CN101743995A - Efficiency glyphosate herbicidal composition - Google Patents
Efficiency glyphosate herbicidal composition Download PDFInfo
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- CN101743995A CN101743995A CN200910261173A CN200910261173A CN101743995A CN 101743995 A CN101743995 A CN 101743995A CN 200910261173 A CN200910261173 A CN 200910261173A CN 200910261173 A CN200910261173 A CN 200910261173A CN 101743995 A CN101743995 A CN 101743995A
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Abstract
The invention discloses an efficiency glyphosate herbicidal composition and a preparation method of dispersible granules, soluble powder and an aqueous solution thereof. The invention is characterized in that the efficiency glyphosate herbicidal composition contains ethylene with a weight percentage of 0.1-20%. Compared with glyphosate used alone, the composition can significantly enhance the herbicidal activity of the glyphosate, reduce the amount of the glyphosate and improve the use efficiency.
Description
Technical field
The present invention relates to a kind of Synergistic herbicide compositions, particularly contain the synergistic composition of glyphosate.
Background technology
Glyphosate (glyphosate), formal name used at school N-((phosphonomethyl)) glycine, N-((phosphonomethyl)) amion acetic acid (Phosphonomethyl Imino Acetic Acid) is a kind of organophosphorus herbicide by the exploitation of U.S. Monsanto Company.Glyphosate absorbs by plant leaf blade and non-woody cauline leaf as non-selective, noresidue herbicide after seedling, conducts to the plant corpus each several part.Very effective to dark root perennial weed and annual and biennial grass family, sedge family and broad leaved weed.The most outstanding characteristics of glyphosate are in can being conducted to underground rhizome downwards and be tillered by the cauline leaf absorption, and are extremely strong to weeds underground organization destructive power.It kills grassland reason mainly is by suppressing the activity of enol acetonyl shikimene phosphate synthase, destroy the conversion of shikimene to phenyl alanine, tyrosine, tryptophan, thereby protein synthesis is interfered and causes plant death.Ethrel is high-quality and efficient plant growth regulator as the agricultural plant growth stimulant, has the promotion fruit maturation, stimulates bleeding, regulates effects such as sex conversion.Ethrel enters in the plant corpus through blade, bark, the fruits and seeds of plant, is transmitted to the position of working, and just discharges ethene, can play the physiological action of endogenous hormones ethene, promotes fruit maturation, induces flower bud differentiation, fruit abscission etc. at once.Also there be not at present the relevant report of ethrel to the synergistic effect of glyphosate.
Summary of the invention
But the object of the present invention is to provide a kind of preparation method who has the glyphosate composition of notable synergistic effect and introduce its dispersible granule, soluble powder and aqua.Ethrel can discharge ethene in plant corpus, the physiological action that plays endogenous hormones ethene also can flow by the bleeding in the stimulating plant body when plant changes vegetative period over to from resting stage.For the glyphosate herbicidal of inhaling conduction in having, the acceleration that bleeding flows in the plant body helps to accelerate glyphosate and conducts in plant corpus.
By a large amount of biologicall test experiments, the researcher finds that this glyphosate and ethrel combination can obviously promote glyphosate and kill careless speed and effect.
The researcher also makes the composition of glyphosate and ethrel water dispersible granules, soluble powder and three kinds of formulations of aqua, and has carried out the comparative efficacy test with the agent of glyphosate list.
When the composition of glyphosate and ethrel was made water dispersible granules, wherein each composition weight proportioning was: glyphosate 1%--80%, ethrel 0.1%--20%, surfactant 5%--10%, disintegrant 1%--5%, carrier 10%--80%.Surfactant is one or more in lignosulfonates, lauryl sodium sulfate, fatty acid sulphate, aliphatic alcohol polyethenoxy, nekal, the dodecyl polyoxyethylene ether phosphate.Disintegrant is one or more in bentonite, ammonium sulfate, urea, the magnesium sulfate.Carrier is a kind of in algae soil, kaolin, white carbon, the nacrite.
When the composition of glyphosate and ethrel was made soluble powder, wherein each composition weight proportioning was: glyphosate 1%--80%, ethrel 0.1%-20%, surfactant 5%--15%, carrier 10%--80%.Surfactant is lignosulfonates, lauryl sodium sulfate, fatty acid sulphate, aliphatic alcohol polyethenoxy, nekal, benzylphenol APEO, alkylphenol polyoxyethylene, draw back in the powder one or more.Carrier is a kind of in ammonium sulfate, potassium sulphate, the ammonium chloride.
When the composition of glyphosate and ethrel was made aqua, wherein each composition weight proportioning was: glyphosate 1%--80%, ethrel 0.1%-20%, surfactant 5%--15%.Surfactant is one or more in benzylphenol APEO, alkylphenol polyoxyethylene, the aliphatic alcohol polyethenoxy.
Compare with the agent of glyphosate list, the present invention has following advantage:
1. herbicide effect is more rapid, and the glyphosate drug effect was brought into play than the fast 48--72 of single glyphosate formulation hour.
2. reduce glyphosate unit are consumption 20%--40%, help economizing on resources and protecting environment.
3. be applied to genetically modified crops, can obviously promote plant growth.
Embodiment
In order to make purpose of the present invention, technical scheme and advantage clearer, the present invention describes with following specific embodiment, but the present invention is limited to these examples absolutely not.The following stated only is the present invention embodiment preferably, only is used to explain the present invention, can not therefore be interpreted as the restriction to claim of the present invention.Should be pointed out that all any modifications of being made within the spirit and principles in the present invention, be equal to replacement and improvement etc., all should be included within protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with appended claims.
The percentage composition that relates among the embodiment is weight percentage.
The preparation method of embodiment 1 60% glyphosate ethrel water dispersible granules
Glyphosate 60%
Ethrel 0.5%
Sodium lignin sulfonate (dispersant) 6%
Benzylphenol APEO (surfactant) 3%
Urea (disintegrant) 4%
Diatomite (filler) supplies 100%
Said mixture is evenly mixed, and comminution by gas stream adds suitable quantity of water and mediates, and the mixture pelleting of gained, is drying to obtain product.
The 60% glyphosate ethrel water dispersible granules that makes and regular convention formula 60% glyphosate water dispersible granules (glyphosate 60% sodium lignin sulfonate 6% benzylphenol APEO 3% urea 5% diatomite supplies 100%) are carried out the biological test of pesticide effectiveness in field to be compared as follows:
Behind preceding stubble paddy rice harvesting, medication in 5-7 days before the stubble rice transplanting of back drained Tanaka's water after 2-3 days before the medication, convert 20 kilograms of sprayings of water for every mu, then transplanting rice after water conservation 3-5 days.Not dispenser of blank, not weeding.After the dispenser transplanting rice being carried out conventional cultivation handles.The upgrowth situation of 2,5 days range estimation weeds after the medication, each weeds kind and quantity of handling of observation in 15 days behind the transplanting rice.The computational analysis method of drug effect is as follows:
* 100% is counted in strain preventive effect=(check plot weeds strain number-treatment region weeds strain number)/check plot weeds strain
Calculate respectively and respectively handle the herbicidal effect of sub-district.
Handle 160% glyphosate ethrel water dispersible granules 150g/ mu
Handle 260% glyphosate ethrel water dispersible granules 125g/ mu
Handle 360% glyphosate water dispersible granules 200g/ mu
Not weeding of not dispenser of blank
15 days strain preventive effects relatively behind table 1 transplanting rice
The preparation method of embodiment 230% glyphosate ethrel soluble powder
Ammonium glyphosate 33.5% (weight)
Ethrel 5% (weight)
Neopelex 5% (weight)
Fatty alcohol-polyoxyethylene ether 7% (weight)
Ammonium sulfate supplies 100%
Mentioned component is mixed, behind comminution by gas stream, promptly get product.
To appeal preparation and regular convention formula 30% soluble glyphosate pulvis (ammonium glyphosate 33.5% lauryl sodium sulfate 5% fatty alcohol-polyoxyethylene ether 7% ammonium sulfate 100%) carries out the biological test of pesticide effectiveness in field and is compared as follows:
Behind preceding stubble paddy rice harvesting, medication in 5-7 days before the stubble rice transplanting of back drained Tanaka's water after 2-3 days before the medication, convert 10 kilograms of sprayings of water for every mu, then transplanting rice after water conservation 3-5 days.Not dispenser of blank, not weeding.After the dispenser transplanting rice being carried out conventional cultivation handles.The upgrowth situation of 2,5 days range estimation weeds after the medication, each weeds kind and quantity of handling of observation in 15 days behind the transplanting rice.The computational analysis method of drug effect is as follows;
* 100% is counted in strain preventive effect=(check plot weeds strain number-treatment region weeds strain number)/check plot weeds strain
Calculate respectively and respectively handle the herbicidal effect of sub-district.
Handle 130% glyphosate ethrel soluble powder 300g/ mu
Handle 230% glyphosate ethrel soluble powder 250g/ mu
Handle 330% soluble glyphosate pulvis 400g/ mu
Not weeding of not dispenser of blank
15 days strain preventive effects relatively behind table 2 transplanting rice
The preparation method of embodiment 3 30% glyphosate ethephon agents
Glyphosate isopropyl amine salt 41% (weight)
Ethrel 10% (weight)
Alkylphenol polyoxyethylene 6% (weight)
Fatty alcohol-polyoxyethylene ether 5% (weight)
Water supplies 100%
Mentioned component dissolved to stir in water promptly get product.
To appeal preparation and regular convention formula 30% gyphosate solution (glyphosate isopropyl ammonium salt 41% alkylphenol polyoxyethylene 7% fatty alcohol-polyoxyethylene ether 6% water supplies 100%) carries out the biological test of pesticide effectiveness in field and is compared as follows:
Behind preceding stubble paddy rice harvesting, medication in 5-7 days before the stubble rice transplanting of back drained Tanaka's water after 2-3 days before the medication, convert 10 kilograms of sprayings of water for every mu, then transplanting rice after water conservation 3-5 days.Not dispenser of blank, not weeding.After the dispenser transplanting rice being carried out conventional cultivation handles.The upgrowth situation of 2,5 days range estimation weeds after the medication, each weeds kind and quantity of handling of observation in 15 days behind the transplanting rice.The computational analysis method of drug effect is as follows;
* 100% is counted in strain preventive effect=(check plot weeds strain number-treatment region weeds strain number)/check plot weeds strain
Calculate respectively and respectively handle the herbicidal effect of sub-district.
Handle 130% glyphosate ethephon agent 300g/ mu
Handle 230% glyphosate ethephon agent 250g/ mu
Handle 330% gyphosate solution 400g/ mu
Not weeding of not dispenser of blank
15 days strain preventive effects relatively behind table 3 transplanting rice
Claims (9)
1. a Gyphosate herbicice composition is characterized in that: contain the 0.1%--20% ethrel in the quality percentage composition.
2. according to claim 1, it is characterized in that: the glyphosate in the composition is glyphosate, ammonium glyphosate, glyphosate potassium, glyphosate isopropyl amine salt or other organic salt, and content is 1%--80%.
3. according to claim 1, it is characterized in that: composition can be made into water dispersible granules, soluble powder or aqua.
4. according to claim 3, it is characterized in that: when composition is made water dispersible granules, contain glyphosate or salt 1%--80%, ethrel 0.1%--20%, surfactant 5%--10%, disintegrant 1%--5% and carrier by weight percentage and complement to 100%.
5. according to claim 4, it is characterized in that: described surfactant comprises one or more in lignosulfonates, lauryl sodium sulfate, fatty acid sulphate, aliphatic alcohol polyethenoxy, nekal, the dodecyl polyoxyethylene ether phosphate; Described disintegrant comprises one or more in bentonite, ammonium sulfate, urea, the magnesium sulfate; Described carrier comprises a kind of in diatomite, kaolin, white carbon, the nacrite.
6. according to claim 3, it is characterized in that: when composition is made soluble powder, contain glyphosate or salt 1%--80%, ethrel 0.1%--20%, surfactant 5%--15% and carrier by weight percentage and complement to 100%.
7. according to claim 6, it is characterized in that: described surfactant comprises lignosulfonates, lauryl sodium sulfate, fatty acid sulphate, aliphatic alcohol polyethenoxy, nekal, benzylphenol APEO, alkylphenol polyoxyethylene, draw back in the powder one or more; Described carrier is one or more in ammonium sulfate, potassium sulphate, the ammonium chloride.
8. according to claim 3, it is characterized in that: when composition is made aqua, it is characterized in that: the water that contains glyphosate or salt 1%--80%, ethrel 0.1%--20%, surfactant agent 5%--15% and surplus by weight percentage.
9. it is characterized in that according to Claim 8: described surfactant comprises one or more in benzylphenol APEO, alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, alkyl glycoside, tallow amine ethyl group thing, Tea Saponin, cocoa butter amide compound, the organosilicon.
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| Application Number | Priority Date | Filing Date | Title |
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| CN200910261173A CN101743995A (en) | 2009-12-23 | 2009-12-23 | Efficiency glyphosate herbicidal composition |
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| CN200910261173A CN101743995A (en) | 2009-12-23 | 2009-12-23 | Efficiency glyphosate herbicidal composition |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102027990A (en) * | 2010-11-11 | 2011-04-27 | 河北科技大学 | Composite ethephon preparation used for spraying and accelerating maturation of vegetables and fruits |
| CN102578140A (en) * | 2012-01-05 | 2012-07-18 | 南京登博生物科技有限公司 | Plant growth and development inhibitor and application thereof |
| CN102972434A (en) * | 2011-09-02 | 2013-03-20 | 深圳诺普信农化股份有限公司 | Glufosinate-ammonium weeding composition |
| CN103858863A (en) * | 2014-02-14 | 2014-06-18 | 南京善为生物科技有限公司 | Environmental-friendly thiamethoxam water-soluble powder and preparation method thereof |
| CN104604932A (en) * | 2015-02-11 | 2015-05-13 | 南通江山农药化工股份有限公司 | Glyphosate potassium salt preparation and forming equipment thereof |
| CN106172481A (en) * | 2016-07-14 | 2016-12-07 | 南京农业大学 | A kind of plant seed developmental inhibitors for controlling weeds and application thereof |
| CN109042719A (en) * | 2018-06-07 | 2018-12-21 | 安阳工学院 | A kind of Gyphosate herbicice synergist containing ethephon (CEPHA),2-(chloroethyl) phosphonic acid and the glyphosate-class herbicides containing the synergist |
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| CN101558762A (en) * | 2008-04-16 | 2009-10-21 | 孙忠富 | Cotton early-maturity antifrosting litter boll opening agent |
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2009
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101558762A (en) * | 2008-04-16 | 2009-10-21 | 孙忠富 | Cotton early-maturity antifrosting litter boll opening agent |
Non-Patent Citations (2)
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| 朱金文等: "6种植物生长调节剂对草甘膦生物活性的影响", 《上海交通大学学报（农业科学版）》 * |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102027990A (en) * | 2010-11-11 | 2011-04-27 | 河北科技大学 | Composite ethephon preparation used for spraying and accelerating maturation of vegetables and fruits |
| CN102972434A (en) * | 2011-09-02 | 2013-03-20 | 深圳诺普信农化股份有限公司 | Glufosinate-ammonium weeding composition |
| CN102578140A (en) * | 2012-01-05 | 2012-07-18 | 南京登博生物科技有限公司 | Plant growth and development inhibitor and application thereof |
| CN103858863A (en) * | 2014-02-14 | 2014-06-18 | 南京善为生物科技有限公司 | Environmental-friendly thiamethoxam water-soluble powder and preparation method thereof |
| CN103858863B (en) * | 2014-02-14 | 2016-09-21 | 南京善思生物科技有限公司 | A kind of environmentally friendly Diacloden water solube powder and preparation method thereof |
| CN104604932A (en) * | 2015-02-11 | 2015-05-13 | 南通江山农药化工股份有限公司 | Glyphosate potassium salt preparation and forming equipment thereof |
| CN104604932B (en) * | 2015-02-11 | 2016-08-24 | 南通江山农药化工股份有限公司 | Glyphosate potassium salt pref and former thereof |
| CN106172481A (en) * | 2016-07-14 | 2016-12-07 | 南京农业大学 | A kind of plant seed developmental inhibitors for controlling weeds and application thereof |
| CN106172481B (en) * | 2016-07-14 | 2019-09-20 | 南京农业大学 | It is a kind of for the vegetable seeds developmental inhibitors of controlling weeds and its application |
| CN109042719A (en) * | 2018-06-07 | 2018-12-21 | 安阳工学院 | A kind of Gyphosate herbicice synergist containing ethephon (CEPHA),2-(chloroethyl) phosphonic acid and the glyphosate-class herbicides containing the synergist |
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Application publication date: 20100623 |