CN101785872A - Air purification part and device with air self-purification function - Google Patents
Air purification part and device with air self-purification function Download PDFInfo
- Publication number
- CN101785872A CN101785872A CN201010107307A CN201010107307A CN101785872A CN 101785872 A CN101785872 A CN 101785872A CN 201010107307 A CN201010107307 A CN 201010107307A CN 201010107307 A CN201010107307 A CN 201010107307A CN 101785872 A CN101785872 A CN 101785872A
- Authority
- CN
- China
- Prior art keywords
- air
- ozone
- cleaning member
- unit
- air cleaning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000746 purification Methods 0.000 title claims abstract description 41
- 238000004887 air purification Methods 0.000 title abstract description 4
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 52
- 230000015556 catabolic process Effects 0.000 claims abstract description 22
- 238000006555 catalytic reaction Methods 0.000 claims abstract description 22
- 238000006731 degradation reaction Methods 0.000 claims abstract description 22
- 238000000354 decomposition reaction Methods 0.000 claims abstract description 7
- 238000004140 cleaning Methods 0.000 claims description 55
- 230000003197 catalytic effect Effects 0.000 claims description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 15
- 239000011941 photocatalyst Substances 0.000 claims description 15
- 239000003814 drug Substances 0.000 claims description 14
- 239000000796 flavoring agent Substances 0.000 claims description 10
- 235000019634 flavors Nutrition 0.000 claims description 10
- 229940079593 drug Drugs 0.000 claims description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 8
- 239000003517 fume Substances 0.000 claims description 8
- 239000008187 granular material Substances 0.000 claims description 8
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 229910000510 noble metal Inorganic materials 0.000 claims description 5
- 229910021536 Zeolite Inorganic materials 0.000 claims description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- 150000001768 cations Chemical class 0.000 claims description 4
- 230000001413 cellular effect Effects 0.000 claims description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 4
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 4
- 229910052753 mercury Inorganic materials 0.000 claims description 4
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004408 titanium dioxide Substances 0.000 claims description 4
- 239000010457 zeolite Substances 0.000 claims description 4
- 206010012735 Diarrhoea Diseases 0.000 claims description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052737 gold Inorganic materials 0.000 claims description 3
- 239000010931 gold Substances 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- 230000002186 photoactivation Effects 0.000 claims description 3
- 229910052697 platinum Inorganic materials 0.000 claims description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims 1
- 229910052748 manganese Inorganic materials 0.000 claims 1
- 239000011572 manganese Substances 0.000 claims 1
- 239000003344 environmental pollutant Substances 0.000 abstract description 13
- 231100000719 pollutant Toxicity 0.000 abstract description 13
- 230000006378 damage Effects 0.000 abstract description 8
- 238000005516 engineering process Methods 0.000 abstract description 6
- 230000008901 benefit Effects 0.000 abstract description 5
- 238000001914 filtration Methods 0.000 abstract description 4
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 230000000593 degrading effect Effects 0.000 abstract 2
- 230000006870 function Effects 0.000 description 30
- 239000000126 substance Substances 0.000 description 18
- 239000007789 gas Substances 0.000 description 16
- 238000000034 method Methods 0.000 description 8
- 238000009423 ventilation Methods 0.000 description 8
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 230000002159 abnormal effect Effects 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 239000003153 chemical reaction reagent Substances 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- -1 phenolic aldehyde Chemical class 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 239000000356 contaminant Substances 0.000 description 4
- 238000011109 contamination Methods 0.000 description 4
- 238000007146 photocatalysis Methods 0.000 description 4
- 230000001699 photocatalysis Effects 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 230000009967 tasteless effect Effects 0.000 description 3
- 239000012808 vapor phase Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000000809 air pollutant Substances 0.000 description 2
- 231100001243 air pollutant Toxicity 0.000 description 2
- 238000003915 air pollution Methods 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 150000003071 polychlorinated biphenyls Chemical class 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000002341 toxic gas Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 208000017667 Chronic Disease Diseases 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 206010073310 Occupational exposures Diseases 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 238000003421 catalytic decomposition reaction Methods 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- VOOLKNUJNPZAHE-UHFFFAOYSA-N formaldehyde;2-methylphenol Chemical compound O=C.CC1=CC=CC=C1O VOOLKNUJNPZAHE-UHFFFAOYSA-N 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000004630 mental health Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 231100000675 occupational exposure Toxicity 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000035943 smell Effects 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Images
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The invention discloses an air purification part, which comprises a filtering unit used for filtering polluted air, a catalyzing and degrading unit capable of generating ozone and carrying out a light-catalyzed reaction so as to catalyze and degrade the filtered air, and an ozone decomposition and purification unit used for purifying the ozone in the catalyzed and degraded air and releasing the purified air. The invention further discloses a device with an air self-purification function. The air purification part and the device fully develop the advantages of the low energy consumption and high degradation rate of vacuum ultraviolet catalysis, fully degrade the polluted air and perform advanced purification on secondary pollutants and unnecessary ozone produced by the polluted air in combination with ozone catalyzing and degrading technology, thereby reducing the damage of the polluted air to the environment and providing a more healthier working environment for workers.
Description
Technical field
The present invention relates to the air purifying process field, especially relate to a kind of air cleaning member and have the device of air self-purification function.
Background technology
Chemical pollutant in the room air produces harm to health, even the volatile organic matter of low concentration (VOCs) also can cause the generation of urgency/chronic disease, benzene, formaldehyde, trichloroethane, trichloroethylene, Polychlorinated biphenyls (PCB) have been confirmed to be carcinogen.Therefore, clearly stipulated the minimum limit value of multiple air pollutants in China " IAQ (indoor air quality) standard (GB/T18883-2002) ".And some special microenvironments, as places such as chemical laboratory, biology laboratory, medical laboratory and hospitals, airborne volatile organic contaminant concentration and kind are far above general place, its polluter mainly comes from depositing in a large number of chemical drugs, reagent and frequently uses, many abnormal flavour and harmful substance continuously towards periphery in the surrounding air volatilization discharge, the staff of long term exposure in this environment physical and mental health is caused serious harm.
Air pollution can be divided into physical pollution, chemical contamination and biologic contamination three major types, control to hospital, medical laboratory, these class place air pollutants of biochemical laboratory, from nearly 10 years bibliographical information, mainly be control to physical pollution (as: radiation, vibration etc.) and biologic contamination (as: virus, fungus etc.), report to chemical contamination control is rarely found, and corresponding precautionary measures seldom.And common common organic pollution, for example benzene,toluene,xylene etc. is but threatening medical worker and patient's health.For example, the department of stomatology in hospital, methyl methacrylate, formaldehyde cresol formocresol, Oleum Ocimi Gratissimi, enzyme phenolic aldehyde liquid is that oral anesthestia and tooth are repaired common chemical reagent, these medicaments have hypotoxicity, the characteristics of high volatile volatile and strong and stimulating abnormal smells from the patient, depositing and taking the complicated pollutant system of formation in the room air that evaporate in the allocation process, the normal ultraviolet sterilization that adopts of hospital in addition, in the disinfecting process, these materials issue at ultraviolet radiation and estrangedly separate and react, generate the secondary pollution of different toxicity and abnormal flavour, form more complicated pollutant system, the health of serious harm medical worker.Therefore be necessary to reduce these medicines deposit with use in volatilization, diffusion in room air.
For reduce chemical drugs, reagent deposit with use in to air volatilization diffusion, in places such as chemical laboratory and reagent storages, usually take chemical drugs and reagent storage in cabinet, and in fume hood, take measures such as allotment with sealing, lucifuge function.Airtight depositing easily caused gas pollutant excessive concentration in the local space, medicine take in the process cabinet door repeatedly switch the access person is in the highly polluted environment short time, simultaneously these pollutant can't be diffused in the surrounding air with avoiding, become one of primary pollution source of room air pollution.
Chinese patent CN201243782 discloses a kind of medical drugs cabinet of taking a breath, constituted by cabinet, cabinet door and air exchanging apparatus and gas exchange pipeline, the air exchange pipeline is made by metal or engineering plastics, air exchanging apparatus is installed in the inner correct position of cabinet, and above cabinet, be provided with gas exchange passage and cabinet inside and be provided with air exchanging apparatus and be connected and communicate, during use, directly open air exchanging apparatus, need ventilation to open at any time, need to end to close at any time.Chinese patent CN1954917 also discloses a kind of medical cupboard that has sealing device.It is by cabinet, obturator between cabinet door and cabinet, the cabinet door constitutes, and on cabinet or cabinet door, be provided with gas turnover valve as required, cabinet inside is provided with heat exchanger, heat exchanger on this medical cupboard can link to each other with refrigeration machine, constitute refrigerator, cabinet is made by adiabator, and is mainly used in the various chemicals of storage.But these two patents all adopt ventilation to reduce the pollutant levels local space in, and this is the process that pollutant shift, and does not reach the purpose of the real purification of dusty gas.
Operations such as high volatility, abnormal flavour, deleterious chemicals generally use in fume hood, allotment, fume hood by suction function with indoor gas suction ventilation pipeline and be discharged into outdoor, the circulation of realization room air reaches the purpose of improving IAQ (indoor air quality).But the installation of fume hood is strict to the building structure in room, requires to be fixedly mounted on usually to close on constructure ventilation pipeline place, and can't move as required.Chinese patent CN2148603 and CN2355822 disclose a kind of noxious substance safety operation platform respectively, pass through fan action, make and discharge non-toxic gas after the volatilization toxic gas adsorbs after filtration when operating in the case, and the negative pressure shape recyclegas that forms vertical laminar flow in the case does not harm the preceding staff of gathering hole, and is free from environmental pollution yet.Chinese patent CN201329286 also discloses a kind of dangerous things safety operation platform, be provided with a collecting chamber in this operation stage body, collecting chamber one end is connected with operating table surface, be connected by ventilation shaft between the other end and the ventilation and negative pressure ventilation machine, avoid the further diffusion of hazardous particle and the volatilization of poisonous substances to a certain extent, reduced the danger of tumor pharmacy staff occupational exposure.These two kinds of methods also only are that pollutant are transferred to adsorbent or transferred to other space.
The VUV photocatalysis technology is one of effective method in the present vapor phase contaminants degradation technique, has advantages such as the efficient of removal height, energy consumption are low, long service life.The exploitation that relevant research and patent achievement mostly concentrate on the novel photocatalysis agent prepares and various novel reaction Design of device, but still this technology is not used for the product or the application of special environment pollutant removal.Simultaneously, the VUV photocatalysis technology also has its weak point, may have secondary pollution in the product of catalytic degradation, and ozone concentration may exceed standard in the tail gas of discharging.
Summary of the invention
In view of this, the present invention need provide a kind of air cleaning member, and described air cleaning member can carry out deep purifying to contaminated air, and simple in structure, easily manufactured.The present invention also needs to provide a kind of device with air self-purification function in addition, described device with air self-purification function can reduce or the pollution abatement air to the harm of environment, provide more healthy working environment to the staff.
According to one embodiment of present invention, provide a kind of air cleaning member.Described air cleaning member comprises: filter element is used to filter contaminated air; Catalytic degradation unit, described catalytic degradation unit can produce ozone and carry out light-catalyzed reaction, so that the air that is filtered is carried out catalysis and degraded; And ozone decomposing, purifying unit, described ozone decomposing, purifying unit is used to purify the airborne ozone by catalysis and degraded, and discharges the air that is cleaned.
According to one embodiment of present invention, described air cleaning member further comprises: air driven unit, described air driven unit are used to drive air and flow.
According to one embodiment of present invention, described catalytic degradation unit comprises: the ultraviolet transmitter unit, but described ultraviolet transmitter unit emission wavelength is less than the ultraviolet of 200nm, to produce ozone; And photocatalyst layer, described photocatalyst layer and the adjacent setting of described ultraviolet transmitter unit are so that ozone carries out ozone-light-catalyzed reaction in ultraviolet light diarrhea photoactivation agent.
According to one embodiment of present invention, described photocatalyst is a titanium dioxide, noble metal, cation or anion-modified titanium dioxide and ZnO, WO
3, Ga
2O
3, In
2O
3And at least a in the modified light catalyst.
According to one embodiment of present invention, described ultraviolet transmitter unit is the vacuum ultraviolet low pressure mercury lamp of emission 185nm or the vacuum ultraviolet Excimer lamp of emission 172nm.
According to one embodiment of present invention, described filter element is made up of drainage screen or the formed filter course of granule filter material.
According to one embodiment of present invention, described granule filter material is active carbon, NACF, cellular activated carbon, zeolite or Vermiculitum.
According to one embodiment of present invention, described ozone decomposing, purifying unit is made up of the formed ozone decomposition catalyst of at least a material with carbon element that carries in a gold, manganese, palladium or the platinum.
According to another embodiment of the present invention, provide a kind of device with air self-purification function, having comprised: casing, described casing have to be needed the space that purifies and is formed with at least one opening; And aforesaid air cleaning member, described air cleaning member is used to purify the air in the described space describedly needing in the better purifying space, being arranged on described opening part.
According to an embodiment more of the present invention, a kind of air cleaning member is provided, comprising: main body; Be arranged on the filter element in the described main body, be used to filter contaminated air; With the catalytic degradation unit of the adjacent setting of described filter element, described catalytic degradation unit can produce ozone and carry out light-catalyzed reaction, so that the air that is filtered is carried out catalysis and degraded; And ozone decomposing, purifying unit, described ozone decomposing, purifying unit is arranged on the air outflow end and is contained in the described main body, is used to purify the airborne ozone by catalysis and degraded, and discharges the air that is cleaned.
According to above-mentioned air cleaning member of the present invention, it gives full play to the advantage that the light-catalysed energy consumption of VUV is low, degradation rate is high, dusty gas is fully degraded, combined with ozone catalytic decomposition technology is carried out deep purifying to the secondary pollution and the unnecessary ozone of its generation simultaneously, thereby reduced the harm of contaminated air, provide more healthy working environment to the staff to environment.Thus, the present invention eliminates the harmful gas that evaporate into the room air from polluting the source, improves the air quality of particular job environment such as laboratory, hospital.
In addition,,, when described air cleaning member damages, can replace thus, thereby reduce the maintenance cost of described device because described air cleaning member can replace according to the device with air self-purification function of the present invention.
Additional aspect of the present invention and advantage part in the following description provide, and part will become obviously from the following description, or recognize by practice of the present invention.
Description of drawings
Above-mentioned and/or additional aspect of the present invention and advantage are from obviously and easily understanding becoming the description of embodiment below in conjunction with accompanying drawing, wherein:
Fig. 1 has shown the structural representation of air cleaning member according to an embodiment of the invention;
Fig. 2 has shown the structural representation according to the device with air self-purification function of the first embodiment of the present invention;
Fig. 3 has shown the vapor phase contaminants spectrogram of the air that the opening part of the device with air self-purification function shown in Fig. 2 is inside and outside;
Fig. 4 has shown the structural representation of the device with air self-purification function according to a second embodiment of the present invention;
Fig. 5 has shown the structural representation of the device with air self-purification function of a third embodiment in accordance with the invention;
Fig. 6 has shown the structural representation of the device with air self-purification function of a fourth embodiment in accordance with the invention;
Fig. 7 has shown the structural representation of the device with air self-purification function according to a fifth embodiment of the invention; And
Fig. 8 has shown the structural representation of the device with air self-purification function according to a sixth embodiment of the invention.
The specific embodiment
Describe embodiments of the invention below in detail, the example of described embodiment is shown in the drawings, and wherein identical from start to finish or similar label is represented identical or similar elements or the element with identical or similar functions.Below by the embodiment that is described with reference to the drawings is exemplary, only is used to explain the present invention, and can not be interpreted as limitation of the present invention.
Fig. 1 has shown the structural representation of air cleaning member 100 according to an embodiment of the invention.As shown in fig. 1,
Described air cleaning member 100 comprises: main body 600; Be arranged on the filter element 200 in the described main body 600, be used to filter contaminated air; With the catalytic degradation unit 300 of described filter element 200 adjacent settings, described catalytic degradation unit 300 can produce ozone and carry out light-catalyzed reaction, so that the air that is filtered is carried out catalysis and degraded; And ozone decomposing, purifying unit 400, described ozone decomposing, purifying unit 400 is arranged on the air outflow end and is contained in the described main body 600, is used to purify the airborne ozone by catalysis and degraded, and discharges the air that is cleaned.
According to one embodiment of present invention, air cleaning member 100 may further include: air driven unit 500, described air driven unit 500 are used to drive air and flow.As shown in fig. 1, described air driven unit 500 can be blower fan, and is arranged on the exit or the porch of air, to quicken the circulation of air.
According to one embodiment of present invention, described catalytic degradation unit 300 can comprise: ultraviolet transmitter unit 301, but described ultraviolet transmitter unit 301 emission wavelengths are less than the ultraviolet of 200nm, to produce ozone; And photocatalyst layer 302, described photocatalyst layer 302 and described ultraviolet transmitter unit 301 adjacent settings are so that ozone carries out ozone-light-catalyzed reaction in ultraviolet light diarrhea photoactivation agent.According to one embodiment of present invention, described photocatalyst can be titanium dioxide, noble metal, cation or anion-modified titanium dioxide and ZnO, WO
3, Ga
2O
3, In
2O
3And at least a in the modified light catalyst.According to one embodiment of present invention, described ultraviolet transmitter unit 301 is the vacuum ultraviolet low pressure mercury lamp of emission 185nm or the vacuum ultraviolet Excimer lamp of emission 172nm.According to one embodiment of present invention, described filter element 200 is made up of drainage screen or the formed filter course of granule filter material.According to one embodiment of present invention, described granule filter material can be active carbon, NACF, cellular activated carbon, zeolite or Vermiculitum.According to one embodiment of present invention, described ozone decomposing, purifying unit 400 can be formed by carrying the formed ozone decomposition catalyst of golden material with carbon element.
Describe in detail according to air cleaning member of the present invention below in conjunction with Fig. 1.For described filter element 200, dusty gas at first passes through described filter element 200 under the effect of the air driven unit 500 of the blower fan that for example is installed in open side.Filter element 200 can be made up of filter courses such as drainage screen, granule filter materials.Wherein drainage screen can be basic, normal, high effect drainage screen.Described granule filter material can be the active carbon of different substrate materials such as ature of coal, coconut husk, bamboo charcoal, and also available NACF, cellular activated carbon, zeolite, Vermiculitum etc. are removed the filtrate of particulate matter.
According to one embodiment of present invention, but described catalytic degradation unit 300 mainly comprises photocatalyst layer and emission wavelength uviol lamp two parts less than 200nm.Described photocatalyst can be a titanium dioxide, noble metal, cation or anion-modified titanium dioxide, and ZnO, WO
3, Ga
2O
3, In
2O
3Have the photocatalyst of photocatalysis response performance and a photocatalyst of modification on these photocatalyst bases etc. any.Described uviol lamp can be the uviol lamp of emission wavelength less than 200nm, includes but not limited to launch the vacuum ultraviolet low pressure mercury lamp of 185nm, promptly produces ozone lamp, the vacuum ultraviolet Excimer lamp of emission 172nm.
Wavelength can decompose the hydroxyl radical free radical of airborne steam, oxygen generation strong oxidizing property less than the vacuum ultraviolet (for example wavelength is the ultraviolet of 185nm) of 200nm, hydroxyl radical free radical can be with most organic pollution oxidation Decomposition in the air after just filtering, and can be oxidized to carbon dioxide to carbon monoxide, oxidation of hydrogen is a water.Wavelength is less than the vacuum ultraviolet of 200nm, produces ozone thereby can also decompose airborne oxygen as the vacuum ultraviolet of 185nm, further improves the efficient of light-catalyzed reaction.In addition, wavelength can also directly make the pollutant light degradation less than the vacuum ultraviolet (as the vacuum ultraviolet of 185nm) of 200nm.Wavelength can be subjected to the trapping agent of the electronics of optical excitation generation as photocatalyst less than the ozone that vacuum ultraviolet produced of 200nm, and accelerates light-catalyzed reaction.Ozone also can be decomposed the generation active oxygen once more by ultraviolet, and active oxygen and water molecule reaction produce hydroxyl radical free radical again, and active oxygen, hydroxyl radical free radical all can be directly and pollutant reaction, purify air.
Ozone decomposing, purifying unit 400 mainly is made up of the ozone decomposition catalyst of carbon material supported noble metal preparation, promptly can be formed by being loaded onto few wherein a kind of gold, manganese, palladium or the formed ozone decomposition catalyst of platinum material with carbon element.Need to prove that any material that can be used for catalytic degradation ozone may be used to form above-mentioned ozone decomposing, purifying unit 400, above-mentioned only for exemplary purposes, rather than in order to limit protection scope of the present invention.,, be used for further removing degrade residual thing, secondary product and residual ozone, thereby reach the purpose that purifies air by described ozone decomposing, purifying unit 400 through the air after 300 processing of described catalytic degradation unit by absorption and catalytic degradation effect.
The air self-purification device comprises: casing, described casing have to be needed the space that purifies and is formed with at least one opening; And foregoing air cleaning member, described air cleaning member is used to purify the air in the described space describedly needing in the better purifying space, being arranged on described opening part.Need to prove that this device can be for any equipment (will be elaborated below) that needs cleaning air in it,, wherein need to carry out airfiltering opening part as long as this air cleaning member is installed to according to the present invention.
Describe in detail according to various devices with air self-purification function of the present invention with reference to Fig. 2-8 below, wherein Fig. 2 has shown the structural representation according to the device with air self-purification function of the first embodiment of the present invention; Fig. 3 has shown the vapor phase contaminants spectrogram of the air that the opening part of the device with air self-purification function shown in Fig. 2 is inside and outside; Fig. 4 has shown the structural representation of the device with air self-purification function according to a second embodiment of the present invention; Fig. 5 has shown the structural representation of the device with air self-purification function of a third embodiment in accordance with the invention; Fig. 6 has shown the structural representation of the device with air self-purification function of a fourth embodiment in accordance with the invention; Fig. 7 has shown the structural representation of the device with air self-purification function according to a fifth embodiment of the invention; And Fig. 8 has shown the structural representation of the device with air self-purification function according to a sixth embodiment of the invention.
Need to prove that for succinct purpose, installation of the present invention is very simple, identical or close among NM technical characterictic and the embodiment 1 in embodiment 2-6, thus omitted.
Embodiment 1
In the present embodiment, air cleaning member 100 is applied to for example device with air self-purification function 700 of medical cupboard, described medical cupboard 700 upper ends have opening, and described air cleaning member 100 is installed in the top of medical cupboard 700, form air purification type medical cupboard, as shown in Figure 2 with taste removal, purification function.Can select for use axial flow blower to be used to drive circulation of air in the described air cleaning member 100, purified gas is directly discharged from the top of medical cupboard from the bottom to top.
Down, described medical cupboard 700 is carried out measure of merit in working order, air sample is gathered at the air outlet place in cabinet 800 and outside the cabinet 800 respectively, carries out gas chromatography-mass spectrometry analysis, and the result of described gas chromatography-mass spectrometry analysis is presented among Fig. 3.Shown in 3, before air cleaning member was opened, the gas chemistry substance classes that contains in the cabinet inner air was various, and the concentration height is shown in the fine rule among Fig. 3.After opening air cleaning member 100, new air admission cabinet 800, the air in the cabinet 800 is purified.The kind of the chemical substance that air contained after handling through air cleaning member 100 simultaneously and concentration all obviously will be less than air cleaning member and open the polluter that air are contained in the preceding cabinet 800.This shows that this medical cupboard 700 can not only guarantee air quality in the medical cupboard, can guarantee outwards discharging simultaneously or to the quality of room air air discharged.
Embodiment 3
In the present embodiment, air cleaning member 100 is applied to the laboratory operation platform, can forms clean flavor operating board 2700, as shown in Figure 5.Air cleaning member 100 is installed at the bottom of clean flavor operating board 2700, adopts for example air driven unit of centrifugal blower 2500, purified gas is discharged respectively from the both sides of clean flavor operating board 2700.
Embodiment 4
In the present embodiment, with described air cleaning member 100 and integral cabinet coupling, install two air cleaning members 100 respectively additional in the cabinet both sides, form tasteless purification type integral cabinet 3700, as shown in Figure 6, need to prove that the quantity of air cleaning member 100 can be set according to the number of these tasteless purification type integral cabinet 3700 upper sheds, to realize purification fully to air in it.
Embodiment 5
In the present embodiment,, form tasteless medicament cabinet, as shown in Figure 7, select cross-flow fan for use, purification back gas is discharged by the cabinet rear portion air cleaning member 100 and for example medicament cabinet coupling at hospital, place, pharmacy.
Embodiment 6
In the present embodiment, air cleaning member 100 is installed in the small box, forms portable drug and take case 5700, as shown in Figure 8.In the present embodiment, select for use cross-flow fan to be used as air driven of the present invention unit, purification back gas is discharged by the cabinet rear portion.This portable drug is taken case 5700 and be can be placed on the work top of surgeon dentist, makes the doctor when taking, allocating the bigger medicament of abnormal flavour, and the gas with foreign flavor that volatilizes is got rid of by air cleaning member 100, reduces the volatilization in room air.
According to aforesaid device of the present invention with air self-purification function, by above-mentioned air cleaning member is combined with locker, storing platform or working place, storing platform, working place include but not limited to chemical drugs cabinet, laboratory fume hood, laboratory operation platform, hospital pharmacy cabinet, kitchen cabinet etc.Size according to the described air cleaning member 100 of the size adjustment of locker/platform, working place, by pollutant levels, kind, complexity optimized air cleaning member each unitary composition and running parameter, for example select different capacity, different types of air driven unit by unit interval demand of processing quantity and air flow direction requirement, for example blower fan (as axial flow blower, centrifugal blower or crossflow fan) is formed the air cleaning member 100 that satisfies different user demands.Described air cleaning member 100 can be installed in the diverse location of locker/platform, working place, for example upside of casing, downside, left side, right side, front side or rear side etc. as required.
Thus, air cleaning member 100 of the present invention and use its device with air self- purification function 700,1700,2700,3700,4700,5700 can be under normal temperature and pressure conditions to have the abnormal flavour, the harmful substance that are produced in the device of air self-purification function and purify to described, thereby keep the purification of air in the described device with air self-purification function, make institute's air discharged not pollute the environment simultaneously.
Any mentioning " embodiment ", " embodiment ", " illustrative examples " etc. mean concrete member, structure or the characteristics described in conjunction with this embodiment and are contained among at least one embodiment of the present invention.Not necessarily refer to identical embodiment in this schematic statement everywhere of this description.And when describing concrete member, structure or characteristics in conjunction with any embodiment, what advocated is, realizes that in conjunction with other embodiment such member, structure or characteristics all drop within those skilled in the art's the scope.
Although the specific embodiment of the present invention is described in detail with reference to a plurality of illustrative examples of the present invention, but it must be understood that, those skilled in the art can design multiple other improvement and embodiment, and these improve and embodiment will drop within the spirit and scope.Particularly, within the scope of aforementioned open, accompanying drawing and claim, can make rational modification and improvement aspect the layout of parts and/or subordinate composite configuration, and can not break away from spirit of the present invention.Except the modification and the improvement of parts and/or layout aspect, its scope is limited by claims and equivalent thereof.
Claims (11)
1. air cleaning member comprises:
Filter element is used to filter contaminated air;
Catalytic degradation unit, described catalytic degradation unit can produce ozone and carry out light-catalyzed reaction, so that the air that is filtered is carried out catalysis and degraded; And
Ozone decomposing, purifying unit, described ozone decomposing, purifying unit is used to purify the airborne ozone by catalysis and degraded, and discharges the air that is cleaned.
2. air cleaning member according to claim 1 further comprises: air driven unit, described air driven unit are used to drive air and flow.
3. air cleaning member according to claim 1 is characterized in that, described catalytic degradation unit comprises:
The ultraviolet transmitter unit, but described ultraviolet transmitter unit emission wavelength is less than the ultraviolet of 200nm, to produce ozone; And
Photocatalyst layer, described photocatalyst layer and the adjacent setting of described ultraviolet transmitter unit are so that ozone carries out ozone one light-catalyzed reaction in ultraviolet light diarrhea photoactivation agent.
4. air cleaning member according to claim 3 is characterized in that, described photocatalyst is a titanium dioxide, noble metal, cation or anion-modified titanium dioxide and ZnO, WO
3, Ga
2O
3, In
2O
3And at least a in the modified light catalyst.
5. air cleaning member according to claim 3 is characterized in that, described ultraviolet transmitter unit is the vacuum ultraviolet low pressure mercury lamp of emission 185nm or the vacuum ultraviolet Excimer lamp of emission 172nm.
6. air cleaning member according to claim 1 is characterized in that, described filter element is made up of drainage screen or the formed filter course of granule filter material.
7. air cleaning member according to claim 6 is characterized in that, described granule filter material is active carbon, NACF, cellular activated carbon, zeolite or Vermiculitum.
8. air cleaning member according to claim 1 is characterized in that, described ozone decomposing, purifying unit is made up of the formed ozone decomposition catalyst of at least a material with carbon element that carries in gold, palladium, manganese or the platinum.
9. device with air self-purification function comprises:
Casing, described casing have to be needed the space that purifies and is formed with at least one opening; And
Air cleaning member as claimed in claim 1, described air cleaning member is used to purify the air in the described space describedly needing in the better purifying space, being arranged on described opening part.
10. the device of air self-purification function according to claim 9 is characterized in that, described device is formed medical cupboard, laboratory fume hood, distinguish the flavor of operating board, integral cabinet or portable drug taken a kind of in the case only.
11. an air cleaning member comprises:
Main body;
Be arranged on the filter element in the described main body, be used to filter contaminated air;
With the catalytic degradation unit of the adjacent setting of described filter element, described catalytic degradation unit can produce ozone and carry out light-catalyzed reaction, so that the air that is filtered is carried out catalysis and degraded; And
Ozone decomposing, purifying unit, described ozone decomposing, purifying unit is arranged on the air outflow end and is contained in the described main body, is used to purify the airborne ozone by catalysis and degraded, and discharges the air that is cleaned.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201010107307A CN101785872A (en) | 2010-02-09 | 2010-02-09 | Air purification part and device with air self-purification function |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201010107307A CN101785872A (en) | 2010-02-09 | 2010-02-09 | Air purification part and device with air self-purification function |
Publications (1)
Publication Number | Publication Date |
---|---|
CN101785872A true CN101785872A (en) | 2010-07-28 |
Family
ID=42529340
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201010107307A Pending CN101785872A (en) | 2010-02-09 | 2010-02-09 | Air purification part and device with air self-purification function |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101785872A (en) |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102000354A (en) * | 2010-10-26 | 2011-04-06 | 天津泰达环保有限公司 | High-efficiency indoor stink purification method |
CN103055340A (en) * | 2012-10-25 | 2013-04-24 | 郦宏 | Deodorization system of waste transfer station |
CN103267321A (en) * | 2013-05-30 | 2013-08-28 | 深圳中元宏康科技有限公司 | Operating room air purifying system |
CN103861858A (en) * | 2014-03-12 | 2014-06-18 | 亿丰洁净科技江苏股份有限公司 | Green ventilation cabinet for laboratory |
CN104913387A (en) * | 2015-05-29 | 2015-09-16 | 广东美的制冷设备有限公司 | Filtration component and air conditioner |
CN105509151A (en) * | 2015-12-31 | 2016-04-20 | 天津市天朝鼎盛环保科技有限公司 | Novel air purifying device |
CN105887157A (en) * | 2016-05-13 | 2016-08-24 | 中环清新人工环境工程技术(北京)有限责任公司 | Preparation method of honeycomb shaped nanometer material capable of purifying air |
CN106237840A (en) * | 2016-08-25 | 2016-12-21 | 北京航天环境工程有限公司 | VOC exhaust treatment system |
CN106237841A (en) * | 2016-08-25 | 2016-12-21 | 北京航天环境工程有限公司 | Organic waste gas treatment system |
CN106823781A (en) * | 2017-01-10 | 2017-06-13 | 清华大学 | A kind of air purifier for removing indoor VOCs and preparation method thereof |
CN111013355A (en) * | 2019-12-30 | 2020-04-17 | 大气(广东)科技发展有限公司 | Process and device for treating atmospheric combined pollution |
CN111497571A (en) * | 2020-04-16 | 2020-08-07 | 广西科学院 | Novel indoor air purification method |
US11364319B2 (en) | 2019-06-19 | 2022-06-21 | Industrial Technology Research Institute | Air purifier and air purifying method |
WO2023022583A1 (en) * | 2021-08-19 | 2023-02-23 | Instituto Tecnológico y de Estudios Superiores de Monterrey | Portable air purifier |
-
2010
- 2010-02-09 CN CN201010107307A patent/CN101785872A/en active Pending
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102000354A (en) * | 2010-10-26 | 2011-04-06 | 天津泰达环保有限公司 | High-efficiency indoor stink purification method |
CN103055340A (en) * | 2012-10-25 | 2013-04-24 | 郦宏 | Deodorization system of waste transfer station |
CN103267321B (en) * | 2013-05-30 | 2016-08-10 | 深圳橙果医疗科技有限公司 | Operating room air cleaning system |
CN103267321A (en) * | 2013-05-30 | 2013-08-28 | 深圳中元宏康科技有限公司 | Operating room air purifying system |
CN103861858A (en) * | 2014-03-12 | 2014-06-18 | 亿丰洁净科技江苏股份有限公司 | Green ventilation cabinet for laboratory |
CN104913387B (en) * | 2015-05-29 | 2017-09-19 | 广东美的制冷设备有限公司 | Filter assemblies and air conditioner |
CN104913387A (en) * | 2015-05-29 | 2015-09-16 | 广东美的制冷设备有限公司 | Filtration component and air conditioner |
CN105509151A (en) * | 2015-12-31 | 2016-04-20 | 天津市天朝鼎盛环保科技有限公司 | Novel air purifying device |
CN105887157A (en) * | 2016-05-13 | 2016-08-24 | 中环清新人工环境工程技术(北京)有限责任公司 | Preparation method of honeycomb shaped nanometer material capable of purifying air |
CN105887157B (en) * | 2016-05-13 | 2017-05-31 | 中环清新人工环境工程技术(北京)有限责任公司 | A kind of preparation method that can be used for the cellular nano material of purification of air |
CN106237840A (en) * | 2016-08-25 | 2016-12-21 | 北京航天环境工程有限公司 | VOC exhaust treatment system |
CN106237841A (en) * | 2016-08-25 | 2016-12-21 | 北京航天环境工程有限公司 | Organic waste gas treatment system |
CN106823781A (en) * | 2017-01-10 | 2017-06-13 | 清华大学 | A kind of air purifier for removing indoor VOCs and preparation method thereof |
US11364319B2 (en) | 2019-06-19 | 2022-06-21 | Industrial Technology Research Institute | Air purifier and air purifying method |
CN111013355A (en) * | 2019-12-30 | 2020-04-17 | 大气(广东)科技发展有限公司 | Process and device for treating atmospheric combined pollution |
CN111497571A (en) * | 2020-04-16 | 2020-08-07 | 广西科学院 | Novel indoor air purification method |
CN111497571B (en) * | 2020-04-16 | 2022-07-29 | 广西科学院 | Novel indoor air purification method |
WO2023022583A1 (en) * | 2021-08-19 | 2023-02-23 | Instituto Tecnológico y de Estudios Superiores de Monterrey | Portable air purifier |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101785872A (en) | Air purification part and device with air self-purification function | |
US7828940B2 (en) | Onsite chemistry air filtration system | |
KR101414562B1 (en) | Eco ventilator | |
KR102206278B1 (en) | Apparatus for purifying air using ultraviolet rays | |
KR20140003240A (en) | Apparatus for cleaning fluid | |
KR100807152B1 (en) | Device for purifying polluted air | |
KR102293117B1 (en) | Air purifier | |
KR20110135526A (en) | Ceiling air cleaning device | |
CN102811794A (en) | System and method for air purification using enhanced multi-functional coating based on pn-situ photocatalytic oxidation and ozonation | |
KR20120119475A (en) | Multiple air cleaning devices | |
CN108458415A (en) | A kind of ultraviolet light and TiO2Photocatalyst is combined the air cleaning unit and its purification method of sterilizing | |
CN1486778A (en) | Photocatalytic air purifier | |
JP2018143636A (en) | Reaction tube and air purification device | |
AU2018100807A4 (en) | An Air purification system | |
EP4151918A1 (en) | Air purification device | |
KR100799106B1 (en) | Air Purification Combind with Sub Sterilization Device | |
CN103388859A (en) | All-dimensional inlet air purification device | |
JP4404140B2 (en) | Deodorizing unit | |
JP6147033B2 (en) | Contaminated air purification device using photocatalyst | |
CN110925926A (en) | Computer room air purification system | |
KR20220096596A (en) | Air purifier with sterilization function | |
CN202069903U (en) | Medical air disinfecting and purifying device | |
JP7406855B2 (en) | Air cleaner | |
CN204973574U (en) | Novel photo -catalyst odor treatment equipment | |
KR200255178Y1 (en) | A filter for air conditioner |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C12 | Rejection of a patent application after its publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20100728 |