CN106823781A - A kind of air purifier for removing indoor VOCs and preparation method thereof - Google Patents
A kind of air purifier for removing indoor VOCs and preparation method thereof Download PDFInfo
- Publication number
- CN106823781A CN106823781A CN201710016531.3A CN201710016531A CN106823781A CN 106823781 A CN106823781 A CN 106823781A CN 201710016531 A CN201710016531 A CN 201710016531A CN 106823781 A CN106823781 A CN 106823781A
- Authority
- CN
- China
- Prior art keywords
- aluminium flake
- vuv
- ozone
- fixed plate
- air
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000012855 volatile organic compound Substances 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 31
- 238000013033 photocatalytic degradation reaction Methods 0.000 claims abstract description 15
- 238000000746 purification Methods 0.000 claims abstract description 14
- 241000237983 Trochidae Species 0.000 claims abstract description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 75
- 239000003054 catalyst Substances 0.000 claims description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 32
- 239000011572 manganese Substances 0.000 claims description 27
- 238000010438 heat treatment Methods 0.000 claims description 22
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 21
- 229910052782 aluminium Inorganic materials 0.000 claims description 21
- 239000010936 titanium Substances 0.000 claims description 21
- 229910052719 titanium Inorganic materials 0.000 claims description 21
- 239000004411 aluminium Substances 0.000 claims description 17
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 14
- 239000010410 layer Substances 0.000 claims description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 12
- 239000002002 slurry Substances 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 11
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims description 10
- 230000008929 regeneration Effects 0.000 claims description 10
- 238000011069 regeneration method Methods 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 9
- 239000011259 mixed solution Substances 0.000 claims description 9
- 239000004202 carbamide Substances 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 7
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 7
- 238000011068 loading method Methods 0.000 claims description 7
- 239000012286 potassium permanganate Substances 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- 239000012459 cleaning agent Substances 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 229910000831 Steel Inorganic materials 0.000 claims description 5
- 239000008187 granular material Substances 0.000 claims description 5
- 239000004519 grease Substances 0.000 claims description 5
- 239000011229 interlayer Substances 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 239000010959 steel Substances 0.000 claims description 5
- 239000004408 titanium dioxide Substances 0.000 claims description 5
- 239000003245 coal Substances 0.000 claims description 4
- 238000007598 dipping method Methods 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- JYLNVJYYQQXNEK-UHFFFAOYSA-N 3-amino-2-(4-chlorophenyl)-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(CN)C1=CC=C(Cl)C=C1 JYLNVJYYQQXNEK-UHFFFAOYSA-N 0.000 claims description 3
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 3
- 244000060011 Cocos nucifera Species 0.000 claims description 3
- 229910021536 Zeolite Inorganic materials 0.000 claims description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 3
- 239000000853 adhesive Substances 0.000 claims description 3
- 230000001070 adhesive effect Effects 0.000 claims description 3
- 239000002671 adjuvant Substances 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 150000001768 cations Chemical class 0.000 claims description 3
- 230000001413 cellular effect Effects 0.000 claims description 3
- 239000003610 charcoal Substances 0.000 claims description 3
- 239000013527 degreasing agent Substances 0.000 claims description 3
- 238000005237 degreasing agent Methods 0.000 claims description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 3
- QZQVBEXLDFYHSR-UHFFFAOYSA-N gallium(III) oxide Inorganic materials O=[Ga]O[Ga]=O QZQVBEXLDFYHSR-UHFFFAOYSA-N 0.000 claims description 3
- 238000007654 immersion Methods 0.000 claims description 3
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 3
- 238000007789 sealing Methods 0.000 claims description 3
- 239000010457 zeolite Substances 0.000 claims description 3
- 239000000706 filtrate Substances 0.000 claims 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 1
- 239000010931 gold Substances 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- 238000007146 photocatalysis Methods 0.000 abstract description 11
- 230000001699 photocatalysis Effects 0.000 abstract description 11
- 239000003344 environmental pollutant Substances 0.000 abstract description 6
- 231100000719 pollutant Toxicity 0.000 abstract description 6
- 238000011161 development Methods 0.000 abstract description 3
- 238000004887 air purification Methods 0.000 abstract description 2
- 239000002585 base Substances 0.000 description 12
- 230000000694 effects Effects 0.000 description 11
- 238000000034 method Methods 0.000 description 11
- 230000015556 catabolic process Effects 0.000 description 10
- 238000006731 degradation reaction Methods 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 8
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 8
- 230000003197 catalytic effect Effects 0.000 description 7
- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical class [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 239000010408 film Substances 0.000 description 4
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 4
- 229940071125 manganese acetate Drugs 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000002604 ultrasonography Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000006555 catalytic reaction Methods 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- -1 dichloro (trichlorine) ethene Chemical compound 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 108090000565 Capsid Proteins Proteins 0.000 description 2
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 2
- 206010013786 Dry skin Diseases 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 239000000809 air pollutant Substances 0.000 description 2
- 231100001243 air pollutant Toxicity 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000005238 degreasing Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 150000002823 nitrates Chemical class 0.000 description 2
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- 238000000643 oven drying Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 230000002000 scavenging effect Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000011953 bioanalysis Methods 0.000 description 1
- 238000003421 catalytic decomposition reaction Methods 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000004064 dysfunction Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000003694 hair properties Effects 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- VASIZKWUTCETSD-UHFFFAOYSA-N oxomanganese Chemical compound [Mn]=O VASIZKWUTCETSD-UHFFFAOYSA-N 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8668—Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/66—Ozone
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/32—Manganese, technetium or rhenium
- B01J23/34—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/45—Gas separation or purification devices adapted for specific applications
- B01D2259/4508—Gas separation or purification devices adapted for specific applications for cleaning air in buildings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/80—Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
- B01D2259/804—UV light
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Biomedical Technology (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
The present invention relates to a kind of air purifier for removing indoor VOCs and preparation method thereof, belong to technical field of air purification, more particularly to a kind of VUV photocatalysis air purifying device.Air purifier of the invention includes drain pan, photocatalytic degradation unit, ozone decomposed clean unit, fan, top shell, shell body.The present invention can continue at room temperature, VOCs rapidly in degraded room air, while purification secondary pollutant and unnecessary ozone, and simple structure, it is easily manufactured, more healthy living environment can be provided for indoor occupant, the development for photocatalysis air purifying device is significant.
Description
Technical field
The present invention relates to technical field of air purification, more particularly to a kind of VUV photocatalysis air purifying device.
Background technology
In recent years, the control of environmental pollution and improvement are that human society faces and key subjects urgently to be resolved hurrily, people couple
The understanding of environmental protection extends to interior by outdoor.Waving for interior is discharged into from gasoline, construction material, furniture, cigarette, electrical equipment etc.
Hair property organic chemicals (VOCs) kind up to more than 300, including formaldehyde, benzene homologues, ammonia, dichloro (trichlorine) ethene, an oxygen
Change high-risk, the toxic gas high such as carbon, nitrogen dioxide, sulfur dioxide.These chemical substances can trigger human and animal's body machine
The dysfunction of energy, long-term suction even can be with diseases such as leukemogenesis, cancers.In face of the severe shape of room air pollution
Gesture, people are in the urgent need to seeking a kind of economical and effective and environment-friendly processing method.
The purification style of room air is divided into natural purification method and forces the method for purification.Self-purification is exactly by leading to naturally
Wind, windowing ventilation or installation ventilating fan, indoor contaminated air, the lighter field of suitable pollutant are replaced with fresh air
Close, while the effect of self-purification depends on the clean-up performance of outdoor environment.It is then using certain technology or skill to force purification
Art product makes the quality of room air take a turn for the better, be particularly well-suited to room and office space etc. with sealing and pollutant be difficult to
The situation of outdoor diffusion.
Forcing purification can be divided into absorption method and decomposition method two ways again.Absorption method is the conventional process side of room air
Method, generally using either physically or chemically air pollutants are collected, such as mechanical filter formula, absorption type, electrostatic, negative
Oxonium ion air purifier etc..Such method is preferable for the removal effect of solid grain contamination, has the disadvantage dirty for gaseous state
The dye thing particularly removal effect of VOCs is poor.For adsorption cleaning device, over time, sorbing material is up to
Saturation, when temperature, wind speed are increased to a certain degree, the pollutant for being adsorbed is possible to separate out, is again introduced into
Among room air, it is therefore desirable to which timing updates.
Decomposition method is that gaseous contaminant is degraded by chemically reacting, and eventually becomes harmless material, such as light
Catalytic air purifier, ozone air purifier and bioanalysis air purifier, wherein photocatalysis technology is used as a kind of Novel oxygen
Change technology is increasingly subject to the concern of domestic and foreign scholars.There is researcher to investigate nano-TiO within 20032The photocatalysis performance of coating with
And performance (the HVAC 2002,32,23-25 of several photocatalysis air purifying devices of commercial type；Beijing University of Technology is learned
Report 2005,31,58-62), find TiO2Particle have to indoor air pollutants such as nitrogen dioxide, sulfur dioxide and formaldehyde compared with
Degradation effect well simultaneously lists some technical problems existing for several photocatalysis air purifying devices, such as nanomaterial loadings
Not enough almost play a role firmly or not, its research provides base for the development of photocatalysis air purifying device from now on
Plinth.2007, researcher was by WO3Modified P25 is carried on honeycomb aluminum (Indoor Air 2007,17,305-316), in UVC
Photocatalytic degradation low concentration VOCs obtains good degradation effect, but the too high high cost of energy consumption under (254nm) light.There is report within 2013
Road is by TiO2(Journal of Hazardous Materials 2013,261,130-138) is supported on carbon fabric fiber,
The light catalytic purifying room air under vacuum-ultraviolet light, the relatively low degradation efficiency of energy consumption is higher, but which presence can not be effective
Remove the excessive ozone of generation and form pollution.2014, Pd was carried on TiO by researcher2On film, vacuum is purple at room temperature
Outer Photocatalytic Degradation of Toluene and ozone obtain good removal effect (Chemical Engineering Journal 2014,
252,337-345), but the method introduce precious metals pd, improve preparation cost be not easy to practical application.
In sum, indoor air cleaner or a new and old technology and the field deposited is also one rising
Field.Nowadays, various indoor air cleaners emerge in an endless stream, but all less desirable for clean-up effect.Must be comprehensive
The advantage of various cleaning principles, improves its performance, designs the indoor air cleaner of comprehensive stronger multiple purifying effect,
Indoor air quality could thoroughly be improved.
By the use of titanium dioxide as photochemical catalyst, the catalytic degradation VOCs under vacuum-ultraviolet light, including hard-degraded substance and
Other method is difficult to the contaminant trace species for removing, and ultimately generates CO2And H2O.Although having catalyst inactivation, catalyst to be difficult to admittedly
The shortcomings of fixed, concentration reduction degradation efficiency also declines, produces unnecessary ozone therewith, but generally the technology is expected to turn into clean room
The effective means of VOCs in interior air.
The content of the invention
The present invention is directed to deficiency of the prior art, proposes a kind of air purifier for removing indoor VOCs, and the present invention can
VOCs to continue at room temperature, rapidly in degraded room air, while purification secondary pollutant and unnecessary ozone, and knot
Structure is simple, easily manufactured, can provide more healthy living environment for indoor occupant, and the development for photocatalysis air purifying device has
It is significant.
A kind of air purifier for removing indoor VOCs, it is characterised in that the clarifier includes drain pan, photocatalytic degradation
Unit, ozone decomposed clean unit, fan, top shell, shell body；
There is the drain pan sieve aperture to be flowed into for air and filtering bulky grain debris, and leg is provided with drain pan；
The photocatalytic degradation unit includes VUV lamps, VUV lamp bases, support, titanium sheet, fixed plate, the control of VUV circuit for lamp
Device；VUV lamps are fixed on VUV lamp bases, at least one, VUV lamps, and titanium sheet is housed on support, and titanium sheet is fixed on by fixed plate
On support, fixed plate realizes that surrounding is sealed to its inner part, while having VUV circuit for lamp control devices, circuit on the outside of fixed plate
Control device includes lamp ballast, ballast fixed plate, binding post, and ballast is fixedly mounted in ballast fixed plate, connects
Line terminals are connected with power switch；
The ozone decomposed clean unit includes ozone-removing device cabin and the ozone-removing device being placed in it, ozone decomposed
Clean unit top is provided with sealing plate and is provided with special air outlet, and fan is embedded at air outlet admittedly, fan and air outlet size phase
Adapt to；
There are air outlet, power switch, temperature control panel, wind speed control switch, time control switch in the top shell, electricity
Source switch is connected with fan, heating rod, VUV lamp power supplys respectively, and wind speed control switch is connected with fan governor, and time control is opened
Close and be connected with heating stick controller；
Shell body is combined with drain pan, top shell and for clarifier part to be encapsulated in the inside.
Fan is additionally provided between the drain pan and photocatalytic degradation unit, for controlling the more multicontaminated air of purification.
The support, fixed plate are the support and fixed plate of steel.
The fixed plate outside is equipped with Weight plate with the corresponding surface of VUV circuit for lamp control devices.
The VUV lamps are 4-9, are fixed on VUV lamp bases in the 4-9 lattice that support is separated into respectively, in support
On to be disposed with titanium sheet adjacent with VUV lamps.
It is loaded with titanium dioxide in the titanium sheet, noble metal, cation or anion-modified titanium dioxide and ZnO,
WO3、Ga2O3、In2O3And its at least one of modified light catalyst.
The ozone-removing device includes the filter layer formed by screen pack, granule filter material and/or is load Mn oxide
Aluminium flake situ regeneration device.
Granule filter material in the filter layer is cocoanut active charcoal, the coal mass active carbon of dipping KI, NACF,
One or more in cellular activated carbon or zeolite.
The aluminium flake situ regeneration device of the load Mn oxide is that the Mn oxide loaded on aluminium flake is removal ozone
Catalyst, aluminium flake is at least a piece of, and hole is provided with the interspersed heating rod of aluminium flake interlayer or on aluminium flake, and heating rod is interspersed in hole.
A kind of aluminium flake preparation method for loading Mn oxide is as follows：
(1) aluminium flake is carried out into ungrease treatment, water is moistened completely to surface；
(2) permanganate is soluble in water, stirring adds adjuvant ammoniacal liquor or urea after it is fully dissolved, stirring is to equal
Even mixing；
(3) aluminium flake obtained by step (1) treatment is put into and is placed in water bath with thermostatic control again into the mixed solution of step (2) and adds
Heat；
(4) aluminium flake after the completion of step (3) is taken out, washs and dry；
(5) it is 1-10 with the part by weight of catalyst, water-based adhesive, water:1-5:1-10 prepares catalyst pulp；
(6) in the slurry of aluminium flake immersion step (5) for obtaining step (4), to aluminium base on or aluminium flake on uniform hanging,
In -105 DEG C of dryings of room temperature 15 minutes；
(7) after repeat step (6) 3-5 times, it is completely dried the aluminium flake for obtaining loading Mn oxide；
The concentration of permanganate is 0.1-60g/L in the mixed solution, and the concentration of ammoniacal liquor or urea is 1.0-40g/L.
The surface area of the aluminium base is 0.2-28cm with the concentration ratio of permanganate2:0.1-60g/L。
The particle of the catalyst is more than 100 mesh, is birnessite manganese dioxide catalyst；The catalyst pulp
PH value is 5-9.
Ungrease treatment in the step (1) is cleaned the grease of aluminum flake surface using cleaning agent, then is washed with clear water
Wash；The cleaning agent is the degreasing agent of acid, alkalescence or organic solvent.
Permanganate in the step (2) is water-soluble permanganate, is potassium permanganate, sodium permanganate, permanganic acid amine
In one kind or their any combination.
The water bath with thermostatic control heating-up temperature of the step (3) is -95 DEG C of room temperature, and the time is 0.5-12 hours.
The drying temperature of the step (4) is -350 DEG C of room temperature.
The solid content of slurry is 5-50% in the step (5).
The drying of the step (7) be load Mn oxide aluminium flake be put into baking oven in be machined to be completely dried.
Advantages of the present invention is mainly reflected in：
(1) titanium dioxide film materials catalyst and the equal preparation process is simple of Mn oxide, the low cost of aluminium flake load, easily
In large-scale production.
(2) advantage that energy consumption is low, degradation rate is high of VUV photocatalysis has been given full play to, the gas to polluting fills
The degraded for dividing.
(3) secondary pollution and unnecessary ozone that combined with ozone catalytic decomposition technology is produced to it carry out deep purifying.
(4) Mn oxide of aluminium flake load can recover to remove ozone activity by heating unit in-situ regeneration, while photocatalysis
Unit and ozone filter layer can be replaced, so as to reduce the maintenance cost of the clarifier.
Brief description of the drawings
Fig. 1 is the internal structure schematic perspective view of the embodiment of the present invention 1.
Fig. 2 be top shell of the present invention, drain pan schematic diagram, wherein, Fig. 2 a top shell structural representations, Fig. 2 b be bottom case structure signal
Figure.
Fig. 3 is the schematic diagram of ozone purification unit of the present invention, wherein, Fig. 3 a are ozone-removing device cabin, active carbon layer, load
The aluminium flake situ regeneration device schematic diagram of Mn oxide, Fig. 3 b illustrate for heating rod is interspersed in the aluminium flake hole of load Mn oxide
Figure.
Fig. 4 is that photocatalytic degradation unit of the present invention installs 4 or 9 vacuum UV lamp schematic diagrames.
The internal structure schematic perspective view of Fig. 5 embodiment of the present invention 2.
Fig. 6 is schematic appearance of the present invention.
In figure：(1) procapsid (2) Weight plate (3) fixed plate (4) titanium sheet (5) support (6) ozone-removing device cabin (7) heating
Rod (8) aluminium carrier sheet (9) blower tray (10) wind speed control switch (11) time control switch (12) temperature control panel (13)
Power switch (14) top shell (15) fan (16) filter layer (17) back casing (18) lamp ballast (19) ballast fixed plate (20)
Binding post (21) VUV lamp (22) VUV lamp base (23) drain pan (24) aluminium loads film perforation (25) air outlet
Specific embodiment
Embodiment 1
A kind of air purifier for removing indoor VOCs of the invention, as shown in figure 1, the clarifier includes drain pan 23, light
(shell body is by procapsid 1 and back casing 17 for catalytic degradation unit, ozone decomposed clean unit, fan 15, top shell 14, shell body
Composition)；
Drain pan 23 have sieve aperture be used for air flow into and filtering bulky grain debris, be provided with drain pan leg make clarifier and
Leave space in placed side.
Photocatalytic degradation unit is used to carry out light-catalyzed reaction, produces ozone to carry out catalytic degradation, light to pollutant VOCs
Catalytic degradation unit includes：The VUV lamps 21 on VUV lamp bases 22 are fixed on, VUV lamps are one, the vacuum that the present embodiment is used
Ultraviolet lamp is ZW10D15Y-Z212, can launch wavelength for 185nm ultraviolet light, produce ozone.One steel support 5 is used for branch
Support titanium sheet 4, titanium sheet 4 is directly fixed on support 5 by fixed plate 3, or is fixed on fixed plate 3 and titanium sheet 4 by screw
On support 5, the present embodiment uses fixing form (fixed plate is corresponding with the size of support inside casing) VUV lamp bases 22, VUV
Lamp 21, steel support 5, titanium sheet 4 are sealed by fixed plate surrounding and realize physical isolation with VUV circuit for lamp control devices.In fixation
The outside of plate is while be provided with VUV (vacuum ultraviolet) circuit for lamp control device, circuit control device includes being fixed on ballast
Lamp ballast 18, binding post 20 in fixed plate 19, binding post is connected with power switch, and the present embodiment uses commercially available
Lamp ballast, binding post, model are respectively BS-ZSZ101E, JHT4502.Catalyst is loaded with titanium sheet 4, what is loaded urges
Agent is titanium dioxide, noble metal, cation or anion-modified titanium dioxide and ZnO, WO3、Ga2O3、In2O3And its change
At least one of property photochemical catalyst, titanium sheet 4 is adjacent with vacuum UV lamp 21, and the present embodiment is used and is loaded with porous surface two
The titanium sheet 4 of thin film of titanium oxide.
Ozone decomposed clean unit is used to decompose the ozone of photocatalytic degradation unit output, and ozone decomposed clean unit has one
Ozone-removing device cabin 6, the polytetrafluoroethylmaterial material that the present embodiment ozone-removing device cabin 6 uses, ozone-removing device is placed in cabin,
As shown in Figure 3.Ozone decomposed clean unit top is provided with blower tray and is provided with air outlet, the size of fan 15 and air outlet chi
It is very little be adapted, fan 15 is embedded in air outlet admittedly, with ensure transfer out be purification after air, fan can be by wind speed control switch
10 regulation air quantity.The fan that the present embodiment is used for commercially available, model A2V13C38TBT-1.
Ozone-removing device can be individually the filter layer 16 formed by screen pack, granule filter material, or Supported Manganese oxygen
The combination of the aluminium flake situ regeneration device, or filter layer of compound and the aluminium flake situ regeneration device of load Mn oxide,
As shown in Figure 3.
A kind of form of ozone-removing device of the present invention is filter layer 16, and the granule filter material in filter layer can be coconut activated
One or more in charcoal, the dipping coal mass active carbon of KI, NACF, cellular activated carbon or zeolite, this implementation
Example uses the coal mass active carbon of dipping KI.
Another form of ozone-removing device of the present invention is the aluminium carrier sheet 8 for loading Mn oxide, is loaded in aluminium carrier sheet
Mn oxide be the catalyst for removing ozone, aluminium carrier sheet is at least a piece of, upper and lower in aluminium carrier sheet or interlayer is provided with heating
Rod is provided with hole in aluminium carrier sheet, and heating rod 7 is interted in hole, and heating rod 7 is interspersed to be arranged in aluminium carrier sheet interlayer or hole,
Not shown in the figure of interlayer, heating rod is arranged in structure in hole as shown in Figure 3 b to heating rod.The manganese loaded in aluminium carrier sheet
Oxide realizes that 0.5-2 hours in-situ regeneration recovers catalysis activity at 25-80 DEG C by heating rod.This implementation ozone-removing device
The aluminium flake situ regeneration device of the load Mn oxide of use, form is that heating rod is interspersed to be arranged in aluminium load film perforation.
Top shell 14 is provided with air outlet, power switch 13, temperature control panel 12, wind speed control switch 10, the present embodiment
The model of use is TG250, time control switch 11, and the model that the present embodiment is used is DKJ-Y120K, controls adding for heating rod
Hot timing, power switch is connected with fan, heating rod, VUV lamp power supplys respectively, wind speed control switch and fan governor phase
Even, time control switch is connected with heating rod temperature controller.
Drain pan, top shell are fastened on the upper and lower opening of shell body respectively, and clarifier part is encapsulated in into the inside.
Embodiment 2
On the basis of the air purifier of embodiment 1, a wind can be also installed between drain pan and photocatalytic degradation unit
Fan, as shown in figure 5, can control to suck more air for needing and purifying.
VUV lamps number in embodiment 1 and 2 can also be 4 or 9, can reach more preferable photocatalytic degradation VOCs effects,
As shown in Figure 4.VUV lamp bases 23 are separated into 4 or 9 lattice with steel support, VUV lamps are installed in correspondence lattice, pacified on support 5
Equipped with titanium sheet 4, titanium sheet is adjacent with vacuum UV lamp, and titanium sheet 4 is fixed on support 5 by hollow fixed mount and screw.
Weight plate, the weight of Weight plate can also be installed with VUV circuit for lamp control device opposite faces on the outside of fixed plate
Match with VUV circuit for lamp control devices, for keeping balance clarifier is more consolidated.
The preparation method of aluminium carrier sheet 8 of the invention is as follows：
(1) aluminium flake is carried out into ungrease treatment, water is moistened completely to surface；
(2) permanganate is soluble in water, stirring adds adjuvant ammoniacal liquor or urea after it is fully dissolved, stirring is to equal
Even mixing；
(3) aluminium flake obtained by step (1) treatment is put into and is placed in water bath with thermostatic control again into the mixed solution of step (2) and adds
Heat；
(4) aluminium flake after the completion of step (3) is taken out, washs and dry；
(5) it is 1-10 with the part by weight of catalyst, water-based adhesive, water:1-5:1-10 prepares catalyst pulp；
(6) in the slurry of aluminium flake immersion step (5) for obtaining step (4), to aluminium base on or aluminium flake on uniform hanging,
In -105 DEG C of dryings of room temperature 15 minutes；
(7) after repeat step (6) 3-5 times, it is completely dried the aluminium flake for obtaining loading Mn oxide；
The concentration of permanganate is 0.1-60g/L in the mixed solution, and the concentration of ammoniacal liquor or urea is 1.0-40g/L.
The surface area of the aluminium base is 0.2-28cm with the concentration ratio of permanganate2:0.1-60g/L。
The particle of the catalyst is more than 100 mesh, is birnessite manganese dioxide catalyst；The catalyst pulp
PH value is 5-9.
Ungrease treatment in the step (1) is cleaned the grease of aluminum flake surface using cleaning agent, then is washed with clear water
Wash；The cleaning agent is the degreasing agent of acid, alkalescence or organic solvent.
Permanganate in the step (2) is water-soluble permanganate, is potassium permanganate, sodium permanganate, permanganic acid amine
In one kind or their any combination.
The water bath with thermostatic control heating-up temperature of the step (3) is -95 DEG C of room temperature, and the time is 0.5-12 hours.
The drying temperature of the step (4) is -350 DEG C of room temperature.
The solid content of slurry is 5-50% in the step (5).
The drying of the step (7) be load Mn oxide aluminium flake be put into baking oven in be machined to be completely dried.
Concrete example 1：
6g potassium permanganate is weighed, is added into 100mL pure water, ultrasound is to being completely dissolved.It is subsequently added 4mL ammoniacal liquor molten
Liquid, stirs and evenly mixs.Quality is removed the grease and oxide layer on surface for the aluminium flake of 20g through degreasing, alkali cleaning, is cleaned with pure water to table
Face moistens completely, in then putting into above-mentioned potassium permanganate-ammonia water mixture.This solution is placed at 40 DEG C of water bath with thermostatic control and is reacted
2h.Aluminium flake is taken out, is dried at 60 DEG C, obtain pretreated aluminium flake.
29.44g manganese acetates and 24.24g ferric nitrates are weighed, the water of 400mL is added, ultrasound is complete to manganese acetate and ferric nitrate
Dissolving.12.64g potassium permanganate and 2.0g CTAB are weighed, the water of 400mL is added, the solution of gained is stirred continuously, and to it
In the mixed solution of manganese acetate and ferric nitrate is dropwise added dropwise.140 DEG C of reactions 2 are small during the solution that will be thoroughly mixed is positioned over reactor
When.The Mn oxide centrifugation of generation, washing are placed in 105 DEG C of oven dryings, that is, obtain manganese dioxide-catalyst.Grinding, takes
It is standby more than the powder of 100 mesh.
20g manganese dioxide powder body catalysts are weighed, 10g acryloid cements are added, 50g deionized waters mix, consolidate
Content is about 25% slurry, and regulation slurry pH is 8, then removes the foam of pulp surface.
Pretreated aluminium flake is immersed in above-mentioned slurry, stirring, to aluminium flake on uniform hanging, then take out 100
Dried 15 minutes at DEG C, be repeated 3 times.After 4 hours are completely dried at 100 DEG C, the manganese oxide catalyst of aluminium flake load is obtained
Scavenging material.
Concrete example 2：
6g potassium permanganate is weighed, is added into 100mL pure water, ultrasound is to being completely dissolved.1g urea is subsequently added, is stirred
Mix.Quality is removed the grease and oxide layer on surface for the aluminium flake of 20g through degreasing, alkali cleaning, cleans complete to surface with pure water
Moistening, in putting into above-mentioned potassium permanganate-urea mixed solution afterwards.This solution is placed at 80 DEG C of water bath with thermostatic control and reacts 3h.Take out
Aluminium flake, dries at 105 DEG C, obtains pretreated aluminium flake.
29.44g manganese acetates and 12.12g ferric nitrates are weighed, the water of 400mL is added, ultrasound is complete to manganese acetate and ferric nitrate
Dissolving.12.64g potassium permanganate and 2.0g CTAB are weighed, the water of 400mL is added, the solution of gained is stirred continuously, and to it
In the mixed solution of manganese acetate and ferric nitrate is dropwise added dropwise.100 DEG C of reactions 2 are small during the solution that will be thoroughly mixed is positioned over reactor
When.The Mn oxide centrifugation of generation, washing are placed in 105 DEG C of oven dryings, that is, obtain manganese dioxide-catalyst.Grinding, takes
It is standby more than the powder of 100 mesh.
25g manganese dioxide powder body catalysts are weighed, 10g polyurethane binder and 20g deionized waters is added, mixing is obtained
Solid content is about 45.5% slurry, and regulation slurry pH is 7.
Pretreated aluminium flake is immersed in above-mentioned slurry, stirring, to aluminium flake on uniform hanging, then take out 100
Dried 15 minutes at DEG C, be repeated 5 times.After 4 hours are completely dried at 100 DEG C, the manganese oxide catalyst of aluminium flake load is obtained
Scavenging material.
Air purifier of the invention, primarily efficient filter unit is arranged on low side, filters contaminated air (drain pan, filtering
Bulky grain object)；Adjacent with primarily efficient filter unit is photocatalytic degradation unit, can produce ozone and carry out light-catalyzed reaction,
Catalytic degradation is carried out to the VOCs in air；It is afterwards ozone decomposed unit, is used to purify unnecessary ozone and secondary pollution,
Again the air being cleaned is discharged by being arranged on the axial flow blower on top.
Claims (10)
1. it is a kind of remove indoor VOCs air purifier, it is characterised in that the clarifier include drain pan, photocatalytic degradation list
Unit, ozone decomposed clean unit, fan, top shell, shell body；
There is the drain pan sieve aperture to be flowed into for air and filtering bulky grain debris, and leg is provided with drain pan；
The photocatalytic degradation unit includes VUV lamps, VUV lamp bases, support, titanium sheet, fixed plate, VUV circuit for lamp control devices；
VUV lamps are fixed on VUV lamp bases, at least one, VUV lamps, and titanium sheet is housed on support, and titanium sheet is fixed on support by fixed plate
On, fixed plate realizes that surrounding is sealed to its inner part, while there is VUV circuit for lamp control devices on the outside of fixed plate, circuit control
Device includes lamp ballast, ballast fixed plate, binding post, and ballast is fixedly mounted in ballast fixed plate, terminals
Son is connected with power switch；
The ozone decomposed clean unit includes ozone-removing device cabin and the ozone-removing device being placed in it, ozone decomposed purification
Unit top is provided with sealing plate and is provided with special air outlet, and fan is embedded at air outlet admittedly, and fan is adapted with air outlet size；
There are air outlet, power switch, temperature control panel, wind speed control switch, time control switch in the top shell, power supply is opened
Pass be connected with fan, heating rod, VUV lamp power supplys respectively, wind speed control switch is connected with fan governor, time control switch and
Heating stick controller is connected；
Shell body is combined with drain pan, top shell and for clarifier part to be encapsulated in the inside.
2. clarifier according to claim 1, it is characterised in that be additionally provided between the drain pan and photocatalytic degradation unit
Fan, for controlling the more multicontaminated air of purification.
3. clarifier according to claim 1 and 2, it is characterised in that the support, fixed plate are the support of steel and solid
Fixed board.
4. clarifier according to claim 1 and 2, it is characterised in that the fixed plate outside controls dress with VUV circuit for lamp
The corresponding surface put is equipped with Weight plate.
5. clarifier according to claim 1 and 2, it is characterised in that the VUV lamps are 4-9, respectively in support point
It is fixed on VUV lamp bases in the 4-9 lattice being divided into, titanium sheet is disposed with support adjacent with VUV lamps.
6. clarifier according to claim 1 and 2, it is characterised in that be loaded with titanium dioxide in the titanium sheet, your gold
Category, cation or anion-modified titanium dioxide and ZnO, WO3、Ga2O3、In2O3And its at least the one of modified light catalyst
Kind.
7. clarifier according to claim 1 and 2, it is characterised in that the ozone-removing device is included by screen pack, particle
Filter layer and/or be the aluminium flake situ regeneration device for loading Mn oxide that filtrate is formed.
8. clarifier according to claim 7, it is characterised in that the granule filter material in the filter layer is coconut activated
One or more in charcoal, the dipping coal mass active carbon of KI, NACF, cellular activated carbon or zeolite.
9. clarifier according to claim 7, it is characterised in that the aluminium flake situ regeneration device of the load Mn oxide
That the Mn oxide loaded on aluminium flake is the catalyst for removing ozone, aluminium flake is at least a piece of, in the interspersed heating rod of aluminium flake interlayer or
Hole is provided with aluminium flake, heating rod is interspersed in hole.
10. a kind of aluminium flake preparation method of the Mn oxide of load according to claim 9 is as follows：
(1) aluminium flake is carried out into ungrease treatment, water is moistened completely to surface；
(2) permanganate is soluble in water, stirring adds adjuvant ammoniacal liquor or urea after it is fully dissolved, and is stirred until homogeneous mixed
Close；
(3) aluminium flake obtained by step (1) treatment is put into the mixed solution of step (2) and is placed in water bath with thermostatic control heating again；
(4) aluminium flake after the completion of step (3) is taken out, washs and dry；
(5) it is 1-10 with the part by weight of catalyst, water-based adhesive, water:1-5:1-10 prepares catalyst pulp；
(6) in the slurry of aluminium flake immersion step (5) for obtaining step (4), to aluminium base on or aluminium flake on uniform hanging, in room
The drying 15 minutes of -105 DEG C of temperature；
(7) after repeat step (6) 3-5 times, it is completely dried the aluminium flake for obtaining loading Mn oxide；
The concentration of permanganate is 0.1-60g/L in the mixed solution, and the concentration of ammoniacal liquor or urea is 1.0-40g/L.
The surface area of the aluminium base is 0.2-28cm with the concentration ratio of permanganate2:0.1-60g/L。
The particle of the catalyst is more than 100 mesh, is birnessite manganese dioxide catalyst；The pH value of the catalyst pulp
It is 5-9.
Ungrease treatment in the step (1) is cleaned the grease of aluminum flake surface using cleaning agent, then is washed with clear water；Institute
State the degreasing agent that cleaning agent is acid, alkalescence or organic solvent.
Permanganate in the step (2) is water-soluble permanganate, in being potassium permanganate, sodium permanganate, permanganic acid amine
A kind of or their any combination.
The water bath with thermostatic control heating-up temperature of the step (3) is -95 DEG C of room temperature, and the time is 0.5-12 hours.
The drying temperature of the step (4) is -350 DEG C of room temperature.
The solid content of slurry is 5-50% in the step (5).
The drying of the step (7) be load Mn oxide aluminium flake be put into baking oven in be machined to be completely dried.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710016531.3A CN106823781A (en) | 2017-01-10 | 2017-01-10 | A kind of air purifier for removing indoor VOCs and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710016531.3A CN106823781A (en) | 2017-01-10 | 2017-01-10 | A kind of air purifier for removing indoor VOCs and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106823781A true CN106823781A (en) | 2017-06-13 |
Family
ID=59118505
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710016531.3A Pending CN106823781A (en) | 2017-01-10 | 2017-01-10 | A kind of air purifier for removing indoor VOCs and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106823781A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107569987A (en) * | 2017-09-28 | 2018-01-12 | 彩融电光源技术（上海）有限公司 | A kind of processing method and processing device of middle low concentration VOCs gases |
| CN109985486A (en) * | 2019-05-13 | 2019-07-09 | 天津市圣宁生物科技有限公司 | A kind of novel ozone filter device |
| CN109999624A (en) * | 2019-04-11 | 2019-07-12 | 南京大学环境规划设计研究院股份公司 | The integration apparatus of adsoption catalysis coupling processing acid waste gas and organic exhaust gas |
| CN113019306A (en) * | 2019-12-25 | 2021-06-25 | 广东美的白色家电技术创新中心有限公司 | Adsorbing material and preparation method and application thereof |
| WO2022095619A1 (en) * | 2020-11-06 | 2022-05-12 | 佛山市顺德区美的电热电器制造有限公司 | Air purifier and catalyst preparation method |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001246227A (en) * | 2000-01-05 | 2001-09-11 | Reiko Udagawa | Air cleaner for copier |
| CN101785872A (en) * | 2010-02-09 | 2010-07-28 | 清华大学 | Air purification part and device with air self-purification function |
| CN201996882U (en) * | 2011-02-25 | 2011-10-05 | 广东雪莱特光电科技股份有限公司 | Photo-hydrogen ion sterilization module |
| CN103028358A (en) * | 2012-12-25 | 2013-04-10 | 同济大学 | Photoelectric catalytic reactor based on titanium dioxide nanotube arrays |
| CN105854592A (en) * | 2016-04-28 | 2016-08-17 | 清华大学 | Air purifying material and preparation method and application thereof |
| CN106000093A (en) * | 2016-07-22 | 2016-10-12 | 清华大学 | In-situ regenerating device for purifying air and purifier comprising same |
| CN206508799U (en) * | 2017-01-10 | 2017-09-22 | 清华大学 | A kind of air purifier for removing indoor VOCs |
-
2017
- 2017-01-10 CN CN201710016531.3A patent/CN106823781A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001246227A (en) * | 2000-01-05 | 2001-09-11 | Reiko Udagawa | Air cleaner for copier |
| CN101785872A (en) * | 2010-02-09 | 2010-07-28 | 清华大学 | Air purification part and device with air self-purification function |
| CN201996882U (en) * | 2011-02-25 | 2011-10-05 | 广东雪莱特光电科技股份有限公司 | Photo-hydrogen ion sterilization module |
| CN103028358A (en) * | 2012-12-25 | 2013-04-10 | 同济大学 | Photoelectric catalytic reactor based on titanium dioxide nanotube arrays |
| CN105854592A (en) * | 2016-04-28 | 2016-08-17 | 清华大学 | Air purifying material and preparation method and application thereof |
| CN106000093A (en) * | 2016-07-22 | 2016-10-12 | 清华大学 | In-situ regenerating device for purifying air and purifier comprising same |
| CN206508799U (en) * | 2017-01-10 | 2017-09-22 | 清华大学 | A kind of air purifier for removing indoor VOCs |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107569987A (en) * | 2017-09-28 | 2018-01-12 | 彩融电光源技术（上海）有限公司 | A kind of processing method and processing device of middle low concentration VOCs gases |
| CN109999624A (en) * | 2019-04-11 | 2019-07-12 | 南京大学环境规划设计研究院股份公司 | The integration apparatus of adsoption catalysis coupling processing acid waste gas and organic exhaust gas |
| WO2020207236A1 (en) * | 2019-04-11 | 2020-10-15 | 南京大学环境规划设计研究院股份公司 | Integrated equipment for adsorption and catalytic coupling treatment of acid waste gas and organic waste gas |
| CN109999624B (en) * | 2019-04-11 | 2023-12-08 | 南京大学环境规划设计研究院集团股份公司 | Integrated equipment for treating acid waste gas and organic waste gas by adsorption and catalysis coupling |
| CN109985486A (en) * | 2019-05-13 | 2019-07-09 | 天津市圣宁生物科技有限公司 | A kind of novel ozone filter device |
| CN109985486B (en) * | 2019-05-13 | 2024-05-31 | 天津市圣宁生物科技有限公司 | Ozone filtering device |
| CN113019306A (en) * | 2019-12-25 | 2021-06-25 | 广东美的白色家电技术创新中心有限公司 | Adsorbing material and preparation method and application thereof |
| WO2022095619A1 (en) * | 2020-11-06 | 2022-05-12 | 佛山市顺德区美的电热电器制造有限公司 | Air purifier and catalyst preparation method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106823781A (en) | A kind of air purifier for removing indoor VOCs and preparation method thereof | |
| CN105597528A (en) | Waste gas purification device and process | |
| CN106642487A (en) | Fresh air and indoor air purification integrated device and purification method | |
| CN104456755A (en) | Bi-power combined type air purifier | |
| CN201578969U (en) | Reproducible indoor air purifier | |
| CN110252300A (en) | Ag/MnO2Catalyst and its preparation and the application in formaldehyde is gone in room temperature | |
| CN101209411A (en) | Active carbon fiber with nano photocatalyst and processing method thereof | |
| CN101360955B (en) | Biological process for purifying air in confined rooms and apparatus thereof | |
| CN106000093B (en) | A kind of situ regeneration device purifying air and the clarifier containing the device | |
| CN106139743A (en) | A kind of preparation method of layer structure air purifying filter mesh sheet | |
| CN106939140A (en) | Photocatalyst spray its preparation method | |
| CN108607583A (en) | A kind of carbon-based oxyhalogen bismuth composite catalyst of photocatalytic degradation volatile organic matter and its preparation method and application | |
| JP2007275292A (en) | Deodorization filter and deodorizing device | |
| CN206508799U (en) | A kind of air purifier for removing indoor VOCs | |
| CN107243321A (en) | A kind of air cleaning material of long-acting removal organic polluter | |
| CN111215123A (en) | Can simultaneously remove COS and H in garbage gasification2S catalyst and preparation method thereof | |
| CN107314456A (en) | Can highly effectively removing volatile organic gas vertical indoor air cleaner | |
| CN110227346A (en) | A kind of leather and fur products exhaust treatment system | |
| CN103272575B (en) | A kind of nanometer titanic oxide composite photochemical catalyst material and preparation method thereof | |
| CN110038425B (en) | graphene-TiO 2 Photocatalytic air purifier | |
| CN108212148B (en) | Attapulgite clay composite catalyst for removing formaldehyde and preparation method and application thereof | |
| CN104826589A (en) | Rice husk containing bactericidal active carbon filter material and preparation method thereof | |
| CN110354892A (en) | The preparation method of oxide modifying MCM-48 molecular sieve and its application in denitration collaboration demercuration | |
| CN115870011A (en) | Nano-catalyst for efficiently degrading ammonia pollutants and application method thereof | |
| CN108607521A (en) | A kind of modified oxidized aluminium base scavenging material and preparation method thereof except formaldehyde |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170613 |
|
| WD01 | Invention patent application deemed withdrawn after publication |