CN101781150A - Anti-blocking agent of fertilizer - Google Patents

Anti-blocking agent of fertilizer Download PDF

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Publication number
CN101781150A
CN101781150A CN201010116144A CN201010116144A CN101781150A CN 101781150 A CN101781150 A CN 101781150A CN 201010116144 A CN201010116144 A CN 201010116144A CN 201010116144 A CN201010116144 A CN 201010116144A CN 101781150 A CN101781150 A CN 101781150A
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China
Prior art keywords
fatty acid
fertilizer
rcoo
magnesium
blocking agent
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CN201010116144A
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Chinese (zh)
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CN101781150B (en
Inventor
招志谋
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Guang Dong New Luyuan Chemical Co ltd
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GUANG DONG NEW LUYUAN CHEMICAL CO Ltd
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Publication of CN101781150A publication Critical patent/CN101781150A/en
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Publication of CN101781150B publication Critical patent/CN101781150B/en
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Abstract

The invention relates to an anti-blocking agent of fertilizer. The anti-blocking agent of the fertilizer mainly comprises inorganic components and organic components, wherein the inorganic components comprise the following chemical components: 45%-65% of silicon dioxide (SiO2), 10%-25% of magnesium oxide (MgO), 10%-20% of calcium oxide (CaO), 8%-15% of aluminium sesquioxide (Al2O3) and 6%-12% of iron sesquioxide(Fe2O3); and the percentage content of each organic component in the formula is as follows: 1%-5% of plant animal oil, 1%-5% of C14-C20 alkyl primary amine, 0.5%-1% of C12-C20 alkane sulfonate, 2%-5% of magnesium fatty acid Mg(RCOO)2 and 2%-5% of zinc fatty acid Zn(RCOO)2. The anti-blocking agent of the fertilizer has the advantages of good anti-blocking performance, high added value, capability of solving the problems of macrotrichium and pulverization, less dosage, simple and convenient operation, easy degradation, no dust, environmental protection and wide usable range, and is abundant in necessary nutrient elements of calcium, magnesium, sulphur and the like for crop growth.

Description

A kind of anti-caking agent for fertilizer
Technical field
The present invention relates to the agent of a kind of chemical fertilizer anti-caking, be specifically related to the anti-caking agent for fertilizer of the anti-caking of a kind of suitable chloro, nitro, urine base and S-based compound fertilizer, belong to chemical fertilizer auxiliary agent production technical field.
Background technology
Chemical fertilizer absorbs airborne moisture easily, in the process of producing and storing, lump easily, its visual appearance has been subjected to certain influence behind the fertilizer caking, bring a lot of inconvenience for simultaneously carrying and use, because caking, the peasant just need smash with the fertilizer of hard thing with caking when using the fertilizer of caking, make things convenient for the nutrient in the crop absorption fertilizer, use such fertilizer very inconvenient, and need spended time that the fertilizer of caking is smashed, time-consuming taking a lot of work, and be difficult to reach the effect that does not have caking preceding.In order to solve the problem of fertilizer caking, lot of domestic and international enterprise has carried out deep research with regard to this problem, work out the anti-hard caking agent that suitable different fertilizer is used, comprising cationic and aniorfic surfactant, nonionic surface active agent, the anti-hard caking agent of types such as inert powder.
There is the problem of following several respects in domestic used anti-hard caking agent at present: one, though adopt the anti-hard caking agent effect of import relatively good, price increases the cost of product than higher; Its two, home-made anti-hard caking agent preventing blocking effect is not fine, price is relatively cheap, to the anti-caking of some chemical fertilizer products, can't satisfy the requirement of production.
Summary of the invention
The object of the present invention is to provide a kind of agglomeration preventing performance good, the chemical fertilizer anti-caking agent that shatter value height, cost are low relatively.
In order to address the above problem, the technical solution adopted in the present invention is:
The agent of a kind of chemical fertilizer anti-caking, the per-cent of the chemical ingredients of its inorganic component is: silicon-dioxide SiO 2: 45%~65%, magnesium oxide MgO:10%~25%, calcium oxide CaO:10%~20%, aluminium sesquioxide Al 2O 3: 8%~15%, ferric oxide Fe 2O 3: 6%~12%; Organic constituent shared percentage composition in whole prescription is a vegetable and animals oils: 1%~5%; C 14-C 20Kiber alkyl amine: 1%~5%; C 12-C 20Alkylsulfonate: 0.5%~1%, fatty acid magnesium Mg (RCOO) 2: 2%~5%, fatty acid zinc Zn (RCOO) 2: 2%~5%.
R in described fatty acid magnesium and the fatty acid zinc is C 14-C 20Alkyl or alkylene.
Described inorganic component mainly is made up of Sodium sulfate anhydrous.min(99) and stone powder.
The structure of this prescription is to be made of inorganic component and organic constituent, inorganic component in the prescription is to be represented by the percentage composition of the chemical ingredients of inorganic component, the content of organic constituent represents that with organic constituent shared percentage ratio in prescription used inorganic component need to determine the raw material of employing as the case may be.
The present invention with respect to the beneficial effect of prior art is:
(1) the anti-caking performance is good, and shatter value reaches 98%;
(2) value added height has solved particle and " has become mildewed " and reach " efflorescence " problem;
(3) consumption is few, and cost is low, and composite fertilizer per ton only needs about 11 yuan of costs;
(4) simple to operation, directly cooling drum is sent in the agent of this anti-caking with auger;
(5) degraded easily, no dust is the novel pollution-free environmentfriendly products;
(6) use range is wide, is applicable to chloro, nitro, urine base and S-based compound fertilizer;
(7) be rich in nutritive elements such as the essential calcium of plant growth, magnesium, sulphur.
Embodiment
Below by embodiment the present invention is described in further details, these embodiment only are used for illustrating the present invention, do not limit the scope of the invention.
Embodiment 1
Silicon-dioxide SiO 2: 45%, magnesium oxide MgO:25%, calcium oxide CaO:10%, aluminium sesquioxide Al 2O 3: 10%, ferric oxide Fe 2O 3: 10%; The per-cent that organic constituent accounts for the prescription total amount is vegetable and animals oils: 5%; C 14-C 20Kiber alkyl amine: 5%; C 12-C 20Alkylsulfonate: 1%, fatty acid magnesium Mg (RCOO) 2: 5%, fatty acid zinc Zn (RCOO) 2: 5%.
Embodiment 2
Silicon-dioxide SiO 2: 65%, magnesium oxide MgO:10%, calcium oxide CaO:10%, aluminium sesquioxide Al 2O 3: 9%, ferric oxide Fe 2O 3: 6%; The per-cent that organic constituent accounts for the prescription total amount is vegetable and animals oils: 2%; C 14-C 20Kiber alkyl amine: 5%; C 12-C 20Alkylsulfonate: 1%, fatty acid magnesium Mg (RCOO) 2: 5%, fatty acid zinc Zn (RCOO) 2: 5%.
Embodiment 3
Silicon-dioxide SiO 2: 50%, magnesium oxide MgO:15%, calcium oxide CaO:15%, aluminium sesquioxide Al 2O 3: 8%, ferric oxide Fe 2O 3: 12%; The per-cent that organic constituent accounts for the prescription total amount is vegetable and animals oils: 5%; C 14-C 20Kiber alkyl amine: 2%; C 12-C 20Alkylsulfonate: 0.5%, fatty acid magnesium Mg (RCOO) 2: 5%, fatty acid zinc Zn (RCOO) 2: 3%.
Embodiment 4
Silicon-dioxide SiO 2: 55%, magnesium oxide MgO:20%, calcium oxide CaO:10%, aluminium sesquioxide Al 2O 3: 8%, ferric oxide Fe 2O 3: 7%; The per-cent that organic constituent accounts for the prescription total amount is vegetable and animals oils: 3%; C 14-C 20Kiber alkyl amine: 5%; C 12-C 20Alkylsulfonate: 0.8%, fatty acid magnesium Mg (RCOO) 2: 3%, fatty acid zinc Zn (RCOO) 2: 2%.
Embodiment 5
Sodium sulfate anhydrous.min(99) 40%, stone powder 49%; The per-cent that organic constituent accounts for the prescription total amount is vegetable and animals oils: 2%; C 14-C 20Kiber alkyl amine: 3%; C 12-C 20Alkylsulfonate: 1%, fatty acid magnesium Mg (RCOO) 2: 3%, fatty acid zinc Zn (RCOO) 2: 2%.
Embodiment 6
Sodium sulfate anhydrous.min(99) 35%, stone powder 44%; The per-cent that organic constituent accounts for the prescription total amount is vegetable and animals oils: 5%; C 14-C 20Kiber alkyl amine: 5%; C 12-C 20Alkylsulfonate: 1%, fatty acid magnesium Mg (RCOO) 2: 5%, fatty acid zinc Zn (RCOO) 2: 5%.
Embodiment 7
Sodium sulfate anhydrous.min(99) 20%, stone powder 49%, Attapulgite 20%; The per-cent that organic constituent accounts for the prescription total amount is vegetable and animals oils: 3%; C 14-C 20Kiber alkyl amine: 3%; C 12-C 20Alkylsulfonate: 1%, fatty acid magnesium Mg (RCOO) 2: 2%, fatty acid zinc Zn (RCOO) 2: 2%.

Claims (3)

1. chemical fertilizer anti-caking agent is characterized in that the chemical ingredients of its inorganic component is: silicon-dioxide SiO 2: 45%~65%, magnesium oxide MgO:10%~25%, calcium oxide CaO:10%~20%, aluminium sesquioxide Al 2O 3: 8%~15%, ferric oxide Fe 2O 3: 6%~12%; The percentage composition of each component of organic constituent in prescription is vegetable and animals oils: 1%~5%, and C 14-C 20Kiber alkyl amine: 1%~5%, C 12-C 20Alkylsulfonate: 0.5%~1%, fatty acid magnesium Mg (RCOO) 2: 2%~5%, fatty acid zinc Zn (RCOO) 2: 2%~5%.
2. a kind of chemical fertilizer anti-caking according to claim 1 agent is characterized in that the R in described fatty acid magnesium and the fatty acid zinc is C 14-C 20Alkyl or alkylene.
3. a kind of chemical fertilizer anti-caking according to claim 1 agent is characterized in that described inorganic component contains Sodium sulfate anhydrous.min(99) and stone powder.
CN2010101161445A 2010-02-22 2010-02-22 Anti-blocking agent of fertilizer Expired - Fee Related CN101781150B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2010101161445A CN101781150B (en) 2010-02-22 2010-02-22 Anti-blocking agent of fertilizer

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Application Number Priority Date Filing Date Title
CN2010101161445A CN101781150B (en) 2010-02-22 2010-02-22 Anti-blocking agent of fertilizer

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CN101781150A true CN101781150A (en) 2010-07-21
CN101781150B CN101781150B (en) 2012-03-28

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102050671A (en) * 2010-11-10 2011-05-11 湖北富邦科技股份有限公司 Anti-caking agent for liquid fertilizer and preparation method thereof
CN104355898A (en) * 2014-11-23 2015-02-18 青岛锐志农业技术服务有限公司 Chelated compound fertilizer containing various elements
CN104478611A (en) * 2014-12-19 2015-04-01 中化化肥有限公司烟台作物营养与植物保护研究中心 Synergisticanti-caking agent for macroelement WSF (water-soluble fertilizer)
CN106348874A (en) * 2016-08-30 2017-01-25 安徽尚诚生物科技有限公司 Anti-blocking agent for efficient compound fertilizer
CN107043292A (en) * 2017-03-06 2017-08-15 广东新绿源化工有限公司 A kind of oyster shell whiting chemical fertilizer anti-caking agent
CN108358703A (en) * 2018-04-10 2018-08-03 湖北富邦科技股份有限公司 A kind of nitro fertilizer anti-caking agents and preparation method and application
WO2019196291A1 (en) * 2018-04-10 2019-10-17 湖北富邦科技股份有限公司 Anti-caking agent used for nitrogen-based fertilizer, preparation method therefor and application thereof
CN110776372A (en) * 2019-12-18 2020-02-11 安徽海豚生物科技有限公司 Production process of powdery anti-caking agent for compound fertilizer

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1281619B (en) * 1963-11-13 1969-04-03 Henkel & Cie Gmbh Schuett- and free-flowing, in particular powdery detergents, wetting agents and emulsifiers
CN1137068C (en) * 2001-11-08 2004-02-04 宁国市中化司尔特化肥有限公司 Anti-coagulating agent for composite fertilizer
CN1431179A (en) * 2003-02-28 2003-07-23 戴星 Versatile anti caking additive for chemical fertilizer and its manufacturing methods
CN101450878A (en) * 2007-11-29 2009-06-10 襄樊隆福矿业有限公司 Anti-caking agent for mineral composite fertilizer and production method and use thereof
CN101555178B (en) * 2009-05-25 2012-07-11 自贡市鸿康实业有限公司 Anti-caking agent for fertilizer and preparation method and applications thereof

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102050671A (en) * 2010-11-10 2011-05-11 湖北富邦科技股份有限公司 Anti-caking agent for liquid fertilizer and preparation method thereof
CN102050671B (en) * 2010-11-10 2012-11-28 湖北富邦科技股份有限公司 Anti-caking agent for liquid fertilizer and preparation method thereof
CN104355898A (en) * 2014-11-23 2015-02-18 青岛锐志农业技术服务有限公司 Chelated compound fertilizer containing various elements
CN104478611A (en) * 2014-12-19 2015-04-01 中化化肥有限公司烟台作物营养与植物保护研究中心 Synergisticanti-caking agent for macroelement WSF (water-soluble fertilizer)
CN106348874A (en) * 2016-08-30 2017-01-25 安徽尚诚生物科技有限公司 Anti-blocking agent for efficient compound fertilizer
CN107043292A (en) * 2017-03-06 2017-08-15 广东新绿源化工有限公司 A kind of oyster shell whiting chemical fertilizer anti-caking agent
CN108358703A (en) * 2018-04-10 2018-08-03 湖北富邦科技股份有限公司 A kind of nitro fertilizer anti-caking agents and preparation method and application
WO2019196291A1 (en) * 2018-04-10 2019-10-17 湖北富邦科技股份有限公司 Anti-caking agent used for nitrogen-based fertilizer, preparation method therefor and application thereof
WO2019196290A1 (en) * 2018-04-10 2019-10-17 湖北富邦科技股份有限公司 Nitro fertilizer anti-caking agent as well as preparation method and application thereof
CN108358703B (en) * 2018-04-10 2021-03-02 湖北富邦科技股份有限公司 Nitro fertilizer anti-caking agent, preparation method and application
CN110776372A (en) * 2019-12-18 2020-02-11 安徽海豚生物科技有限公司 Production process of powdery anti-caking agent for compound fertilizer

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Effective date of registration: 20160302

Address after: 510000, Suixi County, Zhanjiang Province, Guangdong Province, Beizhen Province, 374 lines north

Patentee after: GUANGDONG BOKE INDUSTRIAL Co.,Ltd.

Address before: 524000, Suixi County, Guangdong Province, then 57 town of agriculture and forestry road

Patentee before: GUANG DONG NEW LUYUAN CHEMICAL Co.,Ltd.

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Address after: 524338 Jin Yuan Road 1, Ling Bei Industrial Park, Suixi County, Zhanjiang, Guangdong.

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Address before: 510000, Suixi County, Zhanjiang Province, Guangdong Province, Beizhen Province, 374 lines north

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