dry oven.
Embodiment 1:
75 parts polyphenylene oxide resin (PPE), 8 parts of hydrogenated styrene-butadiene-styrenes (SEBS) and 0.2 part of primary antioxidant and 0.2 part of auxiliary antioxidant add from the first weight-loss type feeder mouth after height mixes, 25 parts of polystyrene resins (PS) add from the second weight-loss type feeder mouth after height mixes with 2.5 parts of linear low density of polyethylene (LDPE), 10 parts of liquid flame retardants add from the liquid charging opening through liquor pump, twin screw extruder plasticizing, fusion then, extrude, tie rod, cooling, pelletizing.Pellet prepares test bars and goods by injection moulding machine then at 110 ℃ of dry 2h of air dry oven.Primary antioxidant is 3,5-di-tert-butyl-hydroxy phenyl propionic acid stearyl alcohol ester; Auxiliary antioxidant is tricresyl phosphite (a nonyl phenyl).
Embodiment 2:
75 parts polyphenylene oxide resin (PPE), 8 parts of hydrogenated styrene-butadiene-styrenes (SEBS) and 0.2 part of primary antioxidant and 0.2 part of auxiliary antioxidant add from the first weight-loss type feeder mouth after height mixes, 25 parts of polystyrene resins (PS) add from the second weight-loss type feeder mouth after height mixes with 5 parts of linear low density of polyethylene (LDPE), 10 parts of liquid flame retardants add from the liquid charging opening through liquor pump, twin screw extruder plasticizing, fusion then, extrude, tie rod, cooling, pelletizing.Pellet prepares test bars and goods by injection moulding machine then at 110 ℃ of dry 2h of air dry oven.Primary antioxidant is 3,5-di-tert-butyl-hydroxy phenyl propionic acid stearyl alcohol ester; Auxiliary antioxidant is tricresyl phosphite (a nonyl phenyl).
Embodiment 3:
75 parts polyphenylene oxide resin (PPE), 8 parts of hydrogenated styrene-butadiene-styrenes (SEBS) and 0.2 part of primary antioxidant and 0.2 part of auxiliary antioxidant add from the first weight-loss type feeder mouth after height mixes, 25 parts of polystyrene resins (PS) add from the second weight-loss type feeder mouth after height mixes with 1 part of silicone master batch, 10 parts of liquid flame retardants add from the liquid charging opening through liquor pump, twin screw extruder plasticizing, fusion then, extrude, tie rod, cooling, pelletizing.Pellet prepares test bars and goods by injection moulding machine then at 110 ℃ of dry 2h of air dry oven.Primary antioxidant is 3,5-di-tert-butyl-hydroxy phenyl propionic acid stearyl alcohol ester; Auxiliary antioxidant is tricresyl phosphite (a nonyl phenyl).Silicone master batch is to be the dimethyl silicone oil of carrier with the new LDPE (film grade).
Embodiment 4:
75 parts polyphenylene oxide resin (PPE), 8 parts of hydrogenated styrene-butadiene-styrenes (SEBS) and 0.2 part of primary antioxidant and 0.2 part of auxiliary antioxidant add from the first weight-loss type feeder mouth after height mixes, 25 parts of polystyrene resins (PS) add from the second weight-loss type feeder mouth after height mixes with 2 parts of silicone master batch, 10 parts of liquid flame retardants add from the liquid charging opening through liquor pump, twin screw extruder plasticizing, fusion then, extrude, tie rod, cooling, pelletizing.Pellet prepares test bars and goods by injection moulding machine then at 110 ℃ of dry 2h of air dry oven.Primary antioxidant is 3,5-di-tert-butyl-hydroxy phenyl propionic acid stearyl alcohol ester; Auxiliary antioxidant is tricresyl phosphite (a nonyl phenyl).Silicone master batch is to be the dimethyl silicone oil of carrier with the new LDPE (film grade).
Embodiment 5:
75 parts polyphenylene oxide resin (PPE), 8 parts of hydrogenated styrene-butadiene-styrenes (SEBS) and 0.2 part of primary antioxidant and 0.2 part of auxiliary antioxidant add from the first weight-loss type feeder mouth after height mixes, 25 parts of polystyrene resins (PS), 2 parts of silicone master batch and 2.5 parts of linear low density of polyethylene (LDPE) add from the second weight-loss type feeder mouth after height mixes, 10 parts of liquid flame retardants add from the liquid charging opening through liquor pump, twin screw extruder plasticizing, fusion then, extrude, tie rod, cooling, pelletizing.Pellet prepares test bars and goods by injection moulding machine then at 110 ℃ of dry 2h of air dry oven.Primary antioxidant is 3,5-di-tert-butyl-hydroxy phenyl propionic acid stearyl alcohol ester; Auxiliary antioxidant is tricresyl phosphite (a nonyl phenyl).Silicone master batch is to be the dimethyl silicone oil of carrier with the new LDPE (film grade).
Embodiment 6:
75 parts polyphenylene oxide resin (PPE), 8 parts of hydrogenated styrene-butadiene-styrenes (SEBS) and 0.2 part of primary antioxidant and 0.2 part of auxiliary antioxidant add from the first weight-loss type feeder mouth after height mixes, 25 parts of polystyrene resins (PS), 1 part of silicone master batch and 5 parts of linear low density of polyethylene (LDPE) add from the second weight-loss type feeder mouth after height mixes, 10 parts of liquid flame retardants add from the liquid charging opening through liquor pump, twin screw extruder plasticizing, fusion then, extrude, tie rod, cooling, pelletizing.Pellet prepares test bars and goods by injection moulding machine then at 110 ℃ of dry 2h of air dry oven.Primary antioxidant is 3,5-di-tert-butyl-hydroxy phenyl propionic acid stearyl alcohol ester; Auxiliary antioxidant is tricresyl phosphite (a nonyl phenyl).Silicone master batch is to be the dimethyl silicone oil of carrier with the new LDPE (film grade).
The raw material weight umber proportioning of table 1 embodiment 1～6, Comparative Examples 1
| Component | Comparative Examples 1 | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 |
| ??PPE | ??75 | ??75 | ??75 | ??75 | ??75 | ??75 | ??75 |
| ??PS | ??25 | ??25 | ??25 | ??25 | ??25 | ??25 | ??25 |
| ??SEBS | ??8 | ??8 | ??8 | ??8 | ??8 | ??8 | ??8 |
| ??BDP | ??10 | ??10 | ??10 | ??10 | ??10 | ??10 | ??10 |
| ??LDPE | ??0 | ??2.5 | ??5 | ??2.5 | ??5 | ||
| Silicone master batch | ??0 | ??0 | ??0 | ??1 | ??2 | ??2 | ??1 |
| Primary antioxidant | ??0.2 | ??0.2 | ??0.2 | ??0.2 | ??0.2 | ??0.2 | ??0.2 |
| Auxiliary antioxidant | ??0.2 | ??0.2 | ??0.2 | ??0.2 | ??0.2 | ??0.2 | ??0.2 |
Composition properties test result in table 2 embodiment and the Comparative Examples
| Performance index | Comparative Examples 1 | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 |
| Tensile strength Mpa | ??66.2 | ??64.4 | ??62.7 | ??66.0 | ??65.6 | ??62.9 | ??64.8 |
| Flexural strength Mpa | ??105.4 | ??102.6 | ??100.8 | ??104.1 | ??104.5 | ??101.9 | ??103.5 |
| Shock strength (breach) KJ/m 2 | ??20.0 | ??24.4 | ??28.1 | ??23.7 | ??23.3 | ??24.5 | ??25.8 |
| Flame retardant rating (3.2mm) | ??V0 | ??V0 | ??V0 | ??V0 | ??V0 | ??V0 | ??V0 |
| Performance index | Comparative Examples 1 | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 |
| Welding pressure Mpa | ??2.2 | ??2.0 | ??1.9 | ??2.0 | ??1.9 | ??1.8 | ??1.8 |
| The goods The apparent phenomenon | Obvious scratch | The moderate scratch | Slight scratch | The moderate scratch | Slight scratch | No scratch | No scratch |
By embodiment 1-6 and Comparative Examples 1 relatively, can obviously see, the adding of auxiliary agent, the welding pressure when obviously having reduced ultrasonic welding, what make goods has apparently obtained obvious improvement.
Embodiment 7:
The consumption of each component (weight) is:
50～100 parts of polyphenylene oxide resins (50,70,100 parts of examples)
20～40 parts of polystyrene resins (20,30,40 parts of examples)
2～10 parts on elastomerics (2,5,10 parts of examples)
4～15 parts of fire retardants (4,8,15 parts of examples)
1～10 part of polyolefine (1,6,10 parts of examples)
0.5～5 part of silicone master batch (0.5,3,5 parts of examples)
0.2～0.5 part of primary antioxidant (0.2,0.3,0.5 part of example)
0.2～0.5 part of auxiliary antioxidant (0.2,0.3,0.5 part of example).
Polyphenylene oxide resin is 2, the polymkeric substance of 6-xylenol and 2, and 6-xylenol and 2,3, the multipolymer of 6-pseudocuminol, its limiting viscosity is 0.2-0.6dl/g.
Described polystyrene resin is a polystyrene.
Elastomerics is styrene-butadiene rubber(SBR), HSBR, ethylene-propylene rubber(EPR) or polyolefine.
Fire retardant is triphenylphosphate (TPP), tetraphenyl (bisphenol-A) bisphosphate (BDP), tetraphenyl resorcinol diphosphate (RDP) or fragrant alkene condensed phosphoric acid esters (PX-200).
Polyolefine is high density polyethylene(HDPE), new LDPE (film grade), linear low density polyethylene, ethylene-propylene copolymer, ethylene-butene copolymer or polypropylene.
Described silicone master batch is to be dimethyl silicone oil, methyl phenyl silicone oil, ethyl hydroxy silicon oil, methyl phenyl vinyl silicone rubber or the silicone resin of carrier with the new LDPE (film grade).Content of siloxane is at 40-60%.
Described primary antioxidant is 3,5-di-tert-butyl-hydroxy phenyl propionic acid stearyl alcohol ester, β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid stearyl alcohol ester or 2,2 methylene-biss (4-methyl-6-tert butyl phenol); Auxiliary antioxidant is tricresyl phosphite (nonyl phenyl) or tricresyl phosphite (2, the 4-di-tert-butyl-phenyl) ester.
All the other are with embodiment 6.
Claims (7)
1. polyphenyl ether resin material that is used for processing charger case, it is characterized in that: the component by following weight is formed:
50～100 parts of polyphenylene oxide resins
20～40 parts of polystyrene resins
2～10 parts on elastomerics
4～15 parts of fire retardants
1～10 part of polyolefine
0.5～5 part of silicone master batch
0.2～0.5 part of primary antioxidant
0.2～0.5 part of auxiliary antioxidant.
2. the polyphenyl ether resin material that is used for processing charger case according to claim 1 is characterized in that: described polystyrene resin is a polystyrene.
3. the polyphenyl ether resin material that is used for processing charger case according to claim 1 and 2 is characterized in that: elastomerics is styrene-butadiene rubber(SBR), HSBR, ethylene-propylene rubber(EPR) or polyolefine.
4. the polyphenyl ether resin material that is used for processing charger case according to claim 1 and 2 is characterized in that: fire retardant is triphenylphosphate, tetraphenyl (bisphenol-A) bisphosphate, tetraphenyl resorcinol diphosphate or fragrant alkene condensed phosphoric acid esters.
5. the polyphenyl ether resin material that is used for processing charger case according to claim 1 and 2 is characterized in that: polyolefine is high density polyethylene(HDPE), new LDPE (film grade), linear low density polyethylene, ethylene-propylene copolymer, ethylene-butene copolymer or polypropylene.
6. the polyphenyl ether resin material that is used for processing charger case according to claim 1 and 2 is characterized in that: described silicone master batch is to be dimethyl silicone oil, methyl phenyl silicone oil, ethyl hydroxy silicon oil, methyl phenyl vinyl silicone rubber or the silicone resin of carrier with the new LDPE (film grade).
7. the polyphenyl ether resin material that is used for processing charger case according to claim 1 and 2, it is characterized in that: described primary antioxidant is 3,5-di-tert-butyl-hydroxy phenyl propionic acid stearyl alcohol ester, β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid stearyl alcohol ester or 2,2 methylene-biss (4-methyl-6-tert butyl phenol); Auxiliary antioxidant is tricresyl phosphite (nonyl phenyl) or tricresyl phosphite (2, the 4-di-tert-butyl-phenyl) ester.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1249163C (en) * | 2001-09-14 | 2006-04-05 | 旭化成化学株式会社 | Polyphenylene ether composition |
| CN1314762C (en) * | 2005-07-27 | 2007-05-09 | 广州金发科技股份有限公司 | High toughness packing reinforced polyphenyl thioether composite material and its preparation method |
| CN101358028A (en) * | 2008-09-02 | 2009-02-04 | 宁波一舟塑胶有限公司 | Halogen-free flame-retardant thermoplastic elastomer electrical cable material using polyphenylene ether as base material and preparation method thereof |
| CN101358027A (en) * | 2007-07-31 | 2009-02-04 | 比亚迪股份有限公司 | Polyphenylene ether resin composition and method of preparing the same |
| CN101423658A (en) * | 2008-11-27 | 2009-05-06 | 中国蓝星（集团）股份有限公司 | Polyphenylene oxide resin composition and method for inhibiting discoloration of polyphenylene oxide resin |
-
2010
- 2010-03-16 CN CN2010101302617A patent/CN101792590B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1249163C (en) * | 2001-09-14 | 2006-04-05 | 旭化成化学株式会社 | Polyphenylene ether composition |
| CN1314762C (en) * | 2005-07-27 | 2007-05-09 | 广州金发科技股份有限公司 | High toughness packing reinforced polyphenyl thioether composite material and its preparation method |
| CN101358027A (en) * | 2007-07-31 | 2009-02-04 | 比亚迪股份有限公司 | Polyphenylene ether resin composition and method of preparing the same |
| CN101358028A (en) * | 2008-09-02 | 2009-02-04 | 宁波一舟塑胶有限公司 | Halogen-free flame-retardant thermoplastic elastomer electrical cable material using polyphenylene ether as base material and preparation method thereof |
| CN101423658A (en) * | 2008-11-27 | 2009-05-06 | 中国蓝星（集团）股份有限公司 | Polyphenylene oxide resin composition and method for inhibiting discoloration of polyphenylene oxide resin |
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