CN101736584A - Preparation method of anti-bacteria non-woven fabric and antibacterial agent - Google Patents
Preparation method of anti-bacteria non-woven fabric and antibacterial agent Download PDFInfo
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- CN101736584A CN101736584A CN200910259701A CN200910259701A CN101736584A CN 101736584 A CN101736584 A CN 101736584A CN 200910259701 A CN200910259701 A CN 200910259701A CN 200910259701 A CN200910259701 A CN 200910259701A CN 101736584 A CN101736584 A CN 101736584A
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Abstract
The invention discloses a preparation method of an anti-bacteria non-woven fabric and an antibacterial agent. The anti-bacteria non-woven fabric is prepared by comprising the steps of: dissolving chitosan by using lactic acid to prepare the chitosan solution; dissolving zinc lactate in deionized water to prepare the zinc lactate solution; mixing the chitosan solution with the zinc lactate solution to prepare the antibacterial agent; and modifying a non-woven fabric in an antibacterial way: adding the antibacterial agent on the non-woven fabric, drying to prepare the anti-bacteria non-woven fabric. According to the second part of antibacterial performance of fabrics in GB/T20944.2-2007, the anti-bacteria non-woven fabric prepared by the invention has bacterial inhibiting ratio more than 99 percent through absorptive method detection, is qualified through skin irritation and vagina mucosa irritation and skin allergic reaction irritation tests, and meets sanitation requirements on sanitation standard GB15980-1995 of disposable medical supplies and sanitation standard GB15979-2002 of disposable hygienic products.
Description
[technical field]
The present invention relates to the manufacture method of a kind of antibacterial non-woven and antiseptic.
[background technology]
At present, antibacterial non-woven is various in style, many products its antibacterial effect that covets, and ignored its harmfulness to human body and environment.
Publication number is that wherein divalent zinc ion comes from zinc sulphate hydrate, zinc acetate, zinc chloride, zinc nitrate in the Chinese patent application " preparation method of shitosan/zinc compound bactericide " of CN100360035C; Use spirit of vinegar dissolving shitosan.Wherein, zinc nitrate is corrosive.At high temperature decomposing to produce to have stimulates and hypertoxic oxides of nitrogen gas, sucks to cause poisoning.Zinc chloride toxicity is very strong, can severe irritation and burn skin and mucous membrane.Zinc acetate has harm to environment, and rabbit skin irritation test slightly stimulates.Zinc sulfate has spread effect to stomach, and environment is had harm.Acetic acid belongs to the lower toxicity material, and penetrating odor is arranged, and is very big to skin irritation.Acetic acid acidity is bigger, and behind the dissolving shitosan, the pH value of solution value is lower than 4.5, and mixed solution needs could use behind the adjust pH.In sum, zinc chloride, zinc nitrate toxicity are bigger, and zinc sulfate, zinc acetate all have harm to environment, if use the antiseptic of above-mentioned zinc salt for main antimicrobial component, can spread effect be arranged to human body, and environment is had certain harm.
In the preparation method of above-mentioned shitosan/zinc compound bactericide, make the chitosan-zn complex solution after, still can't use.The acetone and the ethanol that need further to add capacity obtain white precipitate, and with the ethanol washing, grind into powder is used dissolving with hydrochloric acid, the NaOH adjust pH, and just can use after the high-temperature sterilization.This process cost height, complex process, practicality is relatively poor.
Chitin is a kind of natural polysaccharide that extracts from the crust of shellfishs such as shrimp, crab, also is that nature is only second to cellulosic second largest living resources.Shitosan is the deacetylated derivative of chitin; have excellent biological compatibility, biodegradability, Nantural non-toxic and multiple biologically active; especially broad spectrum antibacterial; and owing on its strand a lot of amino, hydroxyl isoreactivity group are arranged; have very high reactivity, and be easy to transition metal ions generation complex reaction.In recent years, shitosan has been subjected to people's extensive concern as a kind of natural antibacterial agent.But the antibacterial activity of comparing shitosan with traditional antiseptic is lower, and is by the antibacterial activity of methods such as modification, blend raising shitosan, most important as the application of antiseptic for shitosan.Though by can improve the antibacterial activity of shitosan to a certain extent to the derivatization treatment of shitosan, but effect is also not obvious, still can't satisfy its application demand, and the derivatization process complexity of shitosan, severe reaction conditions is unfavorable for large-scale production.Metal ion has stronger antibacterial activity as traditional antiseptic, but its bio-toxicity can not satisfy the requirement of the green non-poisonous product of current development.Now, the most frequently used metal ion comprises silver ion, zinc ion and copper ion.The silver ion antimicrobial agent cost is higher, and the potential risk of oxidation blackening is arranged." ecological textile specification requirement " GB/T18885-2002 and " the general and special technical requirement of ecological textile " Oeko-Tex100-2002 have strictness to limit the quantity of to copper ion.
[summary of the invention]
Main purpose of the present invention is: provide a kind of environmental-protecting performance better, to the more friendly antiseptic of human body and environment and the preparation method of antibacterial non-woven.
For achieving the above object, the present invention proposes a kind of preparation method of antiseptic, comprise the steps:
Preparation chitosan solution: use the lactic acid dissolution shitosan, make chitosan solution;
Preparation zinc lactate solution: zinc lactate is dissolved in the deionized water system zinc lactate solution;
Mix: chitosan solution is mixed with zinc lactate solution, obtain antiseptic.
Simultaneously, the present invention proposes a kind of preparation method of antibacterial nonwoven cloth, comprise the steps:
Preparation chitosan solution: use the lactic acid dissolution shitosan, make chitosan solution;
Preparation zinc lactate solution: zinc lactate is dissolved in the deionized water system zinc lactate solution;
Preparation antiseptic: chitosan solution is mixed with zinc lactate solution, make antiseptic;
Non-weaving cloth is antibacterial modified: antiseptic is added on the non-weaving cloth, and oven dry makes antibacterial non-woven.
Above-mentioned preparation method of antibacterial nonwoven cloth, in the embodiment wherein, the detailed process of preparation chitosan solution comprises: shitosan is dried, cool off standby; With the cooled shitosan of lactic acid dissolution, be heated to it is dissolved fully, make chitosan solution.
Above-mentioned preparation method of antibacterial nonwoven cloth, in the embodiment wherein, the detailed process of preparation zinc lactate solution comprises: zinc lactate is dissolved in the deionized water, and heating makes its whole dissolvings, makes 2.97-7.42% (m/v) zinc lactate solution.
Above-mentioned preparation method of antibacterial nonwoven cloth, in the embodiment wherein, the detailed process of described preparation antiseptic comprises: with chitosan solution and zinc lactate solution, mix by 1: 10 (v/v).And according to product purpose interpolation surfactant.
Above-mentioned preparation method of antibacterial nonwoven cloth, in the embodiment wherein, the antibacterial modified detailed process of non-weaving cloth comprises: in the finishing process of non-weaving cloth, with padding method or spray-on process or other method for sorting antiseptic is added on the non-weaving cloth, last liquid rate is 10-150% (m/m), oven dry makes antibacterial non-woven.
Above-mentioned preparation method of antibacterial nonwoven cloth in the embodiment wherein, in the process of described preparation chitosan solution, adopts 0.3% (v/v) lactic acid dissolution shitosan.
Above-mentioned preparation method of antibacterial nonwoven cloth, in the embodiment wherein, described shitosan is dried 4-6h in 105 ℃ of baking ovens, its deacetylation 〉=90%, molecular weight ranges 100,000-300,000.
Above-mentioned preparation method of antibacterial nonwoven cloth, in the embodiment wherein, described chitosan solution concentration is 0.5-2% (m/v).
Above-mentioned preparation method of antibacterial nonwoven cloth, in the embodiment wherein, described zinc lactate is the food-grade zinc lactate, purity 〉=98%.
The antibacterial non-woven that the present invention makes, according to the evaluation-part 2 of GB/T20944.2-2007 textiles-anti-microbial property: absorption process detects, bacteriostasis rate＞99%; Skin irritation, vaginal mucosa irritation, skin allergic reaction test are up to the standards; Satisfy disposable use amenities sanitary standard GB15979-2002, the hygienic requirements of disposable use medical supplies sanitary standard GB15980-1995 is applicable to medical and high-grade health products such as doing antibacterial mask, medical dressing, sanitary napkin, paper diaper, wet sanitary napkins.
The zinc lactate that the present invention uses has no stimulation to human body, and environment is not had harm.Its security is better than other zinc salts such as above-mentioned zinc sulfate, zinc acetate, zinc chloride and zinc nitrate.
The present invention is with 0.3% (v/v) lactic acid dissolution shitosan.The nontoxic odorlessness of lactic acid, very little to skin irritation, and acid little.With after zinc lactate solution mixes, the pH of mixed value is 5.5-5.9 with the chitosan solution of 0.3% (v/v) lactic acid dissolution, and mixed solution need not adjust pH again.
The chitosan-zn complex solution that the present invention makes behind the suitable a certain proportion of surfactant of adding of product purpose such as hydrophilic finish, hydrophobic finish etc., can directly use, and cost is low, and is practical.
Raw material and solvent safety that the present invention uses are non-stimulated, and raw material consumption and antiseptic concentration are minimized cost under the prerequisite that guarantees good antibiotic property, well balance security of products, antibiotic property and economy.
[specific embodiment]
The present invention is described in further detail below by specific embodiment.
Embodiment one:
Take by weighing 1g chitin powder, 105 ℃ of oven for drying 4h cool off standby.With 0.3% (v/v) lactic acid 100mL, be heated to 76 ℃ with 1g chitin powder dissolution, filter and obtain 1% (m/v) chitin solution.Take by weighing 2.97g food-grade zinc lactate, be dissolved in 100mL water, be heated to 90 ℃, make its whole dissolvings, obtain 2.97% (m/v) zinc lactate solution.1% chitin solution and 2.97% zinc lactate solution mixed by 1: 10.Add the hydrophilic finish of 1% (v/v), obtain antiseptic.In finishing process, making the last liquid rate of non-weaving cloth with padding method is 150% (m/m), and oven dry promptly gets antibacterial non-woven.In the last liquid rate, m/m represents that quality than quality, refers to the ratio of antiseptic quality and cloth quality.
Embodiment two:
1kg chitin powder, 105 ℃ of oven for drying 5h cool off standby.With 0.3% (v/v) lactic acid 100L, be heated to 90 ℃ with 1kg chitin powder dissolution, filter and obtain 1% (m/v) chitin solution.59.4kg zinc lactate is dissolved in 1m
3In the water, be heated to 90 ℃ and make its whole dissolvings, the cooling back adds the 1% chitin solution mixing that 100L prepares, and adds the hydrophilic finish mixing of 10L, promptly obtains antimicrobial.Suitably add some essence and regulate smell.In finishing process, making the last liquid rate of non-weaving cloth with padding method is 50% (m/m), and oven dry promptly gets antibacterial non-woven.
Embodiment three:
1kg chitin powder, 105 ℃ of oven for drying 6h cool off standby.With 0.3% (v/v) lactic acid 100L, be heated to 90 ℃ with 1kg chitin powder dissolution, filter and obtain 1% (m/v) chitin solution.74.2kg zinc lactate is dissolved in 1m
3In the water, be heated to 92 ℃ and make its whole dissolvings, the cooling back adds 1% (m/v) chitin solution mixing that 100L prepares, and adds 10L and refuses water finish mixing, promptly obtains antimicrobial.In finishing process, making the last liquid rate of non-weaving cloth with spray-on process is 10% (m/m), and oven dry promptly gets antibacterial non-woven.
Above content be in conjunction with concrete preferred implementation to further describing that the present invention did, can not assert that concrete enforcement of the present invention is confined to these explanations.For the general technical staff of the technical field of the invention, without departing from the inventive concept of the premise, can also make some simple deduction or replace, all should be considered as belonging to protection scope of the present invention.
Claims (10)
1. a preparation method of antibacterial nonwoven cloth comprises the steps:
Preparation chitosan solution: use the lactic acid dissolution shitosan, make chitosan solution;
Preparation zinc lactate solution: zinc lactate is dissolved in the deionized water system zinc lactate solution;
Preparation antiseptic: chitosan solution is mixed with zinc lactate solution, make antiseptic;
Non-weaving cloth is antibacterial modified: antiseptic is added on the non-weaving cloth, and oven dry makes antibacterial non-woven.
2. preparation method of antibacterial nonwoven cloth as claimed in claim 1 is characterized in that: the detailed process of preparation chitosan solution comprises: shitosan is dried, cool off standby; With the cooled shitosan of lactic acid dissolution, be heated to it is dissolved fully, make chitosan solution.
3. preparation method of antibacterial nonwoven cloth as claimed in claim 1 is characterized in that: the detailed process of preparation zinc lactate solution comprises: zinc lactate is dissolved in the deionized water, and heating makes its whole dissolvings, makes 2.97-7.42% (m/v) zinc lactate solution.
4. preparation method of antibacterial nonwoven cloth as claimed in claim 1 is characterized in that: the detailed process of described preparation antiseptic comprises: with chitosan solution and zinc lactate solution, mix by 1: 10 (v/v), and add surfactant according to product purpose.
5. preparation method of antibacterial nonwoven cloth as claimed in claim 1, it is characterized in that: the antibacterial modified detailed process of non-weaving cloth comprises: in the finishing process of non-weaving cloth, with padding method or spray-on process or other method for sorting antiseptic is added on the non-weaving cloth, last liquid rate is 10-150% (m/m), oven dry makes antibacterial non-woven.
6. preparation method of antibacterial nonwoven cloth as claimed in claim 2 is characterized in that: in the process of described preparation chitosan solution, adopt 0.3% (v/v) lactic acid dissolution shitosan.
7. preparation method of antibacterial nonwoven cloth as claimed in claim 2 is characterized in that: described shitosan is dried 4-6h in 105 ℃ of baking ovens, its deacetylation 〉=90%, molecular weight ranges 100,000-300,000.
8. as claim 2 or 4 described preparation method of antibacterial nonwoven cloth, it is characterized in that: described chitosan solution concentration is 0.5-2% (m/v).
9. preparation method of antibacterial nonwoven cloth as claimed in claim 3 is characterized in that: described zinc lactate is the food-grade zinc lactate, purity 〉=98%.
10. the preparation method of an antiseptic comprises the steps:
Preparation chitosan solution: use the lactic acid dissolution shitosan, make chitosan solution;
Preparation zinc lactate solution: zinc lactate is dissolved in the deionized water system zinc lactate solution;
Mix: chitosan solution is mixed with zinc lactate solution, obtain antiseptic.
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| CN2009102597016A CN101736584B (en) | 2009-12-23 | 2009-12-23 | Preparation method of anti-bacteria non-woven fabric and antibacterial agent |
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| CN2009102597016A CN101736584B (en) | 2009-12-23 | 2009-12-23 | Preparation method of anti-bacteria non-woven fabric and antibacterial agent |
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| CN101736584B CN101736584B (en) | 2012-03-07 |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101914851A (en) * | 2010-08-02 | 2010-12-15 | 孙伟 | Antibacterial agent and preparation method of antibacterial nonwoven cloth |
| CN103147305A (en) * | 2013-03-26 | 2013-06-12 | 无锡嘉德纺织制品有限公司 | Chitin composite textile auxiliary and preparation method thereof |
| CN103334306A (en) * | 2013-05-18 | 2013-10-02 | 安徽工程大学 | Silver-carrying chitosan composite antibacterial agent, preparation method of the silver-carrying chitosan composite antibacterial agent, and fabric compounding finishing method |
| CN104452289A (en) * | 2014-12-23 | 2015-03-25 | 常熟市华博毛纺织有限公司 | Finishing process of shirt fabric |
| CN104499356A (en) * | 2014-12-04 | 2015-04-08 | 成都顺发消洗科技有限公司 | Plant-type fruit cleaning wet tissue for removal of pesticide residues |
| CN106345311A (en) * | 2016-09-19 | 2017-01-25 | 江苏海纳空调净化设备有限公司 | Antibacterial non-woven filter film and weaving process thereof |
| CN106521947A (en) * | 2016-09-19 | 2017-03-22 | 江苏海纳空调净化设备有限公司 | Non-woven filter cloth for air conditioner |
| CN107456321A (en) * | 2017-09-19 | 2017-12-12 | 安徽省银锂子生物科技发展有限公司 | A kind of nanometer silver antimicrobial sanitary napkin and its production method |
| CN108396558A (en) * | 2018-04-16 | 2018-08-14 | 佛山市尚柏科技有限公司 | A kind of weaving antibacterial finishing agent and its application |
| CN109303050A (en) * | 2018-07-26 | 2019-02-05 | 合肥华盖生物科技有限公司 | A kind of high temperature resistant type complex antimicrobials and preparation method thereof |
| CN109609590A (en) * | 2018-12-21 | 2019-04-12 | 扬州倍加洁日化有限公司 | A kind of anti-microbial property test method of wet tissue product |
| CN110638359A (en) * | 2019-11-11 | 2020-01-03 | 苏州宝丽洁日化有限公司 | Preparation method of wet tissue without antibacterial agent residue on skin after use |
| CN114158568A (en) * | 2021-11-12 | 2022-03-11 | 兴业皮革科技股份有限公司 | Composite antibacterial agent and preparation method and application thereof |
| WO2023101569A1 (en) * | 2021-12-03 | 2023-06-08 | Biovalley Spółdzielnia Socjalna | Method for obtaining antimicrobially active nonwoven fabric |
-
2009
- 2009-12-23 CN CN2009102597016A patent/CN101736584B/en active Active
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101914851A (en) * | 2010-08-02 | 2010-12-15 | 孙伟 | Antibacterial agent and preparation method of antibacterial nonwoven cloth |
| CN103147305A (en) * | 2013-03-26 | 2013-06-12 | 无锡嘉德纺织制品有限公司 | Chitin composite textile auxiliary and preparation method thereof |
| CN103334306A (en) * | 2013-05-18 | 2013-10-02 | 安徽工程大学 | Silver-carrying chitosan composite antibacterial agent, preparation method of the silver-carrying chitosan composite antibacterial agent, and fabric compounding finishing method |
| CN104499356A (en) * | 2014-12-04 | 2015-04-08 | 成都顺发消洗科技有限公司 | Plant-type fruit cleaning wet tissue for removal of pesticide residues |
| CN104499356B (en) * | 2014-12-04 | 2016-08-31 | 成都顺发消洗科技有限公司 | A kind of plant type is dispelled pesticide residues fruit washing wet tissue |
| CN104452289A (en) * | 2014-12-23 | 2015-03-25 | 常熟市华博毛纺织有限公司 | Finishing process of shirt fabric |
| CN106345311A (en) * | 2016-09-19 | 2017-01-25 | 江苏海纳空调净化设备有限公司 | Antibacterial non-woven filter film and weaving process thereof |
| CN106521947A (en) * | 2016-09-19 | 2017-03-22 | 江苏海纳空调净化设备有限公司 | Non-woven filter cloth for air conditioner |
| CN107456321A (en) * | 2017-09-19 | 2017-12-12 | 安徽省银锂子生物科技发展有限公司 | A kind of nanometer silver antimicrobial sanitary napkin and its production method |
| CN107456321B (en) * | 2017-09-19 | 2018-12-25 | 安徽省银锂子生物科技发展有限公司 | A kind of nanometer silver antimicrobial sanitary napkin and its production method |
| CN108396558A (en) * | 2018-04-16 | 2018-08-14 | 佛山市尚柏科技有限公司 | A kind of weaving antibacterial finishing agent and its application |
| CN109303050A (en) * | 2018-07-26 | 2019-02-05 | 合肥华盖生物科技有限公司 | A kind of high temperature resistant type complex antimicrobials and preparation method thereof |
| CN109609590A (en) * | 2018-12-21 | 2019-04-12 | 扬州倍加洁日化有限公司 | A kind of anti-microbial property test method of wet tissue product |
| CN110638359A (en) * | 2019-11-11 | 2020-01-03 | 苏州宝丽洁日化有限公司 | Preparation method of wet tissue without antibacterial agent residue on skin after use |
| CN114158568A (en) * | 2021-11-12 | 2022-03-11 | 兴业皮革科技股份有限公司 | Composite antibacterial agent and preparation method and application thereof |
| CN114158568B (en) * | 2021-11-12 | 2023-09-12 | 兴业皮革科技股份有限公司 | Composite antibacterial agent and preparation method and application thereof |
| WO2023101569A1 (en) * | 2021-12-03 | 2023-06-08 | Biovalley Spółdzielnia Socjalna | Method for obtaining antimicrobially active nonwoven fabric |
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| CN101736584B (en) | 2012-03-07 |
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Address after: 261205 No. 6446 Baotong Street, Weifang High-tech Zone, Shandong Province Patentee after: Junfu nonwovens Co., Ltd Address before: 261205 Shandong city of Weifang province Baotong Street No. 6446 Patentee before: Shandong Jofo Nonwoven Co., Ltd. |
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Effective date of registration: 20201117 Address after: Room 368, building B, Zhaoqing New Area Investment Development Co., Ltd., Beiba District, Guicheng, Dinghu District, Zhaoqing City, Guangdong Province Patentee after: ZHAOQING TIANYI NONWOVEN MATERIALS Co.,Ltd. Address before: 261205 No. 6446 Baotong Street, Weifang High-tech Zone, Shandong Province Patentee before: Junfu nonwovens Co.,Ltd. |
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Address after: 526070 room 368, factory building (b), Zhaoqing New District Investment Development Co., Ltd., eight districts north of Guicheng, Dinghu District, Zhaoqing City, Guangdong Province Patentee after: Junfu nonwovens (Zhaoqing) Co.,Ltd. Address before: 526000 room 368, workshop (Building B), Zhaoqing New District Investment Development Co., Ltd., No.8 District, Guicheng North, Dinghu District, Zhaoqing City, Guangdong Province Patentee before: ZHAOQING TIANYI NONWOVEN MATERIALS Co.,Ltd. |