CN101781859B - Burn-out printing non-woven fabric and processing technique thereof - Google Patents

Burn-out printing non-woven fabric and processing technique thereof Download PDF

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Publication number
CN101781859B
CN101781859B CN2010101089156A CN201010108915A CN101781859B CN 101781859 B CN101781859 B CN 101781859B CN 2010101089156 A CN2010101089156 A CN 2010101089156A CN 201010108915 A CN201010108915 A CN 201010108915A CN 101781859 B CN101781859 B CN 101781859B
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burn
woven fabric
thickener
out printing
etching
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CN101781859A (en
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徐百欢
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Shaoxing Ronglida Textile Technology Co., Ltd.
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SHAOXING RONGLIDA TEXTILE TECHNOLOGY Co Ltd
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Abstract

The invention provides a burn-out printing non-woven fabric and a processing technique thereof, which belong to the technical field of textiles. The burn-out printing non-woven fabric is obtained by printing burn-out pulp patterns on a non-woven fabric consisting of mixed fibers and destroying and dissolving one or more fibers in the mixed fibers. The burn-out printing non-woven fabric of the invention is characterized in that the indistinct printing patterns with hollowed engraving effect are obtained after the non-woven fabric is subjected to burn-out printing, and the appearance of the burn-out printing non-woven fabric is colorful. The appearance quality of the non-woven fabric is promoted, the design thought of a non-woven fabric product is expanded, and the burn-out printing non-woven fabric can be applied in the industries such as decoration and the like.

Description

Burn-out printing non-woven fabric and processing technology thereof
Technical field
The invention provides a kind of burn-out printing non-woven fabric and processing technology thereof, belong to field of nonwoven fabric technology.
Background technology
Transparent processing, corrosion processing are also claimed in burn-out printing, are by two kinds of fibrous fabrics, and wherein a kind of fiber can be destroyed by certain chemicals, and another kind of fiber is then unaffected; Therefore after available a kind of chemicals furnishing printing paste stamp,, make wherein a kind of fiber destruction through appropriate postprocessing.Burnt-out fabric have colored type novel, frivolous transparent, decorative pattern outstanding, clear-cut, the smooth external appearance characteristic of feel; Be similar to workmanship; Quite receive users at home and abroad and consumer's favorable comment, it is in China's weaving exported product, receives one of kind of welcoming the international market.The burn-out printing fabric of China is initial by the sixties, and common have two kinds of etching polyester-cotton fabric and etching velvetings.The early stage bale of cotton covers polyester filament and is spun into the grey cloth that cladded yarn is made into, and after burn-out printing, makes a kind of transparent, stamp product of being rich in concave-convex sense.Also have polyester cotton blending light color burn-out printing fabric, flower type nature, unique style, just as organdie, like transparent nontransparent, bright and colourful, sparkling and crystal-clear prominent order.Improving constantly of Along with people's quality of life, art up to dress ornament, personalization is more and more pursued, development to some extent, innovation to some extent on traditional burn-out printing basis.In recent years, the development of etching garment piece stamp is very fast.The knitted outerwear of picture cotton and nylon sets off out the color and luster of internal layer in the transparent colored type after burn-out printing, be rich in third dimension, and is graceful unique.At present burnt-out fabric is mainly as bunting, like the tablecloth, curtain, cover for seat, bedcover, pillowcase and the summer clothes of usefulness such as star hotel, top restaurant, honored guest's reception room, aircraft, train, steamer and indoor decoration, handkerchief etc.
Summary of the invention
The object of the present invention is to provide a kind of burn-out printing non-woven fabric and preparation method thereof.
For realizing above-mentioned purpose, the technical scheme that the present invention adopted is:
A kind of burn-out printing non-woven fabric is on the nonwoven fabric that blended fiber is formed, to print etching slurry pattern, removes wherein one or more fibers and makes to destroy and to dissolve.
Further optimize as such scheme, the blended fiber that said nonwoven fabric selects for use acid-proof alkaline to differ greatly is processed.
Said nonwoven fabric is any one in polypropylene fibre/polyamide fibre nonwoven fabric, polypropylene fibre/non-woven viscose fabric, terylene/non-woven viscose fabric, terylene/polyamide fibre nonwoven fabric, terylene/polyvinyl nonwoven fabric, the polypropylene fibre/polyvinyl nonwoven fabric.
A kind of processing technology of burn-out printing non-woven fabric comprises the steps:
(1) prepares former paste, etching slurry, 5~15 parts of thickeners, water are mixed with former paste for 72~85 parts; 6~12 parts of etching agent, 0.1~1 part of bleeding agent, former paste are deployed into the etching slurry together; (the umber here all refers to parts by mass)
(2) on nonwoven fabric, print etching slurry pattern, the sizing amount is 100~300g/m 2
(3) nonwoven that will print etching slurry is distributed under 80~90 ℃ the temperature conditions behind preliminary drying 5~10min, under 145~160 ℃ of temperature conditions, bakes 3~7min again, washing then, oven dry.
Said thickener is a kind of in acid resistance thickener and the alkali resistance thickener.
Said acid resistance thickener is any one in starch, converted starch, cellulose derivative, the seed glue, and the etching agent corresponding with the acid resistance thickener is any one in aluminum sulfate, ferric sulfate, sulfuric acid, formic acid, red fuming nitric acid (RFNA), the concentrated hydrochloric acid; Said alkali resistance thickener is any one in etherification starch, the natural plant gum derivative, and the etching agent corresponding with the alkali resistance thickener is any one in NaOH, the potassium hydroxide.
Said converted starch is any one in print thickener, yellow starch gum, the etherification starch; Cellulose derivative is any one in methylcellulose, the CMC; Seed glue is any one in guar gum, the locust bean gum; The natural plant gum derivative is any one in hydroxyethyl saponin gum, the locust tree glue etherate.
Said bleeding agent is any one in isomery ten pure APEOs, isomerous tridecanol polyoxyethylene ether, the penetrating agent JFC.
Need to prove that at this above umber all refers to parts by mass.
Burn-out printing non-woven fabric of the present invention is printed etching slurry pattern on the blended fiber nonwoven fabric, after oven dry, baking, eccysis etching residue promptly gets burn-out printing non-woven fabric.Simple some is said, on nonwoven fabric, is printed with etching slurry pattern exactly, to destroy and moltenly to remove wherein one or more fibers and make.Principle is, the blended fiber nonwoven fabric, and the acid-proof alkaline of its fiber has than big-difference.
Burn-out printing non-woven fabric of the present invention, its nonwoven fabric have obtained the decalcomania of indistinct dim, through-carved work effect after burn-out printing, product appearance is bright and colourful.The present invention has promoted the exterior quality of nonwoven fabric, has expanded the mentality of designing of nonwoven fabric product, and its product can be applicable to industries such as decoration.
The raw material explanation:
The basic composition of viscose is cellulose (C 6H 10O 5) n, chemical composition is with cotton similar, more alkaline-resisting and not acidproof, but alkaline-resisting acid resistance is all poor than cotton.Under low wet acidic heating condition, viscose glue is easy to decompose etching.Acidic materials commonly used have sulfuric acid, aluminum sulfate, ferric sulfate, nitric acid etc.
Polypropylene fibre claims that also the polypropylene fiber is one of fiber that consumption is maximum in the non-woven production, and polypropylene fibre is made up of isotactic polypropylene, has chemical resistance preferably, and except red fuming nitric acid (RFNA), outside the dense caustic soda, polypropylene fibre is good to the bronsted lowry acids and bases bronsted lowry resistance.
The basic composition material of terylene is that PET is formed by terephthalic acid (TPA) and glycol ester exchange, condensation reaction.Contain ester bond in the big molecule of dacron polyester, thus not anti-highly basic, easily hydrolysis, when high temperature more so.Terylene is acidproof, is insoluble to organic acid, and is very stable to the inorganic acid of low concentration under low temperature, but can be dissolved in the benzoic acid of the concentrated sulfuric acid and heating, more stable to general organic solvent.
Nylon fibre is to be that raw material is processed through the high score material that amido link connects with organic diamine and diacid, amino acid or caprolactam; Polyamide fibre is stable to the effect of most chemical reagent; But; It dissolves in phenols, dense inorganic acid, formic acid and causes the fracture of amido link and degrade under the normal temperature, at high temperature dissolves in the methanol solution of ethylene glycol, glacial acetic acid, propylene glycol, zinc chloride or calcium chloride, and fluoroacetic acid, fluoroethanol etc.
The main component of polyvinyl is a polyvinyl alcohol, and generally the vinyl alcohol acetate (being vinyl acetate) with stable performance is a monomer polymerization, then the polyvinyl acetate alcoholysis that generates is obtained polyvinyl alcohol, and chemical stability is good, and is alkaline-resisting, not anti-strong acid.
The specific embodiment
Through specific embodiment the present invention is described further below, but the present invention is not limited by following examples.
Embodiment one
A kind of burn-out printing non-woven fabric is on the nonwoven fabric that blended fiber is formed, to print etching slurry pattern, removes wherein one or more fibers and makes to destroy and to dissolve.Wherein, the blended fiber that nonwoven fabric selects for use acid-proof alkaline to differ greatly is processed, and the nonwoven fabric that present embodiment is selected for use is terylene/non-woven viscose fabric.
The processing technology of burn-out printing non-woven fabric of the present invention comprises the steps:
(1) prepares former paste, etching slurry, 5 parts of thickeners, water are mixed with former paste for 72 parts; 6 parts of etching agent, 0.1 part of bleeding agent, former paste are deployed into the etching slurry together.Wherein, thickener is a guar gum, and the etching agent is an aluminum sulfate, and bleeding agent is a penetrating agent JFC.
(2) on nonwoven fabric, print etching slurry pattern, the sizing amount is 200g/m 2
(3) nonwoven that will print etching slurry is distributed under 80 ℃ the temperature conditions behind the preliminary drying 10min, under 145 ℃ of temperature conditions, bakes 7min again, washing then, oven dry.
Embodiment two
A kind of burn-out printing non-woven fabric is on the nonwoven fabric that blended fiber is formed, to print etching slurry pattern, removes wherein one or more fibers and makes to destroy and to dissolve.Wherein, the blended fiber that nonwoven fabric selects for use acid-proof alkaline to differ greatly is processed, and the nonwoven fabric that present embodiment is selected for use is polypropylene fibre/non-woven viscose fabric.
The processing technology of burn-out printing non-woven fabric of the present invention comprises the steps:
(1) prepares former paste, etching slurry, 7 parts of thickeners, water are mixed with former paste for 75 parts; 8 parts of etching agent, 0.2 part of bleeding agent, former paste are deployed into the etching slurry together.Wherein, thickener is a print thickener, and the etching agent is a ferric sulfate, and bleeding agent is a penetrating agent JFC.
(2) on nonwoven fabric, print etching slurry pattern, the sizing amount is 100g/m 2
(3) nonwoven that will print etching slurry is distributed under 82 ℃ the temperature conditions behind the preliminary drying 9min, under 150 ℃ of temperature conditions, bakes 6min again, washing then, oven dry.
Embodiment three
A kind of burn-out printing non-woven fabric is on the nonwoven fabric that blended fiber is formed, to print etching slurry pattern, removes wherein one or more fibers and makes to destroy and to dissolve.Wherein, the blended fiber that nonwoven fabric selects for use acid-proof alkaline to differ greatly is processed, and the nonwoven fabric that present embodiment is selected for use is terylene/polyamide fibre nonwoven fabric.
The processing technology of burn-out printing non-woven fabric of the present invention comprises the steps:
(1) prepares former paste, etching slurry, 10 parts of thickeners, water are mixed with former paste for 79 parts; 9 parts of etching agent, 0.5 part of bleeding agent, former paste are deployed into the etching slurry together.Wherein, thickener is the etherification starch in the acid resistance thickener, and the etching agent is a formic acid, and bleeding agent is an isomerous tridecanol polyoxyethylene ether.
(2) on nonwoven fabric, print etching slurry pattern, the sizing amount is 300g/m 2
(3) nonwoven that will print etching slurry is distributed under 85 ℃ the temperature conditions behind the preliminary drying 8min, under 152 ℃ of temperature conditions, bakes 5min again, washing then, oven dry.
Embodiment four
A kind of burn-out printing non-woven fabric is on the nonwoven fabric that blended fiber is formed, to print etching slurry pattern, removes wherein one or more fibers and makes to destroy and to dissolve.Wherein, the blended fiber that nonwoven fabric selects for use acid-proof alkaline to differ greatly is processed, and the nonwoven fabric that present embodiment is selected for use is terylene/non-woven viscose fabric.
The processing technology of burn-out printing non-woven fabric of the present invention comprises the steps:
(1) prepares former paste, etching slurry, 12 parts of thickeners, water are mixed with former paste for 82 parts; 10 parts of etching agent, 0.8 part of bleeding agent, former paste are deployed into the etching slurry together.Wherein, thickener is a hydroxyethyl saponin gum, and the etching agent is a NaOH, and bleeding agent is isomery ten pure APEOs.
(2) on nonwoven fabric, print etching slurry pattern, the sizing amount is 150g/m 2
(3) nonwoven that will print etching slurry is distributed under 88 ℃ the temperature conditions behind the preliminary drying 7min, under 157 ℃ of temperature conditions, bakes 4min again, washing then, oven dry.
Embodiment five
A kind of burn-out printing non-woven fabric is on the nonwoven fabric that blended fiber is formed, to print etching slurry pattern, removes wherein one or more fibers and makes to destroy and to dissolve.Wherein, the blended fiber that nonwoven fabric selects for use acid-proof alkaline to differ greatly is processed, and the nonwoven fabric that present embodiment is selected for use is terylene/polyvinyl nonwoven fabric.
The processing technology of burn-out printing non-woven fabric of the present invention comprises the steps:
(1) prepares former paste, etching slurry, 15 parts of thickeners, water are mixed with former paste for 85 parts; 12 parts of etching agent, 1 part of bleeding agent, former paste are deployed into the etching slurry together.Wherein, thickener is a locust tree glue etherate, and the etching agent is a potassium hydroxide, and bleeding agent is isomery ten pure APEOs.
(2) on nonwoven fabric, print etching slurry pattern, the sizing amount is 250g/m 2
(3) nonwoven that will print etching slurry is distributed under 90 ℃ the temperature conditions behind the preliminary drying 5min, under 160 ℃ of temperature conditions, bakes 3min again, washing then, oven dry.
Embodiment six
A kind of burn-out printing non-woven fabric is on the nonwoven fabric that blended fiber is formed, to print etching slurry pattern, removes wherein one or more fibers and makes to destroy and to dissolve.Wherein, the blended fiber that nonwoven fabric selects for use acid-proof alkaline to differ greatly is processed, and the nonwoven fabric that present embodiment is selected for use is polypropylene fibre/polyamide fibre nonwoven fabric.
The processing technology of burn-out printing non-woven fabric of the present invention comprises the steps:
(1) prepares former paste, etching slurry, 9 parts of thickeners, water are mixed with former paste for 77 parts; 9 parts of etching agent, 0.4 part of bleeding agent, former paste are deployed into the etching slurry together.Wherein, thickener is a methylcellulose, and the etching agent is a red fuming nitric acid (RFNA), and bleeding agent is an isomerous tridecanol polyoxyethylene ether.
(2) on nonwoven fabric, print etching slurry pattern, the sizing amount is 230g/m 2
(3) nonwoven that will print etching slurry is distributed under 86 ℃ the temperature conditions behind the preliminary drying 6min, under 155 ℃ of temperature conditions, bakes 4min again, washing then, oven dry.
The foregoing description only is used to the inventive concept of the present invention of explaining, but not to the qualification of rights protection of the present invention, allly utilizes this design that the present invention is carried out the change of unsubstantiality, all should fall into protection scope of the present invention.

Claims (3)

1. the processing technology of a burn-out printing non-woven fabric is characterized in that comprising the steps:
(1) prepares former paste, etching slurry, 5~15 parts of thickeners, water are mixed with former paste for 72~85 parts; 6~12 parts of etching agent, 0.1~1 part of bleeding agent, former paste are deployed into the etching slurry together;
(2) on nonwoven fabric, print etching slurry pattern, the sizing amount is 100~300g/m 2
(3) nonwoven that will print etching slurry is distributed under 80~90 ℃ the temperature conditions behind preliminary drying 5~10min, under 145~160 ℃ of temperature conditions, bakes 3~7min again, washing then, oven dry;
Said thickener is a kind of in acid resistance thickener and the alkali resistance thickener;
Said acid resistance thickener is any one in converted starch, cellulose derivative, the seed glue, and the etching agent corresponding with the acid resistance thickener is any one in aluminum sulfate, ferric sulfate, sulfuric acid, formic acid, red fuming nitric acid (RFNA), the concentrated hydrochloric acid; Said alkali resistance thickener is any one in etherification starch, the natural plant gum derivative, and the etching agent corresponding with the alkali resistance thickener is any one in NaOH, the potassium hydroxide.
2. the processing technology of burn-out printing non-woven fabric according to claim 1, it is characterized in that: said converted starch is any one in print thickener, yellow starch gum, the etherification starch; Cellulose derivative is any one in methylcellulose, the CMC; Seed glue is any one in guar gum, the locust bean gum; The natural plant gum derivative is any one in hydroxyethyl saponin gum, the locust tree glue etherate.
3. the processing technology of burn-out printing non-woven fabric according to claim 1, it is characterized in that: said bleeding agent is any one in isomery ten pure APEOs, isomerous tridecanol polyoxyethylene ether, the penetrating agent JFC.
CN2010101089156A 2010-02-05 2010-02-05 Burn-out printing non-woven fabric and processing technique thereof Expired - Fee Related CN101781859B (en)

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CN103358736A (en) * 2012-03-31 2013-10-23 常熟市启弘纺织实业有限公司 Microgroove multicolor three-dimensional printing process
CN103835165A (en) * 2012-11-20 2014-06-04 江南大学 Burnout polyester-cotton fabric based on dispersed dye transfer printing
CN103643554A (en) * 2013-11-30 2014-03-19 江苏奥森新材料有限公司 Production method of burn-out printing non-woven fabric
CN103711012A (en) * 2013-12-26 2014-04-09 株洲华夏龙服饰研发有限公司 Printing and dyeing method of cotton cloth type blended fabric and product
CN103806212B (en) * 2014-02-27 2015-07-29 福建省长乐市欣美针纺有限公司 A kind of preparation method of decorated fire cloth
CN104060488A (en) * 2014-06-06 2014-09-24 苏州大学 Method for processing burnt-out revealed denim style effect denim
CN104032592B (en) * 2014-06-17 2017-01-11 东华大学 Printing and dyeing method of polypropylene non-woven fabric material
CN104963222A (en) * 2015-08-03 2015-10-07 黄佳雯 Ultrasoft coating printing paste for discharge
CN104947464A (en) * 2015-08-03 2015-09-30 黄佳雯 Process of super-soft wrinkle finishing and printing with transparent printing paste
CN106368007A (en) * 2016-08-30 2017-02-01 浙江正宇纺织印染基地有限公司 Environment-friendly printing gum and preparing method thereof
CN106637786B (en) * 2017-01-09 2018-11-16 利郎(中国)有限公司 A kind of decorated fire fabric and its decorated fire technique
CN109487592A (en) * 2018-10-12 2019-03-19 上海先拓精细化工有限公司 A kind of one-piece type efficient alkaline terylene etching agent
CN110318277B (en) * 2019-05-10 2020-10-13 上海咏姿时装有限公司 Method for manufacturing burnt-out fabric
CN110512446A (en) * 2019-09-04 2019-11-29 江苏阳光股份有限公司 A kind of burn-out printing technique of mao of Tencel fabric
CN113322666A (en) * 2021-06-02 2021-08-31 天津齐邦新材料有限公司 Manufacturing method of filament superfine fiber mask cloth with 3D patterns

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CN101187180A (en) * 2007-11-12 2008-05-28 青岛藤华服装有限公司 Ready-made clothes grade cloth burnt-out printing process
CN101297078A (en) * 2005-10-27 2008-10-29 世联株式会社 Opal-finished fabric

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CN101187180A (en) * 2007-11-12 2008-05-28 青岛藤华服装有限公司 Ready-made clothes grade cloth burnt-out printing process

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