CN101760145A - Halogen-free flame-retardant hot-melt pressure sensitive adhesive tape and preparation method thereof - Google Patents
Halogen-free flame-retardant hot-melt pressure sensitive adhesive tape and preparation method thereof Download PDFInfo
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Abstract
The invention discloses a halogen-free flame-retardant hot-melt pressure sensitive adhesive tape, which is provided with a base material, a layer of pressure-sensitive adhesive is hot-melt coated on at least one surface of the base material, and the pressure-sensitive adhesive consists of the following components in parts by weight: 20-80 parts of polyolefine resin, 10-60 parts of tackifier, 5-30 parts of halogen-free flame retardant, 0-3 parts of silane coupling agent and 0.1-3 parts of auxiliary agent. The invention further discloses a preparation method of the pressure sensitive adhesive tape. The halogen-free flame-retardant hot-melt pressure sensitive adhesive tape of the invention has the following beneficial effects that: 1, the production process is simple and can realize one-step production; 2, the sensitive adhesive tape is environmentally friendly and energy-saving, has wide bonding range and high adhesive force; and 3, the pressure sensitive adhesive tape has good flame retardant property, and basically does not have influence on the bonding strength and the electrical property of the adhesive tape. The halogen-free flame-retardant hot-melt pressure sensitive adhesive tape obtained by the invention can be widely applied on the fields of building materials, electronics, interior fabric bonding of automobiles and the like.
Description
Technical field
The present invention relates to a kind of halogen-free flame-retardant hot-melt pressure sensitive adhesive tape and preparation method thereof.
Background technology
Along with emerging in an endless stream of event of fire, fire retardant material more and more obtains paying attention to, and industries such as building, electronics all require material to have excellent flame-retardant performance, to reduce the danger that fire takes place.
Usually, utilize Organohalogen compounds and Sb
2O
3Composite use can reach good flame retardancy under the less situation of addition.But this type of fire retardant material can produce and has corrodibility and toxic hydrogen halide in a large number in combustion processes, and bigger to the harm of human body, according to statistics, the lethal ratio of fire sootiness is up to 78.9%.Therefore, halogen-free flame retardants obtains the favor of more and more fire retardant material producers, wherein, and with being most widely used of metal hydroxide combustion inhibitor and expansion type flame retardant.
Simultaneously,, relate to all respects such as daily life, industrial application, export trade packing, and it is few to have the pressure sensitive adhesive kind of flame retardant resistance because the pressure sensitive adhesive product-use is extensive, and also very few in the research in this field both at home and abroad.At present, business-like fire-retardant pressure-sensitive adhesive film is mainly used in electron trade and automobile industry, as the 5011N etc. in day east.
Usually, fire-retardant Pressuresensitive Tape generally has two types, be a kind of be that to rely on the flame retardant resistance of base material to realize fire-retardant, introduced the Pressuresensitive Tape that a kind of halogen-free flameproof base material and pressure-sensitive adhesive layer are formed as patent 03133048.7, this adhesive tape must guarantee flame retardant resistance by the base material of fire retardant polyolefin.And for example patent 03101420 discloses a kind of odorless and halogen-free flame-retardant pressure-sensitive adhesive tape that has the cloth base material, described two-layer all by tackifier resins, fire retardant (metal hydroxides and inorganic fire-retarded auxiliary agent) and the acquisition of employing aminoalkyl group organoalkoxysilane sulfurized natural rubber based elastomeric, its base material is the cloth base material through fire-retardant finish by using the inflammable cloth base material of natural rubber based fire-retardant combination dipping to obtain preferably, and the fire-retardant rank of adhesive tape satisfies UL-510FR combustion test flame-retardant standard.Another kind is that the pressure sensitive adhesive composition has flame retardant resistance, a kind of acrylic acid series pressure-sensitive adhesive tape halogen-free flame retardants and method thereof have been introduced as patent 200510028764.2, by with joining in the acrylate pressure sensitive adhesive after halogen-free flame retardants and the organic solvent grinding, obtain Pressuresensitive Tape through coating.But this method long processing time (2～4 hours), and owing to the content of fire retardant reaches more than 25% at least, so need a large amount of solution in the preparation process, cause inefficiency and not environmental protection.
Because most pressure sensitive adhesive goods adopt solution coat production, as polyacrylate(s) pressure sensitive adhesive and part rubber-like, use tank solution in process of production, contaminate environment not only, harmful, and increased the danger and the complicacy of operating, improved energy consumption.
Summary of the invention
First purpose of the present invention is at the deficiencies in the prior art part, provides that a kind of flame retardant properties is good, applied widely, bonding force strong and the halogen-free flame-retardant hot-melt pressure sensitive adhesive tape of environmental protection and energy saving.
Second purpose of the present invention is to overcome the shortcoming of existing solution coat method, and a kind of method of utilizing heat seeling coating prepared halogen-free flame-retardant hot-melt pressure sensitive adhesive tape is provided.
For reaching first purpose, the present invention adopts following technical scheme:
A kind of halogen-free flame-retardant hot-melt pressure sensitive adhesive tape has a base material, and the one side at least of this base material goes up heat seeling coating one deck pressure sensitive adhesive, and described pressure sensitive adhesive is made up of the component of following weight part:
20～80 parts of polyolefin resines
10～60 parts of tackifier
5～30 parts of halogen-free flame retardantss
0～3 part of silane coupling agent
0.1～3 part of auxiliary agent.
Further, described polyolefin resin is any of polyethylene, polypropylene, atactic polyolefin, polybutene and ethylene copolymer, or their combinations of at least two kinds.Preferred ethylene copolymer and the atactic polyolefin of adopting.The melt flow rate (MFR) of this polyolefin resin (MFR) is preferably 0.5～200g/10min, more preferably 10～150g/10min.
Further, described tackifier are the combination of any or they in terpenes, C5 petroleum resin, C5C9 copolymerized petroleum resin, hydrogenated petroleum resin, rosin, polymerized rosin, modified phenolic, the ester gum.The softening temperature of tackifier is preferably 60～150 ℃, more preferably 70～100 ℃.
Further, described halogen-free flame retardants is any in NP copolymerization fire retardant, micro encapsulation red phosphorus combustion inhibitor, metal hydroxide combustion inhibitor, polyphosphoric acid amine, trimeric cyanamide, Pentaerythritols, the silicon-series five-retardant, or their combinations of at least two kinds.Preferred weight part of this halogen-free flame retardants is 8～25 parts, and more preferably weight part is 10～20 parts.
Further, described silane coupling agent is the combination of any or they in vinyl silicane coupling agent, amino silicane coupling agent, two amino silicane coupling agent, epoxy silane coupling, the phenylamino silane coupling agent, preferably uses vinyl silicane coupling agent and amino silicane coupling agent.
Further, described auxiliary agent comprises white oil, oxidation inhibitor and UV light stabilizing agent.
Further, described base material is any in dry goods, plastics film class, expanded plastic class, paper tape and the tinsel.Described fabric is single fabric or the MIXED FABRIC by the union yarn braiding of cotton yarn, short fiber, trevira, polypropylene fibre or acrylic fibre; Described plastics film comprises PVC, PE, PP, EVA, PET and TPU; Described paper tape comprises flaxen fiber paper, kraft paper, goffered paper and glassine paper; Described tinsel comprises aluminium foil, Copper Foil.
Further, the thickness of described base material is greater than 0.03 millimeter, and process fire retardant immersion treatment or fire retardant interpolation processing.
Further, on the upper and lower surface face of described base material respectively heat seeling coating one deck pressure sensitive adhesive is arranged.
For reaching second purpose, the present invention adopts following technical scheme:
A kind of preparation method of halogen-free flame-retardant hot-melt pressure sensitive adhesive tape, be made up of following steps:
A, polyolefin resin and white oil are mixed, make polyolefin resin surface adhesion white oil, utilize high speed dispersor to mix with tackifier, halogen-free flame retardants, silane coupling agent and auxiliary agent then;
B, the mixture that A is gone on foot join in the extrusion coated machine, and in mixing under 120～190 ℃ the temperature condition and extrusion coated on the one side at least of base material, compound then separate-type paper promptly gets Pressuresensitive Tape.
As preferably, described extrusion coated machine is the extrusion coated machine of twin screw.
By the halogen-free flame-retardant hot-melt pressure sensitive adhesive tape that the present invention obtains, have following beneficial effect: 1, production process is simple, can realize a stepization production; 2, environmental protection and energy saving, bonding in extensive range, the bounding force height; Flame retardant properties is good, and the bonding strength and the electrical property of adhesive tape do not had influence substantially.The halogen-free flame-retardant hot-melt pressure sensitive adhesive tape that the present invention obtains can be widely used in fields such as building materials, electronics, automobile inner decoration facing are bonding.
Embodiment
One, preparation halogen-free flame-retardant hot-melt pressure sensitive adhesive tape.
The preparation method of the halogen-free flame-retardant hot-melt pressure sensitive adhesive tape of each embodiment carries out: (the weight part proportioning such as the following table of each component of pressure sensitive adhesive) as follows
A, polyolefin resin and white oil are mixed, make polyolefin resin surface adhesion white oil, to guarantee that fire-retardant powder is uniformly dispersed, and play lubrication, utilize high speed dispersor to mix with tackifying resin, halogen-free flame retardants, dispersion and bonding auxiliary agent (silane coupling agent) and auxiliary agent (oxidation inhibitor and UV light stabilizing agent) then;
B, the mixture that A is gone on foot join in the extrusion coated machine, and in mixing and extrusion coated to the upper and lower surface of base material under 120～190 ℃ the temperature condition, compound then separate-type paper promptly gets Pressuresensitive Tape.
Unit: weight part
| Raw material | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 | Embodiment 8 | Embodiment 9 |
| Base material | ??PET | ??PET | ??PET | ??PET | ??PET | ??PET | ??PET | Non-woven fabrics | Non-woven fabrics |
| ??PO1 | ??20 | ??30 | ??30 | ??35 | |||||
| ??PO2 | ??35 | ??35 | ??35 | ??45 | |||||
| ??PO3 | ??50 | ??5 | |||||||
| Tackifying resin 1 | ??60 | ??50 | ??25 | ??30 | ??50 | ||||
| Tackifying resin 2 | ??10 | ??30 | ??54 | ??25 | |||||
| NP copolymerization fire retardant | ??9 | ||||||||
| Polyphosphoric acid amine | ??15 | ??12 | ??14 | ??10 | ??14 | ??14 | ??15 | ??12 | |
| Trimeric cyanamide | ??6 | ??11 | ??5 | ??7 | ??7 | ??5 | |||
| Tripentaerythritol | ??7 | ??5 | ??3 | ??3 | ??3 | ||||
| Organic silicon fibre retardant | ??1 | ??1 | ??1 | ??2 | ??1 | ??2 |
| Raw material | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 | Embodiment 8 | Embodiment 9 |
| Silane coupling agent | ??0.5 | ??0.5 | ??3 | ??2 | ??3 | ??3 | ??2 | ||
| Auxiliary agent | ??1 | ??1 | ??1 | ??1 | ??1 | ??1 | ??1 | ??1 | ??1 |
Annotate: PET thickness is 0.03mm; PO1 is EVA (VA content 28%, MI are 150g/10min); PO2 is APAO (Degussa 508); PO3 is polybutene (molecular weight is 3000); Tackifying resin 1 is petroleum resin (70 ℃ of softening temperatures); Tackifying resin 2 is terpine resin (90 ℃ of a softening temperature); Silane coupling agent is A151; Auxiliary agent comprises white oil, oxidation inhibitor (1010) and UV light stabilizing agent (Tinuvin 783), and three's ratio is 6: 3: 1.
Two, performance evaluation.
For comparing the halogen-free flameproof belt performance, adopt following testing method, estimated as UL94 testing vertical flammability, 180 ℃ of stripping strengths.
1, UL94 testing vertical flammability: carry out the VTM test by UL94 " the plastic material inflammability test of equipment and device component " standard, be divided into VTM-0, VTM-1, VTM-2 Three Estate.
2,180 ° of peeling strength tests of pressure-sensitive adhesive tape: undertaken by the GB/T2792-1998 standard.
The sealing tape sample that 20mm * 200mm is long is bonded on the PE test board, presses three times with the rod rollback on sample of rolling of 2Kg, and places after 30 minutes, and the 180 ° of directions in 23 ℃ of lower edges are peeled off with 300mm/min speed, the test stripping strength.
3, insulation paste adhesive tape disruptive strength testing experiment: the sample of getting gluing bandwidth 12mm, long 300mm is tested by the GB7752-87 standard.
Test the halogen-free flameproof adhesive tape of above nine embodiment, the result is as follows:
| Performance | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 | Embodiment 8 | Embodiment 9 |
| Bonding strength (N/m) | ??1220 | ??980 | ??1237 | ??830 | ??1030 | ??850 | ??930 | ??1060 | ??1180 |
| Flame retardant properties UL94 | ??V0 | ??V0 | ??V0 | ??V0 | ??V0 | ??V0 | ??V0 | ??V0 | ??V0 |
| Disruptive strength (V/m) | ??4.6 | ??4.7 | ??4.6 | ??4.1 | ??4.1 | ??4.3 | ??4.3 | ??/ | ??/ |
Claims (10)
1. a halogen-free flame-retardant hot-melt pressure sensitive adhesive tape has a base material, it is characterized in that, the one side at least of described base material goes up heat seeling coating one deck pressure sensitive adhesive, and described pressure sensitive adhesive is made up of the component of following weight part:
20～80 parts of polyolefin resines
10～60 parts of tackifier
5～30 parts of halogen-free flame retardantss
0～3 part of silane coupling agent
0.1～3 part of auxiliary agent.
2. a kind of halogen-free flame-retardant hot-melt pressure sensitive adhesive tape according to claim 1 is characterized in that, described polyolefin resin is any of polyethylene, polypropylene, atactic polyolefin, polybutene and ethylene copolymer, or their combinations of at least two kinds.
3. a kind of halogen-free flame-retardant hot-melt pressure sensitive adhesive tape according to claim 1, it is characterized in that described tackifier are the combination of any or they in terpenes, C5 petroleum resin, C5C9 copolymerized petroleum resin, hydrogenated petroleum resin, rosin, polymerized rosin, modified phenolic, the ester gum.
4. a kind of halogen-free flame-retardant hot-melt pressure sensitive adhesive tape according to claim 1, it is characterized in that, described halogen-free flame retardants is any in NP copolymerization fire retardant, micro encapsulation red phosphorus combustion inhibitor, metal hydroxide combustion inhibitor, polyphosphoric acid amine, trimeric cyanamide, Pentaerythritols, the silicon-series five-retardant, or their combinations of at least two kinds.
5. a kind of halogen-free flame-retardant hot-melt pressure sensitive adhesive tape according to claim 1, it is characterized in that described silane coupling agent is the combination of any or they in vinyl silicane coupling agent, amino silicane coupling agent, two amino silicane coupling agent, epoxy silane coupling, the phenylamino silane coupling agent.
6. a kind of halogen-free flame-retardant hot-melt pressure sensitive adhesive tape according to claim 1 is characterized in that, described base material is any in dry goods, plastics film class, expanded plastic class, paper tape and the tinsel.
7. a kind of halogen-free flame-retardant hot-melt pressure sensitive adhesive tape according to claim 1 is characterized in that the thickness of described base material is no less than 0.03 millimeter, and adds processing through fire retardant immersion treatment or fire retardant.
8. a kind of halogen-free flame-retardant hot-melt pressure sensitive adhesive tape according to claim 1 is characterized in that, on the upper and lower surface face of described base material respectively heat seeling coating one deck pressure sensitive adhesive is arranged.
9. the preparation method of a kind of halogen-free flame-retardant hot-melt pressure sensitive adhesive tape as claimed in claim 1 is characterized in that, is made up of following steps:
A, polyolefin resin and white oil are mixed, make polyolefin resin surface adhesion white oil, utilize high speed dispersor to mix with tackifier, halogen-free flame retardants, silane coupling agent and auxiliary agent then;
B, the mixture that A is gone on foot join in the extrusion coated machine, and in mixing under 120～190 ℃ the temperature condition and extrusion coated on the one side at least of base material, compound then separate-type paper promptly gets Pressuresensitive Tape.
10. preparation method according to claim 9 is characterized in that, described extrusion coated machine is the extrusion coated machine of twin screw.
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| CN 200910214043 CN101760145B (en) | 2009-12-22 | 2009-12-22 | Halogen-free flame-retardant hot-melt pressure sensitive adhesive tape and preparation method thereof |
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| CN 200910214043 CN101760145B (en) | 2009-12-22 | 2009-12-22 | Halogen-free flame-retardant hot-melt pressure sensitive adhesive tape and preparation method thereof |
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| CN102286257A (en) * | 2011-06-16 | 2011-12-21 | 上海邦中高分子材料有限公司 | Special high temperature resistant adhesive resins for steel-plastic composite pipe and preparation method thereof |
| CN103160222A (en) * | 2011-12-14 | 2013-06-19 | 常熟市新华化工有限公司 | Preparation method of electrical flame retardant adhesive tape |
| CN104817969A (en) * | 2015-04-23 | 2015-08-05 | 杜卫卫 | Stabilizer containing halogen-free flame-retardant hot-melt adhesive membrane for conductive fabric and preparation method of hot-melt adhesive membrane |
| CN105647444A (en) * | 2016-02-18 | 2016-06-08 | 河源市鑫达科技有限公司 | Special flame-retardant hot melt adhesive for aluminum-plastic panel and preparation method of hot melt adhesive |
| CN105647434A (en) * | 2016-02-02 | 2016-06-08 | 平湖展鹏热熔胶膜有限公司 | Hot-melt glue film for combining polypropylene cellular boards and preparing method of hot-melt glue film |
| CN106634703A (en) * | 2016-11-18 | 2017-05-10 | 安徽柳峰包装材料有限责任公司 | Flame-retardant hot-melt adhesive |
| CN106753052A (en) * | 2016-12-06 | 2017-05-31 | 佛山市高明区生产力促进中心 | A kind of modified flame-retardant plastic binder |
| CN107805465A (en) * | 2017-10-23 | 2018-03-16 | 江阴通利光电科技有限公司 | One kind can heavy industry non-woven fabrics non-flammable adhesive tape |
| CN108034375A (en) * | 2017-12-08 | 2018-05-15 | 江苏伊诺尔新材料科技有限公司 | Ultrathin fire-resistant adhesive tape |
| CN108753205A (en) * | 2018-06-28 | 2018-11-06 | 安徽尼古拉电子科技有限公司 | A kind of military project electronic component flame-retardant hot-melt adhesive and preparation method thereof |
| US10526515B2 (en) | 2014-12-30 | 2020-01-07 | 3M Innovative Properties Company | Halogen-free flame retardant pressure sensitive adhesive and tape |
| CN110951417A (en) * | 2018-09-26 | 2020-04-03 | 东莞市台煜塑胶科技有限公司 | Foaming hot melt adhesive and preparation process thereof |
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| CN1317529A (en) * | 2001-04-02 | 2001-10-17 | 广州市鹿山化工材料有限公司 | Adhesive for coating on steel pipe |
| CN1401721A (en) * | 2002-09-06 | 2003-03-12 | 广州市鹿山化工材料有限公司 | Hot-melt polyolefin adhesive and composite structure film using same |
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| CN102286257A (en) * | 2011-06-16 | 2011-12-21 | 上海邦中高分子材料有限公司 | Special high temperature resistant adhesive resins for steel-plastic composite pipe and preparation method thereof |
| CN103160222A (en) * | 2011-12-14 | 2013-06-19 | 常熟市新华化工有限公司 | Preparation method of electrical flame retardant adhesive tape |
| US10526515B2 (en) | 2014-12-30 | 2020-01-07 | 3M Innovative Properties Company | Halogen-free flame retardant pressure sensitive adhesive and tape |
| CN104817969A (en) * | 2015-04-23 | 2015-08-05 | 杜卫卫 | Stabilizer containing halogen-free flame-retardant hot-melt adhesive membrane for conductive fabric and preparation method of hot-melt adhesive membrane |
| CN105647434A (en) * | 2016-02-02 | 2016-06-08 | 平湖展鹏热熔胶膜有限公司 | Hot-melt glue film for combining polypropylene cellular boards and preparing method of hot-melt glue film |
| CN105647434B (en) * | 2016-02-02 | 2017-10-03 | 平湖展鹏热熔胶膜有限公司 | Compound hot melt adhesive film of polypropylene cellular board and preparation method thereof |
| CN105647444A (en) * | 2016-02-18 | 2016-06-08 | 河源市鑫达科技有限公司 | Special flame-retardant hot melt adhesive for aluminum-plastic panel and preparation method of hot melt adhesive |
| CN106634703A (en) * | 2016-11-18 | 2017-05-10 | 安徽柳峰包装材料有限责任公司 | Flame-retardant hot-melt adhesive |
| CN106753052A (en) * | 2016-12-06 | 2017-05-31 | 佛山市高明区生产力促进中心 | A kind of modified flame-retardant plastic binder |
| CN107805465A (en) * | 2017-10-23 | 2018-03-16 | 江阴通利光电科技有限公司 | One kind can heavy industry non-woven fabrics non-flammable adhesive tape |
| CN108034375A (en) * | 2017-12-08 | 2018-05-15 | 江苏伊诺尔新材料科技有限公司 | Ultrathin fire-resistant adhesive tape |
| CN108753205A (en) * | 2018-06-28 | 2018-11-06 | 安徽尼古拉电子科技有限公司 | A kind of military project electronic component flame-retardant hot-melt adhesive and preparation method thereof |
| CN110951417A (en) * | 2018-09-26 | 2020-04-03 | 东莞市台煜塑胶科技有限公司 | Foaming hot melt adhesive and preparation process thereof |
| CN114058101A (en) * | 2021-10-25 | 2022-02-18 | 广东金发科技有限公司 | PE-based flame-retardant laminating film material and preparation method and application thereof |
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Effective date of registration: 20201106 Address after: 510700 No.22, Pubei Road, YUNPU Industrial Zone, Huangpu District, Guangzhou City, Guangdong Province Patentee after: GUANGZHOU LUSHAN NEW MATERIALS Co.,Ltd. Patentee after: Jiangsu Lushan New Material Co.,Ltd. Address before: 510530, 22, Po Bei Road, Dongcheng Po Po Industrial Zone, Whampoa District, Guangdong, Guangzhou Patentee before: GUANGZHOU LUSHAN NEW MATERIALS Co.,Ltd. |